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Methanol (methyl alcohol)
Methanol (methyl alcohol)
Chemicals-organic
Y - Indicates information is in the hazardous materials information resource system (hmirs).
PMICA - Item does not contain precious metal.
CRITL- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.
042690 - Alcohol amyl etc
635 - Chemicals, other than drugs or sundries
9 - Other or no special handling required (sh)
A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.
C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp
R - Flammable liquids, un class 3 (flammable liquids label)
W - Rating variable
Questions & Answers: |
|
| What are the historical prices recorded for this stock number? | |
| Historical data shows pricing from $45.16 to $75.26.. | |
| Does NSN 6810-00-292-9676 have a shelf life? | |
| No. There is no shelf life applicable for this NSN. | |
| What NATO entities are users of this NSN? | |
| Department Of The Army, Department Of The Air Force, Defense Threat Reduction Agency, U.s. Marine Corps, Department Of The Navy, Spain, Singapore, Republic Of Korea, United Kingdom, Greece, Turkey, and Nato Maintenance and Supply Agency | |
| What is the NIIN of NSN 6810-00-292-9676? | |
| 002929676 or 00-292-9676 | |
| Does NSN 6810-00-292-9676 require demilitarization? | |
| Yes - ITAR Controlled | |
| What is the most recent solicitation for NSN 6810-00-292-9676? | |
| No solicitations for this NSN. | |
| When was this national stock number assigned to the federal catalog? | |
| Jan 01, 1963 | |
Ld50 lc50 mixture: ld50 (oral rat) is 6200 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute-inhalation/ingestion: may cause
upper respiratory/gastrointestinal tract
irritation,headache,nausea,vomiting,drowsiness,cns
depression,anesthetic,shock,coma.Eyes: can cause irritation,optical
nerv e damage & blindness.Skin: drying & defatting.Chronic-may cause
blindness, drunkenness & dermatitis.
effects of overexposure: inhalation or ingestion may cause upper
respiratory/gastrointestinal tract irritation, headache, nausea,
vomiting, drowsiness, cns depression, anesthetic, shock, coma. Can
cause eyes irritation, optic al nerve damage & blindness. Can cause
drying & defatting of skin.
medical cond aggravated by exposure: pre-existing skin disorders may be
more susceptible to this material.
First aid: get medical attention in all cases.Swallowed: if
conscious,drink water/milk to dilute.Induce vomiting if advised by
physician/poison control center.Inhaled: immediately remove to fresh
air.Provide cpr i f necessary.Skin: flush with plenty of cool
water.Eyes: flush with water for at least 15 minutes.Keep eyelids
open.The use of 1-2% sodium bicarbonate solution as the lavage
solution is recommended.
Hcc: f5
boiling pt: =65.C, 149.F
melt/freeze pt: =-97.8c, -144.F
vapor pres: 100 @ 21c
vapor density: 1.11
spec gravity: 0.796
evaporation rate & reference: 12
solubility in water: miscible
appearance and odor: clear, colorless, highly polar liquid; slightly
alcoholic odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizers, strong acids, strong alkalis at high temperatures and
materials reactive with hydroxyl compounds.
stability condition to avoid: high heat, sparks, open flames and other
sources of ignition
hazardous decomposition products: carbon monoxide, carbon dioxide,
aldehydes and acids
Waste disposal methods: dispose by incineration or contact with a
licensed chemical waste disposal agency. Discharge, treatment or
disposal may be subject to federal, state or local environmental
protection regulations. The hazardous waste number is u154.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 99.85%
other rec limits: none specified
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Effects of overexposure: eye: irrt,optic nerv
damage,blind.Skn: irrt,dry,defat,inhl,ingest: head,naus,depress,shock
,coma,eye dam
First aid: eye: flush 15 min w/ample water.Skn: water wash.Inhl: remove to
fresh air,art resp.Ingest: induce vomit or gas lavage.Call phys
immed all cases.Control shock.Suggested 1-2% sod bicarbonate for
lavage & ac idosis control
Hcc: f5
boiling pt: =65.C, 149.F
vapor pres: 100
vapor density: 1.11
spec gravity: 0.79
evaporation rate & reference: 12 (buac=1)
solubility in water: complete
appearance and odor: clear flammable liquid, alcohol odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizers.Chromic anhydride,perchloric acid;see supp
stability condition to avoid: avoid ignition sources.Spontaneous ign
occurs at 385c.
hazardous decomposition products: formaldehyde,co,formic acid.
Waste disposal methods: incinerate in approved facility iaw all laws &
regs.Epa haz waste id# is u154.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 99.9%
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Effects of overexposure: eye: irrit. Skn: defatting.
inh: hdch,dizz,weak,gastrointest/sight problems.
ing: drunk,drows,blindness.
First aid: skin: wash w water.Eyes: flush w water.Inhaled: giv cpr/oxygen
if necessary.Ingest: immediately induce vomiting by having victim
drink soapy water.For all routes keep patient warm/cover eyes.Seek
medical attention.
Hcc: f2
boiling pt: b.P. Text: 148f,64c
vapor pres: 92
vapor density: 1.1
spec gravity: 0.79
evaporation rate & reference: 6.3(ether=1)
solubility in water: complete
appearance and odor: colorless liquid,mild alcohol odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidants,active metals,isocyanates.
stability condition to avoid: heat,ignition sources.
hazardous decomposition products: combustion reported to yield co*2 &
co.
