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Karl Fisher Reagent

NSN: 6810-00-084-9334 | Model: SK3-500
NSN Properties and Flags
NATO Stock Number
6810-00-084-9334
DEMIL
NO
General Description
Single solution, stabilized

Pricing and Availability

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NSN 6810-00-084-9334 Datasheet

Supply Class (FSC):
Chemicals
Cross Reference:
  • SK3-500
Cage Codes:
  • Fisher Scientific Company L.l.c. (CAGE 22527)
Identification:
HMIC

Y - Indicates information is in the hazardous materials information resource system (hmirs).

PMIC

A - Item does not contain precious metal.

CRITL

- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.

Freight Information:
  • NMFC:

    043940 - Chemicals noi

  • WCC:

    635 - Chemicals, other than drugs or sundries

  • SHC:

    9 - Other or no special handling required (sh)

  • ADC:

    A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.

  • ACC:

    C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp

  • TCC:

    R - Flammable liquids, un class 3 (flammable liquids label)

  • LTL:

    W - Rating variable

NSN Management Codes:
  • SOS
    Sms
  • AAC
    J
  • Quantity per pack
    1
  • Unit of Measure
    Bt
  • Shelf Life
    18 mo.
  • Classification Control
    U
  • MGMT_CTL
    Sf9---n
  • Repariability

Questions & Answers:

What are the historical prices recorded for this stock number?
Historical data shows pricing from $461.70 to $769.50..
Does NSN 6810-00-084-9334 have a shelf life?
No. There is no shelf life applicable for this NSN.
What NATO entities are users of this NSN?
Department Of The Air Force, and Department Of The Navy
What is the NIIN of NSN 6810-00-084-9334?
000849334 or 00-084-9334
Does NSN 6810-00-084-9334 require demilitarization?
Yes - ITAR Controlled
What is the most recent solicitation for NSN 6810-00-084-9334?
No solicitations for this NSN.
When was this national stock number assigned to the federal catalog?
Jan 01, 1963
MSDS

Material Safety

MSDS BCYDX SO-K-3 (KARL FISCHER REAGENT)

Hazards

Effects of overexposure: irritats skin;can cause cns depres;harmful if
swallowed,inhaled or absorbed through skin.

First Aid

First aid: danger! May be fatal if swallowed.Avoid prolonged breathing
of vapor.Use with adequate ventilation. Antidote: external - wash
with plenty of water; internal-give sodium thiosulfate.1 tbsp in a
glass of water. Or starch paste. See supp data

Chemical Properties

Hcc: f5
nrc/state lic num: not relevant
boiling pt: b.P. Text: 115-125c
vapor pres: unk
vapor density: unk
spec gravity: 1.16
evaporation rate & reference: >1(ether=1)
solubility in water: complete
appearance and odor: dark brown liquid;irritating pungent pyridine odor
percent volatiles by volume: 70

Reactivity

Stability indicator/materials to avoid: yes
none
stability condition to avoid: high temperatures,ignition sources
hazardous decomposition products: emits toxic vaps of iodine & sulfur
oxides when heated.

Proper Disposal

Waste disposal methods: wear rubber cloves,scba, protect clthg. Add
slowly to lg vol of agitated soln of na*2 co*2 & ca(oh)*2. Add this
soln to lg excess of h*20. Elim ign sources or keep in covd drs.

hdle & dispose lw all appl intern, fed, state & local regs.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: 2-methoxyethanol (egme) (sara iii)
cas: 109-86-4
rtecs #: kl5775000
= wt: 43.

osha pel: s, 25 ppm
acgih tlv: s, 5 ppm; 9192

ingred name: pyridine (sara iii)
cas: 110-86-1
rtecs #: ur8400000
= wt: 43.

osha pel: 5 ppm
acgih tlv: 5 ppm; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs

ingred name: iodine
cas: 7553-56-2
rtecs #: nn1575000
= wt: 13.8
osha pel: c 0.1 ppm
acgih tlv: c 0.1 ppm; 9192

ingred name: sulfur dioxide (sara iii)
cas: 7446-09-5
rtecs #: ws4550000
= wt: .1
osha pel: 5 ppm/5 stel
acgih tlv: 2 ppm/5 stel; 9293

MSDS BCYDY 184924 AQUAMETER REAGENT (KARL FISHER)

Hazards

Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: product is readily absorbed thorough
skin and can produce full set of symptoms.

effects of overexposure: headache,dizziness,nausea,breathing difficulty.

medical cond aggravated by exposure: none listed on msds.

First Aid

First aid: eyes: flush with water.Call physician. Skin: remove
contaminated clothing. Flush with water. Inhaled: remove from
exposure. Ingested: give 2 glasses of water and induce vomiting.

give milk or whites of eg g. Call physician.

Chemical Properties

Hcc: f5
nrc/state lic num: not relevant
boiling pt: =130.C, 266.F
vapor pres: 25mm @ 20c
vapor density: 2.6 (air)
spec gravity: 1.14
evaporation rate & reference:
solubility in water: soluble
appearance and odor: dark brown liquid,unpleasant odor (pyridine)
percent volatiles by volume: 87

Reactivity

Stability indicator/materials to avoid: no
water. Product reacts with water. (moist conditions).

stability condition to avoid: moisture,heat,flame,ignition sources.

hazardous decomposition products: iodine,vapors,sulfur dioxide,organic
vapors.

Proper Disposal

Waste disposal methods: dispose i/a/w federal,state,local regulations.

mfr suggests chemical landfill or chemical incinerator.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: pyridine (sara iii)
cas: 110-86-1
rtecs #: ur8400000
= wt: 13.

other rec limits: acgih stel 10 ppm
osha pel: 5 ppm
acgih tlv: 5 ppm; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs

ingred name: 2-methoxyethanol (egme) (sara iii)
cas: 109-86-4
rtecs #: kl5775000
= wt: 57.2
osha pel: s, 25 ppm
acgih tlv: s, 5 ppm; 9192

ingred name: sulfur dioxide (sara iii)
cas: 7446-09-5
rtecs #: ws4550000
= wt: 6.8
osha pel: 5 ppm/5 stel
acgih tlv: 2 ppm/5 stel; 9293

ingred name: iodine
cas: 7553-56-2
rtecs #: nn1575000
= wt: 12.6
osha pel: c 0.1 ppm
acgih tlv: c 0.1 ppm; 9192

ingred name: diethanolamine (sara iii)
cas: 111-42-2
rtecs #: kl2975000
= wt: 10.4
osha pel: 3 ppm
acgih tlv: 3 ppm; 9192
epa rpt qty: 1 lb
dot rpt qty: 1 lb

MSDS BCYDZ KARL FISCHER REAGENT

Hazards

Effects of overexposure: irritates eyes, skin, cenral nervous sys
depressant on long exposure.Headache,dizziness.Nausea.Burns

First Aid

First aid: skin; wash with soap and water; eye: flush thoroughly with
ater; inh: remove to fresh air; in: get medical assistance.

Chemical Properties

Hcc: f5
nrc/state lic num: not relevant
spec gravity: 1.14
solubility in water: soluble
appearance and odor: brown liquid. Pungent. Sickening odor.

percent volatiles by volume: 80

Reactivity

Stability indicator/materials to avoid: yes
water, acids.

stability condition to avoid: contact with moisture.

hazardous decomposition products: oxides of sulfur, nitrogen, and iodine
vapors.

Proper Disposal

Waste disposal methods: keep in covered drums,pending disposal. Handle &
dispose in full compliance with all applicable
international,federal,state, & local regulations.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: 2-methoxyethanol (egme) (sara iii)
cas: 109-86-4
rtecs #: kl5775000
fraction by wt: 37%
osha pel: s, 25 ppm
acgih tlv: s, 5 ppm; 9192

ingred name: pyridine (sara iii)
cas: 110-86-1
rtecs #: ur8400000
fraction by wt: 37%
osha pel: 5 ppm
acgih tlv: 5 ppm; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs

ingred name: iodine
cas: 7553-56-2
rtecs #: nn1575000
fraction by wt: 17%
osha pel: c 0.1 ppm
acgih tlv: c 0.1 ppm; 9192

ingred name: sulfur dioxide (sara iii)
cas: 7446-09-5
rtecs #: ws4550000
fraction by wt: 9%
osha pel: 5 ppm/5 stel
acgih tlv: 2 ppm/5 stel; 9293

MSDS BCYFB KARL FISCHER REAGENT, 9312

Hazards

Ld50 lc50 mixture: see ingredients
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation: nausea, vomiting,
headache, unconsciousness, coughing, difficult breathing.

skin/eyes: burns. Ingestion: gastrointestinal irritation,
convulsions. Chronic: 2-methoxyethanol appears on the navy listing
of occupational chemical reproductive hazards. Seek consultation
from appropriate health (efts of overexp)
explanation of carcinogenicity: not relevant
effects of overexposure: hlth haz: professionals concerning latest
hazard list information & safe handling & exposure information .

kidney damage, liver damage, damage to blood forming tissue.

medical cond aggravated by exposure: none identified.

First Aid

First aid: ingest: call md. Do not induce vomiting. If conscious, give
large amounts of water. Inhal: remove to fresh air. If not
breathing, give artf resp. If breathing difficult, give oxygen.

skin: immed flush skin w/plenty of water for @ least 15 minutes
while removing contamd clthg & shoes. Wash clthg before re-use.

eyes: immed flush w/plenty of water for at least 15 minutes.

Chemical Properties

Hcc: f4
spec gravity: 0.93
solubility in water: complete (100%)
appearance and odor: dark brown liquid; disagreeable odor.

percent volatiles by volume: 100

Reactivity

Stability indicator/materials to avoid: yes
water, strong oxidizing agents, strong bases, organic materials,
caustics.

stability condition to avoid: heat, flame, sources of ignition.

hazardous decomposition products: oxides of sulfur, oxides of nitrogen,
iodine.

Proper Disposal

Waste disposal methods: dispose in accordance with all applicable
federal, state and local environmental regulations. Epa hazardous
waste number: u196 (toxic waste).

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: ethanol, 2-methoxy; (2-methoxyethanol) (egme) (sara iii)
ld50: (oral, rat) 2460 mg/kg
cas: 109-86-4
rtecs #: kl5775000
fraction by wt: 25-35%
osha pel: 25 ppm, s
acgih tlv: 5 ppm, s

ingred name: iodine-sulfur dioxide complex
fraction by wt: 20-30%
osha pel: n/k
acgih tlv: n/k

ingred name: pyridine (sara iii) ld50: (oral, rat) 891 mg/kg
cas: 110-86-1
rtecs #: ur8400000
fraction by wt: 10-20%
osha pel: 5 ppm
acgih tlv: 5 ppm
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs

ingred name: methanol (sara iii) ld50: (oral, rat) 5628 mg/kg
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 25-40%
osha pel: 200 ppm; 250 stel, s
acgih tlv: 200 ppm; 250 stel, s
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs

MSDS BKNSJ SK3

Hazards

Ld50 lc50 mixture: ld50 (oral rat) is 891 mg/kg (pyridine)
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute-inhalation: sulfur dioxide is
corrosive/sensitizer.May cause chest pain,severe choking,violent
cough,unconsciousness,possibly death.Eye: irritant &
corrosive.Skin: corrosive,sensitizer,irritant,nar
cotic.Ingestion: narcotic,corrosive,nephrotoxin,kidney & liver
damage.Chronic-cns effects & toxic encephalopathy.

effects of
overexposure: headache,dizziness,drowsiness,fatigue,ataxia,weakness,
tremors,gi upset,anorexia,weight loss,personality
changes,cyanosis,abdominal & back pain,nausea,vomiting,increased
urinary frequency,nervousness,v ertigo,giddiness,facial
paralysis,anexity,mental confusion,unconsciousness.Death resulted
from lung & kidney injury.

medical cond aggravated by exposure: none specified by manufacturer.

First Aid

First aid: get immediate medical care.Inhalation: remove to fresh
air.Give cpr if needed.Eyes: immediately flush with plenty of water
for 15-20 minutes holding eyelids open.Skin: remove contaminated
clothing.Wash s kin with soap and
water.Ingestion: treatsymptomatically.If vomiting occurs,keep head
lower than hips to prevent aspiration.

Chemical Properties

Hcc: f5
nrc/state lic num: not relevant
boiling pt: =115.C, 239.F
melt/freeze pt: =-60.C, -76.F
decomp temp: decomp text: not provided
spec gravity: 1.16
evaporation rate & reference: > 1 (n-butyl acetate=1)
solubility in water: complete
appearance and odor: dark brown liquid

Reactivity

Stability indicator/materials to avoid: yes
strong oxidizing agents,caustics,acids,ccl4,chromic
trioxide,acetylene,aluminum,nh3,acrolein,brf5,cesium azide,plastics
stability condition to avoid: high heat, open flames
hazardous decomposition products: thermal decomposition include toxic
and hazardous iodine and iodine compounds,and oxides of
carbon,nitrogen and sulfur.

Proper Disposal

Waste disposal methods: disposal must be in accordance with standards
applicable to generators of hazardous waste, 40 cfr 262, epa
hazardous waste number d001. 100 pound cercla section 103
reportable quantity.Pyridine-regula tory level: 5 mg/l.Epa hazardous
waste number d038.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: 2-methoxyethanol (egme) (sara iii)
cas: 109-86-4
rtecs #: kl5775000
fraction by wt: 52.3%
other rec limits: none specified
osha pel: s, 25 ppm
acgih tlv: s, 5 ppm; 9192

ingred name: pyridine (sara iii)
cas: 110-86-1
rtecs #: ur8400000
fraction by wt: 26.5%
other rec limits: none specified
osha pel: 5 ppm
acgih tlv: 5 ppm; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs

ingred name: iodine
cas: 7553-56-2
rtecs #: nn1575000
fraction by wt: 13.7%
other rec limits: none specified
osha pel: c 0.1 ppm
acgih tlv: c 0.1 ppm; 9192

ingred name: sulfur dioxide (sara iii)
cas: 7446-09-5
rtecs #: ws4550000
fraction by wt: 7.4%
other rec limits: none specified
osha pel: 5 ppm/5 stel
acgih tlv: 2 ppm/5 stel; 9293

MSDS CBQCQ KARL FISHER REAGENT,SK 3-1,SK 3-4,SK 3-500,SO-K-3

Hazards

Ld50 lc50 mixture: ld50 (oral, rat) 891 mg/kg (pyridine)
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: liver, kidneys, cns.

acute- eye: may cause burns. Skin: causes burns. May be absorbed
therough skin in harmful amounts. Ingestion: causes gi burns, kidney
and liver damage. May cause cns d epression. Inhalation: may cause
respiratory tract irritation with burning pain in nose and thoat.

death may occur due to respiratory failure. Chronic- may cause skin
sensitization, dermatitis; liver, kidney, brain & cns damage.

explanation of carcinogenicity: this compound contains no ingredients at
concentrations of 0.1% or greater that are carcinogens or suspect
carcinogens.

effects of overexposure: irritation, burns, headache, dizziness, nausea,
vomiting, drowsiness, blurred vision, pain, burns, coughing,
wheezing, shortness of breath, collapse, unconsciousness, coma and
possible death.

medical cond aggravated by exposure: persons with pre-existing skin
disorders, eye problems or impaired liver, kidney, cns or
gastrointestinal function may be more susceptible to the effects of
this product.

First Aid

First aid: get medical help if symptoms persist. Inhaled: remove to fresh
air. Provide cpr/oxygen if needed. Eyes/skin: flush with water for
15 minutes. Hold eyelids open. Oral: do not induce vomiting. Call
physici an or poison control center asap. If conscious, drink 2- 4
glasses of milk or water. Never give anytihing by mouth to an
unconscious person. Note to physician: treat symptomatically &
supportively.

Chemical Properties

Hcc: f5
nrc/state lic num: not relevant
vapor density: na
spec gravity: 0.93
ph: na
viscosity: na
evaporation rate & reference: na
solubility in water: soluble
appearance and odor: dark brown liquid - disagreeable odor
percent volatiles by volume: na
corrosion rate: na

Reactivity

Stability indicator/materials to avoid: yes
water, organic materials, strong bases, strong acids, strong oxidizing
agents, halogens, metals & metal oxides, acid anhydrides,halogens &
interhalogens and oils.

stability condition to avoid: high temperatures, imcompatible materials,
ignition sources.

hazardous decomposition products: carbon monoxide, carbon dioxide,
oxides of nitrogen, oxides of sulfur, hydrogen iodide, iodine

Proper Disposal

Waste disposal methods: dispose of in accordance with all local, state
and federal regulations. Recommended procedure is by incineration.

Ingredients List

Ingred name: 2-methoxyethanol (methyl cellosolve) (sara 313)
cas: 109-86-4
rtecs #: kl5775000
fraction by wt: 52.25%
other rec limits: none recommended
osha pel: s, 25 ppm
acgih tlv: s, 5 ppm; 9596

ingred name: pyridine (sara 313) (cercla)
cas: 110-86-1
rtecs #: ur8400000
fraction by wt: 25.40%
other rec limits: none recommended
osha pel: 5 ppm
acgih tlv: 5 ppm; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs

ingred name: sulfur dioxide (sara 302)
cas: 7446-09-5
rtecs #: ws4550000
fraction by wt: 7.80%
other rec limits: none recommended
osha pel: 5 ppm
acgih tlv: 2 ppm/5 stel; 9596

ingred name: iodine
cas: 7553-56-2
rtecs #: nn1575000
fraction by wt: 14.55%
other rec limits: none recommended
osha pel: c 0.1 ppm
acgih tlv: c 0.1 ppm; 9596