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Nitric acid and sulfonitric acids
Nitric acid; sulfonitric acids
Chemicals-inorganic
Y - Indicates information is in the hazardous materials information resource system (hmirs).
PMICA - Item does not contain precious metal.
CRITL- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.
043940 - Chemicals noi
450 - Acids, liquid, corrosive
9 - Other or no special handling required (sh)
A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.
C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp
W - Rating variable
W - Corrosive materials, un class 8 (corrosive label)
Questions & Answers: |
|
| What are the historical prices recorded for this stock number? | |
| Historical data shows pricing from $99.87 to $166.46.. | |
| Does NSN 6810-00-237-2954 have a shelf life? | |
| No. There is no shelf life applicable for this NSN. | |
| What NATO entities are users of this NSN? | |
| Department Of The Army, Department Of The Air Force, U.s. Marine Corps, Department Of The Navy, Food and Drug Administration, Bureau Of Mines, Bureau Of Engraving and Printing, Bureau Of The Mint, National Aeronautics and Space Administration, Department Of Energy, Brazil, Republic Of Korea, Greece, and Turkey | |
| What is the NIIN of NSN 6810-00-237-2954? | |
| 002372954 or 00-237-2954 | |
| Does NSN 6810-00-237-2954 require demilitarization? | |
| Yes - ITAR Controlled | |
| What is the most recent solicitation for NSN 6810-00-237-2954? | |
| No solicitations for this NSN. | |
| When was this national stock number assigned to the federal catalog? | |
| Jan 01, 1963 | |
Ld50 lc50 mixture: ld50, 50-500 mg/kg oral- unspecified
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation- may cause severe
respiratory irritation. Pulmonary edema may be immediate. May cause
erosion of the teeth and possibly jaw necrosis. Bronchial pneumonia
may occur. Skin- severe pain and b urns. Possible dermatitis.
eyes- pain and lacrimation, photophobia, and burns. See
supplemental safety and health.
effects of overexposure: eye: pain,tearing,burns necrosis.
skin: yellow-brown
stain,burns,necrosis.Inhalation: cough,headache,dizziness,weakness,d
ry throat & nose,chest pain,dyspnea,cyanosis,pulm edema.
ingestion: pain,vomiting,b loody diarrhea,burns of mouth,trachea,gi
tract; circulatory collapse,asphyxia.
medical cond aggravated by exposure: any pre-existing sensitivity or
organ dysfunction.
First aid: get prompt medical attention all exposures! Eye: flush 15-20
minutes w/ample water. Skin: remove contaminated clothing. Wash
gently w/soap & water 15-20 minutes. Inhalation: remove to fresh
air. Give oxy gen or art respiration as required. Ingestion: do not
induce vomiting. If conscious,give ample cold water or milk diluent
then 2 oz milk magnesia or alumina (no carbonates).
Hcc: c1
boiling pt: b.P. Text: 181f,83c
melt/freeze pt: m.P/f.P text: -44f/-42c
vapor pres: 48 mmhg
vapor density: 3.2
spec gravity: 1.5
solubility in water: very soluble
appearance and odor: colorless to pale yellow liquid with a suffocating
odor.
Stability indicator/materials to avoid: yes
reducing agents, organic chemicals & materials, powdered metals, wood,
strong bases.
stability condition to avoid: extreme heat, sunlight
hazardous decomposition products: thermal decomposition products may
include toxic oxides of nitrogen.
Waste disposal methods: landspread or landfill iaw all laws & regs.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara iii)
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 70%
osha pel: 2 ppm/4 stel
acgih tlv: 2 ppm/4 stel; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 30%
Effects of overexposure: sever burns to eyes,skin.Inhal ov vapor damages
respir tract. Symptoms may be delayed.
First aid: skin: flush with plenty water.Eyes: flush w/water 15 min.Get
immediate medical attn.If inhaled;remove to fresh air,get immediate
medical attn.
Hcc: c1
nrc/state lic num: not relevant
boiling pt: =122.C, 251.6f
vapor pres: 8
vapor density: 1.58
spec gravity: 1.42
evaporation rate & reference:
solubility in water: complete
appearance and odor: colorless liquid,pungent odor.
Stability indicator/materials to avoid: yes
metals,h*2s,wood,excelsior,papre products,similar organics
hazardous decomposition products: poisonous oxides of nitrogen(gaseous)
Waste disposal methods: dilute and neutralize.If permitted by
local,state and federal regulations.Flush neutral residue to sewer
with plenty of water.Contact local authorities for disposal
compliance.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara iii)
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 70%
osha pel: 2 ppm/4 stel
acgih tlv: 2 ppm/4 stel; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 30%
Effects of overexposure: accelerated respiratory rate,decreased vital
capacity.Skin & eyes-intense pain & severe burns
First aid: eyes,skin-flush with water for 15 min.Skin-cover with baking
soda.Ingestion-give water with milk of magnesia or aluminum
hydroxide gel.Do not use baking soda or emetics.If above not
available give mil k or egg whites with water call doctor
immediately
Hcc: c4
nrc/state lic num: not relevant
boiling pt: =86.C, 186.8f
vapor pres: 62
spec gravity: 1.504
solubility in water: complete
appearance and odor: transparent,colorless to yellow,pungent odor,liq.
Stability indicator/materials to avoid: yes
organics,flammables,caustics
stability condition to avoid: avoid elevated temperatures and pressures
hazardous decomposition products: hydrogen in contact with
metals,nitrogen oxides
Waste disposal methods: add slowly to a large solution of soda ash and
slaked lime by stirring.Discharge the solution with large amount of
wate into an approved container
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara iii)
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 71%
osha pel: 2 ppm/4 stel
acgih tlv: 2 ppm/4 stel; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Effects of overexposure: vap or mists are extremely irritating & cause
burns.Fumes are particularly harmful *see addl data*
First aid: inh: remove to fresh air.Give oxygen/cpr if needed.Get med
attn;eyes/skin: flush w/lg amt h*2o for 15 min.Remove contmntd
clothes/shoes.Wash clothes before re-use.Get med attn;ing: give lg
qty milk/water contng magnesia milk.Do not induce vomitg.Get md.
Hcc: c4
nrc/state lic num: not relevant
boiling pt: =119.4c, 247.F
vapor pres: unk
vapor density: unk
spec gravity: 1.42
solubility in water: complete
appearance and odor: clear liquid,suffocating yellowish in color.
percent volatiles by volume: unk
Stability indicator/materials to avoid: yes
acetc acid,aniline,h*2cro*4,acetone,alcohol,flamm liq,hcn,cu
hazardous decomposition products: oxides on nitrogen,nitrous fumes.
Waste disposal methods: keep in covered drums,pending disposal. Handle &
dispose in full compliance with all applicable
international,federal,state, & local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara iii)
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 70.5%
osha pel: 2 ppm/4 stel
acgih tlv: 2 ppm/4 stel; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: unidentified components(as impurities not specified)
fraction by wt: unk
Ld50 lc50 mixture: tlv 2 ppm/lc50,mouse inhale: 67 ppm/4hrs
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eyes, skin, teeth,
respiratory & gi tracts. Acute- inhale: severe irritation/burns of
respiratory system, lung inflammation, unconsciousness & may be
fatal. Eye/skin: severe irritation/bur ns. Oral: severe burns,
ulceration of mouth, throat, stomach, dental erosion & may be
fatal. Chronic- none reported.
explanation of carcinogenicity: none
effects of overexposure: eyes, skin, respiratory and gastrointestinal
tracts irritation or burns; coughing, difficult breathing, chest
pain, abdominal pain, nausea, vomiting, dental erosion
medical cond aggravated by exposure: damaged skin, eye disorders,
lung/respiratory system diseases
First aid: get medical care immediately in all cases.
eyes/skin: immediately flush with water for at least 15 minutes.
keep eyelids open. Treat for chemical burns if necessary.
inhalation: remove to fresh air. Pro vide cpr/oxygen if needed.
ingestion: ifconscious, drink 1-2 glasses of milk/water. Do not
induce vomiting.
Hcc: c1
nrc/state lic num: not relevant
boiling pt: =121.7c, 251.F
melt/freeze pt: =-34.4c, -30.F
vapor density: unknown.
spec gravity: 1.4
ph:
solubility in water: complete
appearance and odor: a water white to slightly yellow liquid that
darkens; characteristic no2 odor
Stability indicator/materials to avoid: yes
bases, alcohols, cyanides, combustibles, organic materials, metallic
powders, carbides, hydrogen sulfides, turpentine
stability condition to avoid: heat, light
hazardous decomposition products: oxides of nitrogen including nitrous
oxide (n2o), nitric oxide (no), nitrogen dioxide (no2); nitric acid
mist or vapors
Waste disposal methods: observe federal, state and local environmental
regulators for proper disposal. Consider recycling. Keep
combustibles (wood, paper, oil, etc..) away from spilled material.
reportable quantity (rq) is 1 000 pounds.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara iii) - contact your supplier to
determine exact percent by weight of nitric acid in purchased
product
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 68%
other rec limits: none recommended
osha pel: 2 ppm
acgih tlv: 2 ppm/4 stel; 9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
Effects of overexposure: decoloration of the skin & acid burns.Extremely
corrosive to all body;vap hazardous to lungs.
First aid: immediately flush skin or eyes for 15 min. Remove
contaminated clothing or shoes. If inhaled, get to fresh air. In
all cases, call doctor
Hcc: c1
boiling pt: =86.C, 186.8f
spec gravity: 1.42
solubility in water: complete
appearance and odor: clear to slight yellow liq charactrstc chokg odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
metallic powders, carbides, hydrogen sulfide, terpentine
stability condition to avoid: spillage may release dangerous gas
hazardous decomposition products: oxides of nitrogen
Waste disposal methods: add slowly to large volume of soda ash solution
w/agitation. Add nutralized solution to running water & flush to
sewer.Handle & dispose iaw local,state & federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara iii)
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 70.0%
osha pel: 2 ppm/4 stel
acgih tlv: 2 ppm/4 stel; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: unidentified compenents;%wt by difference
fraction by wt: 30%
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: corrosive! Inhalation can cause
coughing, choking, & inflamation of the respiratory tract.
swallowing can cause burns to mouth & g.I. Tract. Eye contact can
cause severe burns & damage. Skin co ntact can cause severe burns
and eye damage. Chronic: concentrated vapors may cause
bronchitis,erosion of teeth.
explanation of carcinogenicity: data per msds
effects of overexposure: inflamation of the nose, throat, upper
respiratory tract, eyes, skin and mucous membranes. Very corrosive
and can cause severe burns and damage. Long term exposures seldom
occur due to the corrosive p roperties of the acid.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the eyes, skin, or
respiratory tract may be at increased risk from exposure.
First aid: inhalation: remove to fresh air. Resuscitate if not breathing.
get medical attention. Eyes: immediately flush with plenty of water
for 15 minutes holding eyelids open. Get immediate medical
attention. S kin: remove contaminated clothing. Wash with soap and
water. Get immediate medical attention. Ingestion: do not induce
vomiting. Give nothing by mouth if unconscious. Get immediate
medical attention.
Hcc: c1
boiling pt: =122.2c, 252.F
vapor pres: 62
vapor density: >1.0
spec gravity: 1.4073
ph: acid
evaporation rate & reference:
solubility in water: complete
appearance and odor: colorless liquid with a sharp pungent odor
percent volatiles by volume: 100.0
Stability indicator/materials to avoid: yes
strong bases,metallic powders,carbides,h*2s,and combustible organics.
stability condition to avoid: high heat, open flames and other sources
of ignition
hazardous decomposition products: when heated to decompositon, emits
toxic oxides of nitrogen fumes.
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state and local laws and regulations. Dispose
in a rcra-approved waste facility or sewer the neurtalized slurry
with excess water if local ordinances allow.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara iii)
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 70.0%
other rec limits: none specified
osha pel: 2 ppm/4 stel
acgih tlv: 2 ppm/4 stel; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
other rec limits: none specified
Ld50 lc50 mixture: ld 50 oral rat is
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: corrosive to all body tissues.
severe irritation and burns to eyes, skin, respiratory and
gastrointestinal tracts. Chronic: dermatitis, mouth ulceration,
erosion of teeth, bronchial pneumonia.
effects of overexposure: eyes: flush with water for at leat 15 minutes.
skin: wash with soap and water while removing contaminated clothing
and shoes. Inhalation: remove to fresh air. Give oxygen/cpr if
needed. Ingestion: giv e large amounts of water or milk. Do
notinduce vomiting. For all exposures get immediate medical
attention.
medical cond aggravated by exposure: individuals with a history of eye,
skin and respiratory disorders may be at increased risk from
exposure.
First aid: eyes: flush with plenty of water for at least 15 minutes.If
irritation persists,see doctor. Skin: wash with mild soap and water
while removing contaminated clothing and shoes. Inhalation: remove
victim t o fresh air.Give oxygen/cpr if needed.See doctor.
ingestion: do not induce vomit.See doctor immediately.
Hcc: c1
boiling pt: =82.8c, 181.F
melt/freeze pt: =-42.2c, -44.F
vapor pres: 48 @ 68f
vapor density: 2.2
spec gravity: 1.5
ph: acidic
solubility in water: complete
appearance and odor: colorless fuming liquid with an acrid,suffocating
odor.
Stability indicator/materials to avoid: yes
combustible materials, metallic powders, hydrogen sulfide, carbides,
alcohols, reacts with water to produce heat.
stability condition to avoid: extreme heat
hazardous decomposition products: oxides of nitrogen.
Waste disposal methods: contact your local environmental officer.
dispose of in accordance with all federal, state and local
regulations. Epa hazardous waste number d002.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara iii)
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 70.0%
osha pel: 2 ppm/4 stel
acgih tlv: 2 ppm/4 stel; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 30.0%
Effects of overexposure: eyes: causes severe damage,even blingness
v.Rapidly.Skin: causes burns,possible deep **see supp data
First aid: skin: immed flush w/water for 15 min.Call dr. Discard contam
shoes.Eyes: flush w/water until med help is arrived.Get med attn.Do
not use chem antidote.Ingestn: do not induce vomiting.Dilute by
giving wat er.Give milk of magnesia. *see supp data
Hcc: c1
nrc/state lic num: not relevant
boiling pt: =121.1c, 250.F
vapor pres: 5.5
vapor density: 1.3
spec gravity: 1.420
evaporation rate & reference: slower than ether
solubility in water: miscible
appearance and odor: colorless/yellow color liquid.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong alkali,flammable liq,organic material,reducers
hazardous decomposition products: nitrogen compounds,acid fumes
Waste disposal methods: sm spill: flush down drain w large amt of
water.Large spill: collect & add slowly to large vol of soda ash &
slaked lime soln. Add neutralized soln to excess running water.
**tosalvage tank.Absorb remai ning liq on absorbent matl.& shovel
into container
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara iii)
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 70%
osha pel: 2 ppm/4 stel
acgih tlv: 2 ppm/4 stel; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: aqueous solution,hazard unknown,unidentified
fraction by wt: 30%
Effects of overexposure: accelerated respiratory rate,decreased vital
capacity.Skin and eyes: intense pain and severe burns.
First aid: internal: large amounts of lukewarm water with salt/soapy
water or milk.Follow with egg white.Thin corn starch.Causes
vomiting.Repeat 3 times.Skin: use deluge shower.Remove all
contaminated clothing was h area with soap and water for 15
minutes.See data
Hcc: c4
nrc/state lic num: not relevant
boiling pt: =86.C, 186.8f
vapor pres: 62
spec gravity: 1.504
solubility in water: complete
appearance and odor: transparent,colorless to yellow,pungent odor.
Stability indicator/materials to avoid: yes
stability condition to avoid: avoid elevated temperatures and pressures.
hazardous decomposition products: hydrogen in contact with
metals;nitrogen oxides
Waste disposal methods: add slowly to a large amount of solution of soda
ash and slaked lime by stirring. Discharge the solution with large
amount of water into approved container.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara iii)
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 71%
osha pel: 2 ppm/4 stel
acgih tlv: 2 ppm/4 stel; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: human ldlo = 430 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: breathing high conc.,>200 ppm
may cause death after several minutes of exposure. Swallowing large
quantities can cause death. Chronic: may cause erosion of the
teeth, lesions on the skin, bronc hial irritation, coughing, and
pneumonia.
explanation of carcinogenicity: none of the compounds in this product is
listed by iarc, ntp, or osha as a carcinogen.
effects of overexposure: vapors and mists are extremely corrosive to the
nose, throat, mucous membranes, eyes, skin, mouth. Brief contact of
the liquids or mists will severly damage the eyes and prolonged
contact may cause pe rmanent eye injury which may be followedby
blindness. May cause ulcers of the skin.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the eyes, skin, or
respiratory tract may be at increased risk from exposure.
First aid: inhalation: remove to fresh air. Resuscitate if not breathing.
get medical attention. Eyes: immediately flush with plenty of water
for 15 minutes holding eyelids open. Get medical attention.
skin: remove contaminated clothing. Wash with soap and water. If
irritation persists, get medical advice. ingestion: do not induce
vomiting. Give nothing by mouth if unconscious. Get immediate
medical attention.
Hcc: c1
boiling pt: b.P. Text: 181-251f
melt/freeze pt: m.P/f.P text: -29.2--43.6
vapor pres: 42.0
vapor density: 1.4
spec gravity: 1.3-1.5(h2o=1)
evaporation rate & reference:
solubility in water: 100%
appearance and odor: colorless to yellow to light brown liquid w/
pungent odor
Stability indicator/materials to avoid: yes
reducing agents, alkalis, and any oxidizable materials and active
metals.
stability condition to avoid: heat, water or steam.
hazardous decomposition products: thermal decomposition liberates toxic,
corrosive fumes of nitrogen oxide and hydrogen nitrate.
Waste disposal methods: dispose of contaminated product and materials
used in cleaning up spills or leaks in a manner approved for this
material. Consult appropriate federal, state and local regulatory
agencies to ascertain proper disposal procedures.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara iii)
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 56-70%
osha pel: 2 ppm/4 stel
acgih tlv: 2 ppm/4 stel; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: lc50 (inhl rat) is 244 ppm
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: material is a corrosive acid solution
and will cause irritation and burns to eyes, skin, respiratory
tract and gastrointestinal tract. Ingestion will result in burns to
the mouth, throat, and gastroin testinal tract. Chronic: prolonged
exposure may lead to delayed effects including scarring and
infection of liver/kidney
explanation of carcinogenicity: none of the chemicals in this product is
listed by iarc, ntp or osha as a carcinogen.
effects of overexposure: eye and skin burns develop immediately.
ingestion may cause abdominal pain, nausea, vomiting, hemorrhaging,
and perforation of organs. Concentrated solutions cause deep
ulcers and stain skin a yellow -brown color. Inhalation: coughing
and choking - can lead to pneumonia and pulmonary edema.
medical cond aggravated by exposure: persons with a history of eye, skin
and respiratory disorders may be at increased risk from exposure.
First aid: eye: immediately flush with plenty of water for 15 minutes.
get medical attention. Skin: remove contaminated clothing. Wash
with soap and water. Inhalation: remove to fresh air. Give oxygen
if breathi ng is difficult. Give artificial respiration if victim
is not breathing. Ingestion: do not induce vomiting. Give victim
large amounts of water to dilute material. Get medical attention.
Hcc: c1
boiling pt: =122.2c, 252.F
melt/freeze pt: =-33.9c, -29.F
vapor pres: 62 @20c
vapor density: 2.3
spec gravity: 1.41
ph:
solubility in water: complete
appearance and odor: clear, colorless to slightly yellow liquid with
suffocating acrid fumes/odor
Stability indicator/materials to avoid: yes
strong bases, metallic powders, carbides, hydrogen sulfide, turpentine,
combustible organics.
stability condition to avoid: extremely high temperatures
hazardous decomposition products: carbon dioxide, carbon monoxide,
oxides of nitrogen
Waste disposal methods: dispose of in accordance with all applicable
federal, state and local regulations. Diluted and neutralized
material can probably be flushed to waste water treatment via a
sewer.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara iii)
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 70%
other rec limits: none specified
osha pel: 2 ppm/4 stel
acgih tlv: 2 ppm/4 stel; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: ldlo (oral rat) is 430 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation of vapors causes severe
irritation or burns of the respiratory system, pulmonary edema, or
lung inflammation. Eye contact causes severe damage and possible
blindness. Skin contact causes bu rns and possible deep ulceration.
ingestion causes severe burns to mouth, throat, and stomach.
explanation of carcinogenicity: this chemical is not listed by iarc,
ntp, or osha as a carcinogen.
effects of overexposure: severe irritation or burns to eyes, nose and
throat. Pulmonary edema, bronical emphysema, conjunctivitis,
stomatitis, dental erosion, nausea and vomiting.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the respiratory tract may
be at increased risk from exposure.
First aid: inhalation: remove to fresh air. Resuscitate if not breathing.
get medical attention. Eyes: immediately flush with plenty of water
for 15 minutes holding eyelids open. Get prompt medical attention.
skin : remove contaminated clothing. Wash with plenty of water for
15 minutes. Get medical advice. Ingestion: do not induce vomiting.
give nothing by mouth if unconscious. Get immediate medical
attention.
Hcc: c1
vapor pres: 8
vapor density: 1
spec gravity: 1.400
solubility in water: complete
appearance and odor: clear colorless liquid.
Stability indicator/materials to avoid: yes
bases, reducing agents, alcohols, brass, copper alloys, galvanized
iron, aluminum, steel, amines, alkali metals.
stability condition to avoid: none specified by manufacturer.
hazardous decomposition products: oxides of nitrogen.
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state and local environmental regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara iii)
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 70%
other rec limits: none specified
osha pel: 2 ppm/4 stel
acgih tlv: 2 ppm/4 stel; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: tlv is 2 ppm
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute-severe irritation/burns of
eye,skin,respiratory system.Inhaling causes coughing,difficulty in
breathing,chest pain,pulmonary edema,lung
inflammation,unconsciousness & may be fatal.Orally causes
nausea,vomiting,severe burns & ulceration of
mouth,throat,stomach.May be fatal.Chronic-damage to lung & teeth.
effects of overexposure: severe irritation/burns of eye, skin,
respiratory system. Inhaling causes coughing, difficulty in
breathing, chest pain, pulmonary edema, lung inflammation,
unconsciousness & may be fatal. Orally caus es nausea, vomiting,
severe burns & ulceration of mouth, throat, stomach. May be fatal.
medical cond aggravated by exposure: persons with pre-existing skin
disorders or eye problems or impaired respiratory function or
cardiopulmonary disease may be more susceptible to the effects of
the substance.
First aid: get medical attention immediately.Eye/skin: immediately flush
with water for at least 15 minutes.Hold eyelids open.Inhaled: remove
to fresh air & provide oxygen/cpr if needed.Oral: do not induce
vomiting .If conscious,drink large amount of water/milk/milk of
magnesia.Call a physician immediately.Never give anything by mouth
to an unconscious person.
Hcc: c4
boiling pt: =120.6c, 249.F
melt/freeze pt: =-41.7c, -43.F
vapor pres: 9
spec gravity: 1.4
ph: 1(.1m)
solubility in water: complete
appearance and odor: clear, colorless liquid, suffocating (choking) odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong bases, combustibles, strong reducing agents, most common metals,
organic materials, alcohols, carbides. Carbonate
stability condition to avoid: heat, light, moisture
hazardous decomposition products: nitrogen oxides , hydrogen gas
Waste disposal methods: dispose of in accordance with all applicable
federal, state and local regulations. Epa hazardous waste number:
doo1, d002 (ignitable,corrosive waste). Keep combustibles (wood,
paper, oil, etc..) away from spilled material.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara iii) *
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 65-71%
other rec limits: none specified
osha pel: 2 ppm/4 stel *
acgih tlv: 2 ppm/4 stel; 9192 *
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 29 - 35%
other rec limits: none specified
Ld50 lc50 mixture: tlv 2 ppm.
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eyes, skin, respiratory
& gi tracts. Corrosive. Acute- may be fatal if ingested/inhaled.
severe burns & ulceration to mouth, throat, stomach. Severe eye,
skin, respiratory tract irritati on, coughing, difficulty in
breathing, pulmonary edema. Chronic- obstructive pulmonary disease
and dental erosion.
explanation of carcinogenicity: none
effects of overexposure: eyes, skin, respiratory and gastrointestinal
tracts irritation/burns, coughing, abdominal pain, nausea,
vomiting, dental erosion
medical cond aggravated by exposure: damaged skin, eye disorders,
lung/respiratory system diseases and tooth
First aid: get medical care immediately in all cases.
eyes/skin: immediately flush with water for at least 15 minutes.
keep eyelids open. Inhalation: remove to fresh air. Provide
cpr/oxygen if needed. Ingestion: if conscious, drink milk/water or
milk ofmagnesia. Do not induce vomiting.
Hcc: c1
nrc/state lic num: not relevant
boiling pt: b.P. Text: 183f - 251f
melt/freeze pt: m.P/f.P text: -42f - 61f
vapor pres: 2-103 @68f
spec gravity: 1.5
solubility in water: miscible
appearance and odor: colorless or yellowish, fuming liquid - choking
odor
Stability indicator/materials to avoid: yes
oxidizing agents, strong bases, combustible matter, metal powder
stability condition to avoid: heat, steam, combustible materials, sparks
and flames (hydrogen gas may be present)
hazardous decomposition products: toxic and corrosive fumes, oxides of
nitrogen and hydrogen gas
Waste disposal methods: contact federal, state and local environmental
regulators for guidance regarding proper disposal. Epa hazardous
substance. Keep combustibles (wood, paper, oil, etc..) away from
spilled material.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara iii)
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 70%
other rec limits: 100 ppm (mfr)
osha pel: 2 ppm
acgih tlv: 2 ppm/4 stel; 9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: tlv 2 ppm
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eyes, skin, teeth,
respiratory & gi tracts. Acute- inhale: severe irritation/burns of
respiratory system, lung inflammation, unconsciousness & may be
fatal. Eye/skin: severe irritation/bur ns. Oral: severe burns,
ulceration of mouth, throat, stomach, dental erosion & may be
fatal. Chronic- teeth erosion.
explanation of carcinogenicity: none
effects of overexposure: eyes, skin, respiratory and gastrointestinal
tracts irritation and burns; coughing, difficult breathing, chest
pain, abdominal pain, nausea, vomiting, dental erosion, tearing,
redness of eyes, swellin g, corneal damage, severe skin damage,
immediate pain and burns of mouth, throat, esophagus
medical cond aggravated by exposure: damaged skin, eye disorders,
lung/respiratory system diseases
First aid: get medical care immediately in all cases.
eyes/skin: immediately flush with water for at least 15 minutes.
keep eyelids open. Treat for chemical burns if necessary.
inhalation: remove to fresh air. Pro vide cpr/oxygen if needed.
ingestion: ifconscious, drink 1-2 glasses of milk/water. Do not
induce vomiting. If possible, do not leave victim unattended.
Hcc: c4
nrc/state lic num: not relevant
boiling pt: =122.2c, 252.F
melt/freeze pt: =-33.9c, -29.F
vapor pres: 62 @ 68f
vapor density: >1
spec gravity: 42 deg be: 1.407
ph:
evaporation rate & reference:
solubility in water: 100.0 %
appearance and odor: colorless liquid with a sharp pungent odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
bases, alcohols, cyanides, combustibles, organic materials, metallic
powders, carbides, hydrogen sulfides, turpentine
stability condition to avoid: heat, light, moisture
hazardous decomposition products: oxides of nitrogen including nitrous
oxide (n2o), nitric oxide (no), nitrogen dioxide (no2); nitric acid
mist or vapors
Waste disposal methods: observe federal, state and local environmental
regulators for proper disposal. Consider recycling. Keep
combustibles (wood, paper, oil, etc..) away from spilled material.
reportable quantity (rq) is 1 000 pounds.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara iii)
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 69 - 71%
other rec limits: none recommended
osha pel: 2 ppm
acgih tlv: 2 ppm/4 stel; 9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: tlv 2 ppm/lc50, rat inhalation: 244 ppm.
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eyes, skin, teeth,
respiratory & gi tracts. Acute- corrosive. Inhale: can cause
breathing difficulty, pulmonary edema which may be fatal.
eye/skin: severe burns. May cause permanent eye da mage.
oral: immediate pain & burns of mouth, throat, esophagus & gi tract.
may be fatal. Chronic- erosion of teeth.
explanation of carcinogenicity: none
effects of overexposure: irritation, burns, coughing, difficult
breathing, chest pain, abdominal pain, nausea, vomiting, dental
erosion, chocking, skin redness or yellow-brown stain, eye damage,
death
medical cond aggravated by exposure: damaged skin, eye disorders,
lung/respiratory system diseases
First aid: get medical care immediately in all cases.
eyes/skin: immediately flush with water for at least 15 minutes.
keep eyelids open. Treat for chemical burns if necessary.
inhalation: remove to fresh air. Pro vide cpr/oxygen if needed.
ingestion: ifconscious, drink large amount of milk/water. Do not
induce vomiting.
Hcc: c1
nrc/state lic num: not relevant
boiling pt: b.P. Text: 252f,122c
melt/freeze pt: m.P/f.P text: -29f,-34c
vapor pres: 62 @ 68f
vapor density: 2.17
spec gravity: 1.41
solubility in water: infinite
appearance and odor: clear, colorless to slightly yellow liquid;
suffocating odor
Stability indicator/materials to avoid: yes
bases, alcohols, cyanides, combustibles, organic materials, metallic
powders, carbides, hydrogen sulfides, turpentine
stability condition to avoid: heat, light
hazardous decomposition products: oxides of nitrogen including nitrous
oxide (n2o), nitric oxide (no), nitrogen dioxide (no2); nitric acid
mist or vapors
Waste disposal methods: observe federal, state and local environmental
regulators for proper disposal. Consider recycling. Keep
combustibles away from spilled material. Reportable quantity (rq)
is 1000 pounds. Neutralized sl urry may be flushed to sewer with
waterif allowed
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara 302/313) (cercla)
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 70%
other rec limits: none recommended
osha pel: 2 ppm
acgih tlv: 2 ppm/4 stel; 9495
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: tlv 2 ppm/lc50, rat inhalation: 244 ppm.
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eyes, skin, teeth,
respiratory & gi tracts. Acute- corrosive. Inhale: can cause
breathing difficulty, pulmonary edema which may be fatal.
eye/skin: severe burns. May cause permanent eye da mage.
oral: immediate pain & burns of mouth, throat, esophagus & gi tract.
may be fatal. Chronic- erosion of teeth.
explanation of carcinogenicity: none
effects of overexposure: irritation, burns, coughing, difficult
breathing, chest pain, abdominal pain, nausea, vomiting, dental
erosion, chocking, skin redness or yellow-brown stain, eye damage,
death
medical cond aggravated by exposure: damaged skin, eye disorders,
lung/respiratory system diseases
First aid: get medical care immediately in all cases.
eyes/skin: immediately flush with water for at least 15 minutes.
keep eyelids open. Treat for chemical burns if necessary.
inhalation: remove to fresh air. Pro vide cpr/oxygen if needed.
ingestion: ifconscious, drink large amount of milk/water. Do not
induce vomiting.
Hcc: c4
nrc/state lic num: not relevant
boiling pt: b.P. Text: 248f - 252f
melt/freeze pt: =-41.1c, -42.F
vapor pres: 49-55 @77f
vapor density: 2.17
spec gravity: 1.37 - 1.42
ph:
solubility in water: infinite
appearance and odor: clear, colorless to slightly yellow liquid;
suffocating odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
bases, alcohols, cyanides, combustibles, organic materials, metallic
powders, carbides, hydrogen sulfides, turpentine
stability condition to avoid: heat, light
hazardous decomposition products: oxides of nitrogen including nitrous
oxide (n2o), nitric oxide (no), nitrogen dioxide (no2); nitric acid
mist or vapors
Waste disposal methods: observe federal, state and local environmental
regulators for proper disposal. Consider recycling. Keep
combustibles away from spilled material. Reportable quantity (rq)
is 1000 pounds. Neutralized sl urry may be flushed to sewer with
waterif allowed
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara 302/313) (cercla)
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 60 - 71%
other rec limits: none recommended
osha pel: 2 ppm
acgih tlv: 2 ppm/4 stel; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: oral ld50 (rat) is >90 ml/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: **corrosive** eyes: may cause severe
burns and irreversible eye damage.Skin: may cause severe irritation
and deep penetrating ulcers.Ingestion: may cause gastrointestinal
tract burns and perforations. inhalation: may be fatal if inhaled
may cayse irritation to the respiratory tract with burning pain in
the nose and throat, coughing, wheesing, shortness of breath and
pulmonary edema..Chronic: repea ted inhalation may causechronic
bronchitis. Repeated exposure may cause erosion of teeth.
explanation of carcinogenicity: there are no ingredients above 0.1%
which are identified as carcinogens by ntp,iarc or osha.
effects of overexposure: severe burns and irreversible eye damage.Skin:
may cause severe irritation and deep penetrating ulcers.Ingestion:
may cause gastrointestinal tract burns and perforations.
inhalation: may be fatal if i nhaled may cayse irritation to the
respiratory tract with burning pain in the nose and throat,
coughing, wheesing, shortness of breath and pulmonary
edema..Chronic: repeated inhalation may causechron ic bronchitis.
repeated exposure may cause erosion of teeth.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: skin: remove contaminated clothing; wash with soap and water.
get medical attention if irritation persists. Eyes: flush with
water for 15 minutes.Do not rub eyes. Get medical attention
immediately. In halation: remove to fresh air. Give oxygen or
artificial respiration if needed. Ingestion: do not induce
vomiting. Get prompt qualified medical attention.
Hcc: c1
boiling pt: =86.C, 186.8f
melt/freeze pt: =-42.C, -43.6f
vapor pres: 6.8
spec gravity: 1.50
ph: 1.0
evaporation rate & reference: not available.
solubility in water: soluble in water
appearance and odor: clear or yellowish liquid, strong acrid odor.
percent volatiles by volume: np
corrosion rate: np
Stability indicator/materials to avoid: yes
incompatable with other materials; acids e.G acetic acid,formic acid,
alcohols and glycols, aldehydes, amids, amines,azo,diazo, and
hydrazines, carbamates,cyanides, ditiocarbamates.
stability condition to avoid: high temperatures, incompatabile
materials, moisture, reducing agents
hazardous decomposition products: decomposes when in contact with air,
light, or organic matter. High temperatures, incompatible
materials, moisture, reducing agents.Nitrogen oxides.
conditions to avoid polymerization: has not been reported.
Waste disposal methods: dispose of in amanner consistent with federal,
state, and local regulations. Not listed as a material banned from
land disposal according to rcra. epa hazardous waste number d002.
Ingred name: nitric acid
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 69-71%
other rec limits: none recommended
osha pel: 2 ppm
acgih tlv: 2 ppm/4 stel; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 29-31%
other rec limits: none recommended
Ld50 lc50 mixture: none specified by manufacturer.
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: can be fatal if inhaled or swallowed.
inhalation of vapors can cause severe burns to respiratory
passages, pneumonia, pulmonary edema. Causes severe burns on
contact with any body tissue. Symptoms of lung injury may be
delayed.
explanation of carcinogenicity: no ingredient of a concentration of 0.1%
or greater is listed as a carcinogen or suspected carcinogen.
effects of overexposure: inhalation-burns to respiratory passages,
pneumonia, pulmonary edema; may be fatal. Skin-severe burns.
eyes-severe burns. Ingested-fatal.
medical cond aggravated by exposure: respiratory conditions.
First aid: get immediate medical attention in all cases of overexposure!
skin-immediately flush with water. Eyes-immediately flush with
water for 15 minutes. Inhaled-remove to fresh air. Give artificial
respirat ion if breathing has stopped. Ingested-do not induce
vomiting! If conscious, give water freely. Get medical attention.
Hcc: c4
boiling pt: =122.2c, 252.F
melt/freeze pt: =-33.7c, -29.F
vapor pres: 62
vapor density: 2.5
spec gravity: 1.41
solubility in water: appreciable
appearance and odor: colorless liquid; acrid odor.
Stability indicator/materials to avoid: yes
water, bases, reducing agents, organic materials, combustible matter.
stability condition to avoid: strong oxidizing agent-avoid contact with
all combustible matter.
hazardous decomposition products: oxides of nitrogen.
conditions to avoid polymerization: will not occur.
Waste disposal methods: neutralize to ph 6-9. Contact your local
permitted waste disposal site (tsd) for permissable treatment
sites. Always contact a permitted waste disposer (tsd) to assure
compliance with all local, state and federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara 302/313) (cercla)
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 100%
other rec limits: none recommended
osha pel: 2 ppm
acgih tlv: 2 ppm/4 stel; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: tlv 2 ppm. Lc50 (inh, rat) 49 ppm/4h.
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eyes, skin, teeth,
respiratory & gi tracts. Acute- corrosive. Inhale: can cause
breathing difficulty, pulmonary edema which may be fatal.
eye/skin: severe burns. May cause permanent eye da mage.
oral: immediate pain & burns of mouth, throat, esophagus & gi tract.
may be fatal. Chronic- erosion of teeth.
explanation of carcinogenicity: none
effects of overexposure: severe irritation, severe burns, coughing,
difficulty breathing, chest pain, abdominal pain, nausea, vomiting,
dental erosion, chocking, skin redness or yellow-brown stain, eye
damage, blindness, deat h
medical cond aggravated by exposure: damaged skin, eye disorders,
lung/respiratory system diseases
First aid: get immediate medical help. Eyes/skin: immediately flush with
water for at least 15 minutes. Hold eyelids open. Inhaled: remove to
fresh air. Provide cpr/oxygen if necessary. Oral: do not induce
vomiting . If conscious, drink large amount of milk/water. Never
give anything by mouth to an unconscious person. If vomiting occurs
spontaneously, keep head below hips to prevent aspiration.
Hcc: c4
nrc/state lic num: not relevant
boiling pt: =121.1c, 250.F
melt/freeze pt: =-33.7c, -29.F
vapor pres: 4.2 @ 68f
vapor density: 2.5
spec gravity: 1.3 - 1.5
ph: acidic
evaporation rate & reference:
solubility in water: 100%
appearance and odor: clear, yellow to light brown liquid;
suffocating/pungent odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
bases, alcohols, cyanides, combustibles, organic materials, metals,
carbides, water, reducing agents, carbonates
stability condition to avoid: heat, light
hazardous decomposition products: oxides of nitrogen including nitrous
oxide (n2o), nitric oxide (no), nitrogen dioxide (no2); nitric acid
mist or vapors
Waste disposal methods: observe federal, state and local environmental
regulators for proper disposal. Consider recycling. Keep
combustibles away from spilled material. Reportable quantity (rq)
is 1000 pounds.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara 302/313) (cercla)
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 70 - 89%
other rec limits: none recommended
osha pel: 2 ppm
acgih tlv: 2 ppm/4 stel; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
other rec limits: none recommended
osha pel: not relevant
acgih tlv: not relevant
Ld50 lc50 mixture: lc50 (rat): 244 ppm (no2)/30 m
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eyes, skin, teeth,
respiratory & gi tracts. Acute- corrosive & poison. Inhale: vapors
can cause pneumonia which may be fatal. Eye/skin: severe burns. May
cause blindness, deep skin ulcers. Oral: severe pain & burns of
mouth, throat, esophagus & gi tract. Chronic- erosion of teeth,
lung damage.
explanation of carcinogenicity: none
effects of overexposure: severe irritation, burns, coughing, difficult
breathing, chest pain, abdominal pain, nausea, vomiting, dental
erosion, chocking, skin redness or yellow-brown stain, eye damage,
skin lesions, death
medical cond aggravated by exposure: persons with pre-existing skin
disorders, eye, cardio pulmonary and lung diseases may be more
susceptible to the effects of this product.
First aid: get immediate medical help for all cases of exposure.
eye/skin: at once flush with water for at least 15 minutes. Hold
eyelids open. Inhaled: move to fresh air. Provide cpr/oxygen if
needed. Oral: do not induce vomiting. If conscious, drink large
amount of milk/water. Never give anything by mouth to an
unconscious person.
Hcc: c1
nrc/state lic num: not relevant
boiling pt: b.P. Text: 252f,122c
melt/freeze pt: m.P/f.P text: -44f,-42c
vapor pres: 48 @ 68f
vapor density: 2-3
spec gravity: 1.41
ph: 1 0.1m
solubility in water: 100%
appearance and odor: clear, colorless to yellowish liquid;
suffocating,acrid odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
bases, carbides, cyanides, combustibles, organic materials, metallic
powder, turpentine, hydrogen sulfide, iron, copper
stability condition to avoid: heat, light
hazardous decomposition products: oxides of nitrogen including nitrous
oxide (n2o), nitric oxide (no), nitrogen dioxide (no2); nitric acid
mist or vapors
Waste disposal methods: observe federal, state and local environmental
regulators for proper disposal. Consider reusing. Keep combustibles
away from spilled material.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: nitric acid (sara 302/313) (cercla)
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 65 - 70%
other rec limits: none recommended
osha pel: 2 ppm
acgih tlv: 2 ppm/4 stel; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 30 - 35%
other rec limits: none recommended
osha pel: not relevant
acgih tlv: not relevant
route of entry inds - inhalation: yes
skin: yes
ingestion: no
carcinogenicity inds - ntp: no
iarc: no
osha: no
effects of exposure: matl corro to any body tissue it contacts. Dental erosion
also.Tarorg: skin,eye,muc memb resp tract,teeth.Acute: irrit &/or corr
burns of skin,upper resp tract, delayed pulm edema,pneumonitis,bronchitit
s,dental erosion.Chronic: none reported.
explanation of carcinogenicity: this product is not considered a carcinogen by
ntp/iarc/osha.
signs and symptions of overexposure: irrit &/or corro burns of
skin,eye,upper resp tract,delayed pulm edema,pneumonitis,bronchitis,dental
erosion.
medical cond aggravated by exposure: none reported
first aid: eye-immed flush include under eyelids,gently well w/lots of h2o
@least 15mins.Treat for burns.Skin: immed wash w/soap/h2o.Watch for chem
burns,treat them.Inhal: remove to fresh air.Restore &/or support
breath.Expo severe hospitilization w/monitor by train med person to detect
delay onset of severe pulm edema @least 72hrs.Ingest: call pois cntrl cntr.
never give anything by mouth if unconsc/convuls.Do nt induce vomit.Expo
person resp- onsive give 1-2glasses of milk/h2o asap aft expo.Get med help
for all expo.Seek prompt med assist for treat/observ/support aft 1staid.Note
to dr-wash skin w/5%soln so dium bicarbonate.Ingest(see supplementa)
hcc: c4
nrc/state lic no: not relevant
boiling point: =122.C, 251.6f
melt/freeze pt: =-34.C, -29.2f
spec gravity: 1.4(68% by wt)
ph: very acidic
solubility in water: complete
appearance and odor: h20 white to yellow liq ages to brown; n02odor
product id: nitric acid
cage: 75656
company name: los angeles chemical co
street: 4545 ardine st
po box: 1987
city: south gate ca
zipcode: 90280
health emergency phone: 800/356-3129 poison cont
label required ind: y
date of label review: 02/04/1999
status code: a
origination code: f
chronic hazard ind: y
eye protection ind: yes
skin protection ind: yes
signal word: danger
respiratory protection ind: yes
health hazard: severe
contact hazard: severe
fire hazard: none
=======================================================
responsible party cage: 75656
trans id no: 139147
product id: nitric acid
msds prepared date: 05/21/1993
review date: 08/10/2001
mfn: 1
net unit weight: 7.3 lbs
multiple kit number: 0
unit of issue: bt
container qty: 4
type of container: bottle
additional data: cargo air only.
Hazard and precautions: matl corro to any body tissue it contacts. Dental
erosion also.Tarorg: skin,eye,muc memb resp tract,teeth.Acute: irrit &/or
corr burns of skin,upper resp tract, delayed pulm
edema,pneumonitis,bronchitit s,dental erosion.Chronic: none reported.Target
organs: all body tissues,teeth.1staid: eye/skin-flush immed @least 15mins.Treat
burns.Inhal: remove to fresh air.Restore &/or support breath.Severe expo
hosp italize-monitor delay onset of severe pulm edema @least
72hrs.Ingest-call pois cntrl cntr.Unconsc/convuls never give anything by
mouth.Gie 1-2glass of h2o/mil.Get med help for all exposure.
spill release procedures: notify saf pers,provide venti,remove all ign sources
immed in case contact w/metals(prod hi flamm h2 gas).Cleanup pers need prot
against contact w/matl inhal.Containn lg spill, collect waste.Use h2osp ray
to direct acid away frm incompat chems.Neutra w/soda ash or sodium
bicarbonate.Use absorbent(sand,earth,vermiculite)on slurry,place intocntnr
suitable for eventual dispo/reclam/destruction.
neutralizing agent: soda ash or sodium bicarbonate
waste disposal methods: consider reclamation,recyc,destruction rather than
dispo in landfill.Contact supplier/lic contractor for detailed
recommendations.Follow fed/state/loc regs.Air contam 29cfr1910.1000 subpart
z.
handling and storage precautions: store in cool dry well-venti area away frm
incompatible chems.Consider outside,isolate or detached storage.Protect cntnr
from direct sunlight.Build all storage fac of nonflamm matls that are
resistant to chem attack by nitric acid.Protect cntnrs frm phys dmg.Preplan
for routine use/emerg responses.
other precautions: proper venti essential in bulk storage areas;consider
installing auto monitoring syst to detect haz levels of nitrogen oxides that
can develop frm this matl.Separate nitric acid frm hydrazine,diethyle
netriamine,fluorides,& all other corro except sulfuric acid & sulfur
trioxide when shipping or trans ferring it.
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation-corrosive! Inhalation of
vapors can cause breathing difficulties & lead to pneumonia &
pulmonary edema which may be fatal. Ingestion-swallowing nitric
acid can cause immediate pain & burns of the mouth, throat,
esophagus & gastrointestinal tract. Skin-corrosive! Can cause
redness, pain & sevre burns. Concentrated solutions cause deep
ulcers & stain skin a yellow or yellow-brown color. E ye-corrosive!
vapors are irritating & may cause damage to the eyes. Contact may
cause sevre burns & permanent eye damage. Chronic: long-term
exposure to concentrated vapors may cause erosion of teeth & lung
damage.
explanation of carcinogenicity: none
effects of overexposure: nitric acid is extremely hazardous, it is
corrosive, reactive, an oxidizer, and a poison. Inhalation: other
symptoms may include coughing, choking, and irritation of the nose,
throat and respiratory t ract.
medical cond aggravated by exposure: persons with pre-existing skin
disorders, eye disease or cardiopulmonary disease may be more
susceptible to the effects of this substance.
First aid: inhalation-remove to fresh air. If not breathing give
artificial respiration. If breathing is difficult, give oxygen.
call a physician. Ingestion-do not induce vomiting. Give large
quantities of water or milk is available. Never give anything by
mouth to an unconscious person. Get medical attention immediately.
skin-immediately flush skin with plenty of water for 15 min while
removing contaminated clothes/shoes. Get medical attention
immediately. Eye-immediately flush eyes with plenty of water for 15
min, lifting lower & upper eyelids occasionally. Get medical
attention immediately.
Hcc: c1
boiling pt: =122.2c, 252.F
melt/freeze pt: =-42.C, -43.6f
vapor pres: 48 mmhg
vapor density: (air=1)2-3
spec gravity: 1.41
ph: 1.0(0.1m soluti
solubility in water: infinitely soluble
appearance and odor: colorless to yellowish liquid odor: suffocating,
acrid
percent volatiles by volume: 70f
Stability indicator/materials to avoid: yes
a dangerously powerful oxidizing agent, concentrated nitric acid is
incompatible with most substances. Especially strong bases,
metallic powders, carbides, hydrogen sulfides, turpentine, and
combustible organics.
stability condition to avoid: stable under ordinary conditions of use
and storage. Containers may burst when heated. Avoid light & heat.
hazardous decomposition products: when heated to decomposition, emits
toxic nitrogen oxides fumes and hydrogen nitrate. Will react with
water or steam to produce heat and toxic and corrosive fumes.
conditions to avoid polymerization: will not occur
Waste disposal methods: whatever cannot be saved for recovery should be
managed in an appropiate & approved waste facility. Although not a
listed rcra hazardous waste, this material may exhibit one or more
chacteristics of a hazardous waste & require appropiate analysis
to determine specific disposal requirements. State & local
disposal regulations may differ from federal
Ingred name: nitric acid
cas: 7697-37-2
rtecs #: qu5775000
minumum % wt: 67.
maxumum % wt: 70.
osha pel: 5 mg/m3;2 ppm
acgih tlv: 5.2 mg/m3;2 ppm
acgih stel: 10 mg/m3;4 ppm
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
minumum % wt: 30.
maxumum % wt: 35.
Routes of entry: inhalation: yes skin: yes ingestion: yes
health hazards acute and chronic: inhalation: corrosive! Inhalation of
vapors can cause breathing difficulties & lead to pneumonia &
pulmonary edema, which may be fatal. Ingestion: corrosive!
swallowing nitric acid can cause immediate pain & burns of the
mouth, throat, esophagus & gastrointestinal tract. Skin: corrosive!
can cause redness, pain & severe skin burns. Concentrated solutions
cause deep ulcers & stain skin a yellow or y ellow-brown color.
eye: corrosive! Vapors are irritating & may cause damage to the
eyes. Contact may cause severe burns & permananentdamage.
chronic: erosion of teeth & lung damage.
effects of overexposure: inhalation: inhalation of vapors can cause
breathing difficulties & lead to pneumonia & pulmonary edema, which
may be fatal. Other symptoms may include coughing, choking &
irritation of the nose, thro at,& respiratory tract. Ingestion:
swallowing can cause immediate pain & burns of the mouth, throat,
esophagus & gastrointestinal tract. Skin can cause redness, pain &
severe skin burns. Concentrated solutions cause deep ulcers &
stain skin a yellow or yellow-brown color. Eye: vapors are
irritating & may cause damage to the eyes. Contact may cause severe
burns & permananent eye damage.
medical cond aggravated by exposure: persons with pre-existing skin
disorders, eye disease, or cardiopulmonary disease may be more
susceptible to the effects of this substance.
First aid: immediate first aid treatment reduces the health effects of
this substance. Inhalation: remove to fresh air. If not breathing,
give artificial respiration. If breathing is difficult, give
oxygen. Call a physician. Ingestion: do not induce vomiting! Give
large quantities of water or milk if available. Never give anything
by mouth to an unconscious person. Get medical attention
immediately. Skin: mm ediately flush skin with plenty of water for
at least 15 minutes while removing contaminated clothing & shoes.
wash clothing & thoroughly clean shoes before reuse. Get medical
attention immediately.
Hcc: c1
boiling pt: =122.C, 251.6f
melt/freeze pt: =-42.C, -43.6f
vapor pres: 48@20c(68f)
vapor density: 2-3(air=1)
spec gravity: 1.41
ph: 1.0
evaporation rate & reference: no data found.
solubility in water: infinitely soluble
appearance and odor: colorless to yellowish liquid. Suffocating, acrid
odor.
percent volatiles by volume: 100
A dangerously powerful oxidizing agent, concentrated nitric acid is
incompatible with most substances, especially strong bases,
metallic powders, carbides, hydrogen sulfide, turpentine, and
combustible organics.
stability condition to avoid: light and heat. Stable under ordinary
conditions of use and storage. Containers may burst when heated.
hazardous decomposition products: when heated to decomposition, emits
toxic nitrogen oxides fumes and hydrogen nitrate. Will react with
water or steam to produce heat and toxic and corrosive fumes.
conditions to avoid polymerization: will not occur
Waste disposal methods: whatever cannot be saved for recovery or
recycling should be managed in an appropriate & approved waste
facility. Although not a listed rcra hazardous waste, this material
may exhibit one or more char acteristics of a hazardous waste &
require appropriate analysis to determine specific disposal requi
rements. Dispose iaw local, state & fed regs.
Ingred name: nitric acid
cas: 7697-37-2
rtecs #: qu5775000
minumum % wt: 65.
maxumum % wt: 70.
osha pel: 5 mg/m3;2 ppm
acgih tlv: 5.2 mg/m3;2 ppm
acgih stel: 10 mg/m3;4 ppm
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
minumum % wt: 30.
maxumum % wt: 35.
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eye: causes severe eye burns. May
cause irreversible eye injury. May cause chemical conjunctivitis
and corneal damage. Skin: causes skin burns. May cause deep,
penetrating ulcers of the skin. May caus e skin rash (in milder
cases), and cold and clammy skin with cyanosis or pale color.
ingestion: may cause severe and permanent damage to the digestive
tract. Causes gastrointestinal tract burns. May c uase perforation
of the digestive tract. May cause systemic effects. Inhalation:
effects may be delayed. Causes chemical burns to the respirtory
tract. See supplemental data.
effects of overexposure: causes eye and skin burns. May cause severe
respiratory tract irritation with possible burns. May cause severe
digestive tract irritation with possible burns.
First aid: eyes: get medical aid immediately. Do not allow victim to rub
or keep eyes closed. Extensive irrigation is required (at least 30
minutes). Skin: get medical aid immediately. Immediately flush skin
wit h plenty of soap and water for at least 15 minutes while
removing contaminated clothing and shoes. Wash clothing before
reuse. Destroy contaminated shoes. Ingestion: do not induce
vomiting. If victim is conscious and alert, give 2-4 cupfuls of
milk or water. Never give anything by mouth to an unconscious
person. See other information.
Hcc: c1
boiling pt: =86.C, 186.8f
melt/freeze pt: =-42.C, -43.6f
vapor pres: 6.8 mm hg
vapor density: 1.50
spec gravity: 1.50
ph: 1.0
viscosity: na
evaporation rate & reference: na
solubility in water: soluble in water
appearance and odor: clear to yellow liquid, strong acrid odor
Stability indicator/materials to avoid: yes
incompatabilty with other materials: reducing agents,acids, alcohols and
glycols, aldehydes, amids, amines, azo,diazo, and hydrazines,
carbamates, cyanides, dithiocarbamates, esters, ethers, fluorides,
hydrocarbons e.G benze
stability condition to avoid: high temperatures, incompatible materials,
igntion sources, dust generation, moisture, combustible materials,
reducing agents.
hazardous decomposition products: decomposes when in contact with air,
light, or organic matter. Nitrogen oxides.
conditions to avoid polymerization: has not been reported.
Waste disposal methods: chemical waste generators must determine whether
a discarded chemical is classified as a hazardous waste. Us epa
guidelines for the classification determination are listed in 40
cfr parts 261.3. Addit ionally, waste generators must consult state
and local hazardous waste regulations to ensure complet e and
accurate classification.
Ingred name: nitric acid
cas: 7697-37-2
rtecs #: qu5775000
fraction by wt: 68-70%
osha pel: 5 mg/m3;2 ppm
acgih tlv: 5.2 mg/m3;2 ppm
acgih stel: 10 mg/m3;4 ppm
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 29-31%