Waste disposal methods: eliminate ignition sources.Notify
authorities.Package and dispose in accordance with local,state and
federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 99.9%
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Effects of overexposure: harmful if inhaled.May be fatal or cause
blindness if swallowed.Repeated contact irritates skin,eyes
First aid: inh: remove to fresh air,give oxy/cpr if needed.Get med
asst;skin: remove contmntd clothng,flush w/plenty of water.Get med
attn;eyes: flush w/plenty of water for at least 15 min.Get med
attn;ing: give ple nty of h*2o to drink,induce vomit & trnspt to
hosp
Hcc: f5
boiling pt: =64.9c, 148.8f
melt/freeze pt: =-97.8c, -144.F
vapor pres: 96
vapor density: 1.11
spec gravity: 0.7913
viscosity: 0.59 cps
evaporation rate & reference: 5.9 (n-butyl acetate=1)
solubility in water: complete
appearance and odor: colorless liquid with faint alcoholic odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
oxidizing & corrosive matl.
stability condition to avoid: source of ignition
hazardous decomposition products: co*2,co
conditions to avoid polymerization: unk
Waste disposal methods: methyl alcohol is a land-banned rcra hazardous
waste (u154) and must be incinerated/reclaimed in accordance with
all applicable environmental regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: >99%
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Effects of overexposure: weakness,headache,nausea vomiting,abdominal
pain,dimness of vision,unconsciousness,dermatitis,cramps
First aid: move to fresh air.Remove contaminated clothing,wash body with
soap & water.Ingestion: induce vomiting.Eyes: wash with water for at
least 15 minutes.Seek medical attention.Combat
shock: oxygen,stimulants if indicated.Stomach wash if swallowed
Hcc: f5
boiling pt: =63.9c, 147.F
vapor pres: 92
vapor density: 1.1
spec gravity: 0.8
evaporation rate & reference: 2.0,butyl acetate
solubility in water: complete
appearance and odor: clear,colorless liquid,slight alcohol odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
all sources of ignitions oxidizers
stability condition to avoid: keep away from open flame
hazardous decomposition products: co*2,co
Waste disposal methods: incinerate i/a/w all local, state & federal
regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 99.9%
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Effects of overexposure: irritation of eyes,skin & respiratory tract.
ingestion may result in blindness & death
First aid: inhal: rmv to fresh air. If not brthng give cpr; if brthng
diff give oxygen. Eye: immed flush w/plenty of water. Skin: wash
w/soap&water. Rmv contam clthg%shoes. Ingest: induce vomit. Rpt
until vomit is c lear. Nothg by mouth if unconsc. Get medical attn.
Hcc: f5
boiling pt: =64.4c, 148.F
vapor pres: 92
vapor density: 1.11
spec gravity: 0.7924
evaporation rate & reference: 2.0, butyl acetate
solubility in water: complete
appearance and odor: colorless liquid,slight alcohol odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizers
stability condition to avoid: open flame,high temperatures.
hazardous decomposition products: co*2,co
Waste disposal methods: varies with locality.Supplier should be able to
advise.Incineration possible in many areas.Consult federal,state &
local authorities.Dispose in accordance with federal,state and
local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 99.9%
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: ld50 oral rat=5628mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: see signs & symptoms of
overexposure. Chronic: marked impairment of vision and enlargement
of the liver has been reported.Repeated or prolonged exposure may
cause skin irritation
effects of overexposure: eyes: irritant,eye
lesion;skin: defatting,dryness,cracking;skin absorption: symptoms
similar to inhalation;inhalation: irritant,toxic to nervous system &
optic nerve,headache,drowiness,nausea,vomit,blurre d
vision,blindness,coma,death,ingestion: symptoms similar to
inhalation,can cause blindness.Fatal dose=100-125ml
medical cond aggravated by exposure: person with pre-existing skin
disorders or eye problems or impaired liver or kidney function.
First aid: eyes: flush with plenty of water.See doctor
immediate;skin*remove contaminated clothing.Wash with plenty soap &
water if irritation persists,see doctor;inhalation: remove to fresh
air.Give cpr/oxygen if needed.See doctor;ingestion: give 2 glasses
of water & induce vomit immediately.See doctor immediately.Nothing
by mouth if unconscious.
Hcc: f2
boiling pt: b.P. Text: 148f(64.5c)
melt/freeze pt: m.P/f.P text: -144f(-98c)
vapor pres: 97
vapor density: 1.1
spec gravity: 0.8
evaporation rate & reference: 5.9 (butyl acetate=1)
solubility in water: complete
appearance and odor: clear,colorless liquid.Characteristic odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizing agents. Will attack some forms of
plastic,rubber,coating. May react with metallic al to form haz gas.
stability condition to avoid: heat,sparks,open flames.
hazardous decomposition products: co,co*2formaldhyde
Waste disposal methods: dispose as hazardous waste in a rca approved
facility.Do not flush to sewer.Comply with all applicable
federal,state & local envirinmental regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: >99%
other rec limits: none
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: ld50 oral rat=5628mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: see signs & symptoms of
overexposure chronic: marked impairment of vision and enlargement of
the liver has been reported.Repeated or prolonged exposure may
cause skin irritation
effects of overexposure: eyes: irritant,eye
lesion;skin: defatting,dryness,cracking;skin absorption: symptoms
similar to inhalation;inhalation: irritant,toxic to nervous system &
optic nerve,headache,drowsiness,nausea,vomit,blurr ed
vision,blindness,coma,death,ingestion: symptoms similar to
inhalation,can cause blindness.Fatal dose=100-125ml
medical cond aggravated by exposure: person with pre-existing skin
First aid: eyes: flush with plenty of water.See docto
immediate;skin*remove contaminated clothing.Wash with plenty soap &
water if irritation persists,see doctor;inhalation: remove to fresh
air.Give cpr/oxygen nee ded.See doctor;ingestion: give 2 glassesof
water & induce vomit immediately.See doctor immediately.Nothing by
mouth if unconscious.
Hcc: f5
boiling pt: =64.4c, 148.F
melt/freeze pt: =-97.8c, -144.F
vapor pres: 97
vapor density: 1.1
spec gravity: 0.8
evaporation rate & reference: 5.9 (butyl acetate=1)
solubility in water: complete
appearance and odor: clear,colorless liquid.Characteristic odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizing agents. Will attack some forms of plasti
rubber,coating. May react with metallic al to form haz gas.
stability condition to avoid: heat,sparks,open flames.
hazardous decomposition products: co,co*2formaldhyde
Waste disposal methods: dispose as hazardous waste in a rca approved
facility.Not flush to sewer.Comply with all applicable
federal,state & local envirinmental regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 100%
other rec limits: none
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
effects of overexposure: harmful if inhaled.May be fatal or cause
blindness if swallowed.Repeated contact irritates skin,eyes
First aid: inh: remove to fresh air,give oxy/cpr if needed.Get med
asst;skin: remove contmntd clothng,flush w/plenty of water.Get m
attn;eyes: flush w/plenty of water for at least 15 min.Get med
attn;ing: give plent y of h*2o to drink,induce vomit & trnspt to
hosp
Hcc: f5
boiling pt: b.P. Text: 148.5f
melt/freeze pt: m.P/f.P text: -144f,-98c
vapor pres: 96
vapor density: 1.11
spec gravity: 0.7913
evaporation rate & reference: 5.9 (n-butyl acetate=1)
solubility in water: complete
appearance and odor: colorless liquid with faint alcoholic odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
oxidizing & corrosive matl.
stability condition to avoid: source of ignition
hazardous decomposition products: co*2,co
conditions to avoid polymerization: unk
Waste disposal methods: methyl alcohol is a land-banned rcra hazardous
waste (u154) and must be incinerated/reclaimed in accordance with
all applicable environmental regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: >99%
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: ld50 oral rat= 5628 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eyes: irritation, eye lesions. Skin:
defatting, drying, cracking, skin absorbtion reacts similar to
inhalation. Inhalation and ingestion: irritation, toxic to nervous
system and optic nerve, headache, drowsiness, nausea, vomiting,
blurred vision, blindness, coma, death. Enlargement of liver has
been reported.
effects of overexposure: eyes: irritant, eye lesions. Skin: defatting,
dryness, cracking. Skin absorption reacts similar to inhalation.
inhalation and ingestion: irritation, toxic to nervous system and
optic nerve, headache, drowsiness, nausea, vomiting, blurred
vision, blindness, coma, death. Enlargement of liver has been
reported.
medical cond aggravated by exposure: person with pre-existing skin
disease may be at increased risk from exposure.
First aid: eyes: flush with plenty of water. Get medical attention.
skin: remove contaminated clothing. Wash area with soap and water.
if irritation persists, get medical attention. Inhalation: move to
fresh air . Give cpr/ oxygen if needed. Get medical attention.
ingestion: give 2 glasses of water and induce vomiting. Get medical
attention. Give nothing by mouth if unconscious.
Hcc: f5
nrc/state lic num: not relevant
boiling pt: =64.4c, 148.F
melt/freeze pt: =-97.6c, -144.F
vapor pres: 97
vapor density: 1.1
spec gravity: 0.8
evaporation rate & reference: 5.9 (butyl acetate=1)
solubility in water: complete
appearance and odor: clear, colorless liquid. Characteristic odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizing agents.Will attack some forms of
plastic,rubber,coating.May react with aluminum to form hazardous
gas.
stability condition to avoid: heat, sparks, open flames.
hazardous decomposition products: carbon monoxide, carbon dioxide,
formaldhyde.
conditions to avoid polymerization: will not occur.
Waste disposal methods: dispose of waste in accordance with local, state
and federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 99.85%
other rec limits: none specified
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: none specified by manufacturer.
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eyes: will irritate the eyes. Liquid
and mists will irritate and may burn. Skin: brief contact may dry
the skin. Prolonged contact may irritate the skin causing
dermatitis. Ingestion: can cause blinde ss, dizziness, headaches,
nausea. Inhalation: headache, nausea, vomiting, dizziness, visual
disturbance, sleepiness
effects of overexposure: swallowing 100-250 ml of methanol can be fatal.
absorption of methanol is rapid but excretion is slow, resulting in
delayed or compounding effects of repeated exposure. Initial
symptoms may be only mi ld intoxication but these may become more
severe 12-18 hours. Toxic effects are exerted on the central
nervous system.
medical cond aggravated by exposure: eye, skin, respiratory disorders,
impaired liver or kidney functions.
First aid: eye: flush with copious amounts of water for at least 15
minutes. Seek medical help. Skin: remove contaminated clothing.
wash skin with soap and water. If irritation persists, seek medical
help. Inhal ation: remove to fresh air. Get medicalhelp. Ingestion:
induce vomiting. After vomiting give milk, water or solution of
sodium bicarbonate. Get immediate medical attention.
Hcc: f5
boiling pt: b.P. Text: 149f,65c
melt/freeze pt: m.P/f.P text: -144f,-98c
vapor pres: 96-100
vapor density: 1.1
spec gravity: 0.79
evaporation rate & reference: >2 (n-butyl acetate=1)
solubility in water: complete
appearance and odor: colorless liquid, mild alcohol odor.
Stability indicator/materials to avoid: yes
strong oxidizing agents, aluminum, zinc, any metal that displaces
hydrogen acids, and alkalis.
stability condition to avoid: heat, sparks, open flame
hazardous decomposition products: carbon monoxide, carbon dioxide,
formaldehyde, and unidentified organic compounds
conditions to avoid polymerization: in black smoke
Waste disposal methods: keep out of sewers, storm drains, surface waters
and soil. Consult federal, state, and local regulatory agencies to
ascertain proper disposal procedures.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 99%
other rec limits: none specified
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ld50 lc50 mixture: ld50 oral rat= 5628 mg/kg
route of entry inds - inhalation: yes
skin: yes
ingestion: yes
carcinogenicity inds - ntp: no
iarc: no
osha: no
effects of exposure: eyes: irritation, eye lesions. Skin: defatting, drying,
cracking, skin absorbtion reacts similar to inhalation. Inhalation and
ingestion: irritation, toxic to nervous system and optic nerve, headache,
drowsiness, nausea, vomiting, blurred vision, blindness, coma, death.
enlargement of liver has been reported.
explanation of carcinogenicity: product contains no ingredients currently
classified as carcinogenic by ntp, iarc or osha.
signs and symptions of overexposure: eyes: irritant, eye lesions. Skin:
defatting, dryness, cracking. Skin absorption reacts similar to inhalation.
inhalation and ingestion: irritation, toxic to nervous system and optic
nerve, headache, drowsiness, nausea, vomiting, blurred vision, blindness,
coma, death. Enlargement of liver has been reported.
medical cond aggravated by exposure: person with pre-existing skin disease may
be at increased risk from exposure.
first aid: eyes: flush with plenty of water. Get medical attention. Skin:
remove contaminated clothing. Wash area with soap and water. If irritation
persists, get medical attention. Inhalation: move to fresh air . Give cpr/
oxygen if needed. Get medical attention. Ingestion: give 2 glasses of water
and induce vomiting. Get medical attention. Give nothing by mouth if
unconscious.
hcc: f2
b.P. Text: 148f,64c
m.P/f.P text: -144f(-98c)
decomp text: unknown
vapor pres: 97
vapor density: 1.1
spec gravity: 0.8
evaporation rate & reference: 5.9 (butyl acetate=1)
solubility in water: complete
appearance and odor: clear, colorless liquid. Characteristic odor.
percent volatiles by volume: 100
corrosion rate: unknown
product id: methanol (methyl alcohol)
cage: 81349
company name: military specifications promulgated by military
street: depts/agencies under auth of def std
po box: manual
city: 4120 3-m nk
zipcode: 00000
health emergency phone: 804-279-3131
label required ind: y
date of label review: 10/06/1993
status code: c
label date: 10/06/1993
origination code: f
chronic hazard ind: y
eye protection ind: yes
skin protection ind: yes
signal word: danger
respiratory protection ind: yes
health hazard: severe
contact hazard: severe
fire hazard: severe
=======================================================
responsible party cage: 81349
trans id no: 68244
product id: methanol (methyl alcohol)
msds prepared date: 10/06/1993
review date: 10/06/1993
mfn: 1
net unit weight: 32 oz
multiple kit number: 0
review ind: y
unit of issue: qt
container qty: g
type of container: can
Hazard and precautions: eyes: irritation, lesions. Skin: defatting, drying,
cracking, skin absorbtion same as inhalation. Inhalation and ingestion:
irritation, toxic to nervous system and optic nerve, headache, nausea, vomit
ing, blurred vision, blindness, coma, death. Enlargement of liver reported.
first aid: eyes: flush with plenty of water. Get medical attention. Skin:
remove contaminated clothing. Wash area with soap and water. If irritation
persists, get medical attention. Inhalation: move to fresh air. Give cpr/
oxygen if needed. Get medical attention. Ingestion: give 2 glasses of water
and induce vomiting. Get medical attention.
spill release procedures: remove ignition sources. Ventilate area. Wear
respiratory protection and protective clothing. Absorb in inert material and
place in appropriate container for proper disposal.
neutralizing agent: none specified by manufacturer.
waste disposal methods: dispose of waste in accordance with local, state and
federal regulations.
handling and storage precautions: protect against physical damage.Outside or
detached storage preferred.Inside storage should be for flammable liquid.
separate from oxidizing materials
other precautions: storage and use areas should be non-smoking. Spark- proof,
and explosion-proof equipment should be used in the storage and handling
area.
Ld50 lc50 mixture: ld50 oral rat=5628mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation-a slight irritant to the
mucous membranes. Toxic effects exerted upon nervous system,
particularly the optic nerve. Ingestion-toxic. Skin-methyl alcohol
is a defatting agent. Eye-irritant. continued exposure can cause
eye lesions.
effects of overexposure: inhalation-symptoms of overexposure may include
headache, drowsiness, nausea, vomiting, blurred vision, blindness,
coma, & death. Aperson can get better but then worse again up to 30
hours later. Inge stion-can intoxicate and cause blindness.
skin-can cause skin to become dry and cracked.
medical cond aggravated by exposure: persons with pre-existing skin
disorders or eye problems or impaired liver or kidney function may
be more susceptible to the effects of the substance.
First aid: inhalation-remove to fresh air. If not breathing, give cpr.
if hard to breath, give oxygen. Call physician. Ingestion-induce
vomiting immediately by giving two glasses of water & sticking
finger down throat. Call a physician. Skin-remove any clothing.
wash skin with soap 7 water for 15 min. Eye-wash eyes with plenty
of water for at least 15 min. Get medical attention immediately.
Hcc: f5
boiling pt: =64.4c, 148.F
melt/freeze pt: =-97.8c, -144.F
vapor pres: 97
vapor density: 1.1
spec gravity: 0.8
evaporation rate & reference: 5.9 (butyl acetate=1)
solubility in water: miscible with water
appearance and odor: clear, colorless liquid, characteristic odor.
Stability indicator/materials to avoid: yes
strong oxizing agents such as nitrates, perchlorates or sulfuric acid.
will attack some forms of plastic/rubber/coatings
stability condition to avoid: high temperatures, sparks, and open
flames.
hazardous decomposition products: carbon oxides and formaldehyde may
form when heated to decomposition.
Waste disposal methods: collect as hazardous waste and atomize in a
suitable rcra approved combustion chamber, or absorb with
vermiculite, dry sand or earth for disposal as hazardous waste in a
rcra approved facility. Do not flush to sewer. Rq: 5000 lbs.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
other rec limits: none
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: oral ld50 (rat) is 5628 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: inhalation is harmful & may be
fatal, cns depression. Contact may cause irritation; may cause
dermatitis, corneal damage. Ingestion is harmful & may be fatal;
may cause cns depression, gi tract irritation, hearing loss.
chonic: prolonged/repeated exposure may cause kidney and/or liver
damage.
explanation of carcinogenicity: no ingredient of a concentration of 0.1%
or greater is listed as a carcinogen or suspected carcinogen.
effects of overexposure: inhaled-headache, nausea, vomiting, dizziness,
narcosis, respiratory failure, low blood pressure, cns depression.
eyes-irritation, corneal damage. Skin-irritation, dermatitis.
ingested-blindness, head ache, nausea, vomiting, dizziness, gi
tract irritation, cns depression, hearing loss.
medical cond aggravated by exposure: eye disorders, skin disorders,
liver or kidney disorders.
First aid: in all cases get medical attention. Eyes-flush with water for
15 minutes. Skin-remove contaminated clothes. Wash with mild soap &
water. Inhaled-remove to fresh air. Administer oxygen or artificial
re spiration as needed. Ingested-call a physician. Induce vomiting.
Hcc: f5
boiling pt: b.P. Text: 149f,65c
melt/freeze pt: m.P/f.P text: -144f,-98c
vapor pres: 96
vapor density: 1.11
spec gravity: 0.79
evaporation rate & reference: 4.6 (n-butyl acetate=1)
solubility in water: complete
appearance and odor: clear, colorless liquid; pungent odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizing agents, strong acids, zinc, aluminum, magnesium.
stability condition to avoid: heat, flame, other sources of ignition.
hazardous decomposition products: carbon monoxide and carbon dioxide,
formaldehyde.
conditions to avoid polymerization: will not occur.
Waste disposal methods: dispose of in accordance with local, state and
federal environmental regulations. Epa/rcra hazwaste number u154
may apply to product as purchased.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara 313) (cercla)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 100%
other rec limits: none recommended
osha pel: s, 200 ppm
acgih tlv: s,200ppm/250stel; 96
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: oral rat ld50 5628mg/kg.
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eye: severely irrit causing
pain,redness.Skin: expo can lead to inflamm,followed by
derm.Ingest: dil solnt may cause severe abdominal
pian,anorexia,nau,vomit.Hi conc may lead to blur
vision,speed,blindne ss,unconsc,death.Blood levels of methanol &
degree of acidosis are more indicative of risk than amt
ingested.(supplemen)
explanation of carcinogenicity: per msds: classification of
carcinogenicity: none.
effects of overexposure: damage to liver,kidney,lung,blood,& central
nervous system.
medical cond aggravated by exposure: persons w/existing
skin,kidney,liver,eye disorders may be @incr risk when expo to
methanol. Target organs: respiratory system,liver,kidnesy,central
nervous system,gastrointestinal tract,eyes.
First aid: ensure dr has access to msds.Eye: immed flush w/lg amts of h2o
for 15mins,lift lids.Get med attn asap.Skin: flush immed w/lg atms
of h2o for @least 15mins while removing contam cloth.Irrit persist
aft g lush get med attn promptly.Inhal: immed remove to fresh
air.Call emerg med care.Not breath give art resp;diffi give
oxy.Ingest: immed call dr.Induce vomit of consc patient immed.Drink
lg amts of h2o-dil
Hcc: f5
boiling pt: b.P. Text: 148f,65c
melt/freeze pt: m.P/f.P text: -144f,-98c
decomp temp: decomp text: np
vapor pres: 96.1 @20c
vapor density: 1.11
spec gravity: 0.7925 @20c
ph: np
viscosity: np
evaporation rate & reference: 4.6 buac=1
solubility in water: complete
appearance and odor: clear, colorless liquid, slight alcohol odor,
liquid
percent volatiles by volume: 100
corrosion rate: np
Stability indicator/materials to avoid: yes
strong oxid agents.Chcl3+na methoxide;zn(c2h5)2.Alkyl al
salts;ch3cobr;chcl3+naoh;cr(iii)oxide;c3n3cl3;i2+ethanol+hgo.
stability condition to avoid: strong oxidizers,excessive heat & ignition
sources.
hazardous decomposition products: acrid smoke, irrit fumes,carbon
monoxide, carbon dioxide
Waste disposal methods: methanol is spent solvt classified as
haz,f003,must be managed according to state/fed haz waste regs.Dont
discharge to sewer.Wear appropr ppe.Take up w/sand/vermi/similart
inert matl.Cercal rq: 5000lbs /2270kg notify ncrc 800-424-8802 upon
release.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara 313) (cercla)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 100%
other rec limits: none recommended
osha pel: s, 200 ppm
acgih tlv: s,200ppm/250stel; 96
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: ld50 (orl rat) is 5628 mg/kg (rtecs).
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: causes eye and skin irritaion. May
cause anesthetic effects, liver effects, blindness, acidosis. May
cause nausea, weakness, temporary cns depression, loss of
consciousness, blindness, abnormal kidney function, death.
explanation of carcinogenicity: methanol has been reported to cause
birth defects in rats exposed to very high concentrations (20,000
ppm), per msds.
effects of overexposure: irritation, tearing. Burning sensation, drying
skin, defatting, dizziness, nausea, vomiting, drowsiness, headache,
fatigue, convulsions, unconsciousness, death, blindness, swelling
of eyes and redness
medical cond aggravated by exposure: individuals with pre-existing
diseases of the eye, skin, respiratory tract, liver, kidney, cns
may have increased susceptibility to the toxicity of excessive
exposures.
First aid: eye: immediately flush with water for 15 minutes. Hold eyelids
open. See physician. Skin: wash affected area with soap & water. If
irritation persists, see doctor. Inhaled: remove to fresh air.
provide c pr/oxygen if needed. Obtain emergency medical help.
oral: if conscious, immediately induce vomiting by drinking water &
pressing finger down throat. Call a physician/poison control center
immediately.
Hcc: f5
boiling pt: b.P. Text: 148f,65c
melt/freeze pt: m.P/f.P text: -144f,-98c
decomp temp: decomp text: not known
vapor pres: 127
vapor density: 1.1
spec gravity: 0.79
viscosity: 1 cps @ 86f
evaporation rate & reference: >1 (n-butyl acetate=1)
solubility in water: 100%
appearance and odor: clear, colorless liquid - alcoholic odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizing agents, chromic anhydride, lead perchlorate or
perchloric acids
stability condition to avoid: heat, flame, sparks, other ignition
sources
hazardous decomposition products: none specified by manufacturer.
Waste disposal methods: dispose in accordance with all applicable local,
state and federal regulations. Epa hazardous waste number is u154
(toxic waste). Rq for methanol is 5000 lbs. Preferred method is
incineration or biolo gical treatment in an approved facility.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara 313) (cercla)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 100% %
other rec limits: none recommended
osha pel: s, 200 ppm
acgih tlv: s,200ppm/250stel; 95
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: oral rat: ld50=7.5 g/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: skin: repeated or prolonged contact
causes drying, brittleness, cracking & irritation. Prolonged skin
contact with methanol-soaked material has produced toxic effects
including vision effects & death . Eyes: may cause eye injury which
may persist for several days. Liquid (& vapor in high
concentrations) causes irritation, tearing, & burning sensation.
inhalation: high levels cause stupor, headache , nausea, dizziness,
unconsciousness, adverse effects on vision. Ingestion: poisonous or
fatal if swallowed. Small amount (2 or more oz) can cause
sluggishness, nausea, vomiting, severe illness, blind ness, death
if not treated.
explanation of carcinogenicity: no evidence of carcinogenic potential in
limited animal studies in which methanol was given orally or
applied to the skin.
effects of overexposure: eyes: injury which may last several days,
irritation, burning sensation. Skin: drying, brittleness, cracking,
irritation, toxic effects, death. Inhalation: stuper, headache,
nausea, dizziness, unconsc iousness, adverse effect on vision.
ingestion: poisonous or fatal, mental sluggishness, nausea,
vomiting, severe illness, adverse effects on vision with possible
blindness or death.
medical cond aggravated by exposure: significant exposure to this
chemical may adversely affect people with chronic disease of the
central nervous system, skin, gastrointestinal tract and/or eyes.
First aid: skin: remove contaminated clothing & wash contaminated skin
with large amounts of soap & water. If irritation persists,
contact a physician. Eyes: flush eyes with water for at least 15
mins. Contact a physician immediately. Inhalation: remove patient
from contaminated area. If breathing has stopped, give artificial
respiration, then oxygen if needed. Contact a physician
immediately. Ingestion: in duct vomiting of conscious patient
immediately by giving 2 glasses of water & presssing finger down
throat. Contact a physician immediately.
Hcc: f5
boiling pt: =64.6c, 148.3f
melt/freeze pt: =-97.8c, -144.F
vapor pres: 96.0 hg at 20 deg c
vapor density: 1.11(air=1
spec gravity: 0.792(h2o=1@ 20/20 deg c)
evaporation rate & reference: 2.0 (buac=1)
solubility in water: complete
appearance and odor: clear, colorless, mobile liquid, mild alcohol odor.
percent volatiles by volume: 100.0
Federal regulatory information: recipient must communicate all pertinent
information herein to employees and customers. Manufacturer
certifies that all components are either on the tsca inventory or
qualify for an exemption.
state regulatory information: the following chemicals associated with
the prodict are subject to the right-to-know regulations in these
states: methanol, cas # 67-56-1: ct, fl, il, la, ma, nj, ny, pa,
ri.
Waste disposal methods: all notification, clean-up and disposal should
be carried out in accordance with federal, state, local
regulations. Preferred methods of waste disposal are incineration
or biological treatment in fede ral, state approved facility.
hazardous waste no. U154, d001.
Ingred name: methanol
cas: 67-56-1
rtecs #: pc1400000
minumum % wt: 99.5
maxumum % wt: 99.85
osha pel: 260 mg/m3;200 ppm
acgih tlv: 262 mg/m3;200 ppm
acgih stel: 328 mg/m3;250 ppm
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: ld50, mouse 7300 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute- liquid, mist, or vapors can
cause eye, skin & respiratory tract irritation & central nervous
system depression. Inhalation: high conc. May cause cns depression.
victims may improve & then get w orse again up to 30 hours later.
skin: upon prolonged or repeated contact, absorption through the
skin may occur & produce toxic effects similar to inhalation
exposure. Eyes: irritation. Direct contac t with liquid,
conjuctivitis & corneal burns may occur. Ingeston: may cause
serious poisoning with effects similar to those of inhalation &
absorption throught the skin. Chronic- slowing eliminated ca using
cumulative poisoning.
effects of overexposure: acute- inhalation: symptoms may include
headache, weakness, drowsiness, lighheadedness, nausea, difficult
breathing, drunkenness, eye irritation, blurred vision, blindness,
loss of consciousness, ver tigo, fatigue, convulsions & possibly
death, depending on exposure. Victims may improve & then get worse
again up to 30 hours later. skin: drying, cracking, & inflammation
of the skin. eyes: buring sensation, tearing, redness, or
swelling. ingestion: similar to inhalation & absorption through
skin.
medical cond aggravated by exposure: personnel with pre-existing cns
disease, skin disorders, impaired liver or kidney function, gi
tract disorders or chronic respiratory diseases should avoid
exposure.
First aid: eyes: immediately flush with copious amounts of tepid water
for at least 15 minutes. Seek medical att'n. Skin: immediately
flush exposed area with copious amounts of tepid water for at least
15 minute s while removing contaminated clothing & shoes, followed
by washing area thoroughly with soap & water. Seed medical att'n if
symptoms develop. inhalation: move patient to fresh air & keep
warm & at r est. Monitor for respiratory distress. Ingestion: if
conscious, immediately give patient two glasses of water & induce
vomiting (if immediate medical att'n is not available). Get medical
att'n.
Hcc: f2
boiling pt: =64.4c, 148.F
melt/freeze pt: =-97.6c, -144.F
vapor pres: 1.86 psia @68f
vapor density: 1.11@60f
spec gravity: 0.792 @68f
ph: 7.2
solubility in water: 100%
appearance and odor: colorless liquid. Faintly sweet pungent odor like
ethyl alcohol.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
chloroform+sodium methoxide & diethyl zinc. Alkyl aluminum salts,
acetyl bromide, chloroform+sodium hydroxide, cyanuric chloride,
nitric acid, etc. Beryllium dihydride, metals (potassium,
magnesium, etc). Oxidizing material
hazardous decomposition products: excessive heating and/or incomplete
combustion will generate carbon monoxide, formaldehyde, and
possibly unburned methanol.
conditions to avoid polymerization: will not occur.
Waste disposal methods: waste must be disposed of i/a/w federal, state &
local environmental control regulations. Waste methanol in
concentrations equal to or greater than 24%, by wieght, meets the
definition of an ignitable hazardous waste. Product grade
methanol, when disposed, is listed hazardous waste.
Ingred name: methanol
cas: 67-56-1
rtecs #: pc1400000
minumum % wt: 99.
maxumum % wt: 100.
osha pel: 260 mg/m3;200 ppm
acgih tlv: 262 mg/m3;200 ppm
acgih stel: 328 mg/m3;250 ppm
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: not provided
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: eye: believed to cause mild eye
irritation upon short-term exposure. Upon direct contact with the
liquid, conjunctivitis and corneal burns may occur. Methanol's main
toxic effect is exerted upo n the nervous system, particularly the
optic nerves and possibly the retina. The condition can progress to
permanent blindness. Skin: upon prolonged repeated exposure,
absorption throught the skin may occur and product exic effects
similar to those resulting from inhalaiton exposure. Inhalation:
may cause dizziness, headache, drowsiness, nausea, unconsciousness.
chronic: skin contact may cause a p ersistent irritation or
dermatitis.
explanation of carcinogenicity: this product is not currently listed as
a carcinogen by ntp, osha, or iarc.
effects of overexposure: headache, dizziness, drowsiness, nausea,
unconsciousness and coma.
medical cond aggravated by exposure: not provided
First aid: eye: flush thoroughly with water for at least 15 minutes. Get
medical attention. Skin: wash exposed area with soap and water.
remove and clean contaminated clothing. If irritation develops seek
medica l attention. Ingestion: call a doctor immediately. If person
is conscious, immediately give 2 glasses of water and induce
vomiting. Do not make an unconscious person vomit. Never give
anything by mout h to an unconscious or convulsing person.
inhalation: remove to fresh air. If not breathing, give
mouth-to-mouth artificial respiration and seek medical attention.
if breathing is difficult, qualified personnel may administer
oxygen.
Hcc: f5
nrc/state lic num: not relevant
boiling pt: =64.4c, 148.F
melt/freeze pt: m.P/f.P text: not provided by mfr
decomp temp: decomp text: not provided by mfr
vapor pres: 96 mmhg @ 68 deg f (20c)
vapor density: 1.11(air=1
spec gravity: 0.796 @ 60 deg f (15.6 c)
viscosity: no information found
evaporation rate & reference: no information found
solubility in water: infinite
appearance and odor: colorless, characteristic odor
percent volatiles by volume: 100
corrosion rate: not provided
Stability indicator/materials to avoid: yes
this material reacts violently with : heat, strong oxidizers, strong
acids
stability condition to avoid: heat
hazardous decomposition products: products evolved when subject to heat
or combustion: carbon monoxide and carbon dioxide may be formed on
burning.
Waste disposal methods: incinerate or place in rcra permitted waste
management facility. Remarks: no waste classification of product
has been established. Recycle or incinerate according to local,
state, and federal regulati ons.
Ingred name: methanol
cas: 67-56-1
rtecs #: pc1400000
= wt: 99.9
other rec limits: not provided
osha pel: 260 mg/m3;200 ppm
acgih tlv: 262 mg/m3;200 ppm
acgih stel: 328 mg/m3;250 ppm
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: ld50 (oral, rat) = 5,628 mg/kg
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eyes: may cause moderate irritation
and painful sensitization to light. Skin: may cause irritaion. May
be absorbed through skin in harmful amounts. Ingestion: may cause
irritation of digestive tract a nd respiratory failure. May cause
vascular collapse, damage and kidney failure. Inhalation: may cause
respiratory irritation, liver and kidney damage. May cause adverse
cns effects including headache, convulsions, and possible death.
may cause visual impairment, possible permanent blindness. Chronic:
may cause dermatitis. Chronic inhalation and ingestion may cause
effects similar to those of acute inhalation and ingestion.
explanation of carcinogenicity: not listed by acgih, iarc, niosh, ntp,
or osha.
effects of overexposure: eyes: may cause moderate irritation and painful
sensitization to light. Skin: may cause irritaion. Ingestion: may
cause irritation of digestive tract and respiratory failure. May
cause vascular collap se, damage and kidney failure. Inhalation:
may cause respiratory irritation, liver and kidney damage. May
cause adverse cns effects including headache, convulsions, and
possible death. May cause visua l impairment, possible permanent
blindness.
medical cond aggravated by exposure: not provided
First aid: eyes: flush with water for at least 15 minutes, occasionally
lifting upper and lower lids. Get medical aid immediately. Do not
allow victim to rub/keep eyes closed. Skin: flush with plenty of
soap and water while removing contaminated clothing and shoes. Get
medical aid if irritaion develops/persists. Ingestion: if victim is
conscious and alert, give 2-4 cupfuls of milk/water. Get medical
aid imme diately. Induce vomiting by giving 1 teaspoon of syrup of
ipecac. Inhalation: get medical aid immediately. Remove from
exposure to fresh air immediately. If not breathing, give
artificial respiration. if breathing is difficult, give oxygen.
Hcc: f5
nrc/state lic num: not relevant
boiling pt: =64.8c, 148.6f
melt/freeze pt: =-98.C, -144.4f
decomp temp: decomp text: not available
vapor pres: 29 mm hg (20c/68f)
vapor density: 1.1
spec gravity: 0.7910q/cm3
viscosity: 0.006 p at 68f
evaporation rate & reference: none known
solubility in water: misicible with water
appearance and odor: clear colorless liquid, slight alcohol-like odor
percent volatiles by volume: 99-100
corrosion rate: not provided
Stability indicator/materials to avoid: yes
oxidants (such as baium perchlorate, bromine, chlorine, hydrogen
peroxide, lead perchlorate, perchloric acid, sodium hypochlorite).
active metals (potassium and magnesium). See nfpa fire protection
guide.
stability condition to avoid: high temperatures, incompatible materials,
ignition sources.
hazardous decomposition products: carbon monoxide, carbon dioxide,
formaldehyde.
Waste disposal methods: dispose of in a manner consistent with local,
state and federal regulations. Rcra u-series: waste number u154
(ignitable waste). This material is banned from land disposal
according to rcra.
Ingred name: methyl alcohol
cas: 67-56-1
rtecs #: pc1400000
minumum % wt: 99.
maxumum % wt: 100.
other rec limits: 200 ppm (niosh)
osha pel: 260 mg/m3;200 ppm
acgih tlv: 262 mg/m3;200 ppm
acgih stel: 328 mg/m3;250 ppm
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs