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Nitric acid and sulfonitric acids
Nitric acid; sulfonitric acids
Chemicals-inorganic
Y - Indicates information is in the hazardous materials information resource system (hmirs).
PMICA - Item does not contain precious metal.
CRITL- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.
043940 - Chemicals noi
450 - Acids, liquid, corrosive
9 - Other or no special handling required (sh)
A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.
C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp
W - Rating variable
W - Corrosive materials, un class 8 (corrosive label)
Questions & Answers: |
|
| What are the historical prices recorded for this stock number? | |
| Historical data shows pricing from $76.75 to $127.91.. | |
| Does NSN 6810-00-237-2918 have a shelf life? | |
| No. There is no shelf life applicable for this NSN. | |
| What NATO entities are users of this NSN? | |
| Bulgaria, Spain, Singapore, Malaysia, Australia, Canada, Germany, Republic Of Korea, Italy, Greece, and Turkey | |
| What is the NIIN of NSN 6810-00-237-2918? | |
| 002372918 or 00-237-2918 | |
| Does NSN 6810-00-237-2918 require demilitarization? | |
| Yes - ITAR Controlled | |
| What is the most recent solicitation for NSN 6810-00-237-2918? | |
| No solicitations for this NSN. | |
| When was this national stock number assigned to the federal catalog? | |
| Jan 01, 1963 | |
Effects of overexposure: skin and eyes: burns.Inhalation: irritation and
toxic. Development of pulmonary edema.
First aid: eyes: flush eyes with water for 15 minutes. Call
doctor.Skin: clothing must be removed and decontaminate skin by
shower for at least 15 minutes. Inhalation: call doctor.Remove
victim from area. Oxygen gi ven if patient has any symptoms.
Hcc: c1
boiling pt: b.P. Text: 244f,118c
spec gravity: 1.38
evaporation rate & reference: < 1 (ether = 1)
solubility in water: complete
appearance and odor: colorless to light yellow liquid with a pungent
odor.
Stability indicator/materials to avoid: yes
organic material/combustibles,most metal,oxidizable matl.
stability condition to avoid: high temperatures
hazardous decomposition products: oxides of nitrogen at high
temperatures
conditions to avoid polymerization: improper designed equipment
(storage)
Waste disposal methods: dilute with water,neutralize with alkali and
flush to sewer with plenty of water if permitted by applicable
disposal regulations.Neutralized waste may have to be disposed of
by an approved contractor.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara iii)
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: >61%
osha pel: 2 ppm/4 stel
acgih tlv: 2 ppm/4 stel; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt:
Effects of overexposure: causes severe burns.Vapor/gas extreme
hazard.Symptoms may be delayed.May cause nitrous gas poison.
First aid: remove to fresh air; get medical attention; give cpr or
oxygen if need. If contact,flush w. H2o for 15 min. Speed of
removal is critical. Remove & isolate contaminated clothing. Keep
warm & quiet.Effe cts may be delayed; observe victim.
Hcc: c1
boiling pt: b.P. Text: 248f,120c
vapor pres: 4
vapor density: 1.4
spec gravity: 1.4078
evaporation rate & reference: < 1 (ether = 1)
solubility in water: complete
appearance and odor: water white-pale yellow liquid with an acrid odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
metals,alkali,carbides,hydrogen sulfide,flammables acids
stability condition to avoid: spillage may release dangerous gas.
hazardous decomposition products: oxides of nitrogen.
Waste disposal methods: wear rubber cloves,scba, protect clthg. Add
slowly to lg vol of agitated soln of na2 co2 & ca(oh)2. Add this
soln to lg excess of h20. Elim ign sources or keep in covd drs.
hdle & dispose lw all appl intern, fed, state & local regs.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara iii)
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 67.2%
osha pel: 2 ppm/4 stel
acgih tlv: 2 ppm/4 stel; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 32.8%
Ld50 lc50 mixture: not provided
routes of entry: inhalation: yes skin: yes ingestion: no
health hazards acute and chronic: eye: can cause permanent eye injury.
can injure cornae & cause blindness. Skin: can cause permanent skin
damage. Swallowing: swallowing material may be harmful. May cause
burns & destroy tissue in mo uth, throat & digestive tract. Low
blood pressure & shock may occur as result of severe tissue injury.
inhalation: breathing of vapor or mist is possible. Brathing may be
harmful or fatal.
explanation of carcinogenicity: not provided
effects of overexposure: eyes: stinging, tearing, redness & swelling of
eyes. Skin: redness, burning & swelling of skin, burns & other skin
damage. Swallowing: severe stomach & intestinal irritation (
nausea, vomiting, diarrh ea), abdominal pain, vomiting of blood.
medical cond aggravated by exposure: preexisting conditions of following
organs (or organ systems) may be aggrevated by exposure to
material: skin, lung (for example, asthma-like conditions).
First aid: eyes: immediately flush gently with water for at least 15
minutes while holding eyelids apart. If symptoms develop due to
vapor exposure move from exposure. Get medical help. Skin: remove
contaminated clothes. Flush area with large amountsof water. If
skin is damaged, get medical help. If symptoms continue, get
medical help. Launder clothes before reuse. Ingestion: get
immediate medical help. Do n ot induce vomiting. If conscious,
rinse mouth with water & give water or milk to drink. Inhalation:
move to fresh air. Get immediate medical help. If not breathing
give cpr. If breathing difficult, gi ve oxygen. Keep warm & quiet.
Hcc: c1
boiling pt: =117.8c, 244.F
vapor pres: 6.8 mmhg @ 68f
vapor density: > 1.0
spec gravity: 1.408
evaporation rate & reference: slower than ether
solubility in water: complete
appearance and odor: fuming white to yellow liquid
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
organic materials, reducing agents, strong alkalies. Reacts with most
metals to release hydrogen gas which can form explosive mixtures
with air.
hazardous decomposition products: nitrogen compounds, acid fumes
Waste disposal methods: scoop up and place in suitable container or pump
to salvage tank to await proper disposal. Dispose of in accordance
with local, state & federal regulations.
Ingred name: nitric acid (sara iii)
cas: 7697-37-2
rtecs #: qu5775000
= wt: 67.
osha pel: 2 ppm/4 stel
acgih tlv: 2 ppm/4 stel; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
minumum % wt: 31.
maxumum % wt: 35.
Effects of overexposure: severe burns to skin & eyes.Accelerates
respiratory rate.Inhalation symptoms may not appear for hrs.
First aid: eyes & skin-flush with large amounts of water for at least 15
min.Ingestion-give large amounts of water.Get physician
immediately! Inhalation-move to fresh air-call physician.
Hcc: c1
boiling pt: =86.1c, 187.F
spec gravity: 1.502
evaporation rate & reference: colorless liquid,o
appearance and odor: dor-sweet to acrid
Stability indicator/materials to avoid: yes
organic materials,combustibles,most metals area attacked
stability condition to avoid: high temperatures
hazardous decomposition products: oxides of nitrogen at high
temperatures
Waste disposal methods: after neutralization place material in
containers suitable for shipment to disposal area.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara iii)
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 61%
osha pel: 2 ppm/4 stel
acgih tlv: 2 ppm/4 stel; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Effects of overexposure: accelerated respiratory rate, decreased vital
capacity. Causes intense pain and severe burns to eyes
First aid: eyes: rinse with water.Skin: fully wash with 5% solution of
sodium bicarbonate,or soap and water. Burns: treat with cloth
immersed in a saturated solution of potassium
thiosulfate.Internal;orally adminis ter soap solution,calcium
hydroxide,aluminum hydro
Hcc: c1
boiling pt: b.P. Text: 187f,86c
vapor pres: 62
spec gravity: 1.504
solubility in water: complete
appearance and odor: transparent, colorless to yellow liquid with a
pungent odor.
Stability indicator/materials to avoid: yes
stability condition to avoid: elevated temperatures and pressures
hazardous decomposition products: hydrogen in contact with
metals;nitrogen oxides.
Waste disposal methods: add slowly to a large amount of solution of soda
ash and slaked lime by stirring.Discharge the solution into
approved storage container.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara iii)
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 61%
osha pel: 2 ppm/4 stel
acgih tlv: 2 ppm/4 stel; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: corrosive! Inhalation can cause
coughing, choking, & inflamation of the respiratory tract.
swallowing can cause burns to mouth & g.I. Tract. Eye contact can
cause severe burns & damage. Skin co ntact can cause severe burns
and deep ulcers & discolor skin.Lung injury possible.
explanation of carcinogenicity: data per msds
effects of overexposure: severe irritation of the nose, throat, upper
respiratory tract, eyes, skin and mucous membranes. Very corrosive
and can cause severe burns and damage.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the eyes, skin, or
respiratory tract may be at increased risk from exposure.
First aid: inhalation: remove to fresh air. Resuscitate if not breathing.
get medical attention. Eyes: immediately flush with plenty of water
for 15 minutes holding eyelids open. Get immediate medical
attention. S kin: remove contaminated clothing. Wash with soap and
water. Get immediate medical attention. Ingestion: do not induce
vomiting. Give nothing by mouth if unconscious. Get immediate
medical attention.
Hcc: c1
boiling pt: b.P. Text: 246f,119c
melt/freeze pt: m.P/f.P text: -6f,-21c
vapor density: 1.6-1.7
spec gravity: 1.355-1.408
evaporation rate & reference: < 1.0 (n-butyl acetate)
solubility in water: 100 %
appearance and odor: clear, colorless liquid with a sharp, pungent odor.
percent volatiles by volume: 100.0
Stability indicator/materials to avoid: yes
organic,and combustible,wood or wood dust,finely divided metals.
stability condition to avoid: high temperatures, sparks, and open flames
or direct sunlight
hazardous decomposition products: when heated to decompositon, emits
toxic vapors of no or no2. Will react with water to produce heat
and toxic fumes.
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state and local laws and regulations. Dispose
in a rcra-approved waste facility or sewer the neurtalized slurry
with excess water if local ordinances allow.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara iii)
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 56-67%
other rec limits: none specified
osha pel: 2 ppm/4 stel
acgih tlv: 2 ppm/4 stel; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
other rec limits: none specified
Routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: corrosive! Inhalation can cause
coughing, choking, & inflamation of the respiratory tract.
swallowing can cause burns to mouth & g.I. Tract. Eye contact can
cause severe burns & damage. Skin co ntact can cause severe burns
and deep ulcers & discolor skin. Chronic: unknown.
explanation of carcinogenicity: nitric acid is not listed by iarc, ntp,
or osha as a carcinogen.
effects of overexposure: inflammation of the nose, throat, upper
respiratory tract, eyes, skin and mucous membranes. Very corrosive
and can cause severe burns and damage. Long term exposures seldom
occur due to the corrosive properties of the acid.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the eyes, skin, or
respiratory tract may be at increased risk from exposure.
First aid: inhalation: remove to fresh air. Resuscitate if not breathing.
get medical attention. Eyes: immediately flush with plenty of water
for 15 minutes holding eyelids open. Get immediate medical
attention. S kin: remove contaminated clothing. Wash with soap and
water. Get immediate medical attention. Ingestion: do not induce
vomiting. Give lots of water to drink. Get immediate medical
attention.
Hcc: c1
boiling pt: b.P. Text: 252f,122c
melt/freeze pt: m.P/f.P text: -42f,-41c
vapor pres: 8
vapor density: 1
spec gravity: 1.40
ph: < 1
evaporation rate & reference: < 1
solubility in water: complete
appearance and odor: clear, colorless to yellow liquid.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizing agents,combustible & organic materials, metals & metal
powders.
stability condition to avoid: extremely high temperatures
hazardous decomposition products: when heated, emits toxic fumes and
nitrogen oxides.
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state and local laws and regulations. Dispose
in a rcra-approved waste facility or sewer the neutralized slurry
with excess water if local ordinances allow.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara iii)
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 62-68%
other rec limits: none specified
osha pel: 2 ppm/4 stel
acgih tlv: 2 ppm/4 stel; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: corrosive & poison!
acute-inhalation: may be fatal., lung injury, coughing, choking, &
inflamation of the respiratory tract. Ingestion: harmful,burns to
mouth & g.I. Tract. Eye: severe burns & damage. Sk in: severe burns
and deep ulcers & discoloration of skin.
effects of overexposure: severe irritation of the nose, throat, upper
respiratory tract, eyes, skin and mucous membranes. Severe burns
and damage to tissues.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the eyes, skin, or
respiratory tract may be at increased risk from exposure.
First aid: inhalation: remove to fresh air. Resuscitate if not breathing.
get medical attention. Eyes: immediately flush with plenty of water
for 15 minutes holding eyelids open. Get immediate medical
attention. S kin: remove contaminated clothing. Wash with soap and
water. Get immediate medical attention. Ingestion: do not induce
vomiting. Give nothing by mouth if unconscious. Get immediate
medical attention.
Hcc: c1
boiling pt: b.P. Text: 246f,119c
melt/freeze pt: m.P/f.P text: -6f,-21c
vapor density: 1.6-1.7
spec gravity: 1.355-1.408
evaporation rate & reference: < 1.0 (n-butyl acetate)
solubility in water: 100 %
appearance and odor: clear, colorless liquid with a sharp, pungent odor.
percent volatiles by volume: 100.0
Stability indicator/materials to avoid: yes
organic,and combustible,wood or wood dust,finely divided metals.
stability condition to avoid: high temperatures, sparks, and open flames
or direct sunlight
hazardous decomposition products: when heated to decompositon, emits
toxic oxides of nitrogen. Will react with water to produce heat and
toxic fumes.
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state and local laws and regulations. Dispose
in a rcra-approved waste facility or sewer the neurtalized slurry
with excess water if local ordinances allow.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara iii) *
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: >61%
other rec limits: none specified
osha pel: 2 ppm/4 stel *
acgih tlv: 2 ppm/4 stel; 9192 *
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
other rec limits: none specified
Ld50 lc50 mixture: tlv: air: 2 ppm
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eye-"danger" corrosive. Skin"danger"
corrosive. Inhalation-hramful if inhaled. Ingestion-harmful if
swallowed.
explanation of carcinogenicity: this compound contains no ingredients at
concentrations of 0.1% or greater that are carcinogens or suspect
carcinogens.
effects of overexposure: skin irritation/burns, eye irritation/burns,
respriatory tract irritation, gi tract damage.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: eyes-immediately flush with plenty of clean water for at
least 15 min. Call a physician. External-immediately flush skin
with plenty of running water for at least 15 minutes. Call
physician internal-d o not induce vomiting. Immediately drink a
lareg quantity of milk or water abd call a physician.
inhalation-immeidtaely move to fresh air. If not breathing perform
cpr. If hard breathe, give oxygen.
Hcc: c1
boiling pt: b.P. Text: 250f,121c
melt/freeze pt: m.P/f.P text: -31f,-35c
decomp temp: decomp text: not given
vapor pres: not given
vapor density: not given
spec gravity: 1.408
ph:
evaporation rate & reference: not given
solubility in water: complete
appearance and odor: clear, colorless to pale yellow liquid with a sharp
acidic odor.
Stability indicator/materials to avoid: yes
alkali, oxidizable organics, other oxidizers, chlorine releasers,
sulfur, suifides, cyanides, aluminum, magneseium and .
stability condition to avoid: none specified by manufacturer.
hazardous decomposition products: when heated to decomposition, it emits
toxc nitric acid fumes and toxic oxides of nitrogen.
Waste disposal methods: dispose of product in a lecensed hazardous waste
disposal facility in accordance with all applicable laws. When
empty thoroughly rinse container with water before disposal, return
to manufacturer or a ny other industrial use.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara iii)
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 67% min
other rec limits: none recommended
osha pel: 2 ppm
acgih tlv: 2 ppm/4 stel; 9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: corrosive! Inhalation: severe
irritation of the respiratory tract. Ingestion: harmful or fatal,
cause severe burns to mouth & g.I. Tract. Eye: can cause severe
burns & irreversible damage. Skin: ca n cause severe burns and deep
ulcers. Chronic-dental erosion, chronic brochitis, lung damage.
explanation of carcinogenicity: data per msds
effects of overexposure: severe irritation and burns of the nose,
throat, upper respiratory tract, eyes, skin and mucous membranes.
stinging, teariing, redness, swelling, pain.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the eyes, skin, or
respiratory tract may be at increased risk from exposure.
First aid: inhalation: remove to fresh air. Resuscitate if not breathing.
get medical attention. Eyes: immediately flush with plenty of water
for 15 minutes holding eyelids open. Get immediate medical
attention. S kin: remove contaminated clothing. Wash with soap and
water. Get immediate medical attention. Ingestion: do not induce
vomiting. Drink 1-2 glasses of milk. Get immediate medical
attention.
Hcc: c1
boiling pt: b.P. Text: 246f,119c
melt/freeze pt: m.P/f.P text: -6f,-21c
vapor density: 1.5-1.7
spec gravity: 1.355-1.408
ph:
evaporation rate & reference:
solubility in water: complete
appearance and odor: clear, colorless liquid with a sharp, pungent odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
organic,and combustible,wood or wood dust,finely divided metals.
stability condition to avoid: high temperatures, sparks, and open flames
or direct sunlight
hazardous decomposition products: toxic vapors of nitrogen oxides (no &
no2).
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state and local laws and regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara iii)
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 56-67%
other rec limits: none specified
osha pel: 2 ppm/4 stel
acgih tlv: 2 ppm/4 stel; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 33-44%
other rec limits: none specified
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: exposure to nitric acid represents
dual health hazard: specifically, tissue corrosion from topical
contact and acute pulmonary edema or chronic obstructive pulmonary
disease from inhalation.
explanation of carcinogenicity: not carcinogenic.
effects of overexposure: irritation of eyes, respiratory system. Eye
burns. Skin burns with yellowing of skin. Delayed pulmonary edema.
dental erosion.
medical cond aggravated by exposure: eye, skin, lungs, teeth,
respiratory system.
First aid: eye, skin-immediate water flush. Inhalation-fresh air,
artificial respiration. Ingestion-call physician!!
Hcc: c1
boiling pt: b.P. Text: 183f-251f
melt/freeze pt: m.P/f.P text: -42 to -61f
vapor pres: 2.6-103
spec gravity: 1.5 (h2o=1)
solubility in water: miscible
appearance and odor: colorless or yellowish, fuming, liquid. Choking
odor.
Stability indicator/materials to avoid: yes
combustible matter, strong bases, metal power, oxidizable material.
stability condition to avoid: heat, sparks, flame, steam. Combustible
materials.
hazardous decomposition products: toxic and corrosive fumes, nox,
hydrogen nitrate
Waste disposal methods: to be performed in compliance with all local,
state, and federal regulations. Note: epa hazardous substance.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara iii)
cas: 7697-37-2
rtecs #: qu5775000
osha pel: 2 ppm;4 ppm stel
acgih tlv: 2 ppm;4 ppm stel
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: none specified by manufacturer.
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: danger!Causes burns to
skin/eyes.Eye: corro to eye w/possible perm dmg depending on length
of expo & 1staid action given.Skin: corro to skin possibly resulting
in 3rd degree burns depending on length of expo & 1staid action
given.Can be harmful if absorbed.Can cause allergic contact derm in
susceptible people.(supplemen)
effects of overexposure: a review of available data does not identify
any symptoms from exposure not previously mentioned.
medical cond aggravated by exposure: a review of available data does not
identiy any worsening of existing conditions.
First aid: eye: immed flush for @least 15mins while holding eyelids
open.Call dr @once.Skin: immed flush w/watwer for @least 15mions.For
lg splash flood body under shower.Call dr @once.Ingest: dont induce
vomit.Giv e water.Call dr.Inhal: remove to fresh air.Treat
symptoms.Call dr.Dr: based on individual reactions of patient dr's
judgment should be used to control sympt/clinc
condition.Unfonc/trouble breath (suppl)
Hcc: c1
boiling pt: b.P. Text: np
melt/freeze pt: m.P/f.P text: np
decomp temp: decomp text: np
vapor pres: np
vapor density: np
spec gravity: np
ph:
viscosity: np
evaporation rate & reference: np
solubility in water: completely
appearance and odor: colorless, liquid, acrid odor
percent volatiles by volume: np
corrosion rate: np
Alkaline
matls(ammonia/solns,carbonates,naoh(caaustic),koh,ca(oh)2(lime),cya
nides,sulfides,hypochlorites,chlorites)(sup)
stability condition to avoid: none specified by manufacturer.
hazardous decomposition products: event of combustion co2,nox may be
formed.Dont breath smoke.Fumes.Wear suitable protective eqpmt.
Waste disposal methods: released into enviro see cercla.Product becojes
waste meets criteria of haz waste per rcra-d002.Acid solns should
be neutrali bef discharge to sanitary sewer.Altern may be dispo
into waste treat plant which has ph cntrl sys in
operation.(hndl/storag)
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara 302/313) (cercla)
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 10%
other rec limits: none recommended
osha pel: 2 ppm
acgih tlv: 2 ppm/4 stel; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: tlv 2 ppm. Lc50 (4 hr, rat): 49 ppm
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eyes, skin, teeth,
respiratory & gi tracts. Acute- corrosive. Inhale: few minutes
exposure to high concentrations (>200 ppm) may cause death.
eye/skin: severe burns. May cause damage/death . Oral: severe
abdominal pain, kidney damage, collapse, death. Chronic- erosion of
teeth, lesions on skin, pneumonia.
explanation of carcinogenicity: none
effects of overexposure: severe irritation, burns, coughing, difficult
breathing, chest pain, abdominal pain, nausea, vomiting, dental
erosion, chocking, skin redness or yellow-brown stain, eye damage,
skin lesions, death
medical cond aggravated by exposure: persons with pre-existing skin
disorders, eye, cardio pulmonary and lung diseases may be more
susceptible to the effects of this product.
First aid: get immediate medical help for all cases of exposure.
eye/skin: at once flush with water for at least 15 minutes. Hold
eyelids open. Inhaled: move to fresh air. Provide cpr/oxygen if
needed. Oral: do not induce vomiting. If conscious, drink large
amount of milk/water, milk of magnesia or egg white. Never give
anything by mouth to an unconscious person.
Hcc: c1
nrc/state lic num: not relevant
boiling pt: b.P. Text: 181f - 251f
melt/freeze pt: m.P/f.P text: -29 to -44f
vapor pres: 9
vapor density: 1.4
spec gravity: 1.3 - 1.5
ph: 1 0.1m
evaporation rate & reference:
solubility in water: 100%
appearance and odor: clear, colorless to yellow to light brown liquid;
suffocating/pungent odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
bases, carbides, cyanides, combustibles, organic materials, active
metals, turpentine, hydrogen sulfide, iron, copper
stability condition to avoid: heat, water or steam
hazardous decomposition products: oxides of nitrogen including nitrous
oxide (n2o), nitric oxide (no), nitrogen dioxide (no2); nitric acid
mist or vapors
Waste disposal methods: observe federal, state and local environmental
regulators for proper disposal. Consider recycling. Keep
combustibles away from spilled material.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara 302/313) (cercla)
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 56 - 70%
other rec limits: none recommended
osha pel: 2 ppm
acgih tlv: 2 ppm/4 stel; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
other rec limits: none recommended
osha pel: not relevant
acgih tlv: not relevant
Ld50 lc50 mixture: tlv 2 ppm. Lc50 (4 hr, rat): 49 ppm
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eyes, skin, teeth,
respiratory & gi tracts. Acute- corrosive. Inhale: few minutes
exposure to high concentrations (>200 ppm) may cause death.
eye/skin: severe burns. May cause damage/death . Oral: severe
abdominal pain, kidney damage, collapse, death. Chronic- erosion of
teeth, lesions on skin, pneumonia.
explanation of carcinogenicity: none
effects of overexposure: severe irritation, burns, coughing, difficult
breathing, chest pain, abdominal pain, nausea, vomiting, dental
erosion, chocking, skin redness or yellow-brown stain, eye damage,
skin lesions, death
medical cond aggravated by exposure: persons with pre-existing skin
disorders, eye, cardio pulmonary and lung diseases may be more
susceptible to the effects of this product.
First aid: get immediate medical help for all cases of exposure.
eye/skin: at once flush with water for at least 15 minutes. Hold
eyelids open. Inhaled: move to fresh air. Provide cpr/oxygen if
needed. Oral: do not induce vomiting. If conscious, drink large
amount of milk/water, milk of magnesia or egg white. Never give
anything by mouth to an unconscious person.
Hcc: c1
nrc/state lic num: not relevant
boiling pt: b.P. Text: 186f - 252f
melt/freeze pt: m.P/f.P text: -29 to -44f
vapor pres: 9
vapor density: 1.4
spec gravity: 1.3 - 1.5
ph: 1 0.1m
evaporation rate & reference:
solubility in water: 100%
appearance and odor: clear, colorless to yellow to light brown liquid;
suffocating/pungent odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
bases, carbides, cyanides, combustibles, organic materials, active
metals, turpentine, hydrogen sulfide, iron, copper
stability condition to avoid: heat, water or steam
hazardous decomposition products: oxides of nitrogen including nitrous
oxide (n2o), nitric oxide (no), nitrogen dioxide (no2); nitric acid
mist or vapors
Waste disposal methods: observe federal, state and local environmental
regulators for proper disposal. Consider recycling. Keep
combustibles away from spilled material.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara 302/313) (cercla)
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 90 - 99%
other rec limits: none recommended
osha pel: 2 ppm
acgih tlv: 2 ppm/4 stel; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
other rec limits: none recommended
osha pel: not relevant
acgih tlv: not relevant
Ld50 lc50 mixture: lc50 (inhalation, rat): 244 ppm no2/30m
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eyes, skin, respiratory
and gastrointestinal tracts. Acute - poison! Danger! Strong
oxidizer, corrosive!. Inhalation of vapors can result in breathing
difficulties and lead to pneumoni a and pulmonary edema, which may
be fatal. vapors are irritating and may cause damage to eyes. May
cause severe burns and permanent eye damage. Can cause severe skin
burns, deep ulcers and stain skin a yellow or yellow-brown color.
swallowing nitric acid can cause immediate pain and burns of the
mouth, throat, esophagus and gastrointestinal tract. Chronic -
vapors may cause erosion of teeth and l ung damage.
explanation of carcinogenicity: none
effects of overexposure: severe irritation, severe burns; cough, nausea,
nasal discharge, respiratory failure, redness of eyes, blurred
vision, burning sensation in mouth and pharynx, salivation,
abdominal pain, vomiting bloo d, diarrhea, hematuria, difficulty
breathing, shock, rapid pulse, death, blindness, erosion of teeth,
deep skin ulcers, yellow skin stain, pain
medical cond aggravated by exposure: persons with pre-existing skin
disorders, eye problems or impaired cardiovascular diseases may be
more susceptible to the effects of this product.
First aid: obtain medical attention immediately. Inhaled: remove from
exposure to fresh air immediately. If not breathing, give
artificial respiration. If breathing is difficult, give oxygen.
eyes: immediately flush eye with plenty of water for at least 15
minutes. Occasionally lifting the upper and lower lids. do not
allow victim to rub or keep eyes closed. Skin: flush with large
amount of running water f or at least 15 minutes. Ingestion: do not
induce vomiting. If victim is conscious and alert, wash out mouth
with running water. Give large quantities of milk or water to
drink.
Hcc: c1
boiling pt: =122.2c, 252.F
melt/freeze pt: =-42.C, -43.6f
vapor pres: (mm hg)48@20c(68f)
vapor density: (air=1)2.3
spec gravity: 1.41
ph: 1.0(0.1m solut)
solubility in water: infinitely soluble
appearance and odor: colorless to yellowish liquid - suffocation acid
odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
most substances, especially strong bases, metallic powders, carbides,
hydrogen sulfide, turpentine, and combustible organics
stability condition to avoid: stable under ordinary conditions of use
and storage. Containers may burst when heated.
hazardous decomposition products: toxic vapors of nitrogen oxides and
hydrogen nitrate, corrosive fumes
conditions to avoid polymerization: will not occur.
Waste disposal methods: whatever cannot be saved for recovery or
recycling should be handled as hazardous waste. Dispose of waste in
accordance with local, state, and federal laws and regulations.
dispose of container and un used contents in accordance with
federal, state and local requirements.
Ingred name: nitric acid (sara iii)
cas: 7697-37-2
rtecs #: qu5775000
minumum % wt: 65.
maxumum % wt: 70.
other rec limits: none specified
osha pel: 2 ppm/4 stel
acgih tlv: 2 ppm/4 stel; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
minumum % wt: 30.
maxumum % wt: 35.
other rec limits: none specified
ld50 lc50 mixture: ld50 (oral, rat) n/k
route of entry inds - inhalation: yes
skin: no
ingestion: no
carcinogenicity inds - ntp: no
iarc: no
osha: no
effects of exposure: target organs: eyes, skin, mucous membranes of the
respiratory tract, teeth. This material is corrosive to any body tissues it
contacts. Dental erosion is also reported. Acute effects - irritation an
d/or corrosive burns of skin, eyes, andupper respiratory tract (urt), delayed
pulmonary edema, pneumonitis, bronchitis, and dental erosion. Chronic effects
- none reported.
explanation of carcinogenicity: none
signs and symptions of overexposure: dental erosion, severe irritation, pain,
burns of skin, eyes, and upper respiratory tract
medical cond aggravated by exposure: none reported.
first aid: inhalation: remove exposed person to fresh air; restore and/or
support his or her breathing as needed. If exposure is severe,
hospitalization is needed. Eye contact: immediately flush eyes, including
under eyelids, gently with plenty of running water for at least15 minutes.
treat for eye burns. Skin contact: immediately wash affected area with soap
and water. Treat chemical burns. Ingestion: call a poison control center.
never give anything by mouth to someone who is unconscious or convulsing. Do
not induce vomiting. If person is responsive, give him or her 1-2 glasses of
milk or water to drin k as soon as possible. Get medical help.
hcc: c1
boiling point: =121.7c, 251.F
melt/freeze pt: =-34.4c, -30.F
spec gravity: 1.4(h20=1)
ph: very acidic
solubility in water: complete
appearance and odor: c/ce please fill out this part.
product id: nitric acid
cage: 75656
company name: los angeles chemical co
street: 4545 ardine st
po box: 1987
city: south gate ca
zipcode: 90280
health emergency phone: 323-562-9500
label required ind: y
date of label review: 08/18/1999
status code: a
year procured: 1999
origination code: f
eye protection ind: yes
skin protection ind: yes
signal word: danger
respiratory protection ind: yes
health hazard: severe
contact hazard: severe
fire hazard: none
=======================================================
responsible party cage: 75656
trans id no: 147395
product id: nitric acid
msds prepared date: 05/21/1993
review date: 08/19/1999
mfn: 1
net unit weight: 7.29 lbs
multiple kit number: 0
unit of issue: bt
container qty: 0
type of container: see addn info
additional data: the un id number and the percentage per the manufacturer.
cargo aircraft only.
Hazard and precautions: target organs: eyes, skin, mucous membranes of the
respiratory tract, teeth. This material is corrosive to any body tissues it
contacts. Dental erosion is also reported. Acute effects - irritation an
d/or corrosive burns of skin, eyes, andupper respiratory tract (urt), delayed
pulmonary edema, pneumonitis, bronchitis, and dental erosion. Chronic effects
- none reported.
spill release procedures: notify safety personnel, provide ventilation,
eliminate ignition sources. Cleanup personnel need protection against contact
with and inhaltion of nitric acid. Contain large spills and collect waste. U
se water sprays to direct acid away fromincompatibles. Neutralize spilled
acid with soda ash or sodium bicarbonate. Use sand, earth or vermiculite and
place into containers for disposal/reclamation.
neutralizing agent: soda ash or sodium bicarbonate
waste disposal methods: condider reclamation, recycling, or destruction rather
than disposal in a landfill. Contact your supplier or a licensed contractor
for detailed recommendations. Follow local, state, and federal regula tions.
handling and storage precautions: store nitric acid in a cool, dry,
well-ventilated area away from incompatible chemicals. Consider outside,
isolated or detached storage. Protect container from direct sunlight and
physical damage. Bu ild all storage facilities of nonflammable materials that
are resistant to nitric acid.
other precautions: do not eat, drink, or smoke in any work area. Provide annual
medical exams to workers who are exposed to nitric acid. Workers must receive
training before handling this material in the workplace. Keep acid off of
your clothing and equipment. Avoid transferring it from hands to mouth while
eating, dr inking or smoking.