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Dichloromethane (methylene chloride)
Saturated chlorinated derivatives of acyclic hydrocarbons, n.E.S.
Chemicals-organic
Y - Indicates information is in the hazardous materials information resource system (hmirs).
PMICA - Item does not contain precious metal.
CRITL- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.
045310 - Methylene chloride etc
635 - Chemicals, other than drugs or sundries
9 - Other or no special handling required (sh)
A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.
C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp
T - 55.0
Z - No special type of cargo code applicable
Questions & Answers: |
|
| What are the historical prices recorded for this stock number? | |
| Historical data shows pricing from $45.52 to $75.87.. | |
| Does NSN 6810-00-397-3720 have a shelf life? | |
| No. There is no shelf life applicable for this NSN. | |
| What NATO entities are users of this NSN? | |
| Department Of The Air Force, Department Of The Navy, Canada, Portugal, Italy, and Turkey | |
| What is the NIIN of NSN 6810-00-397-3720? | |
| 003973720 or 00-397-3720 | |
| Does NSN 6810-00-397-3720 require demilitarization? | |
| Yes - ITAR Controlled | |
| What is the most recent solicitation for NSN 6810-00-397-3720? | |
| No solicitations for this NSN. | |
| When was this national stock number assigned to the federal catalog? | |
| Apr 15, 1974 | |
Ld50 lc50 mixture: oral ld50 (rat) = 167 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: acute: may cause eye & skin
irritation. Inhalation may cause respiratory tract irritation and
narcosis. Central nervous system depressant. Loss of consciousness
and even death can occur at high levels of exposure. Chronic:
prolonged or repeated contact with liquid on the skin can cause
irritation and dermatitis.
explanation of carcinogenicity: listed as a suspected carcinogen by
iarc. (2b)
effects of overexposure: headache, dizziness, drowsiness, nausea,
tingling or numbness of the extremities, senses of fullness in the
head, sense of warmth, stupor or dullness, lethargy and drunkeness.
very high concentrations may lead to unconsciousness or even death
in confined or poorly ventilated areas.
medical cond aggravated by exposure: methylene chloride is metabolized
by the body to carbon monoxide. This can be sufficient to produce a
substantial stress on the cardiovascular system by elevated levels
of carbonyhemoglobin.
First aid: inhalation: remove to fresh air. If not breathing, give cpr.
if breathing is difficult, give oxygen. Call a physician. Eye:
flush immediately with large amounts of water for 15 minutes. Get
medical at tention. Skin: remove contaminated clothing. Wash with
soap and water promptly. Ingestion: do not induce vomiting. Give
milk or water to drink only if conscious. Get immediate medical
attention.
Hcc: t4
boiling pt: b.P. Text: 104f,40c
melt/freeze pt: m.P/f.P text: -139f,-95c
vapor pres: 400 mmhg
vapor density: 2.9
spec gravity: 1.3266
evaporation rate & reference: 27.5(n-butyl acetate = 1)
solubility in water: slight
appearance and odor: clear,colorless liquidwith a mild chloroform odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
alkali metals, finely powdered aluminum & magnesium
stability condition to avoid: high temperatures
hazardous decomposition products: when involved in fire, methylene
chloride emits highly toxic and irritating hydrogen chloride and
phosgene fumes.
Waste disposal methods: contaminated sawdust, vermiculite or porous
surface must be disposed of in a permitted hazardous waste
management facility. Recovered liquids may be reprocessed or
incinerated or must be treated in a permitted hazardous waste
management facility.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 100.0%
osha pel: 500 ppm/c,1000; z2
acgih tlv: 50 ppm, a2; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Effects of overexposure: eye: irrit. Skin: irrit;absorbed thr skin.
inh: irrit, loss of coordination/balance. See sup data
First aid: remove to fresh air;use oxygen respirator for severe cases.
(eye & skin: flush w/ water for 15 minutes, if irritation persists
call md. Ingest: call md, give water or milk and induce vomiting.
advise md not to use adrenalin-ge msds ref)
Hcc: t4
boiling pt: b.P. Text: 104f,40c
vapor pres: 350
vapor density: 2.93
spec gravity: 1.326
evaporation rate & reference: 14.5(buac=1)
solubility in water: insoluble
appearance and odor: clear liquid, aromatic odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
alkali metals,finely powdered aluminum & magnesium (ge ref)
stability condition to avoid: exposure to high temps (open flame,
welding arcs, etc)ge ref
hazardous decomposition products: hydrogen chloride phosgene at high
temps (ge msds ref)
Waste disposal methods: mfr recommends burying absorbent in landfill.
waste solvent may be reclaimed by filtration & distillation
procedures or dispose via licensed waste solvent disposal company
(ge msds ref). Disposal meth od must be iaw fed, state & local
codes.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 100%
osha pel: 500 ppm/c,1000; z2
acgih tlv: 50 ppm, a2; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Effects of overexposure: eye-pain&moderate irrit. Poss transient corneal
injury. Skin-moderate irrit to burn.See supp data
First aid: eye: irrigate w/flowing h2o immed for at least 15 minutes.
call md.Skin: wash thoroughly. Wash clothing.Inhalatn: move to fresh
air.Call md.Mouth to mouth if nec. Ingestn: do not induce
vomiting.Call md.N ehc holds note to physician/treatment info.
Hcc: t4
boiling pt: b.P. Text: 104f(39.8c)
vapor pres: 340
vapor density: 2.93
spec gravity: 1.320
solubility in water: moderate
appearance and odor: colorless liquid
percent volatiles by volume: 100
Hazardous decomposition products: hcl,small amounts phosgene and
chlorine
Waste disposal methods: send solvent to a reclaimer. In some cases,
small amount may be transported to an area where it can be placed
on the ground and allowed to evaporate safely if local,state, and
federal regulations perm it.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 100%
osha pel: 500 ppm/c,1000; z2
acgih tlv: 50 ppm, a2; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: oral ld50 (rat) is 2524 mg/kg
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: yes iarc: yes osha: no
health hazards acute and chronic: acute: inhalation may cause
respiratory irritation, liver injury, blood disorders, and central
nervous system effects (cns). Contact may cause skin and eye
irritation. Ingestion may cause gi tract irr itation and cns
effects. Chronic: prolonged or repeated exposure may cause
dermatitis, central nervous system effects.
explanation of carcinogenicity: methylene chloride (dichloromethane) is
listed as an anticipated carcinogen by ntp & a (2b) probable
carcinogen by iarc.
effects of overexposure: inhaled: mental confusion, light-headedness,
nausea, vomiting, headache, shortness of breath. Eyes: redness,
pain, inflammation. Skin: burns, redness, pain. Ingested:
light-headedness, dizzizness, nau sea, vomiting, headache.
medical cond aggravated by exposure: pre-existing skin, respiratory,
liver, kidney disorders may be aggravated by exposure.
First aid: inhaled: remove to fresh air. Give artificial respiration if
breathing stopped; give oxygen if breathing difficult. See doctor.
eyes: flush with lots of water for 15 minutes. See doctor. Skin:
remove contaminated clothes. Wash with soap and water. Ingested:
if conscious, give water and induce vomiting. Get immediate medical
attention.
Hcc: t4
boiling pt: b.P. Text: 104f,40c
melt/freeze pt: m.P/f.P text: -142f,-97c
vapor pres: 350 mm hg
vapor density: 2.9(air=1)
spec gravity: 1.3 (water=1)
evaporation rate & reference: 27.5 (n-butyl acetate=1)
solubility in water: moderate
appearance and odor: clear, colorless liquid; chloroform-like odor.
Stability indicator/materials to avoid: yes
strong oxidizer, strong caustics and chemically active metals.
stability condition to avoid: open flames and electrical arcs . Contact
with incompatible materials.
hazardous decomposition products: phosgene gas and hydrochloric acid
mist
Waste disposal methods: collected spills may be atomized in a
rcra-approved combustion chamber or shipped to rcra approved
facility for disposal; ensure compliance with local, state &
federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: >99%
other rec limits: none specified
osha pel: 500 ppm/c,1000; z2
acgih tlv: 50 ppm, a2; 9293
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: ld50 (oral rat) = 1500-2500 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: yes iarc: yes osha: no
health hazards acute and chronic: may cause cns effects,
carboxyhemoglobinemis, liver & kidney effects. Eye: irritation,
pain, slight corneal injury. Prolonged &/or repeated skin
contact: irritation, burns, drying, cracking. Inhalation: cns
effects, anesthesia, cardiac arrythmias. Ingestion: if aspirated is
absorbed rapidly by lungs.
explanation of carcinogenicity: contains dichloromethane (methylene
chloride). See individual iarc & ntp reports for details of
carcinogenicity.
effects of overexposure: eye: irritation, pain. Skin: irritation, burns,
drying, flaking. Inhalation: respiratory irritation, anesthetic
effects, dizziness, headache, drunkenness, cardiac arrythmias,
unconsciousness, death. Inge stion: single dose toxicity is low. If
aspirated, is rapidly absorbed by lungs.
medical cond aggravated by exposure: mfr gave no information of msds.
First aid: if any irritation persists or severe, get medical attention.
eye: flush w/water for 15 min. Skin: wash w/flowing water.
inhaled: remove from contaminated area. Aid or restore breathing as
needed. Ingeste d: do not induce vomiting. Call physician or
transport to emergency facility immediately. Physician to determine
advisability of vomiting or lavage.
Hcc: t4
nrc/state lic num: none
boiling pt: b.P. Text: 104f,40c
vapor pres: 355 mm
vapor density: 2.93
spec gravity: 1.320
solubility in water: 2.0 gm/100 gm
appearance and odor: colorless liquid, penetrating ether-like odor,
irritating at high concentration
Stability indicator/materials to avoid: yes
amines, aluminum, sodium, potassium, magnesium
stability condition to avoid: hydrolysis, open flames, welding arcs,
other high temperatures.
hazardous decomposition products: hcl, phosgene, chlorine
conditions to avoid polymerization: will not occur.
