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Methylchloroform (1, 1, 1-trichloroethane)
Saturated chlorinated derivatives of acyclic hydrocarbons, n.E.S.
Chemicals-organic
Y - Indicates information is in the hazardous materials information resource system (hmirs).
PMICA - Item does not contain precious metal.
CRITL- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.
045290 - Methyl chloroform etc
635 - Chemicals, other than drugs or sundries
9 - Other or no special handling required (sh)
A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.
C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp
P - Poison, class b, un class 6 (poison label)
W - Rating variable
Questions & Answers: |
|
| What are the historical prices recorded for this stock number? | |
| Historical data shows pricing from $0.04 to $0.07.. | |
| Does NSN 6810-00-476-5612 have a shelf life? | |
| No. There is no shelf life applicable for this NSN. | |
| What NATO entities are users of this NSN? | |
| Department Of The Army, Department Of The Air Force, U.s. Marine Corps, Department Of The Navy, U.s. Coast Guard, Poland, Brazil, Spain, Singapore, Kuwait, Malaysia, Australia, New Zealand, France, Germany, Republic Of Korea, United Kingdom, Portugal, Italy, Greece, and Turkey | |
| What is the NIIN of NSN 6810-00-476-5612? | |
| 004765612 or 00-476-5612 | |
| Does NSN 6810-00-476-5612 require demilitarization? | |
| Yes - ITAR Controlled | |
| What is the most recent solicitation for NSN 6810-00-476-5612? | |
| No solicitations for this NSN. | |
| When was this national stock number assigned to the federal catalog? | |
| Jun 16, 1971 | |
Effects of overexposure: irritation of respiratory
system,dizziness,nausea,lightheadedness,headache,loss of
coordination.
First aid: remove to fresh air.If not breathing give artif. Resp.If
breathing is difficult,give oxygen.Eye contact: flush w/plenty of
water for at least 15 min. If irritation occours,consult a
doctor.Dkin: wash th oroughly w/plenty soap & water
Hcc: t4
nrc/state lic num: =
boiling pt: b.P. Text: 165.4f
vapor pres: 120
vapor density: 4.54
spec gravity: 1.31.
evaporation rate & reference: 0.35,ethyl ether.
solubility in water: negligible.
appearance and odor: clear,colorless liquid;ether-like odor.
percent volatiles by volume: 100.
Stability indicator/materials to avoid: yes
avoid mixing with caustic soda,caustic potash,oxidizing matl
stability condition to avoid: avoid open flames,hot glowing surfaces &
exectric arcs.
hazardous decomposition products: no
Waste disposal methods: epa-approved incineration or cnotact local waste
disposal contractor.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroethane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 100%.
other rec limits: none recommended
osha pel: 350 ppm
acgih tlv: 350 ppm/450stel;9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
Ld50 lc50 mixture: oral ld50 (rat) is 10300mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: irritation of eyes,skin &
respiratory tract; central nervous system (cns) depression.
chronic: cardiac arrhythmia,cns depression,dermatitis,kidney and
liver damage.
explanation of carcinogenicity: none
effects of overexposure: inhalation: coughing, wheezing, shortness of
breath, dizziness, headache, nausea, vomiting. Eyes: redness,
tearing. Skin: redness, rash. Ingestion: nausea, vomiting,
dizziness,diarrhea.
medical cond aggravated by exposure: respiratory
ailments,dermatitis;cirrhosis of the liver.
First aid: inhaled: remove to fresh air, give cpr/oxygen if needed;
eyes/skin: flush with large amounts water for 15 min; ingestion:
rinse mouth; get medical attention for eyes, breathing difficulty,
or other sy mptoms of overexposure.
Hcc: t4
boiling pt: b.P. Text: 162f,72c
vapor pres: 135 mm hg
vapor density: 4.54
spec gravity: 1.3
ph: 6-7.5
evaporation rate & reference: 0.35 (ethyl ether=1)
solubility in water: negligible
appearance and odor: clear,colorless liquid,mild chloroform-like odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
caustic soda,caustic potash,oxidizing agents.
stability condition to avoid: open flames,hot glowing surfaces,electric
arcs, sources of ignition.
hazardous decomposition products: hydrogen chloride and traces of
phosgene.
Waste disposal methods: dispose collected material in accordance with
local,state and federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroethane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: >93.0%
other rec limits: none recommended
osha pel: 350 ppm
acgih tlv: 350 ppm/450stel;9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
Ld50 lc50 mixture: oral ld50 (rat) = 10300 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: may cause eye & skin
irritation. May cause respiratory tract irritation. Central nervous
system depressant. Loss of consciousness and even death can occur
at high levels of exposure. Swallowing may result in irritation of
the mouth and gi tract with effects like inhalation. Chronic: not
known.
explanation of carcinogenicity: not listed as a carcinogen by ntp, iarc
or osha
effects of overexposure: incoordination and impaired judgment may occur
at vapor exposures from 500-1000 ppm. Dizziness, drowsiness, and
general anestethic effects may occur in ranges of 1000 ppm and
higher.
medical cond aggravated by exposure: persons with existing respiratory
and dermal conditions may be at increased risk.
First aid: inhalation: remove to fresh air. If not breathing, give cpr.
if breathing is difficult, give oxygen. Call a physician. Eye:
flush immediately with large amounts of water for 15 minutes. Get
medical at tention. Skin: remove contaminated clothing. Wash with
soap and water promptly. Ingestion: do not induce vomiting. Give
milk or usp mineral oil. Get immediate medical attention.
Hcc: t4
boiling pt: b.P. Text: 162f,72c
melt/freeze pt: m.P/f.P text: -49f,-45c
vapor pres: 135
vapor density: 4.54
spec gravity: 1.31
ph: 6-7.5
evaporation rate & reference: 0.35 (ethyl ether=1)
solubility in water: negligible
appearance and odor: clear, colorless liquid with ether-like odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
avoid mixing with caustic soda, caustic potash, or oxidizing materials.
shock sensitive compounds may be formed.
stability condition to avoid: avoid open flames,hot glowing surfaces or
electric arcs.
hazardous decomposition products: when involved in fire,
1,1,1-trichloroethane emits highly toxic and irritating hydrogen
chloride and phosgene fumes.
Waste disposal methods: collected matl be disposed of in a permitted
hazardous waste managment facility in accordance with local,state &
federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: >95.0%
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: sec-butyl alcohol (sara iii)
cas: 78-92-2
rtecs #: eo1750000
fraction by wt:
osha pel: 150 ppm
acgih tlv: 100 ppm; 9293
Ld50 lc50 mixture: oral ld50 (rat) is >10,000 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: yes iarc: yes osha: no
health hazards acute and chronic: product is irritating to body tissues,
and is a central nervous system depressant, causing nausea and
dizziness. Chronic over exposure may cause dermatitis, liver
and/or kidney damage.
explanation of carcinogenicity: 1,4-dioxane is listed as a carcinogen by
iarc, ntp. Tested as a mixture, the product showed no
carcinogenicity.
effects of overexposure: headache, dizziness, drowsiness, nausea,
tingling or numbness of the extremities, senses of fullness in the
head, sense of warmth, stupor or dullness, lethargy and
drunkenness. Very high concentration s may lead to unconsciousness
or even death in confined or poorly ventilated areas.
medical cond aggravated by exposure: none given by manumacturer.
First aid: eye: flush w/water 15 min, hold lids open. skin: wash with
soap & water. Remove contaminated clothing and launder before
reuse. inhaled: remove to fresh air. Restore breathing if
necessary. Ingested: d o not induce vomiting. Give 2 large glasses
of milk or water and get immediate medical care. Give nothing by
mouth if unconscious. if irritation persists or is severe,see a
doctor.
Hcc: t4
boiling pt: b.P. Text: 165f,74c
vapor pres: 100 mm
vapor density: 4.55
spec gravity: 1.321
solubility in water: 0.07%
appearance and odor: clear, colorless liquid,irritating odor
percent volatiles by volume: 100%
Stability indicator/materials to avoid: yes
water and aluminum storage containers will deteriorate the material.
powdered reactive metals such as aluminum or zinc.
stability condition to avoid: high temperatures, arcs, sparks, and open
flames
hazardous decomposition products: when involved in fire, product emits
highly toxic and irritating fumes of hydrogen chloride and
phosgene.
Waste disposal methods: dispose i/a/w all federal, state and local
regulations. manufacturer suggests recycle (preferred) or
incinerate.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 96.5%
other rec limits: none specified
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: 1,4-dioxane (diethylene dioxide) (sara iii)
cas: 123-91-1
rtecs #: jg8225000
fraction by wt: 2.5%
other rec limits: none specified
osha pel: s, 100 ppm
acgih tlv: s, 25 ppm; 9293
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
ingred name: 1,2-butylene oxide (sara iii)
cas: 106-88-7
rtecs #: ek3675000
fraction by wt: 0.47%
other rec limits: none specified
epa rpt qty: 1 lb
dot rpt qty: 1 lb
ingred name: nitromethane
cas: 75-52-5
rtecs #: pa9800000
fraction by wt: 0.34%
other rec limits: none specified
osha pel: 100 ppm
acgih tlv: 100 ppm; 9192
Effects of overexposure: conjunctivitis,dermatitis,dizziness,mental
confusion,drowsiness,incoordination,unconsciousness.
First aid: eyes: flush eyes with plenty of water,get medical attention,if
irritation or injury develops.Skin: flush skin with plenty of
h*2o,get medical attention.Inhalation: if breathing stops,give
artificial resp iration.Ingestion: induce vomiting.No antidote know
Hcc: t4
boiling pt: b.P. Text: 165f
vapor pres: 100
vapor density: 4.55
spec gravity: 1.321
solubility in water: 0.07g/100g
appearance and odor: colorless liquid
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
water-slow hydrolysis produces corrosive acid.
stability condition to avoid: avoid open flames,welding arcs or other
high temp.Sources.
hazardous decomposition products: hydrogen chloride & very small amounts
of phosgene & cl*2
Waste disposal methods: send solvent to reclaimer.In some cases it can
be transported to an area where it can be placed on the ground and
allowed to evaporate safely.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 100%
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
Ld50 lc50 mixture: oral ld50 (rat) = 10300 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: skin,central nervous
system,cardio vascular system and eyes.See also signs and symptoms
of overexposure.
explanation of carcinogenicity: contains diethylene ether(1,4-dioxane).
1,4-dioxane listed by ntp and iarc as an animal carcinogen 11,4-d.
effects of overexposure: eyes/skin: irritation. Systemic
effects: respiratory tract irritation,anesthesia in high
concentrations,nausea and vomiting,diarrhea and abdominal
pain,cancer in animals.
medical cond aggravated by exposure: increased sensitivity to adrenalin
may be caused by over exposure.
First aid: eyes: flush with plenty of water for 15 minutes.See doctor.
skin: remove contaminated clothing and shoes. Wash with soap and
water.See doctor. Inhalation: remove victim to fresh air.Give
oxygen/cpr if needed.See doct0r. Ingestion: see
doctorimmediately.--never administer adrenaline--
Hcc: t4
boiling pt: b.P. Text: 162f(72c)
melt/freeze pt: m.P/f.P text: -36f(fz pt)
vapor pres: 100
vapor density: 4.6
spec gravity: 1.3
evaporation rate & reference: 0.4 (ether = 1)
solubility in water: moderate
appearance and odor: colorless clear liquid.Mildly sweet odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
none specified by manufacturer.
stability condition to avoid: contact with open flame, hot surfaces or
emissions from welding arc.
hazardous decomposition products: hydrogen chloride,phosgene and other
highly toxic substances.
Waste disposal methods: dispose of i/a/w federal, state & local
regulations
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 90-95%
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: 1,4-dioxane (diethylene dioxide) (sara iii)
cas: 123-91-1
rtecs #: jg8225000
other rec limits: nonr
osha pel: s, 100 ppm
acgih tlv: s, 25 ppm; 9293
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
Ld50 lc50 mixture: oral ld50 (rat) = 10300 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: may cause eye & skin
irritation. May cause respiratory tract irritation. Central nervous
system depressant. Loss of consciousness and even death can occur
at high levels of exposure.
explanation of carcinogenicity: not listed as a carcinogen by ntp, iarc
or osha
effects of overexposure: incoordination and impaired judgment may occur
at vapor exposures from 500-1000 ppm. Dizziness, drowsiness, and
general anestethic effects may occur in ranges of 1000 ppm and
higher.
medical cond aggravated by exposure: increased sensitivity to adrenaline
may be caused by over exposure.
First aid: inhalation: remove to fresh air. If not breathing, give cpr.
if breathing is difficult, give oxygen. Call a physician. Eye:
flush immediately with large amounts of water for 15 minutes. Get
medical at tention. Skin: remove contaminated clothing. Wash with
soap and water promptly. Ingestion: do not induce vomiting. Give
milk or usp mineral oil. Get immediate medical attention.
Hcc: t4
boiling pt: =73.9c, 165.F
melt/freeze pt: m.P/f.P text: none
vapor pres: 100
vapor density: 4.58
spec gravity: 1.34
evaporation rate & reference: 6.0 (n-butyl acetate=1)
solubility in water: slight
appearance and odor: clear, colorless liquid. Mild, chloroform-like
odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong caustics; strong oxidizing agents; chemicall-active metals such
as zinc, aluminum, magnesium powders, etc.
stability condition to avoid: high heat, open flames and other sources
of ignition
hazardous decomposition products: when involved in fire,
1,1,1-trichloroethane emits highly toxic and irritating hydrogen
chloride and phosgene fumes.
Waste disposal methods: dispose of i/a/w federal, state & local
regulations
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroethane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 100%
other rec limits: none recommended
osha pel: 350 ppm
acgih tlv: 350 ppm/450stel;9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
Routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: yes iarc: yes osha: no
health hazards acute and chronic: acute-eye: irritation with possible
corneal injury. Skin: irritation,defatting.
inhalation: dizziness,drowsiness,throat irritation(above 1,000ppm);
unconsciousness,cns depression,cardiac sensitization(ab ove
10,000ppm). Chronic: dermatitis, liver and heart disorders.
explanation of carcinogenicity: 1,4 diethylene dioxide is listed by ntp
and iarc as a possible carcinogen.
effects of overexposure: eye: irritation, redness and pain.
inhalation: dizziness, drowsiness, nausea, vomiting, unconsciousness
& even death in extreme cases.
medical cond aggravated by exposure: pre-existing conditions effecting
liver and heart.
First aid: inhalation: remove to fresh air, provide cpr/oxygen if needed.
eye contact: flush with water for 15 minutes. Skin contact: wash with
soap and water. Get med attention if symptoms persist. Ingestion: do
no t induce vomiting, get medical help immediately.
Hcc: t4
boiling pt: b.P. Text: 165f/74c
vapor pres: 100 mmhg
vapor density: 4.6
spec gravity: 1.32
evaporation rate & reference: 0.4 (ether =1)
solubility in water: negligible
appearance and odor: clear, colorless liquid, mildly sweet odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong alkalies,oxidizers & reactive materials.
stability condition to avoid: contact with open flame,hot surfaces.
hazardous decomposition products: hydrogen chloride, & phosgene.
Waste disposal methods: recovered liquids may be sent to licensed
reclaimer or incineration facility. Contaminated material must be
disposed of in a permitted waste management facility. Consult
federal,state or local disposa l authorities for approved
procedures.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 96.5%
other rec limits: none specified by m.
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: 1,4-dioxane (diethylene dioxide) (sara iii)
cas: 123-91-1
rtecs #: jg8225000
fraction by wt: 2.5%
other rec limits: none specified by m.
osha pel: s, 100 ppm
acgih tlv: s, 25 ppm; 9293
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
ingred name: 1,2-butylene oxide (sara iii)
cas: 106-88-7
rtecs #: ek3675000
fraction by wt: 0.47%
other rec limits: none specified
epa rpt qty: 1 lb
dot rpt qty: 1 lb
ingred name: nitromethane
cas: 75-52-5
rtecs #: pa9800000
fraction by wt: 0.34%
other rec limits: none specified
osha pel: 100 ppm
acgih tlv: 100 ppm; 9192
Ld50 lc50 mixture: oral ld50 (rat) = 10300 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: may cause eye & skin
irritation. May cause respiratory tract irritation. Central nervous
system depressant. Loss of consciousness and even death can occur
at high levels of exposure.
explanation of carcinogenicity: product contains no ingredients
currently classified as carcinogenic by ntp, iarc or osha.
effects of overexposure: above 1000 ppm: dizziness, drowsiness, throat
irritation. Unconsciousness and death above 10000ppm. Prolonged or
repeated skin contact can cause irritation, defatting of skin and
dermatitis. Slight te mporary eye irritation and/or corneal injury.
aspiration hazard; can cause chemical pneumonia.
medical cond aggravated by exposure: acute and chronic liver disease and
rhythm disorders of the heart.
First aid: inhalation: remove to fresh air. If not breathing, give
artificial respiration. Call a physician. Eye: flush immediately
with large amounts of water for 15 minutes. Get medical attention.
skin: remove contaminated clothing. Wash with soap and water
promptly. Ingestion: do not induce vomiting. Get immediate medical
attention. Note: adrenalin should never be given to persons
overexposed to product.
Hcc: t4
boiling pt: b.P. Text: 165f,74c
melt/freeze pt: m.P/f.P text: not given
vapor pres: 100 @20c
vapor density: 4.6
spec gravity: 1.32
evaporation rate & reference: 0.4 (ether=1)
solubility in water: negligible
appearance and odor: clear, colorless liquid, mildly sweet odor
percent volatiles by volume: 100 %
Stability indicator/materials to avoid: yes
strong alkalies, oxidizers and reactive metals
stability condition to avoid: avoid contact with open flame, electric
arcs or other hot surfaces which can cause thermal decomposition
hazardous decomposition products: when involved in fire,
1,1,1-trichloroethane emits highly toxic and irritating hydrogen
chloride, chlorine and phosgene
Waste disposal methods: prevent waste from contaminating surrounding
environment. Discard any product, residue, disposal container or
liner in accordance with all federal, state and local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 95.5% %
other rec limits: none recommended
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9293
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: 1,4-dioxane (diethylene dioxide) (sara iii)
cas: 123-91-1
rtecs #: jg8225000
other rec limits: none recommended
osha pel: s, 100 ppm
acgih tlv: s, 25 ppm; 9293
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
Ld50 lc50 mixture: tlv: 350 ppm
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: harmful if swallowed or inhaled.
explanation of carcinogenicity: not listed as a carcinogen by ntp, iarc
or osha
effects of overexposure: causes eye and skin irritation.
medical cond aggravated by exposure: increased sensitivity to adrenaline
may be caused by over exposure.
First aid: inhalation: remove to fresh air. If not breathing, give cpr.
if breathing is difficult, give oxygen. Call a physician. Eye:
flush immediately with large amounts of water for 15 minutes. Get
medical at tention. Skin: remove contaminated clothing. Wash with
soap and water promptly. Ingestion: do not induce vomiting. Give
milk or usp mineral oil. Get immediate medical attention.
Hcc: n1
boiling pt: b.P. Text: 165f,74c
melt/freeze pt: m.P/f.P text:
spec gravity: 1.32
solubility in water: negligible
appearance and odor: clear, colorless liquid with a mild, sweetish,
solvent odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
oxidizers, reactive metals and caustics.
stability condition to avoid: hot storage.
hazardous decomposition products: when heated to decomposition, it emits
highly toxic chloride fumes with a small amount of phosgene & toxic
carbon oxides
Waste disposal methods: this product, if disposed as shipped, is not a
hazardous waste as specified in 40 cfr 261. Consult state or local
officials for proper disposal method.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 95% min
other rec limits: none recommended
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9293
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: sec-butyl alcohol (sara iii)
cas: 78-92-2
rtecs #: eo1750000
fraction by wt: 1-2%
other rec limits: none recommended
osha pel: 150 ppm
acgih tlv: 100 ppm; 9293
ingred name: 1,3-dioxolane
cas: 646-06-0
rtecs #: jh6760000
fraction by wt: 2%
other rec limits: none recommended
Ld50 lc50 mixture: oral ld50 (rat) is 9600mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eyes: may cause irritation.Inhal: may
irritate nose,thrat and respiratory tract.May cause cns
depression.Ingest: may cause lung damage if vomited after
swallowing(aspiration pneumonitis).
explanation of carcinogenicity: there are no ingredients above 0.1%
which are identified as carcinogens by ntp,iarc or osha.
effects of overexposure: eyes: pain,tearing,inflammation.Cns
depression: giddiness,headache,dizziness,nausea
...Unconsciousness,death.Aspiration pneumonotis: coughing,labored
breathing,cyanosis(bluish skin) ...Death.
medical cond aggravated by exposure: persons with pre-existing
respiratory ailments may be at increased risk from exposure.
First aid: skin: remove contaminated clothing;wash with water.Eyes: flush
with water for 15 minutes.Inhal: remove to fresh air.Give oxygen or
artificial respiration if needed.Ingest: do not induce vomiting.Get
promp t qualified medical attention.If spontaneous vomiting
occurs,keep head lower than hips.
Hcc: t4
boiling pt: b.P. Text: 165f,74c
vapor pres: 100
spec gravity: 1.3
evaporation rate & reference: 0.37 (n-butyl acetate=1)
solubility in water: negligible
appearance and odor: liquid;water white;distinctive sweet odor
Stability indicator/materials to avoid: yes
strong oxidizing agents,hot reactive
metals(ca,zn,mg,al),barium,lithium.
stability condition to avoid: high heat,open flames.
hazardous decomposition products: hydrochloric acid gas,other corrosive
vapors.
Waste disposal methods: dispose of in accordance with federal,state and
local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: >95%
other rec limits: none recommended
osha pel: 350 ppm
acgih tlv: 350 ppm/450stel;9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: ethylene dichloride (sara iii)
cas: 107-06-2
rtecs #: ki0525000
fraction by wt:
other rec limits: none recommended
osha pel: 50 ppm; z-2
acgih tlv: 10 ppm; 9394
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
ingred name: 1-nitropropane
cas: 108-03-2
rtecs #: tz5075000
fraction by wt:
other rec limits: none recommended
osha pel: 25 ppm
acgih tlv: 25 ppm; 9394
ingred name: tert-butyl alcohol (sara iii)
cas: 75-65-0
rtecs #: eo1925000
fraction by wt:
other rec limits: none recommended
osha pel: 100 ppm
acgih tlv: 100ppm; 9394
ingred name: glycol methyl ether
cas: 646-06-0
rtecs #: jh6760000
fraction by wt:
other rec limits: none recommended
ingred name: sec-butyl alcohol (sara iii)
cas: 78-92-2
rtecs #: eo1750000
fraction by wt:
other rec limits: none recommended
osha pel: 150 ppm
acgih tlv: 100 ppm; 9394
ingred name: 1,2-butylene oxide (sara iii)
cas: 106-88-7
rtecs #: ek3675000
fraction by wt:
other rec limits: none recommended
epa rpt qty: 1 lb
dot rpt qty: 1 lb
ingred name: volatile organic compounds
rtecs #: 9999999vo
fraction by wt: 6.0%
other rec limits: none recommended
Ld50 lc50 mixture: tlv= 350 ppm in air.
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: skin: skin absorption possible from
extended expo.Moderate irrit & defat derm. Eyes: progressive irrit
from slight to moderate. Inhal: nose/throat irrit.Head,nau,gi
signs,vertigo,micoordination,cns depre
s,narcosis.Liver/kidney/lung/spleen toxicity from chronic expo may
occur. Ingest: throat/esophagus.Inhal symp,vomit,diarr
effects of overexposure: skin irrit, defatting dermatitis. Eye irrit.
nose/throat irrit, headaches, nausea, gastrointestinal signs,
vertigo, micoordination, central nervous sys depression, narcosis.
liver/kidney/lung/spleen t oxicity. Throat/esophagus irrit,
vomiting, diarrhea.
medical cond aggravated by exposure: none specified by mfg.
First aid: eyes: irrigation immed w/water for 5mins. Skin: wash off in
flowing water or shower. Inhal: remove to fresh air if effects
occur. Ingest: do not induce vomit. Call physician &/or transport to
emergency fa cility.
Hcc: t4
boiling pt: b.P. Text: 165f,74c
vapor pres: 100 @20c
vapor density: 4.5
spec gravity: 1.322
evaporation rate & reference: 1, ether=1
solubility in water: negligible
appearance and odor: clear liquid.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
avoid contact w/strong alkalies.
stability condition to avoid: heat, sparks, open flames. Avoid
pressurized systems containing aluminum.
hazardous decomposition products: burning may produce carbon monoxide
&/or carbon dioxide and hydrogen chloride, phosgene & various
hydrocarbons.
Waste disposal methods: sm spill: allow solvent to evaporate in hood.
dispose of solids in compliance w/local, state and federal
regulations. Lg spills: dispose of in compliance w/local, state and
federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 100%
other rec limits: none recommended
osha pel: 350 ppm
acgih tlv: 350 ppm/450stel;9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
Ld50 lc50 mixture: tlv for me chloroform is 350 ppm.
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eye, skin, lung, cns.
acute & chronic- inhalation of high concentrations of vapors/mists
may cause cns depression. Also, may cause permanent brain damage.
may cause eye irritation, pain & conjunctivitis. May cause
defatting of skin & chemical burns. Ingestion may result in pain &
irritation of gi tract.
explanation of carcinogenicity: none
effects of overexposure: headache, drowsiness, dizziness, loss of
coordination, irritation to eyes, skin, respiratory and
gastrointestinal tracts, skin defatting, diarrhea, abdominal pain,
eye pain and discomfort, confusion, coma, death
medical cond aggravated by exposure: persons with pre-existing skin
disorders, eye problems or impaired respiratory function may be
more susceptible to the effects of this product.
First aid: get medical help if symptoms persist. Inhaled: remove to fresh
air. Provide cpr/oxygen if needed. Eyes/skin: flush with water for
15 minutes. Oral: do not induce vomiting. If concious, drink large
amount of water. Get immediate medical attention. Note to
physician: never administer adrenaline following over exposure.
increased sensitivity of heart to adrenaline may be caused by
overexposure.
Hcc: t4
nrc/state lic num: not relevant
boiling pt: b.P. Text: 176f,80c
vapor pres: 135
vapor density: 4.54
spec gravity: 1.310
evaporation rate & reference: 0.35 (ethyl ether=1)
solubility in water: negligible
appearance and odor: clear, colorless liquid - ethereal odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong bases, strong oxidizing agents. Shock sensitive compounds may be
formed
stability condition to avoid: open ignition sources, high heat
hazardous decomposition products: may form carbon monoxide, carbon
dioxide, hydrochloric acid, phosgene.
Waste disposal methods: material may be disposed of by a licensed
reclaimer. Comply with local, state and federal laws. Waste may be
classified as u226 under rcra.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara 313)
(cercla)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 100%
other rec limits: none recommended
osha pel: 350 ppm
acgih tlv: 350 ppm/450stel;9495
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
Ld50 lc50 mixture: ld50 (oral, rat) is likely >2,000 mg/kg.
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: lung, eye, skin, cns,
heart. Acute- eye: causes irritation, pain. Skin: irritation,
defatting. Prolonged contact may result in absorption. Inhale: may
cause cns effects, irregular heartbeat s. Concentrations as low as
10,000 ppm can cause death. Oral: harmful if ingested. Chronic-
liver, kidney, thyroid effect
explanation of carcinogenicity: none
effects of overexposure: irritation, nausea, vomiting, headache,
dizziness, skin defatting and cracking, weakness, low blood
pressure, irregular heartbeats, unconsciousness, death, pain
medical cond aggravated by exposure: persons with pre-existing skin
disorders or eye problems or impaired liver, kidney or respiratory
function may be more susceptible to the effects of the substance.
First aid: get medical attention if symptoms persist. Eyes: immediately
flush with water for 15 minutes. Hold eyelids open. Skin: wash with
soap & water. Inhaled: remove to fresh air. Provide cpr/oxygen if
necessar y. Oral: do not induce vomiting. Call physician
immediately.
Hcc: t4
nrc/state lic num: not relevant
boiling pt: b.P. Text: 165f,74c
vapor pres: 100 @ 68f
vapor density: 4.5
spec gravity: 1.310
solubility in water: 0.07% @ 25c/77f
appearance and odor: clear, colorless liquid - irritating odor at high
concentrations
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
water, reactive metals (i.E., aluminum, zinc powder, potassium, sodium,
etc.)
stability condition to avoid: open flames, electrical arcs, excessive
heat
hazardous decomposition products: hydrogen chloride, carbon monoxide,
carbon dioxide, phosgene and chlorine may be formed.
Waste disposal methods: discharge, treatment or disposal is subject to
federal, state or local regulations. Recycling or incineration is
recommended. Contract with a licensed chemical disposal agency.
considered a toxic wast e number u226 under rcra 40 cfr 261.33.Rq
1000 lb
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara 313)
(cercla)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 95.0%
other rec limits: none recommended
osha pel: 350 ppm
acgih tlv: 350 ppm/450stel;9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: 1,3-dioxolane
cas: 646-06-0
rtecs #: jh6760000
fraction by wt: 2.85%
other rec limits: none recommended
ingred name: 1,2-butylene oxide (sara 313) (cercla)
cas: 106-88-7
rtecs #: ek3675000
fraction by wt: 0.47%
other rec limits: none recommended
epa rpt qty: 1 lb
dot rpt qty: 1 lb
ingred name: nitromethane
cas: 75-52-5
rtecs #: pa9800000
fraction by wt: 0.43%
other rec limits: none recommended
osha pel: 100 ppm
acgih tlv: 20 ppm; 9596
ingred name: sec-butyl alcohol (sara 313)
cas: 78-92-2
rtecs #: eo1750000
fraction by wt: 1.22%
other rec limits: none recommended
osha pel: 150 ppm
acgih tlv: 100 ppm; 9596