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Photographic Developer Replenisher

NSN: 6750-00-965-4951 | Model: 188 8825

A chemical used to reactivate a processing solution to its original working strength and volume. It does not include replenisher, x-ray film processing.

NSN Properties and Flags
NATO Stock Number
6750-00-965-4951
DEMIL
NO
Physical Form
Liquid and powder
Reproduction Type
Color
Unit Package Yield
100.000 liters
Sequential Usage
Second stage
Material Processing Method
Automatic
Grain Control
Not rated
Image Contrast
Not rated
Unit Package Content Form
Separate units for mixing
Material Type For Which Designed
Film
Special Features
This item is made up of two seperate part numbers, purchased as a kit; p/n 869 2428 (c/o parts a and a1) and p/n 878 4464 (c/o parts b, c, d)

Pricing and Availability

Send us a request for quote using the form below. Our team will contact you with an up to date pricing and availability quote ASAP.

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NSN 6750-00-965-4951 Datasheet

Supply Class (FSC):
Photographic Supplies
Cross Reference:
  • 188 8825
  • VNF-1/RVNP COLOR DEV REPL
Cage Codes:
  • Eastman Kodak Company (CAGE 19139)
Schedule B & Trade:
  • Schedule B: 9010506000 (NAICS 333316)

    Apparatus and equipment for photographic labs nesoi

  • SITC: 88135

    Apparatus and equipment for photographic (including cinematographic) laboratories, n.E.S.; negatoscopes; projection screens

  • End Use: 21190

    Photo, service industry machinery

Identification:
HMIC

Y - Indicates information is in the hazardous materials information resource system (hmirs).

PMIC

U - Precious metal content is unknown

CRITL

- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.

Freight Information:
  • NMFC:

    043940 - Chemicals noi

  • WCC:

    756 - Photo equipment and supplies, other than film or paper (see 759)

  • SHC:

    9 - Other or no special handling required (sh)

  • ADC:

    A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.

  • ACC:

    P - Photographic supplies and equipment, including training films.

  • LTL:

    W - Rating variable

  • TCC:

    W - Corrosive materials, un class 8 (corrosive label)

NSN Management Codes:
  • SOS
    Sms
  • AAC
    V
  • Quantity per pack
    1
  • Unit of Measure
    Pg
  • Shelf Life
    24 mo.
  • Classification Control
    X
  • MGMT_CTL
    J2200x-
  • Repariability
    This is a nonreparable item. if condemned or economically unserviceable, then dispose at the level authorized replace the item.

Questions & Answers:

What are the historical prices recorded for this stock number?
Historical data shows pricing from $480.53 to $800.89..
Does NSN 6750-00-965-4951 have a shelf life?
No. There is no shelf life applicable for this NSN.
What NATO entities are users of this NSN?
Republic Of Korea
What is the NIIN of NSN 6750-00-965-4951?
009654951 or 00-965-4951
Does NSN 6750-00-965-4951 require demilitarization?
Yes - ITAR Controlled
What is the most recent solicitation for NSN 6750-00-965-4951?
No solicitations for this NSN.
When was this national stock number assigned to the federal catalog?
Jan 01, 1960
MSDS

Material Safety

MSDS BFZVY 188 8825, VNF-1/RVNP COLOR DEVELOPER REPLENISHER, PART A

Hazards

Ld50 lc50 mixture: ld50 (oral rat) is 246(f)-400(m) mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhaled: vapor irritating. May cause
allergic skin reaction. Some asthmatics or hyper sensitive
individuals may experience difficult breathing. Eye: causes severe
burns. Vapor irritating. Skin: causes se vere burns. May cause
allergic skin reaction. Ingested: may be fatal if swallowed. May
cause allergic skin reaction.

explanation of carcinogenicity: manufacturer gave no comments other than
the above references to the three listings.

effects of overexposure: inhalation: vapor may be irritating. Eyes:
liquid causes severe burns. Skin: prolonged skin contact causes
burns. Repeated skin contact may cause an allergic skin reaction.

ingestion: harmful if swall owed. Causes mouth and esophageal
burns.

medical cond aggravated by exposure: some asthmatics or hyper sensitive
individuals may experience difficult breathing.

First Aid

First aid: inhaled: if synptoms occur, move to fresh air & get immed.

medical attn. Eye: immed. Flush w/water 15 min. Get immed. Medical
attn. Skin: immed. Flush with water 15 min. While removing
contaminated cloth ing. Launder before reuse. Get medical attn.

ingested: do not induce vomiting. Give victim a glass of water.

nothing by mouth if unconscious. Call physician or poison control
center immediately!

Chemical Properties

Hcc: b1
nrc/state lic num: none
boiling pt: b.P. Text: >212f,>100c
vapor pres: 18 mm
vapor density: 0.6
spec gravity: 1.21
ph: 14
solubility in water: complete
appearance and odor: slight yellow liquid,slight odor
percent volatiles by volume: 90

Reactivity

Stability indicator/materials to avoid: yes
strong oxidizing agents, acids
stability condition to avoid: no information given by mfr on msds.

hazardous decomposition products: carbon dioxide, carbon monoxide,
oxides of nitrogen
conditions to avoid polymerization: will not occur.

Proper Disposal

Waste disposal methods: discharge, treatment or disposal may be subject
to federal, state or local laws. Contract with a licensed chemical
disposal agency.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 25-30%
other rec limits: none established

ingred name: benzyl alcohol
cas: 100-51-6
rtecs #: dn3150000
fraction by wt: 20-25%
other rec limits: none established

ingred name: ethylene glycol (sara iii)
cas: 107-21-1
rtecs #: kw2975000
fraction by wt: 16%
osha pel: c 50 ppm
acgih tlv: c 50 ppm,vapor; 9192
epa rpt qty: 1 lb
dot rpt qty: 1 lb

ingred name: sodium hydroxide (sara iii)
cas: 1310-73-2
rtecs #: wb4900000
fraction by wt: 15-20%
osha pel: 2 mg/m3
acgih tlv: c 2 mg/m3; 9293
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs

ingred name: ethylenediamine (sara iii)
cas: 107-15-3
rtecs #: kh8575000
fraction by wt: 10-15%
osha pel: 10 ppm
acgih tlv: s, 10 ppm; 9192
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs

MSDS BFZVZ 188 8825 VNF-1/RVNP COLOR DEVELOPER REPLENISHER, PART A-1

Hazards

Routes of entry: inhalation: no skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: expected to be a low hazard for
recommended handling. May cause transient irritation to eyes.

explanation of carcinogenicity: manufacturer gave no comments other than
the above references to the three listings.

effects of overexposure: eye: irritation. No other symptoms given on
msds.

medical cond aggravated by exposure: no information given by mfr on
msds.

First Aid

First aid: get medical attention if any symptoms persist. Inhaled: if
synptoms occur, move to fresh air. Eye: immed. Flush w/ water 15
min. Skin: wash with soap & water. Ingested: drink 1-2 glasses of
water. Get imm ediate medical attention.

Chemical Properties

Hcc: f8
nrc/state lic num: none
boiling pt: b.P. Text: >212f
vapor pres: 18 mm
vapor density: 0.6
spec gravity: 1.40
ph: 10.2
solubility in water: complete
appearance and odor: light yellow liquid, ammonia odor
percent volatiles by volume: 60

Reactivity

Stability indicator/materials to avoid: yes
strong oxidizing agents
stability condition to avoid: no information given by mfr on msds.

hazardous decomposition products: carbon dioxide and carbon monoxide,
oxides of phosphorus
conditions to avoid polymerization: will not occur.

Proper Disposal

Waste disposal methods: discharge, treatment or disposal may be subject
to federal, state or local laws. Flush to sewer with large amounts
of water.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: phosphonic acid,(1-hydroxyethylidene)di-
cas: 2809-21-4
rtecs #: sz8562100
fraction by wt: 35-40%

ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 60-65%

MSDS BFZWB 188 8825 VNF-1/RVNP COLOR DEVLPR REPLNSHER,PART C

Hazards

Ld50 lc50 mixture: none specified by manufacturer.

routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhal: airborne dust irrit.In contact
w/strong acids/heated sulfites may liberate sulfur dioxide
gas.Sulfur dioxide gas irrit to resp tract.Some asthmatics or
sulfite-sensitive individuals may experien ce wheezing or chest
tightness.Eye/skin: causes irrit.Ingest: harmful.Cause burns of gi
tract.Some asthmatics or (supplem)
explanation of carcinogenicity: per msds: carcinogenicity
classification: iarc/acgih/ntp/osha: none.

effects of overexposure: inhal irrit. Irrit resp tract due to sufur
dioxide. Wheezing or chest tightness, stomach upset, hives,
faintness, weakness, diarrhea. Eye/skin irrit. Harmful if ingest.

burns gi tract.

medical cond aggravated by exposure: none specified by manufacturer.

First Aid

First aid: inhal: if symptomatic move to fresh air. Get med attn if
symptons persist. Eyes: immed flush w/plenty of water for @least
15mins.Get med attn. Skin: immed flush w/plenty of water for @least
15mins while removing contamin cloth/shoes.Get med attn. Ingest: do
not induce vomit.Give victim a glass of water.Never give anything
by mouth if unconsc.Call physician/poison control center immed.

Chemical Properties

Hcc: n1
boiling pt: b.P. Text: np
melt/freeze pt: m.P/f.P text: n/avai
decomp temp: decomp text: np
vapor pres: negligible
vapor density: na
spec gravity: >1.0
ph: na
viscosity: np
evaporation rate & reference: np
solubility in water: appreciable.

appearance and odor: solid, white color, odorless.

percent volatiles by volume: na
corrosion rate: np

Reactivity

Stability indicator/materials to avoid: yes
strong acids.

stability condition to avoid: none specified by manufacturer.

hazardous decomposition products: sulfur dioxide, oxides of phosphorus.

haz combust prod: none (non-combustible).

Proper Disposal

Waste disposal methods: discharge/treatment/disposal may be subject to
national/state/local laws. Flush to sewer w/lg amts of water. Chem
subj to reporting reqmts of sara 313 title iii/40cfr372: none.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium phosphate, tribasic (cercla)
cas: 7601-54-9
rtecs #: tc9490000
fraction by wt: 80-85%
other rec limits: none recommended
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs

ingred name: sodium sulfite
cas: 7757-83-7
rtecs #: we2150000
fraction by wt: 15-20%
other rec limits: none recommended

MSDS BFZWC 188 8825, VNF1/RVNP COLOR DEVELOPER REPLENISHER, PART C

Hazards

Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eye: causes irritation. Skin: causes
irritation. Inhalated: airborne dust is irritating. Ingested: harmful
if swallowed. May cause burns to gastrointestinal tract if
swallowed.

explanation of carcinogenicity: this compound contains no ingredients at
concentrations of 0.1% or greater that are carcinogens or suspect
carcinogens.

effects of overexposure: eye: irritation. Skin: irritation. Inhalated:
airborne dust is irritating. Ingested: harmful if swallowed. May
cause burns to gastrointestinal tract if swallowed.

medical cond aggravated by exposure: no information given by mfr on
msds.

First Aid

First aid: inhaled: if symptomatic, move to fresh air & get medical
attn.If symptoms persist eye: immed. Flush w/water 15 min. Get
medical attn. Skin: immed. Flush with water 15 min. While removing
contaminated clo thing. Launder before reuse. Get medical attn.

ingested: do not induce vomiting. Give victim a glass of water.

nothing by mouth if unconscious. Call physician or poison control
center immediately!

Chemical Properties

Hcc: f8
nrc/state lic num: none
boiling pt: b.P. Text: not given
melt/freeze pt: m.P/f.P text: not given
vapor pres: negligible
vapor density: not given
spec gravity: >1.0
evaporation rate & reference: not given
solubility in water: appreciable
appearance and odor: white solid,odorless

Reactivity

Stability indicator/materials to avoid: yes
strong acids
stability condition to avoid: no information given by mfr on msds.

hazardous decomposition products: none specified by manufacturer.

conditions to avoid polymerization: will not occur.

Proper Disposal

Waste disposal methods: discharge, treatment or disposal may be subject
to federal, state or local laws. Flush to sewer with large amounts
of water.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: phosphoric acid, trisodium salt, decahydrate
cas: 7601-54-9
rtecs #: tc9490000
fraction by wt: 80-85%
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs

ingred name: sodium sulfite
cas: 7757-83-7
rtecs #: we2150000
fraction by wt: 15-20%

MSDS BFZWD 188 8825, VNF1/RVNP COLOR DEVELOPER REPLENISHER, PART D

Hazards

Ld50 lc50 mixture: ld50 (oral rat) is 400(m),246(f) mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhaled: harmful if inhaled. Airborne
dust irritating. Eyes: causes irritation. Airborne dust irritating.

however, immediate flushing of eyes w/water will minimize any
irritative effect. Skin: causes irr itation. May produce an allergic
skin reaction. Ingested: harmful if swallowed.

explanation of carcinogenicity: tests have produced "no observed effect"
as reported by mfr.

effects of overexposure: inhaled: harmful if inhaled. Irritation.

eyes: causes irritation. Airborne dust irritating. Skin: causes
irritation. May produce an allergic skin reaction. Ingested: harmful
if swallowed.

medical cond aggravated by exposure: no information given by mfr on
msds.

First Aid

First aid: inhaled: move to fresh air.Treat symptomatically. Get medical
attn.If symptoms persist. Eye: immed. Flush w/ water 15 min. Get
medical attn. Skin: immed.Flush w/water 15 min. While removing
contaminated clothing. Launder before reuse. Get medical attn.

ingested: call physician or poison control center immediately.

induce vomiting as directed by medical personnel. Nothing by mouth
if unconscious.

Chemical Properties

Hcc: b3
nrc/state lic num: none
melt/freeze pt: =210.C, 410.F
decomp temp: =210.C, 410.F
vapor pres: negligible
evaporation rate & reference: negligible
solubility in water: appreciable
appearance and odor: tan colored powder; odorless
percent volatiles by volume: n/k.

Reactivity

Stability indicator/materials to avoid: yes
material can react with strong oxidizing agents.

stability condition to avoid: this material can decompose above 210c
(410f). Avoid temperatures above 110c (230f).

hazardous decomposition products: carbon dioxide, carbon monoxide,
oxides of nitrogen, oxides of sulfur.

conditions to avoid polymerization: will not occur.

Proper Disposal

Waste disposal methods: discharge, treatment or disposal may be subject
to federal, state or local laws. Incinerate. Since emptied
containers retain product residue, follow label warnings even after
container is emptied.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: 4-(n-ethyl-n-2-methanesulfonylaminoethyl)-2-
methylphenylenediamine
cas: 25646-71-3
rtecs #: pb0431000
fraction by wt: 85-90%
other rec limits: kodak 1.0 mg/m3 twa

ingred name: citrazinic acid
cas: 99-11-6
rtecs #: ns1400000
fraction by wt: 10-15%
other rec limits: none specified

MSDS BVGMW 188 8825 VNF-1/RVNP COLOR DEVELOPER REPLENISHER,WORKING SOLN

Hazards

Routes of entry: inhalation: no skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhal: expected to be a low hazard for
recommended hanlding. Eyes: causes irritation. Skin: causes
irritation. May cause allergic skin reaction. Ingest: expected to be
a low ingest haz. May cause inrritat ion of the gastrointestinal
tract.

explanation of carcinogenicity: per msds: none.

effects of overexposure: eye & skin irritation. Gastrointestinal tract
irritation.

medical cond aggravated by exposure: none specified by manufacturer.

First Aid

First aid: inhal: move to fresh air. Treat symptomatically. Get med attn
if symptoms persist. Eyes: immed flush w/ plenty of water for @least
15mins. Get med attn. Skin: immed flush w/plenty of water. Wash
w/non-al kaline (aicd) typ skin cleaner. Skin irrit/allergic skin
rx develops get med attn. Remove comtamin clothing/shoes.

ingest: drink 1-2 glasses of water. Seek med attn.

Chemical Properties

Hcc: b3
boiling pt: >100.C, 212.F
vapor pres: 18mm @20c
vapor density: 0.6
spec gravity: 1.04
ph: 11.9
evaporation rate & reference: none specified by manufa.

solubility in water: complete
appearance and odor: liquid, colorless, odorless.

percent volatiles by volume: 95

Reactivity

Stability indicator/materials to avoid: yes
none w/common matls & contmainants w/which the matl may reasonably come
into contact.

stability condition to avoid: none specified by manufacturer.

hazardous decomposition products: haz combust prod: none(non
combustible).

Proper Disposal

Waste disposal methods: discharge, treatment, lor disposal may be
subject to national, state, or local laws. Flush to sewer w/lg amts
of water. Contains a chemical subject to reporting reqmts of sec
313 or tit iii of sara & 40 cfr part 372 (ethylene glycol).

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 90-95%
other rec limits: none recommended

ingred name: 4-(n-ethyl-n-2-methanesulfonylaminoethyl)-2-
methylphenylenediamine
cas: 25646-71-3
rtecs #: pb0431000
fraction by wt:
other rec limits: none recommended

ingred name: sodium phosphate, tribasic (sara iii)
cas: 7601-54-9
rtecs #: tc9490000
fraction by wt: 1-5%
other rec limits: none recommended
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs

ingred name: sodium sulfite
cas: 7757-83-7
rtecs #: we2150000
fraction by wt:
other rec limits: none recommended

ingred name: sodium sulfate
cas: 7757-82-6
rtecs #: we1650000
fraction by wt:
other rec limits: none recommended

MSDS BZPJF 878 4464 VNF-1/RVNP COLOR DEVLPR REPLNISHER,PART A, (CONC)

Hazards

Ld50 lc50 mixture: none specified by manufacturer.

routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhal: vap irrit.May cause allergic
skin reaction.Some asthmatics or hypersensitive individuals may
experience difficult breathing. Eye: causes severe burns.Vap
irrit.Skin: causes severe burns.May cause allergic skin
rx.Ingest: may be fatal ifswallowed.May cause burns of
gastrointestinal tract.May cause kidney dmg.

explanation of carcinogenicity: per msds: carcinogenicity
classification: acgih/ntp/osha: none.Airc: ethylene glycol not classif
as human carc(a4).

effects of overexposure: inhal irrit. Allergic skin reaction., difficult
breathing, severe eye burns, eye irrit. Severe skin burns, fatal if
swallowed. Burns gastrintestinal tract. Kidney damage.

medical cond aggravated by exposure: some asthmatics or hypersensitive
individuals may experience difficult breathing.

First Aid

First aid: inhal: if symptomatic move to fresh air. Get med attn if
symptons persist. Eyes: immed flush w/plenty of water for @least
15mins.Get med attn immed. Skin: immed flush w/plenty of water for
@least 15mins while removing contamin cloth/shoes.Getmed attn.

ingest: do not induce vomit. Give a glass of water. Never give
anything by mouth if unconsc. Call physician or poison control
center immed.

Chemical Properties

Hcc: b1
boiling pt: >100.C, 212.F
melt/freeze pt: m.P/f.P text: np
decomp temp: decomp text: np
vapor pres: 18mm @20c
vapor density: 0.6
spec gravity: 1.21
ph: 14
viscosity: np
evaporation rate & reference: np
solubility in water: complete.

appearance and odor: liquid, slight yellow slight odor.

percent volatiles by volume: 85-90
corrosion rate: np

Reactivity

Stability indicator/materials to avoid: yes
strong oxidizing agents, acids.

stability condition to avoid: none specified by manufacturer.

hazardous decomposition products: haz combust prod: carbon dioxide,
carbon monoxide, oxides of nitrogen.

Proper Disposal

Waste disposal methods: discharge/treatment/disposal may be subject to
national/state/local laws. Flush to sewer w/lg amts of water. Chem
subj to reporting reqmts of sec 313 title iii
sara/40cfr372: ethylene glycol.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
minumum % wt: 25.

maxumum % wt: 30.

other rec limits: none recommended

ingred name: benzyl alcohol
cas: 100-51-6
rtecs #: dn3150000
minumum % wt: 20.

maxumum % wt: 25.

other rec limits: none recommended

ingred name: sodium hydroxide (cercla)
cas: 1310-73-2
rtecs #: wb4900000
minumum % wt: 15.

maxumum % wt: 20.

other rec limits: none recommended
osha pel: 2 mg/m3
acgih tlv: c 2 mg/m3; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs

ingred name: ethylene glycol (sara 313) (cercla)
cas: 107-21-1
rtecs #: kw2975000
= wt: 16.

other rec limits: none recommended
acgih tlv: c stel39ppm,a4,vap96
epa rpt qty: 1 lb
dot rpt qty: 1 lb

ingred name: ethylenediamine (sara 302) (cercla)
cas: 107-15-3
rtecs #: kh8575000
minumum % wt: 10.

maxumum % wt: 15.

other rec limits: none recommended
osha pel: 10 ppm
acgih tlv: s, 10 ppm; 9596
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs

MSDS BZPJG 878 4464,VNF-1/RVNP COLR DEVELR REPLR,PART A1

Hazards

Routes of entry: inhalation: no skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: expected to be a low hazard for
recommended handling. May cause transient irritation to eyes.

explanation of carcinogenicity: manufacturer gave no comments other than
the above references to the three listings.

effects of overexposure: eye: irritation. No other symptoms given on
msds.

medical cond aggravated by exposure: no information given by mfr on
msds.

First Aid

First aid: get medical attention if any symptoms persist. Inhaled: if
synptoms occur, move to fresh air. Eye: immed. Flush w/ water 15
min. Skin: wash with soap & water. Ingested: drink 1-2 glasses of
water. Get imm ediate medical attention.

Chemical Properties

Hcc: c2
nrc/state lic num: none
boiling pt: b.P. Text: >212f
vapor pres: 18 mm
vapor density: 0.6
spec gravity: 1.40
ph: 10.2
solubility in water: complete
appearance and odor: light yellow liquid, ammonia odor
percent volatiles by volume: 60

Reactivity

Stability indicator/materials to avoid: yes
strong oxidizing agents
stability condition to avoid: no information given by mfr on msds.

hazardous decomposition products: carbon dioxide and carbon monoxide,
oxides of phosphorus
conditions to avoid polymerization: will not occur.

Proper Disposal

Waste disposal methods: discharge, treatment or disposal may be subject
to federal, state or local laws. Flush to sewer with large amounts
of water.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: phosphonic acid,(1-hydroxyethylidene)di-
cas: 2809-21-4
rtecs #: sz8562100
fraction by wt: 35-40%

ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 60-65%

MSDS BZPJH 869 2428,VNF-1/RVNP COLR DEVELR REPLR,PART B

Hazards

Ld50 lc50 mixture: oral ld50 (rat): 25mg/kg.

routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhal: harmful if inhaled. Eyes: causes
irrit. Skin: causes irrit. Ingest: may be fatal if swallowed. May
cause convulsions.

explanation of carcinogenicity: per msds: none.

effects of overexposure: eye/skin irritaion. Harmful if inhaled &
ingested.

medical cond aggravated by exposure: none specified by manufacturer.

First Aid

First aid: inhal: move to fresh air. Treat symptomatically. Get med attn.

eyes: immed flush w/plenty of wter for @least 15mins. Get med attn.

skin: immed flush w/plenty of water for @least 15mins while removing
con tamin cloth/shoes. Get med attn. Ingest: induce vomit as
directed by med personnel. Never give anything by mouth if unconsc.

call physician or poison control center immed.

Chemical Properties

Hcc: f8
melt/freeze pt: m.P/f.P text: decomp 100c
decomp temp: decomp text: melts 100c
vapor pres: n/availabl
vapor density: n/availabl
spec gravity: 0.87
ph: n/avai
solubility in water: decomposes
appearance and odor: solid (crystals), white color, amine odor.

percent volatiles by volume: n/avai

Reactivity

Stability indicator/materials to avoid: yes
rxs w/water.Contact w/water/acid liberates toxic highly flamm gas.Expo
to water pressure in cntnr may develop.Str oxidiz
stability condition to avoid: however matl can decompose above 100c
(212f) . Avoid temps above 50c (122f).

hazardous decomposition products: diborane gas, hydrogen.

Proper Disposal

Waste disposal methods: discharge/treatment/disposal may be subject to
national/state/loc laws.Flush to sewer w/lg amts of water.Since
emptied cntnrs retain product residue follow label warnings even
aft cntnr is emptied.No chem subject to sec 313 titiii sara
&40cfr372.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: tertiary butylamine borane
cas: 7337-45-3
rtecs #: eo3900000
fraction by wt: 100%
other rec limits: none recommended

MSDS BZPJJ 869-2428 VNF-1/RVNP DEVLPR REPLNR, PART C

Hazards

Ld50 lc50 mixture: none specified by manufacturer.

routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhal: airborne dust irrit.In contact
w/strong acids/heated sulfites may liberate sulfur dioxide
gas.Sulfur dioxide gas irrit to resp tract.Some asthmatics or
sulfite-sensitive individuals may experien ce wheezing or chest
tightness.Eye/skin: causes irrit.Ingest: harmful.Cause burns of gi
tract.Some asthmatics or (supplem)
explanation of carcinogenicity: per msds: carcinogenicity
classification: iarc/acgih/ntp/osha: none.

effects of overexposure: inhal irrit. Irrit resp tract due to sufur
dioxide. Wheezing or chest tightness, stomach upset, hives,
faintness, weakness, diarrhea. Eye/skin irrit. Harmful if ingest.

burns gi tract.

medical cond aggravated by exposure: none specified by manufacturer.

First Aid

First aid: inhal: if symptomatic move to fresh air. Get med attn if
symptons persist. Eyes: immed flush w/plenty of water for @least
15mins.Get med attn. Skin: immed flush w/plenty of water for @least
15mins while removing contamin cloth/shoes.Get med attn. Ingest: do
not induce vomit.Give victim a glass of water.Never give anything
by mouth if unconsc.Call physician/poison control center immed.

Chemical Properties

Hcc: n1
boiling pt: b.P. Text: np
melt/freeze pt: m.P/f.P text: n/avai
decomp temp: decomp text: np
vapor pres: negligible
vapor density: na
spec gravity: >1.0
ph: na
viscosity: np
evaporation rate & reference: np
solubility in water: appreciable.

appearance and odor: solid, white color, odorless.

percent volatiles by volume: na
corrosion rate: np

Reactivity

Stability indicator/materials to avoid: yes
strong acids.

stability condition to avoid: none specified by manufacturer.

hazardous decomposition products: sulfur dioxide, oxides of phosphorus.

haz combust prod: none (non-combustible).

Proper Disposal

Waste disposal methods: discharge/treatment/disposal may be subject to
national/state/local laws. Flush to sewer w/lg amts of water. Chem
subj to reporting reqmts of sara 313 title iii/40cfr372: none.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium phosphate, tribasic (cercla)
cas: 7601-54-9
rtecs #: tc9490000
fraction by wt: 80-85%
other rec limits: none recommended
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs

ingred name: sodium sulfite
cas: 7757-83-7
rtecs #: we2150000
fraction by wt: 15-20%
other rec limits: none recommended

MSDS BZPJK 878 4464 VNF-1/RVNP COLOR DEVLPR REPLNISHER,PART A,WORK SOLN

Hazards

Ld50 lc50 mixture: none specified by manufacturer.

routes of entry: inhalation: no skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhal: expected to be low hazard for
recommended hndlg. Eye: cause irrit.Skin: causes irrit. May cause
allergic skin rx.Ingest: expected to be low ingest haz.May cause
irrit of gastrointestinal tract.

explanation of carcinogenicity: per msds: carcinogenicity
classification: acgih/ntp/osha: none.

effects of overexposure: eye irritation. Skin irritation. Allergic skin
reaction. Irrit of gastrointestinal tract.

medical cond aggravated by exposure: none specified by manufacturer.

First Aid

First aid: inhal: move to fresh air.Treat symptomatically.If symptons
persist get med attn. Eyes: immed flush w/plenty of water for @least
15mins.Get med attn. Skin: immed flush w/plenty of water.Wash
w/nonalkaline (acid)typ skin cleaner.Irrit/allergic rxoccurs get
med attn.Remove contam cloth/shoes.Ingest: drink 1-2 glasses of
water.Seek med attn.Nevet give anyting by mouth if unconsc.

Chemical Properties

Hcc: b1
boiling pt: >100.C, 212.F
melt/freeze pt: m.P/f.P text: np
decomp temp: decomp text: np
vapor pres: 18mm @20c
vapor density: 0.6
spec gravity: 1.04
ph: 11.9
viscosity: np
evaporation rate & reference: np
solubility in water: complete.

appearance and odor: liquid, colorless, odorless.

percent volatiles by volume: 90-95
corrosion rate: np

Reactivity

Stability indicator/materials to avoid: yes
none w/common materials & contaminants w/which matl may reasonably come
into contact.

stability condition to avoid: none specified by manufacturer.

hazardous decomposition products: haz combust prod: none
(non-combustible).

Proper Disposal

Waste disposal methods: discharge/treatment/disposal may be subject to
national/state/local laws. Flush to sewer w/lg amts of water.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
minumum % wt: 90.

maxumum % wt: 95.

other rec limits: none recommended

ingred name: sodium phosphate, tribasic (cercla)
cas: 7601-54-9
rtecs #: tc9490000
minumum % wt: 1.

maxumum % wt: 5.

other rec limits: none recommended
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs

ingred name: sodium sulfite
cas: 7757-83-7
rtecs #: we2150000
< wt: 1.

other rec limits: none recommended
ingred
name: 4-(n-ethyl-n-2-methanesulfonylaminoethyl)-2-methylphenylenedia
mine
cas: 25646-71-3
rtecs #: pb0431000
< wt: 1.

other rec limits: none recommended

ingred name: sodium sulfate
cas: 7757-82-6
rtecs #: we1650000
< wt: 1.

other rec limits: none recommended

MSDS BZQWY 869 2428 VNF-1/RVNP COLOR DEVELOPER REPLENISHER,PART B

Hazards

Ld50 lc50 mixture: oral ld50 (rat) is 25 mg/kg.

routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: eyes: causes irritation. Skin:
causes irritation. Harmful if absorbed through skin. Inhalation:
harmful if inhaled. Ingestion: may be fatal if swallowed. May cause
convulsions. Chronic: none spe cified by manufacturer.

explanation of carcinogenicity: none.

effects of overexposure: eyes: irritation. Skin irritation. Inhalation:
harmful if inhaled. Ingestion: may be fatal if swallowed. May cause
convulsions.

medical cond aggravated by exposure: none specified by manufacturer.

First Aid

First aid: eyes: flush with large amounts of water. Get medical
attention. Skin: remove contaminated clothing. Flush contact area
with large amounts of water. Get medical attention. Inhalation:
move to fresh air . Treat symptomatically.Get medical
attention.Ingestion: induce vomiting as directed by medical
personnel.Do not give anything by mouth if unconscious.Get medical
attention.Call poison control center.

Chemical Properties

Hcc: f8
melt/freeze pt: m.P/f.P text: 212f,100c
decomp temp: decomp text: 212f,100c
spec gravity: 0.87
solubility in water: decomposes
appearance and odor: solid (crystals), white color, amine odor.

Reactivity

Stability indicator/materials to avoid: yes
strong oxidizers. Water; contact liberates toxic gas/pressure buildup.

acid; liberates flammable material, toxic gas.

stability condition to avoid: material can decompose above 100c (212f).

avoid temperatures above 50c (122f).

hazardous decomposition products: diborane gas, hydrogen.

conditions to avoid polymerization: will not occur.

Proper Disposal

Waste disposal methods: dispose of waste in accordance with local, state
and federal regulations. Flush to sewer with large amounts of
water. Emptied containers retain product residue, follow label
warnings even after contai ner is emptied.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: tert-butylamine borane
cas: 7337-45-3
rtecs #: eo3900000
fraction by wt: 100%
other rec limits: none recommended

MSDS BZQWZ 878 4464 VNF-1/RVNP COLOR DVLPR REPLNSHER, PART A-1

Hazards

Ld50 lc50 mixture: none specified by manufacturer.

routes of entry: inhalation: no skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhal: expected to be a low hazard for
recommended handling. Eyes: no specific hazard known. May cause
transient irritation. Skin: low hazard for recommended hndlg.

ingegst: expected to be low ingest haza rd.

explanation of carcinogenicity: per msds: carcinogenicity
classification: iarc/acgih/ntp/osha: none.

effects of overexposure: transient eye irritation.

medical cond aggravated by exposure: none specified by manufacturer.

First Aid

First aid: inhal: if symptomatic move to fresh air. Get med attn if
symptons persist. Eyes: any matl that contacts eye should be washed
out immed w/water. If symptoms occur get med attn. Skin: wash w/soap
& water. get med attn if symptoms occur. Ingest: drink 1-2 glasses
of water. Seek med attn. Never give anything by mouth if unconsc.

Chemical Properties

Hcc: b3
boiling pt: b.P. Text: >212f,>100c
melt/freeze pt: m.P/f.P text: np
decomp temp: decomp text: np
vapor pres: 18mm @20c
vapor density: 0.6
spec gravity: 1.40
ph: 10.2
viscosity: np
evaporation rate & reference: np
solubility in water: complete.

appearance and odor: liquid, light yellow color, ammonia odor.

percent volatiles by volume: 60-65
corrosion rate: np

Reactivity

Stability indicator/materials to avoid: yes
strong oxidizing agents, acids.

stability condition to avoid: none specified by manufacturer.

hazardous decomposition products: haz combust prod: carbon dioxide,
carbon monoxide, oxides of nitrogen, oxides of phosphorus.

Proper Disposal

Waste disposal methods: discharge/treatment/disposal may be subject to
national/state/local laws. Flush to sewer w/lg amts of water. Chem
subj to reporting reqmts of sec 313 title iii sara/40cfr372: none.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 60-65%
other rec limits: none recommended

ingred name: (nitrilotris(methylene)triphosphonic acid, k salt
cas: 2235-43-0
fraction by wt: 35-40%
other rec limits: none recommended

MSDS BZQXB 869 2428 VNF-1/RVNP COLOR DEVELOPER REPLENISHER,PART D

Hazards

Ld50 lc50 mixture: ld50 (oral rat) is 400(m),246(f) mg/kg.

routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: eyes: causes irritation.

airborne dust irritating. Skin: causes irritation. May produce
allergic skin reaction. Inhalation: harmful if inhaled. Airborne
dust irritating. Ingestion: harmful if s wallowed. Chronic: none
specified by manufacturer.

explanation of carcinogenicity: none.

effects of overexposure: eyes: irritation. Skin: irritation, allergic
skin reaction. Inhalation: harmful if inhaled. Irritation.

ingestion: harmful if swallowed.

medical cond aggravated by exposure: none specified by manufacturer.

First Aid

First aid: eyes: flush with large amounts of water. Get medical
attention. Skin: remove contaminated clothing. Flush area with
water. Get medical attention if symptoms persist. Inhalation: move
to fresh air. Tre at symptomatically. Get medical attention if
symptoms persist. Ingestion: induce vomiting as directed by medical
personnel. Get medical attention. Call poison control center.

Chemical Properties

Hcc: f8
melt/freeze pt: m.P/f.P text: 410f,210c
decomp temp: decomp text: 410f,210c
vapor pres: negligible
solubility in water: appreciable
appearance and odor: tan colored solid (crystal). Odorless.

percent volatiles by volume: n/k.

Reactivity

Stability indicator/materials to avoid: yes
material can react with strong oxidizing agents.

stability condition to avoid: this material can decompose above 210c
(410f). Avoid temperatures above 110c (230f).

hazardous decomposition products: carbon dioxide, carbon monoxide,
oxides of nitrogen, oxides of sulfur.

conditions to avoid polymerization: will not occur.

Proper Disposal

Waste disposal methods: discharge, treatment or disposal may be subject
to federal, state or local laws. Incinerate. Since emptied
containers retain product residue, follow label warnings even after
container is emptied.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: 4-(n-ethyl-n-2-methanesulfonylaminoethyl)-2-
methylphenylenediamine sesquisulfate monohydrate
cas: 25646-71-3
rtecs #: pb0431000
fraction by wt: 85-90%
other rec limits: kodak 1.0 mg/m3 twa

ingred name: citrazinic acid
cas: 99-11-6
rtecs #: ns1400000
fraction by wt: 10-15%
other rec limits: none recommended

MSDS CCVRZ 188 8825 VNF-1/RVNP COLOR DVLPR REPLNSHER, PART A-1

Hazards

Ld50 lc50 mixture: none specified by manufacturer.

routes of entry: inhalation: no skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhal: expected to be a low hazard for
recommended handling. Eyes: no specific hazard known. May cause
transient irritation. Skin: low hazard for recommended hndlg.

ingegst: expected to be low ingest haza rd.

explanation of carcinogenicity: per msds: carcinogenicity
classification: iarc/acgih/ntp/osha: none.

effects of overexposure: transient eye irritation.

medical cond aggravated by exposure: none specified by manufacturer.

First Aid

First aid: inhal: if symptomatic move to fresh air. Get med attn if
symptons persist. Eyes: any matl that contacts eye should be washed
out immed w/water. If symptoms occur get med attn. Skin: wash w/soap
& water. get med attn if symptoms occur. Ingest: drink 1-2 glasses
of water. Seek med attn. Never give anything by mouth if unconsc.

Chemical Properties

Hcc: b3
boiling pt: b.P. Text: >212f,>100c
melt/freeze pt: m.P/f.P text: np
decomp temp: decomp text: np
vapor pres: 18mm @20c
vapor density: 0.6
spec gravity: 1.40
ph: 10.2
viscosity: np
evaporation rate & reference: np
solubility in water: complete.

appearance and odor: liquid, light yellow color, ammonia odor.

percent volatiles by volume: 60-65
corrosion rate: np

Reactivity

Stability indicator/materials to avoid: yes
strong oxidizing agents, acids.

stability condition to avoid: none specified by manufacturer.

hazardous decomposition products: haz combust prod: carbon dioxide,
carbon monoxide, oxides of nitrogen, oxides of phosphorus.

Proper Disposal

Waste disposal methods: discharge/treatment/disposal may be subject to
national/state/local laws. Flush to sewer w/lg amts of water. Chem
subj to reporting reqmts of sec 313 title iii sara/40cfr372: none.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 60-65%
other rec limits: none recommended

ingred name: (nitrilotris(methylene)triphosphonic acid, k salt
cas: 2235-43-0
fraction by wt: 35-40%
other rec limits: none recommended

MSDS CFCTK 878 4464 VNF-1/RVNP COLOR DEVELOPER REPLENISHER, PART A-1

Hazards

Ld50 lc50 mixture: oral ld50 (rat): not given
routes of entry: inhalation: no skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: expected to be a low inhalation hazard
for recommended handling. May cause transient eye irritation. Low
skin contact hazard for recommended handling. Expected to be a low
ingestion hazard.

explanation of carcinogenicity: this compound contains no ingredients at
concentrations of 0.1% or greater that are carcinogens or suspect
carcinogens.

effects of overexposure: eye irritation.

medical cond aggravated by exposure: none specified by manufacturer.

First Aid

First aid: inhalation: if symptomatic, move to fresh air. Get medical
attention if symptoms persist. Eyes: wash out immediately with
water. Get medical attention if symptoms occur. Skin: wash with
soap and water . Get medical attention if symptoms occur.

ingestion: drink 1-2 glasses of water. Seek medical attention.

never give anything by mouth to an unconscious person.

Chemical Properties

Hcc: b3
boiling pt: >100.C, 212.F
melt/freeze pt: m.P/f.P text: not given
vapor pres: 18
vapor density: 0.6
spec gravity: 1.40
ph: 10.2
evaporation rate & reference: not given
solubility in water: complete
appearance and odor: light yellow liquid, ammonia odor
percent volatiles by volume: 60-65%

Reactivity

Stability indicator/materials to avoid: yes
strong oxidizing agents, acids.

stability condition to avoid: none specified by manufacturer.

hazardous decomposition products: carbon dioxide, carbon monoxide,
oxides of nitrogen, oxides of phosphorus

Proper Disposal

Waste disposal methods: discharge, treatment or disposal may be subject
to national, state or local laws. may require neutralization if ph
< 2.0 or ph > 12.5. Dispose of in accordance with all applicable
federal, state and local regulations.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 60-65%
other rec limits: none recommended

ingred name: (nitrilotris(methylene)triphosphonic acid, k salt
cas: 2235-43-0
fraction by wt: 35-40%
other rec limits: none recommended

MSDS CKVJB 188 8825,PT A,KODAK VNF-1/RVNP COLOR DEVELOPER REPLENISHER

Hazards

Ld50 lc50 mixture: not provided
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: contains ethylene glycol. Can cause
kidney damage. Can cause cns effects. May cause adverse
reproductive effects following ingestion based on animal data.

contains ethylenediamine. Can cause lung dama ge. May cause kidney
damage based on animal data. cause liver damage based on animal
data. Inhalation: mist extremely irritating. Harmful if inhaled.

may cause allergic respiratory reaction. Eyes: ca uses severe
burns. Mist extremely irritating. Skin: causes severe burns. May
cause allergic skin reaction. Harmful if absorbed through skin.

ingestion: harmful or fatal if swallowed. May cause burns o f
gastrointestinal tract if swallowed.

explanation of carcinogenicity: (components present at 0.1% or more): -
international agency for research on cancer (iarc): none - american
conference of governmental industrial hygienists (acgih): ethylene
glycol & ethylenediamine - not classifiable as a human carcinogen
(a4) - national toxicology program (ntp): none - occupational
safety and health administration (osha): none
effects of overexposure: inhalation: mist extremely irritating. Eyes:
causes severe burns. Mist extremely irritating. Skin: causes severe
burns. May cause allergic skin reaction. Ingestion: may cause burns
of gastrointestinal tract if swallowed.

medical cond aggravated by exposure: not provided

First Aid

First aid: inhalation: move to fresh air. If breathing is difficult,
give oxygen. If not breathing, give artificial respiration. Get
medical attention even if symptoms of irritation are mild/quickly
subside as l ung injury may have occurred. Eyes: immediately flush
with plenty of water for at least 15 minutes. Get medical attention
immediately. Skin: immediately flush with water for at least 15
minutes while removing contaminated clothing. Get medical
attention immediately. Ingestion: do not induce vomiting. Give
victim a glass of water. Call physician/poison control center
immediately. Never give anythin g by mouth to an unconscious
person.

Chemical Properties

Hcc: b1
nrc/state lic num: not relevant
boiling pt: >100.C, 212.F
melt/freeze pt: m.P/f.P text: not provided
decomp temp: decomp text: not provided
vapor pres: 68f: 24 mbar (18 mm hg)
vapor density: 0.6
spec gravity: 1.21
ph: 14
viscosity: not provided
evaporation rate & reference: not provided
solubility in water: complete
appearance and odor: slight yellow liquid. Odor: slight
percent volatiles by volume: 85-90 wt
corrosion rate: not provided

Reactivity

Stability indicator/materials to avoid: yes
strong oxidizing agents, acids, combustible material, halogenated
materials.

stability condition to avoid: not provided
hazardous decomposition products: carbon dioxide, carbon monoxide,
oxides of nitrogen.

Proper Disposal

Waste disposal methods: discharge, treatment, or disposal is subject to
national, state, or local laws. Contract with a licensed chemical
disposal agency. Since emptied containers retain product residue,
follow label warning s even after container is emptied.

Ingredients List

Ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
minumum % wt: 25.

maxumum % wt: 30.

other rec limits: not provided
code: f
code: f

ingred name: benzyl alcohol
cas: 100-51-6
rtecs #: dn3150000
minumum % wt: 20.

maxumum % wt: 25.

other rec limits: not provided
osha pel: not provided
acgih tlv: not provided

ingred name: sodium hydroxide
cas: 1310-73-2
rtecs #: wb4900000
minumum % wt: 15.

maxumum % wt: 20.

other rec limits: not provided
osha pel: 2 mg/m3
acgih stel: c2 mg/m3
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs

ingred name: ethylene glycol
cas: 107-21-1
rtecs #: kw2975000
= wt: 16.

other rec limits: not provided
osha pel: not provided
acgih stel: c127 mg/m3;c50 ppm
epa rpt qty: 1 lb
dot rpt qty: 1 lb

ingred name: ethylenediamine
cas: 107-15-3
rtecs #: kh8575000
minumum % wt: 10.

maxumum % wt: 15.

other rec limits: not provided
osha pel: 25 mg/m3;10 ppm
acgih tlv: 25 mg/m3;10 ppm
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs

MSDS CKVJC 188 8825,PT A-1,KODAK VNF-1/RVNP COLOR DEVELOPER REPLENISHER

Hazards

Ld50 lc50 mixture: not provided
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: effects of exposure: inhalation: low
hazard for recommended handling. Eyes: no specific hazard known.

may cause transient irritation. Skin: low hazard for recommended
handling. ingestion: expected to be a low ingestion hazard.

explanation of carcinogenicity: carcinogenicity classification
(components present at 0.1% or more): - international agency for
research on cancer (iarc): none - american conference of
governmental industrial hygienists (acgih): non e - national
toxicology program (ntp): none - occupational safety and health
administration (osha): none
effects of overexposure: eyes: may cause transient irritation.

medical cond aggravated by exposure: not provided

First Aid

First aid: inhalation: if symptomatic, move to fresh air. Treat
symptomatically. Get medical attention if symptoms persist. Eyes:
any material that contacts the eye should be washed out immediately
with water. G et medical attention if symptoms occur. Skin: wash
with soap and water. Get medical attention if symptoms occur.

ingestion: drink 1-2 glasses of water. seek medical attention.

never give anything by mouth to an unconscious person.

Chemical Properties

Hcc: b1
nrc/state lic num: not relevant
boiling pt: >100.C, 212.F
melt/freeze pt: m.P/f.P text: not provided
decomp temp: decomp text: not provided
vapor pres: (68f): 24 mbar (18 mm hg)
vapor density: 0.6
spec gravity: 1.40
ph: 10.2
viscosity: not provided
evaporation rate & reference: not provided
solubility in water: complete
appearance and odor: light yellow liquid. Odor: ammonia
percent volatiles by volume: 60-65 % wt
corrosion rate: not provided

Transportation

Hazmat hot line: (716) 722-2400 between 8 a.M. And 5 p.M. (eastern
standard time), monday through friday.

Reactivity

Stability indicator/materials to avoid: yes
strong oxidizing agents, acids
stability condition to avoid: not provided
hazardous decomposition products: carbon dioxide, carbon monoxide,
oxides of nitrogen, oxides of phosphorus

Proper Disposal

Waste disposal methods: discharge, treatment, or disposal may be subject
to national, state, or local laws. Flush to sewer with large
amounts of water.

Ingredients List

Ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
minumum % wt: 60.

maxumum % wt: 65.

other rec limits: not provided

ingred name: substituted phosphonate
cas: 2235-43-0
rtecs #: sz9880000
minumum % wt: 35.

maxumum % wt: 40.

other rec limits: not provided

MSDS CKVJD 188 8825,PT B,KODAK VNF-1/RVNP COLOR DEVELOPER REPLENISHER

Hazards

Ld50 lc50 mixture: oral ld-50 (rat): 25 mg/kg
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: effects of exposure: inhalation:
harmful if inhaled. If diborane gas is liberated at concentrations
above recommended exposure limits due to contact with a strong
oxidizer, acid, or water, it may cau se respiratory tract
irritation, drowsiness, chest tightness, coughing, wheezing,
pulmonary edema, and death. Effects may be delayed. Eyes: causes
irritation. Skin: causes irritation. Harmful if absor bed through
skin. Ingestion: may be fatal if swallowed. May cause convulsions.

explanation of carcinogenicity: carcinogenicity classification
(components present at 0.1% or more): - international agency for
research on cancer (iarc): none - american conference of
governmental industrial hygienists (acgih): non e - national
toxicology program (ntp): none - occupational safety and health
administration (osha): none
effects of overexposure: inhalation: if diborane gas is liberated at
concentrations above recommended exposure limits due to contact
with a strong oxidizer, acid, or water, it may cause respiratory
tract irritation, drowsine ss, chest tightness, coughing, wheezing,
pulmonary edema, and death. Effects may be delayed. Eyes: causes
irritation. Skin: causes irritation. Ingestion: may cause
convulsions.

medical cond aggravated by exposure: not provided

First Aid

First aid: inhalation: move to fresh air. Treat symptomatically. Get
medical attention. Eyes: immediately flush with plenty of water for
at least 15 minutes. Get medical attention. skin: immediately
flush with plenty of water for at least 15 minutes while removing
contaminated clothing and shoes. Get medical attention. Wash
contaminated clothing before reuse. Destroy or thoroughly clean
contaminated shoes. ingestion: induce vomiting as directed by
medical personnel. Never give anything by mouth to an unconscious
person. Call a physician or poison control center immediately.

Chemical Properties

Hcc: f8
nrc/state lic num: not relevant
melt/freeze pt: m.P/f.P text: deomposes
decomp temp: =100.C, 212.F
vapor pres: not available
vapor density: not availa
spec gravity: 0.87
ph: not available
solubility in water: decomposes
appearance and odor: white solid (crystal) odor: amine
percent volatiles by volume: not availabl
corrosion rate: not provided

Transportation

Product call the kodak worldwide transportation hazmat hot line:
(716) 722-2400 between 8 a.M. And 5 p.M. (eastern standard time),
monday through friday .

Reactivity

Stability indicator/materials to avoid: yes
material can react with water. Contact with water liberates toxic gas.

pressure may develop in container if contents are exposed to water.

contact with acid liberates flammable material, toxic gas. Strong
oxidizing agents.

stability condition to avoid: stable. Consult your technical safety
experts. Exotherm onset temperature: 100c by dta.

hazardous decomposition products: diborane gas, hydrogen. Carbon
dioxide, carbon monoxide, oxides of nitrogen.

Proper Disposal

Waste disposal methods: discharge, treatment, or disposal may be subject
to national, state, or local laws. Contract with a licensed
chemical disposal agency. Since emptied containers retain product
residue, follow label war nings even after container is emptied.

Ingredients List

Ingred name: tert-butylamine borane
cas: 7337-45-3
= wt: 100.

other rec limits: not provided

MSDS CKVJG 188 8825,PT C,KODAK VNF-1/RVNP COLOR DEVELOPER REPLENISHER

Hazards

Ld50 lc50 mixture: not provided
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: effects of exposure: inhalation:
airborne dust irritating. May be harmful if inhaled. May cause
irritation to the mucous membranes and upper respiratory tract. In
contact with strong acids or if heat ed, sulfites may liberate
sulfur dioxide gas. sulfur dioxide gas is irritating to the
respiratory tract. Eyes: causes burns. Airborne dust irritating.

skin: causes burns. This material has a low pote ntial to cause
allergic skin reactions; however, cases of human skin sensitization
have been reported. Ingestion: harmful if swallowed. May cause
burns of the gastrointestinal tract if swallowed.

explanation of carcinogenicity: carcinogenicity classification
(components present at 0.1% or more): - international agency for
research on cancer (iarc): none - american conference of
governmental industrial hygienists (acgih): non e - national
toxicology program (ntp): none - occupational safety and health
administration (osha): none
effects of overexposure: inhalation: airborne dust irritating. May cause
irritation to the mucous membranes and upper respiratory tract. In
contact with strong acids or if heated, sulfites may liberate
sulfur dioxide gas. s ulfur dioxide gas is irritating to the
respiratory tract. Eyes: causes burns. Airborne dust irritating.

skin: causes burns. Ingestion: may cause burns of the
gastrointestinal tract if swallowed.

medical cond aggravated by exposure: some asthmatics, hypersensitive or
sulfite-sensitive individuals may experience difficult breathing,
wheezing, chest tightness, stomach upset, hives, faintness,
weakness and diarrhea.

First Aid

First aid: inhalation: if symptomatic, move to fresh air. Treat
symptomatically. Get medical attention if symptoms occur. Eyes:
immediately flush with plenty of water for at least 15 minutes. Get
medical attenti on immediately. Skin: immediately flush with plenty
of water for at least 15 minutes while removing contaminated
clothing and shoes. Get medical attention if symptoms occur. Wash
contaminated clothing before reuse. Destroy or thoroughly clean
contaminated shoes. Ingestion: do not induce vomiting. Give victim
a glass of water. Call a physician or poison control center
immediately. Never give anythi ng by mouth to an unconscious
person.

Chemical Properties

Hcc: b1
nrc/state lic num: not relevant
melt/freeze pt: m.P/f.P text: not available
decomp temp: decomp text: not provided
vapor pres: negligible
spec gravity: >1.0
solubility in water: appreciable
appearance and odor: white odorless solid
corrosion rate: not provided

Transportation

Product call the kodak worldwide transportation hazmat hot line:
(716) 722-2400 between 8 a.M. And 5 p.M. (eastern standard time),
monday through friday .

Reactivity

Stability indicator/materials to avoid: yes
strong acids
stability condition to avoid: not provided
hazardous decomposition products: sulfur dioxide, oxides of phosphorus.

Proper Disposal

Waste disposal methods: discharge, treatment, or disposal may be subject
to national, state, or local laws. Flush to sewer with large
amounts of water. Since emptied containers retain product residue,
follow label warnings e ven after container is emptied.

Ingredients List

Ingred name: trisodium phosphate
cas: 7601-54-9
rtecs #: tc9490000
minumum % wt: 80.

maxumum % wt: 85.

other rec limits: not provided
osha pel: not provided
acgih tlv: not provided
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs

ingred name: sodium sulfite
cas: 7757-83-7
rtecs #: we2150000
minumum % wt: 15.

maxumum % wt: 20.

other rec limits: not provided
osha pel: not provided
acgih tlv: not provided

MSDS CKVJH 188 8825,PT D,KODAK VNF-1/RVNP COLOR DEVELOPER REPLENISHER

Hazards

Ld50 lc50 mixture: not provided
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: effects of exposure: general: may
cause kidney damage based on animal data. Inhalation: harmful if
inhaled. Airborne dust irritating. Eyes: causes irritation. Skin:
causes irritation. May cause allerg ic skin reaction. Ingestion:
harmful if swallowed. May cause irritation of the gastrointestinal
tract.

explanation of carcinogenicity: carcinogenicity classification
(components present at 0.1% or more): - international agency for
research on cancer (iarc): none - american conference of
governmental industrial hygienists (acgih): no ne - national
toxicology program (ntp): none - occupational safety and health
administration (osha): none
effects of overexposure: inhalation: airborne dust irritating. Eyes:
causes irritation. Skin: causes irritation. Ingestion: may cause
irritation of the gastrointestinal tract.

medical cond aggravated by exposure: not provided

First Aid

First aid: inhalation: move to fresh air. Treat symptomatically. Get
medical attention if symptoms persist. Eyes: immediately flush with
plenty of water for at least 15 minutes. Get medical attention.

skin: imm ediately flush with plenty of water forat least 15
minutes while removing contaminated clothing and shoes. Get medical
attention if symptoms occur. Wash contaminated clothing before
reuse. Destroy or thoroughly clean contaminated shoes. Ingestion:
induce vomiting as directed by medical personnel. Call a physician
or poison control center immediately. Never give anything by mouth
to an unconscio us person.

Chemical Properties

Hcc: b1
nrc/state lic num: not relevant
melt/freeze pt: m.P/f.P text: not available
decomp temp: decomp text: not provided
vapor pres: negligible
spec gravity: not available
ph: not available
solubility in water: appreciable
appearance and odor: tan, odorless solid (crystal)
corrosion rate: not provided

Transportation

Product call the kodak worldwide transportation hazmat hot line:
(716) 722-2400 between 8 a.M. And 5 p.M. (eastern standard time),
monday through friday .

Reactivity

Stability indicator/materials to avoid: yes
strong oxidizing agents
stability condition to avoid: stable. not fully evaluated. Materials
containing similar structural groups can decompose if heated above
210c (410f).

hazardous decomposition products: carbon dioxide, carbon monoxide,
oxides of nitrogen, oxides of sulfur.

Proper Disposal

Waste disposal methods: discharge, treatment, or disposal may be subject
to national, state, or local laws. Incinerate. Since emptied
containers retain product residue, follow label warnings even after
container is emptied.

Ingredients List

Ingred
name: 4-(n-ethyl-n-2-methanesulfonylaminoethyl)-2-methylphenylenedia
mine sesquisulfate monohydrate
cas: 25646-71-3
rtecs #: pb0431000
minumum % wt: 85.

maxumum % wt: 90.

other rec limits: 1.0 mg/m3 (mfr)
osha pel: not provided
acgih tlv: not provided

ingred name: citrazinic acid
cas: 99-11-6
rtecs #: ns1400000
minumum % wt: 10.

maxumum % wt: 15.

other rec limits: not provided
osha pel: not provided
acgih tlv: not provided

MSDS CKVKH 188 8825,WKG SOL,KODAK VNF-1/RVNP COLOR (SEE SUPPL DATA)

Hazards

Ld50 lc50 mixture: not provided
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation: expected to be low hazard
for industrial or commercial handling by trained personnel. In
contact with strong acids or heated, sulfites liberate sulfur
dioxide gas. Sulfur dioxide gas is ir ritating to respiratory
tract. Asthmatics or sulfite-sensitive individuals may experience
wheezing or chest tightness. Eyes: causes irritation. Skin: causes
irritation. May cause allergic skin reactio n. Ingestion: may be
harmful if swallowed. May cause irritation of the gastrointestinal
tract. Some asthmatics or sulfite-sensitive individuals may
experience wheezing, chest tightness, stomach upset, hives,
faintness, weakness and diarrhea
explanation of carcinogenicity: (components present at 0.1% or more): -
international agency for research on cancer (iarc): none - american
conference of governmental industrial hygienists (acgih): ethylene
glycol & ethylenediamine - not classifiable as a human carcinogen
(a4) - national toxicology program (ntp): none - occupational
safety and health administration (osha): none
effects of overexposure: inhalation: in contact with strong acids or
heated, sulfites liberate sulfur dioxide gas. Sulfur dioxide gas is
irritating to respiratory tract. Asthmatics or sulfite-sensitive
individuals may experie nce wheezing or chest tightness. Eyes:
causes irritation. Skin: causes irritation. Ingestion: may cause
irritation of the gastrointestinal tract. Some asthmatics or
sulfite-sensitive individuals may e xperience wheezing, chest
tightness, stomach upset, hives, faintness, weakness and diarrhea
medical cond aggravated by exposure: some asthmatics, hypersensitive or
sulfite-sensitive individuals may experience difficult breathing,
wheezing, chest tightness, stomach upset, hives, faintness,
weakness and diarrhea.

First Aid

First aid: inhalation: if symptomatic, move to fresh air. Treat
symptomatically. Get medical attention if symptoms persist. Eyes:
immediately flush with plenty of water for at least 15 minutes. Get
medical atten tion. Skin: immediately flush with plenty of water
for at least 15 minutes while removing contaminated clothing and
shoes. If skin irritation or an allergic skin reaction develops,
get medical attenti on. Ingestion: do not induce vomiting. Give
victim a glass of water. Call a physician or poison control center
immediately. Never give anything by mouth to an unconscious person.

Chemical Properties

Hcc: b3
nrc/state lic num: not relevant
boiling pt: >100.C, 212.F
melt/freeze pt: m.P/f.P text: not provided
decomp temp: decomp text: not provided
vapor pres: (68f): 24 mbar (18 mm hg)
vapor density: 0.6
spec gravity: 1.04
ph: 11.9
viscosity: not provided
evaporation rate & reference: not provided
solubility in water: complete
appearance and odor: colorless, odorless liquid.

percent volatiles by volume: 90-95 wt
corrosion rate: not provided

Transportation

Worldwide transportation hazmat hot line: (716) 722-2400 between 8
a.M. And 5 p.M. (eastern standard time), monday through friday.

Reactivity

Stability indicator/materials to avoid: yes
none with common materials and contaminants with which the material may
reasonably come into contact.

stability condition to avoid: not provided
hazardous decomposition products: none

Proper Disposal

Waste disposal methods: flush to sewer with large amount of water.

Ingredients List

Ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
minumum % wt: 90.

maxumum % wt: 95.

other rec limits: not provided
code: f
code: f

ingred name: trisodium phosphate
cas: 7601-54-9
rtecs #: tc9490000
minumum % wt: 1.

maxumum % wt: 5.

other rec limits: not provided
osha pel: not provided
acgih tlv: not provided
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs

ingred name: sodium sulfite
cas: 7757-83-7
rtecs #: we2150000
< wt: 1.

other rec limits: not provided
osha pel: not provided
acgih tlv: not provided
ingred
name: 4-(n-ethyl-n-2-methanesulfonylaminoethyl)-2-methylphenylenedia
mine sesquisulfate monohydrate
cas: 25646-71-3
rtecs #: pb0431000
< wt: 1.

other rec limits: 1 mg/m3 (mfr)
osha pel: not provided
acgih tlv: not provided

ingred name: sodium sulfate
cas: 7757-82-6
rtecs #: we1650000
< wt: 1.

other rec limits: not provided
osha pel: not provided
acgih tlv: not provided

ingred name: ethylenediamine
cas: 107-15-3
rtecs #: kh8575000
< wt: 1.

other rec limits: not provided
osha pel: 25 mg/m3;10 ppm
acgih tlv: 25 mg/m3;10 ppm
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs