NationalStockNumber.INFO
Worldwide distributor of NSN parts and consumables located in the USA.
Worldwide distributor of NSN parts and consumables located in the USA.
Send us a request for quote using the form below. Our team will contact you with an up to date pricing and availability quote ASAP.
Dichloromethane (methylene chloride)
Saturated chlorinated derivatives of acyclic hydrocarbons, n.E.S.
Chemicals-organic
Y - Indicates information is in the hazardous materials information resource system (hmirs).
PMICA - Item does not contain precious metal.
CRITL- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.
045310 - Methylene chloride etc
635 - Chemicals, other than drugs or sundries
9 - Other or no special handling required (sh)
A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.
C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp
P - Poison, class b, un class 6 (poison label)
T - 55.0
Questions & Answers: |
|
| What are the historical prices recorded for this stock number? | |
| Historical data shows pricing from $4,281.21 to $7,135.36.. | |
| Does NSN 6810-00-616-9188 have a shelf life? | |
| No. There is no shelf life applicable for this NSN. | |
| What NATO entities are users of this NSN? | |
| Department Of The Army, Department Of The Air Force, U.s. Marine Corps, Department Of The Navy, and Greece | |
| What is the NIIN of NSN 6810-00-616-9188? | |
| 006169188 or 00-616-9188 | |
| Does NSN 6810-00-616-9188 require demilitarization? | |
| Yes - ITAR Controlled | |
| What is the most recent solicitation for NSN 6810-00-616-9188? | |
| No solicitations for this NSN. | |
| When was this national stock number assigned to the federal catalog? | |
| Jan 01, 1963 | |
Routes of entry: inhalation: yes skin: yes ingestion: yes
health hazards acute and chronic: acute: irritation of
eyes,skin,respiratory tract; cns
depression,dizziness,nausea,headache,vomiting;carboxyhemoglobin
levels can be elveated in person. Chronic: liver,kidney or lung
disease; or dermatit is.
explanation of carcinogenicity: suspected carcinogen.Osha has not
finalized standard.
effects of overexposure: inh: headache,verigo,drowsiness,narcisis
skin: burning sensation, slight dermatitis,irrit to eyes.
medical cond aggravated by exposure: liver,kidney disease, lung
disease,anemia
First aid: inhalation: remove to fresh air;call a physician. Skin: wash
with soap & water. Eyes: wash thorough with plenty of water; call a
physician if needed. Ingestion: do not induce vomiting;call a
physician imm ediately.
Hcc: t4
boiling pt: b.P. Text: 103f/39.5c
vapor pres: 352
vapor density: 2.9
spec gravity: 1.31
evaporation rate & reference: 0.7 (ether=1)
solubility in water: moderate
appearance and odor: colorless clear liquid;mildly sweet odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong alkalies,oxidizing materials.
stability condition to avoid: contact with open flame, hot surfaces
hazardous decomposition products: hydrogen chloride,phosgene(small
amounts
Waste disposal methods: recovered liquid may be sent to a licensed
reclaimer or incinerated.Contaminated absorbent material. Must
dispose of in a permitted waste msnagement facility. Consult
federal,state or local disposal a uthorities for approved
procedures.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii)
cas: 75-09-2
rtecs #: pa8050000
osha pel: 500 ppm/c,1000; z2
acgih tlv: 50 ppm, a2; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: propylene oxide (sara iii)
cas: 75-56-9
rtecs #: tz2975000
fraction by wt:
osha pel: 100 ppm
acgih tlv: 20 ppm; 9293
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
Effects of overexposure: eye: irrit. Skin: irrit;absorbed thru skin.
inh: irrit, loss of coordination/balance. See sup data
First aid: remove to fresh air;use oxygen respirator for severe cases.
(eye & skin: flush w/ water for 15 minutes, if irritation persists
call md. Ingest: call md, give water or milk and induce vomiting.
advise ma not to use adrenalin-ge msds ref).
Hcc: t4
nrc/state lic num: grade a. Flamma
boiling pt: b.P. Text: 104f,40c
vapor pres: 350
vapor density: 2.93
spec gravity: 1.326
evaporation rate & reference: 14.5 (buac=1)
solubility in water: insoluble
appearance and odor: clear liquid, aromatic odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
alkali metals,finely powdered aluminum & magnesium (ge ref)
stability condition to avoid: exposure to high temps (open flame,
welding arcs,etc)ge ref.
hazardous decomposition products: hydrogen chloride,phosgene at high
temps (ge msds ref)
Waste disposal methods: mfr recommends burying absorbent in
landfill.Waste solvent may be reclaimed by filtration &
distillation procedures or dispose via licensed waste solvent
disposal company (ge msds ref). Disposal metho s must be iaw fed,
state & local codes.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 100%
osha pel: 500 ppm/c,1000; z2
acgih tlv: 50 ppm, a2; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: yes
health hazards acute and chronic: acute: irritation of eyes,skin and
respiratory tract,cns
effects,dizziness,weakness,fatigue,nausea,headache,g. I. Tract
disturbances,nausea,vomiting,diarrhea. Chronic: increase co level in
blood causing cardiovascular stress,cns effects.
explanation of carcinogenicity: methylene chloride is suspected
carcinogen by iarc or acgih;liver abnormalities,lung damage (among
lab animals).
effects of overexposure: eye,skn: irrt,inhl: irrt,dizz,weak,fatigue,
naus,head,unconsc.Ingest: also gi irrt,naus,vomit,diarr.
medical cond aggravated by exposure: pre-existing conditions may be
worsen.
First aid: inhal: rmv to fresh air. If not brthng give cpr; if brthng
diff give oxygen. Eye: immed flush w/plenty of water. Skin: wash
w/soap & water. Rmv contam clthg & shoes. Ingest: do not induce
vomit. Nothg by mouth if unconsc. Get medical attn.
Hcc: t4
boiling pt: b.P. Text: 104f,40c
vapor pres: 355 mmhg
vapor density: 2.9
spec gravity: 1.322
evaporation rate & reference: 1.8 (ethyl ether=1)
solubility in water: slight
appearance and odor: clear, colorless liquid. Ether-like odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
aluminum, strong alkalais
hazardous decomposition products: carbon monoxide,carbon
dioxide,hydrogen chloride,phosgene
Waste disposal methods: place absorbed material in containers suitable
for shipment to disposal areas.Environmental laws take
precedence.Liquid wastes may be destroyed by liquid incineration
with off gas scrubber
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: no ingredient for this formulation_ingredient
Ld50 lc50 mixture: oral ld50 (rat) is 2524 mg/kg
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: yes iarc: yes osha: no
health hazards acute and chronic: acute: inhalation may cause
respiratory irritation, liver injury, blood disorders, and central
nervous system effects (cns). Contact may cause skin and eye
irritation. Ingestion may cause gi tract irr itation and cns
effects. Chronic: prolonged or repeated exposure may cause
dermatitis, central nervous system effects.
explanation of carcinogenicity: methylene chloride (dichloromethane) is
listed as an anticipated carcinogen by ntp & a (2b) probable
carcinogen by iarc.
effects of overexposure: inhaled: mental confusion, light-headedness,
nausea, vomiting, headache, shortness of breath. Eyes: redness,
pain, inflammation. Skin: burns, redness, pain. Ingested:
light-headedness, dizzizness, nau sea, vomiting, headache.
medical cond aggravated by exposure: pre-existing skin, respiratory,
liver, kidney disorders may be aggravated by exposure.
First aid: inhaled: remove to fresh air. Give artificial respiration if
breathing stopped; give oxygen if breathing difficult. See doctor.
eyes: flush with lots of water for 15 minutes. See doctor. Skin:
remove contaminated clothes. Wash with soap and water. Ingested:
if conscious, give water and induce vomiting. Get immediate medical
attention.
Hcc: t4
boiling pt: b.P. Text: 104f,40c
melt/freeze pt: m.P/f.P text: -142f,-97c
vapor pres: 350 mm hg
vapor density: 2.9(air=1)
spec gravity: 1.3 (water=1)
evaporation rate & reference: 27.5 (n-butyl acetate=1)
solubility in water: moderate
appearance and odor: clear, colorless liquid; chloroform-like odor.
Stability indicator/materials to avoid: yes
strong oxidizer, strong caustics and chemically active metals.
stability condition to avoid: open flames and electrical arcs . Contact
with incompatible materials.
hazardous decomposition products: phosgene gas and hydrochloric acid
mist
Waste disposal methods: collected spills may be atomized in a
rcra-approved combustion chamber or shipped to rcra approved
facility for disposal; ensure compliance with local, state &
federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: >99%
other rec limits: none specified
osha pel: 500 ppm/c,1000; z2
acgih tlv: 50 ppm, a2; 9293
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Effects of overexposure: irrit of eyes/resp tract. Hdache, dizz, stupor,
nausea, vomit, anemia, skin burns.
First aid: eyes: irrigate w/flowing water immed & continuously 15 min,
see md. Skin: wash w/flowing water. Wash clothing before reuse.
inh: remove to fresh air if effects occur. Call md & transport to
emergency facility.
Hcc: t4
boiling pt: b.P. Text: 104f
vapor pres: 340
vapor density: 2.93
spec gravity: 1.320
solubility in water: 2gms/100gms
appearance and odor: colorless liq
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
aluminum, poss sodium, potassium & magnesium
hazardous decomposition products: open flames & welding arcs can cause
hcl, sm amts phosg, cl
Waste disposal methods: send solvent to recalimer. In some cases, sm
amts may be transported to area where it can be placed on ground &
allowed to evaporate safely if local, state, fed reg permit.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 100%
osha pel: 500 ppm/c,1000; z2
acgih tlv: 50 ppm, a2; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Routes of entry: inhalation: yes skin: yes ingestion: yes
health hazards acute and chronic: acute: irritant,cns
depressant;headache,dizziness,nausea,vomiting.
chronic: dermatitis,anemia,cns effects.
explanation of carcinogenicity: suspected carcinogen;the matter still
under debate,osha has not finalized.
effects of overexposure: headache,mental
confusion,depression,fatague,loss of
appetite,nausea,vomiting,cough,diarrhea,death.
medical cond aggravated by exposure: pre-existing conditions may be
worsen.
First aid: remove from contaminated area.Call a doctor immed. Wash
contaminated areas of skin well with water.Remove contaminated
clothing.
Hcc: t4
boiling pt: b.P. Text: 104f/39.8c
vapor pres: 352
vapor density: 2.93
spec gravity: 1.32.
evaporation rate & reference:
solubility in water: moderate
appearance and odor: colorless liquid,ether like odor
percent volatiles by volume: 100.
Stability indicator/materials to avoid: yes
aluminum,titanium,pure oxygen & alkali metals
stability condition to avoid: open flames,electrical arc.
hazardous decomposition products: hydrogen chloride,phoshenr,&other
toxic products (small qtys
Waste disposal methods: waste disposal of methylene chloride depends
upon local conditions. Be sure all fed.,state and local regulations
regarding health & pollution are followed.Methylene chloride is
normally recovered from residues by distillation.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 100%
osha pel: 500 ppm/c,1000; z2
acgih tlv: 50 ppm, a2; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: rat: lc50 88000mg/cum/30m;ld50 2136mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: yes iarc: yes osha: yes
health hazards acute and chronic: product is irritating to
eyes,skin,mucous membranes. It is toxic if inhaled,ingested or
absorbed through skin.
explanation of carcinogenicity: agencies are arguing carcinogenity. Best
to take precautions.
effects of overexposure: eye: burning,irritation.
skin: irritation,drying,cracking.Absorption similar to inhalation.
inhalation: drowsiness,dizziness,central nervous system depression.
ingested: central nervous system depression. g/i irritation plus
aspiration hazard.
medical cond aggravated by exposure: persons with pre-existing skin
disorders,respiratory,liver or kidney problems.
First aid: eye: flush eyes with water. If irritation persists,get medical
attention. Skin: remove contaminated clothing. Wash with soap &
water. Inhaled: remove from exposure. Give cpr or oxygen if needed.
give med ical attention. Ingested: get immediate medical attention.
if conscious & alert,induce vomiting.
Hcc: t4
boiling pt: b.P. Text: 104f/40c
vapor pres: 390mm@20c
vapor density: 2.9
spec gravity: 1.320
evaporation rate & reference: 14.50 buac
solubility in water: negligible
appearance and odor: clear colorless or nearly colorless liquid,
characteristic odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong alkalies
stability condition to avoid: none stated
hazardous decomposition products: thermal decomposition may yield
co,co2,phosgene,and/or hcl
Waste disposal methods: dispose i/a/w federal,state,local regulations.
do not flush to sewer or waterway. Beware of rq = 1000 lb or 1.75
drum.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 100%
other rec limits: 50 ppm
osha pel: 500 ppm/c,1000; z2
acgih tlv: 50 ppm, a2; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Effects of overexposure: light headedness,mental
confustion,nausea,headache.Tingling or creeping skin feeling on
inhalation.
First aid: remove to fresh air,if unconscious,use artificial respiration
& call a physician,keep warm & comfortable. For eye contact.Wash
with water for 15 min. In case of skin contact, wash with soap &
water
Hcc: t4
boiling pt: b.P. Text: 104f
vapor pres: 350
vapor density: 2.93
spec gravity: 1.326
evaporation rate & reference: 1.8
solubility in water: moderate
appearance and odor: clear,colorless liquid with pleasant,aromatic odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
aluminum,potassium,sodium
stability condition to avoid: excessive heat,autoignition temperature
1180-1220f
hazardous decomposition products: phosgene gas
conditions to avoid polymerization: high temperature
Waste disposal methods: residue may be poured on sand,earth or ashes at
a safe distance from occupied areas & allowed to evaporate into the
atmosphere,accordly in consultation with local,state & federal
authorities.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 100%
osha pel: 500 ppm/c,1000; z2
acgih tlv: 50 ppm, a2; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: ld50 (oral rat) = 1500-2500 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: yes iarc: yes osha: no
health hazards acute and chronic: may cause cns effects,
carboxyhemoglobinemis, liver & kidney effects. Eye: irritation,
pain, slight corneal injury. Prolonged &/or repeated skin
contact: irritation, burns, drying, cracking. Inhalation: cns
effects, anesthesia, cardiac arrythmias. Ingestion: if aspirated is
absorbed rapidly by lungs.
explanation of carcinogenicity: contains dichloromethane (methylene
chloride). See individual iarc & ntp reports for details of
carcinogenicity.
effects of overexposure: eye: irritation, pain. Skin: irritation, burns,
drying, flaking. Inhalation: respiratory irritation, anesthetic
effects, dizziness, headache, drunkenness, cardiac arrythmias,
unconsciousness, death. Inge stion: single dose toxicity is low. If
aspirated, is rapidly absorbed by lungs.
medical cond aggravated by exposure: mfr gave no information of msds.
First aid: if any irritation persists or severe, get medical attention.
eye: flush w/water for 15 min. Skin: wash w/flowing water.
inhaled: remove from contaminated area. Aid or restore breathing as
needed. Ingeste d: do not induce vomiting. Call physician or
transport to emergency facility immediately. Physician to determine
advisability of vomiting or lavage.
Hcc: t4
nrc/state lic num: none
boiling pt: b.P. Text: 104f,40c
vapor pres: 355 mm
vapor density: 2.93
spec gravity: 1.320
solubility in water: 2.0 gm/100 gm
appearance and odor: colorless liquid, penetrating ether-like odor,
irritating at high concentration
Stability indicator/materials to avoid: yes
amines, aluminum, sodium, potassium, magnesium
stability condition to avoid: hydrolysis, open flames, welding arcs,
other high temperatures.
hazardous decomposition products: hcl, phosgene, chlorine
conditions to avoid polymerization: will not occur.
Waste disposal methods: sent to licensed reclaimers or to permitted
incinerators. Any disposal practice must be i/a/w federal, state &
local regulations. Do not dump into sewers, on ground or into any
body of water.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 99.9%
osha pel: 500 ppm/c,1000; z2
acgih tlv: 50 ppm, a2; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: ld50 oral rat=2136 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: inhalation & ingestion are harmful &
may be fatal. Overexposure to this product can produce elevated
carhoxyhemoglobin levels in the blood. Contact with skin ort in
temporary corneal damage. Chronic e ff: kidney,liver,lung,blood
explanation of carcinogenicity: methylene chloride is listed as possible
carcinogenic to human by iarc.
effects of overexposure: inhale: headache,nausea,vomiting,narcosis,
weakness,fatique,dizziness,irritation of respiratory tract,numbness
of extrenities,central nervous system depression,purvous system
depression, gastrointestin al irritation, & unconscious
medical cond aggravated by exposure: ness.
First aid: inhale: remove to fresh air, if not breathing, give artificial
respiration. If breathing is difficult, give oxygen; in case of
contact, flush eyes or skin with plenty of water for at least 15
minutes w hing before reuse; ingest: do not induce vomiting, see a
physician.
Hcc: t4
boiling pt: b.P. Text: 104f/40c
melt/freeze pt: m.P/f.P text: -139f/-95c
vapor pres: 350
vapor density: 2.9
spec gravity: 1.32
evaporation rate & reference: 27.5 (bu ac =1)
solubility in water: moderate(1-10 %)
appearance and odor: clear,colorless liquid. Penetrating ether-like
odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
alkali metals,strong oxidizing agents,strong bases, oxides of
nitrogen,zinc,aluminum,water,magnesium,amines,rubber,etc.
stability condition to avoid: heat, flame, other sources of ignition,
moisture, light.
hazardous decomposition products: hydrogen
chloride,phosgene,chlorine,carbon monoxide, carbon dioxide.
Waste disposal methods: disposal.Dispose of in accordance with all
applicable federal, state and local environmental regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: >98%
osha pel: 500 ppm/c,1000; z2
acgih tlv: 50 ppm, a2; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: oral ld50 (rat) = 2000-4000 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: yes iarc: yes osha: no
health hazards acute and chronic: acute-eye: irritant,causing pain &
inflammation.Skin: prolonged contact may cause irritation &
dermatitis.Inhalation: may cause cns
depression,vomiting,unconsciousness & death.Ingestion: may cause
vomitin g,cns depression.Aspiration causes chemical
pneumonia.Chronic-dermatitis,headache,mental
confusion,depression,vomiting.
explanation of carcinogenicity: listed as a suspected carcinogen by iarc
(2b) and ntp (ac).
effects of overexposure: irritation of eyes causing pain & inflammation.
prolonged skin contact may cause irritation & dermatitis.
inhalation may cause cns depression, vomiting, unconsciousness &
death. Ingestion may cause gi tract irritation, vomiting, cns
depression and unconsciousness. Aspiration causes chemical
pneumonia.
medical cond aggravated by exposure: persons with angina or heart
disease should not be exposed to this product.
First aid: call a physician in all cases.Inhalation: remove to fresh
air.Give cpr/oxygen if needed.Eye: flush with water for 15
minutes,holding eyelids apart.Skin: wash with soap & water.A
soothing ointment may be applied.Ingestion: if conscious,drink
several glasses of water & induce vomiting.
Hcc: t4
boiling pt: b.P. Text: 104f,40c
melt/freeze pt: m.P/f.P text: -142f,-97c
vapor pres: 420 @ 25c
vapor density: 2.93
spec gravity: 1.32
evaporation rate & reference: 0.62 (n-butyl acetate=1)
solubility in water: 1.3 %
appearance and odor: clear, colorless liquid with ether-like odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
alkali metals and pure oxygen
stability condition to avoid: high heat, open flames and electrical arcs
hazardous decomposition products: when involved in fire, methylene
chloride emits highly toxic and irritating hydrogen chloride and
phosgene fumes.
Waste disposal methods: package,store,transport and dispose of all waste
material and any contaminated equipment in accordance with all
applicable local, state and federal regulations. Shipments of waste
materials are subjec t to manifesting requirements per applicalbe
laws.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 100%
other rec limits: none specified
osha pel: 500 ppm/c,1000; z2
acgih tlv: 50 ppm, a2; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: proprietary mixture (proprietary stabilizers with propylene
oxide)
fraction by wt:
other rec limits: none specified
osha pel: 100 ppm 8hr twa(mfr)
acgih tlv: 20 ppm 8hr twa(mfr)
Ld50 lc50 mixture: oral ld50 (rat) = 3000 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: yes iarc: yes osha: no
health hazards acute and chronic: acute: may cause eye and skin
irritation. Inhalation may cause respiratory tract irritation and
narcosis. Central nervous system depressant. Loss of consciousness
and even death can occur at high leve ls of exposure. Chronic:
central nervous system depressant, dermatitis, liver damage.
explanation of carcinogenicity: listed as a suspected carcinogen by iarc
and ntp.
effects of overexposure: eye and skin irritation, headache, dizziness,
drowsiness, nausea, tingling or numbness of the extremities, sense
of fullness in the head, sense of warmth, stupor or dullness,
lethargy and drunkeness. very high concentrations may lead to
unconsciousness or even death in confined or poorly ventilated
areas.
medical cond aggravated by exposure: methylene chloride is metabolized
by the body to carbon monoxide. This can be sufficient to produce a
substantial stress on the cardiovascular system by elevated levels
of carbonyhemoglobin.
First aid: inhalation: remove to fresh air. If not breathing, give cpr.
if breathing is difficult, give oxygen. Call a physician. Eye:
flush immediately with large amounts of water for 15 minutes. Get
medical at tention. Skin: remove contaminated clothing. Wash with
soap and water promptly. Ingestion: do not induce vomiting. Give
milk or water to drink only if conscious. Get immediate medical
attention.
Hcc: t4
boiling pt: b.P. Text: 104f,40c
melt/freeze pt: m.P/f.P text: -143f fz pt
vapor pres: 420
vapor density: 2.93
spec gravity: 1.32
evaporation rate & reference: 14.5 (butyl acetate = 1)
solubility in water: 1.3%
appearance and odor: clear, colorless liquid with an ether-like odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizers, caustics, active metals such as al, mg powders, k and
na. Pure oxygen, concentrated nitric acid.
stability condition to avoid: high heat, open flames and other sources
of ignition
hazardous decomposition products: when involved in fire, methylene
chloride emits highly toxic and irritating hydrogen chloride and
phosgene fumes.
Waste disposal methods: contaminated sawdust, vermiculite or porous
surface must be disposed of in a permitted hazardous waste
management facility. Recovered liquids may be reprocessed or
incinerated or must be treated in a permitted hazardous waste
management facility.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 100%
other rec limits: none specified
osha pel: 500 ppm/c,1000; z2
acgih tlv: 50 ppm, a2; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: oral ld50 (rat) = 167 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: acute: may cause eye & skin
irritation. Inhalation may cause respiratory tract irritation and
narcosis. Central nervous system depressant. Loss of consciousness
and even death can occur at high levels of exposure. Chronic:
prolonged or repeated contact with liquid on the skin can cause
irritation and dermatitis.
explanation of carcinogenicity: listed as a potential carcinogen by
iarc. Not believed to pose a measurable risk to man when handled as
recommended.
effects of overexposure: headache, dizziness, drowsiness, nausea,
tingling or numbness of the extremities, senses of fullness in the
head, sense of warmth, stupor or dullness, lethargy and
drunkenness. Inhalation of high conc entrations may lead to
unconsciousness,reduced ability of the blood to transport oxygen,
cardiac arrhythmias and death.
medical cond aggravated by exposure: methylene chloride is metabolized
to carbon monoxide. This may be sufficient to produce a substantial
stress on the cardiovascular system. Persons with liver or kidney
disorders are at increased risk.
First aid: eyes: flush with running water for 15 minutes while holding
eyelid. Get medical attention immediately. Skin: wash with water.
remove contaminated clothing. Get medical attention. Inhalation:
remove to fresh air. Give mouth-to-mouth resuscitation if not
breathing. Give oxygen if breathing is difficult. Get medical
attention. Ingestion: do not induce vomiting. Get medical attention
immediately.
Hcc: t4
boiling pt: b.P. Text: 104f,40c
melt/freeze pt: m.P/f.P text: -139f,-95c
vapor pres: 355
vapor density: 2.93
spec gravity: 1.320
evaporation rate & reference: 14.5 (n-butyl acetate=1)
solubility in water: moderate
appearance and odor: clear, colorless liquid. Chloroform-like odor.
note: a gas above 104f.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
water, amines, and aluminum. Possibly sodium, potassium and magnesium.
stability condition to avoid: hydrolysis produces small amounts of
hydrochloric acid. Avoid open flames, welding arcs, or other high
temperatures.
hazardous decomposition products: when involved in fire, methylene
chloride emits highly toxic and irritating hydrogen chloride and
phosgene fumes.
Waste disposal methods: contaminated sawdust, vermiculite or porous
surface must be disposed of in a permitted hazardous waste
management facility. Recovered liquids may be reprocessed or
incinerated or must be treated in a permitted hazardous waste
management facility.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 99.9%
other rec limits: none specified
osha pel: 500 ppm/c,1000; z2
acgih tlv: 50 ppm, a2; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: yes iarc: yes osha: no
health hazards acute and chronic: inhalation: metnhylene chloride
depresses the central nervous system. Skin: prolonged or repeated
contact may cause irritation, defatting of skin & dermatitis. Eyes:
vapors may irritate eyes.
explanation of carcinogenicity: methylene chloride is listed on the iarc
& ntp carcinogen list but not by osha.
effects of overexposure: inhalation: nausea, headache, vomiting,
numbness and tingling in arms and legs and rapid heartbeat, loss of
consciousness and death have occured.
medical cond aggravated by exposure: alcoholism, acute and chronic
liver, chronic lung disease, anemia, coronary disease or rhytm
disorders of the heart.
First aid: inhalation: remove to fresh air. If breathing has stopped,
administer artificial respiration. Call a physician. Skin: remove
contaminated clothing. Wash exposed area with large amounts of
water for 15 min. Eyes: flush eyes immediately with water for 15
min. If irritation persists, call physician. Ingestion: do not
induce vomiting. Contact physician or emergency medical facility
immediately.
Hcc: t4
boiling pt: b.P. Text: 104f,40c
vapor pres: 350
vapor density: 2.9
spec gravity: 1.32
evaporation rate & reference: 0.7 (ether=1)
solubility in water: 1.32 gm/100 gm
appearance and odor: colorless clear liquid; mildly sweet odor.
percent volatiles by volume: 100%
Stability indicator/materials to avoid: yes
strong alkalies, oxygen, nitrogen peroxide, sodium, potassium, & other
oxidizers & reactive metals.
stability condition to avoid: contact with open flame, electric arcs, or
other hot surfaces which can cause thermal decomposition.
hazardous decomposition products: hydrogen chloride,phosgene, chloride.
conditions to avoid polymerization: will not occur.
Waste disposal methods: recovered liquid may be sent to a licensed
reclaimer or incinerated. Contaminated material must be disposed of
in a permitted waste msnagement facility. Consult federal, state or
local disposal author ities for approved procedures.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 100%
other rec limits: none recommended
osha pel: 500 ppm/c,1000; z2
acgih tlv: 50 ppm, a2; 9293
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: tlv: 50 ppm
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eyes-can cause irritation. Skin-can
cause irritation. Breathing-excessive inhalation of vapors can
cause nasal and respiratory irritation. Swallowing-can cause
gastrointestinal irritation.
explanation of carcinogenicity: methylene chloride has been listed as a
possible carcinogen by iarc and ntp.
effects of overexposure: breathing-can cause central nervous effects
including dizziness, weakness, fatigue, nausea, headache and
possible unconsciousness, and even death. Swallowing-can cause
nausea, vomiting, and diarrhea.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: skin-wash exposed area with soap & water. Remove contaminated
clothing. Eyes-flush with large amounts of water. Get medical
attention. Swallowed-do not induce vomiting. Immediately drink 2
glasses of water. Call physician. Breathed-remove individual to
fresh air. If bresthing is hard, give oxygen. If breathing has
stopped, give artficial respiration. Do not give stimulants.
Hcc: t4
boiling pt: b.P. Text: 102-104f
vapor pres: 355 mmhg
vapor density: 2.9
spec gravity: 1.318-1.322
evaporation rate & reference: 1.8 (ethyl ether=1)
appearance and odor: clear, colorless liquid. Ether-like odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
avoid contact with aluminum.
stability condition to avoid: none specified by manufacturer.
hazardous decomposition products: none specified by manufacturer.
Waste disposal methods: destroy by liquid incineration with off-gas
scrubber. Contaminated absorbent may be deposited in a landfill in
accordance with local, state and federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara iii)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 100.0%
other rec limits: none determined
osha pel: 500 ppm/c,1000; z2
acgih tlv: 50 ppm, a2; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
METHYLENE CHLORIDE INDUSTRIAL GRADE
Ld50 lc50 mixture: ld50 (oral, rat) is unknown.
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: yes iarc: yes osha: no
health hazards acute and chronic: target organs: lungs, eyes, skin, liver
& kidneys. Acute- eye: causes irritation. Skin: causes irritation.
prolonged/repeated skin contact may result in drying & absorption.
inhale: may cause irritation, cns depression in high
concentrations. Oral: low toxicity. Aspiration hazard. Chronic- may
cause liver & kidney damage.
explanation of carcinogenicity: methylene chloride is listed as a
potential human carcinogen by ntp, iarc and acgih.
effects of overexposure: irritation, nausea, vomiting, headache,
dizziness, skin defatting and burns, elevated carboxyhemoglobin
levels in blood, tearing and swelling, drowsiness, fatigue
medical cond aggravated by exposure: persons with pre-existing skin
disorders or eye problems or impaired cns, liver, kidney,
cardiovascular or respiratory function may be more susceptible to
the effects of the substance.
First aid: call physician if symptoms persist. Inhaled: remove to fresh
air. Provide cpr/oxygen if needed. Eyes/skin: flush with water for
15 minutes. Hold eyelids open. Oral: do not induce vomiting. If
person is d rowsy/unconscious, place on left side with head down.
get medical attention. If possible, do not leave individual
unattended. Note to physician: symptomatic drugs may initiate
cardiac arrhy
Hcc: t4
nrc/state lic num: not relevant
viscosity: not relevant
Hazardous decomposition products: hydrogen chloride, carbon monoxide,
carbon dioxide, phosgene and chlorine
conditions to avoid polymerization: water contamination
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara 313) (cercla)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 100%
other rec limits: none recommended
osha pel: 500 ppm; z-2
acgih tlv: 50 ppm, a2; 9495
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: ld50 (oral, rat) is 1500-2500 mg/kg.
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: yes iarc: yes osha: no
health hazards acute and chronic: target organs: lung, eye, skin, liver,
kidney. Acute- eye: causes irritation. Skin: irritation, defatting.
prolonged skin contact may result in burns & absorption. Inhale: may
cause cns depression. Narcot ic in high concentrations.
oral: harmfulif ingested. Chronic- long term overexposure may cause
liver & kidney damage.
explanation of carcinogenicity: methylene chloride is listed as a
potential human carcinogen by ntp, iarc and acgih.
effects of overexposure: irritation, nausea, vomiting, headache,
dizziness, skin defatting and burns, elevated carboxyhemoglobin
levels, weakness
medical cond aggravated by exposure: persons with pre-existing skin
disorders or eye problems or impaired liver, kidney, cardiovascular
or respiratory function may be more susceptible to the effects of
the substance.
First aid: get medical attention if symptoms persist.
eyes/skin: immediately flush with water for at least 15 minutes.
hold eyelids open. Wash skin with soap & water. Inhaled: remove to
fresh air. Provide cpr/oxyg en if necessary. Oral: do not induce
vomiting. Call physician. Never give anything by mouth to an
unconscious person.
Hcc: t4
nrc/state lic num: not relevant
boiling pt: b.P. Text: 104f,40c
melt/freeze pt: m.P/f.P text: -142f,-97c
vapor pres: 355 @ 68f
vapor density: 2.93
spec gravity: 1.320
viscosity: not relevant
solubility in water: 2 % @ 25c/77f
appearance and odor: colorless liquid - irritating odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizing agents, chemically active metals (aluminum, magnesium,
potassium powders), amines, strong bases
stability condition to avoid: sunlight, uv light, open flames,
electrical arcs, excessive heat
hazardous decomposition products: hydrogen chloride, carbon monoxide,
carbon dioxide, phosgene and chlorine may be formed.
Waste disposal methods: discharge, treatment or disposal may be subject
to federal, state or local regulations. Can be incinerated.
contract with a licensed chemical disposal agency. Since emptied
containers retain product r esidue, follow label warnings.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methylene chloride (sara 313) (cercla)
cas: 75-09-2
rtecs #: pa8050000
fraction by wt: 99.5%
other rec limits: none recommended
osha pel: 500 ppm; z-2
acgih tlv: 50 ppm, a2; 9495
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: propylene oxide (sara 302/313) (cercla)
cas: 75-56-9
rtecs #: tz2975000
fraction by wt: 0.5%
other rec limits: none recommended
osha pel: 100 ppm
acgih tlv: 20 ppm; 9495
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
Ld50 lc50 mixture: ld50(oral,rat): 1600 mg/kg/lc50: 52 gm/m3
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: yes iarc: yes osha: no
health hazards acute and chronic: target organs: cns, liver, heart.
acute- can cause eye irritation, damage. Prolonged skin contact
causes burns. May be absorbed through skin. Inhalation causes
narcotic, cns & cardiovascular system eff ects. Ingestion may cause
cns depression, vomiting. Aspiration hazard. Chronic- liver,
kidney, cns effects, dermatitis.
explanation of carcinogenicity: methylene chloride is listed as a
potential human carcinogen by ntp, iarc and acgih.
effects of overexposure: irritation, nausea, vomiting, headache,
dizziness, skin defatting, dermatitis, pain, burns
medical cond aggravated by exposure: persons with pre-existing skin
disorders or eye problems or impaired liver, kidney, cardiovascular
or respiratory function may be more susceptible to the effects of
the substance.
First aid: get medical help if symptoms persist. Inhaled: move to fresh
air. Provide cpr/oxygen if needed. Eyes: immediately flush with
water for 15 minutes. Hold eyelids open. Skin: wash with soap &
water. Oral: do not induce vomiting. If conscious, drink plenty of
water. Seek immediate medical attention. If vomiting occurs, keep
head below hips. Do not give anything by mouth to an unconscious
person.
Hcc: t4
nrc/state lic num: not relevant
boiling pt: =40.C, 104.2f
melt/freeze pt: =-97.C, -142.6f
vapor pres: 400 @ 75f
vapor density: 2.9
spec gravity: 1.33
evaporation rate & reference: 27.5 (butyl acetate=1)
solubility in water: 1.32% @ 68f/20c
appearance and odor: clear, liquid - chloroform like odor
Stability indicator/materials to avoid: yes
strong oxidizers, strong caustics, plastic, rubber, nitric acid,water
and heat.Chemically active metal: aluminum and manganesium
powder,sodium,lithium and potassium.Liquid methylene chloride will
attack some forms of plastic
stability condition to avoid: moisture, heat, open flames, ignition
sources, electrical arcs, and incompatible materials.
hazardous decomposition products: hydrochloric acid, carbon monoxide,
carbon dioxide, phosgene may be formed.
Waste disposal methods: discharge, treatment or disposal is subject to
federal, state or local regulations. Can be incinerated. Contract
with a licensed chemical disposal agency. Since emptied containers
retain product resid ue, follow label warnings.
Ingred name: methylene chloride (sara 313) (cercla)
cas: 75-09-2
rtecs #: pa8050000
minumum % wt: 99.
maxumum % wt: 100.
other rec limits: none recommended
osha pel: 25 ppm
acgih tlv: 50 ppm, a2; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: ld50 (oral, rat) 1,600 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: yes iarc: yes osha: yes
health hazards acute and chronic: target organs: eyes, skin, cns, cvs
(hmis). Acute - inhalation: the major potential route of exposure.
high concentrations of vapor/mist can cause cns depression with
symptoms of headache, dizziness, stupor, loss of consciousness or
death depending on concentration and duration of exposure. Can
cause irregular heartbeat, cardiac arrest. Causes adverse effects
on lungs, liver, kidney, nervous syste m. Carboxyhemoglobin levels
become elevated which may contribute to stress on cardiovascular
system. Smoking increases the effect. Eyes/skin: causes irritation.
can be absorbed through skin. Chronic - toxic effects on liver and
kidney.
explanation of carcinogenicity: possible cancer hazard.
effects of overexposure: headache, dizziness, stupor, loss of
consciousness, death, irregular heartbeat, irritation, cardiac
sensitization and increased risk of cardiac arrest
medical cond aggravated by exposure: alcoholism, acute and chronic liver
and kidney disease, chronic lung disease, anemia, coronary disease
or rhythm disorders of the heart.
First aid: inhalation: remove to fresh air. If breathing has stopped,
administer artificial respiration. Contact physician or emergency
medical facility immediately. Skin: remove contaminated clothing
and shoes. Wash exposed area thoroughly with soap and water for at
least 15 minutes. Wash contaminated clothing before reuse. Eye:
immediately flush eyes with large amount of water for at least 15
minutes while frequently lifting the upper and lower eyelids. If
irritation persists, call a physician. Ingestion: do not induce
vomiting. Contact physician or emergency medical facility
immediately. Never give an ything by mouth to unconscious person.
Hcc: t4
nrc/state lic num: not relevant
boiling pt: =40.1c, 104.2f
vapor pres: 350 @ 20c/68f
vapor density: 2.9
spec gravity: 1.32
evaporation rate & reference: 0.7 (ether=1)
solubility in water: 1.32 gm/100 ml @ 25c
appearance and odor: colorlless, clear liquid, mildly sweet odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong alkalies, oxygen, nitrogen peroxide, sodium, potassium, and
other oxidizers and reactive metals.
stability condition to avoid: avoid contact with open flame, electric
arcs, or other hot surfaces which can cause thermal decomposition.
hazardous decomposition products: hydrogen chloride, phosgene, chlorine.
conditions to avoid polymerization: will not occur.
Waste disposal methods: all disposals of this material must be done in
accordance with local, state, and federal regulations. Waste
characterization and compliance with disposal regualtions are the
responsibilities of the wa ste generator. Recovered liquids from
spill residues may be sent to an epa permitted reclaimer or in
cineration facility.
Ingred name: dichloromethane
cas: 75-09-2
rtecs #: pa8050000
= wt: 100.
other rec limits: none recommended
osha pel: 25 ppm
osha stel: 125 ppm
acgih tlv: 174 mg/m3;50 ppm
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: ld50 (oral, rat) 1600 mg/kg
reports of carcinogenicity: ntp: yes iarc: yes osha: yes
health hazards acute and chronic: skin: can cause drying, irritation,
dermatitis. And chemical burns. This product may be absorbed
through the skin. Eyes: may cause irritation, experienced as
stinging and discomfort or pain. Corneal i njury may occur.
ingestion: may cause abdominal pain, nausea, diarrhea, vomiting,
cns depression. Aspiration into lungs can cause chemical
pneumonitis. May cause blood disorders. Inhalation: may resul t in
respiratory irritation, dizziness, headache, nausea, drunkenness,
fatigue, unconsciousness, death. Carbonyhemoglobinemia can cause
stress on the cardiovascular system. May cross placenta and can be
excreted in breast milk.
explanation of carcinogenicity: methylene chloride
effects of overexposure: skin: can cause drying, irritation, dermatitis.
and chemical burns. Eyes: may cause irritation, experienced as
stinging and discomfort or pain. Ingestion: may cause abdominal
pain, nausea, diarrhea, v omiting, cns depression. Inhalation: may
result in respiratory irritation, dizziness, headache, nausea,
drunkenness, fatigue, unconsciousness, death.
medical cond aggravated by exposure: medical conditions aggravated
include blood system disorders, cardiovascular disorders, kidney
disorders, liver disorders, skin disorders and allergies.
First aid: skin: remove contaminated clothing and shoes. Wash exposed
areas with soap and water. Get medical attention. Eye: flush eyes
with water for at least 15 minutes. Get medical attention.
ingestion: call a physician immediately! Do not induce vomiting!
give 2-3 (16 oz) glasses of water. Do not give anything by mouth to
an unconscious person. Inhalation: remove to fresh air. If
breathing has stopped gi ve artificial respiration. If breathing is
difficult, give oxygen. Get medical attention.
Hcc: t4
nrc/state lic num: not relevant
boiling pt: =40.C, 104.F
melt/freeze pt: =96.7c, 206.F
decomp temp: decomp text: not provided
vapor pres: 350 mmhg @ 20 c
vapor density: 2.9
spec gravity: 1.32 @ 25 c
viscosity: not provided
evaporation rate & reference: 0.7 (butyl acetate=1)
solubility in water: 2 g/100 g @ 25 c
appearance and odor: clear and colorless liquid, sweet odor.
percent volatiles by volume: 100
corrosion rate: not provided
Stability indicator/materials to avoid: yes
combustible material, bases, metals, oxidizing materials, alkalies,
amines, oxygen.
stability condition to avoid: keep away from heat, sparks, and open
flames.
hazardous decomposition products: halogenated compounds, oxides of
carbon, hydrogen chloride, phosgene,. Chlorine.
Waste disposal methods: discharge, treatment, or disposal may be subject
to federal, state, or local laws. State and local regulations and
restrictions are complex and may differ from federal disposal
regulations.
Ingred name: methylene chloride
cas: 75-09-2
rtecs #: pa8050000
= wt: 100.
other rec limits: not provided
osha pel: see table z-2
acgih tlv: 174 mg/m3;50 ppm
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: 1500-2500 mg/kg
reports of carcinogenicity: ntp: yes iarc: yes
health hazards acute and chronic: eye; may cause pain. May cause
moderate eye irritation which may be slow to heal. May cause slight
corneal injury. Vapors may irritate eyes. Skin: prolonged or
repeated exposure may cause skin irritat ion, even a burn. Repeated
contact may cause drying or flaking of skin. Ingestion: small
amounts swallowed incidental to normal handling operations are not
likely to cause injury. If aspirated may be readily absorbed 7
result in injury to bosy systems. Inhalation: unconsiousness,
death, irritation of uppper respiratory tract, anesthetic/narcotic
effects, cardiac arrhythmias.
explanation of carcinogenicity: this chemical is listed as a potential
carcinogen by iarc and ntp. Methylene chloride has been shown to
increase the incidence of malignant tumors in mice. Methylene
chloride is not believed to pose a measurable carcinogenic risk to
man when handled as recommended.
effects of overexposure: excessive exposure may cause central nervous
system effects, carboxyhemoglobinemia, thereby impairing the
blood's ability to transport oxygen. Observations in animals
include liver and kidney effects.
medical cond aggravated by exposure: no data provided by manufacturer
First aid: eye: irrigate with flowing water immediately and continuously
for 15 minutes. Consult medical personnel. Skin wash off in flowing
water or shower. Ingestion: do not induce vomiting. Call a
physician a nd/or transport to emergency facility immediately.
inhalation: remove to fresh air. If not breathing, give artificial
respiration. If breathing is difficult, oxygen should be
administered by qualified personnel. Call a physician or transport
to a medical facility.
Hcc: t4
vapor pres: 355 mmhg@ 20c
vapor density: 2.93
spec gravity: 1.320@25/25c
solubility in water: 2.0g/100g @ 25c
appearance and odor: colorless liquid. Odor: irritating odor
Stability indicator/materials to avoid: yes
avoid contact with metals such as: aluminum powders, magnesium powders,
potassium, sodium, and zinc powder. Avoid unintended contact with
amines. Avoid contact with strong bases and strong oxidizers.
stability condition to avoid: avoid direct sunlight or ultraviolet
sources. Avoid open flames, welding arcs, or other high temperature
sources which induce thermal decomposition.
hazardous decomposition products: hazardous decomposition products may
include and area not limited to hydrogen chloride and trace amounts
of chlorine and phosgene
conditions to avoid polymerization: will not occur
Waste disposal methods: do not dump into any sewers, on the ground, or
into any body of water. All disposal methods must be in compliance
with all federal, state/provincial and local laws and regulations.
regulations may va ry in different locations. Waste
characterizations and compliance with applicable laws are the respo
nsibility soley of the waste generator.
Ingred name: methylene chloride
cas: 75-09-2
rtecs #: pa8050000
= wt: 99.9
osha pel: see table z-2
acgih tlv: 174 mg/m3;50 ppm
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs