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The last inventory check on this NSN was done on 04/09/2024. Due to rapid changes in inventory this may not be the current stock qty.
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Sulfuric acid and oleum
Sulfuric acid; oleum
Chemicals-inorganic
Y - Indicates information is in the hazardous materials information resource system (hmirs).
PMICA - Item does not contain precious metal.
CRITL- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.
043940 - Chemicals noi
450 - Acids, liquid, corrosive
9 - Other or no special handling required (sh)
A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.
C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp
W - Rating variable
W - Corrosive materials, un class 8 (corrosive label)
Questions & Answers: |
|
| What are the historical prices recorded for this stock number? | |
| Historical data shows pricing from $231.78 to $386.30.. | |
| Does NSN 6810-00-227-1845 have a shelf life? | |
| No. There is no shelf life applicable for this NSN. | |
| What NATO entities are users of this NSN? | |
| Department Of The Army, Department Of The Air Force, Department Of The Navy, Bureau Of Engraving and Printing, Poland, Spain, Singapore, Morocco, Malaysia, Germany, Republic Of Korea, Greece, and Turkey | |
| What is the NIIN of NSN 6810-00-227-1845? | |
| 002271845 or 00-227-1845 | |
| Does NSN 6810-00-227-1845 require demilitarization? | |
| Yes - ITAR Controlled | |
| What is the most recent solicitation for NSN 6810-00-227-1845? | |
| No solicitations for this NSN. | |
| When was this national stock number assigned to the federal catalog? | |
| Jan 01, 1963 | |
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
effects of overexposure: causes sever burns to eyes,skin,mucousa.Can be
fatal if ingested.Respir irrit if inhaled.
First aid: skin/eyes: flush w lg amounts h2o for 15 min.Remove
contaminated clothing.Ingest: drink lg amts h2o.Do not induce
vomit.Inhalation: remove to fresh air.Give cpr/o2 if need.Observe
for delayed reaction.In all cases,get prompt medical attention.
Hcc: c1
boiling pt: b.P. Text: 154f,68c
spec gravity: 1.835
solubility in water: complete
appearance and odor: colorless to slight yellow, clear to turbid oily
liquid.
Stability indicator/materials to avoid: yes
acid, anhydrides, alkali, allyl/unsaturated organics, amines, glycols,
organic oxides, oximes, nitrogen compounds (supp)
stability condition to avoid: high heat, moisture
hazardous decomposition products: oxides sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: disposal is subject to federal,state and local
regs.Users should review their operations for compliance,then
consult with appropriate regulatory agencies before
discharging,disposing of material.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 96.0%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 4.0%
Ld50 lc50 mixture: ld50 (oral rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute - inhalation: severe irritation
or burns of the respiratory system, pulmonary edema, or lung
inflammation. Skin and eyes: severe burns. Ingestion: severe burns
to mouth, throat, and stomach. May affect kidney function.
chronic: may damage lungs.
explanation of carcinogenicity: this product is not listed by iarc, ntp,
or osha as a carcinogen.
effects of overexposure: severe irritation or burns to eyes, nose and
throat. Pulmonary edema, bronchial emphysema, conjunctivitis,
stomatitis, dental erosion, nausea and vomiting.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the respiratory tract may
be at increased risk from exposure.
First aid: inhalation: remove to fresh air. Resuscitate if not
breathing. Get medical attention. Eyes: immediately flush with
plenty of water for 15 minutes holding eyelids open. Get medical
attention. Skin: rem ove contaminated clothing. Wash with plenty of
water for 15 minutes. Get medical advice. Ingestion: do not induce
vomiting. Give nothing by mouth if unconscious. Get immediate
medical attention.
Hcc: c1
boiling pt: b.P. Text: 621f,327c
melt/freeze pt: m.P/f.P text: 28.0f,-2.2c
vapor pres: < 0.3
vapor density: 3.4
spec gravity: 1.84
ph: < 1
evaporation rate & reference: < 1 (n-butyl acetate = 1)
solubility in water: complete
appearance and odor: clear, colorless, oily liquid. Odorless.
