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Dichloromethane (methylene chloride)
Saturated chlorinated derivatives of acyclic hydrocarbons, n.E.S.
Chemicals-organic
Y - Indicates information is in the hazardous materials information resource system (hmirs).
PMICA - Item does not contain precious metal.
CRITL- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.
045310 - Methylene chloride etc
635 - Chemicals, other than drugs or sundries
9 - Other or no special handling required (sh)
A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.
C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp
P - Poison, class b, un class 6 (poison label)
T - 55.0
Questions & Answers: |
|
| What are the historical prices recorded for this stock number? | |
| Historical data shows pricing from $646.79 to $1,077.98.. | |
| Does NSN 6810-00-244-0290 have a shelf life? | |
| No. There is no shelf life applicable for this NSN. | |
| What NATO entities are users of this NSN? | |
| Department Of The Army, Department Of The Air Force, U.s. Marine Corps, Department Of The Navy, U.s. Coast Guard, Bureau Of Engraving and Printing, Brazil, Spain, Republic Of Korea, Portugal, Greece, and Turkey | |
| What is the NIIN of NSN 6810-00-244-0290? | |
| 002440290 or 00-244-0290 | |
| Does NSN 6810-00-244-0290 require demilitarization? | |
| Yes - ITAR Controlled | |
| What is the most recent solicitation for NSN 6810-00-244-0290? | |
| No solicitations for this NSN. | |
| When was this national stock number assigned to the federal catalog? | |
| Jan 01, 1963 | |
Effects of
overexposure: eyes: irritation;inhal: respi.Irritation,dizziness,weakn
ess,nausea,headache;ingest: g.I.Irr,nausea vomt
First aid: inhale: remove to fresh air, give cpr/o*2 if
need;eyes/skin: flush w lg amts h*2o for 15 min;ingest: rinse mouth;
get medical attention for eyes, breathing difficulty, or other
symptoms of overexposure.
Hcc: t4
boiling pt: b.P. Text: 104f/40c
vapor pres: 68
vapor density: 2.9
evaporation rate & reference: 1.8(ethyl ether=1)
solubility in water: negligible
appearance and odor: colorless liquid with chloroform like odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
aluminum
stability condition to avoid: none noted
hazardous decomposition products: none noted by the mfr
Waste disposal methods: dispose of collected material in accordance with
local,state and federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 100%
osha pel: 500 ppm/c,1000; z2
acgih tlv: 50 ppm, a2; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: ld50 (oral, rat) is 2524 mg/kg.
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: yes iarc: yes osha: no
health hazards acute and chronic: acute- inhalation may cause liver
injury, blood disorders, narcosis, mental confusion, cns
depression, unconsciousness & death. Can be absorbed & cause
symptoms similar to inhalation, if ingested. May be absorbed
through skin. Contact witheyes may cause pain & inflammation.
chronic- causes dermatitis & cns depression.
explanation of carcinogenicity: the agent is possibly carcinogenic to
human.
effects of overexposure: eyes, skin and respiratory tract irritation,
nausea, vomiting, headaches, eye and skin redness and pain
medical cond aggravated by exposure: persons with pre-existing skin
disorders or eye problems or impaired liver, kidney, cardiovascular
or respiratory function may be more susceptible to the effects of
the substance.
First aid: get medical attention immediately. Eye/skin: immediately flush
with water for at least 15 minutes. Hold eyelids open.
inhaled: remove to fresh air & provide oxygen/cpr if needed. Oral: if
conscious, indu ce vomiting by drinking two glasses of water and
sticking finger down throat. Call a physician immediately. Never
give anything by mouth to an unconscious person.
Hcc: t4
boiling pt: b.P. Text: 104f,40c
melt/freeze pt: m.P/f.P text: -142f,-97c
vapor pres: 350 @ 68 f
vapor density: 2.9
spec gravity: 1.3
viscosity: not known
evaporation rate & reference: 27.5 (n-butyl acetate=1)
solubility in water: 1.32 g% @ 68 f
appearance and odor: clear, colorless liquid with a chloroform-like odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizers and caustics. Chemically active metals such as
aluminum & magnesium powders, sodium, potassium, lithium
stability condition to avoid: stable under ordinary conditions of use
and storage. Avoid contact with open flames and electrical arcs.
hazardous decomposition products: emits highly toxic gas of phosgen when
heated to decomposition. Contact with hot surface/flame may form
phosgene and hcl
Waste disposal methods: collect as hazardous waste and atomize in a
suitable rcra approved combustion chamber. Dispose of in full
compliance with all applicable federal, state and local
regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 100%
other rec limits: none recommended
osha pel: 500 ppm/c,1000; z2
acgih tlv: 50 ppm, a2; 9293
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: oral ld50 (rat) = 167 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: acute: may cause eye & skin
irritation. Inhalation may cause respiratory tract irritation and
narcosis. Central nervous system depressant. Loss of consciousness
and even death can occur at high levels of exposure. Chronic:
prolonged or repeated contact with liquid on the skin can cause
irritation and dermatitis.
explanation of carcinogenicity: listed as a potential carcinogen by
iarc. Not believed to pose a measurable risk to man when handled as
recommended.
effects of overexposure: headache, dizziness, drowsiness, nausea,
tingling or numbness of the extremities, senses of fullness in the
head, sense of warmth, stupor or dullness, lethargy and
drunkenness. Inhalation of high conc entrations may lead to
unconsciousness,reduced ability of the blood to transport oxygen,
cardiac arrhythmias and death.
medical cond aggravated by exposure: methylene chloride is metabolized
to carbon monoxide. This may be sufficient to produce a substantial
stress on the cardiovascular system. Persons with liver or kidney
disorders are at increased risk.
First aid: eyes: flush with running water for 15 minutes while holding
eyelid. Get medical attention immediately. Skin: wash with water.
remove contaminated clothing. Get medical attention. Inhalation:
remove to fresh air. Give mouth-to-mouth resuscitation if not
breathing. Give oxygen if breathing is difficult. Get medical
attention. Ingestion: do not induce vomiting. Get medical attention
immediately.
Hcc: t4
boiling pt: b.P. Text: 104f,40c
melt/freeze pt: m.P/f.P text: -139f,-95c
vapor pres: 355
vapor density: 2.93
spec gravity: 1.320
evaporation rate & reference: 14.5 (n-butyl acetate=1)
solubility in water: moderate
appearance and odor: clear, colorless liquid. Chloroform-like odor.
note: a gas above 104f.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
water, amines, and aluminum. Possibly sodium, potassium and magnesium.
stability condition to avoid: hydrolysis produces small amounts of
hydrochloric acid. Avoid open flames, welding arcs, or other high
temperatures.
hazardous decomposition products: when involved in fire, methylene
chloride emits highly toxic and irritating hydrogen chloride and
phosgene fumes.
Waste disposal methods: contaminated sawdust, vermiculite or porous
surface must be disposed of in a permitted hazardous waste
management facility. Recovered liquids may be reprocessed or
incinerated or must be treated in a permitted hazardous waste
management facility.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 99.9%
other rec limits: none specified
osha pel: 500 ppm/c,1000; z2
acgih tlv: 50 ppm, a2; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Effects of overexposure: irritant to skin & eyes.
First aid: eyes & skin: flush with water.See doctor if irritation
develops. Inhal: remove to fresh air & get medical attention.
ingestion: induce vomiting & get doctor immediately.See add data
Hcc: t4
boiling pt: b.P. Text: 104f (40c)
vapor pres: 340
vapor density: 2.93
spec gravity: 1.320
solubility in water: 2 gm/100 gm
appearance and odor: colorless liquid
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
hazardous decomposition products: hydrogen chloride & phosgene with
thermal degradation.
Waste disposal methods: send solvent to a reclaimer
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 100%
osha pel: 500 ppm/c,1000; z2
acgih tlv: 50 ppm, a2; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: oral ld50 (rat) = 167 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: yes iarc: yes osha: no
health hazards acute and chronic: acute: may cause eye & skin
irritation. Inhalation may cause respiratory tract irritation and
narcosis. Central nervous system depressant. Loss of consciousness
and even death can occur at high levels of exposure. Chronic:
prolonged or repeated contact with liquid on the skin can cause
irritation and dermatitis.
explanation of carcinogenicity: listed as a suspected carcinogen by
iarc. (2b) manufacturer states listing by iarc.
effects of overexposure: headache, dizziness, drowsiness, nausea,
tingling or numbness of the extremities, senses of fullness in the
head, sense of warmth, stupor or dullness, lethargy and drunkeness.
very high concentrations may lead to unconsciousness or even death
in confined or poorly ventilated areas.
medical cond aggravated by exposure: methylene chloride is metabolized
by the body to carbon monoxide. This can be sufficient to produce a
substantial stress on the cardiovascular system by elevated levels
of carbonyhemoglobin.
First aid: inhalation: remove to fresh air. If not breathing, give cpr.
if breathing is difficult, give oxygen. Call a physician. Eye:
flush immediately with large amounts of water for 15 minutes. Get
medical at tention. Skin: remove contaminated clothing. Wash with
soap and water promptly. Ingestion: do not induce vomiting. Give
milk or water to drink only if conscious. Get immediate medical
attention.
Hcc: t4
boiling pt: b.P. Text: 103f,39c
vapor pres: 355
vapor density: 2.9
spec gravity: 1.318
evaporation rate & reference: 1.8 (ether=1)
appearance and odor: colorless liquid with a chloroform-like odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
aluminum
stability condition to avoid: none specified by manufacturer.
hazardous decomposition products: when involved in fire, methylene
chloride emits highly toxic and irritating hydrogen chloride and
phosgene fumes.
Waste disposal methods: contaminated sawdust, vermiculite or porous
surface must be disposed of in a permitted hazardous waste
management facility. Recovered liquids may be reprocessed or
incinerated or must be treated in a permitted hazardous waste
management facility.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 100%
osha pel: 500 ppm/c,1000; z2
acgih tlv: 50 ppm, a2; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: oral ld50 (rat) = 167 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: acute: may cause eye & skin
irritation. Inhalation may cause respiratory tract irritation and
narcosis. Central nervous system depressant. Loss of consciousness
and even death can occur at high levels of exposure. Chronic:
prolonged or repeated contact with liquid on the skin can cause
irritation and dermatitis.
explanation of carcinogenicity: listed as a suspected carcinogen by
iarc. (2b)
effects of overexposure: headache, dizziness, drowsiness, nausea,
tingling or numbness of the extremities, senses of fullness in the
head, sense of warmth, stupor or dullness, lethargy and drunkeness.
very high concentrations may lead to unconsciousness or even death
in confined or poorly ventilated areas.
medical cond aggravated by exposure: methylene chloride is metabolized
by the body to carbon monoxide. This can be sufficient to produce a
substantial stress on the cardiovascular system by elevated levels
of carbonyhemoglobin.
First aid: inhalation: remove to fresh air. If not breathing, give cpr.
if breathing is difficult, give oxygen. Call a physician. Eye:
flush immediately with large amounts of water for 15 minutes. Get
medical at tention. Skin: remove contaminated clothing. Wash with
soap and water promptly. Ingestion: do not induce vomiting. Give
milk or water to drink only if conscious. Get immediate medical
attention.
Hcc: t4
boiling pt: b.P. Text: 104f,40c
melt/freeze pt: m.P/f.P text: -142f,-97c
vapor pres: 349
vapor density: 2.93
spec gravity: 1.32
evaporation rate & reference: 0.71 (ethyl ether = 1)
solubility in water: slight
appearance and odor: clear, colorless liquid with ether-like odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizers and caustics; chemically active metals, such as
aluminum or magnesium powders; sodium, potassium.
stability condition to avoid: high temperatures, sparks, open flames
hazardous decomposition products: when involved in fire, methylene
chloride emits highly toxic and irritating hydrogen chloride and
phosgene fumes.
Waste disposal methods: contaminated sawdust, vermiculite or porous
surface must be disposed of in a permitted hazardous waste
management facility. Recovered liquids may be reprocessed or
incinerated or must be treated in a permitted hazardous waste
management facility.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 100%
other rec limits: 500 ppm
osha pel: 500 ppm/c,1000; z2
acgih tlv: 50 ppm, a2; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: oral ld50 (rat) = 1500 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: acute: may cause eye & skin
irritation. Inhalation may cause respiratory tract irritation and
narcosis. Central nervous system depressant. Loss of consciousness
and even death can occur at high levels of exposure. Chronic:
prolonged or repeated contact with liquid on the skin can cause
irritation and dermatitis.
explanation of carcinogenicity: listed as a suspected carcinogen by
iarc. (2b)
effects of overexposure: headache, dizziness, drowsiness, nausea,
tingling or numbness of the extremities, senses of fullness in the
head, sense of warmth, stupor or dullness, lethargy and drunkeness.
very high concentrations may lead to unconsciousness or even death
in confined or poorly ventilated areas.
medical cond aggravated by exposure: methylene chloride is metabolized
by the body to carbon monoxide. This can be sufficient to produce a
substantial stress on the cardiovascular system by elevated levels
of carbonyhemoglobin.
First aid: inhalation: remove to fresh air. If not breathing, give cpr.
if breathing is difficult, give oxygen. Call a physician. Eye:
flush immediately with large amounts of water for 15 minutes. Get
medical at tention. Skin: remove contaminated clothing. Wash with
soap and water promptly. Ingestion: do not induce vomiting. Give
milk or water to drink only if conscious. Get immediate medical
attention.
Hcc: t4
boiling pt: b.P. Text: 104f,40c
vapor pres: 355mm@20 c
vapor density: 2.93
spec gravity: 1.320
solubility in water: 2.0g/100g @25 c
appearance and odor: colorless liquid with penetrating ether-like odor.
irritating at high concs.
Stability indicator/materials to avoid: yes
amines, possibly sodium, potassium, and magnesium.
stability condition to avoid: hydrolysis producing small amounts of
hydrochloric acid possible with gross water contamination. High
temps, open flames
hazardous decomposition products: when involved in fire, methylene
chloride emits highly toxic and irritating hydrogen chloride and
phosgene fumes.
Waste disposal methods: contaminated sawdust, vermiculite or porous
surface must be disposed of in a permitted hazardous waste
management facility. Recovered liquids may be reprocessed or
incinerated or must be treated in a permitted hazardous waste
management facility.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 99.5%
other rec limits: none specified
osha pel: 500 ppm/c,1000; z2
acgih tlv: 50 ppm, a2; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: propylene oxide (sara iii)
cas: 75-56-9
rtecs #: tz2975000
fraction by wt: 0.5%
other rec limits: none specified
osha pel: 100 ppm
acgih tlv: 20 ppm; 9293
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
Ld50 lc50 mixture: oral ld50 (rat) = 1500-5000 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: yes iarc: yes osha: no
health hazards acute and chronic: acute-may cause eye & skin
irritation.May cause skin chemical burns.Inhalation: may cause
respiratory tract irritation,cns depression,loss of consciousness &
even death.Ingestion: slightly toxic.High do se->cns
depression.Chronic-prolonged/repeated contact with liquid on the
skin can cause irritation and dermatitis.
explanation of carcinogenicity: listed as a suspected carcinogen by iarc
(2b) and ntp (ac).
effects of overexposure: see health hazards section. At very high
concentrations, methylene chloride inhalation can induce cardiac
sensitization to epinephrine-like compounds in experimental
animals. May induce carboxyhemoglo binemia. This material is
practically nontoxic in terms of acute exposure. Lc50 in mice is
about 50 g/m3(15,000 ppm).
medical cond aggravated by exposure: not given.
First aid: inhalation: remove to fresh air.If not breathing,give cpr.If
breathing is difficult,give oxygen.Call a physician.Eye: flush
immediately with water for 15 minutes.Get medical
attention.Skin: wash with soa p & water.Ingestion: if conscious,drink
1-2 glasses of water & induce vomiting.Get immediate medical
attention.
Hcc: t4
boiling pt: b.P. Text: 104f,40c
vapor pres: 349
vapor density: 2.93
spec gravity: 1.33
solubility in water: 1.4 %
appearance and odor: clear, colorless liquid with ether-like odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
corrosive to al,ti,fe,steel,cu,ni.Avoid contact with
oxidizers,alkali,alkaline earth metals,caustic soda,potash.
stability condition to avoid: high heat, open flames
hazardous decomposition products: when involved in fire, methylene
chloride emits highly toxic and irritating hydrogen chloride and
phosgene fumes.
Waste disposal methods: discarded product is a hazardous waste,u-080
under rcra 40 cfr 261.33. Spent methylene chloride & sludge from
recovery of this material are hazardous wastes,f001 & f002. Dispose
of these materials in a facility, permitted for hazardous waste.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 100%
other rec limits: none specified
osha pel: 500 ppm/c,1000; z2
acgih tlv: 50 ppm, a2; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: oral ld50 (rat) = 1500-5000 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: yes iarc: yes osha: no
health hazards acute and chronic: acute-may cause eye & skin
irritation.May cause skin chemical burns.Inhalation: may cause
respiratory tract irritation,cns depression,loss of consciousness &
even death.Ingestion: slightly toxic.High d ose->cns
depression.Chronic-prolonged/repeated contact with liquid on the
skin can cause irritation and dermatitis.
explanation of carcinogenicity: listed as a suspected carcinogen by iarc
(2b) and ntp (ac).
effects of overexposure: see health hazards section. At very high
concentrations, methylene chloride inhalation can induce cardiac
sensitization to epinephrine-like compounds in experimental
animals. May induce carboxyhemoglo binemia. This material is
practically nontoxic in terms of acute exposure. Lc50 in mice is
about 50 g/m3(15,000 ppm).
medical cond aggravated by exposure: not given.
First aid: inhalation: remove to fresh air.If not breathing,give cpr.If
breathing is difficult,give oxygen.Call a physician. Eye: flush
immediately with water for 15 minutes.Get medical attention.Skin:
wash with s oap & water.Ingestion: if conscious,drink 1-2 glasses of
water & induce vomiting.Get immediate medical attention.
Hcc: t4
boiling pt: b.P. Text: 104f,40c
vapor pres: 349
vapor density: 2.93
spec gravity: 1.33
solubility in water: 1.4 %
appearance and odor: clear, colorless liquid with ether-like odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
corrosive to al,ti,fe,steel,cu,ni.Avoid contact with
oxidizers,alkali,alkaline earth metals,caustic soda,potash.
stability condition to avoid: high heat, open flames
hazardous decomposition products: when involved in fire, methylene
chloride emits highly toxic and irritating hydrogen chloride and
phosgene fumes.
Waste disposal methods: discarded product is a hazardous waste,u-080
under rcra 40 cfr 261.33. Spent methylene chloride & sludge from
recovery of this material are hazardous wastes,f001 & f002. Dispose
of these materials in a facility, permitted for hazardous waste.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii) *
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 100%
other rec limits: none specified
osha pel: 500 ppm/c,1000; z2 *
acgih tlv: 50 ppm, a2; 9192 *
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: oral ld50 (rat) = 2136 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: yes iarc: yes osha: no
health hazards acute and chronic: acute: may cause eye and skin
irritation. May cause skin chemical burns. Inhalation: may cause
respiratory tract irritation, cns depression, loss of consciousness
and even death. Ingestion: slightly t oxic. Chronic:
prolonged/repeated contact with liquid on the skin can cause
irritation and dermatitis.
explanation of carcinogenicity: listed as a suspected carcinogen by iarc
(2b) and ntp (ac).
effects of overexposure: eyes: irritation. Skin: skin irritation,
defatting and dermatitis. Inhalation: irritation, dizziness,
nausea, headache, vomiting, numbness, tingling in arms and legs,
and rapid heartbeat. Ingestion: m ay cause vomiting. Single dose
toxicityis low to moderate.
medical cond aggravated by exposure: alcoholism, acute and chronic liver
and kidney disease, chronic lung disease, anemia, coronary disease,
or rhythm disorders of the heart.
First aid: eyes: flush with large amount of water. If irritation
persists get medical attention. Skin: remove contaminated clothing.
wash area with soap and water. Inhalation: remove to fresh air. If
not breathi ng give cpr. If breathing difficult give oxygen. Get
medical attention. Ingestion: do not induce vomiting. Get medical
attention.
Hcc: t4
boiling pt: b.P. Text: 104f,40c
vapor pres: 350
vapor density: 2.9
spec gravity: 1.32
evaporation rate & reference: 0.7,ether = 1
solubility in water: 1.32 gm/100 gm @25c
appearance and odor: clear, colorless liquid, mildly sweet odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong alkalies,oxygen,nitrogen
peroxide,sodium,potassium,oxidizers,reactive metals.Aluminum parts
in press.Fluid system
stability condition to avoid: avoid contact with open flame, electric
arcs, or other hot surfaces which can cause thermal decomposition.
hazardous decomposition products: when involved in fire, methylene
chloride emits highly toxic and irritating hydrogen chloride,
phosgene, and chlorine.
Waste disposal methods: contact your local environmental officer.
dispose of waste in accordance with local, state and federal
regulations. Recovered liquids may be sent to a licensed reclaimer
or incineration facility. Do n ot reuse drum without recycling or
reconditioning.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii), (dichloromethane)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 100%
other rec limits: none specified
osha pel: 500 ppm/c,1000; z2
acgih tlv: 50 ppm, a2; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: oral ld50 (rat) = 167 mg/kg (sax)
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: yes iarc: yes osha: no
health hazards acute and chronic: acute: eye/skin/respiratory tract
irritation, possible corneal injury, narcosis, central nervous
system effects, unconsciousness, kidney/lung damage, even death.
chronic: dermatitis, delayed liver, ki dney and central nervous
system damage.
explanation of carcinogenicity: suspected carcinogen by ntp and iarc.
effects of overexposure: eye pain, skin dryness, headache, dizziness,
drowsiness, nausea, tingling or numbness of the extremities, senses
of fullness in the head, sense of warmth, stupor or dullness,
lethargy and drunkeness. very high concentrations may lead to
unconsciousness or even death in confined or poorly ventilated
areas.
medical cond aggravated by exposure: persons with angina, heart disease,
lung disease, coronary artery disease, anemia or those who are
heavy drinkers or smokers should not be exposed to this product.
First aid: inhalation: remove to fresh air. If not breathing, give cpr.
if breathing is difficult, give oxygen. Call a physician. Eye:
flush immediately with large amounts of water for 15 minutes. Get
medical at tention. Skin: remove contaminated clothing. Wash with
soap and water promptly. Ingestion: do not induce vomiting. Give
milk or water to drink only if conscious. Get immediate medical
attention.
Hcc: t4
boiling pt: b.P. Text: 104f,40c
melt/freeze pt: m.P/f.P text: -139f fz pt
vapor pres: 340
vapor density: 2.9
spec gravity: 1.32
viscosity: 0.43 cp @ 68f
evaporation rate & reference: >1 (butyl acetate = 1)
solubility in water: 1.6%
appearance and odor: colorless liquid. Penetrating ether like odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
alkalies, oxidizing materials, water, aluminum, alkali metals, possibly
sodium, potassium and magnesium.
stability condition to avoid: high heat, open flames and other sources
of ignition.
hazardous decomposition products: when involved in fire, methylene
chloride emits highly toxic and irritating hydrogen chloride and
phosgene fumes.
Waste disposal methods: contaminated sawdust, vermiculite or porous
surface must be disposed of in a permitted hazardous waste
management facility. Recovered liquids may be reprocessed or
incinerated or must be treated in a permitted hazardous waste
management facility.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 100%
other rec limits: none specified
osha pel: 500 ppm/c,1000 ppm
acgih tlv: 50 ppm, a2; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: oral ld50 (rat) is 2136 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: yes iarc: yes osha: no
health hazards acute and chronic: inhalation-slightly toxic.
skin-moderately toxic. Skin/eye-mildly irritating / irritant.
ingestion-slightly toxic.
explanation of carcinogenicity: listed bt ntp and iarc as carcinogenic.
effects of overexposure: inhaled: narcosis. Eyes: irritnt. Skin: irritnt,
dermal: can be absorbed. High concentrations can cause
cardiovascular effects.
medical cond aggravated by exposure: none known.
First aid: inhalation-remove to fresh air. If not breathing, give apr.
if breathing is hard, give oxygen. Call physician. Eye or
skin-flush eye and skin with plenty of water (soap & water for
skin) for at least 15 min. If irritation occurs, call physician.
ingestion-drink large amounts of water. Do not indue vomiting. Take
immediately to a hospital.
Hcc: t4
boiling pt: b.P. Text: 102f,39c
melt/freeze pt: m.P/f.P text: -144f,-98c
vapor pres: 349
vapor density: 2.93
spec gravity: 1.32
ph: 7
evaporation rate & reference: 0.71 ethyl ether=1
solubility in water: 2 g/100g
appearance and odor: clear, colorless liquid with ether-like odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
avoid caustic soda, caustic potash, oxidizing materials.
stability condition to avoid: open flames, hot glowing surfaces,
electric arcs.
hazardous decomposition products: hydrogen chloride(hcl) & possibly
traces of phosgene.
Waste disposal methods: contaminated sawdust, vermiculite, soil or
porous surface must be disposed of in a permitted hazardous waste
management facility. Recovered liquid may be reprocessed or
incinerated or must be treated in a permitted waste management
facility.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 100%
osha pel: 500 ppm/c,1000; z2
acgih tlv: 50 ppm, a2; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: ld50 (oral, rat) is 1500-2500 mg/kg.
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: yes iarc: yes osha: no
health hazards acute and chronic: target organs: lung, eye, skin, liver,
kidney. Acute- eye: transient corneal injury. Skin: irritation,
defatting. Prolonged skin contact may result in burns & absorption.
inhale: irritation, dizziness. Na rcotic in high concentrations.
oral: aspiration hazard. Chronic- long term overexposure may cause
liver & kidney damage.
explanation of carcinogenicity: methylene chloride is listed as a
potential human carcinogen by ntp, iarc and acgih.
effects of overexposure: irritation, nausea, vomiting, headache,
dizziness, skin defatting and burns, elevated carboxyhemoglobin
levels
medical cond aggravated by exposure: persons with pre-existing skin
disorders or eye problems or impaired liver, kidney, cardiovascular
or respiratory function may be more susceptible to the effects of
the substance.
First aid: get immediate medical attention. Eyes/skin: immediately flush
with water for at least 15 minutes. Hold eyelids open. Wash skin
with soap & water. Inhaled: remove to fresh air. Provide cpr/oxygen
if nece ssary. Oral: do not induce vomiting except on advice of
competent medical personnel. If conscious, drink water. Never give
anything by mouth to an unconscious person.
Hcc: t4
nrc/state lic num: not relevant
boiling pt: b.P. Text: 104f,40c
melt/freeze pt: m.P/f.P text: -142f,-97c
vapor pres: 350 @ 68f
vapor density: 2.93
spec gravity: 1.326
viscosity: not relevant
evaporation rate & reference: >1 (ether = 1)
solubility in water: approx. 2% @ 68f/20c
appearance and odor: clear, colorless volatile liquid - penetrating
ethereal odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizing agents, strong caustic, chemically active metals
(aluminum), amines, possibly sodium, potassium & mg
stability condition to avoid: stable under ordinary conditions of use
and storage. Avoid contact with open flames, electrical arcs,
excessive heat
hazardous decomposition products: hydrogen chloride, carbon monoxide,
carbon dioxide, phosgene and chlorine
conditions to avoid polymerization: water contamination
Waste disposal methods: dispose of in accordance with all local, state
and federal regulations. Dispose of in an approved incinerator
equipped with afterburner and scrubber or contract with a licensed
waste disposal service. do not contaminate environment.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara 313) (cercla)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 99.9%
other rec limits: none recommended
osha pel: 500 ppm; z-2
acgih tlv: 50 ppm, a2; 9495
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: ld50 (oral, rat) is 1600 mg/kg.
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: yes iarc: yes osha: no
health hazards acute and chronic: target organs: cns, liver, heart.
acute- affects cns, liver, cardiovascular system & blood. Causes
eyes, skin, respiratory tract irritation. Prolonged skin contact
can cause burns. May be absorbed thro ugh skin. Inhalation may form
carbon monoxide in blood affecting cns & heart. Chronic- cns,
liver, kidney, blood effects
explanation of carcinogenicity: methylene chloride is listed as a
potential human carcinogen by ntp, iarc and acgih.
effects of overexposure: irritation, nausea, vomiting, headache,
dizziness, skin defatting, elevated carboxyhemoglobin levels,
weakness, pain, burns, inflammation, dermatitis, visual
disturbances, bronchitis, unconsciousness
medical cond aggravated by exposure: persons with pre-existing skin
disorders or eye problems or impaired liver, kidney, cardiovascular
or respiratory function may be more susceptible to the effects of
the substance.
First aid: get medical help if symptoms persist. Inhaled: move to fresh
air. Provide cpr/oxygen if needed. Eyes: immediately flush with
water for 15 minutes. Hold eyelids open. Skin: wash with plenty of
soap & wate r. Oral: do not induce vomiting. If conscious, drink
plenty of water. Seek immediate medical attention. If vomiting
occurs, keep head below hips. Do not give anything by mouth to an
unconscious person.
Hcc: t4
nrc/state lic num: not relevant
boiling pt: b.P. Text: 104f,40c
melt/freeze pt: m.P/f.P text: -142f,-97c
vapor pres: 400 @ 75f
vapor density: 2.9
spec gravity: 1.33
viscosity: not relevant
evaporation rate & reference: 27.5 (n-butyl acetate=1)
solubility in water: slight (1.32% @ 68f)
appearance and odor: clear, colorless liquid - chloroform like odor
percent volatiles by volume: 99-100
Stability indicator/materials to avoid: yes
strong oxidizing agents, strong caustics, plastics, rubber, nitric
acid, water+heat, active metals (al, mg, na, li, k)
stability condition to avoid: heat, open flames, electrical arcs,
ignition sources
hazardous decomposition products: hydrogen chloride, carbon monoxide,
carbon dioxide, phosgene and chlorine may be formed.
Waste disposal methods: discharge, treatment or disposal is subject to
federal, state or local regulations. Can be incinerated. Contract
with a licensed chemical disposal agency. Since emptied containers
retain product resid ue, follow label warnings.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara 313) (cercla)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 99- 100%
other rec limits: none recommended
osha pel: 25 ppm
acgih tlv: 50 ppm, a2; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: ld50 (oral, rat) is 2524 mg/kg.
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: yes iarc: yes osha: no
health hazards acute and chronic: acute- inhalation may cause liver
injury, blood disorders, narcosis, mental confusion, cns
depression, unconsciousness & death. Can be absorbed & cause
symptoms similar to inhalation, if ingested. May be absorbed
through skin. Contact witheyes may cause pain & inflammation.
chronic- causes dermatitis & cns depression.
explanation of carcinogenicity: the agent is possibly carcinogenic to
human.
effects of overexposure: eyes, skin and respiratory tract irritation,
nausea, vomiting, headaches, eye and skin redness and pain.
medical cond aggravated by exposure: persons with pre-existing skin
disorders or eye problems or impaired liver, kidney, cardiovascular
or respiratory function may be more susceptible to the effects of
the substance.
First aid: get medical attention immediately. Eye/skin: immediately
flush with water for at least 15 minutes. Hold eyelids open.
inhaled: remove to fresh air & provide oxygen/cpr if needed. Oral: if
conscious, ind uce vomiting by drinking two glasses ofwater and
sticking finger down throat. Call a physician immediately. Never
give anything by mouth to an unconscious person.
Hcc: t4
boiling pt: b.P. Text: 104f,40c
melt/freeze pt: m.P/f.P text: -142f,-97c
decomp temp: decomp text: not given
vapor pres: 400
vapor density: 2.9
spec gravity: 1.33
viscosity: not known
evaporation rate & reference: 27.5 (n-butyl acetate=1)
solubility in water: 1.32 g%
appearance and odor: clear, colorless liquid with a chloroform-like odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizers and caustics. Chemically active metals such as
aluminum & magnesium powders, sodium, potassium, lithium
stability condition to avoid: stable under ordinary conditions of use
and storage. Avoid contact with open flames and electrical arcs.
hazardous decomposition products: emits highly toxic gas of phosgen when
heated to decomposition. Contact with hot surface/flame may form
phosgene and hcl
Waste disposal methods: collect as hazardous waste and atomize in a
suitable rcra approved combustion chamber. Dispose of in full
compliance with all applicable federal, state and local
regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara 313) (cercla)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 100%
other rec limits: none recommended
osha pel: 500 ppm; z-2
acgih tlv: 50 ppm, a2; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: oral rats ld50 1500-2500mg/kg.
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: yes iarc: yes osha: no
health hazards acute and chronic: eye: may cause moderate eye irritation.
skin: prolonged or repeated exposure may cause skin irritation.
ingestion: swallowing large amounts may cause injury. Inhalation: in
confined or poorly ventilated areas, vapors can readily
accumulated and can cause unconsciousness and death.
explanation of carcinogenicity: per msds: per osha 29cfr1910.1200 listed
as potential carcinogen by iarc/ntp.
effects of overexposure: eye-may cause pain. Skin-may cause burns,
drying or flaking of skin. Inhalation-can cause dizziness,
drunkenness, cardiac arrythmias (irregular heartbeats)
unconsciousness and death.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: eye: irrigate w/flow water immediately for 15mins. See
physician. Skin: wash off in flow water/shower. Ingest: don't induce
vomit. Call a physician &/or transport to emergency facility
immediately. Inhal e: remove to fresh air. If not breath give
artificial respiration. If breathing is difficult, oxygen should be
administered by qualified personnel. Call a physician or transport
to a medical facility.
Hcc: t4
boiling pt: b.P. Text: 104f,40c
melt/freeze pt: m.P/f.P text: np
decomp temp: decomp text: np
vapor pres: 355mm
vapor density: 2.93
spec gravity: 1.320
ph: np
evaporation rate & reference: np
solubility in water: 2g/100g @25c.
appearance and odor: colorless liquid, irritating odor.
percent volatiles by volume: np
corrosion rate: np
Stability indicator/materials to avoid: yes
metals (al, mg, k, na, zn powedrs). Amines, strong bases,
strongoxidizers, prolong contact w/or storage in al/al alloys.
stability condition to avoid: avoid direct sunlight/ultraviolet sources,
open flames, weld arc, high temp sources. High energy sources
degrade materls
hazardous decomposition products: smoke contains original material,
unidentified toxic &/or irrit compds.Hydrogen chloride.Trace amts
of phosgene chlorine
Waste disposal methods: don't dumpt into sewers/ground/body of
h2o.Icw/all fed/state/provin/loc laws/regs.Waste
character/complinace w/applica laws waste generator
responsibility.Unused/uncontam prod: send to lic,permitt recy
cler,reclaimer,inciner,other therm destruction dev
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara 313) (cercla)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 98.4%
other rec limits: none recommended
osha pel: 500 ppm; z-2
acgih tlv: 50 ppm, a2; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: propylene oxide (sara 302/313) (cercla)
cas: 75-56-9
rtecs #: tz2975000
fraction by wt: 1.6%
other rec limits: none recommended
osha pel: 100 ppm
acgih tlv: 20 ppm; 9596
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
Ld50 lc50 mixture: ld50 (oral, rat) is 1500-2500 mg/kg.
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: yes iarc: yes osha: no
health hazards acute and chronic: target organs: lung, eye, skin, liver,
kidney. Acute- eye: causes irritation. Skin: irritation, defatting.
prolonged skin contact may result in burns & absorption. Inhale: may
cause cns depression. Narcot ic in high concentrations.
oral: harmfulif ingested. Chronic- long term overexposure may cause
liver & kidney damage.
explanation of carcinogenicity: methylene chloride is listed as a
potential human carcinogen by ntp, iarc and acgih.
effects of overexposure: irritation, nausea, vomiting, headache,
dizziness, skin defatting and burns, elevated carboxyhemoglobin
levels, weakness
medical cond aggravated by exposure: persons with pre-existing skin
disorders or eye problems or impaired liver, kidney, cardiovascular
or respiratory function may be more susceptible to the effects of
the substance.
First aid: get medical attention if symptoms persist.
eyes/skin: immediately flush with water for at least 15 minutes.
hold eyelids open. Wash skin with soap & water. Inhaled: remove to
fresh air. Provide cpr/oxyg en if necessary. Oral: do not induce
vomiting. Call physician. Never give anything by mouth to an
unconscious person.
Hcc: t4
nrc/state lic num: not relevant
boiling pt: b.P. Text: 104f,40c
vapor pres: 355 @ 68f
vapor density: 2.93
spec gravity: 1.320
viscosity: not relevant
solubility in water: 2% @ 25c/77f
appearance and odor: colorless liquid - irritating odor
percent volatiles by volume: 99.9
Stability indicator/materials to avoid: yes
strong oxidizing agents, chemically active metals (aluminum powder,
magnesium powder, potassium, sodium, zinc powder)
stability condition to avoid: open flames, electrical arcs, excessive
heat, direct sunlight, ultra violet sources
hazardous decomposition products: hydrogen chloride, carbon monoxide,
carbon dioxide, phosgene and chlorine may be formed.
Waste disposal methods: discharge, treatment or disposal is subject to
federal, state or local regulations. Recycling or incineration is
recommended. Contract with a licensed chemical disposal agency.
since emptied container s retain product residue, follow label
warnings.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara 313) (cercla)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 99.9%
other rec limits: none recommended
osha pel: 500 ppm; z-2
acgih tlv: 50 ppm, a2; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs