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Sulfuric acid and oleum
Sulfuric acid; oleum
Chemicals-inorganic
Y - Indicates information is in the hazardous materials information resource system (hmirs).
PMICA - Item does not contain precious metal.
CRITL- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.
043940 - Chemicals noi
450 - Acids, liquid, corrosive
9 - Other or no special handling required (sh)
A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.
C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp
W - Rating variable
W - Corrosive materials, un class 8 (corrosive label)
Questions & Answers: |
|
| What are the historical prices recorded for this stock number? | |
| Historical data shows pricing from $66.26 to $110.43.. | |
| Does NSN 6810-00-236-0702 have a shelf life? | |
| No. There is no shelf life applicable for this NSN. | |
| What NATO entities are users of this NSN? | |
| Department Of The Army, Department Of The Air Force, U.s. Marine Corps, Department Of The Navy, U.s. Coast Guard, and Canada | |
| What is the NIIN of NSN 6810-00-236-0702? | |
| 002360702 or 00-236-0702 | |
| Does NSN 6810-00-236-0702 require demilitarization? | |
| Yes - ITAR Controlled | |
| What is the most recent solicitation for NSN 6810-00-236-0702? | |
| No solicitations for this NSN. | |
| When was this national stock number assigned to the federal catalog? | |
| Oct 31, 1969 | |
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
effects of overexposure: causes severe burns to skin and eyes. Inhaling
mist will injure lungs.
First aid: eyes and skin: flush with plenty water for at least 15
minutes. Call a doctor immediately. Ingestion: call a doctor
immediately. Stomach wash is indicated.
Hcc: c1
spec gravity: 1.2085 - 1.2185
evaporation rate & reference: < 1.0 (ether)
solubility in water: complete
appearance and odor: slightly viscous, clear to slightly cloudy liquid.
Stability indicator/materials to avoid: yes
flammables, combustibles, nitrates, oxidizers, carbides, metals
stability condition to avoid: high heat, moisture
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: place neutralized absorbed material in
containers suitable for shipping corrosive wastes to disposal area.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 28.3%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: ld50 (oral rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: inhalation of vapors may cause
severe irritation or burns of the respiratory system, pulmonary
edema, or lung inflammation. May cause severe burns to skin or
eyes. Ingestion may cause severe bu rns to mouth, throat, and
stomach. May affect kidney function. Chronic: may damage lungs.
explanation of carcinogenicity: this product is not listed by iarc, ntp,
or osha as a carcinogen.
effects of overexposure: severe irritation or burns to eyes, nose and
throat. Pulmonary edema, bronchial emphysema, conjunctivitis,
stomatitis, dental erosion, nausea and vomiting.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the respiratory tract may
be at increased risk from exposure.
First aid: inhalation: remove to fresh air. Resuscitate if not
breathing. Get medical attention. Eyes: immediately flush with
plenty of water for 15 minutes holding eyelids open. Get medical
attention. Skin: rem ove contaminated clothing. Wash with plenty of
water for 15 minutes. Get medical advice. Ingestion: do not induce
vomiting. Give nothing by mouth if unconscious. Get immediate
medical attention.
Hcc: c1
boiling pt: b.P. Text: 380f,193c
melt/freeze pt: m.P/f.P text: -31f,-35c
vapor pres: < 0.3
vapor density: 3.4
spec gravity: 1.21
ph: < 1.0
evaporation rate & reference: < 1 (butyl acetate = 1)
solubility in water: complete
appearance and odor: oily, clear to turbid, colorless to light gray
liquid withno odor.
Stability indicator/materials to avoid: yes
water, alkaline solutions, metals, metal powders, carbides, chlorates,
fulminates, nitrates, picrates, organic materials
stability condition to avoid: high heat, moisture
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state, and local environmental regulations. Do
not flush to surface water or sanitary sewer system.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 29.5%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 70.5%
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
effects of overexposure: eyes and skin: will cause burns. Inhalation:
mist will burn/severely irritate respiratory system. Ingestion:
injury.
First aid: eyes and skin: immediately flush with plenty of water for at
least 15 minutes. Get immediate medical attention. Inhalation and
ingestion: get immediate medical attention.
Hcc: c1
boiling pt: b.P. Text: 220f,104c
spec gravity: 1.03
solubility in water: complete
appearance and odor: substantially clear liquid like water.
Stability indicator/materials to avoid: yes
metals, combutible materials.
stability condition to avoid: high heat, moisture
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: neutralize and flush to authorized drain site
with plenty of water. Observe federal, state, and local
regulations. If draining of neutralized material to an authorized
drain site is not allowed, have waste disposed of by an authorized
disposal firm.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 28.9%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
effects of overexposure: causes severe burns to eyes and skin.
inhalation of mist from hot acid can be injurious to lungs.
First aid: in case of contact immediately flush skin or eyes with plenty
of water for at least 15 minutes. For eyes or skin burns, get
immediate medical attention. Soak skin in water or swab generously
up to 30 minutes while awaiting physician.
Hcc: c1
boiling pt: b.P. Text: 233f,112c
vapor pres: 0
vapor density: 2.7
spec gravity: 1.300
solubility in water: complete
appearance and odor: slightly viscous, clear to slightly cloudy liquid
with no odor.
Stability indicator/materials to avoid: yes
combustible materials, nitrates, carbides, chlorates, powdered metals.
stability condition to avoid: high heat, moisture
hazardous decomposition products: hydrogen gas, oxides of sulfur,
hydrogen sulfide
Waste disposal methods: keep in covered drums, pending disposal. Handle
and dispose of in full compliance with all applicable
international, federal, state, and local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 29.5%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 70.5%
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
effects of overexposure: skin irritant. Severe damage may occur if
induced into human eyes.
First aid: irrigate eyes with water. Wash contaminated area of body with
soap and water. Stomach wash if swallowed. Oxygen with use of
intermittent positive pressure breathing apparatus. 5% solution of
sodium bi carbonate as aerosol may be used, as well as
decongestant.
Hcc: c1
solubility in water: complete
appearance and odor: colorless liquid
Stability indicator/materials to avoid: yes
metals, sulfides
stability condition to avoid: high heat, moisture
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: add slowly to a large amount of solution of soda
ash and slaked lime by stirring. Discharge solution into approved
storage container for corrosives.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 28.3%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: ld50 oral rat = 2.14 g/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: chronic: dermatitis, tooth erosion,
chronic cough. Acute: burns, rapid destruction to all tissues
contacted. May cause respiratory irritation.
First aid: eyes: flush with plenty of water for at least 15 minutes. See
doctor. Skin: remove contaminated clothing and shoes. Wash with
soap and water. See doctor. Inhalation: remove victim to fresh air.
give o xygen/cpr if needed. See doctor. Ingestion: do not induce
vomiting. Wash out mouth with water. Give large quantities of water
to drink. Call a physician.
Hcc: c1
spec gravity: 1.265
ph: < 1
solubility in water: complete
appearance and odor: clear liquid.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
solvents, oxidizers, combustible materials, organic materials, alkalis,
powdered metals, amines.
stability condition to avoid: high heat, moisture
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: dispose of in accordance with all applicable
federal, state, and local environmental regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 28.9%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: bal
Ld50 lc50 mixture: ld50 (oral rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: chronic: inhalation of vapors may
cause severe irritation or burns of the respiratory system,
pulmonary edema, or lung inflammation. May cause severe burns to
skin or eyes. Ingestion may cause severe burns to mouth, throat,
and stomach. May affect kidney function. Chronic: may damage lungs.
explanation of carcinogenicity: this product is not listed by iarc, ntp,
or osha as a carcinogen.
effects of overexposure: severe irritation or burns to eyes, nose and
throat. Pulmonary edema, bronical emphysema, conjunctivitis,
stomatitis, dental erosion, nausea and vomiting.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the respiratory tract may
be at increased risk from exposure.
First aid: inhalation: remove to fresh air. Resuscitate if not
breathing. Get medical attention. Eyes: immediately flush with
plenty of water for 15 minutes holding eyelids open. Get medical
attention. Skin: rem ove contaminated clothing. Wash with plenty of
water for 15 minutes. Get medical advice. Ingestion: do not induce
vomiting. Give nothing by mouth if unconscious. Get immediate
medical attention.
Hcc: c1
solubility in water: soluble
appearance and odor: colorless liquid
Stability indicator/materials to avoid: yes
combustibles, reducing agents, strong bases.
stability condition to avoid: high heat, moisture
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state, and local environmental regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt:
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: >63.0%
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: chronic: inhalation of vapors may
cause severe irritation or burns of the respiratory system,
pulmonary edema, or lung inflammation. May cause severe burns to
skin or eyes. Ingestion may cause severe burns to mouth, throat,
and stomach. May affect kidney function. Chronic: may damage lungs.
effects of overexposure: severe irritation or burns to eyes, nose and
throat. Pulmonary edema, bronical emphysema, conjunctivitis,
stomatitis, dental erosion, nausea and vomiting.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the respiratory tract may
be at increased risk from exposure.
First aid: inhalation: remove to fresh air. Resuscitate if not
breathing. Get medical attention. Eyes: immediately flush with
plenty of water for 15 minutes holding eyelids open. Get medical
attention. Skin: rem ove contaminated clothing. Wash with plenty of
water for 15 minutes. Get medical advice. Ingestion: do not induce
vomiting. Give nothing by mouth if unconscious. Get immediate
medical attention.
Hcc: c1
boiling pt: b.P. Text: 230f,110c
vapor pres: 11.8
vapor density: 3.4
spec gravity: 1.84
solubility in water: complete
appearance and odor: colorless to cloudy liquid.
Stability indicator/materials to avoid: yes
combustible material, strong reducing agents, metals, carbides, organic
materials, chlorates.
stability condition to avoid: high heat, moisture
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state, and local environmental regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
other rec limits: none specified
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
other rec limits: none specified
Ld50 lc50 mixture: ld50 oral rat is 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: acute: severe burns and ulceration of
skin, eyes, mouth, throat, esophagus and stomach. Inflammation of
bronchial membranes. Chronic: erosion of teeth, inflammation of
nose, throat and bronchial tubes .
explanation of carcinogenicity: sulfuric acid mists are classified
iarc-2b.
effects of overexposure: if contacted, severe burns and ulceration of
skin and eyes. If inhaled, severe respiratory irritation. If
ingested, severe burns and ulceration.
medical cond aggravated by exposure: sulfuric acid may aggravate skin
diseases such as eczema and dermatitis.
First aid: eyes/skin: flush with plenty of water. See doctor
immediately. Remove contaminated clothing and shoes. Inhalation:
remove to fresh air. Give oxygen/cpr if needed. See doctor.
ingestion: do not induce vomiting. Give milk or water, followed by
2 ounces of milk of magnesia (no carbonates). See doctor
immediately.
Hcc: c1
boiling pt: b.P. Text: 590f (94%)
melt/freeze pt: m.P/f.P text: -17f (94%)
vapor pres: 0.001(94%)
vapor density: 3.38
spec gravity: 1.21 (from tir)
ph: acidic
solubility in water: complete
appearance and odor: oily, colorless to slightly yellow, clear to turbid
liquid. Odorless.
Stability indicator/materials to avoid: yes
organic materials, nitro-compounds, carbides, dienes, alcohols, water,
powdered metals, some non-acid-resistant plastics
stability condition to avoid: temperatures above 572f or higher yield
sulfur trioxide gas, which is toxic, corrosive and an oxidizer.
hazardous decomposition products: sulfuric acid fumes, sulfur dioxide,
sulfur trioxide.
Waste disposal methods: consult your local environmental officer.
dispose of in accordance with federal, state and local
environmental regulations. Epa hazardous waste number d002
corrosive.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 29%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: product's ld50 (oral rat) was not stated
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: third degree burns. Severe
respiratory, skin, and eye irritant. Bronchitis, laryngeal and
pulmonary edema may result.
explanation of carcinogenicity: iarc lists a possible link between
sulfuric acid exposure & laryngeal cancer w/insufficient data for
confirmation.
effects of overexposure: prickling or burning sensation of skin and
mucous membranes. Coughing, sneezing, tightness of chest,
difficulty in breathing.
medical cond aggravated by exposure: any pre-existing respiratory
disease, for example emphysema.
First aid: see supp data. Get immediate medical attention!! Eye: flush
w/water for 15 min. Skin: wash w/soap & water. Remove contaminated
clothing & launder before reuse. Inhaled: remove from exposure. Aid
or resto re breathing as needed. Ingested: do notinduce vomiting.
give large quantities of milk, milk of magnesia, table oil, eggs or
water to drink. Get immediate medical attention. Rinse mouth often.
Hcc: c1
nrc/state lic num: none
boiling pt: b.P. Text: 275f,135c
melt/freeze pt: m.P/f.P text: -80f, 35%
vapor pres: < 1
vapor density: 3.4 (air=1
spec gravity: 1.265
ph: < 1
solubility in water: complete
appearance and odor: clear, colorless liquid.
percent volatiles by volume: unk.
Stability indicator/materials to avoid: yes
metals, organics, nitrates, carbides, chlorates, allyl compounds, and
aldehydes
stability condition to avoid: contact with metals, organics.
hazardous decomposition products: sulfur oxides at high temperature.
reacts w/above to form hydrogen cyanide & hydrogen cyanide.
conditions to avoid polymerization: will not occur. avoid all contact
with organic substances and most metals.
Waste disposal methods: neutralize w/lime or soda ash. Consult
regulations. Epa hazardous waste d002- corrosive & d003-reactive if
discarded w/o prior neutralization.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 34-36%
other rec limits: none specified
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 64-66%
other rec limits: none specified
Ld50 lc50 mixture: ld50 (oral rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: **corrosive** inhalation of vapors may
cause severe irritation or burns of the respiratory system,
pulmonary edema, or lung inflammation. May cause severe burns to
skin or eyes. Blindness may result. ingestion may cause severe
burns to mouth, throat, and stomach. May affect kidney function.
chronic: may damage lungs.
explanation of carcinogenicity: this product is not listed by iarc, ntp,
or osha as a carcinogen.
effects of overexposure: severe irritation or burns to eyes, nose and
throat. Pulmonary edema, bronchial emphysema, conjunctivitis,
stomatitis, dental erosion, nausea and vomiting.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the respiratory tract may
be at increased risk from exposure.
First aid: eyes/skin: immediately flush with plenty of water for at
least 15 minutes while removing contaminated clothing. Inhalation:
remove to fresh air. Observe for possible delayed reaction. Give
oxygen/cpr if needed. Ingestion: do not induce vomiting. Give
several glasses of milk (preferred) or water. For all exposures,
get immediate medical attention.
Hcc: c1
boiling pt: b.P. Text: 275f,135c
vapor density: >1
spec gravity: 1.211
ph: acidic
appearance and odor: liquid,turbid,oily;colorless to slightly
yellow;odorless.
corrosion rate: corrosiv
Stability indicator/materials to avoid: yes
metals,organic substances.
stability condition to avoid: none specified by manufacturer.
hazardous decomposition products: oxides of sulfur,which further reacts
subject material to form hydrogen cyanide and hydrogen sulfide.
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state and local environmental regulations. Epa
hazardous waste number, d0002(corrosive) and d003(reactive).
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 28-29.5%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 20.5%
other rec limits: none recommended
Ld50 lc50 mixture: rat,lc50: 347ppm/1 hr;ld50(oral)2140mg/kg
routes of entry: inhalation: no skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eye, skin, respiratory &
gi tracts. Acute- corrosive! Causes severe eyes, skin & all body
tissue burns. Eye damage may be permanent. May cause skin
ulceration. Mist is irritating to resp iratory tract. Ingestion
causes severe burns. Chronic- may cause dental erosion, impaired
lung function.
explanation of carcinogenicity: none
effects of overexposure: severe irritation and burning, visual
impairment, dental erosion, cough, severe pain, blindness,
wheezing, abnormal lung sounds, skin ulcer, itching and rash,
bleeding, vomiting, diarrhea
medical cond aggravated by exposure: open wounds and sores, respiratory
ailments such as emphysemia and bronchitis
First aid: get medical attention immediately. Eye/skin: immediately flush
with cold water for 15-20 minutes. Hold eyelids open. Continue
rinsing eyes with normal saline until ph=7. Inhaled: remove to fresh
air. Pr ovide oxygen/cpr if needed. Oral: do notinduce vomiting. If
conscious, drink large amount of water. Never give anything by
mouth to an unconscious person.
Hcc: c1
nrc/state lic num: not relevant
boiling pt: b.P. Text: 210f - 250f
melt/freeze pt: m.P/f.P text: -25f to-37f
vapor pres:
vapor density: 3.4
spec gravity: 1.074 - 1.370
ph:
evaporation rate & reference:
solubility in water: 100%
appearance and odor: clear liquid - odorless
Stability indicator/materials to avoid: yes
bases, carbides, metals, strong oxidizing, reducing/organics, water,
cyanides, sulfides, combustibles, metal powders
stability condition to avoid: adding water to acid (always add acid
slowly to water)
hazardous decomposition products: sulfur dioxide
Waste disposal methods: dispose of in accordance with all local, state,
and federal regulations. Epa and superfund reportable discharge is
1000 lbs. If approved, neutralize and transfer to waste treatment
system.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara 302/313) (cercla)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 10 - 51%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3/3 stel; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: product's ld50 (oral rat) was not stated
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: third degree burns. Severe
respiratory, skin, and eye irritant. Bronchitis, laryngeal and
pulmonary edema may result.
explanation of carcinogenicity: iarc lists a possible link between
sulfuric acid exposure & laryngeal cancer w/insufficient data for
confirmation.
effects of overexposure: prickling or burning sensation of skin and
mucous membranes. Coughing, sneezing, tightness of chest,
difficulty in breathing.
medical cond aggravated by exposure: any pre-existing respiratory
disease, for example emphysema.
First aid: see supp data. Get immediate medical attention!! Eye: flush
w/water for 15 min. Skin: wash w/soap & water. Remove contaminated
clothing & launder before reuse. Inhaled: remove from exposure. Aid
or resto re breathing as needed. Ingested: do notinduce vomiting.
give large quantities of milk, milk of magnesia, table oil, eggs or
water to drink. Get immediate medical attention. Rinse mouth often.
Hcc: c1
nrc/state lic num: none
boiling pt: =135.C, 275.F
melt/freeze pt: =-62.2c, -80.F
vapor pres: < 1
vapor density: 3.4 (air=1
spec gravity: 1.265
ph: < 1
solubility in water: complete
appearance and odor: clear, colorless liquid.
percent volatiles by volume: unk.
Stability indicator/materials to avoid: yes
metals, organics, nitrates, carbides, chlorates, allyl compounds, and
aldehydes
stability condition to avoid: contact with metals, organics.
hazardous decomposition products: sulfur oxides at high temperature.
reacts w/above to form hydrogen cyanide & hydrogen sulfide.
conditions to avoid polymerization: will not occur. avoid all contact
with organic substances and most metals.
Waste disposal methods: neutralize w/lime or soda ash. Consult
regulations. Epa hazardous waste d002- corrosive & d003-reactive if
discarded w/o prior neutralization.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 34-36%
other rec limits: none specified
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 64-66%
other rec limits: none specified