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Hydrogen fluoride (hydrofluoric acid)
Inorganic acids, n.E.S.
Chemicals-inorganic
Y - Indicates information is in the hazardous materials information resource system (hmirs).
PMICA - Item does not contain precious metal.
CRITL- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.
043940 - Chemicals noi
635 - Chemicals, other than drugs or sundries
9 - Other or no special handling required (sh)
A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.
C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp
W - Rating variable
W - Corrosive materials, un class 8 (corrosive label)
Questions & Answers: |
|
| What are the historical prices recorded for this stock number? | |
| Historical data shows pricing from $935.51 to $1,559.18.. | |
| Does NSN 6810-00-543-4012 have a shelf life? | |
| No. There is no shelf life applicable for this NSN. | |
| What NATO entities are users of this NSN? | |
| Department Of The Army, Department Of The Air Force, Department Of The Navy, Singapore, Malaysia, Canada, Germany, Republic Of Korea, Italy, Greece, and Turkey | |
| What is the NIIN of NSN 6810-00-543-4012? | |
| 005434012 or 00-543-4012 | |
| Does NSN 6810-00-543-4012 require demilitarization? | |
| Yes - ITAR Controlled | |
| What is the most recent solicitation for NSN 6810-00-543-4012? | |
| No solicitations for this NSN. | |
| When was this national stock number assigned to the federal catalog? | |
| Jan 01, 1963 | |
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: inhalation can cause coughing,
choking, & inflamation of the respiratory tract. Swallowing can
cause burns to mouth & g.I. Tract. Eye contact can cause severe
burns & damage. Skin contact can ca use severe burns and deep
penetration. Chronic: bone and joint changes(fluorosis) kidney and
liver damage,death possible
explanation of carcinogenicity: data per msds
effects of overexposure: eyes & skin-can cause irrit & severe burns.
ingest-severe burns,possible fatal hypocalcemia w/o med
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the eyes, skin, or
respiratory tract may be at increased risk from exposure.
First aid: inhalation: remove to fresh air. Resuscitate if not breathing.
get medical attention. Eyes: immediately flush with plenty of water
for 15 minutes holding eyelids open. Get immediate medical
attention. S kin: remove contaminated clothing. Wash with soap and
water. Get immediate medical attention. Ingestion: do not induce
vomiting. Give nothing by mouth if unconscious. Get immediate
medical attention.
Hcc: c1
boiling pt: b.P. Text: 152f,67c
vapor pres: 110 mmhg
vapor density: 2.21
spec gravity: 1.258
evaporation rate & reference:
solubility in water: complete
appearance and odor: colorless liq,sharp pungent odor;fumes in air
percent volatiles by volume: 100.0
Stability indicator/materials to avoid: yes
carbonates,sulfides & cyanides,alkalies & some oxides
stability condition to avoid: glass,concrete & silicon-bearing matls
hazardous decomposition products: boils away as hydrogen fluoride gas &
water
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state and local laws and regulations. Dispose
in a rcra-approved waste facility .
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: hydrogen fluoride (sara iii)
cas: 7664-39-3
rtecs #: mw7875000
fraction by wt: 70.0%
osha pel: 3 ppm/6 stel (f)
acgih tlv: c 3 ppm (f); 9192
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
Effects of overexposure: eyes,skin: severe irritant.Extreme irritnt to
respir tract.Ingestion can be fatal.
First aid: eyes: flush w h*2o 15 min.Skin: flush w lg amts h*2o.Remove
contaminated clothes.Follow by immers in ice/alc mix(70%)or sat'd
soln epsom salt,or 0.13% benzalkonium soln("zephiran" chloride).Get
immediat e medical attention.Inhale: remove to fresh air(cpr
Hcc: c1
boiling pt: b.P. Text: 218-230f
vapor pres: 10
vapor density: 0.7
spec gravity: 1.15
solubility in water: complete
appearance and odor: colorless fuming liquid;sharp penetrating odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
fluorine,aso*3,p*2o*5,alkali,metals: generate h*2 on contact
hazardous decomposition products: hf evolution increases with
temperature.
Waste disposal methods: consult federal,local,regional regulations for
disposal.May be(1) flushed through drain/sewer after large dilution
w h*2o.(2) in limited quantities,sanitary landfilled,after cautious
neutralization.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: hydrogen fluoride (sara iii)
cas: 7664-39-3
rtecs #: mw7875000
fraction by wt: 60%
osha pel: 3 ppm/6 stel (f)
acgih tlv: c 3 ppm (f); 9192
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 40%
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: vapor/mist extremely corr to
nose/throat/muc mem.Brief exposure causes irrit;prolonged exposure
sever irrit & tissue damage;hi concen results in death.Corr to
eyes.Prolong contact may result in blindn ess.
burns.Sev skin burns,death if burns over lg part of body.Corr to
mouth/throat,death from lg amts
explanation of carcinogenicity: this product is not listed by iarc, ntp,
or osha as a carcinogen.
effects of overexposure: inhal: bronchitis, pulmonary edema, chemical
pneumonitis. Cough, chest pains from brief exposure.
eyes: blindness, burns, death if burns over lg area of body.
ingest: burns tissue, severe abdominal pain, nausea, vomiting,
collapse. Lg quantities can cause death.
medical cond aggravated by exposure: per mfg's msds none known.
First aid: skin: flush w/water then soak area in .13% iced aqueous
zephirin chloride soln for 30-60mins.Use compresses if area can't
be immersed.Ingest: don't induce vomit.Give water or milk.Get immed
med attn.Inh al: remove to fresh air.Give artif resp if needed.Get
med attn.Eye: flush w/lg amts of water.Til med arrives apply 1-2
drops of .5% pontocaine hydrochloride followed by 2nd irrigation
for 15mins.
Hcc: c1
boiling pt: b.P. Text: see supplem
vapor pres: see supple
vapor density: 1.26
spec gravity: see supplem
solubility in water: complete (100%)
appearance and odor: fumes above 48% pungent, irritating odor
Stability indicator/materials to avoid: yes
alkalis;oxidizing or reducing
matls;cyanides;sulfides;glass;concrete;metals;organics such as
cloth,leather;water;acids.
stability condition to avoid: none specified by manufacturer.
hazardous decomposition products: may liberate hydrogen fluoride, flamm
hydrogen gas when contact w/some metals.
Waste disposal methods: dispose of contaminated material in a manner
approved for this material. Consult appropriate local, state and
federal regulatory agencies to ascertain proper waste disposal.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: hydrogen fluoride (sara iii)
cas: 7664-39-3
rtecs #: mw7875000
fraction by wt: 30-70%
other rec limits: none recommended
osha pel: 3 ppm (f)
acgih tlv: c 3 ppm (f); 9394
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
other rec limits: none recommended
Effects of overexposure: conjunctivitis,corneal burns,severe skin
burns,irritation to respiratory tract,eye burns,diarrhea.
First aid: ingestion: do not induce vomiting.Dilute w/ large amts of
h*2o,or milk given.Obtain medical attention.Eyes: flush w/h*2o for
at least 15-30 mins.Skin contact: flush w/large amts of h*2o.Remove
cont.Cloth ing.Inhalation: remove from exposure,getdoctor.
Hcc: c1
boiling pt: b.P. Text: 152f
vapor pres: 125
spec gravity: 1.258
appearance and odor: colorless.Pungent as halogen.
Stability indicator/materials to avoid: yes
glass,concrete,certain metals,silica,cast iron,org.Materials
Waste disposal methods: add slowly to a large amount of solution of soda
ash & slaked lime by stirring.Discharge the solution w/large amount
of h*2o into approved storage containers & ship to an approved
disposal area.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: hydrogen fluoride (sara iii)
cas: 7664-39-3
rtecs #: mw7875000
fraction by wt: 70.0%
osha pel: 3 ppm/6 stel (f)
acgih tlv: c 3 ppm (f); 9192
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 30.0%
Ld50 lc50 mixture: lc50(ihl-rat)= 1276 ppm/ 1 hour.
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: hydrofluoric acid is extremely
irritating and corrosive to skin and mucous membranes. Inhalation
of vapors may cause ulcers of the upper respiratory tract.
concentrations at 50 to 200 ppm are d angerous. Hydrofluoric acid
produces severe skin burns which are slow in healing. The
subcutaneous tissue may be affected, becoming blanched and
bloodless. Gangrene of the affected areas may follow.
explanation of carcinogenicity: data per msds
effects of overexposure: conjunctivitis, corneal burns; severe skin
burns with ulceration; pain behind breastbone, cough, spitting
blood, dyspnea, difficult breathing, bronchopneumonia, cyanosis,
shock, muscle spasms, convuls ions, jaundice, oliguria,
albuminuria, hematura, nausea, vomiting, abdominal pain, diarrhea;
burns and corrosion of mouth, esophagus, stomach and small bowel.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the eyes, skin, or
respiratory tract may be at increased risk from exposure.
First aid: eye contact: irrigate with large amounts of water. Get
medical attention. Skin: mmediately flush in a drenching shower of
water. Remove contaminated clothing. Wash with soap and water. Get
immediate medical attention. Inhalation: remove tofresh air. If
not breathing, give cpr. If breathing is difficult, give oxygen.
get medical attention. Ingestion: swallowing of hydrofluoric acid
causes severe b urns of the mucous membrane of mouth, throat,
esophagus ,and stomach. Drink large amounts of water, then milk or
2 oz. Of milk of magnesia. Get medical atention.
Hcc: c1
boiling pt: =66.7c, 152.F
melt/freeze pt: =-70.4c, -95.F
vapor pres: 130 mmhg
vapor density: 0.714
spec gravity: 1.26
ph: np (acid)
evaporation rate & reference:
solubility in water: complete
appearance and odor: a mobile colorless fluid which fumes in air and has
a sharp acrid odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
alkalies, glass, and ceramics.
stability condition to avoid: high temperatures, sparks, and open
flames. Uncontrolled contact with water and active metals.
excessive heat will cause pressure build-up.
hazardous decomposition products: fluorides and hydrogen gas on contact
with certain metals. Fumes can be highly corrosive
conditions to avoid polymerization: will not occur. However,
non-hazardous endothermic polymerization may occur in both the
liquid and gaseous phases.
Waste disposal methods: tdisposal should be made in accordance with all
applicable federal, state and local laws and regulations. Dispose
in a rcra-approved waste facility or sewer the neutralized slurry
with excess water if local ordinances allow.
Ingred name: hydrogen fluoride (sara iii)
cas: 7664-39-3
rtecs #: mw7875000
fraction by wt: 70.0%
osha pel: 3 ppm/6 stel (f)
acgih tlv: c 3 ppm (f); 9192
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
Ld50 lc50 mixture: lc50 inhal rat =1276ppm/1 hr
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: skin: toxic, burns, attack underlying
tissue & bone. Eye: blindness. Inhalation: pulmonary edema, death,
& toxic. Ingestion: toxic.
explanation of carcinogenicity: none
effects of overexposure: skin: toxic, burns, attack underlying tissue &
bones. Eye: blindness. Inhalation: pulmonary edema & death.
ingestion: toxic.
First aid: eyes: flush thoroughly w/water for at least 15 mins. Skin:
flush thoroughly w/plenty of water. Soak in or apply cold solution
of benzalkonium chloride or magnesium sulfate. Inhalation: remove
to fresh air. Give cpr or oxygen if needed. Ingestion: don't
induce vomiting. Give plenty of water, milk, milk of magnesia or
eggs beaten w/ water. Obtain medical attention in all cases.
Hcc: c1
boiling pt: b.P. Text: 226f,108c
vapor pres: 10
vapor density: 0.7
spec gravity: 0.98
solubility in water: miscible
appearance and odor: colorless, fuming liquid, w/pungent odor.
percent volatiles by volume: >99%
Stability indicator/materials to avoid: yes
acetic anhydride/ethanolamine/ammonia/calcium oxide/
ethylenediamine/ethyleneimine/propiolactone/propylene oxide see sup
hazardous decomposition products: hydrogen & fluorine.
Waste disposal methods: dispose of in accordance w/local, state, &
federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: water, h2o
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 40%
ingred name: hydrogen fluoride (sara iii)
cas: 7664-39-3
rtecs #: mw7875000
fraction by wt: 60%
other rec limits: 2.5 ppm
osha pel: 3 ppm/6 stel (f)
acgih tlv: c 3 ppm (f); 9192
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
Ld50 lc50 mixture: lc50 (inh, rat) 1276 ppm/hr
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: kidneys, respiratory
system, skeletal structures. Acute- corrosive/toxic.
eyes/skin: causes severe burns, eye damge, severe irritation.
rapidly absorbed through skin. Oral: causes severe b urns, toxic
effects on liver, heart, kidneys. Inhale: severe irritation, pain,
inflammation. Chronic- causes bronchitis.
explanation of carcinogenicity: none
effects of overexposure: severe irritation, severe burns, cough, nausea,
nasal discharge, respiratory failure, redness of eyes, blurred
vision, burning sensation in mouth and pharynx, salivation,
abdominal pain, vomiting bloo d, diarrhea, hematuria, difficulty
breathing, shock, rapid pulse, hypocalcemia, death
medical cond aggravated by exposure: persons with pre-existing skin
disorders or eye problems or impaired respiratory function may be
more susceptible to the effects of the substance.
First aid: get immediate medical help for all cases of exposure.
eyes/skin: immediately flush with water for at least 15 minutes.
hold eyelids open. Inhaled: remove to fresh air. Provide cpr/oxygen
if necessary. O ral: do not induce vomiting. If conscious, drink
large amount of water followed by milk or milk of magnesia. Never
give anything by mouth to an unconscious person.
Hcc: c1
nrc/state lic num: not relevant
boiling pt: b.P. Text: 151f,66c
vapor pres: 110
vapor density: 2.21
spec gravity: 1.26
ph:
viscosity: not relevant
evaporation rate & reference:
solubility in water: complete
appearance and odor: fuming colorless liquid with a strong pungent odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
water, glass, concrete, alkalies, some oxidizers, common metals,
lether, rubber and many organics
stability condition to avoid: excessive heat
hazardous decomposition products: fluoride and hydrogen gas
Waste disposal methods: dispose of in accordance with local, state and
federal regulations. Any release of this product to the environment
may be subject to reporting requirements.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: hydrogen fluoride (sara 302/313) (cercla)
cas: 7664-39-3
rtecs #: mw7875000
fraction by wt: 70%
other rec limits: none recommended
osha pel: 3 ppm (f)
acgih tlv: c 3 ppm(f); 9596
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
Ld50 lc50 mixture: lc50(ihl-rat)= 1276 ppm/ 1 hour.
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: -highly toxic by ingestion and
inhalation. Corrosive to all body tissues, and causes burns on
contact. Will penetrate skin and attack the underling tissues and
bones. possible risk of irriversi ble effects. May cause permanent
damageto eyes & lungs. Target organs: liver and kidney.
chronic: causes changes in bones and joints, possible mutagen.
explanation of carcinogenicity: none specified by manufacturer.
effects of overexposure: corneal burns; severe skin burns with
ulceration; pain, cough, spitting blood, dyspnea, difficult
breathing, bronchopneumonia, cyanosis, shock, muscle spasms,
convulsions, coma, nausea, vomiting, abdo minal pain, diarrhea;
burns and corrosion of mouth, esophagus, stomach.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: in case of contact, immediately flush eyes or skin with
copious amounts of water for at elast 15 minutes while removing
contaminated clothes & shoes. Assure adequate flushing of the eyes
by separating the eyelids with fingers. If inhaled, remove to
fresh air. If not breathing give artificial respiration. If
breathing is difficult, give oxygen. If swallowed, wash out mouth
with water provided perso n is conscious. Call a physician. Wash
contaminated clothing before reuse..
Hcc: c1
boiling pt: =18.9c, 66.F
melt/freeze pt: =-70.6c, -95.F
vapor pres: 25mm 20c
vapor density: 0.714
spec gravity: 1.150
evaporation rate & reference:
solubility in water: complete
appearance and odor: colorless liquid
Stability indicator/materials to avoid: yes
alkalies, glass, ceramics, metals, alkali metals.
stability condition to avoid: store away from heat & direct sunlight.
hazardous decomposition products: hydrogen fluoride.
conditions to avoid polymerization: dla-hmis: will not occur. However,
non-hazardous endothermic polymerization may occur in both the
liquid and gaseous phases.
Waste disposal methods: none specified by manufacturer. Dla-hmis:
disposal should be made in accordance with all applicable federal,
state and local laws and regulations. Dispose in a rcra-approved
waste facility or sewer t he neutralized slurry with excess waterif
local ordinances allow.
Ingred name: hydrogen fluoride (sara iii) or hydrofluoric acid
cas: 7664-39-3
rtecs #: mw7875000
= wt: 70.
osha pel: 3 ppm/6 stel (f)
acgih tlv: c 3 ppm (f); 9192
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
Ld50 lc50 mixture: lc50(ihl-rat)= 1276 ppm/ 1 hour.
health hazards acute and chronic: target organs: liver, kidneys. Acute
effects: may be fatal if inhaled, swallowed, or absorbed through
skin. Material is extremely destructive to tissue of the mucous
membranes and upper respiratory tr act, eyes and skin. Inhalation
may be fatal as a result of spasm, inflammation and edema of the
larynex and bronchi, chemical pneumonitis and pulmonary edema.
symptoms of exposure may include burning sensation, coughing,
wheezing, laryngitis, shortness of breath, headache, nausea and
vomiting. To the best of our knowledge the chemical, physical and
First aid: in case of contact, immediately flush eyes or skin with
copious amounts of water for at elast 15 minutes while removing
contaminated clothes and shoes. Assure adequate flushing of the
eyes by separati ng the eyelids with fingers. If inhaled, remove to
fresh air. If not breathing give artificial respiration. If
breathing is difficult, give oxygen. If swallowed, wash out mouth
with water provided per son is conscious. Call a physician. Wash
contaminated clothing before reuse..
Hcc: c1
vapor pres: 25mm 20c
vapor density: 1.27
spec gravity: 1.150
appearance and odor: colorless liquid
Stability indicator/materials to avoid: yes
strong bases. do not store in glass. avoid contact with metals.
stability condition to avoid: store away from heat & direct sunlight.
hazardous decomposition products: hydrogen fluoride.
Waste disposal methods: cautiously dissolve material in water.
neutralize immediately with sodium carbonate/add a little hcl
followed by sodium carbonate if material does not dissolve
completely. Add calcium chloride in exce ss of amount needed to
precipate fluoride, separate insoluble and bury in an approved
landfill for h azardous waste. Observe all regulations.
Ingred name: hydrofluoric acid (sara iii)
cas: 7664-39-3
rtecs #: mw7875000
minumum % wt: 70.
maxumum % wt: 75.
osha pel: 3 ppm (f)
osha stel: 6 ppm (f)
acgih tlv: c 3 ppm (f)
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs