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Methylchloroform (1, 1, 1-trichloroethane)
Saturated chlorinated derivatives of acyclic hydrocarbons, n.E.S.
Chemicals-organic
Y - Indicates information is in the hazardous materials information resource system (hmirs).
PMICA - Item does not contain precious metal.
CRITL- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.
045290 - Methyl chloroform etc
635 - Chemicals, other than drugs or sundries
9 - Other or no special handling required (sh)
A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.
C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp
P - Poison, class b, un class 6 (poison label)
W - Rating variable
Questions & Answers: |
|
| What are the historical prices recorded for this stock number? | |
| Historical data shows pricing from $0.04 to $0.07.. | |
| Does NSN 6810-00-476-5613 have a shelf life? | |
| No. There is no shelf life applicable for this NSN. | |
| What NATO entities are users of this NSN? | |
| Department Of The Army, Department Of The Air Force, Department Of The Navy, U.s. Coast Guard, Poland, New Zealand, Republic Of Korea, Greece, and Turkey | |
| What is the NIIN of NSN 6810-00-476-5613? | |
| 004765613 or 00-476-5613 | |
| Does NSN 6810-00-476-5613 require demilitarization? | |
| Yes - ITAR Controlled | |
| What is the most recent solicitation for NSN 6810-00-476-5613? | |
| No solicitations for this NSN. | |
| When was this national stock number assigned to the federal catalog? | |
| Jun 16, 1971 | |
Routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: yes iarc: yes osha: no
health hazards acute and chronic: acute-eye: irritation with possible
corneal injury. Skin: irritation,defatting.
inhalation: dizziness,drowsiness,throat irritation(above 1,000ppm);
unconsciousness,cns depression,cardiac sensitization(ab ove
10,000ppm). Chronic: dermatitis, liver and heart disorders.
explanation of carcinogenicity: 1,4 diethylene dioxide is listed by ntp
and iarc as a possible carcinogen.
effects of overexposure: eye: irritation, redness and pain.
inhalation: dizziness, drowsiness, nausea, vomiting, unconsciousness
& even death in extreme cases.
medical cond aggravated by exposure: pre-existing conditions effecting
liver and heart.
First aid: inhalation: remove to fresh air, provide cpr/oxygen if needed.
eye contact: flush with water for 15 minutes. Skin contact: wash with
soap and water. Get med attention if symptoms persist. Ingestion: do
no t induce vomiting, get medical help immediately.
Hcc: t4
boiling pt: b.P. Text: 165f/74c
vapor pres: 100 mmhg
vapor density: 4.6
spec gravity: 1.32
evaporation rate & reference: 0.4 (ether =1)
solubility in water: negligible
appearance and odor: clear, colorless liquid, mildly sweet odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong alkalies,oxidizers & reactive materials.
stability condition to avoid: contact with open flame,hot surfaces.
hazardous decomposition products: hydrogen chloride, & phosgene.
Waste disposal methods: recovered liquids may be sent to licensed
reclaimer or incineration facility. Contaminated material must be
disposed of in a permitted waste management facility. Consult
federal,state or local disposa l authorities for approved
procedures.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 96.5%
other rec limits: none specified by m.
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: 1,4-dioxane (diethylene dioxide) (sara iii)
cas: 123-91-1
rtecs #: jg8225000
fraction by wt:
other rec limits: none specified by m.
osha pel: s, 100 ppm
acgih tlv: s, 25 ppm; 9293
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
ingred name: 1,2-butylene oxide (sara iii)
cas: 106-88-7
rtecs #: ek3675000
fraction by wt: >0.5%
other rec limits: none specified
epa rpt qty: 1 lb
dot rpt qty: 1 lb
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: irritation of
eyes,skin,respiratory or g.I.Tracts;cns effects like
headache,dizziness,nausea,vomiting and possible
unconsciousness;redness or burns of eyes/skin
possible.Chronic: drying of skin,d efatting or
dermatitis,liver,kidney,lungs abnormalities or heart problem
explanation of carcinogenicity: this product contains proprietary
inhibitor which includes ( 1,4-dioxane)listed by ntp and iarc as
animal carcinogen.
effects of overexposure: eyes: severe irritation,redness,tearing,blurred
vision;skin: dermatitis;inhalation: respiratory
irritation,dizziness,weakness,fatigue,nausea;ingestion: nausea,vomit
ing,diarrhea.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the eyes, skin, or
respiratory tract may be at increased risk from exposure.
First aid: inhalation: remove to fresh air. Resuscitate if not breathing.
get medical attention. Eyes: immediately flush with plenty of water
for 15 minutes holding eyelids open. Get medical attention.
skin: remove contaminated clothing. Wash with soap and water. If
irritation persists, get medical advice. ingestion: do not induce
vomiting. Give nothing by mouth if unconscious. Get immediate
medical attention.
Hcc: t4
boiling pt: b.P. Text: 190f,88c
vapor pres: 100
vapor density: 4.5
spec gravity: 1.324
evaporation rate & reference: 2.6 (ethyl ether=1
solubility in water: negligible
appearance and odor: clear liquid with mild chloroform-like odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
avoid contact with water,al,mg,open flame,welding arcs.
stability condition to avoid: high temperatures, sparks, and open flames
hazardous decomposition products: carbon monoxide, carbon dioxide and
other unidentified components (hcl,smalll amount of phosgene or
cl*2)
Waste disposal methods: consult local authorities.Disposal must be made
in accordance with all applicable federal, state and local laws and
regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 90-95%
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: proprietary inhibitor package.(include diethylene ether
;1,4-dioxane,listed as animal carcinogen by ntp and iarc.)see#3
ingred name: 1,4-dioxane (diethylene dioxide) (sara iii)
cas: 123-91-1
rtecs #: jg8225000
osha pel: s, 100 ppm
acgih tlv: s, 25 ppm; 9293
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
Ld50 lc50 mixture: oral ldlo(rabbit) 5000 mg/cum
routes of entry: inhalation: yes skin: yes ingestion: yes
health hazards acute and chronic: acute: cns depressant;irritation of
respiratory tract,dizziness,nausea,headache, loss of
co-ordination;irriation of eyes,pain,skin irritation or dermatitis
in the long run.Chronic: liver and kidney dama ge.
effects of overexposure: skin & eyes: mildly
irritating,dermatitis;inhal: cns depressant,nausea,vomiting,liver
and kidney damag
medical cond aggravated by exposure: kidney and liver damage.
First aid: inhale: remove to fresh air, give cpr/o*2 if
need;eyes/skin: flush w lg amts h*2o for 15 min;ingest: rinse mouth;
get medical attention for eyes, breathing difficulty, or other
symptoms of overexposure.
Hcc: t4
boiling pt: b.P. Text: 165f/72c
melt/freeze pt: m.P/f.P text: -49f/-45c
vapor pres: 135
vapor density: 4.54
spec gravity: 1.3
evaporation rate & reference: 0.35(ethyl ethr=1)
solubility in water: negligible
appearance and odor: clear,colorless liquid with ether-like odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizers,strong acid and bases.
stability condition to avoid: open flames,heat,electric arcs
hazardous decomposition products: hcl and traces of phosgene.
Waste disposal methods: dispose of collected material in accordance with
local,state & federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 96.0%
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: 1,4-dioxane (diethylene dioxide) (sara iii)
cas: 123-91-1
rtecs #: jg8225000
osha pel: s, 100 ppm
acgih tlv: s, 25 ppm; 9293
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
ingred name: glycol methylene ether
cas: 646-06-0
rtecs #: jh6760000
ingred name: sec.Butanol
cas: 78-92-2
osha pel: 150 ppm
acgih tlv: 100 ppm; 9293
Ld50 lc50 mixture: oral ld50 (rat) = 10300 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: may cause mild eye & skin irritation.
breathing high concentrations may cause respiratory tract
irritation & cns depression and death. Ingestion of excessive
quantities may cause nausea, vomiting, dia rrhea, & cns depression.
repeated and prolonged overexposure may result in severe skin,
permanent brain or cns damage.
explanation of carcinogenicity: there is limited evidence of liver
damage in long term animal studies. Relevance of these findings to
humans is unknown.
effects of overexposure: direct eye contact with liquid or vapor may
cause stinging, tearing and redness. Skin contact may cause
redness, burning, drying, & cracking. Inhalation may cause
headache, drowsiness, dizziness, loss of coordination, and
fatigue. Ingestion may cause nausea, vomiting, diarrhea, and signs
of nervous system depression.
medical cond aggravated by exposure: persons with pre-existing skin and
lung disorders may be more susceptible to the effects of this
material.
First aid: inhalation: remove to fresh air. Give mouth-to-mouth
resuscitation if not breathing. Give oxygen if breathing is
difficult. Get medical attention. Eyes: flush with running water
for 15 minutes while h olding eyelid. Get medical attention. Skin:
wash with plenty of soap & water. Remove contaminated clothing. Get
medical attention. Ingested: do not induce vomiting. Get medical
attention immediately.
Hcc: t4
boiling pt: b.P. Text: 165f,74c
melt/freeze pt: m.P/f.P text: -23f,-31c
vapor pres: 134 mm hg
vapor density: 4.6
spec gravity: 1.29
evaporation rate & reference: 6.0(n-butyl acetate = 1)
solubility in water: negligible
appearance and odor: clear, colorless liquid with faint, benzene-like
odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizing agents, strong acids, strong alkalies, selected
amines, and reactive metals such as al, k, na, etc.
stability condition to avoid: avoid high pressure in aluminum systems.
hazardous decomposition products: when involved in fire,
1,1,1-trichloroethane emits highly toxic and irritating hydrogen
chloride and phosgene fumes.
Waste disposal methods: dispose of product in accordance with federal,
state and local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 94-98%
other rec limits: none specified
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: 1,4-dioxane (diethylene dioxide) (sara iii)
cas: 123-91-1
rtecs #: jg8225000
fraction by wt: 0-4%
other rec limits: none specified
osha pel: s, 100 ppm
acgih tlv: s, 25 ppm; 9293
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
Effects of overexposure: eye-irrit.Skin-minor irrit if prolong
contact.Anesthetic effct-1000 ppm range,death-too much breathd
First aid: eye-flush w/water-5 min.Skin-wash w/water.Ingest-do not
induce vomit.Call md.No specific antidote.Inhal-move to fresh
air.Give art respir if breath stop.Five oxygen if available.Get
medical help for a ll of above.See supplemental data for addtl
info.
Hcc: t4
boiling pt: b.P. Text: 165f (74c)
vapor pres: 100
vapor density: 4.55
spec gravity: 1.321
solubility in water: 0.07g/100g
appearance and odor: colorless liquid
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
water-slow hydrolysis produces acid,aluminum & its alloys
stability condition to avoid: open flames,welding arcs,high temp cause
decomposition
hazardous decomposition products: hydrogen chloride,small amounts
phosgene & chlorine
Waste disposal methods: send solvent to licensed
reclaimer,incineration,evaporation,evaporation of very small amts
or approved landfill burial iaw local,state,and fed. Regulations.
do not dump into sewers,on the ground,or an y body of water.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 96.4%
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
Effects of overexposure: may cause dizziness,headache or even death in
excess conc.Also may irritate eyes & skin,or narcotic.
First aid: inhale: remove to fresh air, give cpr/o*2 if
need;eyes/skin: flush w lg amts h*2o for 15 min;ingest: rinse mouth;
get medical attention for eyes, breathing difficulty, or other
symptoms of overexposure.
Hcc: t4
boiling pt: b.P. Text: 165f/74c
vapor pres: 100
vapor density: 4.55
spec gravity: 1.332
evaporation rate & reference: not specified
solubility in water: negligible
appearance and odor: colorless liquid,irritating odor at high concentn.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
water,al & its alloys, metallic al & zinc powder
stability condition to avoid: none specified by the mfr.
hazardous decomposition products: hcl, and very small amount of phosgene
conditions to avoid polymerization: open flames,high temp that cause
decomposition.
Waste disposal methods: consult disposal authorities for incineration or
approved landfill in accordance with local,state & federal
regulations.Do not dump into sewers or on the ground or water
courses.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 99.9%
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: irritation of eyes,skin and
respiratory tract: cns effects,headache,loss of co-ordination.
chronic;cardiac arrhythmia,cns depression,dermatitis,lung,kidney
and liver damage.
effects of overexposure: see health hazards data.
medical cond aggravated by exposure: respiratory
ailments,dermatits,cirrhosis of the liver.
First aid: inhalation: remove to fresh air.Cpr,get medical attention
immediately. Eyes: flush with plenty of water for about 15
minutes,call a physician if needed;slin: wash thoroughly with water
and soap,use cream against dermatitis. Ingestion: do not induce
vomiting;call a physician immediately.
Hcc: t4
boiling pt: b.P. Text: 165f/74c
vapor pres: 100
vapor density: 4.54
spec gravity: 1.3
evaporation rate & reference: 0.35 (ethyl-ether-1)
solubility in water: negligible
appearance and odor: clear,colorless liquid,mild chloroform-like odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
caustic soda,caustic potash oxidizing agents.
stability condition to avoid: open flames,hot glowing surfaces,electric
arcs.
hazardous decomposition products: hcl and traces of phosgene
Waste disposal methods: incineration or disposal must be in accordance
with local and state and.Federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
Ld50 lc50 mixture: oral ld50 (rat) = 10300 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: yes iarc: yes osha: no
health hazards acute and chronic: acute: may cause eye & skin
irritation. May cause respiratory tract irritation. Central nervous
system depressant. Loss of consciousness and even death can occur
at high levels of exposure.
explanation of carcinogenicity: 1,4-dioxane is listed as an animal
carcinogen by ntp and iarc.
effects of overexposure: incoordination and impaired judgment may occur
at vapor exposures from 500-1000 ppm. Dizziness, drowsiness, and
general anestethic effects may occur in ranges of 1000 ppm and
higher.
medical cond aggravated by exposure: increased sensitivity to adrenalin
may be caused by over exposure.
First aid: inhalation: remove to fresh air. If not breathing, give cpr.
if breathing is difficult, give oxygen. Call a physician. Eye:
flush immediately with large amounts of water for 15 minutes. Get
medical at tention. Skin: remove contaminated clothing. Wash with
soap and water promptly. Ingestion: do not induce vomiting. Give
milk or usp mineral oil. Get immediate medical attention.
Hcc: t4
boiling pt: b.P. Text: 161f,72c
vapor pres: 100
vapor density: 4.5
spec gravity: 1.3-1.324
evaporation rate & reference: 2.6 (ethly ether=1)
appearance and odor: homogeneous solution that is clear. Apha color 15
max.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
water, reactive metals such as aluminu;m and magnesium.
stability condition to avoid: open flames, welding arcs, resistance
heaters, etc., which can result in thermal decomposition.
hazardous decomposition products: when involved in fire,
1,1,1-trichloroethane emits highly toxic and irritating hydrogen
chloride and phosgene fumes.
Waste disposal methods: disopse of i/a/w federal, state & local
regulations
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: >95%
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: 1,4-dioxane (diethylene dioxide) (sara iii)
cas: 123-91-1
rtecs #: jg8225000
fraction by wt: 2.5%
osha pel: s, 100 ppm
acgih tlv: s, 25 ppm; 9293
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
Ld50 lc50 mixture: oral ld50 (rat) = 10300 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: eye/skin: mild
irritation.Inhalation: moderate irritation.Concentrations
insufficient to produce unconsciousness may produce
gastrointestinal upset and liver & kidney
damage.Ingestion: irritation,v omiting.Absorption may lead to cns
depression,unconsciousness & death.Chronic-liver & kidney injury.
explanation of carcinogenicity: not listed as a carcinogen by ntp, iarc
or osha. It is weakly mutagenic.
effects of overexposure: acute-inhalation of high concentrations or
ingestion may produce symptoms of cns depression ranging from
light-headedness to unconsciousness and death.Can cause
headache,nausea,vomiting,mental confusi on,cough.Exposure of eye
and skin to vapor or liquid may cause irritation.Prolonged skin
contact may cause dermititis.
medical cond aggravated by exposure: persons with medical conditions
similar to effects stated above should not be exposed to this
product.
First aid: get medical attention-inhalation: remove to fresh air.Give
cpr/oxygen if needed.Eye: flush immediately with large amounts of
water for 15 minutes.Skin: wash with soap and water.A soothing
ointment may be applied.Ingestion: do not induce vomiting.Give warm
water.Absorbent such as activated charcoal may be of value.
Hcc: t4
boiling pt: b.P. Text: 165f,74c
melt/freeze pt: m.P/f.P text: -45c fp
vapor pres: 100
vapor density: 4.55
spec gravity: 1.3 - 1.324
evaporation rate & reference: 0.37 (n-butyl acetate=1)
solubility in water: 0.07 %
appearance and odor: clear,colorless liquid with a chloroform-like odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong alkalies such as naoh, alkali metals.
stability condition to avoid: high temperatures, sparks, open flames,
welding arcs.
hazardous decomposition products: when involved in fire,
1,1,1-trichloroethane emits highly toxic and irritating hydrogen
chloride, cl2 and phosgene fumes
Waste disposal methods: dispose of i/a/w federal, state & local
regulations
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: 1,2-butylene oxide (sara iii)
cas: 106-88-7
rtecs #: ek3675000
fraction by wt: 0.3-0.6%
other rec limits: none specified
epa rpt qty: 1 lb
dot rpt qty: 1 lb
ingred name: ethylene dichloride (sara iii)
cas: 107-06-2
rtecs #: ki0525000
fraction by wt: .01-.09%
other rec limits: none specified
osha pel: 50 ppm/c,100ppm
acgih tlv: 10 ppm; 9293
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
ingred name: 1,4-dioxane (diethylene dioxide) (sara iii)
cas: 123-91-1
rtecs #: jg8225000
fraction by wt: 2-2.70%
other rec limits: none specified
osha pel: s, 100 ppm
acgih tlv: s, 25 ppm; 9293
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 96-97.5%
other rec limits: none specified
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: nitromethane
cas: 75-52-5
rtecs #: pa9800000
fraction by wt: 0.2-0.5%
other rec limits: none specified
osha pel: 100 ppm
acgih tlv: 100 ppm; 9192
ingred name: trichloroethylene (sara iii)
cas: 79-01-6
rtecs #: kx4550000
other rec limits: none specified
osha pel: 100 ppm/100 stel
acgih tlv: 50 ppm/100,a5stel;93
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
Ld50 lc50 mixture: oral ld50 (rat) = 10300 mg/kg (1,1,1-tri
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: yes iarc: yes osha: no
health hazards acute and chronic: acute: may cause eye & skin
irritation. May cause respiratory tract irritation. Central nervous
system depressant. Loss of consciousness and even death can occur
at high levels of exposure. Excess exp osure can lead to blood
pressure depression, cardiac sensitization, and ventricular
arrhythmia. Possible liver effects.
explanation of carcinogenicity: 1,4 dioxane is listed as a possible
carcinogen by ntp and iarc.
effects of overexposure: incoordination and impaired judgment may occur
at vapor exposures from 500-1000 ppm. Dizziness, drowsiness, and
general anestethic effects may occur in ranges of 1000 ppm and
higher. May cause eye con junctivitis.
medical cond aggravated by exposure: liver and heart.
First aid: inhalation: remove to fresh air. If not breathing, give cpr.
if breathing is difficult, give oxygen. Call a physician. Eye: flush
immediately with large amounts of water for 15 minutes. Get medical
atte ntion. Skin: remove contaminated clothing. Wash with soap and
water promptly. Ingestion: do not induce vomiting. Give milk or usp
mineral oil. Get immediate medical attention. Avoid aspiration.
Hcc: t4
boiling pt: b.P. Text: 165f,74c
melt/freeze pt: m.P/f.P text: -26f,-32c
vapor pres: 100
vapor density: 4.6
spec gravity: 1.32
evaporation rate & reference: >1 (n-butyl acetate=1)
solubility in water: negligible
appearance and odor: colorless liquid; irritating odor at high
concentrations
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizing agents, alkalis,water,moist air, aluminum, zinc. Do
not store material in aluminum containers.
stability condition to avoid: high temperatures, sparks, open flames,
welding arcs.
hazardous decomposition products: when involved in fire,
1,1,1-trichloroethane emits highly toxic and irritating hydrogen
chloride and phosgene fumes.
Waste disposal methods: dispose of i/a/w federal, state & local
regulations. Unused material will be a land-banned hazardous waste.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 96.5%
other rec limits: none specified
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: 1,4-dioxane (diethylene dioxide) (sara iii)
cas: 123-91-1
rtecs #: jg8225000
fraction by wt: 2.5%
other rec limits: none specified
osha pel: s, 100 ppm
acgih tlv: s, 25 ppm; 9293
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
ingred name: 1,2-butylene oxide (sara iii)
cas: 106-88-7
rtecs #: ek3675000
fraction by wt: 0.47%
other rec limits: none specified
epa rpt qty: 1 lb
dot rpt qty: 1 lb
ingred name: nitromethane
cas: 75-52-5
rtecs #: pa9800000
fraction by wt: 0.34%
other rec limits: none specified
osha pel: 100 ppm
acgih tlv: 100 ppm; 9192
ingred name: tert-butyl alcohol (sara iii)
cas: 75-65-0
rtecs #: eo1925000
fraction by wt: trace
other rec limits: none specified
osha pel: 100 ppm
acgih tlv: 100ppm 9394
ingred name: nitromethane
cas: 75-52-5
rtecs #: pa9800000
fraction by wt: trace
other rec limits: none specified
osha pel: 100 ppm
acgih tlv: 100 ppm; 9192
Ld50 lc50 mixture: oral ld50 (rat) = 10300 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: may cause eye & skin
irritation. May cause respiratory tract irritation. Central nervous
system depressant. Loss of consciousness and even death can occur
at high levels of exposure. Excess exp osure can lead to blood
pressure depression, cardiac sensitization, and ventricular
arrhythmia. Possible liver effects.
explanation of carcinogenicity: not listed as a carcinogen by ntp, iarc
or osha
effects of overexposure: incoordination and impaired judgment may occur
at vapor exposures from 500-1000 ppm. Dizziness, drowsiness, and
general anestethic effects may occur in ranges of 1000 ppm and
higher. May cause eye con junctivitis.
medical cond aggravated by exposure: increased sensitivity to adrenaline
may be caused by over exposure.
First aid: inhalation: remove to fresh air. If not breathing, give cpr.
if breathing is difficult, give oxygen. Call a physician. Eye:
flush immediately with large amounts of water for 15 minutes. Get
medical at tention. Skin: remove contaminated clothing. Wash with
soap and water promptly. Ingestion: do not induce vomiting. Give
milk or usp mineral oil. Get immediate medical attention. Avoid
aspiration.
Hcc: t4
boiling pt: b.P. Text: 165f,74c
melt/freeze pt: m.P/f.P text: -26f,-32c
vapor pres: 100
vapor density: 4.6
spec gravity: 1.32
evaporation rate & reference: >1 (n-butyl acetate=1)
solubility in water: negligible
appearance and odor: clear,colorless liquid; mildly sweet odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizing agents, alkalis,water,moist air, aluminum, zinc. Do
not store material in aluminum containers.
stability condition to avoid: high temperatures, sparks, open flames,
welding arcs.
hazardous decomposition products: when involved in fire,
1,1,1-trichloroethane emits highly toxic and irritating hydrogen
chloride and phosgene fumes.
Waste disposal methods: dispose of i/a/w federal, state & local
regulations. Unused material will be a land-banned hazardous waste.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 96.7%
other rec limits: none specified
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: 1,4-dioxane (diethylene dioxide) (sara iii)
cas: 123-91-1
rtecs #: jg8225000
fraction by wt: 2.5%
other rec limits: none specified
osha pel: s, 100 ppm
acgih tlv: s, 25 ppm; 9293
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
ingred name: 1,2-butylene oxide (sara iii)
cas: 106-88-7
rtecs #: ek3675000
fraction by wt:
other rec limits: none specified
epa rpt qty: 1 lb
dot rpt qty: 1 lb
ingred name: nitromethane
cas: 75-52-5
rtecs #: pa9800000
fraction by wt:
other rec limits: none specified
osha pel: 100 ppm
acgih tlv: 100 ppm; 9192
Ld50 lc50 mixture: oral rat ld50 is >2000 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: material is irritating to body
tissues. Toxicity is low (see ld50). in quantities over 500 ppm
produce increasing cns depression including dizziness, drunkenness
and in extreme cases unconsciousness and death. In lab animals the
product causedthyroid, liver and kidney effects plus decreased
white blood cell counts.
explanation of carcinogenicity: exposure to a very sinilar product did
not cause cancer, showed no fetal toxicity short of mother's
toxicity.
effects of overexposure: eyes: may cause pain. Skin: drying or flaking.
inhalation: dizziness, drunkenness. At concentrations > 10,000 ppm;
may cause unconsciousness and death. May also produce cardiac
arrhythmias. ingested: only relatively large or repeated
ingestions are expected to have effect.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: eye: flush w/water 15 min, hold lids open. Skin: wash with soap
& water. Remove contaminated clothing and launder before reuse.
inhaled: remove to fresh air. Restore breathing if necessary.
ingested: do n ot induce vomiting. Give 2 large glasses of milk or
water and get immediate medical care. Doctor to order vomiting.
nothing by mouth if unconscious. If irritation persists or is
severe,see a doctor.
Hcc: t4
boiling pt: b.P. Text: 165f,74c
vapor pres: 100 mm hg
vapor density: 4.5
spec gravity: 1.31
solubility in water: 0.07gm/100gm
appearance and odor: colorless liquid irritating odor at high
concentrations
corrosion rate: unknownn
Stability indicator/materials to avoid: yes
prolonged contact with water may cause corrosion. Avoid contact with
aluminum and its alloys or other reactive metals.
stability condition to avoid: open flames, welding arcs or other high
temperature sources which induce thermal decomposition.
hazardous decomposition products: hydrogen chloride and very small
amounts of phosgene and chlorinel
Waste disposal methods: dispose i/a/w all federal, state and local
regulations. manufacturer suggests that disposal may be done by
sending to licensed reclaimer or to permitted incinerator.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 95%
other rec limits: none specified
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: 1,3-dioxolane
cas: 646-06-0
rtecs #: jh6760000
fraction by wt: 2.85%
other rec limits: none specified
ingred name: 1,2-butylene oxide (sara iii)
cas: 106-88-7
rtecs #: ek3675000
fraction by wt: 0.47%
other rec limits: none specified
epa rpt qty: 1 lb
dot rpt qty: 1 lb
ingred name: nitromethane
cas: 75-52-5
rtecs #: pa9800000
fraction by wt: 0.43%
other rec limits: none specified
osha pel: 100 ppm
acgih tlv: 100 ppm; 9192
ingred name: sec-butyl alcohol (sara iii)
cas: 78-92-2
rtecs #: eo1750000
fraction by wt: 1.22%
other rec limits: none specified
osha pel: 150 ppm
acgih tlv: 100 ppm; 9293
Reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eyes-can cause severe irritation.
skin-prolonged or repeated contact can acuse moderate irritation.
breathing-excessive inhalation of vapors can cause nasal &
respiratory irritation. Swallowing-can ca use gastrointestinal
irritation.
explanation of carcinogenicity: this compound contains no ingredients at
concentrations of 0.1% or greater that are carcinogens or suspect
carcinogens.
effects of overexposure: eye-can cause redness, tearing, blurred vision.
skin-can cause defatting, dermatitis. Breathing-can cause
dizziness, weakness, fatigue, nausea, headache, possible
unconsciousness and even asphyxiztion . Swallowing-can cause
nausea, vomiting, diarrhea.
First aid: skin-thoroughly wash exposed area with soap & water. Remove
contaminated clothing. Eyes-flush with large amounts of water, get
medical attention. Swallowed-do not induce vomiting. Call a
physician or transport to emergency facility. Braethed-remove
individual to fresh air. If breathing is hard, give oxygen. If
breathing has stopped give artificial respiration. Keep warm, quiet
& get medical atten.
Hcc: n1
boiling pt: b.P. Text: 165f,74c
vapor pres: 100 mmhg
vapor density: 4.5
spec gravity: 1.306
evaporation rate & reference: 2.60
solubility in water: insoluble in water.
appearance and odor: liquid, nonflammable.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
avoid contact with strong alkalies.
stability condition to avoid: none specified by manufacturer.
hazardous decomposition products: may form toxic materials, carbon
dioxide & carbon monoxide, hydrogen chloride, various hydrocarbons,
etc.
Waste disposal methods: allow volatile portion to evaporate in hood.
allow sufficient time for vapors to completely clear hood duct
work. Destroy remaining material by burning in an iron pan.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 100%
other rec limits: none recommended
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9293
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
Ld50 lc50 mixture: oral ld50 (rats): >10,000 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eyes: slight irritation & corneal
injury. Skin: irritation, drying & flaking. Ingestion: aspiration
w/rapid aspiration into lungs. Inhalation: dizziness, drunkenness,
unconsciousness, cardiac arrhythm ias (irregular heartbeats), &
death.
explanation of carcinogenicity: none
effects of overexposure: inhalation: readily absorbed through the lungs,
resulting in injury to other body systems.
First aid: eyes: flush w/water for at least 5 mins. Skin: wash off
w/water or shower. Ingestion: don't induce vomiting. Inhalation:
remove to fresh air. If breathing stops, give mouth-to-mouth
resuscitation. If breathing is difficult, give oxygen. Note to
physician: aspiration may cause systemic effects, decision whether
to induce vomiting should be made by attending physician. See supp.
Boiling pt: b.P. Text: 165f
vapor pres: 100
vapor density: 4.55
spec gravity: 1.330-1.335
solubility in water: 0.07 g/100 g
appearance and odor: colorless liquid w/irritating odor at high
concentrations
Stability indicator/materials to avoid: yes
water, aluminum & its alloys, metallic aluminum & zinc powders
stability condition to avoid: open flames, welding arcs, high
temperatures
hazardous decomposition products: hydrogen chloride, small amounts of
phosgene & chlorine, hydrochloric acid, slow hydrolysis produces
corrosive acid
Waste disposal methods: send unused contents to licensed reclaimer or
permitted incinerators in accordance w/federal, state, & local
regulations. Don't dump into sewers, on the ground or into any body
of water.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroethane) (chlorothene nu),
aerothane tt, chlorothene
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 99.9%
other rec limits: 450 ppm stel
osha pel: 350 ppm
acgih tlv: 1910 mg/cum
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
Ld50 lc50 mixture: ld50 oral (rat)= 10-12 g/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute- inhalation: cns depressant;
irritation of respiratory tract. Eye: irriation of eyes.
skin: irritation and dermatitis. Ingestion: irritation of gi tract,
cns effects. Aspiration into lungs may lead to chemical pneumonia
& pulmonary edema. Chronic: cns, skin.
effects of overexposure: skin & eyes: irritation, dermatitis; inhal: cns
depressant,nausea,vomiting, headache, unconsciousness, death.
ingestion: nausea, vomiting, diarrhea, unconsciousness.
medical cond aggravated by exposure: cns, skin.
First aid: inhalation: remove to fresh air, provide cpr/oxygen if needed.
eye contact: flush with water for 15 minutes. Get medical help. Skin
contact: wash with soap and water. Get med attention if symptoms
persis t. Ingestion: do not induce vomiting, drink 1-2 glasses of
water. Get medical help immediately.
Hcc: t4
boiling pt: b.P. Text: 165f/72c
melt/freeze pt: m.P/f.P text: -49f/-45c
vapor pres: 135 mmhg
vapor density: 4.54
spec gravity: 1.3
evaporation rate & reference: 0.35 (ethyl ethr=1)
solubility in water: negligible
appearance and odor: clear, colorless liquid with ether-like odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizers, caustic soda and caustic potash.
stability condition to avoid: open flames,heat,electric arcs
hazardous decomposition products: hydrogen chloride and traces of
phosgene.
Waste disposal methods: dispose of collected material in accordance with
local, state & federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: >95%
other rec limits: none specified by m.
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: glycol methylene ether
cas: 646-06-0
rtecs #: jh6760000
fraction by wt: balance
ingred name: sec.Butanol
cas: 78-92-2
fraction by wt:
other rec limits: none specified by m.
osha pel: 150 ppm
acgih tlv: 100 ppm; 9293
ingred name: stabilizers
other rec limits: none recommended
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eye-liquid is irritating to eyes.
skin-liquid is mildly irritating to the skin. Inhalation-vapors may
be irritating to the nose, throat & respiratory tract. High vapor
concentrations may cause cns dep ression. Ingestion-early to
moderate cns depression.
explanation of carcinogenicity: this chemical is not listed as having
any evidence of being carcinogenic.
effects of overexposure: eye-may cause pain, tearing, and inflammation.
skin-skin irritation & dermatitis. Ingestion-giddiness, headache,
nausea and dizziness; in extreme cases unconsciousness and death
may occur. Aspiration pneumonitis may evidenced by coughing,
labored breathing and cyanosis, in severe cases death.
medical cond aggravated by exposure: preexisting eye, and respiratory
disorders may be aggravated by exposure to this product.
First aid: eye-hold eyelids open & flush with plenty of water for 15
min. Get medical attention. Skin-remove clothin/shoes. Flush skin
with water. Then wash with soap/water. If irritation occurs,
contact physici an. Inhalation-remove victim to fresh air, if
breathing is hard, provide oxygen; if not breathing give cpr. Get
medical attention. Ingestion-do not indcue vomiting. Get medical
attention.
Hcc: n1
boiling pt: b.P. Text: 165f,74c
vapor pres: 100
vapor density: 4.6
spec gravity: 1.30
evaporation rate & reference: 0.37
solubility in water: negligible
appearance and odor: water white with a distinctive sweet odor.
Stability indicator/materials to avoid: yes
avoid strong oxididants, hot reqctive metals. Barium and lithium.
stability condition to avoid: none specified by manufacturer.
hazardous decomposition products: thermal decomposition yields halogens,
halogen acids, etc.
Waste disposal methods: dispose of easte in accordance with federal,
state and local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: >95%
other rec limits: none recommended
osha pel: 350 ppm
acgih tlv: 350 ppm/450stel;9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: ethylene dichloride (sara iii)
cas: 107-06-2
rtecs #: ki0525000
fraction by wt:
other rec limits: none recommended
osha pel: 50 ppm; z-2
acgih tlv: 10 ppm; 9394
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
ingred name: 1-nitropropane
cas: 108-03-2
rtecs #: tz5075000
fraction by wt:
other rec limits: none recommended
osha pel: 25 ppm
acgih tlv: 25 ppm; 9394
ingred name: tert-butyl alcohol (sara iii)
cas: 75-65-0
rtecs #: eo1925000
fraction by wt:
other rec limits: none recommended
osha pel: 100 ppm
acgih tlv: 100ppm; 9394
ingred name: 1,3-dioxolane
cas: 646-06-0
rtecs #: jh6760000
fraction by wt:
other rec limits: none recommended
ingred name: sec-butyl alcohol (sara iii)
cas: 78-92-2
rtecs #: eo1750000
fraction by wt:
other rec limits: none recommended
osha pel: 150 ppm
acgih tlv: 100 ppm; 9394
ingred name: 1,2-epoxybutane (sara iii)
cas: 106-88-7
rtecs #: ek3675000
fraction by wt:
other rec limits: none recommended
epa rpt qty: 1 lb
dot rpt qty: 1 lb
Routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhal: min effects observed
1000ppm.Unconsc/death possible
>10000ppm.Blood pressure depression,cardiac
sensitization,ventricular arrhythmia can result frm expo to near
-anesthetic levels.Aerosol form more acutely toxic than
vap.Skin: prol/rep contact irrit,defatt,derm.Absoption (supplem)
explanation of carcinogenicity: per msds: product not listed on
osha/iarc/ntp carcinogen lists.Not carcinogenic to lab
animals.Reproductive animal toxici
effects of overexposure: dizziness, drowsiness,throat irrit.
unconsc,death,blood pressure depression, cardiac sensitization,
ventricular arrhythmia, skin irrit, defatting, derm. Slight temp
eye irrit w/slight temp corneal inj ury.Aspiration into lungs
causes chem pneumonia & systemic effects.
medical cond aggravated by exposure: acute & chronic liver disease &
rhythm disorders of the heart.
First aid: inhal: remove to fresh air.Stop breath administer art
resp.Call dr. Skin: remove contamin cloth/shoes.Wash w/soap/water.
eyes: flush immed w/water for @least 15mins.Irrit persists call dr.
ingest: do not induce vomit.Contact dr/emerg med facility immed.
note to dr: adrenalin should never be given to persons overexposed
to 1,1,1-trichloroethane.
Hcc: t4
boiling pt: b.P. Text: 165f,74c
vapor pres: 100 @20c
vapor density: 4.6
spec gravity: 1.32
ph: 7/k
evaporation rate & reference: 0.4, ether-1
solubility in water: 0.07g/100g @25c
appearance and odor: clear, cololess liquid, mildly sweet odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong alkalies,oxidizers,reactive metals(ie
aluminum,potassium,sodium,etc).
stability condition to avoid: avoid contact w/open flame, electric arcs,
or other hot surfaces which can cause thermal decomposition.
hazardous decomposition products: hydrogen chloride, phosgene, chlorine.
Waste disposal methods: do not reuse dr w/o recycling/reconditioning iaw
applicable fed/state/loc laws.Recovered liq may be sent to licensed
reclaimer/incineration facility.Contamin matl must be disposed of
in permitted wast e mgt facility.Consult fed/state/loc authorities.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara 313)
(cercla)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 96.5%
other rec limits: none recommended
osha pel: 350 ppm
acgih tlv: 350 ppm/450stel;9495
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: 1,4-dioxane (diethylene dioxide) (sara 313) (cercla)
cas: 123-91-1
rtecs #: jg8225000
fraction by wt:
other rec limits: none recommended
osha pel: s, 100 ppm
acgih tlv: s, 25 ppm; 9495
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
ingred name: 1,2-butylene oxide (sara 313) (cercla)
cas: 106-88-7
rtecs #: ek3675000
fraction by wt: >0.5%
other rec limits: none recommended
epa rpt qty: 1 lb
dot rpt qty: 1 lb
Ld50 lc50 mixture: ld50 oral, rat: >10,000 mg/kg;
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eye: pain. Slight transient irritation
with slight transient corneal injury. Irritation. Skin: prolonged
or repeated may cause irritation, drying, flaking. Ingestion:
aspirated product may result in i njury to other body systems.
inhalation: high concentrations (10000): unconsciousness, death.
cardiac arthythmias.
explanation of carcinogenicity: this compound contains no ingredients at
concentrations of 0.1% or greater that are carcinogens or suspect
carcinogens.
effects of overexposure: eye pain, transien irritation, skin irritation,
drying, flaking, chemical pneumonia, unconsciousness, cardiac
arthythmias, death.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: eyes: flush with water for 15 minutes while holding eyelids
open. Get medical attention. Skin: remove contaminated clothing.
wash with soap and water. If irritation persist, get medical
attention. Inh alation: remove to fresh air. Restore breathing. Get
medical attention. Ingestion: do not induce vomiting. If occurs,
keep head below hips. Get medical attention.
Hcc: t4
boiling pt: b.P. Text: 165f,74c
melt/freeze pt: m.P/f.P text: not given
vapor pres: 100 @ 20c
vapor density: 4.55
spec gravity: 1.321
evaporation rate & reference: not given
solubility in water: moderate
appearance and odor: colorless liquid, irritating odor at high
concentrations
Stability indicator/materials to avoid: yes
water, aluminum, zinc, amines.
stability condition to avoid: avoid open flames, welding arcs or other
high temperature sources which induce thermal decomposition.
hazardous decomposition products: hydrogen chloride and very small
amounts of phosgene and chlorine.
Waste disposal methods: prevent waste from contaminating surrounding
environment. Discard any product, residue, disposal container or
liner in accordance with all federal, state and local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: 1,1,1-trichloroethane (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 96.5%
other rec limits: none recommended
osha pel: 350 ppm;stel 450 ppm
acgih tlv: 350 ppm;stel 450 ppm
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: diethylene ether (1,4-dioxane) (sara iii)
cas: 123-91-1
rtecs #: jg8225000
fraction by wt: 2.5%
other rec limits: none recommended
osha pel: 25 ppm (skin)
acgih tlv: 25 ppm (skin)
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
ingred name: 1,2-butylene oxide
cas: 106-88-7
rtecs #: ek3675000
fraction by wt: 0.47%
other rec limits: none recommended
osha pel: stel 2 ppm
epa rpt qty: 1 lb
dot rpt qty: 1 lb
ingred name: nitromethane
cas: 75-52-5
rtecs #: pa9800000
fraction by wt: 0.34%
other rec limits: none recommended
osha pel: 100 ppm
acgih tlv: 100 ppm