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Sulfuric acid and oleum
Sulfuric acid; oleum
Chemicals-inorganic
Y - Indicates information is in the hazardous materials information resource system (hmirs).
PMICA - Item does not contain precious metal.
044155 - Chem: corrosive matls, group a
450 - Acids, liquid, corrosive
9 - Other or no special handling required (sh)
A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.
C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp
D - Contaminated cargo (not including any hazardous material)
W - Rating variable
Questions & Answers: |
|
| What are the historical prices recorded for this stock number? | |
| Historical data shows pricing from $35.52 to $59.20.. | |
| Does NSN 6810-00-072-2921 have a shelf life? | |
| No. There is no shelf life applicable for this NSN. | |
| What NATO entities are users of this NSN? | |
| Department Of The Navy, and National Aeronautics and Space Administration | |
| What is the NIIN of NSN 6810-00-072-2921? | |
| 000722921 or 00-072-2921 | |
| Does NSN 6810-00-072-2921 require demilitarization? | |
| Yes - ITAR Controlled | |
| What is the most recent solicitation for NSN 6810-00-072-2921? | |
| No solicitations for this NSN. | |
| When was this national stock number assigned to the federal catalog? | |
| Jan 01, 1963 | |
Effects of overexposure: liquid causes severe burns of skin and eyes.
First aid: eye: flush with water 15 minutes, see a physician. Skin: blot
if practical,then flush with water,obtain medical tratment.
ingestion: do not give emetic,give water,milk or milk of magnesia,
call a physi cian.
Hcc: c1
boiling pt: b.P. Text: 554f/290c
spec gravity: 1.84
solubility in water: complete
appearance and odor: clear colorless liquid
Stability indicator/materials to avoid: yes
combustible materials,organic material,metals.
hazardous decomposition products: fumes of sulfur oxide
Waste disposal methods: dispose of by means as to comply with all
local,state and federal regulations or contact an approved &
licensed disposal agency.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: ld50: (oral,rat) 2140 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhal: corrosive/toxic. Acute: exposure
to conc cntng 5 mg/m3 may cause nose & throat irrit, hdch, cough,
an incr in resp rate/impairment of vent capacity. Delayed symps may
incl pulm edema, tightness in chest, cyanosis, hypotension,
bronchitis or emphysema. Chronic: rptd expos to mist causes
chronic(efts of overexp)
explanation of carcinogenicity: not relevant
effects of overexposure: hlth haz: tracheo-bronchitis, erosion &
discoloration of teeth, bronchial pnmeumonia or gi distrubances.
skin: corrosive. Acute: cntct may cause severe irrit & pain, burns &
vesiculation. Chronic: rptd/pr lngd expos to liq/mist may cause
irrit & derm. Eye: corrosive. Acute: direct cntct w/conc acid soln
may cause (ing 4)
medical cond aggravated by exposure: none specified by manufacturer.
First aid: inhal: remove to fresh air. Support breathing (give o*2/artf
resp). Skin: remove contam clthg & shoes immed. Wash affected area
w/soap or mild detergent & lrg amts of water until no evidence of
chem remains. In case of burns, cover the area with sterile, dry
dressing. Bandange securely, but not too tightly. Get med attn.
eyes: wash immed w/lrg amts of water for at least 15 min, (ing 9)
Boiling pt: b.P. Text: 536f,280c
melt/freeze pt: m.P/f.P text: 37.0f,2.8c
vapor pres: 0.001@ 20c
vapor density: 3.4
spec gravity: 1.8
solubility in water: soluble
appearance and odor: colorless to dark brown, oily liquid.
Stability indicator/materials to avoid: yes
alcohols & hydrogen peroxide, ammonium hydroxide, chlorate, metals
(powdered), perchlorates, steel.
stability condition to avoid: may ignite other combust matls
(wood,paper,oil,etc). Violent rxn w/h*2o & org matl. Flamm,poison
gas may accum in(ing 3)
hazardous decomposition products: thermal decomposition products include
highly toxic fumes of sulfur oxides.
Waste disposal methods: disposal must be in accordance with federal,
state and local regulations .
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 98%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 2%
ingred name: cndtns to avoid (stab): confined spaces. Runoff to sewer
may create fire or explosion hazard.
rtecs #: 9999999zz
ingred name: efts of overexp: severe dmg, often leading to blindess.
dilute solns produce more transient efts from which (ing 5)
rtecs #: 9999999zz
ingred name: ing 4: recovery may be complete. Exposure to the mist
causes eye irrit & lacrimation. Chronic: rptd/prlngd expos (ing 6)
rtecs #: 9999999zz
ingred name: ing 5: may cause conjunctivitis and lacrimation. Ingest:
acute: severe burning pain in mouth, throat & abdomen (ing 7)
rtecs #: 9999999zz
ingred name: ing 6: followed by vomiting & dirrhea of dark, precipitated
blood. Asphyxia may occur from swelling of the throat.(ing 8)
rtecs #: 9999999zz
ingred name: ing 7: perforation of the esophagus and stomach may occur.
rtecs #: 9999999zz
ingred name: first aid proc: occasnly lifting the upper & lower lids,
until no evidence of chem remains. In case of burns, (ing 10)
rtecs #: 9999999zz
ingred name: ing 9: apply sterile bandages loosely without medication.
get med attn. Ingest: if victim is conscious, give lrg (ing 11)
rtecs #: 9999999zz
ingred name: ing 10: quantities of water immediately to dilute the acid.
do not induce vomiting. Get medical attn immediately.
rtecs #: 9999999zz
ingred name: spill proc: w/slaked lime, sodium bicarbonate/crushed
limestone. Air spill: knock down vaps w/water spray. Keep (ing 13)
rtecs #: 9999999zz
ingred name: ing 12: upwind. Water spill: neut w/agricultural lime, slaked
lime, crushed limestone or sodium bicarbonate. Add (ing 14)
rtecs #: 9999999zz
ingred name: ing 13: suitable agent to neutralize spilled matl to ph-7.
occup spill: keep combust (wood, paper, oil, etc.) (ing 15)
rtecs #: 9999999zz
ingred name: ing 14: away from spilled matl. Do not touch spilled matl.
do not get h*2o inside cntnr. Stop leak if you can do (ing 16)
rtecs #: 9999999zz
ingred name: ing 15: it without risk. Use water spray to reduce vaps. Do
not put water on leak/spill area. Clean up only under(ing 17)
rtecs #: 9999999zz
ingred name: ing 16: the supervision of an expert. Dike spill for later
disp. Do not apply water unless directed to do so. (ing 18)
rtecs #: 9999999zz
ingred name: ing 17: keep unnec people away. Isolate hazard area and
deny entry. Ventilate closed spaces before entering.
rtecs #: 9999999zz
Ld50 lc50 mixture: see ingredient 1.
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: acute: inhal: 80 mg/m3 immed dangerous
to life/hlth. Mists may cause muc memb irrit. Low concs may cause
incrd pulm air flow resist & subsequent shallower & more rapid
brthg. Hot concentrated mists ma y cause rapid loss of
consciousness w/poss lung dmg. Single overexp may lead to
laryngeal, (efts of overexp)
explanation of carcinogenicity: sulfuric acid: iarc mono on eval of
carcin risk of chems to man, vol 54, pg 41, 1992: group 1. Animal:
pulm irrit.
effects of overexposure: hlth haz: tracheobronchial & pulm edema. Skin:
concentrated acid may cause sev second & third degree burns
w/necrosis due to its affinity for water & subsequent sev
dehydrating action. Poss charring m ay occur leading to shock &
collapse. Rsltg wounds may be long in healing & may cause scarring
that (ing 3)
medical cond aggravated by exposure: none specified by manufacturer.
First aid: inhal: remove to fresh air immed. Perform artf resp if nec.
maintain airway, blood press & resp. Keep warm & at rest. Treat
symptomatically & supportively. Get med attn immed. Qualified med
pers shoul d consider admin oxygen. Skin: remove contam clthg &
shoes immed. Wash w/soap & lge amts of water until no evidence of
chem remains (15-20 min). If burns occur, cover affected area
securely (ing 18)
Boiling pt: b.P. Text: 626f,330c
melt/freeze pt: m.P/f.P text: 50.0f,10.0c
vapor pres: 0.001@20c
vapor density: 3.4
spec gravity: 1.84
ph: 3
solubility in water: soluble
appearance and odor: odorless, clear, colorless, dense hygroscopic oily
liq w/marked acid (sup dat)
Stability indicator/materials to avoid: no
bases, combust matls, hydrogen peroxide, metals, perchlorates. For
complete list of matls to avoid cont nehc .
stability condition to avoid: may ignite other combustible materials
(wood, paper, oil, etc). Violent exothermic reaction with water.
hazardous decomposition products: thermal decomposition may release
toxic oxides of sulfur.
Waste disposal methods: disposal must be in accordance with standards
applicable to generators of hazardous waste, 40 cfr 262. Epa
hazardous waste number d002. 100 pound cercla section 103
reportable quantity.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara 302/313) (cercla) ld50 (oral rat): 2140
mg/kg
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 70-100%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3/3 stel
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 0-30%
osha pel: n/k
acgih tlv: n/k
ingred name: efts of overexp: may rslt in functional inhibition. Dilute
solns may cause irrit. Eye: vaps may cause a (ing 4)
rtecs #: 9999999zz
ingred name: ing 3: burning/stinging sensation w/lacrimation, blurred
vision & conj congestion. Splashes of acid may prdce (ing 5)
rtecs #: 9999999zz
ingred name: ing 4: deep corneal ulceration, kerato-conj & palpebral
lesions w/sev sequelae. Irreparable corneal dmg & (ing 6)
rtecs #: 9999999zz
ingred name: ing 5: blindness as well as scarring of eyelids may occur.
diluted acid may prdce more transient efts from which (ing 7)
rtecs #: 9999999zz
ingred name: ing 6: recovery may be complete. Ingest: may cause burning
pain in mouth, throat, esophagus & abdomen, sour taste(ing 8)
rtecs #: 9999999zz
ingred name: ing 7: & naus followed by vomit & diarr of charred black
stom contents. Dehydration & carbonization of tiss may (ing 9)
rtecs #: 9999999zz
ingred name: ing 8: occur. Brownish/yellowish stains may be found around
mouth, intense thirst, dfclt swallowing, acidemia, (ing 10)
rtecs #: 9999999zz
ingred name: ing 9: stomatitis, rapid & weak pulse, shallow brthg, shock
& poss convls & death may occur. Poss perforation (ing 11)
rtecs #: 9999999zz
ingred name: ing 10: of gi tract may rslt in peritonitis. Chronic:
inhal: rptd expos to mist may cause inflamm of upper resp (ing 12)
rtecs #: 9999999zz
ingred name: ing 11: tract, chronic bronch & etching of dental enamel.
rptd excess expos over long periods of time have rsltd(ing 13)
rtecs #: 9999999zz
ingred name: ing 12: in bronch symps, rhinorrhea, frequent resp tract
infections, emphysema, stomatitis & digestive disturb. (ing 14)
rtecs #: 9999999zz
ingred name: ing 13: chronic inhal may cause acidosis which affects nerv
sys & prdces agitation, hesitant gait & generalized (ing 15)
rtecs #: 9999999zz
ingred name: ing 14: weak. Repro efts have been reported in animals.
skin: rptd cont w/low concs may cause desicration & (ing 16)
rtecs #: 9999999zz
ingred name: ing 15: ulceration of hands, & panaris/chronic purulant
inflamm around nails. Dilute solns may cause derm. (ing 17)
rtecs #: 9999999zz
ingred name: ing 16: eye: rptd expos may rslt in lacrimation & chronic
conj. For more specific info on hlth hazs cont nehc .
rtecs #: 9999999zz
ingred name: first aid proc: w/sterile, dry, loose-fitting dressing. Get
med attn. Eye: wash immed w/lge amts of water, occas(ing 19)
rtecs #: 9999999zz
ingred name: ing 18: lifting upper & lower lids, until no evidence of
chem remains (15-20 min). Continue irrigating w/norm (ing 20)
rtecs #: 9999999zz
ingred name: ing 19: saline until ph has returned to norm (30-60 min).
cover w/sterile bandages. Get med attn. Ingest: do (ing 21)
rtecs #: 9999999zz
ingred name: ing 20: not use gastric lavage/emesis. Give lge amts of
water/milk. Repeat if vomit occurs. Ingested corr should(ing 22)
rtecs #: 9999999zz
ingred name: ing 21: be diluted approx 100 times to render it harmless
to tiss. Do not give anything by mouth to pers who is (ing 23)
rtecs #: 9999999zz
ingred name: ing 22: uncon/otherwise unable to swallow. If vomit occurs,
keep head lower than hips to help pvnt aspir. (ing 24)
rtecs #: 9999999zz
ingred name: ing 23: maintain airway & resp. Treat symptomatically &
supportively. Get med attn immed.
rtecs #: 9999999zz
ingred name: spill proc: isolate haz area & deny entry. Vent clsd spaces
before entering. Reportable qty (rq): 1000 pounds.
rtecs #: 9999999zz
Ld50 lc50 mixture: none specified by manufacturer.
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: acute: inhal: irrit. Incrd pulm air
flow resist, shallower & rapid brthg. Rapid loss of consciousness,
dmg to lungs. Nasal secretions, sneezing, burning/tickling cough,
resp distress, tracheobronchiti s, chem pneumit, spasm of vocal
cords. Bloody nasal secretions & sputum, hematemesis gastritis, &
pulm (efts of overexp)
explanation of carcinogenicity: sulfuric acid: iarc monographs, volume
54, page 41, 1992: group 1. Animal: pulmonary irritation.
effects of overexposure: hlth haz: edema. Laryngeal, tracheobronchial &
pulm edema. Pulm fibrosis, residual bronch, & pulm emphysema. Skin:
sev burns, necrosis, charring, shock & collapse. Scarring. Eye:
burning/stinging, lac rimation, blurred vision & conj congestion.
deep corneal ulceration, kerato-conj & palpebral lesions w/sev (ing
4)
medical cond aggravated by exposure: none specified by manufacturer.
First aid: inhal: remove to fresh air. Perform artf resp. Maintain
airway, blood press & resp. Keep warm & at rest. Treat
symptomatically & supportively. Get med attn immed. Qualified med
pers should consider ad min oxygen. Skin: remove contam clthg
&shoes. Wash w/soap/mild detergent & lge amts of water until no
evidence of chem remains (at least 15-20 min). If burns occur,
cover affected area (ing 13)
Boiling pt: b.P. Text: 626f,330c
melt/freeze pt: m.P/f.P text: 50.0f,10.0c
vapor pres:
vapor density: 3.4
spec gravity: 1.84
ph:
solubility in water: soluble
appearance and odor: odorless, clear, colorless, dense hygroscopic oily
liquid with acid taste
Stability indicator/materials to avoid: yes
acetaldehyde, acetic anhydride, acetone+nitric acid, acetone+potassium,
acetonitrile.Cont nehc for complete list .
stability condition to avoid: combustible matls, water. Poisonous gases
may accumulate. Runoff to sewer. Contact nehc for more information
.
hazardous decomposition products: thermal decomposition may release
toxic oxides of sulfur.
Waste disposal methods: observe all fedl, state & local regulations when
disposing of this substance. Disposal must be i/a/w standards
applicable to generators of hazardous waste, 40 cfr 262. Epa
hazardous waste number d002. 100 pound cercla section 103
reportable quantity.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara 302/313) (cercla)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 70-100%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3/3 stel
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 0-30%
osha pel: n/k
acgih tlv: n/k
ingred name: sup dat: cool contrs w/flooding amts of water, apply from
as far dist as poss. Avoid brthg corr vaps, keep upwind.
rtecs #: 9999999zz
ingred name: efts of overexp: sequelae. Corneal dmg, blindness,
scarring. Glaucoma & cataract. Ingest: burning pain, sour (ing 5)
rtecs #: 9999999zz
ingred name: ing 4: taste, naus, vomit, diarr. Dehydration &
carbonization of tiss, eschars. Brownish/yellowish stains around
(ing 6)
rtecs #: 9999999zz
ingred name: ing 5: mouth, intense thirst, dfclt swallowing, acidemia,
stomatitis, rapid & weak pulse, shallow brthg, shock & (ing 7)
rtecs #: 9999999zz
ingred name: ing 6: poss convls & death. Albumin, blood & casts in
urine, anuria, esophageal & delayed gastric stenosis. (ing 8)
rtecs #: 9999999zz
ingred name: ing 7: perforation of gi tract, peritonitis. Chronic:
inhal: inflamm of upper resp tract, chronic bronch & (ing 9)
rtecs #: 9999999zz
ingred name: ing 8: etching of dental enamel. Bronch symps, rhinorrhea,
frequent resp tract infections, emphysema, stomatitis(ing 10)
rtecs #: 9999999zz
ingred name: ing 9: & digestive disturb. Alkaline depletion of body;
acidosis, agitation, hesitant gait & gen weak. Incrd (ing 11)
rtecs #: 9999999zz
ingred name: ing 10: risk of laryngeal cancer. Repro efts. Skin:
desiccation & ulceration, purulent inflamm around nails. (ing 12)
rtecs #: 9999999zz
ingred name: ing 11: derm. Eye: lacrimation, conjunctivitis. Contact
nehc for more specific information .
rtecs #: 9999999zz
ingred name: first aid proc: securely w/sterile, dry, loose-fitting
dressing. Treat symptomatically & supportively. Get med (ing 14)
rtecs #: 9999999zz
ingred name: ing 13: attn immed. Eye: wash immed w/lge amts of water,
occas lifting upper & lower lids, until no evidence of (ing 15)
rtecs #: 9999999zz
ingred name: ing 14: chem remains (at least 15-20 min). Continue
irrigating w/norm saline until ph has returned to norm (ing 16)
rtecs #: 9999999zz
ingred name: ing 15: (30-60 min). Cover w/sterile bandages. Get med attn
immed. Ingest: do not use gastric lavage/emesis. (ing 17)
rtecs #: 9999999zz
ingred name: ing 16: give lge amts of water/milk. Repeat if vomit
occurs. Ingested corr should be diluted approx 100 times (ing 18)
rtecs #: 9999999zz
ingred name: ing 17: to render it harmless to tiss (dreisbach &
robertson; handbook of pois; 12th ed.). Do not give anything (ing
19)
rtecs #: 9999999zz
ingred name: ing 18: by mouth to pers who is uncon/otherwise unable to
swallow. If vomit occurs, keep head lower than hips (ing 20)
rtecs #: 9999999zz
ingred name: ing 19: to help pvnt aspir. Maintain airway & resp. Treat
symptomatically & supportively. Get med attn immed. (ing 21)
rtecs #: 9999999zz
ingred name: ing 20: antidote: treat symptomatically and supportively.
rtecs #: 9999999zz
ingred name: resp prot: filter; any supp-air resp operated in continuous
flow mode. 50 mg/m3: any chem cartridge resp w/full (ing 23)
rtecs #: 9999999zz
ingred name: ing 22: facepiece & acid gas cartridge(s) in combination
w/high-efficiency particulate filter; any scba w/full (ing 24)
rtecs #: 9999999zz
ingred name: ing 23: facepiece; any supp-air resp w/full facepiece;
contact nehc for a complete list of respirators .
rtecs #: 9999999zz