Stability indicator/materials to avoid: yes
water, most metals, organic materials, strong reducing, oxidizing and
alkaline agents, combustible materials, cyanides.
stability condition to avoid: moisture and heat
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state, and local environmental regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 96.5%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 3.5%
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
effects of overexposure: eyes and skin: causes severe burns and severe
tissue damage. Inhalation: mist irritates respiratory tract. Long
term overexposure may damage teeth.
First aid: skin: wash with soap and water. Eyes: flush with water.
ingestion: do not induce vomiting. Inhalation: remove to fresh air.
give cpr/oxygen if needed. Keep warm and quiet. Remove contaminated
clothing . Never give anything by mouth to unconscious person.
drink water.
Hcc: c1
boiling pt: b.P. Text: 379f,193c
vapor pres: < 0.3
vapor density: 3.4
spec gravity: 1.773
evaporation rate & reference: < 1 (butyl acetate = 1)
solubility in water: complete
appearance and odor: clear to turbid, colorless to light brown. No odor.
percent volatiles by volume: 0
Stability indicator/materials to avoid: yes
combustibles, oxidizers, reducers, metals, cyanides, carbides,
chlorates, nitrates, fulminates, picrates, sulfides
stability condition to avoid: high heat, moisture
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: wear rubber gloves, scba, protective clothing.
add slowly to large volume of agitated solution of na2 co2 &
ca(oh)2. Add this soln to lg excess of h20. Elim ign sources or
keep in covd drs. Hdle & dis pose lw all appl intern, fed, state &
local regs.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: >93%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt:
Ld50 lc50 mixture: rat,lc50: 510mg/m3/2h;ld50: 2140mg/kgrtecs
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eye, skin, respiratory &
gi tracts. Corrosive! Causes severe eyes & skin burns. Vapor
extremely irritating to respiratory tract. Contact with eyes may
result in blindness. Swallowing may be fatal. Inhalation may
damage respiratory tract. Chronic exposure may cause dental
erosion, dermatitis, bronchitis.
explanation of carcinogenicity: none
effects of overexposure: severe eye, skin, respiratory and
gastrointestinal tracts irritation and burning, visual impairment,
dental erosion, nasal secretion, sneezing, shallow and rapid
breathing, a burning/tickling sensatio n followed by cough,
unconsciousness, possible charring of skin, mouth, throat and
esophagus pain, blindness
medical cond aggravated by exposure: open wounds and sores, respiratory
ailments such as emphysemia and bronchitis
First aid: get medical attention immediately. Eye/skin: immediately flush
with water for 15-20 minutes. Hold eyelids open. Continue rinsing
with normal saline until ph=7. Inhaled: remove to fresh air &
provide oxy gen/cpr if needed. Oral: do not induce vomiting. If
conscious, drink large amount of water/milk. Ingested acid must be
diluted about 100 folds. If vomiting occurs, keep head below hips.
Hcc: c1
nrc/state lic num: not relevant
boiling pt: b.P. Text: 626f,330c
melt/freeze pt: m.P/f.P text: 50.0f,10.0c
decomp temp: decomp text: 644f,340c
vapor pres: 0.001 @68f
vapor density: 3.4
spec gravity: 1.84
ph:
solubility in water: soluble
appearance and odor: clear, colorless, dense hygroscopic oily liquid -
odorless
Stability indicator/materials to avoid: yes
acetaldehyde, alcohol, strong bases, chlorates, cyclopentadiene,
metals, nitromethane, organics, strong oxidizing agents
stability condition to avoid: high heat, moisture/water
hazardous decomposition products: toxic oxides of sulfur
Waste disposal methods: dispose of spilled, neutralized, or waste
product, contaminated soil, and other materials in accordance with
all local, state, and federal regulations. Epa hazardous waste
number d002. Reportable quan tity (rq): 1000 lbs.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 70- 100%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 0 - 30%
other rec limits: none recommended
Ld50 lc50 mixture: ld50 (oral rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation of vapors causes severe
irritation or burns of the respiratory system, pulmonary edema, or
lung inflammation. Eye contact causes severe damage and possible
blindness. Skin contact causes bu rns and possible deep ulceration.
ingestion causes severe burns to mouth, throat, and stomach.
explanation of carcinogenicity: this chemical is not listed by iarc,
ntp, or osha as a carcinogen.
effects of overexposure: severe irritation or burns to eyes, nose and
throat. Pulmonary edema, bronical emphysema, conjunctivitis,
stomatitis, dental erosion, nausea and vomiting.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the respiratory tract may
be at increased risk from exposure.
First aid: inhalation: remove to fresh air. Resuscitate if not
breathing. Get medical attention. Eyes: immediately flush with
plenty of water for 15 minutes holding eyelids open. Get prompt
medical attention. Sk in: remove contaminated clothing. Wash with
plenty of water for 15 minutes. Get medical advice. Ingestion: do
not induce vomiting. Give nothing by mouth if unconscious. Get
immediate medical attention
Hcc: c1
boiling pt: b.P. Text: 535f,279c
vapor pres: 0.01
spec gravity: 1.835
ph: 1
evaporation rate & reference: < 1 (ether = 1)
solubility in water: complete
appearance and odor: clear, colorless, oily liquid. No odor.
percent volatiles by volume: 5-10
Stability indicator/materials to avoid: yes
strong alkali, combustible materials, powdered metals, organic
materials.
stability condition to avoid: high heat, moisture
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state, and local environmental regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93%
other rec limits: none specified
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
effects of overexposure: burns eyes, destructive to body tissues, burn
mucous membranes of respiratory tract, bronchitis, emphysema.
First aid: ingestion: do not induce vomiting. Give large quantities of
water or milk. Eyes: immediately flush with large quantities of
water for at least 15 minutes. Skin: flush all areas with water for
15 minut es. Inhalation: remove from contaminated air.
Hcc: c1
spec gravity: 1.8347
solubility in water: appreciable
appearance and odor: colorless, clear to hazy, odorless, oily-looking
liquid.
Stability indicator/materials to avoid: yes
metals, organic materials, nitrates, carbides, chlorates
stability condition to avoid: high heat, moisture
hazardous decomposition products: hydrogen, oxides of sulfur, hydrogen
sulfide
Waste disposal methods: sulfuric acid that cannot be used or chemically
reprocessed should be disposed of in an approved landfill in such a
manner that will not adversely affect the environment.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 98.0%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: ld50 oral rat = 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
effects of overexposure: contact may cause permanent damage to eyes,
severe burns and ulceration of skin. Inhalation causes upper
respiratory irritation and possible pulmonary edema. Ingestion
causes severe injuries.
medical cond aggravated by exposure: respiratory conditions will be
aggravated by breathing acid mists.
First aid: eyes and skin: flush with plenty of water. See doctor
immediately. Remove contaminated clothing and shoes. Inhalation:
remove to fresh air. Give oxygen/cpr if needed. See doctor.
ingestion: give milk or water, followed by 2 ounces of milk of
magnesia (no carbonates). See doctor immediately.
Hcc: c1
boiling pt: b.P. Text: 536f,280c
melt/freeze pt: m.P/f.P text: 37f,3c
vapor pres: 0.001
vapor density: 3.4
spec gravity: 1.8
solubility in water: complete
appearance and odor: colorless to dark brown oily liquid.
Stability indicator/materials to avoid: yes
bases, oxidizers, reducing agents, powdered metals, organic material.
stability condition to avoid: heat, moisture
hazardous decomposition products: sulfur dioxide, sulfur trioxide,
hydrogen sulfide, hydrogen gas
Waste disposal methods: consult your local environmental officer.
dispose of in accordance with federal, state, and local
environmental regualtions.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 98%
other rec limits: none stated
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 2%
Ld50 lc50 mixture: ld50 (oral rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: inhalation of vapors may cause
severe irritation or burns of the respiratory system, pulmonary
edema, or lung inflammation. May cause severe burns to skin or
eyes. Ingestion may cause severe bu rns to mouth, throat, and
stomach. May affect kidney function. Chronic: may damage lungs.
explanation of carcinogenicity: this product is not listed by iarc, ntp,
or osha as a carcinogen.
effects of overexposure: severe irritation or burns to eyes, nose and
throat. Pulmonary edema, bronchial emphysema, conjunctivitis,
stomatitis, dental erosion, nausea and vomiting.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the respiratory tract may
be at increased risk from exposure.
First aid: inhalation: remove to fresh air. Resuscitate if not
breathing. Get medical attention. Eyes: immediately flush with
plenty of water for 15 minutes holding eyelids open. Get medical
attention. Skin: rem ove contaminated clothing. Wash with plenty of
water for 15 minutes. Get medical advice. Ingestion: do not induce
vomiting. Give nothing by mouth if unconscious. Get immediate
medical attention.
Hcc: c1
boiling pt: b.P. Text: 535f,279c
vapor pres: 1
spec gravity: 1.83
ph: < 1.0
solubility in water: complete
appearance and odor: colorless to cloudy liquid. Oily appearance.
pungent odor.
Stability indicator/materials to avoid: yes
water, sulfides, metallic powders, organic materials, oxidizing or
reducing materials, carbides, cyanides, combustibles
stability condition to avoid: high heat, moisture
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state, and local environmental regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93.19%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: ld50 (oral rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: inhalation of vapors may cause
severe irritation or burns of the respiratory system, pulmonary
edema, or lung inflammation. May cause severe burns to skin or
eyes. Ingestion may cause severe bu rns to mouth, throat, and
stomach. May affect kidney function. Chronic: may damage lungs.
explanation of carcinogenicity: this product is not listed by iarc, ntp,
or osha as a carcinogen.
effects of overexposure: severe irritation or burns to eyes, nose and
throat. Pulmonary edema, bronical emphysema, conjunctivitis,
stomatitis, dental erosion, nausea and vomiting.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the respiratory tract may
be at increased risk from exposure.
First aid: inhalation: remove to fresh air. Resuscitate if not breathing.
get medical attention. Eyes: immediately flush with plenty of water
for 15 minutes holding eyelids open. Get medical attention. Skin:
remov e contaminated clothing. Wash with plenty of water for 15
minutes. Get medical advice. Ingestion: do not induce vomiting. Give
nothing by mouth if unconscious. Get immediate medical attention.
Hcc: c1
boiling pt: b.P. Text: 640f,338c
vapor pres: variable
spec gravity: 1.4 - 1.8
ph: 0.3
solubility in water: complete
appearance and odor: clear to slightly cloudy, oily liquid. Odorless to
slightly pungent odor.
percent volatiles by volume: 0 - 20
Stability indicator/materials to avoid: yes
strong oxidizing agents
stability condition to avoid: extremely high temperatures
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state and local environmental regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93.0%
other rec limits: none specified
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: ld50 (oral rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation of vapors causes severe
irritation or burns of the respiratory system, pulmonary edema, or
lung inflammation. Eye contact causes severe damage and possible
blindness. Skin contact causes bu rns and possible deep ulceration.
ingestion causes severe burns to mouth, throat, and stomach.
explanation of carcinogenicity: this chemical is not listed by iarc,
ntp, or osha as a carcinogen.
effects of overexposure: severe irritation or burns to eyes, nose and
throat. Pulmonary edema, bronical emphysema, conjunctivitis,
stomatitis, dental erosion, nausea and vomiting.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the respiratory tract may
be at increased risk from exposure.
First aid: inhalation: remove to fresh air. Resuscitate if not breathing.
get medical attention. Eyes: immediately flush with plenty of water
for 15 minutes holding eyelids open. Get prompt medical attention.
skin : remove contaminated clothing. Wash with plenty of water for
15 minutes. Get medical advice. Ingestion: do not induce vomiting.
give nothing by mouth if unconscious. Get immediate medical
attention.
Hcc: c1
boiling pt: b.P. Text: 535f,279c
vapor pres: 0.01
spec gravity: 1.835
ph: 1
evaporation rate & reference: < 1 (ether = 1)
solubility in water: complete
appearance and odor: clear, colorless, oily liquid. No odor.
percent volatiles by volume: 5-10
Stability indicator/materials to avoid: yes
strong alkali, combustible materials, powdered metals, organic
materials.
stability condition to avoid: none specified by manufacturer.
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state and local environmental regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93%
other rec limits: none specified
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: ld50 (oral rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation of vapors causes severe
irritation or burns of the respiratory system, pulmonary edema, or
lung inflammation. Eye contact causes severe damage and possible
blindness. Skin contact causes bu rns and possible deep ulceration.
ingestion causes severe burns to mouth, throat, and stomach.
explanation of carcinogenicity: this chemical is not listed by iarc,
ntp, or osha as a carcinogen.
effects of overexposure: severe irritation or burns to eyes, nose and
throat. Pulmonary edema, bronical emphysema, conjunctivitis,
stomatitis, dental erosion, nausea and vomiting.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the respiratory tract may
be at increased risk from exposure.
First aid: inhalation: remove to fresh air. Resuscitate if not breathing.
get medical attention. Eyes: immediately flush with plenty of water
for 15 minutes holding eyelids open. Get prompt medical attention.
skin : remove contaminated clothing. Wash with plenty of water for
15 minutes. Get medical advice. ingestion: do not induce vomiting.
give nothing by mouth if unconscious. Get immediate medical
attention.
Hcc: c1
boiling pt: b.P. Text: 529f,276c
melt/freeze pt: m.P/f.P text: -26f,-32c
decomp temp: decomp text: 644f,340c
vapor pres: nil
vapor density: 3.4
spec gravity: 1.834
ph:
solubility in water: complete
appearance and odor: colorless to yellow, oily, odorless liquid.
Stability indicator/materials to avoid: yes
powdered metals, alkalis, organic materials, chlorates, carbides,
fulminates, and water.
stability condition to avoid: contact with some metals may release
hydrogen, a flammable gas. Contact with combustible materials may
start a fire.
hazardous decomposition products: oxides of sulfur and hydrogen
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state and local environmental regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9293
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: ld50 (oral rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation of vapors causes severe
irritation or burns of the respiratory system, pulmonary edema, or
lung inflammation. Eye contact causes severe damage and possible
blindness. Skin contact causes bu rns and possible deep ulceration.
ingestion causes severe burns to mouth, throat, and stomach.
explanation of carcinogenicity: this chemical is not listed by iarc,
ntp, or osha as a carcinogen.
effects of overexposure: severe irritation or burns to eyes, nose and
throat. Pulmonary edema, bronical emphysema, conjunctivitis,
stomatitis, dental erosion, nausea and vomiting.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the respiratory tract may
be at increased risk from exposure.
First aid: inhalation: remove to fresh air. Resuscitate if not breathing.
get medical attention. Eyes: immediately flush with plenty of water
for 15 minutes holding eyelids open. Get prompt medical attention.
skin : remove contaminated clothing. Wash with plenty of water for
15 minutes. Get medical advice. ingestion: do not induce vomiting.
give nothing by mouth if unconscious. Get immediate medical
attention.
Hcc: c1
boiling pt: b.P. Text: 529f,276c
melt/freeze pt: m.P/f.P text: -26f,-32c
decomp temp: decomp text: 644f,340c
vapor pres: nil
vapor density: 3.4
spec gravity: 1.834
ph:
solubility in water: complete
appearance and odor: colorless to yellow, oily, odorless liquid.
Stability indicator/materials to avoid: yes
powdered metals, alkalis, organic materials, chlorates, carbides,
fulminates, and water.
stability condition to avoid: contact with some metals may release
hydrogen, a flammable gas. Contact with combustible materials may
start a fire.
hazardous decomposition products: oxides of sulfur and hydrogen
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state and local environmental regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9293
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: oral ld50 (rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation-inhalation of mist may
cause mucous membrane irritation principally affecting the
respiratory tract epithelium. Skin-contact may cause severe second
& third degree burns with narcosis. Eye- irreparable corneal damage
& blindness as well as scarring of the eyes. Ingestion-may cause a
burning pain in throat.
explanation of carcinogenicity: not carcinogenic.
effects of overexposure: inhalation-vapors may cause nasal secretion,
sneezing, a burning or tickling sensation in the nose. Skin-skin
destruction may occur. Eye-may cause a burning & stinging sensation
in the eye with lacrim ation & blurred vision. Ingestion-a sour
taste & nausea followed by vomiting & diarrhea of charred stomach
contents.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: inhalation-remove from exposure area to fresh air
immediately. If stopped breathing, give artificial respiration.
contact physician. Skin-wash effected area with soap or mild
detergent & large amounts of water. Contact physician. Eye-wash
immediately with water. Contact physician immediately. Ingestion-do
not use gastric lavage or emisis. Dilute with water or milk.
contact physician immediately.
Hcc: c1
boiling pt: b.P. Text: 626f,330c
melt/freeze pt: m.P/f.P text: 50.0f,10.0c
decomp temp: decomp text: 644f,340c
vapor pres:
vapor density: 3.4
spec gravity: 1.84
ph:
solubility in water: soluble.
appearance and odor: odorless, colorless to yellow to dark brown dense
hygroscopic oily liquid.
Stability indicator/materials to avoid: yes
alcohols, ammonium hydroxide, aniline, carbides, chromates, copper,
combustible materials, ethylene glycol, iron, etc.
stability condition to avoid: violent exothermic reaction with water.
avoid direct sunlight.
hazardous decomposition products: thermal decomposition may release
toxic oxides of sulfur.
conditions to avoid polymerization: hazardous polymerization has not
been reported to ocuur under normal temperatures and pressures.
Waste disposal methods: disposal must be in accordance with standards
applicable to generators of hazardous waste, 40 cfr 262. Epa
hazardous waste number d002. 100 pounds cercla section 103
reporatble quantity.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 100%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: none specified by manufacturer.
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: eye: can cause perm injury.Can injure
cornea & cause blindness.Skin: can cause perm dmg.Ingest: may be
harmful or fatal.May cause burns & destroy tissue in
mouth/throat/digestive tract.Low blood pressure & shock may occur
as result of severe tissue injury.Inhal: breath vap/miost
possible.May be harmful or fatal.
explanation of carcinogenicity: per msds: contains sulfuric acid-iarc
lists strong-inor acid mists containing sulfuric acid as causing
canc in humans.
effects of overexposure: eye: stinging,tearing,redness,swelling of
eyes.Skin: redness,brning,swelling of skin,burns,other skin
dmg.Ingest: severe stomach & intestinal
irrit(nau,vomit,diarr)abdominal pain,vomit of blood.Inhal: sev ere
irrit & burns to nose/throat/respiratory tract.
medical cond aggravated by exposure: none specified by manufacturer.
target organ effects: no data.
First aid: eye: immed flush gently w/h2o @least 15mins,hold eyelids
apart.Sympt dvlp frm vap expo immed move into fresh air bef
flush.Seek immed med attn.Skin: remove contam cloth.Flush w/lg amts
of h2o.Skin dmg s eek immed med attn;not dmg/sympt persist seek med
attn.Ingest: seek immed med attn.Dont induce vomit-can further dmg
mouth/throat.Consc/alert immed rinse mouth w/h2o,give milk/h2o to
drink.(supplement)
Hcc: c1
boiling pt: b.P. Text: 212f,100c
melt/freeze pt: m.P/f.P text: np
decomp temp: decomp text: np
vapor pres: 17.5 @68f
vapor density: na
spec gravity: n1.837
ph:
viscosity: np
evaporation rate & reference: slower than ethyl ether
solubility in water: np
appearance and odor: liquid, homogeneous solution, clear and syrupy,
odor-no data
percent volatiles by volume: 5-10
corrosion rate: np
Stability indicator/materials to avoid: yes
avoid contact w/strong alkalies, acid reacts w/most metals to release
hydrogen gas which can form explo mixtures w/air.
stability condition to avoid: none specified by manufacturer.
hazardous decomposition products: may form: acid vapors.
Waste disposal methods: dispose of in accordance with all applicable
local, state and federal regulations.Sulfuric acid-cercla
rq=1000lbs.Sara 302 tpq/rq=1000lbs,sara 313 sulfuric acid(acid
aerosols).
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara 302/313) (cercla)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93.0%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3/3 stel; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 4.8-9.0%
other rec limits: none recommended
Ld50 lc50 mixture: see ingredient 1.
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: acute: eyes: causes sev burns. May
cause irreversible eye injury. Skin: causes burns. Ingest: may
cause sev & perm dmg to digestive tract. Causes gi tract burns.
inhal: harmful if inhaled. May cause s ev irrit of resp tract
w/sore throat, coughing, shortness of brth & delayed lung edema.
may cause muc (efts of overexp)
explanation of carcinogenicity: sulfuric acid: iarc mono on eval of
carcin risk of chemicals to man, vol 54, pg 41, 1992: group 1.
animal: pulm irrit.
effects of overexposure: hlth haz: memb burns. Chronic: prlng/rptd inhal
may cause nosebleeds, nasal congestion, erosion of teeth,
perforation of nasal septum, chest pain & bronchitis. Prlng/rptd
eye cont may cause conjunctiv itis.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: eyes: flush w/plenty of water for at least 15 min, occas
lifting upper & lower lids. Get med aid immed. Skin: get med aid
immed. Flush skin w/plenty of soap & water for at least 15 min
while removing contam clthg & shoes. Speedy action is critical!
ingest: do not induce vomit. If victim is conscious & alert, give
2-4 cupfuls of milk/water. Get med aid immed. Inhal: get med aid
immed. (ing 6)
Boiling pt: b.P. Text: 554f,290c
melt/freeze pt: m.P/f.P text: 50.6f,10.3c
vapor pres:
vapor density: 1.2
spec gravity: 1.841
ph: supdat
evaporation rate & reference: slower than ether
solubility in water: soluble
appearance and odor: colorless (pure) to brown (impure), fuming liquid,
odorless
Stability indicator/materials to avoid: yes
acetic anhydride, acetone cyanhydrin, acetone + nitric acid, acetone +
potassium dichromate, acetonitrile, (sup dat)
stability condition to avoid: incompatible matls, cont w/water, metals,
excess heat, combust matls, org matls, oxidizers, amines, bases.
hazardous decomposition products: oxides of sulfur.
Waste disposal methods: dispose of in a manner consistent with federal,
state, and local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara 302/313) (cercla) ld50 (oral rat): 2140
mg/kg
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 95-98%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3/3 stel
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: sup dat: chlorine trifluoride, chlorosulfonic acid, cuprous
nitride, diisobutylene, epichlorohydrin, ethylene (ing 3)
rtecs #: 9999999zz
ingred name: ing 2: cyanohydrin, ethylene diamine, ethylene glycol,
ethylenimine, fulminates, other acids, iodine (ing 4)
rtecs #: 9999999zz
ingred name: ing 3: heptafluoride, metals, isoprene, lithium silicide,
mercuric nitride, mesityl oxide, p-nitrotoluene, (ing 5)
rtecs #: 9999999zz
ingred name: ing 4: pentasilver trihyd.
rtecs #: 9999999zz
ingred name: first aid proc: remove from expos to fresh air immed. If
not brthg, give artf resp. If brthg is dfclt, give (ing 7)
rtecs #: 9999999zz
ingred name: ing 6: oxygen. Notes to md: treat symptomatically and
supportively. None reported.
rtecs #: 9999999zz
ingred name: eye protection: and full length faceshield .
rtecs #: 9999999zz