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Acs Dioxane

NSN: 6810-00-050-3430 | Model: D111
NSN Properties and Flags
NATO Stock Number
6810-00-050-3430
DEMIL
NO
Physical Form
Liquid
Quantity Within Each Unit Package
16.000 ounces, fluid
Special Handling Feature
Flammable
Melting Point Tempurature Range
+11.0/+11.2 degrees celsius

Pricing and Availability

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NSN 6810-00-050-3430 Datasheet

Supply Class (FSC):
Chemicals
Cross Reference:
  • D111
Cage Codes:
  • Fisher Scientific Company L.l.c. (CAGE 22527)
Schedule B & Trade:
  • Schedule B: 2901106000 (NAICS 325110)

    Saturated acyclic hydrocarbons (excl ethane and butane)

  • SITC: 51114

    Saturated acyclic hydrocarbons

  • End Use: 12540

    Chemicals-organic

Identification:
HMIC

Y - Indicates information is in the hazardous materials information resource system (hmirs).

PMIC

A - Item does not contain precious metal.

CRITL

- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.

Questions & Answers:

What are the historical prices recorded for this stock number?
No pre-dated pricing for this NSN could be found.
Does NSN 6810-00-050-3430 have a shelf life?
No. There is no shelf life applicable for this NSN.
What NATO entities are users of this NSN?
No recorded entities for this stock number.
What is the NIIN of NSN 6810-00-050-3430?
000503430 or 00-050-3430
Does NSN 6810-00-050-3430 require demilitarization?
Yes - ITAR Controlled
What is the most recent solicitation for NSN 6810-00-050-3430?
No solicitations for this NSN.
When was this national stock number assigned to the federal catalog?
Nov 03, 1979
MSDS

Material Safety

MSDS CDWZD 1,4-DIOXANE, D-111

Hazards

Ld50 lc50 mixture: none specified by manufacturer.

routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: yes iarc: yes osha: no
health hazards acute and chronic: acute: inhal: nose, thorat & resp tract
irrit. Cmpd has poor warning properties & can be inhaled in amts
that may cause serious systemic injury. Symps of systemic tox incl
hdch, vertigo, drow, dyspnea, naus & vomit, oliguria, anuria,
hepatomegaly & sev liver & kidney dmg. Inhal cause incrd
salivation, (efts of overexp)
explanation of carcinogenicity: p-dioxane: iarc monographs, supp, vol 7,
pg 201. 1987: group 2b. Ntp 7th annual rpt on carcins, 1994: antic to
be carcin.

effects of overexposure: hlth haz: lacrim, narcos & behavior chgs in
animals. Autopsy showed lung, liver & kidney dmg, congestion &
edema of lungs & incrd blood counts. Skin: irrit w/redness & pain.

allergic cntct derm reported . Skin absorption may occur w/hdch,
naus & vomit; prdced signs of unsteadiness, incoord, narcos,
erythema & liver(ing 7)
medical cond aggravated by exposure: persons with preexisting liver,
kidney, pulmonary or skin disorders may be at an increased risk
from exposure.

First Aid

First aid: inhal: remove to fresh air immed. If brthg has stopped give
artf resp. Maintain airway & blood press & admin o*2 if avail. Keep
warm & at rest. Admin of o*2 should be performed by qualified pers.

get m ed attn immed. Skin: remove contamd clthg & shoes immed. Wash
area w/soap or mild detergent & lg amts of water until no evid of
chem remains (approx 15-20 min). Get med attn immed. Eye: wash (ing
18)

Chemical Properties

Boiling pt: b.P. Text: 214f,101c
melt/freeze pt: m.P/f.P text: 53.0f,11.7c
vapor pres: 27 @ 20c
vapor density: 3.0
spec gravity: 1.034
evaporation rate & reference: 2.7 (butyl acetate=1)
solubility in water: soluble
appearance and odor: colorless liquid with a faint ether-like odor.

Reactivity

Stability indicator/materials to avoid: yes
nickel (raney)+hydrogen; oxidizers(strong); silver perchlorate. Cntct
nehc for complete list of matls to avoid .

stability condition to avoid: forms peroxides on standing, esp when
contamd w/moisture. If distilled or evaporated to dryness, an
explosion may occur.

hazardous decomposition products: thermal decomposition products may
include toxic oxides of carbon.

Proper Disposal

Waste disposal methods: observe all federal, state and local regulations
when storing or disposing of this substance.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: p-dioxane; (1,4-dioxane) (sara 313) (cercla)
cas: 123-91-1
rtecs #: jg8225000
fraction by wt: 100%
osha pel: 100 ppm, s
acgih tlv: 25 ppm, s
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs

ingred name: supdat: flooding amts as fog, solid streams may not be
eftive. Cool cntnrs w/flooding qtys of water, apply from as(ing 3)
rtecs #: 9999999zz

ingred name: ing 2: far a dist as poss. Avoid brthg tox vaps, keep
upwind. Use water spray, dry chem, alcohol foam or co*2 to (ing 4)
rtecs #: 9999999zz

ingred name: ing 3: fight fire. Use water to keep fire-expos cntnrs
cool. If leak/spill has not ignited, use water spray to (ing 5)
rtecs #: 9999999zz

ingred name: ing 4: disperse vaps & protect pers attempting to stop
leak. Water spray may be used to flush spills away from (ing 6)
rtecs #: 9999999zz

ingred name: ing 5: expos & to dilute spills to nonflam mixs. Water may
be ineftive.

rtecs #: 9999999zz

ingred name: efts of overexp: & kidney dmg in animals. Eye: vaps may cause
irrit @ concs >220ppm. No serious disturb by external(ing 8)
rtecs #: 9999999zz

ingred name: ing 7: cntct reported. Ingest: no human data avail. Lg doses
rsltd in weak, depress, coma & death in animals. (ing 9)
rtecs #: 9999999zz

ingred name: ing 8: autopsy revealed hemorr areas in pyloric region of
stom, bladder distended w/urine, slight proteinuria & (ing 10)
rtecs #: 9999999zz

ingred name: ing 9: enlarged kidneys. Aspir may rslt in pneum. Chronic:
inhal: muc memb irrit, hdch, vertigo, loss of appetite,(ing 11)
rtecs #: 9999999zz

ingred name: ing 10: naus & vomit, pain & tenderness in abdomen & lumbar
region, drow, malaise, liver dmg. Uremia, coma, death(ing 12)
rtecs #: 9999999zz

ingred name: ing 11: from acute renal failure. Autopsies showed lung &
brain congestion, cns dmg, liver necrosis, hemorrhagic (ing 13)
rtecs #: 9999999zz

ingred name: ing 12: nephritis & necrosis, leukocytosis & bronchopneum.

skin: dry & cracked, derm, eczema. Skin absorption may (ing 14)
rtecs #: 9999999zz

ingred name: ing 13: have contributed to death of worker after 1 wk
expos. Animal studies show rptd skin applicatn may rslt in(ing 15)
rtecs #: 9999999zz
other rec limits: /k

ingred name: ing 14: liver & kidney dmg. Tumor promoter activity in mice
poss. Eye: conj. Ingest: animal feeding studies prdced (ing 16)
rtecs #: 9999999zz

ingred name: ing 15: liver & kidney dmg, ulceration of stom, hepatomas,
carcinomas of nasal cavity, kidney pelvis, leukemia, (ing 17)
rtecs #: 9999999zz

ingred name: ing 16: lymphosarcoma, cholangiomas & gall bladder
carcinomas. Embryo/fetus efts during 6-15 days of pregnancy in
rats.

rtecs #: 9999999zz

ingred name: first aid: immed w/lg amts of water occasnly lift upper &
lower lids until no evid of chem remains (@ lst 15-20 (ing 19)
rtecs #: 9999999zz

ingred name: ing 18: min). Get med attn immed. Ingest: remove by gastric
lavage/emesis using activated charcoal. Do not perform(ing 20)
rtecs #: 9999999zz

ingred name: ing 19: gastric lavage/emesis if uncon. Maintain blood
press & resp. Give o*2 if resp depressed. Treat symp & (ing 21)
rtecs #: 9999999zz

ingred name: ing 20: supportively. Get med attn immed. Pvnt aspir: keep
head below hips during vomit; use prot measures during (ing 22)
rtecs #: 9999999zz

ingred name: ing 21: lavage. O*2 & lavage should be admin by qualified
med pers. No specific antidote. Treat symp & supportively.

rtecs #: 9999999zz

ingred name: spill proc: haz area! Keep unnec people away; isolate area
& deny entry. Safe drinking water & tox enforcement (ing 24)
rtecs #: 9999999zz

ingred name: ing 23: act (proposition 65) prohibits contam any known
source of drinking water w/chems known to cause cancer/repro tox.

rtecs #: 9999999zz

ingred name: hndlg/stor precs: isolate from combust/oxidizing matls &
all poss sources of ignit. Store away from incompat substances.

rtecs #: 9999999zz

MSDS CDWZF 1,4-DIOXANE, DIII

Hazards

Ld50 lc50 mixture: none specified by manufacturer.

routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: inhal: may be irritating to
nose, throat & resp tract at 220 ppm. This cmpd has poor warning
properties & can be inhaled in amts that may cause serious systemic
injury. Symps of systemic tox may incl hdch, vertigo, drow,
dyspnea, naus, & vomit. Inhal caused incrd salivation, lacrimation,
(efts of overexp)
explanation of carcinogenicity: not relevant.

effects of overexposure: hlth haz: narcosis, behavioral changes, & death
in animals. Autopsy revealed lung, liver & kidney dmg, congestion &
edema of the lungs, & incr blood counts. Skin: may cause irrit
w/redness & pain. Aller gic cntct derm has been rptd. Skin
absorption may occur & cause hdch, naus & vomit. Skin absorption
prdced (ing 3)
medical cond aggravated by exposure: none specified by manufacturer.

First Aid

First aid: ingest: call md immediately . Inhal: remove to fresh air.

support breathing (give o*2/artf resp) . Eyes: immediately flush
w/potable water for a minimum of 15 minutes, seek assistance from
md . Skin: flush w/copious amounts of water. Call md . For more
specific information contact nehc .

Chemical Properties

Boiling pt: b.P. Text: 214f,101c
melt/freeze pt: m.P/f.P text: 54.0f,12.2c
vapor pres: 40 @ 25c
vapor density: 3.0
spec gravity: 1.0337
evaporation rate & reference: 2.7 (butyl acetate=1)
solubility in water: 100%
appearance and odor: colorless liquid with a faint, ethereal odor.

Reactivity

Stability indicator/materials to avoid: yes
decaborane, nickel (raney catalyst), nitric acid + perchloric acid,
oxidizers (strong), silver perchlorate (supdat)
stability condition to avoid: avoid cntct w/heat, sparks, flames/other
sources of ignit. Vaps may be explosive & poisonous; do not allow
(supdat)
hazardous decomposition products: thermal decomposition products may
include toxic oxides of carbon.

conditions to avoid polymerization: hazardous polymerization has not
been reported to occur under normal temperatures and pressures.

Proper Disposal

Waste disposal methods: observe all federal, state and local regulations
when storing or disposing of this substance. Disposal must be in
accordance with standard applicable to generators of hazardous
waste.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: 1,4-dioxane (diethylene dioxide) (sara 313) (cercla)
cas: 123-91-1
rtecs #: jg8225000
fraction by wt: 100.0%
osha pel: s, 100 ppm
acgih tlv: s, 25 ppm; 9495
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs

ingred name: inhivitors
fraction by wt: 100.0%
osha pel: n/k
acgih tlv: n/k

ingred name: efts of overexp: signs of unsteadiness, incoordination,
narcosis, erythema, & liver & kidney dmg in animals. (ing 4)
rtecs #: 9999999zz

ingred name: ing 3: eye: vaps may cause irrit at concs above 220 ppm.

applictn to rabbit eyes cause transient corneal injury. (ing 5)
rtecs #: 9999999zz

ingred name: ing 4: ingest: may cause light burning sensation on cntct
w/oral muc memb. Lrg doses rsltd in weak, incoord, (ing 6)
rtecs #: 9999999zz

ingred name: ing 5: depress, coma & death in animals. Autopsy revealed
hemorrhagic areas in the pyloric region of stomach, (ing 7)
rtecs #: 9999999zz

ingred name: ing 6: bladders distended w/urine, slight proteinuria &
enlarged kidneys. Aspir may rslt in pneumonia. Chronic: (ing 8)
rtecs #: 9999999zz

ingred name: ing 7: inhal: rptd expos cause muc memb irrit, dyspnea, hdch,
vertigo, loss of appetite, naus & vomit, pain & (ing 9)
rtecs #: 9999999zz

ingred name: ing 8: tenderness in the abdomen & lumbar region, drow,
malaise, liver enlargement & dmg, oliguria, anuria, (ing 10)
rtecs #: 9999999zz

ingred name: ing 9: uremia, coma, & death from acute renal failure.

autopsies revealed lung & brain congestion, cns dmg, liver(ing 11)
rtecs #: 9999999zz

ingred name: ing 10: necrosis, hemorrhagic nephritis & necrosis,
leukocytosis, & bronchopneumonia. Skin: prlng/rptd cntct (ing 12)
rtecs #: 9999999zz

ingred name: ing 11: may cause drying & cracking of the skin, derm, &
eczema. Skin absorption may have contributed to the (ing 13)
rtecs #: 9999999zz

ingred name: ing 12: death of a worker following skin & inhal expos for
one week. Animal studies indicate rptd skin applicatn (ing 14)
rtecs #: 9999999zz

ingred name: ing 13: may rslt in liver & kidney dmg. Tumor promoter
activity has been rprtd in mice. Eye: rptd/prlng expos may (ing 15)
rtecs #: 9999999zz

ingred name: ing 14: rslt in conj. Ingest: in animal feeding studies, this
cmpd prdce liver & kidney degeneration & necrosis, (ing 16)
rtecs #: 9999999zz

ingred name: ing 15: ulceration of the stomach, hepatomas, carcinoma of
the nasal cavity, carcinoma of the kidney pelvis, (ing 17)
rtecs #: 9999999zz

ingred name: ing 16: leukemia, lymphosarcoma, cholangiomas, gall bladder
carcinomas, and tumors of the lung. Reproductive (ing 18)
rtecs #: 9999999zz

ingred name: ing 17: effects have been reported in animals.

rtecs #: 9999999zz

ingred name: spill proc: no smoking, flames or flares in hazard area.

keep unnecessary people away; isolate haz area & restrict entry.

rtecs #: 9999999zz

ingred name: other prot equip: to prevent repeated or prolonged skin
contact with this substance.

rtecs #: 9999999zz

ingred name: eye prot: and full length faceshield .

rtecs #: 9999999zz

ingred name: explo haz: are explosive. Due to low electroconductivity of
the substance, flow or agitation may generate (ing 23)
rtecs #: 9999999zz

ingred name: ing 22: electrostatic charges resulting in sparks with
possible ignition.

rtecs #: 9999999zz