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Sulfuric acid and oleum
Sulfuric acid; oleum
Chemicals-inorganic
Y - Indicates information is in the hazardous materials information resource system (hmirs).
PMICA - Item does not contain precious metal.
CRITL- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.
043940 - Chemicals noi
450 - Acids, liquid, corrosive
9 - Other or no special handling required (sh)
A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.
C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp
W - Rating variable
W - Corrosive materials, un class 8 (corrosive label)
Questions & Answers: |
|
| What are the historical prices recorded for this stock number? | |
| Historical data shows pricing from $50.38 to $83.97.. | |
| Does NSN 6810-00-823-8008 have a shelf life? | |
| No. There is no shelf life applicable for this NSN. | |
| What NATO entities are users of this NSN? | |
| Department Of The Army, Department Of The Air Force, U.s. Marine Corps, Department Of The Navy, U.s. Coast Guard, Spain, and Turkey | |
| What is the NIIN of NSN 6810-00-823-8008? | |
| 008238008 or 00-823-8008 | |
| Does NSN 6810-00-823-8008 require demilitarization? | |
| Yes - ITAR Controlled | |
| What is the most recent solicitation for NSN 6810-00-823-8008? | |
| No solicitations for this NSN. | |
| When was this national stock number assigned to the federal catalog? | |
| Jan 01, 1963 | |
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
effects of overexposure: causes severe burns to eyes, skin, and mucousa.
can be fatal if ingested. Respiratory irritation if inhaled.
First aid: skin and eyes: flush with large amounts of water for at least
15 minutes. Remove contaminated clothing. Ingestion: drink large
amounts of water. Do not induce vomiting. Inhalation: remove to
fresh air . Give cpr/o2 if needed. Observe for delayed reaction. In
all cases, get prompt medical attention.
Hcc: c1
boiling pt: b.P. Text: 154f,68c
spec gravity: 1.400
solubility in water: complete
appearance and odor: colorless to slight yellow, clear to turbid, oily
liquid.
Stability indicator/materials to avoid: yes
anhydrides, alkali, organics, amines, gas forming salts, glycols,
organic oxides, oximes, nitro compounds, oxidizers
stability condition to avoid: high heat, moisture
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: disposal is subject to federal, state, and local
regulations. Users should review their operations for compliance,
then consult with appropriate regulatory agencies before
discharging or disposing of material.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 50%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 50%
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
effects of overexposure: severe burns to skin and eyes. Mists and fumes
are irritating to the respiratory tract.
First aid: wash all affected parts thoroughly with water. If in eyes
flush with water for at least 15 minutes and get medical attention.
Hcc: c1
boiling pt: b.P. Text: decomposes
spec gravity: 1.4000
solubility in water: complete
appearance and odor: colorless liquid with a sharp odor.
Stability indicator/materials to avoid: yes
metals, bases
stability condition to avoid: high heat, moisture
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: place any absorbed material in approved dot
container suitable for shipment to disposal area.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 50%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
effects of overexposure: severe burns to skin or eyes.Inhalation of mist
from hot acid can be injurious to lungs.
First aid: eyes: irrigate with water for at least 15 minutes. For get
immediate medical attention. Skin: wash contaminated areas of body
with soap and water. Get immediate medical attention. Ingestion:
stomach w ash. Inhalation: oxygen with use of intermittent positive
pressure breathing apparatus.
Hcc: c1
boiling pt: b.P. Text: 625f,329c
vapor pres: 0
spec gravity: 1.4042
evaporation rate & reference: < 1 (ether = 1)
solubility in water: complete
appearance and odor: slightly viscous, clear to slightly cloudy liquid.
Stability indicator/materials to avoid: yes
carbides, chlorates, fulminates, nitrates, picrates, powdered metals
stability condition to avoid: high heat, moisture
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: neutralize acid with a large amount of water,
soda ash, and slaked lime by stirring. Dispose of by storing in an
approved storage container for corrosive liquids.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 50.0%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: product's ld50 (oral rat) was not stated
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: third degree burns. Severe
respiratory, skin, and eye irritant. Bronchitis, laryngeal and
pulmonary edema may result.
explanation of carcinogenicity: iarc lists a possible link between
sulfuric acid exposure & laryngeal cancer w/insufficient data for
confirmation.
effects of overexposure: prickling or burning sensation of skin and
mucous membranes. Coughing, sneezing, tightness of chest,
difficulty in breathing.
medical cond aggravated by exposure: any pre-existing respiratory
disease, for example emphysema.
First aid: see supp data. Get immediate medical attention!! Eye: flush
w/water for 15 min. Skin: wash w/soap & water. Remove contaminated
clothing & launder before reuse. Inhaled: remove from exposure. Aid
or resto re breathing as needed. Ingested: do notinduce vomiting.
give large quantities of milk, milk of magnesia, table oil, eggs or
water to drink. Get immediate medical attention. Rinse mouth often.
Hcc: c1
nrc/state lic num: none
boiling pt: b.P. Text: 260f,127c
melt/freeze pt: m.P/f.P text: -80f, 35%
vapor pres: < 1
vapor density: 3.4 (air=1
spec gravity: 1.400 (water=1)
ph: < 1
solubility in water: complete
appearance and odor: clear, colorless liquid.
percent volatiles by volume: unk.
Stability indicator/materials to avoid: yes
metals, organics, nitrates, carbides, chlorates, allyl compounds, and
aldehydes
stability condition to avoid: contact with metals, organics.
hazardous decomposition products: sulfur oxides at high temperature.
reacts w/above to form hydrogen cyanide & hydrogen cyanide.
conditions to avoid polymerization: will not occur. avoid all contact
with organic substances and most metals.
Waste disposal methods: neutralize w/lime or soda ash. Consult
regulations. Epa hazardous waste d002- corrosive & d003-reactive if
discarded w/o prior neutralization.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 34-36%
other rec limits: none specified
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 64-66%
other rec limits: none specified
Ld50 lc50 mixture: ld50 (oral rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: inhalation of vapors may cause
severe irritation or burns of the respiratory system, pulmonary
edema, and lung inflammation. May cause severe burns to skin and
eyes. Ingestion may cause severe burns to mouth, throat, and
stomach. May affect kidney function. Chronic: may damage lungs.
explanation of carcinogenicity: this product is not listed by iarc, ntp,
or osha as a carcinogen.
effects of overexposure: severe irritation or burns to eyes, nose, and
throat. Pulmonary edema, bronical emphysema, conjunctivitis,
stomatitis, dental erosion, nausea, and vomiting.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the respiratory tract may
be at increased risk from exposure.
First aid: inhalation: remove to fresh air. Resuscitate if not
breathing. Get medical attention. Eyes: immediately flush with
plenty of water for 15 minutes holding eyelids open. Get medical
attention. Skin: rem ove contaminated clothing. Wash with plenty of
water for 15 minutes. Get medical advice. Ingestion: do not induce
vomiting. Give nothing by mouth if unconscious. Get immediate
medical attention.
Hcc: c1
boiling pt: b.P. Text: 380f,193c
melt/freeze pt: m.P/f.P text: -31f,-35c
vapor pres: < 0.3
vapor density: 3.4
spec gravity: 1.70 - 1.85
ph: < 1
evaporation rate & reference: < 1 (n-butyl acetate = 1)
solubility in water: complete
appearance and odor: oily, clear to turbid, colorless to light gray,
odorless liquid.
Stability indicator/materials to avoid: yes
water, alkaline solutions, metals, metal powder, carbides, chlorates,
fulminates, nitrates, strong oxidizing agents.
stability condition to avoid: reacts violently with water and organic
materials with evolution of heat.
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state, and local environmental regulations. Do
not flush to surface water or sanitary sewer system. If approved,
neutralize and trans fer to waste treatment system.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 78-100%
other rec limits: none specified
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 0-22%
other rec limits: none specified
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: will cause burns to skin and eyes.
inhalation of mist can cause lung injuries. Ingestion can cause
severe injury.
explanation of carcinogenicity: product contains no materials currently
classified as carcinogenic by ntp, iarc or osha.
effects of overexposure: skin, eye burns, lung injury, digestive tract
injury.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: in case of contact, immediately flush skin and eyes with
plenty of water for at least 15 minutes. For eye or skin burns, get
immediate medical attention. For inhalation or ingestion, get
immediate med ical attention.
Hcc: c1
boiling pt: b.P. Text: 220f,104c
spec gravity: 1.2085 - 1.2185
solubility in water: complete
appearance and odor: substantially clear and white liquid.
Stability indicator/materials to avoid: yes
combustible materials
stability condition to avoid: high heat, sparks, open flames, moisture
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: neutralize acid with alkali and flush to sewer
with plenty of water, if permitted by local and state regulations.
dispose of in accordance with all applicable federal, state, and
local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 28-30% %
other rec limits: none specified
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 70-72% %
other rec limits: none specified
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute-corrosive.Swallowed: causes
mouth, throat,esophagus,stomach burns,gastric perforation &
death.Inhalation: severe irritation of the respiratory
tract,sneezing,coughing & lung damage. Skin: burning &
charring.Eyes: irreversible damage & possibly blindness.
chronic-dermatitis,bronchitis,chronic runny nose & bleed,phleg
effects of overexposure: spray or mists are severely irritating to the
eyes and respiratory tract. Causes tickling of the nose and throat.
causes charring of the skin as a result of the great affinity for,
and strong exotherm ic reaction with water.
medical cond aggravated by exposure: skin irritation may be aggravated
in persons with existing skin lesion. Breathing of sprays (sulfuric
acid mists) may aggravate acute or chronic asthma and other chronic
pulmonary disease.
First aid: start first aid and get medical care at once. Eyes: hold
eyelid open and flush with water for 15 minutes. Skin: wipe excess
with a dry cloth. Then wash with plenty of water and soap.
inhalation: remov e to fresh air. Give cpr/oxygen if needed.
ingestion: if conscious, drink 2-3 glasses of water. Do not induce
vomiting. Note to physician: no specific antidote is available.
treat symptomatically.
Hcc: c1
boiling pt: b.P. Text: 380f,193c
melt/freeze pt: m.P/f.P text: 12f,-11c
vapor pres: < 1
vapor density: 3.4
spec gravity: 1.395-1.404
ph: < 1
evaporation rate & reference: not given
solubility in water: complete
appearance and odor: clear, colorless to cloudy, oily liquid. Odorless.
Stability indicator/materials to avoid: yes
organics, chlorates, carbides, fulminates, picrates, metals, water.
stability condition to avoid: when diluting, acid should be added to
diluent. Do not add diluent to sulfuric acid.
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: dispose of in accordance with all applicable
local, state, and federal regulations. This material is rcra
hazardous waste d002, corrosive & d003, reactive. Spills are
subject to cerlca reporting requi rements: reportable quantity =
1000 lbs.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii) *
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 50%
other rec limits: none specified
osha pel: 1 mg/m3 *
acgih tlv: 1 mg/m3; 9192 *
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 50%
other rec limits: none specified
ld50 lc50 mixture: unknown
route of entry inds - inhalation: yes
skin: no
ingestion: no
carcinogenicity inds - ntp: no
iarc: no
osha: no
effects of exposure: third degree burns. Severe respiratory, skin, and eye
irritant. Bronchitis, laryngeal and pulmonary edema may result.
explanation of carcinogenicity: product contains no ingredients currently
classified as carcinogenic by ntp, iarc, or osha.
signs and symptions of overexposure: prickling or burning sensation of skin and
mucous membranes. Coughing, sneezing, tightness of chest, difficulty in
breathing.
medical cond aggravated by exposure: any pre-existing respiratory disease, for
example emphysema.
first aid: inhalation: remove to fresh air. Give mouth-to-mouth resuscitation
if not breathing. Give oxygen if breathing is difficult. Get medical
attention. Eyes: flush with water for at least 15 minutes while holding
eyelids open. Get medical attention. Skin: wash with soap and water. Remove
contaminated clothing. Get medical attention. Ingested: do not induce
vomiting. Get medical attention immediately.
hcc: c1
b.P. Text: 275f,135c
m.P/f.P text: -80f,-62c
decomp text: unknown
vapor pres: < 1
vapor density: 3.4
spec gravity: 1.265
ph: < 1
viscosity: unknown
evaporation rate & reference: unknown
solubility in water: complete
appearance and odor: clear, colorless liquid.
percent volatiles by volume: 0%
corrosion rate: unknown
product id: electrolyte battery acid
cage: 75656
company name: los angeles chemical co
street: 4545 ardine st
po box: 1987
city: south gate ca
zipcode: 90280
label required ind: y
date of label review: 10/05/1992
status code: c
label date: 10/05/1992
year procured: 1991
origination code: f
eye protection ind: yes
skin protection ind: yes
signal word: danger
respiratory protection ind: yes
health hazard: moderate
contact hazard: severe
fire hazard: none
=======================================================
responsible party cage: 75656
trans id no: 87167
product id: electrolyte battery acid
msds prepared date: 10/05/1992
review date: 10/29/1992
mfn: 1
net unit weight: 10.55 lbs
multiple kit number: 0
review ind: y
unit of issue: gl
container qty: 4
type of container: bottle
Hazard and precautions: inhalation of vapors may cause severe irritation or
burns of the respiratory system, pulmonary edema, or lung inflammation. May
cause severe burns to skin or eyes. Ingestion may cause severe burns to
mouth, throat, and stomach. May affect kidney function. Chronic: may damage
lungs. First aid: inhalation: remove to fresh air. Resuscitate if not
breathing. Get medical attention. Eyes: immediately flus h with plenty of
water for 15 minutes holding eyelids open. Get medical attention. Skin: remove
contaminated clothing. Wash with plenty of water for 15 minutes. Get medical
advice. Ingestion: do not ind uce vomiting. Give nothing by mouth if
unconsciou
spill release procedures: wear full acid-protective gear. Remove sources of
ignition. Neutralize spill with lime or soda ash. Flush to waste water
treatment system if allowed. Dike large spills. Do not wash into storm or
sanit ary sewer system.
neutralizing agent: lime or soda ash (min 5.2 lbs per gallon of electrolyte)
waste disposal methods: neutralize with lime or soda ash. Consult regulations.
epa hazardous waste d0002- corrosive snd d0003-reactive if discarded.
handling and storage precautions: do not store near organics. Hydrogen may be
generated inside drums and tanks. Avoid flames and sparks.
other precautions: never add water to containers of acid. Beware of acid
reaction in sewers that may produce flammable hydrogen gas or toxic hydrogen
sulfide.
Ld50 lc50 mixture: h2so4 ld50 rat oral 2140mg/kg;1tsp-1/2oz
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: ingest: corr.Causes burns of
mouth/throat/esophagus/stomach.May cause severe injury-gastric
perforation/peritonitis,death.Inhal: corr muc memb.Sympt-burn
sens,tickling of nose/throat,sneezing,cough,whee
ze,laryngitis,short breath.Mist/spray serious dmg to lung
tissue.Skin: corr.Causes burning/charring.Eye: corr.(sign/sympt)
explanation of carcinogenicity: per msds: no ingred designated by
iarc/ntp/acgih/osha as porbable human carc.
effects of overexposure: health: causes irreversible eye dmg,possible
blindness.Spray/mist severely irrit eye. Overexpo: rep expo may lead
to contact dermatitis,may cause corr of dental enamel,can cause
bronchitis w/cough,phleg m,shortness of breath,emphysema,can cause
chronic runny nose,tearing of eyes,nosebleeds,stomach upsets.
medical cond aggravated by exposure: skin irrit may be aggravated in
individuals w/existing skin lesions.Breathing of vap/spray(mist)may
aggravate acute/chronic asthma & chronic pulmonary disease such as
emphysema & bronchitis.
First aid: speed in remove matl frm contact w/body is primary
importance.Start 1staid @once.Ingest: consc/alert give 2/more glass
of h2o/milk.Dont induce vomit.Get med attn.Skin: immed wipe off matl
w/dry cloth.Wa sh w/lots of soap/h2o w/saf shower @least
15mins.Remove contam cloth/shoes.Get med attn immed.Inhal: move to
fresh air.Not breath give cpr/arat resp;breath diffi/irrit dvlp get
med attn.Eye: (oth preca)
Hcc: c1
boiling pt: b.P. Text: 379f,193c
melt/freeze pt: m.P/f.P text: 12f,-11c
decomp temp: decomp text: np
vapor pres:
vapor density: 3.4
spec gravity: 1.7 78%
ph: np
viscosity: np
evaporation rate & reference: np
solubility in water: miscible
appearance and odor: clear, colorless to cloudy, oily liquid, odorless
percent volatiles by volume: np
corrosion rate: np
Stability indicator/materials to avoid: yes
org,chlorates,carbides,fulminates,picrates,metals.Rx exotherm
w/h2o.Metal surf generate flam/explo h2 gas.Org matl-fire.
stability condition to avoid: when diluting acid shold be added to
diluent.Dont add diluent to acid.
hazardous decomposition products: sulfur oxides.
Waste disposal methods: dispose of in accordance with local, state and
federal regulations.Rcra haz
waste: d002(corro),d003(reactive).Spills subj to
cercla: rq=1000lb.Sara title iii sec 302,313.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara 302/313) (cercla)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 78-100%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3/3 stel; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
other rec limits: none recommended
Ld50 lc50 mixture: ld50 (oral rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation of vapors causes severe
irritation or burns of the respiratory system, pulmonary edema, or
lung inflammation. Eye contact causes severe damage and possible
blindness. Skin contact causes bu rns and possible deep ulceration.
ingestion causes severe burns to mouth, throat, and stomach.
explanation of carcinogenicity: this chemical is not listed by iarc,
ntp, or osha as a carcinogen.
effects of overexposure: severe irritation or burns to eyes, nose and
throat. Pulmonary edema, bronical emphysema, conjunctivitis,
stomatitis, dental erosion, nausea and vomiting.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the respiratory tract may
be at increased risk from exposure.
First aid: inhalation: remove to fresh air. Resuscitate if not breathing.
get medical attention. Eyes: immediately flush with plenty of water
for 15 minutes holding eyelids open. Get prompt medical attention.
skin : remove contaminated clothing. Wash with plenty of water for
15 minutes. Get medical advice. ingestion: do not induce vomiting.
give nothing by mouth if unconscious. Get immediate medical
attention.
Hcc: c1
boiling pt: b.P. Text: 250f-529f
melt/freeze pt: m.P/f.P text: 30f to -21f
vapor pres: < 0.3
vapor density: 3.4
spec gravity: 1.380-1.835
ph: < 1
evaporation rate & reference: < 1 (no reference given)
solubility in water: complete
appearance and odor: clear liquid, no odor
Stability indicator/materials to avoid: yes
water, alkaline solutions, metals, metal powder, carbides, chlorates,
fuminates, nitrates, picrates, strong oxidizers
stability condition to avoid: moisture
hazardous decomposition products: oxides of sulfur and hydrogen
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state and local environmental regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 48-93%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 7-52% %
other rec limits: none recommended
Ld50 lc50 mixture: ld50 (oral rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: inhalation of vapors causes severe
irritation or burns of the respiratory system, pulmonary edema, or
lung inflammation. Eye contact causes severe damage and possible
blindness. Skin contact causes bu rns and possible deep ulceration.
ingestion causes severe burns to mouth, throat, and stomach.
explanation of carcinogenicity: sulfuric acid mists are iarc-2b
effects of overexposure: severe irritation or burns to eyes, nose and
throat. Pulmonary edema, bronical emphysema, conjunctivitis,
stomatitis, dental erosion, nausea and vomiting.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the respiratory tract may
be at increased risk from exposure.
First aid: inhalation: remove to fresh air. Resuscitate if not breathing.
get medical attention. Eyes: immediately flush with plenty of water
for 15 minutes holding eyelids open. Get prompt medical attention.
skin : remove contaminated clothing. Wash with plenty of water for
15 minutes. Get medical advice. Ingestion: do not induce vomiting.
give nothing by mouth if unconscious. Get immediate medical
attention.
Hcc: c1
boiling pt: b.P. Text: 250f-529f
melt/freeze pt: m.P/f.P text: 30f to -21f
vapor pres: < 0.3
vapor density: 3.4
spec gravity: 1.380-1.835
ph: < 1
evaporation rate & reference: < 1 (no reference given)
solubility in water: complete
appearance and odor: clear liquid, no odor
Stability indicator/materials to avoid: yes
water, alkaline solutions, metals, metal powder, carbides, chlorates,
fuminates, nitrates, picrates, strong oxidizers
stability condition to avoid: moisture
hazardous decomposition products: oxides of sulfur and hydrogen
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state and local environmental regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 51%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 49%
other rec limits: none recommended
Ld50 lc50 mixture: rat,lc50: 510mg/m3/2h;ld50(oral)2140mg/kg
routes of entry: inhalation: no skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eye, skin, respiratory &
gi tracts. Acute- corrosive! Causes severe eyes, skin & all body
tissue burns. Eye damage may be permanent. May cause skin
ulceration. Mist is irritating to resp iratory tract. Ingestion
causes severe burns. Chronic- may cause dental erosion, impaired
lung function.
explanation of carcinogenicity: none
effects of overexposure: severe irritation and burning, visual
impairment, dental erosion, cough, severe pain, blindness,
wheezing, abnormal lung sounds, skin ulcer, itching and rash,
bleeding, vomiting, diarrhea
medical cond aggravated by exposure: open wounds and sores, respiratory
ailments such as emphysemia and bronchitis
First aid: get medical attention immediately. Eye/skin: immediately flush
with water for 15-20 minutes. Hold eyelids open. Continue rinsing
eyes with normal saline until ph=7. Inhaled: remove to fresh air.
provide oxygen/cpr if needed. Oral: do not induce vomiting. If
conscious, drink 2-4 cupfuls of milk/water. Never give anything by
mouth to an unconscious person. Note to physician: treat
symptomatically.
Hcc: c1
nrc/state lic num: not relevant
boiling pt: b.P. Text: 554f,290c
decomp temp: decomp text: 644f,340c
vapor pres: 1 @ 295f
vapor density: 3.4
spec gravity: 1.07 - 1.40
ph: 0.3 1n
solubility in water: soluble
appearance and odor: clear, oily liquid - odorless
Stability indicator/materials to avoid: yes
bases, carbides, metals, oxidizers, organics, water, cyanides,
sulfides, combustibles, amines, acetic anhydride
stability condition to avoid: adding water to acid (always add acid
slowly to water), excessive heat
hazardous decomposition products: oxides of sulfur
Waste disposal methods: dispose of in accordance with local, state, and
federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara 302/313) (cercla)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 10 - 51%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3/3 stel; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 49 - 90%
other rec limits: none recommended
osha pel: not relevant
acgih tlv: not relevant