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Photographic Developer Replenisher

NSN: 6750-00-965-4950 | Model: VNF-1/RVNP 1ST DEV REPL

A chemical used to reactivate a processing solution to its original working strength and volume. It does not include replenisher, x-ray film processing.

NSN Properties and Flags
NATO Stock Number
6750-00-965-4950
DEMIL
NO
Physical Form
Liquid and powder
Reproduction Type
Color
Unit Package Yield
100.000 liters
Sequential Usage
First stage
Material Processing Method
Automatic
Grain Control
Not rated
Image Contrast
Not rated
Unit Package Content Form
Separate units for mixing
Material Type For Which Designed
Film

Pricing and Availability

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NSN 6750-00-965-4950 Datasheet

Supply Class (FSC):
Photographic Supplies
Cross Reference:
  • VNF-1/RVNP 1ST DEV REPL
  • 149 3899
Cage Codes:
  • Eastman Kodak Company (CAGE 19139)
Replacements:
  • 6750-00-965-4950 replaces 6750-01-060-6264
Schedule B & Trade:
  • Schedule B: 9010506000 (NAICS 333316)

    Apparatus and equipment for photographic labs nesoi

  • SITC: 88135

    Apparatus and equipment for photographic (including cinematographic) laboratories, n.E.S.; negatoscopes; projection screens

  • End Use: 21190

    Photo, service industry machinery

Identification:
HMIC

Y - Indicates information is in the hazardous materials information resource system (hmirs).

PMIC

U - Precious metal content is unknown

CRITL

- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.

Freight Information:
  • NMFC:

    043940 - Chemicals noi

  • WCC:

    635 - Chemicals, other than drugs or sundries

  • SHC:

    9 - Other or no special handling required (sh)

  • ADC:

    A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.

  • ACC:

    C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp

  • TCC:

    P - Poison, class b, un class 6 (poison label)

  • LTL:

    W - Rating variable

NSN Management Codes:
  • SOS
    Sms
  • AAC
    Y
  • Quantity per pack
    1
  • Unit of Measure
    Kt
  • Shelf Life
    24 mo.
  • Classification Control
    X
  • MGMT_CTL
    9b----t
  • Repariability

Questions & Answers:

What are the historical prices recorded for this stock number?
Historical data shows pricing from $202.50 to $337.50..
Does NSN 6750-00-965-4950 have a shelf life?
No. There is no shelf life applicable for this NSN.
What NATO entities are users of this NSN?
France, Republic Of Korea, and United Kingdom
What is the NIIN of NSN 6750-00-965-4950?
009654950 or 00-965-4950
Does NSN 6750-00-965-4950 require demilitarization?
Yes - ITAR Controlled
What is the most recent solicitation for NSN 6750-00-965-4950?
No solicitations for this NSN.
When was this national stock number assigned to the federal catalog?
Jan 01, 1960
MSDS

Material Safety

MSDS BBZBZ KODAK ME-4/VNF-1/RVNP FIRST DEVELOPER REPL

Hazards

Routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation: dust may cause upper
respiratory tract irritation. Skin: prolonged or repeated contact
may cause irritation & may result in an allergic skin reaction.

explanation of carcinogenicity: none
effects of overexposure: inhalation: dust may cause upper respiratory
tract irritation. Skin: prolonged or repeated contact may cause
irritation & may result in an allergic skin reaction
medical cond aggravated by exposure: skin allergic reaction

First Aid

First aid: inhalation: remove from exposure, treat symptomatically, and
get medical attention. Skin: flush with plenty of water. If skin
irritation or an allergic skin reaction develops, get medical
attention.

