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Acs Nonahydrate Sodium Sulfide

NSN: 6810-00-237-2908 | Model: A-A-59282
NSN Properties and Flags
NATO Stock Number
6810-00-237-2908
DEMIL
NO
Physical Form
Crystal
Quantity Within Each Unit Package
4.000 ounces, avoirdupois

Pricing and Availability

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NSN 6810-00-237-2908 Datasheet

Supply Class (FSC):
Chemicals
Cross Reference:
  • A-A-59282
  • 8044
  • 0C265
Cage Codes:
  • Federal Commercial Item Description (CAGE 58536)
  • Mallinckrodt Inc (CAGE 37940)
  • Federal Specifications (CAGE 81348)
Schedule B & Trade:
  • Schedule B: 2830100000 (NAICS 325180)

    Sodium sulfides

  • SITC: 52341

    Sodium sulfide

  • End Use: 12530

    Chemicals-inorganic

Identification:
HMIC

Y - Indicates information is in the hazardous materials information resource system (hmirs).

PMIC

A - Item does not contain precious metal.

CRITL

- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.

NSN Management Codes:
  • SOS
    Sms
  • AAC
    H
  • Quantity per pack
    No qup
  • Unit of Measure
    Bt
  • Shelf Life
    N/A
  • Classification Control
    U
  • MGMT_CTL
    R2200x-
  • Repariability
    This is a nonreparable item. if condemned or economically unserviceable, then dispose at the level authorized replace the item.

Questions & Answers:

What are the historical prices recorded for this stock number?
Historical data shows pricing from $408.56 to $680.94..
Does NSN 6810-00-237-2908 have a shelf life?
No. There is no shelf life applicable for this NSN.
What NATO entities are users of this NSN?
Department Of The Army, Department Of The Air Force, Department Of The Navy, Tennessee Valley Authority, Brazil, and Republic Of Korea
What is the NIIN of NSN 6810-00-237-2908?
002372908 or 00-237-2908
Does NSN 6810-00-237-2908 require demilitarization?
Yes - ITAR Controlled
What is the most recent solicitation for NSN 6810-00-237-2908?
No solicitations for this NSN.
When was this national stock number assigned to the federal catalog?
Jan 01, 1963
MSDS

Material Safety

MSDS BDLWX SODIUM SULFIDE,NONAHYDRATE,ACS

Hazards

Effects of overexposure: eye & skin-irritant;inhal-highly
toxic;ingestion-corrosive,toxic

First Aid

First aid: eye & skin-immed flush w/water & call physician. Inhal-remove
to fresh air, give oxygen if necessary.Ingestion-give several
glasses milk or water. Do not induce vomit(may occur spont).Call a
physician immed.

Chemical Properties

Hcc: b1
spec gravity: 1.43
solubility in water: appreciable
appearance and odor: white delequescent crystals suflide odor

Reactivity

Stability indicator/materials to avoid: yes
acids,oxidants
stability condition to avoid: light
hazardous decomposition products: hydrogen sulfide;oxides of sulfur &
sodium

Proper Disposal

Waste disposal methods: what cannot be saved for reclamation may be
disposed in a rcra-approved hazardous waste facility. Ensure
compliance with local,state & federal regs.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium sulfide,nonahydrate
cas: 1313-84-4
rtecs #: we1925000
fraction by wt: 100%
acgih tlv: 10 ppm (h*2s)

MSDS BDLWY SODIUM SULFIDE

Hazards

Ld50 lc50 mixture: ipr mouse ld50 53 mg/kg(h*2s lc50 444ppm
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: product is corrosive, burning body
tissues. It is also toxic by forming hydrogen sulfide which affects
the central nervous system.-most likely form of inhalation of
hydrogen sulfide.

effects of overexposure: eye: severe irritation,pain,blurred
vision.Skin: severe irritation,burns,systemic poisoning.

inhaled: dust produces respiratory irritation. Inhalation of
hydrogen sulfide also produces nausea,vomiting,co
llapse,convulsions. Ingestion: severe irrit.G/i system.Contact w
stomach acid yields h*2s & caustic.& nausea,vomit,etc.

First Aid

First aid: eye: flush with water,get medical attention. Skin: remove
contaminated clothing. Wash with soap & water. Flush with water.

get medical attention. Inhaled: remove from exposure. Give oxygen
or cpr as n eeded. Get immediate medical attention.Ingestion: if
conscious give large amount of water or milk. Get immediate medical
attention.

Chemical Properties

Hcc: b1
melt/freeze pt: m.P/f.P text: 122f/50c
spec gravity: 1.427
ph: alk.

solubility in water: 47.5%
appearance and odor: white to yellow to brick red deliquescent
tetragonal crystals, sulfide odor

Reactivity

Stability indicator/materials to avoid: no
moisture,acids,reactive metals,diazonium chloride
salts(explodes),n,n-dichloromethyl amine (explodes)
stability condition to avoid: occasionally reacts explosively to
friction or heat.

hazardous decomposition products: hydrogen sulfide,sulfur oxides.

Proper Disposal

Waste disposal methods: dispose i/a/w federal,state,local regulations.

hmis: dilute spills with water(use care),then carefully react with
hypochlorite to a small chlorine residual. Neutralize to ph 6-9
before disposing. If d issolving solids,carefully & slowly addto
water.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium sulfide nonahydrate
cas: 1313-84-4
rtecs #: we1925000
fraction by wt: 100%
osha pel: none established
acgih tlv: none established

ingred name: hydrogen sulfide (sara iii)
cas: 7783-06-4
rtecs #: mx1225000
osha pel: (c),20 ppm
acgih tlv: 10 ppm/15 stel; 9293
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs

MSDS BDLWZ SODIUM SULFIDE, 9-HYDRATE

Hazards

Routes of entry: inhalation: no skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: severe irritation and burns.

explanation of carcinogenicity: none of the chemicals in this product is
listed by iarc, ntp or osha as a carcinogen.

effects of overexposure: contact with skin or eyes may cause severe
irritation or burns.

medical cond aggravated by exposure: persons with a history of skin
disorders may be at increased risk from exposure.

First Aid

First aid: if swallowed, if conscious, immediately induce vomiting. In
case of contact, immediately flush eyes with plenty of water for at
least 15 minutes. Flush skin with water.

Chemical Properties

Hcc: b1
nrc/state lic num: not relevant
melt/freeze pt: =50.C, 122.F
spec gravity: 1.43
solubility in water: appreciable
appearance and odor: yellow crystals with odor of hydrogen sulfide.

percent volatiles by volume: 0

Reactivity

Stability indicator/materials to avoid: yes
strong oxidizing agents, strong acids, most common metals.

stability condition to avoid: high temperatures, sparks, and open flames
hazardous decomposition products: hydrogen sulfide

Proper Disposal

Waste disposal methods: dispose in accordance with all applicable
federal,state & local environmental regulations.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium sulfide, 9-hydrate
cas: 1313-84-4
rtecs #: we1925000
fraction by wt: 90-100%

MSDS BMCBJ SODIUM SULFIDE (NA2S) NONAHYDRATE

Hazards

Ld50 lc50 mixture: ld50 (oral rat) is 208 mg/kg (anhydrous)
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute-corrosive.Inhale: dust may cause
severe irritation,coughing,pulmonary edema,shortness of
breath,vomiting,dizziness,coma & death.Eye/skin: severe irritation &
pain,blurred vision.Oral: may burn seve rely causing
difficult/impossible speech&
swallowing.Chronic-dermatitis,conjunctivitis & symptoms of acute
exposures.

effects of overexposure: corrosive. Dust may cause severe irritation,
coughing, pulmonary edema, shortness of breath, vomiting,
dizziness, coma & death. Severe eye/skin irritation & pain, blurred
vision. Orally may burn sever ely causing difficult/impossible
speech& swallowing.

medical cond aggravated by exposure: persons with pre-existing skin
disorders or eye problems or impaired respiratory function may be
more susceptible to the effects of the substance.

First Aid

First aid: get medical help in all cases.Skin: wash with soap &
water.Eye: flush with water for 15 minutes,holding eyelids
open.Inhaled: remove to fresh air & provide oxygen/cpr if
needed.Oral: if conscious,drink 2- 4 glasses of water & induce
vomiting.

Chemical Properties

Hcc: b1
melt/freeze pt: m.P/f.P text: 122f,50c
decomp temp: decomp text: 1688f,920c
spec gravity: 1.427
ph: alk.

solubility in water: 47.5% @ 10c
appearance and odor: colorless deliquescent crystals, hydrogen sulfide
odor

Reactivity

Stability indicator/materials to avoid: no
acids,metals,diazonium salts,n,n-dichloromethylamine,strong
oxidizers,(al,cu,zn & their alloys),na carbonate,carbon
stability condition to avoid: flame
hazardous decomposition products: toxic oxides of sulfur

Proper Disposal

Waste disposal methods: dispose of in accordance with local, state and
federal regulations.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium sulfide nonahydrate
cas: 1313-84-4
rtecs #: we1925000
fraction by wt: >99.9%
other rec limits: 20 ppm(hydrogen sul)
osha pel: none established
acgih tlv: none established

MSDS BNPZX SODIUM SULFIDE NONAHYDRATE, 98% A.C.S. REAG

Hazards

Ld50 lc50 mixture: ld50 (ip-mus) is 53 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: material is extremely destructive to
tissue of the mucous membranes and upper respiratory tract, eye and
skin. Inhalation may be fatal as a result of spasm, inflammation
and edema of the larynx and br onchi, chemical pneumonitis and
pulmonary edema.

explanation of carcinogenicity: to the best of our knowledge, the
chemical, physical and toxilogocal properties have not been
thoroughly investigated.

effects of overexposure: symptoms of exposure may inclusde burning
sensation, coughing, wheezing, laryngitis, shortness of breath,
headache, nausea and vomiting.

medical cond aggravated by exposure: none specified by manufacturer.

First Aid

First aid: in case of contact, immediately flush eyes or skin with
copious amounts of water for at least 15 mi. While removing
contaminated clothing and shoes. If inhaled, remove to fresh air.

if not breathing g ive cpr. If breathing is difficult giveoxygen.

if swallowed, wash moutth out with water to provided person is
conscious. Call a physicain.

Chemical Properties

Hcc: b1
spec gravity: 1.427
appearance and odor: white crystalline chunks.

Reactivity

Stability indicator/materials to avoid: yes
strong acids.

stability condition to avoid: air sensitive, light sensitive.

hazardous decomposition products: sulfur oxides, hydrogen sulfide gas.

Proper Disposal

Waste disposal methods: treat a dilute basic solution (ph 10-11) of the
material with a 50% excess of commercial laundry bleach. Control
the ph if necessary. Control the temperature by the addition rate
of bleach & adjust ph if necessary. Let stand
overnight.**seeprecaut**
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium sulfide, nonahydrate
cas: 1313-84-4
rtecs #: we1925000
fraction by wt: 100%
other rec limits: none specified

MSDS BXCMV SODIUM SULFIDE,37 E 5535

Hazards

Ld50 lc50 mixture: ld50 (oral, rat) is 208 mg/kg.

routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eye, skin, respiratory &
gi tracts. Acute- corrosive. Harmful by ingestion, inhalation/skin
absorption. Eyes/skin: causes severe burns. May cause eye damage.

inhale: upper respiratory trac t inflammation. May be fatal.

oral: verytoxic. Causes burns, cns depression, cardiovascular
injury. Chronic- unknown.

explanation of carcinogenicity: none
effects of overexposure: severe burns, irritation, pain, eye damage,
skin inflammation and blistering, coughing, headache, nausea,
vomiting, convulsion, dizziness, coma, death
medical cond aggravated by exposure: individuals with pre-existing
diseases of the eye, skin, respiratory tract, cardiovascular,
central nervous system may have increased susceptibility to the
toxicity of excessive exposures.

First Aid

First aid: get immediate medical help for all cases of exposure.

eyes/skin: flush with water for at least 15 minutes. Hold eyelids
open. Remove contaminated clothing. Inhaled: remove to fresh air.

provide cpr/oxyg en if needed. Oral: do not induce vomiting. If
conscious, drink large amount of milk. If vomiting occurs
spontaneously, keep airway clear. Never give anything by mouth to
an unconscious person.

Chemical Properties

Hcc: b1
nrc/state lic num: not relevant
boiling pt: b.P. Text: decomposes
melt/freeze pt: m.P/f.P text: 122f,50c
decomp temp: decomp text: 428f,220c
spec gravity: 1.43
viscosity: not relevant
evaporation rate & reference: not relevant
solubility in water: 125%
appearance and odor: white crystals - hydrogen sulfide odor

Reactivity

Stability indicator/materials to avoid: no
acids, oxidizers, metals, silver oxide, hydrazine, carbon, water,
mercaptane, diazonium salts, carbon dioxide, bisulfite
stability condition to avoid: light, air, moisture, high temperatures,
sparks, flames, all other sources of ignition
hazardous decomposition products: hydrogen sulfide, sulfur dioxide

Proper Disposal

Waste disposal methods: discharge, treatment or disposal is subject to
local, state and federal regulations. Small quantities may be
dissolved in water and neutralized with acid. The neutralized
solution may be flushed down the drain if permitted.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium sulfide nonahydrate/sodium sulphide
cas: 1313-84-4
rtecs #: we1925000
fraction by wt: 98- 100%
other rec limits: none recommended