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Sulfuric acid and oleum
Sulfuric acid; oleum
Chemicals-inorganic
Y - Indicates information is in the hazardous materials information resource system (hmirs).
PMICA - Item does not contain precious metal.
CRITL- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.
043940 - Chemicals noi
450 - Acids, liquid, corrosive
9 - Other or no special handling required (sh)
A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.
C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp
W - Rating variable
W - Corrosive materials, un class 8 (corrosive label)
Questions & Answers: |
|
| What are the historical prices recorded for this stock number? | |
| Historical data shows pricing from $320.15 to $533.59.. | |
| Does NSN 6810-00-551-5231 have a shelf life? | |
| No. There is no shelf life applicable for this NSN. | |
| What NATO entities are users of this NSN? | |
| Department Of The Army, Department Of The Air Force, U.s. Marine Corps, Department Of The Navy, U.s. Coast Guard, Brazil, Spain, New Zealand, Republic Of Korea, Greece, and Turkey | |
| What is the NIIN of NSN 6810-00-551-5231? | |
| 005515231 or 00-551-5231 | |
| Does NSN 6810-00-551-5231 require demilitarization? | |
| Yes - ITAR Controlled | |
| What is the most recent solicitation for NSN 6810-00-551-5231? | |
| No solicitations for this NSN. | |
| When was this national stock number assigned to the federal catalog? | |
| Jan 01, 1963 | |
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
effects of overexposure: severe eye and skin burns. Ingestion: severe
burns of the mouth and stomach. Inhalation: respiratory irritation.
teeth damage.
First aid: inhalation: remove to fresh air, give cpr/o2 if needed. Eyes
and skin: flush with large amounts of water for at least 15
minutes. Ingestion: rinse mouth. Get medical attention for eyes,
breathing diff iculty, or other symptoms of overexposure.
Hcc: c1
boiling pt: b.P. Text: 535f,279c
vapor pres: < 0.3
vapor density: 3.4
spec gravity: 1.83
evaporation rate & reference: < 1.0 (butyl acetate = 1)
solubility in water: complete
appearance and odor: clear to turbid, colorless to light brown liquid.
percent volatiles by volume: 0.0
Stability indicator/materials to avoid: yes
water, alkaline solutions, metals, strong oxidizing agents, reducing
agents
stability condition to avoid: high heat, moisture
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: comply with federal, state, and local
regulations. If approved neutralize and transfer to waste water
treatment center.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93.2%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
effects of overexposure: skin: causes irritation/severe burns. Eyes:
irritation, corneal burns, conjuctivitis. Ingestion: irritation,
corrosive burns to the mouth, throat, and stomach. Can be fatal if
swallowed. Inhalation: i rritation/burns to the upper respiratory
system, lungs, etc.
First aid: inhalation: remove to fresh air. If not breathing, give cpr.
if breathing is difficult, give oxygen. Eyes: immediately flush
with plenty of water for at least 15 minutes. Skin: wash/rinse with
soap an d water. Remove contaminated clothing and shoes. Ingestion:
dilute with water or milk. Do not induce vomiting. Get medical
attention in all cases.
Hcc: c1
boiling pt: b.P. Text: 534f,279c
spec gravity: 1.835
solubility in water: complete
appearance and odor: oily, colorless to slightly yellow, clear to turbid
liquid.
Stability indicator/materials to avoid: yes
oxidizers, flammable material, reducing material, carbides, chlorates,
sulfides
stability condition to avoid: high heat, moisture
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
conditions to avoid polymerization: avoid allyl compounds and aldehydes:
undergoes polymerization with these.
Waste disposal methods: waste sulfuric acid should be cautiously diluted
w/water & neutralzd w/alkali.Neutralzd waste must be disposed of
i/a/w applicable regulations or may have to be disposed of by an
approved contractor ( epa waste-d002) applies to neutralized waste.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93.0%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water; cas #7732-18-5
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 07.0%
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
effects of overexposure: causes severe burns - extremely corrosive.
repeated inhalation of mist may inflame lungs.
First aid: immediately wash with large amounts of water for at least 15
minutes. Contact a doctor immediately.
Hcc: c1
boiling pt: b.P. Text: 525f,274c
vapor density: 1
spec gravity: 1.8354
solubility in water: complete
appearance and odor: colorless slightly cloudy, oily liquid. Odorless.
Stability indicator/materials to avoid: yes
all metals, all organic materials
stability condition to avoid: high heat, noisture
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: neutralize with bicarbonate of soda and dilute
with water.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: corrosive to all body tissues.
inhaltion may cause serious lung damage. Contact with eyes may
result in total loss of vision. Skin contact may produce severe
necrosis. Fatal dose (adult) 1 teas poon to 1 ounce. Chronic:
repeated exposure causes trachea bronchitis, stomatitus,
conjunctivitis and gastritis.
explanation of carcinogenicity: sulfuric acid is not currently
classified as carcinogenic by ntp, iarc or osha.
effects of overexposure: repeated exposure may cause discoloration of
the teeth. Contact causes corrosion of mucous membranes of mouth,
throat, and esophagus with immediate pain and difficulty in
swallowing.
medical cond aggravated by exposure: those with chronic respiratory,
gastrointestinal, or nervous diseases and any eye and skin diseases
are at greater risk.
First aid: move exposed victim to fresh air. If not breathing, give
artificial respiration. Call emergency medical care. If contact
with material occurs, flush skin or eye with water for 15 minutes.
keep victim quiet and maintain body temperture. If ingested, do
not induce vomiting. Dilute the acid with water or milk.
Hcc: c1
boiling pt: b.P. Text: 529f,276c
spec gravity: 1.8354
solubility in water: complete
appearance and odor: clear, colorless to cloudy liquid. No odor.
percent volatiles by volume: 96 %
Stability indicator/materials to avoid: yes
carbides, fulminates, nitrates, picrates, powdered metals, combustible
materials, water, organic materials.
stability condition to avoid: high heat and pressure, moisture
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: dispose of waste material in accordance with
applicable local, state, and federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93.2%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
effects of overexposure: skin and eyes: causes severe burns. Inhalation:
mist from hot acid can be injurious to lungs.
First aid: eyes and skin: immediately flush with plenty of water for at
least 15 minutes. Get medical attention immediately. Soak skin in
water or swab generously up to 30 minutes, while awaiting doctor.
Hcc: c1
boiling pt: b.P. Text: >233f,>112c
vapor density: 2.7
spec gravity: 1.2135
solubility in water: complete
appearance and odor: slightly viscous, clear to slightly cloudy liquid.
no odor.
Stability indicator/materials to avoid: yes
combustible material, nitrates, carbides, chlorates, powdered metals
stability condition to avoid: high heat, moisture
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: carefully neutral acid with alkali. Dilute with
copious amounts of water. Observe federal, state, and local
effluent regulations. In some instances waste may be best handled
by a chemical disposal con tractor licensed for this purpose.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93.2%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
effects of overexposure: burns to skin, eyes, nose, and other membranes.
chronic - fibrosis, emphysema, conjunctivitis.
First aid: flush eyes and skin with water for at least 15 minutes.
inhalation: remove to uncontaminated area. Ingestion: drink large
amounts of water. Get medical treatment. Administration of oxygen
adequate but should be controlled by arterial bloodgas
verification.
Hcc: c1
boiling pt: b.P. Text: 538f,281c
spec gravity: 1.8354
solubility in water: complete
appearance and odor: clear, colorless to cloudy liquid. Biting odor.
Stability indicator/materials to avoid: yes
see section ix
stability condition to avoid: high heat, moisture
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: dispose in accordance with local, state, and
federal regulations. Neutralization to the required ph is the most
frequent practice prior to disposal. Hydrogen sulfide gas is formed
when acid contacts s ulfides in sewers.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93.2%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: oral rat ld50 is 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eye: irritation, corneal burns
conjunctivitis. Skin severe burns, necrosis, ulceration.
inhalation: irritation, burns to respiratory tract, pulmonary
edema. Lc50 = 20-60 mg/m3. Ingested: irritation, b urns to
gastrointestinal tract. Harmfulif swallowed. Chronic: erosion of
teeth, lesions, bronchitis
explanation of carcinogenicity: not listed as a carcinogen by iarc, ntp,
osha, acgih.
effects of overexposure: eye: irritation, burns, blindness. Skin: severe
burns, necrosis, ulcers. Inhalation: irritation, burns to
respiratory tract. Cough, discomfort, difficulty in breathing,
shortness of breath. Acute expo sure may cause pulmonary edema.
ingestiom: gastrointestinal irritation, burns. Can be fatal if
swallowed.
medical cond aggravated by exposure: none given by manufacturer.
First aid: eyes: flush with water 15 minutes, hold lids open. Skin: wash
with soap and water. Remove contaminated clothing and launder
before reuse. Inhalation: remove to fresh air. Restore breathing if
necessar y. Ingestion: do not induce vomiting. Give 2 large glasses
of milk or water . Get immediate medical care. Give nothing by
mouth if unconscious. If irritation persists or is severe. See a
doctor.
Hcc: c1
boiling pt: b.P. Text: 535f,279c
vapor pres: < 0.3
vapor density: 3.4
spec gravity: 1.835
ph: < 1
evaporation rate & reference: < 1 (n-butyl acetate = 1)
solubility in water: complete
appearance and odor: colorless to light brown, clear to turbid, oily,
odorless liquid.
Stability indicator/materials to avoid: yes
nitro compounds, carbides, dienes, alcohols, oxidizing agents,
aldehydes, allyls, metals
stability condition to avoid: high heat, moisture
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: dispose of in accordance with all federal,
state, and local regulations. Manufacturer makes no suggestions as
to method of disposal.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93.2%
other rec limits: none specified
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: ld50 oral rat = 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: corrosive! Causes severe burns to eyes
and skin on contact. Vapor extremely irritating to respiratory
tract. Contact with eyes may result in permanent visual loss.
swallowing may be fatal. Inhalation may damage respiratory tract.
repeated skin contact with dilute solutions may cause dermatitis.
may cause dental erosion
explanation of carcinogenicity: animal testing indicates that sulfuric
acid does not have the potential to produce carcinogenic, mutagenic
effects.
effects of overexposure: eye irritation, burning. Visual impairment.
respiratory tract irritation. Gastrointestinal tract irritation.
dermatitis. Dental erosion.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: eyes: immediately flush with water for at least 15 minutes.
skin: wipe off excess. Immediately flush with water for at least 15
minutes while removing contaminated clothing. Inhalation: remove to
fres h air. If not breathing, perform artificial respiration.
ingestion: drink copious amounts of water or milk. Do not induce
vomiting. In all cases, get immediate medical attention.
Hcc: c1
boiling pt: b.P. Text: 535f,279c
melt/freeze pt: m.P/f.P text: -21f,-29c
spec gravity: 1.835
evaporation rate & reference: < 1 (butyl acetate = 1)
solubility in water: completely miscible
appearance and odor: clear to slightly cloudy, oily liquid. Odorless to
slightly pungent odor.
Stability indicator/materials to avoid: yes
metals, metal oxides, hydroxides, nitrates, amines, carbonates,
alkaline materials, water
stability condition to avoid: high heat, moisture
hazardous decomposition products: explosive hydrogen gas is generated by
the action of acid on most metals and may accumulate in metal
containers.
Waste disposal methods: dispose of spilled, neutralized, or waste
product, contaminated soil, and other materials in accordance with
all local, state, and federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara 302/313) (cercla)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 75-100%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3/3 stel; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 1-25%
other rec limits: none recommended
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation of vapors causes severe
irritation or burns of the respiratory system, pulmonary edema, or
lung inflammation. Eye contact causes severe damage and possible
blindness. Skin contact causes bu rns and possible deep ulceration.
ingestion causes severe burns to mouth, throat, and stomach.
explanation of carcinogenicity: this chemical is not listed by iarc,
ntp, or osha as a carcinogen.
effects of overexposure: severe irritation or burns to eyes, nose and
throat. Pulmonary edema, bronical emphysema, conjunctivitis,
stomatitis, dental erosion, nausea and vomiting.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the respiratory tract may
be at increased risk from exposure.
First aid: inhalation: remove to fresh air. Resuscitate if not
breathing. Get medical attention. Eyes: immediately flush with
plenty of water for 30 minutes holding eyelids open. Get prompt
medical attention. Sk in: remove contaminated clothing. Wash with
plenty of water for 30 minutes. Get medical advice. Ingestion: do
not induce vomiting. Give nothing by mouth if unconscious. Get
immediate medical attention
Hcc: c1
boiling pt: b.P. Text: 203f,95c
vapor pres: negligible
vapor density: > 1
spec gravity: 1.27
ph: < 1
evaporation rate & reference: < 1 (ether = 1)
solubility in water: complete
appearance and odor: colorless, odorless liquid.
percent volatiles by volume:
Stability indicator/materials to avoid: yes
strong oxidizing or reducing agents, strong alkalis, cyandies,
sulfides, metals, water, combustible materials.
stability condition to avoid: high heat, moisture
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state and local environmental regulations.
unneutralized material will be a corrosive hazardous waste (code
d002).
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93.2%min
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
other rec limits: none specified
Ld50 lc50 mixture: ld50 (oral rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: inhalation of vapors may cause
severe irritation or burns of the respiratory system, pulmonary
edema, or lung inflammation. May cause severe burns to skin or
eyes. Blindness may result. Ingesti on may cause severe burns to
mouth, throat, and stomach. May affect kidney function. Chronic:
may damage lungs.
explanation of carcinogenicity: this product is not listed by iarc, ntp,
or osha as a carcinogen.
effects of overexposure: severe irritation or burns to eyes, nose and
throat. Pulmonary edema, bronchial emphysema, conjunctivitis,
stomatitis, dental erosion, nausea and vomiting.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the respiratory tract may
be at increased risk from exposure.
First aid: eyes/skin: immediately flush with plenty of water for at
least 15 minutes while removing contaminated clothing. Inhalation:
remove to fresh air. Observe for possible delayed reaction. Give
oxygen/cpr if needed. Ingestion: do not induce vomiting. Give
several glasses of milk (preferred) or water. For all exposures,
get immediate medical attention.
Hcc: c1
boiling pt: b.P. Text: 590f,310c
melt/freeze pt: m.P/f.P text: -17f,-27c
decomp temp: decomp text: >572f,>300c
vapor pres:
spec gravity: 1.842
ph: 0.9@1%
solubility in water: complete
appearance and odor: oily, colorless to slightly yellow, clear to turbid
liquid. Odorless.
Stability indicator/materials to avoid: yes
nitro compounds, carbides, alcohols (when heated), oxidizing agents,
alkyl compounds, aldehydes.
stability condition to avoid: avoid temperatures greater than 572f
(300c).
hazardous decomposition products: sulfur trioxide which is toxic,
corrosive and an oxidizer.
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state and local environmental regulations. Epa
hazardous waste number, d0002.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: >93.2%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9293
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: ld50 oral rat = 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: corrosive! Causes severe burns to eyes
& skin on contact. Vapor extremely irritating to respiratory tract.
contact with eyes may result in permanent visual loss. Swallowing
may be fatal. Inhalation ma y damage respiratory tract. Chronic
exposure may cause dental erosion. Target organs: eyes, skin, lungs,
gi tract.
explanation of carcinogenicity: none
effects of overexposure: eye irritation, burning. Visual impairment.
respiratory tract irritation. Gastrointestinal tract irritation.
dermatitis. Dental erosion.
First aid: eyes: immediately flush with water for at least 15 minutes.
skin: wipe off excess. Immediately flush with water for at least 15
minutes while removing contaminated clothing. Inhalation: remove to
fres h air. If not breathing, perform artificial respiration.
ingestion: drink copious amounts of water or milk. Do not induce
vomiting. In all cases, get immediate medical attention.
Hcc: c1
nrc/state lic num: not relevant
boiling pt: b.P. Text: 535f,279c
melt/freeze pt: m.P/f.P text: -21f,-29c
spec gravity: 1.835
ph: 1
evaporation rate & reference: < 1 (butyl acetate = 1)
solubility in water: completely miscible
appearance and odor: clear to slightly cloudy, oily liquid. Odorless to
slightly pungent odor.
Stability indicator/materials to avoid: yes
metals, metal oxides, hydroxides, nitrates, amines, carbonates,
alkaline materials, water
stability condition to avoid: high heat, moisture
hazardous decomposition products: explosive hydrogen gas is generated by
the action of acid on most metals and may accumulate in metal
containers.
Waste disposal methods: dispose of spilled, neutralized, or waste
product, contaminated soil, and other materials in accordance with
all local, state, and federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93.2%min
other rec limits: none specified
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 6.8%max
other rec limits: none specified
Ld50 lc50 mixture: lc50 rat = 500 mg/m3
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: corrosive to all body tissues,
irritation, severe burns of eyes, skin, respiratory, and
gastrointestinal tract. Toxic by inhalation. Chronic: lungs damage,
dental erosion.
effects of overexposure: irritation, burns, eye damage, coughing,
difficulty in breathing.
medical cond aggravated by exposure: open wounds and sores. Emphysema
and bronchitis.
First aid: eyes: flush with water, holding eyelid open for at least 15
minutes. Consult a physician immediately. Skin: wash thoroughly
with plenty of water, remove contaminated clothes. Inhalation:
remove to fre sh air, provide cpr/oxygen if needed. Ingestion:
drink large amounts of water if conscious, then induce vomiting.
consult a physician immediately.
Hcc: c1
boiling pt: b.P. Text: 535f,279c
vapor pres: < 0.5
spec gravity: 1.8354
ph: acidic
solubility in water: complete
appearance and odor: clear to slightly turbid liquid. Off white to straw
color. Usually odorless.
corrosion rate: unknownn
Stability indicator/materials to avoid: yes
alkaline material, salt of other acids, combustibles, and organic
materials.
stability condition to avoid: extreme heat, water.
hazardous decomposition products: toxic sulfur dioxide and sulfur
trioxide.
Waste disposal methods: consult local authorities. Disposal must be in
accordance with local, state, and federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 7%
Ld50 lc50 mixture: ld50 (oral rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation of vapors causes severe
irritation or burns of the respiratory system, pulmonary edema, or
lung inflammation. Eye contact causes severe damage and possible
blindness. Skin contact causes bu rns and possible deep ulceration.
ingestion causes severe burns to mouth, throat, and stomach.
explanation of carcinogenicity: this chemical is not listed by iarc,
ntp, or osha as a carcinogen.
effects of overexposure: severe irritation or burns to eyes, nose and
throat. Pulmonary edema, bronical emphysema, conjunctivitis,
stomatitis, dental erosion, nausea and vomiting.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the respiratory tract may
be at increased risk from exposure.
First aid: inhalation: remove to fresh air. Resuscitate if not breathing.
get medical attention. Eyes: immediately flush with plenty of water
for 15 minutes holding eyelids open. Get prompt medical attention.
skin : remove contaminated clothing. Wash with plenty of water for
15 minutes. Get medical advice. ingestion: do not induce vomiting.
give nothing by mouth if unconscious. Get immediate medical
attention.
Hcc: c1
boiling pt: b.P. Text: 640f,338c
melt/freeze pt: m.P/f.P text: 37.0f,2.8c
spec gravity: 1.8354
ph:
solubility in water: complete
appearance and odor: clear to slightly cloudy, oily liquid; odorless to
slightly pungent odor.
percent volatiles by volume: 0-20
Stability indicator/materials to avoid: yes
water, many metals and strong alkali materials. Carbides, chlorates,
fulminates, nitrates, or picrates. Organic material
stability condition to avoid: none known.
hazardous decomposition products: sulfur trioxide and/or sulfur dioxide.
toxic and explosive hydrogen sulfide may be formed under certain
conditions.
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state and local environmental regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 80-100%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ld50 lc50 mixture: ld50 (oral, rat) 2,140 mg/kg
carcinogenicity inds - ntp: no
iarc: no
osha: no
effects of exposure: concentrated sulfuric acid is a strong mineral acid, an
oxidizing agent, and a dehydrating agent that is rapidly damaging to all
human tissue with which it comes in contact. Ingestion may cause severe
injury or death. Eye contact produces severe or permanent injury. Inhalation
of mists can damage both the upper respiratory tract and the lungs.
explanation of carcinogenicity: this product is not considered a carcinogen by
ntp, iarc, or osha.
signs and symptions of overexposure: concentrated sulfuric acid is a strong
mineral acid, an oxidizing agent, and a dehydrating agent that is rapidly
damaging to all human tissue with which it comes in contact. Ingestion may
cause severe injury or death. Eye contact produces severe or permanent
injury. Inhalation of mists can damage both the upper respiratory tract and
the lungs.
medical cond aggravated by exposure: not provided.
first aid: eye contact: immediately flush eyes with plenty of running water for
at least 15 minutes. Speed is extremely important. Obtain medical attention
as soon as possible. Skin contact: immediately flush af fected areas with
water, removing contaminated clothing while under the safety shower. Continue
washing and get medical attention. Inhalation: remove to fresh air. Restore
breathing. Call a physician immediately. Ingestion: dilute acid immediately
with large amount of milk or water, then give milk of magnesia. Do not induce
vomiting. If occurs spontaneously, give more fluid. Obtain medical attenti on
as soon as possible.
hcc: c1
nrc/state lic no: not relevant
b.P. Text: 281- 338 c
melt/freeze pt: =-36.5c, -34.F
vapor pres: <1 @ 100f
vapor density: unknown
spec gravity: 1.8354
evaporation rate & reference: unknown
solubility in water: completely miscible
appearance and odor: clear, colorless, hygroscopic, oily liquid - odorless
percent volatiles by volume: 100
corrosion rate: unknown
product id: sulfuric acid, concentrated
cage: 75656
company name: los angeles chemical co
street: 4545 ardine st
po box: 1987
city: south gate ca
zipcode: 90280
health emergency phone: 800-356-3129
label required ind: y
date of label review: 12/23/1999
status code: c
mfg label no: unknown.
label date: 06/18/1993
year procured: 2000
origination
eye protection ind: yes
skin protection ind: yes
signal word: danger
respiratory protection ind: no
health hazard: severe
contact hazard: severe
fire hazard: none
=======================================================
responsible party cage: 75656
trans id no: 76489
product id: sulfuric acid, concentrated
msds prepared date: 06/18/1993
review date: 12/23/1999
mfn: 1
net unit weight: 99.4 lbs
multiple kit number: 0
review ind: y
unit of issue: dr
container qty: 1
type of container: drum
additional data: the maximum allowed by passenger/cargo air: 1 l / 30 l. Cargo
aircraft only. Un id number, hazard cl ass per msds.
Hazard and precautions: target organs: eyes, skin, respiratory system, teeth
(). Eye contact: immediately flush eyes with plenty of running water for at
least 15 minutes. Speed is extremely important. Obtain medical atte ntion as
soon as possible. Skin contact: immediately flush affected areas with water,
removing contaminated clothing while under the safety shower. Continue
washing and get medical attention. Inhalatio n: remove to fresh air. Restore
breathing. Call a physician immediately. Ingestion: dilute acid immediately
with large amount of milk or water, then give milk of magnesia. Do not induce
vomiting. Obta in medical attention as soon as possible
spill release procedures: notify safety personnel, provide ventilation. Stop
leak if you can do without risk. Cleanup personnel need protection against
inhaltion or contact. Keep upwind. Contain spill. Minor spills can be dilu
ted with water and neutralized with soda ash or lime. If water is not
available, cover contaminated area with sand, ashes or gravel and neutralize
cautiously with soda ash or lime.
neutralizing agent: suitable alkali such as lime or soda ash
waste disposal methods: follow federal, state, and local regulations. Runoff to
sewer may create hydrogen gas, which is a fire or explosion hazard. Epa (cwa)
rq 1000 lbs (40 cfr 117).
handling and storage precautions: store in clean, ventilated storage areas
having acid-resistant floors and good drainage. Keep out of direct sunlight.
use nonsparking tools free of oil, dirt, grit and vapor-proof electrical
fixtures . Avoid breathing mist or vapors. Avoid contact with skin or eyes.
do not ingest.
other precautions: avoid breathing mist or vapors. Avoid contact with skin or
eyes. Do not ingest. Do not add water to concentrated acid. Drums may contain
hydrogen gas, so open cautiously.
Ld50 lc50 mixture: oral ld50(rat): 2140 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: adverse effects of kidney function and
may be fatal. Target organs: respiratory system, eyes, skin, teeth.
chronic overexposure may result in lung damage.
effects of overexposure: inhalation of vapors may cause severe
irritation of the respiratory system. Liquid may cause severe burns
to skin and eyes. Ingestion is hramful and may be fatal. Ingestion
may cause nausea and vomiti ng. Ingestion may cause severe burns to
mouth, throat, and stomach. May have adverse effects of kidney
function and may be fatal.
medical cond aggravated by exposure: none identified.
First aid: call aphysician. If swallowed, do not induce vomiting; if
conscious, give water, milk or milk of magnesia. If inhaled, remove
to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. In case of contact,
immediately flush eyes or skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash
clothing before reuse.
Hcc: c1
vapor pres: 0
spec gravity: 1.86
solubility in water: appreciable
appearance and odor: clear, colorless to light yellow,oily odorless
liquid
Stability indicator/materials to avoid: yes
water,most common metals. Organic materials,strong oxidizing agents,
combustible materials, strong bases.
stability condition to avoid: moisture,heat
hazardous decomposition products: oxides of sulfur.
Waste disposal methods: dispose in accordance with all applicable
federal, state and local environmental regulations. Epa hazardous
waste number: d002, d003 (corrosive, reactive waste).
Ingred name: deuterated sulfuric acid
cas: 13813-19-9
minumum % wt: 90.
maxumum % wt: 100.
Ld50 lc50 mixture: oral ld50 (rat): 2140 mg/kg.
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: eyes/skin: liquid may cause
severe burns to eyes and skin. Inhalation: vapors may cause severe
irritation of the respiratory system. Ingestion: ingestion is
harmful and may be fatal. May cause severe burns to mouth, throat,
and stomach. May have adverse effect on kidney function and may be
fatal. Chronic: over exposure may result in lung damage. Target
organs: respiratory system, eyes, skin , teeth.
effects of overexposure: inhalation of vapors may cause severe
irritation of the respiratory system, lung damage. Liquid may cause
severe burns to skin and eyes. Ingestion is harmful and may be
fatal. Ingestion may cause naus ea and vomiting. Ingestion may
cause severe burns to mouth, throat, and stomach. May have adverse
effects of kidney function and may be fatal.
medical cond aggravated by exposure: none identified.
First aid: call a physician. If swallowed, do not induce vomiting; if
conscious, give water, milk or milk of magnesia. If inhaled, remove
to fresh air. If not breathing, give artificial respiration. If
breathing is difficult, give oxygen. In case of contact,
immediately flush eyes or skin with plenty of water for at least 15
minutes while removing contaminated clothing and shoes. Wash
clothing before reuse.
Hcc: c1
vapor pres: 0
spec gravity: 1.86
solubility in water: appreciable,100%.(water)
appearance and odor: clear, colorless to light yellow, oily odorless
liquid.
Stability indicator/materials to avoid: yes
water, most common metals, organic materials, strong reducing agents,
combustible materials, strong bases.
stability condition to avoid: moisture, heat.
hazardous decomposition products: oxides of sulfur.
conditions to avoid polymerization: will not occur.
Waste disposal methods: dispose in accordance with all applicable
federal, state and local environmental regulations. Epa hazardous
waste number: d002, d003 (corrosive, reactive waste).
Ingred name: deuterated sulfuric acid
cas: 13813-19-9
minumum % wt: 90.
maxumum % wt: 100.
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3