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Sulfuric acid and oleum
Sulfuric acid; oleum
Chemicals-inorganic
Y - Indicates information is in the hazardous materials information resource system (hmirs).
PMICA - Item does not contain precious metal.
CRITL- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.
043940 - Chemicals noi
450 - Acids, liquid, corrosive
9 - Other or no special handling required (sh)
A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.
C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp
W - Rating variable
W - Corrosive materials, un class 8 (corrosive label)
Questions & Answers: |
|
| What are the historical prices recorded for this stock number? | |
| Historical data shows pricing from $202.30 to $337.16.. | |
| Does NSN 6810-00-146-7520 have a shelf life? | |
| No. There is no shelf life applicable for this NSN. | |
| What NATO entities are users of this NSN? | |
| Department Of The Army, Department Of The Air Force, National Security Agency, U.s. Marine Corps, Department Of The Navy, Food and Drug Administration, Bureau Of Mines, Bureau Of The Mint, National Aeronautics and Space Administration, Department Of Energy, General Services Administration, Tennessee Valley Authority, Veterans Administration, Brazil, Republic Of Korea, Greece, and Turkey | |
| What is the NIIN of NSN 6810-00-146-7520? | |
| 001467520 or 00-146-7520 | |
| Does NSN 6810-00-146-7520 require demilitarization? | |
| Yes - ITAR Controlled | |
| What is the most recent solicitation for NSN 6810-00-146-7520? | |
| No solicitations for this NSN. | |
| When was this national stock number assigned to the federal catalog? | |
| Jan 01, 1963 | |
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
effects of overexposure: skin: causes irritation/corrosive burns. Eyes:
irritation, corneal burns, conjunctivitis. Ingestion: irritation,
corrosive burns to mouth, throat, and stomach. Can be fatal if
swallowed. Inhalation: i rritation/burns to upper respiratory
system, lungs, etc.
First aid: inhalation: remove to fresh air. If not breathing, give cpr.
if breathing is difficult, give oxygen. See doctor. Eyes:
immediately flush with plenty of water for at least 15 minutes. See
doctor. Skin: wash/rinse with soap and water. Removecontaminated
clothing/shoes. See doctor. Ingestion: dilute with h2o/milk. Do not
induce vomiting. See doctor.
Hcc: c1
boiling pt: b.P. Text: 590f,310c
spec gravity: 1.842
solubility in water: complete
appearance and odor: oily, colorless to slight yellow, clear to turbid
liquid.
Stability indicator/materials to avoid: yes
oxidizers, flammable materials, reducing materials, carbides,
chlorates, sulfides
stability condition to avoid: heating >300c(572f): yields sulfur
trioxide gas, which is oxidizer/corrosive/toxic.
hazardous decomposition products: sulfur trioxide. May also yield
hydrogen gas with metal contact.
conditions to avoid polymerization: avoid allyl compounds and aldehydes:
undergoes polymerization with these.
Waste disposal methods: dilute w/water,neutralize w/alkali & flush to
sewer with plenty of water if permitted by applicable disposal
regulations. Neutralized waste may have to be disposed of by an
approved contractor. Dispos er must comply w/fed,state & local
disposal regs.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 99.0%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water; cas #7732-18-5
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 01.0%
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
effects of overexposure: eyes/skin: causes burns, defatting;
vapors/mists are extremely irritating/causes burns. Harmful if
swallowed.
First aid: inhalation: remove to fresh air. Give oxygen/cpr if needed.
get medical attention. Eyes/skin: flush with large amounts of water
for 15 minutes. Remove contaminated clothes/shoes. Wash clothes
before r euse. Get medical attention. Ingestion: give at once large
quantity of milk/water containing milk of magnesia. Do not induce
vomiting.
Hcc: c1
boiling pt: b.P. Text:
vapor pres: < 0.3
vapor density: 3.4
spec gravity: < 1.839
evaporation rate & reference: < 1 (butyl acetate = 1)
solubility in water: complete
appearance and odor: light brown, turbid, oily liquid. Odorless.
Stability indicator/materials to avoid: yes
oxidizers, strong alkalies, lithium, sodium, potassium, chlorates, etc.
stability condition to avoid: high heat
hazardous decomposition products: oxides of sulfur, hydrogen gas.
Waste disposal methods: keep in covered drums,pending disposal. Handle &
dispose in full compliance with all applicable
international,federal,state, & local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt:
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: oral ld50 (rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: inhalation- irritation of
lungs, burns of mucous membranes. Eyes- irritation, burns. Skin-
irritation, burns. Ingestion: severe abdonminal distress, burns of
mouth and esophagus. Nervous system damage. Ph imbalance. Chronic:
chronicbronchitis, pulmonary edema, dermatitis, ulcerations of
skin, lacrymation.
explanation of carcinogenicity: none
effects of overexposure: inhalation: coughing, burning sensation in
chest, tightness in chest. Eyes: irritation, redness, burns. Skin:
burns, redness, itching, blistering. Ingestion: severe stomach
pain, burns around mouth, n ausea, vomiting.
medical cond aggravated by exposure: pre-existing skin and repiratory
disorders.
First aid: eyes: flush with water for at least 15 minutes. See a doctor.
skin: blot if practical, then flush with water. Treat burns. See
doctor. Ingestion: do not induce vomiting. Give water, milk, or
milk of m agnesia. Get immediate medical attention.
Hcc: c1
boiling pt: b.P. Text: 559f,293c
melt/freeze pt: m.P/f.P text: 50.0f,10.0c
decomp temp: decomp text: 644f,340c
vapor pres: < 0.001
vapor density: 3.4
spec gravity: 1.84
ph: < 3
solubility in water: complete
appearance and odor: clear, colorless, odorless liquid.
Stability indicator/materials to avoid: yes
combustible materials,organic materials,metals, reacts violently with
water causing release of heat.
stability condition to avoid: none specified by manufacturer.
hazardous decomposition products: fumes of sulfur oxide
Waste disposal methods: contact your local environmental manager.
dispose of in accordance with local, state, and federal
regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: >95%
other rec limits: none specified
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: product is corrosive to eyes, skin,
and respiratory tract. Manufacturer lists no long term or chronic
effects beyond the corrosivity.
effects of overexposure: severe burns, erosion of teeth, lung damage.
medical cond aggravated by exposure: none
First aid: eyes: immediately flush with water for at least 15 minutes.
skin: flush with water and remove contaminated clothing.
inhalation: remove to fresh air, give oxygen or cpr if needed. Call
a physician. In gestion: do not induce vomiting. Give large amounts
of water and at least one ounce of milk of magnesia diluted with an
equal amount of water. Call a physician.
Hcc: c1
boiling pt: b.P. Text: 626f,330c
vapor pres: 1
vapor density: 3.40
spec gravity: 1.84
solubility in water: complete
appearance and odor: clear, colorless, oily liquid. No odor.
Stability indicator/materials to avoid: yes
caustic compounds, oxidizing or reducing materials, acetic or
chlorosulfonic acids.
stability condition to avoid: moisture, heat
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: dissolve in water and flush down drain in
accordance with alll federal, state, and local laws and
regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 100%
other rec limits: 1 mg/cum
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
explanation of carcinogenicity: none of the ingredients in this product
is listed as a cacinogen by ntp, iarc, or osha.
effects of overexposure: eyes: severe damage/blindness very rapidly.
skin: burns, possible deep ulcerations. Inhalation: fumes cause
damage to the nasal/respiratory passages. Ingestion: severe damage
to mucous membranes/deep tissue.
First aid: skin: immediately flush with water for 15 minutes. Discard
contaminated clothing. Get medical help. Eyes: immediately flush
with water for 15 minutes lifting upper/lower lids until medical
help is obt ained. Call doctor. Dont use chemical antidote.
ingestion: dont induce vomitng. Give water/milk of magnesia. Keep
person warm and quiet. Inhalation: move to fresh air. Get immediate
medical attention.
Hcc: c1
boiling pt: b.P. Text: 554f,290c
spec gravity: 1.840
evaporation rate & reference: < 1 (ether = 1)
solubility in water: complete
appearance and odor: dense, oily liquid. Colorless to dark brown color.
Stability indicator/materials to avoid: yes
strong alkalies, oxidizers, flammable/combustible material, powdered
metals.
stability condition to avoid: high heat
hazardous decomposition products: acid fumes, sulfur oxides, hydrogen
gas
Waste disposal methods: small: flush down drain w/water.Large
spill: collect & add slowly to large vol of agitd soln of soda
ash/slaked lime.Add neutralized soln to excess running water iaw
local regulations.Review local,state /fed regs. To determine
disposal procedure.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: >95%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
effects of overexposure: causes severe burns, conjunctivitis, corneal
necrosis, ulceration, irritation of nose and throat, edema.
First aid: irrigate eyes with water. Wash contaminated areas of body
with soap and water. Stomach wash if swallowed.
Hcc: c1
boiling pt: b.P. Text: 554f,290c
spec gravity: 1.84
solubility in water: appreciable
appearance and odor: clear, colorless, odorless, oily liquid.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
carbides, chlorates, fulminates, nitrates, picrates, powdered metals.
stability condition to avoid: high heat
hazardous decomposition products: oxides of sulfur, hydrogen gas
Waste disposal methods: add slowly to large amount of solution of soda
ash and slaked lime by stirring. Discharge solution with large
amount of water into approved disposal area.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93.0%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: corrosive to all body tissues.
irritation or burns to eyes and skin, irritation of nose, throat,
and lungs, stomach burns. Chronic: pain or burns of skin. Eyes and
lung damage, severe burns of mouth, blurred vision, damage to
teeth.
medical cond aggravated by exposure: pre-existing conditions may be
worsened.
First aid: eyes: flush with plenty of water and seek medical attention
at once. Skin: wash thoroughly with plenty of water and call a
physician. Inhalation: remove to fresh air. Call a physician.
ingestion: do n ot induce vomiting. Give large amounts of water or
milk. Call a physician immediately.
Hcc: c1
boiling pt: b.P. Text: 590f,310c
melt/freeze pt: m.P/f.P text: 6f,-14c
vapor pres: 1.0
vapor density: < 0.3
spec gravity: 1.84
solubility in water: complete
appearance and odor: colorless, oily liquid, odorless.
Stability indicator/materials to avoid: yes
carbonates, cyanides, sulfides, halogens, organic materials. Reactive
substances.
stability condition to avoid: water, steam
hazardous decomposition products: toxic fumes, hydrogen cyanide,
hydrogen sulfide, hydrogen gas, oxides of sulfur.
Waste disposal methods: dispose of collected material in accordance with
local, state, and federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 96.0%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: produces rapid destruction of
tissues and severe burns on contact with bodily tissues of any
kind. Chronic: tissue damage, injury to lungs and gastrointestial
tract.
effects of overexposure: will cause severe burns to skin or eyes.
inhalation of mist can injure lungs. Ingestion causes severe
injury.
medical cond aggravated by exposure: pre-existing conditions may be
worsened.
First aid: speed in removing acid is of primary importance. Immediately
flush skin or eyes with plenty of water for at least 15 minutes.
get medical attention. Inhalation: remove to uncontaminated area.
ingestio n: drink large amounts of water. Get medical attention
immediately.
Hcc: c1
boiling pt: b.P. Text: 526f,274c
spec gravity: 1.835
evaporation rate & reference: < 1 (ether = 1)
solubility in water: complete
appearance and odor: slightly viscous, clear to light yellow liquid.
Stability indicator/materials to avoid: yes
combustible materials, nitrates, carbides, chlorates, metallic powder.
stability condition to avoid: high heat
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: flush away to nearest sewer with lots of water
if local regulations permit. In some cases waste may have to be
hauled away by a disposal contractor to avoid local polution
standards.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt:
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: >2.0%
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
effects of overexposure: rapid destruction of tissues and severe burns
on contact.
First aid: skin: remove contaminated clothing. Use large amounts of
water. Eyes: irrigate with large amounts of water forat least 15
minutes. Seek medical attention quickly.
Hcc: c1
boiling pt: b.P. Text: 538f,281c
vapor density: 2.8
spec gravity: 1.8354
solubility in water: complete
appearance and odor: clear, colorless, heavy liquid with a pungent odor.
Stability indicator/materials to avoid: yes
combustibles, organics, oxidizers, plate and powdered metals
stability condition to avoid: high heat
hazardous decomposition products: hydrogen gas, oxides of sulfur,
hydrogen sulfide
Waste disposal methods: do not allow to come in contact with sulfide
wastes, such as in sewers. Neutralize with soda ash or other
alkaline material, add water to make slurry, and wash down drain
with excess water.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
effects of overexposure: severe burns to eyes or skin. Inhalation
injurious to lungs.Ingestion - severe injury or death
First aid: for contact flush skin or eyes with plenty of water for at
least 15 minutes. For eyes or skin burns, get immediate medical
attention.
Hcc: c1
boiling pt: b.P. Text: 233f - 625f
spec gravity: 1.8473
solubility in water: complete
appearance and odor: slightly viscous, clear to cloudy liquid.
Stability indicator/materials to avoid: yes
avoid contct with combustible materials, nitrates, carbides, metals
stability condition to avoid: high heat
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: neutralize acid with alkali and flush to sewer
with plenty of water if permitted by local and state regulations.
in some cases waste may have to be hauled away by a disposal
contractor.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 98%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: ld50 oral rat = 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
effects of overexposure: contact may cause permanent damage to eyes,
severe burns and ulceration of skin. Inhalation causes upper
respiratory irritation and possible pulmonary edema. Ingestion
causes severe injuries.
medical cond aggravated by exposure: respiratory conditions will be
aggravated by breathing acid mists.
First aid: eyes and skin: flush with plenty of water. See doctor
immediately. Remove contaminated clothing and shoes. Inhalation:
remove to fresh air. Give oxygen/cpr if needed. See doctor.
ingestion: give milk or water, followed by 2 ounces of milk of
magnesia (no carbonates). See doctor immediately.
Hcc: c1
boiling pt: b.P. Text: 536f,280c
melt/freeze pt: m.P/f.P text: 37f,3c
vapor pres: 0.001
vapor density: 3.4
spec gravity: 1.8
solubility in water: complete
appearance and odor: colorless to dark brown, oily liquid.
Stability indicator/materials to avoid: yes
bases, oxidizers, reducing agents, metal powders, and organic material.
stability condition to avoid: heat.
hazardous decomposition products: sulfur dioxide, sulfur trioxide,
hydrogen gas.
Waste disposal methods: consult your local environmental officer.
dispose of in accordance with federal, state, and local
environmental regualtions.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 98%
other rec limits: none stated
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 2%
Ld50 lc50 mixture: ld50 (oral rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: severe irritation of eyes,
skin, respiratory, and gastrointestinal tracts; cns effects like
headache, dizziness, nausea, and vomiting. Redness or burns of eyes
and skin possible. Chronic: damag e to lungs, eyes, erosion of
teeth. Maycause death.
explanation of carcinogenicity: none of the ingredients in this product
are listed as a carcinogen by ntp, iarc, or osha.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the eyes, skin, or
respiratory tract may be at increased risk from exposure.
First aid: inhalation: get fresh air. Resuscitate if not breathing. Get
medical attention. Eyes: immediately flush with plenty of water for
15 minutes holding eyelids open. Get medical attention. Skin:
remove co ntaminated clothing. Wash with soap andwater. If
irritation persists, get medical advice. Ingestion: do not induce
vomiting. Give nothing by mouth if unconscious. Get immediate
medical attention.
Hcc: c1
boiling pt: b.P. Text: 554f,290c
vapor pres: 0.01
vapor density: 3.4
spec gravity: 1.84
evaporation rate & reference: < 1.0 (n-butyl acetate)
solubility in water: complete
appearance and odor: clear, colorless to light yellow, odorless, oily
liquid.
Stability indicator/materials to avoid: yes
strong reducing agents, strong bases, organic materials, combustible
material.
stability condition to avoid: high temperatures
hazardous decomposition products: oxides of sulfur, hydrogen gas
Waste disposal methods: consult local authorities. Disposal must be made
in accordance with all applicable federal, state, and local laws
and regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 73-98%
other rec limits: none specified
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
other rec limits: none specified
Ld50 lc50 mixture: oral ld50 (rat): 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eyes: severe damage, blindness, burns,
irritation. Skin: pain, burns, vesiculation, severe irritation.
inhalation: nose and throat irritation, headache, cough,
respiratory rate increase, chest tightne ss, cyanosis, pulmonary
edema. Ingestion: severe burning in mouth, throat, and abdomen.
explanation of carcinogenicity: none
effects of overexposure: eyes: lacrimation , conjunctivitis. Skin:
dermatitis. Inhalation: hypotension, chronic tracheo-bronchitis,
emphysema, bronchial pneumonia, teeth discoloration and erosion.
ingestion: diarrhea of dark, precipitated blood, asphyxia, throat
swelling, vomiting, gastrointestinal problems, esophagus and
stomach perforation.
medical cond aggravated by exposure: respiratory ailments
First aid: eyes: flush with plenty of water. In case of burns, apply
sterile bandages loosely without medication. Skin: wash with soap
and water. In case of chemical burns, cover with sterile, dry
dressing. Band age securely. Inhalation: remove to fresh air.
ingestion: if victim is conscious, give plenty of water to dilute
acid. Do not induce vomiting. Get medical attention in all cases.
Hcc: c1
boiling pt: b.P. Text: 536f,280c
melt/freeze pt: m.P/f.P text: 37.0f,2.8c
vapor density: 3.4
spec gravity: 1.8
solubility in water: complete
appearance and odor: colorless to dark brown, oily liquid.
Stability indicator/materials to avoid: yes
water, organic materials, acids, alcohols, bases, metals, bromates,
chlorine, nitric acid, sodium, potassium, acetone.
stability condition to avoid: high heat
hazardous decomposition products: toxic fumes of sulfur oxides,
poisonous gases, hydrogen sulfide, hydrogen gas
Waste disposal methods: dispose of in accordance with all local, state,
and federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 98%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water, h2o
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 2%
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute - inhalation: mist causes
respiratory tract irritation, coughing, destruction of mucous
membranes, pulmonary edema. Eyes and skin: will produce severe
burns and injury. Oral: will damage tissues on contact. May cause
severe injury ordeath. Chronic - unknown.
effects of overexposure: mist causes respiratory tract irritation,
coughing, destruction of mucous membranes, pulmonary edema. Will
produce severe eye and skin burns and injury. Orally will damage
tissues on contact. May caus e severe injury or death.
medical cond aggravated by exposure: persons with pre-existing skin
disorders or eye problems or impaired respiratory function may be
more susceptible to the effects of the substance.
First aid: get medical attention immediately. Eyes and skin: immediately
flush with water for at least 15 minutes. Hold eyelids open.
inhalation: remove to fresh air and provide oxygen/cpr if needed.
ingestion: do not induce vomiting. Drink 1 to 2 glasses of water.
call a physician immediately.
Hcc: c2
boiling pt: =276.1c, 529.F
melt/freeze pt: =-28.9c, -20.F
vapor pres:
vapor density: 3.4
spec gravity: 1.8357
ph: < 1
solubility in water: complete
appearance and odor: oily, clear to turbid liquid. Practically no odor.
percent volatiles by volume: 0
Stability indicator/materials to avoid: yes
combustible materials, organic materials, metals, water, nitrates,
carbides, chlorates
stability condition to avoid: high heat
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: small quantities: add to water, adjust ph to
neutral, separate solids and package them for hazardous waste
disposal. Flush the aqueous solution down the drain. Observe all
local, state, and federal re gulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93 - 98%
other rec limits: not specified
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 8990
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 2 - 7%
other rec limits: none specified
Ld50 lc50 mixture: rat,lc50: 510mg/m3/2h;ld50: 2140mg/kgrtecs
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eye, skin, respiratory &
gi tracts. Corrosive! Causes severe eyes & skin burns. Vapor
extremely irritating to respiratory tract. Contact with eyes may
result in blindness. Swallowing may be fatal. Inhalation may
damage respiratory tract. Chronic exposure may cause dental
erosion, dermatitis, bronchitis.
explanation of carcinogenicity: none
effects of overexposure: severe eye, skin, respiratory and
gastrointestinal tracts irritation and burning, visual impairment,
dental erosion, nasal secretion, sneezing, shallow and rapid
breathing, a burning/tickling sensatio n followed by cough,
unconsciousness, possible charring of skin, mouth, throat and
esophagus pain, blindness
medical cond aggravated by exposure: open wounds and sores, respiratory
ailments such as emphysemia and bronchitis
First aid: get medical attention immediately. Eye/skin: immediately flush
with water for 15-20 minutes. Hold eyelids open. Continue rinsing
with normal saline until ph=7. Inhaled: remove to fresh air &
provide oxy gen/cpr if needed. Oral: do not induce vomiting. If
conscious, drink large amount of water/milk. Ingested acid must be
diluted about 100 folds. If vomiting occurs, keep head below hips.
Hcc: c1
nrc/state lic num: not relevant
boiling pt: b.P. Text: 644f,340c
melt/freeze pt: m.P/f.P text: -35f to 23f
decomp temp: decomp text: unknown.
vapor pres: unknown.
spec gravity: 1.82 - 1.84
ph: 1 (1%)
evaporation rate & reference: unknown.
solubility in water: complete
appearance and odor: colorless to yellow, oily, odorless liquid.
Stability indicator/materials to avoid: yes
acetaldehyde, alcohol, strong bases, chlorates, cyclopentadiene,
metals, nitromethane, organics, strong oxidizing agents
stability condition to avoid: high heat, moisture/water
hazardous decomposition products: toxic oxides of sulfur
Waste disposal methods: dispose of spilled, neutralized, or waste
product, contaminated soil, and other materials in accordance with
all local, state, and federal regulations. Epa hazardous waste
number d002. Reportable quan tity (rq): 1000 lbs.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93 - 99%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 1 - 7%
other rec limits: none recommended
Ld50 lc50 mixture: ld50 (oral, rat) is 2140 mg/kg (rtecs)
routes of entry: inhalation: no skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute & chronic- serious burns to all
tissues contacted. Exceedingly dangerous to eye. A single over
exposure to mists may lead to pulmonary edema. Long exposures are
claimed to lead to respiratory in fections, emphysema & digestive
disturbances. May cause dental errosion, bronchitis & death.
explanation of carcinogenicity: product contains no ingredients
currently classified as carcinogenic by ntp, iarc or osha.
effects of overexposure: eye, skin burns, dental errosion, pulmonary
edema, bronchitic symptoms, emphysema, death
medical cond aggravated by exposure: skin irritation may be aggravated
in persons with existing skin lesion. May aggravate pre-existing
eye, teeth and pulmonary diseases.
First aid: speed is essential. Start first aid & get medical care at
once. Eyes/skin: flush with water for at least 15 minutes. Hold
eyelids open. Inhaled: remove to fresh air. Provide cpr/oxygen if
needed. Oral: d o not induce vomiting. If conscious, drink milk or
water. Never give anything by mouth to an unconscious person.
Hcc: c1
boiling pt: b.P. Text: 554f,290c
melt/freeze pt: m.P/f.P text: 51.0f,10.6c
decomp temp: decomp text: 644f,340c
vapor pres: 1 @ 295f
spec gravity: 1.834
viscosity: not known
solubility in water: miscible->great heat
appearance and odor: colorless to dark brown liquid - odorless
Stability indicator/materials to avoid: yes
organics, chlorates, carbides, picrates, metals, strong bases
stability condition to avoid: water, heat, sparks, flame (hydrogen gas
may be present) and steam
hazardous decomposition products: sulfur oxides, hydrogen. May release
corrosive or highly irritating fumes and smoke.
Waste disposal methods: dispose of in accordance with all applicable
local, state and federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9293
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: oral ld50 (rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: inhalation- irritation of
lungs, burns of mucous membranes. Eyes- irritation, burns. Skin-
irritation, burns. Ingestion: severe abdonminal distress, burns of
mouth and esophagus. Nervous system damage. Ph imbalance. Chronic:
chronicbronchitis, pulmonary edema, dermatitis, ulcerations of
skin, lacrymation.
explanation of carcinogenicity: none
effects of overexposure: inhalation: coughing, burning sensation in
chest, tightness in chest. Eyes: irritation, redness, burns. Skin:
burns, redness, itching, blistering. Ingestion: severe stomach
pain, burns around mouth, n ausea, vomiting.
medical cond aggravated by exposure: pre-existing skin and repiratory
disorders.
First aid: eye: flush with water 15 minutes, see a doctor. Skin: blot if
practical, then flush with water. Treat burns. See doctor.
ingestion: do not induce vomiting. Give water, milk or milk of
magnesia.Get imme diate medical attention.
Hcc: c1
boiling pt: b.P. Text: 626f,330c
melt/freeze pt: m.P/f.P text: 50.0f,10.0c
decomp temp: decomp text: 644f,340c
vapor pres:
vapor density: 3.4(air=1)
spec gravity: 1.84 (water=1)
ph:
solubility in water: complete
appearance and odor: clear colorless, odorless oily liquid
Stability indicator/materials to avoid: yes
combustible materials,organic materials,metals, reacts violently with
water causing release of heat.
stability condition to avoid: contact with combustible materials, water,
metals, organic materials.
hazardous decomposition products: fumes of sulfur trioxide and water.
Waste disposal methods: contact local environmental manager. Dispose of
in accordance with local, state and federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: >95%
other rec limits: none specified
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9293
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt:
other rec limits: none recommended
Ld50 lc50 mixture: ld50, rat (oral) 2140 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: unknown iarc: unknown osha: no
health hazards acute and chronic: inhalation produces damaging effects
on mucous membranes & upper respiratory tract may cause lung edema.
swallowing may cause severe burns of the mouth,throat,stomach,
leading to death.Can cause sore throat,vomiting,diarrhea. Skin
contact: corrosive. Symptons of redness,pain, & severe burns can
occur.
effects of overexposure: liquid and mist cause severe burns to all body
tissue. May be fatal if swallowed. Inhalation may cause lung
damage.
medical cond aggravated by exposure: persons with pre-existing skin
disorders or eye problems or impaired respiratory function may be
more susceptible to the effects of the substance.
First aid: inhalation: remove to fresh air. If difficulty breathing,
give oxygen. Call physician. Ingestion: do not induce vomiting.
give large quantities water/milk. Call physician immedediately.
skin: flush sk in with plenty of water for at least 15minutes.
remove cloths/shoes/call a physician. Eyes: flush with water 15
minutes, lifting lower/upper eyelids occasionally. Get medical
attention immediately.
Hcc: c1
boiling pt: b.P. Text: 590f,310c
melt/freeze pt: m.P/f.P text: 6f,-14c
vapor pres: 1@146 c
vapor density:
spec gravity: 1.84
evaporation rate & reference: no information found
solubility in water: complete
appearance and odor: colorless, oily liquid
Stability indicator/materials to avoid: yes
water,bases,organic material, halogens, metal acetylides,oxides and
hydrides, strong oxidizing & reducing agents & other
stability condition to avoid: none specified by manufacturer.
hazardous decomposition products: toxic fumes of oxides of sulfur. Will
react with water or steam to produce toxic and corrosive fumes.
Waste disposal methods: neutralized waste may be containerized and
disposed in a rcra approved waste disposal facility.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 96%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: ld50 oral,rat= 2140mg/kg.
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: highly corrosive.Eye/skin: can result
in severe deep painful burns.Possible blindness.Extensive burns may
result in shock & collapse. Ingest: can result in severe burns of
mouth & throat w/possible perf oration of esophagus or stomach.Can
be fatal.Inhal: fumes can cause irrit or burns to nose/throat/mouth.
explanation of carcinogenicity: per msds: not listed as carcinogenic by
ntp/iarc/osha.
effects of overexposure: highly corrosive.Severe deep painful
burns.Blindness.Shock & collapse.Severe burns of mouth/throat
w/possible perforation of esophagus/stomach.Fatal.Nose/throat/mouth
burns/irrit.Pharynx/abdomen/muc m emb/corneal burns.Gi tract
corro,teeth errosion,nau,vomit of blood.Erroded
tissue.Conj,photophobia.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: inhal: remove to fresh air.Observe for possible delayed
reaction.Breath diffi give oxy.Breath stop give art
resp.Ingest: give lg quant of water or milk if consc.Do not induce
vomit.Eye: immed flush w/lg quant of water for 15mins opening
eyelids.Do not use chem antidotes.Speed is essential.Skin: immed
flush w/lg quant of wter for 15mins while removing contamin
cloth.In all cases get immed med attn.
Hcc: c1
boiling pt: b.P. Text: 625f,329c
vapor pres:
vapor density: approx 3.4
spec gravity: 1.842
solubility in water: soluble
appearance and odor: oily,colorless to slgihtly yellow, clear, odorless
liquid
percent volatiles by volume: 0 @70f
Stability indicator/materials to avoid: yes
acids,acids anhydrides,alkalis,aldehydes,unsat
org,amines,carbides,glycols,hydrated salts,org
oxides,oximes,(supplement)
stability condition to avoid: none specified by manufacturer. However
keep away from heat/sparks/flames. Avoid water contact.
hazardous decomposition products: may form toxic matls: h2so4
mists,so3,gas & other oxides of sulfur.
Waste disposal methods: rq=1000lbs/45kg(approx 65gals). Comply with all
local, state and federal regulations. Aquatic
toxicity: 24.5ppm/24hr/bluegill/lethal/fresh water.
lc50/prawn/42.5ppm/48hr/salt water.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 95-97%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation of vapors causes severe
irritation or burns of the respiratory system, pulmonary edema, or
lung inflammation. Eye contact causes severe damage and possible
blindness. Skin contact causes bu rns and possible deep ulceration.
ingestion causes severe burns to mouth, throat, and stomach.
explanation of carcinogenicity: this chemical is not listed by iarc,
ntp, or osha as a carcinogen.
effects of overexposure: severe irritation or burns to eyes, nose and
throat. Pulmonary edema, bronical emphysema, conjunctivitis,
stomatitis, dental erosion, nausea and vomiting.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the respiratory tract may
be at increased risk from exposure.
First aid: inhalation: remove to fresh air. Resuscitate if not breathing.
get medical attention. Eyes: immediately flush with plenty of water
for 15 minutes holding eyelids open. Get prompt medical attention.
skin : remove contaminated clothing. Wash with plenty of water for
15 minutes. Get medical advice. ingestion: do not induce vomiting.
give nothing by mouth if unconscious. Get immediate medical
attention.
Hcc: c1
boiling pt: b.P. Text: 529f,276c
vapor pres: nil
spec gravity: 1.83
ph:
evaporation rate & reference:
solubility in water: complete
appearance and odor: colorless liquid.
Stability indicator/materials to avoid: yes
strong oxidizing agents
stability condition to avoid: high heat, open flames and other sources
of ignition
hazardous decomposition products: oxides of sulfur, and hydrogen
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state and local environmental regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: oral ld50 (rat): 2140 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: corrosive to eyes and skin on contact.
liquid or spray mist may produce tissue damage particularly on
mucous membranes of eyes, mouth, respiratory tract. Inhalation may
cause severe irritation of resp iratory tract. Can be fatal if
inhaled or ingested. severe overexposure can result in death.
explanation of carcinogenicity: this compound contains no ingredients at
concentrations of 0.1% or greater that are carcinogens or suspect
carcinogens.
effects of overexposure: skin irritation, eye irritation, tissue damage,
coughing, choking, shortness of breath, eye
redness/watering/itching, skin
itching/scaling/reddening/blistering, death.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: get medical attention immediately. Eye/skin: remove contacts.
immediately flush with water for 15-20 minutes. Hold eyelids open.
continue rinsing with normal saline until ph=7. Inhaled: remove to
fresh air & provide oxygen/artificial respiration. If
needed.Ingested: do not induce vomiting. If conscious, drink large
amount of water/milk. Ingested acid must be diluted about 100
folds. If vomiting occu rs, keep head below hips.
Hcc: c1
boiling pt: =290.C, 554.F
melt/freeze pt: =10.5c, 50.9f
vapor pres: 0.01
vapor density: 3.4
spec gravity: 1.84
ph: 1 (1%)
evaporation rate & reference: not given
solubility in water: complete
appearance and odor: thick oily colorless liquid, slight sulfurous odor
Stability indicator/materials to avoid: yes
highly reactive: metals, alkalis, moisture; slightly reactive to
reactive: organic materials, acids; very slightly to slightly
reactive: oxidizing agents, reducing agents, combustible materials
stability condition to avoid: high heat, moisture/water
hazardous decomposition products: toxic oxides of sulfur
Waste disposal methods: per msds: recycle to process, if possible.
dla-hmis: dispose of spilled, neutralized, or waste product,
contaminated soil, and other materials in accordance with all
local, state, and federal regulati ons. Epa hazardous waste number
d002. Reportable quantity (rq): 1000 lbs.
Ingred name: sulfuric acid (sara 302/313) (cercla)
cas: 7664-93-9
rtecs #: ws5600000
= wt: 100.
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3/3 stel; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: oral, rat ld50 = 2140 mg/kg
reports of carcinogenicity: ntp: no iarc: yes osha: yes
health hazards acute and chronic: target organs: none. Eye: cause severe
eye burns. May cause irreversible eye injury. Skin: causes skin
burns. Ingestion: may cause severe and permanent damage to the
digestive tract. Causes gastrointe stinal burns. Inhalation:
harmful if inhaled. May cause severe irritation of the respiratory
tract with sore throat, coughing, shortness of breath and delayed
lung edema. Causes chemical burns to the respiratory tract.
chronic: prolonged or repeated inhalation may cause nosebleeds,
nasal congestion, erosion of teeth, perforation of the nsal septum,
chest pain and bronchitis. Prolonged or repeated eye contact may
cause conjunctivitis.
explanation of carcinogenicity: sulfuric acid: osha: select carcinogen;
iarc: group 1 carcinogen.
effects of overexposure: eye: severe burns. Skin: severe
burns.Ingestion: gastrointestinal tract burns. Inhalation: sore
throat, coughing, shortness of breath, delayed lung edema.
medical cond aggravated by exposure: no data provided by responsible
party.
First aid: eyes: flush with water for at least 15 minutes, lift lids.
get medical aid immediately. Do not allow victim to rub eyes or
keep eyes closed. Skin: get medical aid immediately. Flush with
plenty of soa p & water for at least 15 minutes while removing
clothes & shoes. Speedy action is critical! Ingestion: do not
induce vomiting! If victim is conscious & alert, give 2-4 cups of
milk or water. Never gi ve anything by mouth to one who is
unconscious. Get medical aid immediately. Inhalation: get medical
aid immediately.Remove from exposure to fresh air. If not
breathing, give artificial respiration. I f breathing difficult,
give oxygen.
Hcc: c1
boiling pt: =290.C, 554.F
melt/freeze pt: m.P/f.P text: no data available
decomp temp: =340.C, 644.F
vapor pres: 1 mm hg
spec gravity: 1.415 (52%) 1.836 (98%)
viscosity: no data available
evaporation rate & reference: no data available
solubility in water: soluble
appearance and odor: clear oily liquid. Odorless.
Stability indicator/materials to avoid: yes
acetic anhydride, acetone cyanhydrin, acetone + nitric acid, acetone +
potassium dichromate, acetonitrile + sulfur trioxide, acrolein,
acrylonitrile, alcohols + hydrogen peroxide, allyl alcohol,?..See
supplemental?.
stability condition to avoid: incompatible materials, contact with
water, metals, excess heat, combustible materials, organic
materials, amines, bases.
hazardous decomposition products: oxides of sulfur
conditions to avoid polymerization: has not been reported.
Waste disposal methods: dispose of in a manner consistent with federal,
state & local regulations. Rcra d-series maximum concentration of
contaminants: not listed. Rcra d-series chronic toxicity reference
levels: not listed. rcra f-series: not listed. Rcra p-series: not
listed. Rcra u-series: not listed. Not listed as a ma terial banned
from land disposal according to rcra
Ingred name: sulfuric acid
cas: 7664-93-9
rtecs #: ws5600000
minumum % wt: 52.
maxumum % wt: 98.
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3
acgih stel: 3 mg/m3
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
minumum % wt: 2.
maxumum % wt: 48.
Ld50 lc50 mixture: oral-rat ld50: 2140 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: unknown iarc: yes
health hazards acute and chronic: acute: may be fatal if swallowed.
harmful if inhaled or absorbed through skin. Mateial is extremely
destructive to tissue of the mucous membranes and upper respiratory
tract, eyes, and skin. Inhalatio n may be fatal as a result of
spasm, inflammation and edema of the larynx and bronchi, chemical
pneumonitis, and pulmonary edema. Chronic effects: carcinogen.
explanation of carcinogenicity: the international agency for research on
cancer (iarc) has detemined that occupational exposure to
strong-inorganic-acid mists containing sulfuric acid is
carcinogenic to humans (group 1).
effects of overexposure: symptoms of exposure may include burning
sensation, coughing, wheezing, laryngitis, shortness of breath,
headache, nausea, vomiting, tissue destruction, inflammation and
edema of the larynx and bronch i, chemical pneumonitis, pulmonary
edema.
First aid: in case of contact, immediately flush eyes or skin with
copious amounts of water for at least 15 minutes while removing
contaminated clothing and shoes. Assure adequate flushing of the
eyes by separat ing the eyelids with fingers. If inhaled, remove to
fresh air. If not breathing give artificial respiration. If
breathing is difficult give oxygen. If swallowed, wash out mouth
with water provided per son is conscious. Call a physician
immediately. Wash contaminated clothing before reuse. Discard
contaminated shoes.
Hcc: c1
vapor pres: 1mm @145.8c
vapor density:
spec gravity: 1.840
appearance and odor: viscous colorless liquid.
===================== regulatory information =====================
sara title iii information: this product is subject to sara section 313
reporting requirements
Bases, halides, organic materials, finely powdered metals, protect from
moisture.
stability condition to avoid: do not allow water to enter container
because of violent reaction.
hazardous decomposition products: hazardous combustion or decomposition
products: sulfur oxides
Waste disposal methods: observe all federal, state and local
environmental regulations. Small amounts: cautiously add to large
stirred excess of water (heat and fumes can be controlled by rate
of addition). Adjust ph to neut ral, separate insoluble solids or
liquids and package for disposal. Flush aqueous solution down dra
in with plenty of water.
Ingred name: sulfuric acid
cas: 7664-93-9
rtecs #: ws5600000
minumum % wt: 95.
maxumum % wt: 98.
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3
acgih stel: 3 mg/m3
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs