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Acs Nonahydrate Sodium Sulfide

NSN: 6810-00-234-8378 | Model: A-A-59282
ITAR Registered seal
NSN Properties and Flags
NATO Stock Number
6810-00-234-8378
DEMIL
Yes - ITAR Controlled (Code Q)
Physical Form
Crystal
Quantity Within Each Unit Package
500.0 grams

Pricing and Availability

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NSN 6810-00-234-8378 Datasheet

Supply Class (FSC):
Chemicals
Cross Reference:
  • A-A-59282
  • 8044
  • 2297
  • 3910
  • S425-500
  • O-C-265
Cage Codes:
  • Federal Commercial Item Description (CAGE 58536)
  • Mallinckrodt Inc (CAGE 37940)
  • Honeywell International Inc (CAGE 70308)
  • Avantor Performance Materials, Inc. (CAGE 70829)
  • Fisher Scientific Company L.l.c. (CAGE 22527)
  • Federal Specifications (CAGE 81348)
Replacements:
  • 6810-00-234-8378 replaces 6810-00-174-6610
Schedule B & Trade:
  • Schedule B: 2830100000 (NAICS 325180)

    Sodium sulfides

  • SITC: 52341

    Sodium sulfide

  • End Use: 12530

    Chemicals-inorganic

Identification:
HMIC

Y - Indicates information is in the hazardous materials information resource system (hmirs).

PMIC

A - Item does not contain precious metal.

CRITL

- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.

Freight Information:
  • NMFC:

    046640 - Sodiu (soda) sulphide

  • WCC:

    635 - Chemicals, other than drugs or sundries

  • SHC:

    9 - Other or no special handling required (sh)

  • ADC:

    A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.

  • ACC:

    C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp

  • TCC:

    V - Miscellaneous hazardous materials, un class 9 (no label)

  • LTL:

    W - Rating variable

NSN Management Codes:
  • SOS
    Sms
  • AAC
    H
  • Quantity per pack
    24
  • Unit of Measure
    Bt
  • Shelf Life
    N/A
  • Classification Control
    U
  • MGMT_CTL
    R2200x-
  • Repariability
    This is a nonreparable item. if condemned or economically unserviceable, then dispose at the level authorized replace the item.

Questions & Answers:

What are the historical prices recorded for this stock number?
Historical data shows pricing from $311.65 to $519.41..
Does NSN 6810-00-234-8378 have a shelf life?
No. There is no shelf life applicable for this NSN.
What NATO entities are users of this NSN?
Department Of The Army, Department Of The Air Force, Department Of The Navy, Bureau Of Mines, Brazil, and Turkey
What is the NIIN of NSN 6810-00-234-8378?
002348378 or 00-234-8378
Does NSN 6810-00-234-8378 require demilitarization?
Yes - ITAR Controlled
What is the most recent solicitation for NSN 6810-00-234-8378?
No solicitations for this NSN.
When was this national stock number assigned to the federal catalog?
Jan 01, 1963
MSDS

Material Safety

MSDS BDLMZ SODIUM SULFIDE

First Aid

First aid: irrigate eyes with water; wash contaminated parts of body
with soap & water. If swallowed induce vomiting & call a physician
at once

Chemical Properties

Hcc: b1
solubility in water: appreciable
appearance and odor: colorless, clear crystals

Reactivity

Stability indicator/materials to avoid: yes
carbon, dizonium salts
hazardous decomposition products: hydrogen sulfide,sulfur

Proper Disposal

Waste disposal methods: dispose through approved waste treatment area in
plant following neutralizations.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium sulfide, nonahydrate
cas: 1313-82-2
rtecs #: we1905000
fraction by wt: 100%

MSDS BDLNB SODIUM SULFIDE,NONAHYDRATE,ACS

Hazards

Ld50 lc50 mixture: ld50 (interperitoneal-mouse) 53 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute-corrosive.Inhale: may cause
severe irritation,coughing,sore throat.In air,forms hydrogen
sulfide gas & cause poisoning,unconsciousness & death.Eye/skin: may
cause severe irritation, redness & pain .Oral: abdominal
pain,nausea,vomiting.Maycause sudden collapse &
death.Chronic-dermatitis,conjunctivitis,headache.

effects of overexposure: corrosive. Inhalation may cause severe
irritation, coughing, sore throat. In air, forms hydrogen sulfide
gas & cause poisoning, unconsciousness & death. May cause severe
eyes and skin irritation, redn ess & pain. Orally can cause
abdominal pain, nausea, vomiting. May cause sudden collapse &
death.

medical cond aggravated by exposure: persons with pre-existing skin
disorders or eye problems or impaired respiratory function may be
more susceptible to the effects of the substance.

First Aid

First aid: get medical attention immediately. Eyes: immediately flush
with water for at least 15 minutes. Hold eyelids open. Skin: wash
with soap & water. Inhaled: remove to fresh air & provide
oxygen/cpr if nee ded. Oral: if conscious, drink milk/water. Call a
physician. Aspiration hazard. Keep head lower than hips to prevent
aspiration if vomiting should occur.

Chemical Properties

Hcc: b1
melt/freeze pt: =50.C, 122.F
m.P/f.P text: 122f,50c
spec gravity: 1.427
ph: 13.6 of 10% sol
solubility in water: 47.5% @ 50f.

appearance and odor: white to yellow or brick red crystals. Hydrogen
sulfide odor. Ph of 10% soln>13

Reactivity

Stability indicator/materials to avoid: yes
carbon, diazonium chloride salts, acids, zinc, aluminum, oxidants.

stability condition to avoid: occasionally explosive by friction and
quick heating. Exposure to air produces h2s gas.Exothermic reaction
with moisture
hazardous decomposition products: thermal decomposition may release
toxic oxides of sodium and sulfur.

Proper Disposal

Waste disposal methods: contact your local environmental officer.

dispose of in accordance with all applicable federal, state and
local regulations.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium sulfide, hydrated with >= 30% water
cas: 1313-82-2
rtecs #: we1910000
fraction by wt: 100%
other rec limits: none specified

MSDS BDLNC SODIUM SULFIDE

Hazards

Effects of overexposure: skin/eyes: causes sev burns.Removes
hair;ingest: irrit muc memb,gi tract;inhal;forms h*2s,irrit resp.

First Aid

First aid: skin: wash w.Soap & h*2o. Eyes: flush w. H*2o. Ingested: don't
induce vomiting. Inhaled: remove to fresh air. Give cpr/oxygen if
need. Keep warm & quiet. Remove contaminated clothing. Never give
anything by mouth to unconscious person.

Chemical Properties

Hcc: b1
spec gravity: 1.85
solubility in water: appreciable
appearance and odor: yellow to buff colored flakes/solid w/charctr odor

Reactivity

Stability indicator/materials to avoid: yes
strong/weak acids; oxidizing matl.

stability condition to avoid: moisture
hazardous decomposition products: so*2,na/20,h*2s gas

Proper Disposal

Waste disposal methods: keep in covered drums,pending disposal. Handle &
dispose in full compliance with all applicable
international,federal,state, & local regulations.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium sulfide nonahydrate (% of h*20 in crystal form: 35% &
na*2s content: 62-62%
cas: 1313-84-4
rtecs #: we1925000
fraction by wt: >99%

MSDS BKYJK SX0770 SODIUM SULFIDE GR, CRYSTALS 500G

Hazards

Ld50 lc50 mixture: oral ld50 (rat): 53 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eyes/skin: irritation & burns.

inhalation: irritation & burns to the respiratory tract. Ingestion:
nausea, vomiting, diarrhea, & gastrointestinal irritation.

explanation of carcinogenicity: none
effects of overexposure: eyes/skin: irritation & burns. Inhalation:
irritation & burns to the respiratory tract. Ingestion: nausea,
vomiting, diarrhea, & gastrointestinal irritation.

First Aid

First aid: eyes: flush thoroughly w/water for at least 15 mins. Skin:
wash w/soap & water. Inhalation: remove to fresh air. Ingestion:
obtain medical attention in all cases.

Chemical Properties

Melt/freeze pt: m.P/f.P text: 1688f
spec gravity: 1.427
solubility in water: appreciable
appearance and odor: white to slightly yellow crystals or granules.

Reactivity

Stability indicator/materials to avoid: yes
acids, oxidizers, & other organic acids.

hazardous decomposition products: toxic hydrogen sulfide gas, sulfur
oxides

Proper Disposal

Waste disposal methods: dispose of in accordance w/local, state, &
federal regulations.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium sulfide, nonahydrate
cas: 1313-84-4
rtecs #: we1925000

MSDS BPYFT SODIUM SULFIDE,NONAHYDRATE

Hazards

Ld50 lc50 mixture: oral ld50 (rat) is 208 mg/kg
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: inhalation may cause severe
respiratory irritation, hydrogen sulfide poisoning. Contact with
skin and eyes may cause severe irritation or burns. Swallowing may
cause severe digestive system irr itation, hydrogen sulfide
poisoning. Chronic: prolonged or repeated exposure may cause
conjunctivitis, dermatitis.

explanation of carcinogenicity: not carcinogenic.

effects of overexposure: inhalation: coughing, sneezing, choking,
shortness of breath, headache, nausea, vomiting, dizzines,
unconsciousness, or death. Eyes: burning sensation, tearing, pain,
blurred vision. Skin: redness, bu rns, swelling, pain. Ingested:
burns inmouth and throat, severe stomach pain, nausea, vomiting,
dizziness.

medical cond aggravated by exposure: none specified by manufacturer.

First Aid

First aid: inhaled: move to fresh air. Perform cpr if needed. Maintain
airway, blood pressure & respiration. Get a physician. Eyes: flush
with lots of water for 15 minutes, hold lids open. Get medical
attention. Skin: remove contaminated clothes. Washwith soap &
water. See doctor. Ingested: get immediate medical attention.

doctor- gastric lavage or emesis. Give sodium bicarbonate to reduce
acidity.

Chemical Properties

Hcc: b1
boiling pt: =920.C, 1688.F
melt/freeze pt: =50.C, 122.F
decomp temp: =920.C, 1688.F
spec gravity: 1.427 (water=1)
ph: >7
solubility in water: appreciable
appearance and odor: colorless, deliquescent crystalline solid; hydrogen
sulfide odor

Reactivity

Stability indicator/materials to avoid: yes
strong mineral acids, copper and alloys, aluminum and alloys, metals,
strong oxidizing agents, zinc and alloys
stability condition to avoid: contact with incompatibles. Temperatures
above 248f.

hazardous decomposition products: oxides of sulfur.

Proper Disposal

Waste disposal methods: observe all federal, state and local regulations
when storing or disposing of this substance.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium sulfide, hydrated
cas: 1313-82-2
rtecs #: we1910000
fraction by wt: 99.9%
other rec limits: none recommended

MSDS BQCQB SODIUM SULFIDE

Hazards

Ld50 lc50 mixture: none specified by manufacturer.

routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: inhal: highly toxic (50-100ppm
in air) hydrogen sulfide which may accum in confined spaces due to
decomp of sodium sulfide or from its rxn w/acids. Symptoms include
painful conj/hdach/naus/dizz /coughing &, in extreme cases, pulm
edema & poss death. Ingest: corrosive, toxic. Sodium sulfide is a
(efts of overexp)
explanation of carcinogenicity: not relevant
effects of overexposure: hlth haz: strong base & can cause sev burns on
muc memb. Hydrolysis by gastric fluids rels tox hydrogen sulfide.

symps/efts are similar to those under inhal. Skin: irritant. Cont
can prdce serious cau stic burns w/painful inflamm & poss destruct
of tiss. Eyes: irritant. Inflamm/tearing/pain may be expected.(supp
data)
medical cond aggravated by exposure: persons w/pre-existing skin
disorders or eye problems, or impaired liver, kidney or respiratory
function may be more susceptible to the effects of the substance.

First Aid

First aid: inhal: remove to fresh air. If not brthg, give artf resp. If
brthg is dfclt, give o*2. Call md. Ingest: give sev glasses of
water/milk, if avail, to drink. Vomit may occur spont, but do not
induce! Neve r give anything by mouth to uncon person. Get med attn
immed. Skin: immed flush w/plenty of water for at least 15 min while
removing contamd clthg/shoes & wash before reuse. Call md immed.

(supp data)

Chemical Properties

Hcc: c2
melt/freeze pt: m.P/f.P text: 122f,50c
solubility in water: 200g in 100g of h*2o
appearance and odor: white crystals with sulfide odor.

Reactivity

Stability indicator/materials to avoid: no
acids, oxidants.

stability condition to avoid: darkens on exposure to air or light.

sodium hydroxide forms in aqueous solutions.

hazardous decomposition products: hydrogen sulfide at room temperature,
oxides of sulfur and sodium under fire conditions.

Proper Disposal

Waste disposal methods: whatever cannot be saved for reclamation may be
disposed in a rcra apprvd haz waste facility. Do not contact
w/acids. Do not handle w/bare hands. Ensure compliance w/local,
state and federal regulatio ns.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium sulfide. Pel/tlv: 10ppm; 15ppm stel (h*2s).

cas: 1313-82-2
rtecs #: we1905000
osha pel: see ingredient name
acgih tlv: see ingredient name

MSDS BQKNP SODIUM SULFIDE, 9-HYDRATE

Hazards

Ld50 lc50 mixture: ld50 (interperitoneal-mouse) 53 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute- corrosive. Inhalation: severe
irritation to upper respiratory tract. Eye/skin: severe irritation,
burns. Ingestion: severe burns to mouth, throat and stomach.

chronic- dermatitis, conjunctivitis , headache.

effects of overexposure: inhalation: coughing, sore throat. eyes and
skin: irritation, redness & pain. ingestion: abdominal pain,
nausea, vomiting. May cause sudden collapse & death.

medical cond aggravated by exposure: persons with pre-existing skin
disorders or eye problems or impaired respiratory function may be
more susceptible to the effects of the substance.

First Aid

First aid: get medical attention immediately. Eye: immediately flush with
water for at least 15 minutes holding eyelids open. Skin: wash with
soap & water. Inhal: remove to fresh air & provide oxygen/cpr if
needed. ingestion: if conscious, drink milk/water. Call a
physician.

Chemical Properties

Hcc: b1
boiling pt: =173.9c, 345.F
melt/freeze pt: =50.C, 122.F
spec gravity: 1.86
solubility in water: 10%
appearance and odor: white to yellow crystals, hydrogen sulfide odor
percent volatiles by volume: 0

Reactivity

Stability indicator/materials to avoid: yes
carbon, diazonium chloride salts, acids, zinc, aluminum, oxidants
stability condition to avoid: flames, excessive heat, moisture
hazardous decomposition products: toxic oxides of sulfur and hydrogen
gas.

Proper Disposal

Waste disposal methods: dispose of in accordance with all local, state
and federal regulations.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium sulfide, nonahydrate
cas: 1313-82-2
rtecs #: we1910000
minumum % wt: 90.

maxumum % wt: 100.

other rec limits: none specified

MSDS BRGHL SODIUM SULFIDE, ACS

Hazards

Ld50 lc50 mixture: ld50 (interperitoneal-mouse) 53 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation-may cause severe irritation
of mucous membranes, sore throat, shortness of breath. If exposed
to air, poisoning may occur. Low concentrations may cause nausea,
vomiting, delirium, unconscio usness. High concentrations: sudden
collapse, convulsion, & death. Skin-severe irritation & possible
burns.

explanation of carcinogenicity: not carcinogenic.

effects of overexposure: corrosive. Skin-redness, pain & possibly skin
burns. Eyes-redness, pain, blurred vision, corneal burns may occur.

ingestion-corrosion of gastric mucosa with sore throat, nausea &
vomiting. Chronic: he adache, insomnia, loss of appetite, vomiting.

medical cond aggravated by exposure: none specified by manufacturer.

First Aid

First aid: inhalation-remove to fresh air. Give cpr if needed, oxygen if
available. Seek medical attention. Skin-wash area with soap & water
for 15 min cover with dry sterile dressing, seek medical help.

eyes-fl ush with water or normal saline for 20 min. In case of
burns cover with dry sterile bandage. Get help. Ingestion-give
water or milk to dilute the substance. Get immediate medicak help.

Chemical Properties

Hcc: r1
melt/freeze pt: =50.C, 122.F
spec gravity: 1.427
solubility in water: 47.5% @ 10c
appearance and odor: white to yellow or brick red deliquescent
tetragonal crystals/flakes.

Reactivity

Stability indicator/materials to avoid: yes
diazonium chloride salts, carbon, acids, zinc, aluminum, oxidants.

stability condition to avoid: occasionally explosive by friction & quick
heating. Avoid exposing crystals to air or moisture.

hazardous decomposition products: thermal decomposition may release
toxic oxides of sodium and sulfur.

Proper Disposal

Waste disposal methods: contact your district director of the epa.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium sulfide
cas: 1313-82-2
rtecs #: we1910000
fraction by wt: 100%
other rec limits: none specified

MSDS BXCMS SODIUM SULFIDE,37 E 5535

Hazards

Ld50 lc50 mixture: ld50 (oral, rat) is 208 mg/kg.

routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eye, skin, respiratory &
gi tracts. Acute- corrosive. Harmful by ingestion, inhalation/skin
absorption. Eyes/skin: causes severe burns. May cause eye damage.

inhale: upper respiratory trac t inflammation. May be fatal.

oral: verytoxic. Causes burns, cns depression, cardiovascular
injury. Chronic- unknown.

explanation of carcinogenicity: none
effects of overexposure: severe burns, irritation, pain, eye damage,
skin inflammation and blistering, coughing, headache, nausea,
vomiting, convulsion, dizziness, coma, death
medical cond aggravated by exposure: individuals with pre-existing
diseases of the eye, skin, respiratory tract, cardiovascular,
central nervous system may have increased susceptibility to the
toxicity of excessive exposures.

First Aid

First aid: get immediate medical help for all cases of exposure.

eyes/skin: flush with water for at least 15 minutes. Hold eyelids
open. Remove contaminated clothing. Inhaled: remove to fresh air.

provide cpr/oxyg en if needed. Oral: do not induce vomiting. If
conscious, drink large amount of milk. If vomiting occurs
spontaneously, keep airway clear. Never give anything by mouth to
an unconscious person.

Chemical Properties

Hcc: b1
nrc/state lic num: not relevant
boiling pt: b.P. Text: decomposes
melt/freeze pt: m.P/f.P text: 122f,50c
decomp temp: decomp text: 428f,220c
spec gravity: 1.43
viscosity: not relevant
evaporation rate & reference: not relevant
solubility in water: 125%
appearance and odor: white crystals - hydrogen sulfide odor

Reactivity

Stability indicator/materials to avoid: no
acids, oxidizers, metals, silver oxide, hydrazine, carbon, water,
mercaptane, diazonium salts, carbon dioxide, bisulfite
stability condition to avoid: light, air, moisture, high temperatures,
sparks, flames, all other sources of ignition
hazardous decomposition products: hydrogen sulfide, sulfur dioxide

Proper Disposal

Waste disposal methods: discharge, treatment or disposal is subject to
local, state and federal regulations. Small quantities may be
dissolved in water and neutralized with acid. The neutralized
solution may be flushed down the drain if permitted.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium sulfide nonahydrate/sodium sulphide
cas: 1313-84-4
rtecs #: we1925000
fraction by wt: 98- 100%
other rec limits: none recommended

MSDS CBRXF 3910 SODIUM SULFIDE, 9-HYDRATE

Hazards

Ld50 lc50 mixture: none specified by manufacturer.

routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhal: irrit of upper resp tract.

skin/eye: severe burns. Skin absorption: may be harmful.

ingest: severe burns to
mouth/throat/stomach,nausea,vomiting,diarrhea. Chronic effects: none
identified.

explanation of carcinogenicity: per
msds: carcinogenicity: ntp/iarc/zlist/osha: no.

effects of overexposure: irrit of upper resp tract. Severe eye/skin
burns. Skin absorbtion harmful. Severe burns to
mouth/throat/stomach, nausea, diarrhea, vomiting.

medical cond aggravated by exposure: respiratory system disease, central
nervous system disorders. Target organs: eye/skin.

First Aid

First aid: ingest: call physician.Do not induce vomit.Give water,milk,or
milk fo magnesia if consc. Inhal: remove to fresh air.Not breath
give art resp;breath diffi give oxy.Prompt action essential.

skin: immed flu sh w/plenty of water for @least 15mins.

Chemical Properties

Hcc: b1
boiling pt: b.P. Text: 345f,174c
melt/freeze pt: m.P/f.P text: 122f,50c
decomp temp: decomp text: np
vapor pres: na
vapor density: na
spec gravity: 1.86
ph: supplm
viscosity: np
evaporation rate & reference: na
solubility in water: appreciable (>10%)
appearance and odor: solid, white to yellow crystals, sulfur dioxide
odor.

percent volatiles by volume: 0
corrosion rate: np

Reactivity

Stability indicator/materials to avoid: yes
strong oxidizing agents, strong acids, most common metals.

stability condition to avoid: heat, flame, other sources of ignition.

hazardous decomposition products: hydrogen sulfide.

Proper Disposal

Waste disposal methods: dispo iaw all applicable local, state and
federal environmental regulations.Sara 313 toxi chem/cercla haz
subst: no.Eap haz waste no: d002(corr waste).

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium sulfide nonahydrate/sodium sulphide
cas: 1313-84-4
rtecs #: we1925000
fraction by wt: 98-100%
other rec limits: none recommended

MSDS CCLPM SODIUM SULFIDE NONAHYDRATE,78861

Hazards

Ld50 lc50 mixture: ld50 (oral, rat) is not known.

routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eyes, skin, respiratory
and gastrointestinal tracts. Acute- corrosive. Inhalation of
hydrogen sulfide gas can be fatal. Ingestion of small amounts can
be rapidly fatal. Extremely destruc tive to the tissue of the upper
respiratory tract, eyes and skin. Causes unconsciousness and death.

chronic- unknown.

explanation of carcinogenicity: none
effects of overexposure: severe irritation, coughing, pulmonary edema,
shortness of breath, vomiting, dizziness, death, pain, blurred
vision, unconsciousness, diarrhea
medical cond aggravated by exposure: persons with pre-existing skin
disorders or eye problems or impaired respiratory function may be
more susceptible to the effects of the substance.

First Aid

First aid: get immediate medical help for all cases of exposure.

eyes/skin: flush with water for at least 15 minutes. Hold eyelids
open. Inhaled: remove to fresh air. Provide cpr/oxygen if necessary.

oral: do not i nduce vomiting. If conscious, drink 1-2glasses of
milk/water. Never give anything by mouth to an unconscious person.

if vomiting occurs spontaneously, keep head below hips to prevent
aspiration.

Chemical Properties

Hcc: b1
nrc/state lic num: not relevant
boiling pt: b.P. Text: decomposes
melt/freeze pt: =50.C, 122.F
decomp temp: =920.C, 1688.F
spec gravity: 1.427
ph: alkali
viscosity: not relevant
evaporation rate & reference: not relevant
solubility in water: 18%
appearance and odor: colorless to slightly yellow deliquescent crystals,
hydrogen sulfide odor

Reactivity

Stability indicator/materials to avoid: yes
strong acids, strong oxidizing agents
stability condition to avoid: light, excessive heat and temperatures
above 300c/572f
hazardous decomposition products: oxides of sulfur and toxic and
flammable hydrogen sulfide gas

Proper Disposal

Waste disposal methods: dispose of in an approved incinerator or
contract with licensed chemical waste disposal service. Discharge,
treatment or disposal is subject to federal, state or local laws.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium sulfide nonahydrate
cas: 1313-84-4
rtecs #: we1925000
fraction by wt: 98- 100%
other rec limits: none recommended