Chemical Properties

Vapor pres: negligible
spec gravity: >1.000
evaporation rate & reference: (n-bu ac = 1): negligible
appearance and odor: white solid; odorless
percent volatiles by volume: negl

Reactivity

Stability indicator/materials to avoid: yes
strong mineral acids
stability condition to avoid: away from acids
hazardous decomposition products: oxides of carbon & sulfur

Proper Disposal

Waste disposal methods: discharge, treatment, or disposal may be subject
to federal, state, or local laws.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium carbonate, monohydrate
cas: 5968-11-6
fraction by wt: 35-40%

ingred name: hydroquinone (sara iii)
cas: 123-31-9
rtecs #: mx3500000
fraction by wt: 5-10%
osha pel: 2 mg/m3
acgih tlv: 2 mg/m3; 9192
epa rpt qty: 1 lb
dot rpt qty: 1 lb

ingred name: sodium phosphate, tribasic (sara iii)
cas: 7601-54-9
rtecs #: tc9490000
fraction by wt: 1-5%
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs

MSDS BFZVW 149 3899,VNF-1/RVNP FIRST DEVPR/REPL, PT-A

Hazards

Routes of entry: inhalation: no skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhale: dust may cause upper
respiratory tract irritation; eyes: contact with the powder causes
eye irritation; skin: prolonged or repeated skin contact may cause
skin irritation. May cause an allergic s kin reaction;
ingest: expected to be a low ingestion hazard.

effects of overexposure: see "health hazards"
medical cond aggravated by exposure: none stated.

First Aid

First aid: inhale: remove from exposure,treat symptomatically, and get
medical attention; eye: flush eyes with plenty of water for at least
15 minutes and get medical attention; skin: flush skin with plenty
of wate r. Wash skin with soap and water. If skin irritation or an
allergic skin reaction develops, get medical attention;
ingest: drink 1-2 glasses of water. Seek medical advice.

Chemical Properties

Hcc: n1
vapor pres: negligible
spec gravity: >1
solubility in water: appreciable
appearance and odor: white granular powder - no odor.

Reactivity

Stability indicator/materials to avoid: yes
strong acids
stability condition to avoid: high temperatures
hazardous decomposition products: thermal decomposition may produce
oxides of sulfur.

Proper Disposal

Waste disposal methods: disposal should be made in accordance with all
applicable federal, state and local laws and regulations.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium sulfite
cas: 7757-83-7
rtecs #: we2150000
fraction by wt: 50-55%
other rec limits: none established

ingred name: sodium carbonate
cas: 5968-11-6
fraction by wt: 35-40%
other rec limits: none established

ingred name: hydroquinone (sara iii)
cas: 123-31-9
rtecs #: mx3500000
fraction by wt: 8%
osha pel: 2 mg/m3
acgih tlv: 2 mg/m3; 9192
epa rpt qty: 1 lb
dot rpt qty: 1 lb

ingred name: sodium phosphate, tribasic (sara iii)
cas: 7601-54-9
rtecs #: tc9490000
fraction by wt: 1-5%
other rec limits: none established
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs

MSDS BFZVX 149 3899,VNF-1/RVNP 1ST DEVEL REPLEN,PART B

Hazards

Routes of entry: inhalation: no skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eyes: no specific hazard known. May
cause transient irritation. Skin: low hazard for recommended
handling. Inhalation: low hazard for recommended handling.

ingestion: harmful if swallowed.

explanation of carcinogenicity: not applicable.

effects of overexposure: none noted by mfr. Low toxicity & low hazard to
health.

medical cond aggravated by exposure: none specified by manufacturer.

First Aid

First aid: eyes: immediately flush eyes with plenty of water for at
least 15 minutes and get medical attention. Skin: wash after each
contact. Get medical attention if symptoms occur. Inhalation: if
symptomatic, remove to fresh air. Get medical attention if
symptoms persist. Ingestion: if swallowed, induce vomiting
immediately as directed by medical personnel. Call a physician or
posion control center.

Chemical Properties

Hcc: n1
boiling pt: b.P. Text: >212f,>100c
vapor pres: 18
vapor density: 0.6
spec gravity: 1.22
ph: 6.0
solubility in water: complete
appearance and odor: clear,colorless solution, odorless
percent volatiles by volume: 65%

Reactivity

Stability indicator/materials to avoid: yes
strong acids
stability condition to avoid: excessive heat
hazardous decomposition products: thermal decomposition or contact with
strong acids may produce cyanide fumes and oxides of sulfur and
nitrogen.

Proper Disposal

Waste disposal methods: consult your local environmental officer.

discharge, treatment, or disposal may be subject to federal, state,
or local laws.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 65-70%
other rec limits: none specified

ingred name: sodium thiocyanate
cas: 540-72-7
rtecs #: xl2275000
fraction by wt: 25-30%
other rec limits: none specified

ingred name: sodium bromide
cas: 7647-15-6
rtecs #: vz3150000
fraction by wt: 1-5%
other rec limits: none specified

ingred name: sodium phosphate, tribasic (sara iii)
cas: 10124-56-8
rtecs #: oy3675000
fraction by wt: 1-5%
other rec limits: none specified
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs

ingred name: sodium bicarbonate
cas: 144-55-8
rtecs #: vz0950000
fraction by wt: 1-5%
other rec limits: none specified
osha pel: not known
acgih tlv: none

MSDS BKBLT 149 3899 VNF-1/RVNP FIRST DEVELOPER REPLENISHER,PART A

Hazards

Ld50 lc50 mixture: oral ld50 (rat) is unknown.

routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: eyes: airborne dust irritating.

repeated exposure to dust may cause injury. Skin: irritation,
allergic skin reaction. Inhalation: airborne dust may cause
irritation of mucous membranes and uppe r respiratory tract.

ingestion: harmfulif swallowed. May cause irritation of gi tract.

chronic: none specified.

explanation of carcinogenicity: none
effects of overexposure: eyes: irritation, injury. Skin: irritation,
allergic skin reaction. Inhalation: irritation of mucous membranes
and upper respiratory tract. Ingestion: harmful if swallowed.

irritation of gi tract.

medical cond aggravated by exposure: none specified by manufacturer.

First Aid

First aid: eyes: flush with large amounts of water. Get medical
attention. Skin: remove contaminated clothing. Wash skin area with
soap and water. If irritation or allergic reaction develops, get
medical attenti on. Inhalation: if symptomatic, move tofresh air.

treat symptomically. Get medical attention if symptoms persist.

ingestion: induce vomiting as directed by medical personnel. Get
medical attention.

Chemical Properties

Hcc: n1
boiling pt: b.P. Text: >212f,>100c
vapor pres: 18
vapor density: 0.6
spec gravity: 1.00
solubility in water: appreciable
appearance and odor: white color solid. Odorless.

percent volatiles by volume: neg.

Reactivity

Stability indicator/materials to avoid: yes
strong acids.

stability condition to avoid: avoid excessive temperatures, fire.

hazardous decomposition products: sulfur dioxide, carbon dioxide, carbon
monoxide.

conditions to avoid polymerization: will not occur.

Proper Disposal

Waste disposal methods: discharge, treatment, or disposal may be subject
to national, state, or local laws. Flush to sewer with large
amounts of water.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium sulfite
cas: 7757-83-7
rtecs #: we2150000
fraction by wt: 50-55%
other rec limits: none recommended

ingred name: sodium carbonate
cas: 497-19-8
rtecs #: vz4050000
fraction by wt: 35-40%
other rec limits: none recommended

ingred name: hydroquinone (sara iii)
cas: 123-31-9
rtecs #: mx3500000
fraction by wt: 8%
other rec limits: none recommended
osha pel: 2 mg/m3
acgih tlv: 2 mg/m3; 9394
epa rpt qty: 1 lb
dot rpt qty: 1 lb

ingred name: sodium hexametaphosphate (sara iii)
cas: 10124-56-8
rtecs #: oy3675000
fraction by wt: 1-5%
other rec limits: none recommended
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs

ingred name: sodium bicarbonate
cas: 144-55-8
rtecs #: vz0950000
fraction by wt: 1-5%
other rec limits: none recommended

MSDS BSYKM 149 3899 VNF-1/RVNP FIRST DEVELOPER REPLENISHER, PART B

Hazards

Ld50 lc50 mixture: none specified by manufacturer.

routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: overexpo to thiocyanates has been
shown to cause thyroid enlg,decr metabolic rate,sympt of
hypothyroidism in hum/anim.Inhal: expect to be low haz for
recommended hndlg.Hcn liberated may cause dizz,head ,rapid resp &
pulse,unconsc,convul,death.Eye: causes irrit.Skin: causes
irrit,harmful if absorb thru skin.Ingest: harmful.

explanation of carcinogenicity: per msds: carcinogenicity
classification: iarc/acgih/ntp/osha: none.

effects of overexposure: thyroid enlargement, decr in metabolic rate,
symptoms of hypothyroidism in humans/animals. Hydrogen cyanide gas
dizz,head,rapid respiration, rapid pulse,unconsc,convulsions,death.

eye/skin irrit, harm ful if absorbed thru skin/ingest.

medical cond aggravated by exposure: none specified by manufacturer.

First Aid

First aid: inhal: symptomatic move to fresh air.Treat symptoma.Sympt
persist get med attn.Eyes: immed flush w/lots of water@least
15mins.Get med attn.Skin: immed flush w/lots of water @least 15min
while removing co nta cloth/shoes.Get med attn.Ingest: induce vomit
as directed by med person.Never give anything by mouth if
unconsc.Call dr/pois cntrl cntr immed.Warning: contact w/strong
oxid/acid liberate hcn.(suppl)

Chemical Properties

Hcc: n1
boiling pt: b.P. Text: >212f,>100c
melt/freeze pt: m.P/f.P text: na
decomp temp: decomp text: np
vapor pres: 18
vapor density: 0.6
spec gravity: 1.22
ph: 6.0
viscosity: np
evaporation rate & reference: np
solubility in water: complete
appearance and odor: liquid, colorless, odorless
percent volatiles by volume: 65-70
corrosion rate: np

Reactivity

Stability indicator/materials to avoid: yes
strong oxidizing agents(sodium hypochlorite(bleach)),strong
acids(h2so4),contact w/both liberates pois gas & flamm matl.

stability condition to avoid: none specified by manufacturer.

hazardous decomposition products: cyanides, carbonyl sulfide.

Proper Disposal

Waste disposal methods: discharge/treatment/dispo may be subj to
nat/state/loc laws.Flush to sewer w/lg amts of water.Since emptied
cntnrs retain prod residue follow label warnings even aft
empty.Chem subj to reporting reqmt s sec 313 title iii
sara/40cfr372: none
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 65-70%
other rec limits: none recommended

ingred name: sodium thiocyanate
cas: 540-72-7
rtecs #: xl2275000
fraction by wt: 25-30%
other rec limits: none recommended

ingred name: potassium iodide
cas: 7681-11-0
rtecs #: tt2975000
fraction by wt:
other rec limits: none recommended

ingred name: sodium bromide
cas: 7647-15-6
rtecs #: vz3150000
fraction by wt: 1-5%
other rec limits: none recommended

MSDS BTWBT 149 3899 VNF-1/RVNP FIRST DEVELOPER REPLENISHER, WORK SOLN

Hazards

Ld50 lc50 mixture: none specified by manufacturer.

routes of entry: inhalation: no skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhal: expected to be low haz for
recommended hndlg.Eye: causes irrit.Skin: causes irrit.May cause
allergic skin reaction.Ingest: expected to be low ingestion hazard.

explanation of carcinogenicity: per msds: carcinogenicity
classification: iarc/acgih/ntp/osha: none.

effects of overexposure: eye irrit, skin irrit, allergic skin reaction.

medical cond aggravated by exposure: none specified by manufacturer.

First Aid

First aid: inhal: if symptomatic move to fresh air.Treat
symptomatically.Get med attn if symptons persist. Eyes: immed flush
w/plenty of wter for @least 15mins.Get med attn. Skin: immed remove
contam cloth/shoes.Wa sh w/soap/plenty of water.Irrit/allergic skin
rx devlps get med attn. Ingest: drink 1-2 glasses of water.Seek med
attn.Never give anything by mouth if unconsc.

Chemical Properties

Hcc: n1
boiling pt: b.P. Text: >212f,>100c
melt/freeze pt: m.P/f.P text: na
decomp temp: decomp text: np
vapor pres: 18
vapor density: 0.6
spec gravity: 1.07
ph: 9-10
viscosity: np
evaporation rate & reference: np
solubility in water: complete
appearance and odor: liquid, colorless, odorless
percent volatiles by volume: 90-95
corrosion rate: np

Reactivity

Stability indicator/materials to avoid: yes
none w/common materials & contaminants w/which material may reasonably
come into contact.

stability condition to avoid: none specified by manufacturer.

hazardous decomposition products: none

Proper Disposal

Waste disposal methods: discharge/treatment/dispo may be subj to
nat/state/loc laws.Flush to sewer w/lg amts of water.Since emptied
cntnrs retain prod residue follow label warnings even aft
empty.Chem subj to reporting reqmt s sec 313 title iii
sara/40cfr372: hydroquinone.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 90-95%
other rec limits: none recommended

ingred name: sodium sulfite
cas: 7757-83-7
rtecs #: we2150000
fraction by wt: 1-5%
other rec limits: none recommended

ingred name: sodium carbonate
cas: 497-19-8
rtecs #: vz4050000
fraction by wt: 1-5%
other rec limits: none recommended

ingred name: hydroquinone (sara 302/313) (cercla)
cas: 123-31-9
rtecs #: mx3500000
fraction by wt: 0.7%
other rec limits: none recommended
osha pel: 2 mg/m3
acgih tlv: 2 mg/m3; 9596
epa rpt qty: 1 lb
dot rpt qty: 1 lb

ingred name: 1-phenyl-3-pyrazolidone
cas: 92-43-3
rtecs #: uq8750000
fraction by wt:
other rec limits: none recommended

MSDS BXWCZ 149 3899 VNF-1/RVNP FIRST DEVELOPER REPLENISHER PART A

Hazards

Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute-airborne dust irritating. May
cause irritation of mucous membranes & upper respiratory tract.

contact with skin & eyes may be irrittaing. May cause allergic skin
reaction. Harmful if swallowed. may cause g/i tract irritation.

chronic-prolonged eye contact may cause eye injury.

explanation of carcinogenicity: in addition to the above, product is
negative w/regard to: acgih cancer, california cancer & reproductive
effects.

effects of overexposure: inhalation: upper respiratory tract irritation.

eyes: irritation. Skin: prolonged or rapeated contact; irritation,
allergic reaction. Ingestion: sulfite allergic reaction.

medical cond aggravated by exposure: mfr gave no information of msds.

First Aid

First aid: if any symptoms occur, get immediate medical attention.

inhalation: if symptomatic,move to fresh air. Eye: flush w/plenty of
water for 15 min. Skin: flush w/water 15 min. Remove contaminated
clothing & l aunder before reuse. Ingestion: induce vomiting as
directed by medical personnel. Nothing by mouth if unconscious.

call physician or poison control center immediately.

Chemical Properties

Hcc: n1
nrc/state lic num: none
vapor pres: negligible
spec gravity: 1.00
solubility in water: appreciable
appearance and odor: white solid; odorless
percent volatiles by volume: nil

Reactivity

Stability indicator/materials to avoid: yes
strong acids.

stability condition to avoid: mfr gave no information of msds.

hazardous decomposition products: carbon dioxide, carbon monoxide,
sulfur dioxide.

conditions to avoid polymerization: will not occur.

Proper Disposal

Waste disposal methods: discharge, treatment, or disposal may be subject
to local, state and federal regulations. Flush to sewer with large
amounts of water.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium sulfite
cas: 7757-83-7
rtecs #: we2150000
fraction by wt: 50-55%
other rec limits: none recommended

ingred name: sodium carbonate
cas: 497-19-8
rtecs #: vz4050000
fraction by wt: 35-40%
other rec limits: none recommended

ingred name: hydroquinone (sara 302/313) (cercla)
cas: 123-31-9
rtecs #: mx3500000
fraction by wt: 8%
other rec limits: none recommended
osha pel: 2 mg/m3
acgih tlv: 2 mg/m3; 9495
epa rpt qty: 1 lb
dot rpt qty: 1 lb

ingred name: sodium hexametaphophate (metaphosphoric acid, hexasodium
salt) (cercla)
cas: 10124-56-8
rtecs #: oy3675000
fraction by wt: 1-5%
other rec limits: none recommended
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs

ingred name: sodium bicarbonate
cas: 144-55-8
rtecs #: vz0950000
fraction by wt: 1-5%
other rec limits: none recommended

ingred name: 1-phenyl-3-pyrazolidone
cas: 92-43-3
rtecs #: uq8750000
fraction by wt:
other rec limits: none recommended

MSDS CLKJH 149 3899, PT A, KODAK VNF-1/RVNP FIRST DEVELOPER (SEE SUPPL)

Hazards

Ld50 lc50 mixture: not provided
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation: harmful if inhaled.

airborne dust irritating. May cause irritation to the mucous
membranes and upper respiratory tract. In contact with strong acids
or heated, sulfites may liberate sulfur dioxide gas. Sulfur
dioxide gas is irritating to respiratory tract. Asthmatics or
hypersensitive individuals may experience difficult breathing.

eyes: causes burns. Repeated exposure to dust may caus e eye
injury. Skin: causes irritation. May cause allergic skin reaction
based on human experience. May cause skin depigmentation.

ingestion: harmful if swallowed. May cause burns of
gastrointestinal t ract if swallowed.

explanation of carcinogenicity: carcinogenicity classification
(components present at 0.1% or more): - international agency for
research on cancer (iarc): none - american conference of
governmental industrial hygienists (acgih): hyd roquinone; a3,
animal carcinogen. - national toxicology program (ntp): none -
occupational safety and health administration (osha): none
effects of overexposure: inhalation: airborne dust irritating. May cause
irritation to the mucous membranes and upper respiratory tract. In
contact with strong acids or heated, sulfites may liberate sulfur
dioxide gas. Sulfur dioxide gas is irritating to respiratory
tract. Eyes: causes burns. Skin: causes irritation. May cause
allergic skin reaction based on human experience. May cause skin
depigmentation. Ingestion: may cause burns of gastrointestinal
tract if swallowed.

medical cond aggravated by exposure: some asthmatics, hypersensitive or
sulfite-sensitive individuals may experience difficult breathing,
wheezing, chest tightness, stomach upset, hives, faintness,
weakness and diarrhea.

First Aid

First aid: inhalation: if symptomatic, move to fresh air. Treat
symptomatically. Get medical attention if symptoms occur. Eyes:
immediately flush with water at least 15 mins. Get medical
attention immediately. S kin: immediately flush with water at least
15 mins while removing contaminated clothing and shoes. If skin
irritation or allergic skin reaction develops, get medical
attention. Wash contaminated clot hing before reuse. Destroy or
thoroughly clean contaminated shoes. Ingestion: do not induce
vomiting. Give victim a glass of water. Never give anything by
mouth to unconscious person. Call a physician or poison control
center immediately.

Chemical Properties

Hcc: n1
nrc/state lic num: not relevant
melt/freeze pt: m.P/f.P text: not available
decomp temp: decomp text: not provided
vapor pres: negligible
spec gravity: 1.00
solubility in water: appreciable
appearance and odor: white, odorless solid.

percent volatiles by volume: negligible
corrosion rate: not provided

Transportation

Transportation hazmat hot line: (716) 722-2400 between 8 a.M. And
5 p.M. (eastern standard time), monday through friday.

Reactivity

Stability indicator/materials to avoid: yes
strong acids
stability condition to avoid: not provided
hazardous decomposition products: sulfur dioxide, carbon dioxide, carbon
monoxide

Proper Disposal

Waste disposal methods: discharge, treatment, or disposal may be subject
to national, state, or local laws. Flush to sewer with large amount
of water. Since emptied containers retain product residue, follow
label warnings ev en after container is emptied

Ingredients List

Ingred name: sodium sulfite
cas: 7757-83-7
rtecs #: we2150000
minumum % wt: 50.

maxumum % wt: 55.

other rec limits: not provided
osha pel: not provided
acgih tlv: not provided

ingred name: sodium carbonate
cas: 497-19-8
rtecs #: vz4050000
minumum % wt: 35.

maxumum % wt: 40.

other rec limits: not provided
osha pel: not provided
acgih tlv: not provided

ingred name: hydroquinone
cas: 123-31-9
rtecs #: mx3500000
= wt: 8.

other rec limits: not provided
osha pel: 2 mg/m3
acgih tlv: 2 mg/m3
epa rpt qty: 1 lb
dot rpt qty: 1 lb

ingred name: sodium hexametaphosphate
cas: 10124-56-8
rtecs #: oy3675000
minumum % wt: 1.

maxumum % wt: 5.

other rec limits: not provided
osha pel: not provided
acgih tlv: not provided
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs

ingred name: sodium bicarbonate
cas: 144-55-8
rtecs #: vz0950000
minumum % wt: 1.

maxumum % wt: 5.

other rec limits: not provided
osha pel: not provided
acgih tlv: not provided

ingred name: 1-phenyl-3-pyrazolidinone
cas: 92-43-3
rtecs #: uq8750000
< wt: 1.

other rec limits: not provided
osha pel: not provided
acgih tlv: not provided

MSDS CLKKH 149 3899, PT B, KODAK VNF-1/RVNP FIRST DEVELOPER (SEE SUPPL)

Hazards

Ld50 lc50 mixture: not provided
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation: expected to be a low
hazard for recommended handling. If hydrogen cyanide gas is
liberated due to contact with a strong oxidizer or acid, it may
cause dizziness, headache, rapid respiratio n, rapid pulse,
unconsciousness, convulsions and death. Eyes: causes burns. Skin:
causes burns. Harmful if absorbed through skin. Ingestion: harmful
if swallowed. may cause burns of the gastrointest inal tract if
swallowed.

explanation of carcinogenicity: carcinogenicity classification
(components present at 0.1% or more): - international agency for
research on cancer (iarc): none - american conference of
governmental industrial hygienists (acgih): hyd roquinone; a3,
animal carcinogen. - national toxicology program (ntp): none -
occupational safety and health administration (osha): none
effects of overexposure: inhalation: if hydrogen cyanide gas is liberated
due to contact with a strong oxidizer or acid, it may cause
dizziness, headache, rapid respiration, rapid pulse,
unconsciousness, convulsions and death. eyes: causes burns. Skin:
causes burns. Ingestion: may cause burns of the gastrointestinal
tract if swallowed.

medical cond aggravated by exposure: not provided

First Aid

First aid: inhalation: move to fresh air. Treat symptomatically. Get
medical attention if symptoms occur. Eyes: immediately flush with
plenty of water for at least 15 minutes. Get medical attention.

skin: imme diately flush with plenty of water at least 15 minutes
while removing contaminated clothing and shoes. Get medical
attention. Wash contaminated clothing before reuse. Destroy or
thoroughly clean conta minated shoes. Ingestion: induce vomiting
as directed by medical personnel. Never give anything by mouth to
an unconscious person. Call a physician or poison control center
immediately.

Chemical Properties

Hcc: n1
nrc/state lic num: not relevant
boiling pt: >100.C, 212.F
decomp temp: decomp text: not provided
vapor pres: 68f: 24 mbar (18 mm hg)
vapor density: 0.6
spec gravity: 1.22
ph: 6.0
viscosity: not provided
evaporation rate & reference: not provided
solubility in water: complete
appearance and odor: colorless, odorless, liquid.

percent volatiles by volume: 65-70 wt
corrosion rate: not provided

Transportation

Transportation hazmat hot line: (716) 722-2400 between 8 a.M. And
5 p.M. (eastern standard time), monday through friday.

Reactivity

Stability indicator/materials to avoid: yes
strong oxidizing agents (e.G. sodium hypochlorite (bleach)), strong
acids (e.G. sulfuric acid). Contact with strong oxidizing agents
or acids liberates poisonous gas. Contact with strong oxidizing
agents or acids liberate
stability condition to avoid: not provided
hazardous decomposition products: cyanides, carbonyl sulfide. Carbon
dioxide, carbon monoxide, oxides of nitrogen, oxides of

Proper Disposal

Waste disposal methods: discharge, treatment, or disposal may be subject
to national, state, or local laws. Flush to sewer with large amount
of water. Since emptied containers retain product residue, follow
label warnings ev en after container is emptied

Ingredients List

Ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
minumum % wt: 65.

maxumum % wt: 70.

other rec limits: not provided
code: f
code: f

ingred name: sodium thiocyanate
cas: 540-72-7
rtecs #: xl2275000
minumum % wt: 25.

maxumum % wt: 30.

other rec limits: not provided
osha pel: not provided
acgih tlv: not provided

ingred name: sodium bromide
cas: 7647-15-6
rtecs #: vz3150000
minumum % wt: 1.

maxumum % wt: 5.

other rec limits: not provided
osha pel: not provided
acgih tlv: not provided

ingred name: potassium iodide
cas: 7681-11-0
rtecs #: tt2975000
< wt: 1.

other rec limits: not provided
osha pel: not provided
acgih tlv: not provided

MSDS CLLDD 149 3899,WKGSOL,KODAK VNF-1/RVNP FIRST DEVELOPER REPLENISHER

Hazards

Ld50 lc50 mixture: not provided
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation: expected to be a low
hazard for usual industrial or commercial handling by trained
personnel. In contact with strong acids or if heated, sulfites may
liberate sulfur dioxide gas. sulfur d ioxide gas is irritating to
respiratory tract. Some asthmatics or hypersensitive individuals
may experience difficult breathing. Eyes: expected to be low hazard
for recommended handling. Skin: may cause allergic skin reaction
based on human experience. Ingestion: may be harmful if swallowed.

some asthmatics or sulfite-sensitive individuals may experience
wheezing, chest tightness, stomach upse t, hives, faintness,
weakness, diarrhea.

explanation of carcinogenicity: carcinogenicity classification
(components present at 0.1% or more): - international agency for
research on cancer (iarc): none - american conference of
governmental industrial hygienists (acgih): hyd roquinone; a3,
animal carcinogen. - national toxicology program (ntp): none -
occupational safety and health administration (osha): none
effects of overexposure: inhalation: in contact with strong acids or if
heated, sulfites may liberate sulfur dioxide gas. sulfur dioxide
gas is irritating to respiratory tract. Skin: may cause allergic
skin reaction.

medical cond aggravated by exposure: some asthmatics, hypersensitive or
sulfite-sensitive individuals may experience difficult breathing,
wheezing, chest tightness, stomach upset, hives, faintness,
weakness and diarrhea.

First Aid

First aid: inhalation: if symptomatic, move to fresh air. Treat
symptomatically. Get medical attention if symptoms persist. Eyes:
any material that contacts the eye should be washed out immediately
with water. G et medical attention if symptoms occur. Skin: wash
with soap and water. If skin irritation or an allergic skin
reaction develops, get medical attention. Remove contaminated
clothing and shoes. Wash co ntaminated clothing before reuse.

destroy or thoroughly clean contaminated shoes. Ingestion: drink
1-2 glasses of water. seek medical attention. Never give anything
by mouth to an unconscious person.

Chemical Properties

Hcc: b3
nrc/state lic num: not relevant
boiling pt: >100.C, 212.F
melt/freeze pt: m.P/f.P text: not provided
decomp temp: decomp text: not provided
vapor pres: (18 mm hg) 68f
vapor density: 0.6
spec gravity: 1.07
ph: 9-10
viscosity: not provided
evaporation rate & reference: not provided
solubility in water: complete
appearance and odor: colorless, odorless liquid.

percent volatiles by volume: 90-95 wt
corrosion rate: not provided

Transportation

Product call the kodak worldwide transportation hazmat hot line:
(716) 722-2400 between 8 a.M. And 5 p.M. (eastern standard
time), monday through fr iday.

Reactivity

Stability indicator/materials to avoid: yes
none with common materials and contaminants with which the material may
reasonably come into contact.

stability condition to avoid: not provided
hazardous decomposition products: none

Proper Disposal

Waste disposal methods: discharge, treatment, or disposal may be subject
to national, state, or local laws. Flush to sewer with large amount
of water. Since emptied containers retain product residue, follow
label warnings ev en after container is emptied.

Ingredients List

Ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
minumum % wt: 90.

maxumum % wt: 95.

other rec limits: not provided
code: f
code: f

ingred name: sodium sulfite
cas: 7757-83-7
rtecs #: we2150000
minumum % wt: 1.

maxumum % wt: 5.

other rec limits: not provided
osha pel: not provided
acgih tlv: not provided

ingred name: sodium carbonate
cas: 497-19-8
rtecs #: vz4050000
minumum % wt: 1.

maxumum % wt: 5.

other rec limits: not provided
osha pel: not provided
acgih tlv: not provided

ingred name: hydroquinone
cas: 123-31-9
rtecs #: mx3500000
= wt: .7
other rec limits: not provided
osha pel: 2 mg/m3
acgih tlv: 2 mg/m3
epa rpt qty: 1 lb
dot rpt qty: 1 lb

ingred name: 1-phenyl-3-pyrazolidinone
cas: 92-43-3
rtecs #: uq8750000
< wt: 1.

other rec limits: not provided
osha pel: not provided
acgih tlv: not provided