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Technical Sodium Fluoride

NSN: 6810-00-059-9069 | Model: B-701
NSN Properties and Flags
NATO Stock Number
6810-00-059-9069
DEMIL
NO
Physical Form
Crystal
Quantity Within Each Unit Package
50.000 pounds
Composition And Percentage
42.9 by weight fluorine
Specification Data
06768-awwa b-701 professional/industrial association standard

Pricing and Availability

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NSN 6810-00-059-9069 Datasheet

Supply Class (FSC):
Chemicals
Cross Reference:
  • B-701
Cage Codes:
  • American Water Works Association (CAGE 06768)
Schedule B & Trade:
  • Schedule B: 2826191500 (NAICS 325180)

    Flourides of ammonium or of sodium

  • SITC: 52310

    Fluorides; fluorosilicates, fluoroaluminates and other complex fluorine salts

  • End Use: 12530

    Chemicals-inorganic

Identification:
HMIC

Y - Indicates information is in the hazardous materials information resource system (hmirs).

PMIC

A - Item does not contain precious metal.

CRITL

- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.

Freight Information:
  • NMFC:

    046340 - Sodiu (soda) fluoride

  • WCC:

    635 - Chemicals, other than drugs or sundries

  • SHC:

    9 - Other or no special handling required (sh)

  • ADC:

    A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.

  • ACC:

    C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp

  • TCC:

    P - Poison, class b, un class 6 (poison label)

  • LTL:

    W - Rating variable

NSN Management Codes:
  • SOS
    Sms
  • AAC
    V
  • Quantity per pack
    1
  • Unit of Measure
    Bg
  • Shelf Life
    N/A
  • Classification Control
    U
  • MGMT_CTL
    R2200x-
  • Repariability
    This is a nonreparable item. if condemned or economically unserviceable, then dispose at the level authorized replace the item.

Questions & Answers:

What are the historical prices recorded for this stock number?
Historical data shows pricing from $464.94 to $774.90..
Does NSN 6810-00-059-9069 have a shelf life?
No. There is no shelf life applicable for this NSN.
What NATO entities are users of this NSN?
Department Of The Army, Department Of The Air Force, and Department Of The Navy
What is the NIIN of NSN 6810-00-059-9069?
000599069 or 00-059-9069
Does NSN 6810-00-059-9069 require demilitarization?
Yes - ITAR Controlled
What is the most recent solicitation for NSN 6810-00-059-9069?
No solicitations for this NSN.
When was this national stock number assigned to the federal catalog?
Jan 01, 1960
MSDS

Material Safety

MSDS BCWPV SODIUM, FLUORIDE (CRYSTALLINE OR POWDER

Hazards

Routes of entry: inhalation: yes skin: unknown ingestion: yes
health hazards acute and chronic: acute: may irritate skin,eyes and
mucous membranes. Chronic: florosis
effects of overexposure: ingestion or inhalation may be harmful and
possibly fatal depending on severity and length of
over-exposure.May irritate skin,eye and mucuous membranes.Chronic
over.Exposure may cause"fluorosis"
medical cond aggravated by exposure: pre-existing conditions may be
worsen.

First Aid

First aid: oral: dilute with milk or limewater,induce vomiting,consult
physician;inhalation: remove to fresh air.Use artificial respiration
or oxygen as needed,consult physician;eyes: irigate with
water,consult a p hysician;skin: wash with soap and water.

Chemical Properties

Hcc: t4
boiling pt: b.P. Text: 3108f/1709c
solubility in water: moderate,4% (at oc)
appearance and odor: crystalline or powder

Reactivity

Stability indicator/materials to avoid: yes
acids
stability condition to avoid: extreme heat,water(moisture)
hazardous decomposition products: highly toxic,corrosive hf

Proper Disposal

Waste disposal methods: dispose of collected material in accorance with
local,state and federal regulations.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium fluoride (sara iii)
cas: 7681-49-4
rtecs #: wb0350000
fraction by wt: 97.0%
osha pel: 2.5 ppm f
acgih tlv: 2.5 mg f/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs

ingred name: unidentified components

MSDS BCWPW SODIUM FLUORIDE,TECHNICAL

Hazards

Effects of overexposure: irritates strongly the tissue by inhalation or
swallowing,nausea,vomiting,stomachache,diarrhea,coma

First Aid

First aid: move victim to fresh air;call emergency medical care.Remove &
isolate contaminated clothing & shoes. In case of contact with
material,immediately flush skin or eyes with running water for at
least 15 mins.

Chemical Properties

Hcc: t4
boiling pt: b.P. Text: 3090f
spec gravity: 1.04
solubility in water: slight
appearance and odor: white,crystal,or powder colored blue for identify.

Reactivity

Stability indicator/materials to avoid: yes
none,other than acidic substances
hazardous decomposition products: none

Proper Disposal

Waste disposal methods: dispose in chemical dump-or flush to an approved
disposal area with large quantities of water,or remove slowly into
a large container of water.Add soda ash slightly by stirring.After
24 hrs,decant or siphon into another container.Neutralizew/6m hcl.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium fluoride (sara iii)
cas: 7681-49-4
rtecs #: wb0350000
osha pel: 2.5 ppm f
acgih tlv: 2.5 mg f/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs

ingred name: fluorine (sara iii)
cas: 7782-41-4
rtecs #: lm6475000
fraction by wt: 47.9%
osha pel: 0.1 ppm
acgih tlv: 1 ppm/2 stel; 9192
epa rpt qty: 10 lbs
dot rpt qty: 10 lbs

MSDS BCWPX SODIUM FLUORIDE,COARSE CRYSTALLINE

Hazards

Ld50 lc50 mixture: oral rat =80 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: unknown iarc: no osha: no
health hazards acute and chronic: acute: corrosive to eyes and skin &
respiratory tract;skin: redness,pain,large open boil like
sore;eyes: redness,pain or blurred vision;abdominal pain,poisoning
and may cause internal bleeding. chronic: irritation,chronic
poisoning.

explanation of carcinogenicity: no
effects of overexposure: skin-may cause formation of lge,open,boil-like
sores,esp in presence of water. Ingest-may produce chronic
poisoning; on contact w/stomach acids can cause internal bleeding.

medical cond aggravated by exposure: pre-existing conditions may be
worsen.

First Aid

First aid: eye & skin-flush w/lge quantities of water; get med attn.

inhal-get to fresh air; if discomfort persist,get med attn.

ingest-drink lge quantity water or 1% calcium chloride soln or lime
water if avail able. Do not induce vomit! Seek med attnimmed.

Chemical Properties

Hcc: t4
boiling pt: b.P. Text: 1695c/3083f
vapor pres: .01
spec gravity: 2.56
evaporation rate & reference: 0.0 (ether=1)
solubility in water: moderate
appearance and odor: white solid,granular or powder,no odor
percent volatiles by volume: 0.0

Reactivity

Stability indicator/materials to avoid: yes
strong acids.

stability condition to avoid: keep away from acids.

hazardous decomposition products: hf produced if mixed with acid

Proper Disposal

Waste disposal methods: dispose of collected material in accordance with
local,state and federal regulations.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium fluoride (sara iii)
cas: 7681-49-4
rtecs #: wb0350000
fraction by wt: 100.0%
osha pel: 2.5 ppm f
acgih tlv: 2.5 mg f/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs

MSDS BLHFQ SODIUM FLUORIDE

Hazards


ld50 lc50 mixture: ld50 (oral rat) is 180 mg/kg
route of entry inds - inhalation: yes
skin: yes
ingestion: no
carcinogenicity inds - ntp: no
iarc: no
osha: no
effects of exposure: acute: inhalation of dust or mist may cause severe mucous
membrane irritation & burns. Effects may not be immediately apparent,
especially with dilute solutions. Chronic: causes severe skin irritation &
burns. Ingestion/inhalation may be harmful & possibly fatal. May be
absorbed through skin & cause fluorosis.

explanation of carcinogenicity: no ingredient of a concentration of 0.1% or
greater is listed as a carcinogen or suspected carcinogen.

signs and symptions of overexposure: mucous membrane irritation/burns, severe
skin irritation/burns, may produce signs of fluorosis such as weight loss,
brittleness of bones, anemia, weakness and stiffness of joints. Internal
bleeding ma y develop.

medical cond aggravated by exposure: any skin, respiratory or mucous membrane
condition
first aid: get medical care.Inhalation: remove to fresh air.Give cpr if
needed.Keep person warm and at rest.Eyes: immediately flush with water for 15
minutes holding eyelids open.Contact an eye specialist immediat ely.Skin: wash
with soap/mild detergent & water.Ingestion: do not induce vomiting.If
conscious,drink several glasses of water or milk.Note to physician: exposed
person should be observed for 48-72 hours.

Chemical Properties


hcc: t4
b.P. Text: 3099f,1704c
m.P/f.P text: 1796f,980c
decomp text: unknown
vapor pres: <0.01@200c
spec gravity: 2.726
viscosity: unknown
solubility in water: moderate
appearance and odor: white, crystalline powder; no odor.

corrosion rate: unknown

HAZCOM Label


product id: sodium fluoride
cage: 75656
company name: los angeles chemical co
street: 4545 ardine st
po box: 1987
city: south gate ca
zipcode: 90280
health emergency phone: 213-664-2121/800-424-9300
label required ind: y
date of label review: 04/17/1997
status code: c
label date: 04/17/1997
year procured: 1997
origination code: f
eye protection ind: yes
skin protection ind: yes
signal word: danger
respiratory protection ind: yes
health hazard: severe
contact hazard: severe
fire hazard: none

Transportation

=======================================================
responsible party cage: 75656
trans id no: 45227
product id: sodium fluoride
msds prepared date: 03/01/1996
review date: 04/17/1997
mfn: 1
net unit weight: 100.0 lbs
multiple kit number: 0
review ind: y
unit of issue: bg
container qty: 0
type of container: un 5m2 bag
additional data: psn is per mfr msds. Reportable quantity is 1000 lbs per msds.

Reactivity

Hazard and precautions: acute: inhalation of dust or mist may cause severe
mucous membrane irritation & burns.Chronic: causes severe skin irritation
& burns.Ingestion/inhalation may be harmful & possibly fatal.May be
absorbed through skin & cause fluorosis. First aid: get medical
care.Inhalation: remove to fresh air.Give cpr if needed.Keep person warm &
at rest.Eyes: immediately flush with water for 15 minutes,lift lids.Conta ct
an eye specialist.Skin: wash with soap/mild detergent & water.Ingestion: do
not induce vomiting.If conscious,drink several glasses of water or milk.Note
to physician: exposed person should be observed for 48-72 hours.Target
organs: lungs,skin,eyes.

Proper Disposal


spill release procedures: wear niosh approved protective clothing and breathing
apparatus. Isolate spill area. Carefully shovel material and place in clean
dry container and cover. Avoid raising dust.

neutralizing agent: none specified by manufacturer.

waste disposal methods: disposal should be subject to all applicable federal,
state and local laws and regulations.

handling and storage precautions: storage-store in a cool dry place,away from
acids.Use only with adequate ventilation,dust mask/self-contained breathing
apparatus.

other precautions: do not raise dust. Keep container closed. Avoid contact with
eyes, skin and clothing. Avoid breathing dust or mist. Protective clothing
should always be worn. In fire, it will decompose, releasing hig hly toxic
hydrogen fluoride gas.

MSDS BMWFV SODIUM SILICOFLUORIDE

Hazards

Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute- highly irritating and toxic by
inhalation and ingestion. Large doses can cause nausea,
vomiting,ciculatory and respiratory problems. Chronic-sclerosis,
pulmonary fibrosis.

effects of overexposure: may produce signs of fluorosis such as weight
loss, brittleness of bones, anemia, weakness and stiffness of
joints. Internal bleeding may develop., nausea, dirrhea, vomting,
abdominal pain, breathing difficulty, coughing, skin irritation.

medical cond aggravated by exposure: respiratory diseases including
asthma and emphysema.

First Aid

First aid: inhalation: remove to fresh air.Give cpr if needed.

eyes: immediately flush with water for 15 minutes holding eyelids
open. Get medical help immediately. Skin: wash with soap & water.

ingestion: induce vo miting. If conscious,drink several glasses of
water or milk. In all cases, seek medical help.

Chemical Properties

Hcc: t4
spec gravity: 2.67
solubility in water: 0.44% @ 0c
appearance and odor: white, crystalline powder, odorless.

Reactivity

Stability indicator/materials to avoid: yes
strong acids
stability condition to avoid: extreme temperatures such as fire
hazardous decomposition products: sodium oxide, hydrofluoric acids and
fluorine.

Proper Disposal

Waste disposal methods: disposal should be subject to all applicable
federal, state and local laws and regulations.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium silicofluoride
cas: 16893-85-9
rtecs #: vv8410000
fraction by wt: 99.5%
other rec limits: none specified

MSDS BTHGG SODIUM FLUORIDE, COARSE

Hazards

Ld50 lc50 mixture: ld50, oral, rat = 180mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhal: severe muc memb irrit
w/cough,sore throat,shortness of breath & labored breath.Repeated
expo to excessive fluoride conc over yrs results in incr bone dens
& eventually crippling fluorosis.Dust: s kin irrit.Sodium fluoride
corr in aqy soln,severe burns,eye irrit.Igest corr of gastric
muc.Ser pois,death.

explanation of carcinogenicity: per msds: prod contains detectable amts
of chem known to state of ca to cause cancer/birth defects or other
reprod harm.

effects of overexposure: cough,sore throat,short of breath,labored
breath.Bone den,cripp fluorosis.Skin irrit,red,pain.Sodium
fluoride: seve burns&eye irrit,red,pain,blurred vision.Corr of
gastric muc: nau,vomit,diarr,adb pain, thirst.Ser
pois: weak,tremors,convulsions,collapse,low blood calcium
levels,coma,resp failure,vent fibr,wt loss,anemia.

medical cond aggravated by exposure: none specified by manufacturer.

First Aid

First aid: eye: flush w/lg quant of water for @least 15mins.Get med attn
immed. Skin: remove contamin cloth/shoes.Wash skin w/soap/water.Get
med attn. Inhal: remove to fresh air.Breath stop give art resp.Get
med at tn. Ingest: if conscious drink lg quant of water, 1% calcium
chloride soln or calcium gluconate.Do not induce vomit.Get med attn
immed.

Chemical Properties

Hcc: t4
boiling pt: b.P. Text: 3099f,1704c
solubility in water: 4% @25c
appearance and odor: white granular solid; little or no odor.

Reactivity

Stability indicator/materials to avoid: yes
acids, glass, aluminum.

stability condition to avoid: when dissolved in water sodium fluoride
forms a corr soln which may attack glass or aluminum.

hazardous decomposition products: therm decomposition may release haz
fumes of hydrogen fluoride & sodium oxides.

Proper Disposal

Waste disposal methods: follow local, state and federal regulations.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium fluoride (cercla)
cas: 7681-49-4
rtecs #: wb0350000
fraction by wt: 97-100%
other rec limits: none recommended
osha pel: 2.5 ppm (f)
acgih tlv: 2.5 mg (f/)m3; 9495
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs

ingred name: sodium silicofluoride
cas: 16893-85-9
rtecs #: vv8410000
fraction by wt: 0-2.5%
other rec limits: none recommended

MSDS BTVWG SODIUM FLUORIDE

Hazards

Ld50 lc50 mixture: not given for product as a whole
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: strong irritant to mucous membranes.

irritant to moist skin; may cause ulders. Severe irritant to eyes.

irritatnt to digestive tract.

explanation of carcinogenicity: this compound contains no ingredients at
concentrations of 0.1% or greater that are carcinogens or suspect
carcinogens.

effects of overexposure: eye irritation, skin irritation, mucous
membrane irritation, nausea, vomiting, diarrhea.

medical cond aggravated by exposure: none specified by manufacturer.

First Aid

First aid: eyes: flush with water for 15 minutes while holding eyelids
open. Get medical attention. Skin: remove contaminated clothing.

wash with soap and water. If irritation persists, get medical
attention. In halation: remove to fresh air. Restore breathing. Get
medical attention. Ingestion: induce vomiting. Give large quantity
of water. Antidote: antacid, lime water or milk. Get medical
attention.

Chemical Properties

Hcc: t4
boiling pt: b.P. Text: 3083f,1695c
melt/freeze pt: m.P/f.P text: 1819f,993c
vapor pres: not given
vapor density: not given
spec gravity: 2.78
evaporation rate & reference: not given
solubility in water: soluble
appearance and odor: white crystalline solid

Reactivity

Stability indicator/materials to avoid: yes
strong acids
stability condition to avoid: none specified by manufacturer.

hazardous decomposition products: hydrogen fluoride
conditions to avoid polymerization: glass or enameled equipment

Proper Disposal

Waste disposal methods: prevent waste from contaminating surrounding
environment. Discard any product, residue, disposal container or
liner in accordance with all federal, state and local regulations.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium fluoride (sara iii)
cas: 7681-49-4
rtecs #: wb0350000
fraction by wt: 98.9% %
other rec limits: none recommended
osha pel: 2.5 ppm (f)
acgih tlv: 2.5 mg (f)/m3; 9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs

MSDS CDFYY SODIUM FLUORIDE

Hazards


ld50 lc50 mixture: ld50 (oral, rat) 180 mg/kg
route of entry inds - inhalation: yes
skin: yes
ingestion: yes
carcinogenicity inds - ntp: no
iarc: no
osha: no
effects of exposure: acute: inhalation ofdustormist may cause
severemucousmembraneirritation & burns. Effects may bot be immediately
apparent, especially with dilute solution. First aid procedures should be
followed even in cases of suspected contact. Chronic: causes severe skin
irritation. Ingestion or inhalation may be harmful & possibly
fataldepending on severity & length of overexposure.May cause fluorosis.

explanation of carcinogenicity: none
signs and symptions of overexposure: product may be absorbed through the skin
and produce signs of fluorosis, such as weight loss, brittleness of bones,
anemia,weaknessandstiffness ofjoints.Internal bleeding may develop.

medical cond aggravated by exposure: any skin, respiratory ormucous membrane
conditions.

first aid: inhalation-remove the exposed person to fresh air at once. If
breathing has stopped, perform artificial respiration.Keep person warm &
at rest. Get medical aid as soon as possible. Eye-immediately flu sh eyes
with large amounts of water. Getmedical aid as soon as possible (eye
specialist). Skin-promptly wash skin using soap & mild detergent &
water. If soaks through clothing, remove promptly & wash skin using soap
or mild detergent & water. Give medicalaidas soon as possible for all
burns. Ingestion-have the person drink as much water as possible. Do not
induce vomiting. Give several glasses of milk. Contact physician
immediately.

Chemical Properties


hcc: t4
nrc/state lic no: not relevant
boiling point: =1704.C, 3099.2f
m.P/f.P text: 980-1040c
decomp text: unknown
spec gravity: 2.726 18c
viscosity: not relevant
solubility in water: 4g/100g h20 0c
appearance and odor: white crystalline powder - odorless

HAZCOM Label


product id: sodium fluoride
cage: 0k1e4
company name: lucier chemical industry dba lci ltd
street: 415 pablo ave n
po box: 49000
city: jacksonville beach fl
zipcode: 32240-9000
health emergency phone: 904-241-1200
label required ind: y
date of label review: 09/28/1999
status code: c
mfg label no: unknown
label date: 02/24/1997
year procured: 1997
origination code: f
chronic hazard ind: y
eye protection ind: yes
skin protection ind: yes
signal word: warning
respiratory protection ind: yes
health hazard: moderate
contact hazard: moderate
fire hazard: none

Transportation

=======================================================
responsible party cage: 0k1e4
trans id no: 45219
product id: sodium fluoride
msds prepared date: 02/01/1993
review date: 03/19/1999
mfn: 1
radioactivity: not relevant
net unit weight: 100 lbs
multiple kit number: 0
review ind: y
unit of issue: bg
container qty: 0
type of container: un 5m2 bag
additional data: dot proper shipping name, un id number, hazard class per msds.

Reactivity

Hazard and precautions: target organs: eye, skin, respiratory & gi tracts.

acute- toxic. May cause eye burns. May be abosrbed through skin. Ingestion
may be fatal. Inhalation may cause severe irritation of mucous membranes
& burns. Chronic- causes fluorosis, internal bleeding, anemia. Store
away from acids. Sweep up spill & place in a suitable container for
disposal. First aid- get medical help if symptoms persist. Inhale d: remove to
fresh air. Provide cpr/oxygen if needed. Eyes: flush with water for 15
minutes. Hold eyelids open. Skin: wash with soap & water. Oral: if
conscious, drink milk (calcium) or large amount of wa ter. Get medical
attention immediately.

Proper Disposal


spill release procedures: employees should be trained in safety procedures for
handling this product. Wear niosh approved protective clothing &
breathing apparatus. Isolate product spill area. Carefully shovel material
& place in clean dry container & cover. Removecontainer from spill
site & dispose of in accordance with federal,state & local
regulations. Chemtrec can be contacted for 24-hour emergency assistance.

waste disposal methods: used or unused product shouldbe tested to determine
hazard status and comply with federal, state and local disposal or discharge
laws. reportable quantity (rq): 1000 pounds.

handling and storage precautions: store in a cool, dry, place away from acids.

use only with adequate ventilation, dust mask or self-contained breathing
apparatus. Protective clothing should always be worn. Avoid contact with
eyes, sk in & clothing. Keeping bag or containerclosed when not in use.

avoid breathing dust or mist.

other precautions: if chemical should become heated, as in a fire, it will
decomposes, releasing highly toxic hydrogen fluoride gas.