Waste disposal methods: sent to licensed reclaimers or to permitted
incinerators. Any disposal practice must be i/a/w federal, state &
local regulations. Do not dump into sewers, on ground or into any
body of water.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 99.9%
osha pel: 500 ppm/c,1000; z2
acgih tlv: 50 ppm, a2; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: oral ld50 (rat) =1500-2500 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: acute: may cause eye & skin irritation.
inhalation may cause respiratory tract irritation and narcosis.
central nervous system depressant, unconsciousness and even death
can occur at high levels of exp osure. Chronic: dermatitis, liver
and kidney damage.
explanation of carcinogenicity: listed as a possible carcinogen by iarc.
effects of overexposure: headache, dizziness, drowsiness, nausea,
tingling or numbness of the extremities, senses of fullness in the
head, sense of warmth, stupor or dullness, lethargy and drunkeness.
very high concentrations may lead to unconsciousness or even death
in confined or poorly ventilated areas.
medical cond aggravated by exposure: cardiac, blood and respiratory
diseases.
First aid: inhalation: remove to fresh air. If not breathing, give cpr.
if breathing is difficult, give oxygen. Call a physician. Eye: flush
immediately with large amounts of water for 15 minutes. Get medical
att ention. Skin: remove contaminated clothing. Wash with soap and
water promptly. Ingestion: do not induce vomiting. Give milk or
water to drink only if conscious. Get immediate medical attention.
Hcc: t4
boiling pt: b.P. Text: 104f,40c
melt/freeze pt: m.P/f.P text: -139f,-95c
vapor pres: 355 mmhg
vapor density: 2.93
spec gravity: 1.320
evaporation rate & reference: 27.5(n-butyl acetate = 1)
solubility in water: slight, 2%
appearance and odor: clear,colorless liquid with a penetrating
ehter-like odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
alkali metals, finely powdered aluminum & magnesium
stability condition to avoid: high temperatures
hazardous decomposition products: when involved in fire, emits highly
toxic and irritating hydrogen chloride, phosgene and chlorine.
Waste disposal methods: dispose of in a permitted hazardous waste
management facility in accordance with local, state and federal
regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 99.9%
osha pel: 500 ppm/c,1000; z2
acgih tlv: 50 ppm, a2; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: ld50 (oral, rat) is 1500-2500 mg/kg.
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: yes iarc: yes osha: no
health hazards acute and chronic: target organs: lung, eye, skin, liver,
kidney. Acute- eye: transient corneal injury. Skin: irritation,
defatting. Prolonged skin contact may result in burns & absorption.
inhale: irritation, dizziness. Na rcotic in high concentrations.
oral: aspiration hazard. Chronic- long term overexposure may cause
liver & kidney damage.
explanation of carcinogenicity: methylene chloride is listed as a
potential human carcinogen by ntp, iarc and acgih.
effects of overexposure: irritation, nausea, vomiting, headache,
dizziness, skin defatting and burns, elevated carboxyhemoglobin
levels
medical cond aggravated by exposure: persons with pre-existing skin
disorders or eye problems or impaired liver, kidney, cardiovascular
or respiratory function may be more susceptible to the effects of
the substance.
First aid: get immediate medical attention. Eyes/skin: immediately flush
with water for at least 15 minutes. Hold eyelids open. Wash skin
with soap & water. Inhaled: remove to fresh air. Provide cpr/oxygen
if nece ssary. Oral: do not induce vomiting except on advice of
competent medical personnel. If conscious, drink water. Never give
anything by mouth to an unconscious person.
Hcc: t4
nrc/state lic num: not relevant
boiling pt: b.P. Text: 104f,40c
melt/freeze pt: m.P/f.P text: -142f,-97c
vapor pres: 350 @ 68f
vapor density: 2.93
spec gravity: 1.326
viscosity: not relevant
evaporation rate & reference: >1 (ether = 1)
solubility in water: approx. 2% @ 68f/20c
appearance and odor: clear, colorless volatile liquid - penetrating
ethereal odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizing agents, strong caustic, chemically active metals
(aluminum), amines, possibly sodium, potassium & mg
stability condition to avoid: stable under ordinary conditions of use
and storage. Avoid contact with open flames, electrical arcs,
excessive heat
hazardous decomposition products: hydrogen chloride, carbon monoxide,
carbon dioxide, phosgene and chlorine
conditions to avoid polymerization: water contamination
Waste disposal methods: dispose of in accordance with all local, state
and federal regulations. Dispose of in an approved incinerator
equipped with afterburner and scrubber or contract with a licensed
waste disposal service. do not contaminate environment.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara 313) (cercla)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 99.9%
other rec limits: none recommended
osha pel: 500 ppm; z-2
acgih tlv: 50 ppm, a2; 9495
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs