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Methanol (methyl alcohol)
Methanol (methyl alcohol)
Chemicals-organic
Y - Indicates information is in the hazardous materials information resource system (hmirs).
PMICA - Item does not contain precious metal.
CRITL- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.
042690 - Alcohol amyl etc
635 - Chemicals, other than drugs or sundries
9 - Other or no special handling required (sh)
A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.
C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp
R - Flammable liquids, un class 3 (flammable liquids label)
W - Rating variable
Questions & Answers: |
|
| What are the historical prices recorded for this stock number? | |
| Historical data shows pricing from $39.65 to $66.08.. | |
| Does NSN 6810-00-597-3608 have a shelf life? | |
| No. There is no shelf life applicable for this NSN. | |
| What NATO entities are users of this NSN? | |
| Department Of The Army, Department Of The Air Force, Defense Threat Reduction Agency, Department Of The Navy, U.s. Coast Guard, National Aeronautics and Space Administration, Poland, Brazil, Spain, Singapore, Kuwait, Germany, Republic Of Korea, Norway, Greece, and Turkey | |
| What is the NIIN of NSN 6810-00-597-3608? | |
| 005973608 or 00-597-3608 | |
| Does NSN 6810-00-597-3608 require demilitarization? | |
| Yes - ITAR Controlled | |
| What is the most recent solicitation for NSN 6810-00-597-3608? | |
| No solicitations for this NSN. | |
| When was this national stock number assigned to the federal catalog? | |
| Jan 01, 1963 | |
Effects of overexposure: dermatitis,muscular
incoordination,headache,dizziness,respiratory
failure,blindnes,impaired renal fu
First aid: inhale: remove to fresh air, give cpr/o*2 if
need;eyes/skin: flush w lg amts h*2o for 15 min;ingest: rinse mouth;
get medical attention for eyes, breathing difficulty, or other
symptoms of overexposure.
Hcc: f5
boiling pt: b.P. Text: 148f/65c
vapor pres: 100
vapor density: 1.11
spec gravity: 0.7891
evaporation rate & reference: 12.0 (but.Acet=1)
solubility in water: miscible
appearance and odor: clear,colorless,flammable,mobile,highly polar liq
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizing materials,chromic anhydride,perchloric acid
stability condition to avoid: sparks and flames
hazardous decomposition products: formaldehyde,co,formic acid.
conditions to avoid polymerization: temperature above 385c
Waste disposal methods: waste material should be incinerated in an
approved combustion system. Disposal must be in accordance with
local, state and federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 99.8%
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: ld50 (oral rat) is 5628 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: methanol is a neurotoxin causing
central nervous system depression. Toxicity varies from one
individual to the next with as little as 4 ml ingested being toxic.
methanol is very toxic to the optic n erve, causing sight
disturbances and blindness well below the toxic amount. It may
cause liver and/or kidney damage.
explanation of carcinogenicity: none of the compounds in this product is
listed by iarc, ntp, or osha as a carcinogen.
effects of overexposure: eye: irritation. skin: irritation, defatting.
inhaled: headache,drowsiness,lassitude,loss of appetite,inability to
concentrate. ingested: g/i
irritation,nausea,vomiting,diarrhea,central nervous system
depression. May cause visual disturbances, upto and including
blindness.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the skin, eye, respiratory
tract, liver or kidney may be at increased risk from exposure.
First aid: eye: flush w/water 15 min, hold lids open. skin: wash with
soap & water. Remove contaminated clothing and launder before
reuse. inhaled: remove to fresh air. Restore breathing if
necessary. Ingested: d o not induce vomiting. Give 2 large glasses
of milk or water and get immediate medical care. Give nothing by
mouth if unconscious. if irritation persists or is severe,see a
doctor.
Hcc: f5
boiling pt: b.P. Text: 149f,65c
melt/freeze pt: m.P/f.P text: -137f,-94c
vapor pres: 97.25 mm
vapor density: 1.11
spec gravity: 0.7914
evaporation rate & reference: 4.6 (butyl acetate = 1)
solubility in water: complete
appearance and odor: clear, colorless liquid,alcohol odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizing agents
stability condition to avoid: high temperatures, sparks, and open flames
hazardous decomposition products: carbon monoxide can form on incomplete
combustion.
Waste disposal methods: dispose i/a/w all federal, state and local
regulations. dgsd-ssh suggests that disposal may be done by
incineration.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Effects of overexposure: eye: irrit. Skn: defatting.
inh: hdch,dizz,weak,gastrointest/sight problems.
ing: drunk,drows,blindness.
First aid: skin: wash w water.Eyes: flush w water.Inhaled: giv cpr/oxygen
if necessary.Ingest: immediately induce vomiting by having victim
drink soapy water.For all routes keep patient warm/cover eyes.Seek
medical attention.
Hcc: f5
boiling pt: b.P. Text: 148f,64c
vapor pres: 92
vapor density: 1.1
spec gravity: 0.79
evaporation rate & reference: 6.3(ether=1)
solubility in water: complete
appearance and odor: colorless liquid,mild alcohol odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidants,active metals,isocyanates.
stability condition to avoid: heat,ignition sources.
hazardous decomposition products: combustion reported to yield co*2 &
co.
Waste disposal methods: eliminate ignition sources.Notify
authorities.Package and dispose in accordance with local,state and
federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 99.9%
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: health hazard to eyes,skin,central
nervous system and gastrointestinal tract.
effects of overexposure: eyes: irritation,stinging,tearing,redness.
skin: irritation,redness,burning,drying,cracking.
inhalation/;irritation of nose and thraoat,nervous system
depression,on,cns depression,drowsiness,dizziness,c
onvulsions,coma,death.
medical cond aggravated by exposure: individuals with pre-existing
respiratory or skin conditions may be more susceptible to the
effects of this material.
First aid: eyes: flush with of water for at least 15 minutes.See doctor.
skin: remove contaminated clothing,flush with soap and warter.See
doctor. Inhalation: move to fresh air.Give oxygen,cpr if needed.See
doctor.
Hcc: f5
boiling pt: b.P. Text: 147f/64c
vapor pres: 96
vapor density: 1.1
spec gravity: 0.7925
evaporation rate & reference: 3.5 (butyl acetate=1)
solubility in water: complete
appearance and odor: clear colorless liquid,characteristic odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizers,strong acids and bases.
stability condition to avoid: sparks;heat,fires.
hazardous decomposition products: carbon monoxide,carbon dioxide.
Waste disposal methods: incinerate or dispose of collected material in
accordance with local,state and federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: >99%
other rec limits: 250 ppm (stel)
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Effects of overexposure: skn/eye: irrit. Inh: hdch,dizz,naus.
ing: irrit,vomit,drunk,drows,blindness.
First aid: eyes/skin: flush w/water.Call dr.Inhal: move to fresh air,keep
quiet and warm call dr. Ingest: give 2 glasses water incude vomiting
immediately.Call dr.Keep person warm/quiet if swallowed inhaled
product .
Hcc: f5
boiling pt: b.P. Text: 147f,64c
vapor pres: 98.
vapor density: 1.1
spec gravity: 0.792
evaporation rate & reference: 5.91(butylacetate)
solubility in water: complete
appearance and odor: clear colorless liquid, alcohol odor.
percent volatiles by volume: 100.
Stability indicator/materials to avoid: yes
oxidizing & corrosive material.
stability condition to avoid: source of ignition/open flames
hazardous decomposition products: may form toxic matls.Co*2 & co.
Waste disposal methods: review all local,state & fed regs to determine
approved disposal procedures.However,waste can be disposed of by
liq incineration or land fill methods iaw local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 99.8%
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: prolonged or repeated inhalation may
cause central nervous system toxic effects leading to blindness or
death. Ingestion can be fatal. Brief contact may cause dryness.
prolonged or repeated skin conta ct may cause dermatitis. May be
absorbed through intact skin. Contact with eyes may cause burns.
chronic- dermatitis.
explanation of carcinogenicity: not listed
effects of overexposure: inhalation may cause headaches, nausea,
vomiting, dizziness, visual disturbances, giddiness, intoxication,
sleepiness, unconsciousness & death. Ingest can cause blindness,
dizziness, headaches, or nau sea. Vapors will irritate eyes. Brief
skin contact may dry the skin. Prolonged contact may irritate the
skin.
medical cond aggravated by exposure: pre-existing skin disorders may be
more susceptible to this material.
First aid: call a doctor if symptoms persist.Eye: immediately flush with
water for 15 minutes,holding eyelids open.Skin: wash with soap &
water.Inhaled: remove to fresh air.Provide cpr/oxygen if
needed.Oral: if cons cious,drink 2-4 glasses of water & induce
vomiting.Call a physician/poison control center immediately.
Hcc: f5
boiling pt: b.P. Text: 148f,64.4c
melt/freeze pt: m.P/f.P text: -144f,-98c
vapor pres: 44.6
vapor density: 1.1
spec gravity: 0.79
solubility in water: complete
appearance and odor: clear, colorless liquid. Characteristic odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizing agents,aluminum,zinc,any metal that displaces
hydrogen;certain plastics,rubbers,acids & alkalis.
stability condition to avoid: heat,sparks,open flames
hazardous decomposition products: may liberate carbon monoxide,carbon
dioxide, formaldehyde, and unidentified organic compounds in black
smoke.
Waste disposal methods: put material into dot approved waste containers.
keep out of sewers, storm drains, surface waters and soil.
incinerate in accordance with all applicable federal, state and
local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii) *
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: >99%
osha pel: s,200ppm/250stel *
acgih tlv: s,200ppm/250stel; 92
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Effects of
overexposure: ingest: narcosis,headache,nausea,vomtg,blindness, &
death;inhal: narcosis,headache,nausea;skin/eye: irt
First aid: inhal: rmv to fresh air. If not brthng give cpr; if brthng
diff give oxygen. Eye: immed flush w/plenty of water. Skin: wash
w/soap&water. Rmv contam clthg&shoes. Ingest: induce vomit. Rpt
until vomit is c lear, nothg by mouth if unconsc. Get medical attn.
Hcc: f5
boiling pt: b.P. Text: 148f,65c
vapor pres: 96
vapor density: 1.11
spec gravity: 0.7925
evaporation rate & reference: 2.0,butyl acetate
solubility in water: complete
appearance and odor: clear, colorless liquid, alcohol odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidants,active metals,isocyanates
stability condition to avoid: heat, ignition sources
hazardous decomposition products: co*2,co,c
Waste disposal methods: chemical incineration;biological
treatment.Approved landfill.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 99.9%
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Effects of overexposure: weakness,headache,nausea,vomiting,abdominal
pain,dimness of vision,convulsions,delirium,coma.
First aid: irrigate eyes with water,stomach wash,with 4% aqueous sodium
carbonate,if swallowed,followed by saline catharis.Move to fresh
air,remove contaminated clothing,wash body with soap & water.Combat
shock: oxygen,stimulants if indicated.Seek medical aid.
Hcc: f5
boiling pt: b.P. Text: 147f,63.9c
vapor pres: 92
vapor density: 1.1
spec gravity: 0.8
solubility in water: complete
appearance and odor: clear,colorless liquid,slight alcoholic odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
oxidizers,acids,alkalis,use no water
stability condition to avoid: ignition sources.
Waste disposal methods: keep in covered drums,pending disposal. Handle &
dispose in full compliance with all applicable
international,federal,state & local regulations. Mfg suggests
incineration;may mix w more flammable solv ent first, or dilute w
h*2o,ship to disposal area.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 100%
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Effects of overexposure: dermatitis, headache, dizziness, nausea,
vomiting, sweating, weaknes, respiratory failure coma
First aid: irrigate eyes with water; wash contaminated areas of body
with soap & water. Ingestion: if conscious-induce vomiting followed
by 1 tsp baking soda in a glass of water. Get physician
immediately.
Hcc: f5
boiling pt: b.P. Text: 148f,64.5c
vapor density: 1.11
spec gravity: 0.7924
solubility in water: complete
appearance and odor: colorless liquid, slight alcohol odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
stability condition to avoid: exposure to sparks & flames
Waste disposal methods: keep in covered drums,pending disposal. Handle &
dispose in full compliance with all applicable
international,federal,state &local regulations. Mfg suggests
flushing sm spill with h*2o.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 100%
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eyes: irritation, blindness as result
of systemic toxicity from skin contact, ingestion or inhalation.
skin: irritation,
absorption/defatting/dermatitis/drying/cracking/redness/scaling.
inhalation: cen tral nervous system depression
w/nausea/headache/dizziness. Ingestion:
weakness/fatigue/dizziness/headaches/nausea.
explanation of carcinogenicity: none
effects of overexposure: eyes: irritation, blindness as result of
systemic toxicity from skin contact, ingestion or inhalation. Skin:
absorption, irritation, defatting, dermatitis, drying, cracking,
redness, scaling. Inhalati on: central nervous system depression,
nausea, headache, dizziness. Ingestion: weakness, fatigue,
dizziness, headaches.
First aid: eyes: flush w/running water for at least 15 minutes. Skin:
wash w/soap & water. Inhalation: remove from exposure. If breathing
is difficult, give oxygen. If breathing ceases, administer
artificial res piration followed by oxygen. Ingestion: poison, call
a physician & induce vomiting immediately. Physican note: ethanol
is antidotal - blood level range 1-1.5 mg/l.
Hcc: f5
boiling pt: b.P. Text: 148f
vapor pres: 96
vapor density: 1.11
spec gravity: 0.7910
evaporation rate & reference: (ethyl ether=1)
solubility in water: complete
appearance and odor: clear, colorless liquid, slight alcohol odor
percent volatiles by volume: 100%
Stability indicator/materials to avoid: yes
anhydrides, sodium, organometallic compounds, oxygen & strong oxidizing
agents.
hazardous decomposition products: co, co2
Waste disposal methods: incinerate or otherwise manage in rcra permitted
waste management facility.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methanol (methyl alcohol), columbian spirits
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: >99%
other rec limits: 200 ppm
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: tlv 200 ppm (ceiling limit)
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: toxic by ingestion. Can be toxic by
skin absorption. Affects central nervous system, especially optic
nerve. Marked impairment of vision and enlargement of the liver has
been reported with chronic exp osure.
explanation of carcinogenicity: this material is not listed as a cancer
causing agent.
effects of overexposure: causes dizziness, nausea, muscle weakness,
narcosis, respiratory failure. Ingestion can produce blindness (100
ml can be fatal). Prolonged or repeated skin contact may cause skin
irritation.
medical cond aggravated by exposure: skin conditions, eye problems, or
impaired liver or kidney function.
First aid: get medical assistance for all cases of overexposure.
skin-wash thoroughly with soap and water. Eyes-immediately flush
thoroughly with large amounts of water. Inhalation-remove to fresh
air; give arti ficial respiration if breathing has stopped.
ingestion-get immediate medical attention. If medical attention is
not immediately available, induce vomiting. Do not induce vomiting
if unconscious.
Hcc: f5
boiling pt: b.P. Text: 147f,64c
melt/freeze pt: m.P/f.P text: -144f,-98c
vapor pres: 97 mmhg
vapor density: 1.1
spec gravity: 0.791
evaporation rate & reference: 5.91 (n-butyl acetate=1)
solubility in water: miscible
appearance and odor: colorless liquid, characteristic alcoholic odor.
percent volatiles by volume: 99.9+
Stability indicator/materials to avoid: yes
oxidizers.
stability condition to avoid: heat; contact with ignition sources.
hazardous decomposition products: oxides of carbon, formaldehyde.
conditions to avoid polymerization: does not occur.
Waste disposal methods: to be performed in compliance with all current
local, state and federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
other rec limits: none recommended
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: ld50 oral rat=5628mg/kg rtecs 92-4
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: methanol is a neurotoxic materiel
which causes central nervous sytem depression,damage to the optic
nerve(finally resulting in blindness) and kidney damage.
effects of
overexposure: eyes: irritation.Skin: defatting,irritation.Inhal: headac
he,drowsiness,lassitude,loss of appetite,inability to
concentrate.Ingest: gi irritation,nausea,vomiting,diarrhea,cns
depression.
medical cond aggravated by exposure: persons with diseases affecting the
skin,eyes or respiratory system,liver or kidney may be at increased
risk from exposure.
First aid: eyes: flush with water for 15 minutes,while holding lids
opened.Skin: remove contaminated clothing;wash with soap and
water.Inhal: remove from exposure.Restore breathing if needed.Call
physician.Ingest: d o not induce vomiting.Give 2 glasses ofmilk or
water;call physician or poison control center.
Hcc: f5
boiling pt: b.P. Text: 148f,64.5c
vapor density: 1.11
spec gravity: 0.7924
solubility in water: complete
appearance and odor: colorless liquid, slight alcohol odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizers,active metals,iso-cyanates.
stability condition to avoid: exposure to sparks & flames
hazardous decomposition products: carbon dioxide,carbon monoxide.
Waste disposal methods: keep in covered drums,pending disposal. Handle &
dispose in full compliance with all applicable federal,state &local
regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 100%
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: human ldlo = 6.4 g/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: ingestion or inhalation may produce
headache, weakness, drowsiness, lightheadedness, nausea, vomiting,
drunkeness, irriation of eyes and blurred vision, possible
blindness. Eye irritation can occur if contact eyes. Acts as a
defatting agent on skin, which can result in dermatitis. See supp
data for chronic effects.
explanation of carcinogenicity: this product is not listed by iarc, ntp
or osha as a carcinogen, mutagen, teratogen or neurotoxin.
effects of overexposure: headache, weakness, drowsiness,
lightheadedness, nausea, vomiting, drunkeness, eye irritation,
blurred vision, blindness, skin irritation/defatting, dermatitis,
vertigo, chills unsteady gait, edema of the arms, gastric pain,
insomnia, constricted visual fields, changes in color perception,
double vision, neuritis.
medical cond aggravated by exposure: persons with existing skin, kidney,
liver or eye disorders may be at increased risk when exposed to
methanol. Methanol may also enhance the toxicity of carbon
monoxide.
First aid: inhalation: remove from exposure. Restore breathing. Keep
warm and quiet. Get medical attention. Skin: wash affected area
thoroughly with soap and water. If irritation persists, get medical
attention. Eyes: flush with large amounts of water for 15 minutes.
get medical attention. Ingestion: if conscious, induce vomiting,
then give 2 teaspoons of baking soda in glass of water. Get medical
attention.
Hcc: f5
boiling pt: b.P. Text: 147f,64c
melt/freeze pt: m.P/f.P text: -143f,-97c
decomp temp: decomp text: unknowwn
vapor pres: 96
vapor density: 1.1
spec gravity: 0.791
evaporation rate & reference: not given
solubility in water: miscible
appearance and odor: clear colorless liquid, faint characteristic
alcoholic odor
Stability indicator/materials to avoid: yes
strong oxidizing agents, aluminum, zinc or metals that displace
hydrogen, rubber, chromic anhydride, lead perchlorate
stability condition to avoid: high temperatures, sparks, open flame
hazardous decomposition products: carbon monoxide and toxic vapors such
as formaldehyde
Waste disposal methods: prevent waste from contaminating surrounding
environment. Discard any product, residue, disposal container or
liner in accordance with all federal, state and local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: > 99%
other rec limits: none recommended
osha pel: s,200ppm
acgih tlv: s,200ppm/250stel; 94
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ld50 lc50 mixture: ld50 (oral rat) = 9100 mg/kg
route of entry inds - inhalation: yes
skin: yes
ingestion: no
carcinogenicity inds - ntp: no
iarc: no
osha: no
effects of exposure: acute-compound is an eye & skin irritant. Toxic
effects from short exposures by inhalation, ingestion or skin contact
(absorption) include anesthetic effects, blindness, acidosis. Tests
demonstrate no mutagenic activity.
explanation of carcinogenicity: mfr gave the above listings on the msds but no
other comments about carcinogenicity were recorded.
signs and symptions of overexposure: anesthetic effects, dizziness, headache,
confusion, incoordination, loss of consciousness, blindness, abnormal liver
function, abnormal kidney function, fatality.
medical cond aggravated by exposure: individuals w/preexisting diseases of the
retina or liver may have increased susceptibility to the toxicity of
excessive exposure..
first aid: if any symptom occurs or is severe, get medical attention. Eye: flush
w/water for 15 min. Skin: wash w/soap & water. Remove contaminated
clothing & launder before reuse. Inhaled: remove from contaminated area.
aid or restore breathing as needed. Ingested: as little as 60 ml may be
blinding or fatal. Immediately give 2 glasses water, induce vomiting &
get medical attn. Nothing by mouth if unconscious.
hcc: f2
nrc/state lic no: none
b.P. Text: 147f,64c
m.P/f.P text: -143f,-97c
decomp text: unknown
vapor pres: 127 mm
vapor density: 1.1
spec gravity: 0.791
viscosity: unknown
evaporation rate & reference: >1 (n-buac = 1)
solubility in water: 100%
appearance and odor: liquid, colorless or clear, faint alcoholic
corrosion rate: unknown
product id: 4127 champion air brake anti-freeze
cage: 0pn79
company name: lowe oil co
street: 510 price lane
city: clinton mo
zipcode: 64735-5000
health emergency phone: 816-885-8151
label required ind: y
date of label review: 12/31/1996
status code: c
mfg label no: none
label date: 12/31/1996
origination code: f
eye protection ind: yes
skin protection ind: yes
signal word: danger
respiratory protection ind: yes
health hazard: severe
contact hazard: moderate
fire hazard: severe
=======================================================
responsible party cage: 0pn79
trans id no: 78428
product id: 4127 champion air brake anti-freeze
msds prepared date: 12/31/1994
review date: 12/31/1996
mfn: 1
tech entry nos shipping nm: none
net unit weight: 6.6 lbs
multiple kit number: 0
review ind: y
unit of issue: gl
container qty: 6
type of container: can
additional data: rq is 5000 pounds.
Hazard and precautions: acute-compound is an eye & skin irritant. Toxic
effects from short exposures by inhalation, ingestion or skin contact
(absorption) include anesthetic effects, blindness, acidosis. Tests
demonstrate no mutagenic activity. Store in adequately ventilated area. Keep
away from heat, sparks & flame. Keep containers tightly closed. Do not
store or mix w/strong oxidizers.
spill release procedures: isolate spill area. Take fire & explosion
precautions. Wear protective equipment. Dike large spills. Do not flush to
sewer.
neutralizing agent: mfr gave no information of msds.
waste disposal methods: cleaned up material may be a rcra hazardous waste.
dispose of i/a/w federal, state & local regulations. If approved,
incineration, bio-oxidation, subsurface injection or a licensed disposal
contractor may be used.
handling and storage precautions: store in adequately ventilated area. Keep
away from heat, sparks & flame. Keep containers tightly closed. Do not
store or mix w/strong oxidizers.
other precautions: avoid contact w/eyes, skin or clothing. Avoid prolonged or
repeated breathing of vapor. Wash thoroughly after handling.
Ld50 lc50 mixture: product's ld50 (oral rat) was not stated
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: causes eye and skin irritaion. May
cause anesthetic effects, liver effects, blindness, acidosis. May
cause nausea, weakness, temporary cns depression, loss of
consciousness, blindness, abnormal kidney function, death.
explanation of carcinogenicity: methanol has been reported to cause
birth defects in rats exposed to very high concentrations (20,000
ppm), per msds.
effects of overexposure: irritation, tearing. Burning sensation, drying
skin, defatting, dizziness, nausea, vomiting, drowsiness, headache,
fatigue, convulsions, unconsciousness, death, blindness, swelling
of eyes and redness
medical cond aggravated by exposure: individuals with pre-existing
diseases of the eye, skin, respiratory tract, liver, kidney, cns
may have increased susceptibility to the toxicity of excessive
exposures.
First aid: eye: immediately flush with water for 15 minutes. Hold eyelids
open. See physician. Skin: wash affected area with soap & water. If
irritation persists, see doctor. Inhaled: remove to fresh air.
provide c pr/oxygen if needed. Obtain emergency medical help.
oral: if conscious, immediately induce vomiting by drinking water &
pressing finger down throat. Call a physician/poison control center
immediately.
Hcc: f5
nrc/state lic num: none
boiling pt: =64.4c, 148.F
melt/freeze pt: =-97.8c, -144.F
decomp temp: decomp text: not known
vapor pres: 1.86
vapor density: 1.11
spec gravity: 0.792
ph: 7.2
viscosity: n/p1 cps @ 86f
solubility in water: 100%
appearance and odor: colorless liquid;faintly sweet pungent odor like
ethyl alcohol
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
beryllium dihydride,metals(potassium,magnesium,etc),
oxidants(barium,perchlorate,bromine,chlorine,etc)
stability condition to avoid: heat, flame, sparks, other ignition
sources
hazardous decomposition products: incomplete combustion will generate
carbon monoxide,formaldehyde and possibly unburned methanol
Waste disposal methods: dispose in accordance with all applicable local,
state and federal regulations. Epa hazardous waste number is u154
(toxic waste). Rq for methanol is 5000 lbs. Preferred method is
incineration or biolo gical treatment in an approved facility.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara 313) (cercla)
cas: 67-56-1
rtecs #: pc1400000
minumum % wt: 99.
maxumum % wt: 100.
other rec limits: none recommended
osha pel: s, 200 ppm
acgih tlv: s,200ppm/250stel; 95
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: ld50 (oral rat) is 9100 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: causes eye, skin, nose, and
throat irritation. Harmful if inhalled or absorbed through skin,
causes damage to liver, kidneys, and cns. May be fatal or cause
blindness if swallowed. Cannot be ma de nonpoisonous.
explanation of carcinogenicity: none
effects of overexposure: nausea, weakness, temporary nervous system
depression with anesthetic effects such as dizziness, headache,
confusion, incoordination, and loss of consciousness, or blindness.
higher exposures may lead to abnormal liver, kidney function or
fatality. Ingestion of as little as 60 ml may cause blindness or
fatality.
medical cond aggravated by exposure: individuals with pre-existing
diseases of the retina or liver have increased susceptibility to
the tocity of excessive exposures.
First aid: eyes: flush with large amounts of water. Get medical
attention if irritation persists. Skin: remove contaminated
clothing. Flush skin with large amounts of water. If irritation
persists, get medical a ttention. Inhalation: move to fresh air.
give cpr if not breathing. Give oxygen if needed. Get medical
attention. Ingestion: give two glasses of water and induce
vomiting. Get medical attention
Hcc: f5
boiling pt: b.P. Text: 148f,65c
melt/freeze pt: m.P/f.P text: -144f,-98c
decomp temp: decomp text: not known
vapor pres: 127mm/77f
vapor density: 1.1
spec gravity: 0.791
evaporation rate & reference: >1, (n-butyl acetate=1)
solubility in water: 100%
appearance and odor: clear, colorless liquid, faint alcoholic odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizing agents, chromic anhydride, lead perchlorate, or
perchloric acid (reacts vigorously).
stability condition to avoid: heat, flame, sparks, other ignition
sources.
hazardous decomposition products: carbon monoxide, carbon dioxide and
perhaps formaldehyde
conditions to avoid polymerization: will not occur.
Waste disposal methods: cleaned up material may be rcra hazardous
waste,u154.Dispose in accordance with applicable local,state and
federal regulations.Rq for methanol is 5000 lbs.If
approved,incineration,bio-oxidation,subsur face injection or
licensed contractor may be used.
Ingred name: methyl alcohol (methanol) (sara 313) (cercla)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 100%
other rec limits: s,200ppm,8/12 hr twa
osha pel: s, 200 ppm
acgih tlv: s,200ppm/250stel; 95
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: ld50 (orl rat) is 9100 mg/kg.
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eye, skin, cns,
respiratory & gi tracts. Acute- toxic. Can cause blindness. May
damage nerves & effects cns. May cause irregular heartbeat & coma
by ingestion. Skin absorption may occur. narcotic & neurotoxin by
inhalation. Chronic- may cause dermatitis, liver effects,
blindness, acidosis.
explanation of carcinogenicity: none
effects of overexposure: irritation, tearing. Burning sensation, drying
skin, defatting, dizziness, nausea, vomiting, drowsiness, headache,
fatigue, convulsions, unconsciousness, death, blindness, swelling
of eyes and redness , dermatitis, coma, irregular heatbeat
medical cond aggravated by exposure: individuals with pre-existing
diseases of the eye, skin, respiratory tract, liver, kidney, cns
may have increased susceptibility to the toxicity of excessive
exposures.
First aid: call physician if symptoms persist. Eyes/skin: immediately
flush with water for 15 minutes. Hold eyelids open. Consult
physician. Inhaled: move to fresh air. Provide cpr/oxygen if needed.
oral: if consci ous, drink two glasses of water & inducevomiting.
call a physician/poison control center immediately. Never give
fluid or induce vomiting if patient is unconscious or has
convulsions.
Hcc: f5
nrc/state lic num: not relevent
boiling pt: =64.4c, 148.F
melt/freeze pt: =-97.6c, -144.F
decomp temp: decomp text: not known
vapor pres: 127 @77f
vapor density: 1.11
spec gravity: 0.791
evaporation rate & reference: >1 (n-butyl acetate=1)
solubility in water: 100%
appearance and odor: clear, colorless liquid - faint alcohol odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizing agents, chromic anhydride, lead perchlorate,
perchloric acid
stability condition to avoid: heat, flame, sparks, other ignition
sources, contact with incompatible substances
hazardous decomposition products: carbon monoxide, carbon dioxide
Waste disposal methods: dispose in accordance with applicable local,
state and federal regulations. Epa hazardous waste number is u154
(toxic waste). Rq for methanol is 5000 lbs. Preferred method is
incineration, recycling o r reusing.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara 313) (cercla)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 100%
other rec limits: none recommended
osha pel: s, 200 ppm
acgih tlv: s,200ppm/250stel; 96
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: ingestion of 10ml may cause blindness
routes of entry: inhalation: no skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: ingestion may cause dizziness,
faintness, drowsiness, decreased awareness, blindness, coma, death.
may be absorbed through skin in harmful amounts. Inhalation may
cause respiratory irritation. Skin co ntact may cause
defatting/drying of skin. Eye contact may cause irritation,
blindness. Chronic: eye/liver/kidney damage.
explanation of carcinogenicity: this compound contains no ingredients at
concentrations of 0.1% or greater that are carcinogens or suspect
carcinogens.
effects of overexposure: dizziness, faintness, drowsiness, decreased
awareness or responsiveness, nausea, vomiting, staggering gait,
lack of coordination, blindness, coma, death, skin
drying/defatting, eye irritation, burning sensation in
nose/throat, stinging/watering of eyes, eye redness/tearing.
liver/kidney damage.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: eyes: flush with water for 15 minutes while holding eyelids
open. Get medical attention. Skin: remove contaminated clothing.
wash with soap and water. If irritation persist, get medical
attention. Inh alation: remove to fresh air. Restore breathing. Get
medical attention. Ingestion: if conscious, give 2 glasses of
water. Induce vomiting. Obtain medical attention.
Hcc: f5
boiling pt: b.P. Text: 149f,65c
melt/freeze pt: m.P/f.P text: -144f,-98c
decomp temp: decomp text: not given
vapor pres: 97.25
vapor density: 1.5
spec gravity: .7928
viscosity: not given
evaporation rate & reference: 4.6 (n-butyl acetate=1)
solubility in water: complete
appearance and odor: clear, colorless liquid, characteristic odor
percent volatiles by volume: 100%
Stability indicator/materials to avoid: yes
strong oxidizing agents, strong inorganic acids
stability condition to avoid: high temperatures, sparks, open flames
hazardous decomposition products: carbon monoxide, carbon dioxide
Waste disposal methods: prevent waste from contaminating surrounding
environment. Discard any product, residue, disposal container or
liner in accordance with all federal, state and local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara 313) (cercla)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 100%
other rec limits: none recommended
osha pel: s, 200 ppm
acgih tlv: s,200ppm/250stel; 96
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Health hazards acute and chronic: exposure to lethal concentrations of
methanol has been shown to cause damage to organs, including liver,
kidneys, pancreas, heart, lungs and brain. Although this rarely
occurs, survivors of severe int oxication may suffer from permanent
neurological damage. Eyes: eyes/skin: may cause mild irritation and
dry skin. Breathing: exposure to vapor or mist is possible.
explanation of carcinogenicity: not provided
effects of overexposure: irritation (nose, throat, respiratory tract)
pre-existing lung disorders, e.G. Asthma-like conditions may be
aggravated by exposure. Abdominal and low back pain. Leg cramps.
gastrointestinal irritatio n (nausea, vomiting, disrrhea).
shortness of breath, cns depression (dizziness, weakness, fatigue,
nausea, headache, unconsciousness) blurred vision visual impairment
(including blindness) cyanosis (c haracterized by bluish
discoloration of the skin and nails), coma & death.
medical cond aggravated by exposure: condition sensitive to decrease in
available oxygen such as chronic lung disease, coronary artery
disease, anemias
First aid: skin: remove contaminated clothing, wash exposed area with
soap & water. If symptoms persist, get mediacl help. Launder
clothing before reuse. Eyes: if symptoms develop, move from
exposure & into fres h air, flush eyes gently with water while
holding eyelids apart. If symptoms persist/visual difficulty, get
medical help. Ingested: get medical help. If drowsy or unconscious,
do not give anything by mouth. Place individual on left side with
the head down. If conscious and alert. Induce vomiting if
conscious. Inhalation: move to fresh air. Get medical help. Give
oxygen if breathing difficult. Keep warm/quiet.
Hcc: f5
boiling pt: =63.9c, 147.F
vapor pres: 97.68 mmhg
vapor density: 1.11
spec gravity: .793
evaporation rate & reference: 5.91(nbuac=1)
appearance and odor: clear, apha color 5 max liquid, neat form
percent volatiles by volume: 100.
Stability indicator/materials to avoid: yes
avoid contact with strong oxidizing agents, strong acids, reactive
metals as aluminum and magnesium.
stability condition to avoid: not provided
hazardous decomposition products: may form toxic materials: carbon
dioxide, carbon monoxide, etc.
Waste disposal methods: dispose of in accordance with all local, state
and federal regulations.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
= wt: 100.
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: eye-believed to cause mild
irritation upon short-term exposure. Direct contact with liquid,
conjunctivitis & corneal burns may occur. Methanol's main toxic
effect is on the nervous system, part icularly the optic nerves &
possibly the retina. It can progress to permanent blindness.
skin-absorption through the skin may occur & produce toxic effects
similar to those resulting from inhalation e xposure.
respiratory-overexposure to mist/vapors may cause dizziness,
drowsiness, headache or nausea. Massive overexposure may cause
unconsciousness. Chronic: repeated skin contact may cause a persiste
nt irritation or dermatitis.
explanation of carcinogenicity: this product is not currently listed as
a carcinogen by ntp, osha, or iarc.
effects of overexposure: headache, dizziness, drowsiness, nausea,
unconsiousness, and coma.
First aid: eyes: flush thoroughly with water for at least 15 minutes.
get medical attention. Skin: wash exposed area with soap and water.
remove and clean contaminated clothing. If irritation develops seek
medic al attention. Ingestion: call a doctor immediately. If person
is conscious, immediately give 2 glasses of water and induce
vomiting. Do not make an unconscious person vomit. Never give
anything by mou th to an unconscious or convulsing person.
inhalation: remove to fresh air. If not breathing, give
mouth-to-mouth artificial respiration and seek medical attention.
if breathing is difficult, qualifie d personnel may administer
oxygen.
Hcc: f5
boiling pt: =64.4c, 148.F
vapor pres: 96 mm hg @68f(20c)
vapor density: 1.11@ 60f
spec gravity: 0.796@60f(15.6c)
ph: 7.2
viscosity: no information found
evaporation rate & reference: no information found
solubility in water: infinite
appearance and odor: colorless, characteristic odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizers, strong acids.
stability condition to avoid: heat.
hazardous decomposition products: carbon monoxide and carbon dioxide may
be formed on burning.
conditions to avoid polymerization: does not occur.
Waste disposal methods: incinerate or place in rcra permitted waste
management facility.
Ingred name: methanol
cas: 67-56-1
rtecs #: pc1400000
= wt: 9.99
osha pel: 200 ppm
acgih tlv: 200 ppm
acgih stel: 328 mg/m3;250 ppm
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs