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Methylchloroform (1, 1, 1-trichloroethane)
Saturated chlorinated derivatives of acyclic hydrocarbons, n.E.S.
Chemicals-organic
Y - Indicates information is in the hazardous materials information resource system (hmirs).
PMICA - Item does not contain precious metal.
CRITL- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.
045615 - Poisonous/toxic matls, group a
635 - Chemicals, other than drugs or sundries
9 - Other or no special handling required (sh)
A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.
C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp
V - Miscellaneous hazardous materials, un class 9 (no label)
W - Rating variable
Questions & Answers: |
|
| What are the historical prices recorded for this stock number? | |
| Historical data shows pricing from $259.08 to $431.80.. | |
| Does NSN 6810-00-664-0387 have a shelf life? | |
| No. There is no shelf life applicable for this NSN. | |
| What NATO entities are users of this NSN? | |
| Defense Threat Reduction Agency, National Aeronautics and Space Administration, Bulgaria, Brazil, Spain, Singapore, Malaysia, Canada, New Zealand, Germany, Republic Of Korea, Portugal, Italy, Denmark, Greece, Turkey, and Nato Maintenance and Supply Agency | |
| What is the NIIN of NSN 6810-00-664-0387? | |
| 006640387 or 00-664-0387 | |
| Does NSN 6810-00-664-0387 require demilitarization? | |
| Yes - ITAR Controlled | |
| What is the most recent solicitation for NSN 6810-00-664-0387? | |
| No solicitations for this NSN. | |
| When was this national stock number assigned to the federal catalog? | |
| Jan 01, 1963 | |
Effects of overexposure: loss of coordination & equilibrium to actual
unconsciousness & even death in unventilated areas.
First aid: move to fresh air, use artificial respiration if breathing
has stopped. Administer oxygen after breathing has been restored.
(never administer adrenalin). Call physician.
Hcc: t4
boiling pt: b.P. Text: 165f
vapor pres: 120
vapor density: 4.5
spec gravity: 1.31
evaporation rate & reference: 0.35 (ether=1)
solubility in water: negligible
appearance and odor: colorless liquid, ethereal odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
Waste disposal methods: forced ventilation or evaporation.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroethane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 100%
other rec limits: none recommended
osha pel: 350 ppm
acgih tlv: 350 ppm/450stel;9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
Effects of overexposure: skin,eye irritant,cardiac irritability
First aid: skin,eye contact: flush with plenty of water.Inhalation: remove
to fresh air.Administer oxygen.Avoid sympatomimetic amines such as
epinephrine which may precipitate arrhythmias.Ingestion: induce
vomiting . Call doctor immediatly
Hcc: t4
boiling pt: b.P. Text: 86.3f 30f
vapor pres: 100
vapor density: 4.55
spec gravity: 1.321
solubility in water: negligible
appearance and odor: colorless liquid
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
water
stability condition to avoid: open flame welding areas.Other high temp.
hazardous decomposition products: hydrogen chloride,phosgene and
chlorine
Waste disposal methods: send solvent to reclaimer. In some cases it can
be transported to an area where it can be placed on the ground and
allowed to evaporate safely.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: solvents
fraction by wt: 94.5%
ingred name: additives
fraction by wt: 3.5%
Effects of overexposure: brief exposures: dizz,mild skin & eye irrit.
(excessive exposure).Hdch,drow, (see supp data)
First aid: eyes: flush w/ water for 15 min. Inhal: remove to fresh air.
if breath stops give artificial respiration. Ingest: induce vomit.
(aspiration is a hazard-ge msds-ref) consult md if any symptoms
persist. (skin: wash w/ warm h*2o & soap,see md-ge msds re
Hcc: t4
boiling pt: b.P. Text: 165f,74c
melt/freeze pt: m.P/f.P text:
vapor pres: 100
vapor density: 4.6
spec gravity: 1.321
evaporation rate & reference: 6(n-butyl acetate=1)
solubility in water: negligible
appearance and odor: water clear, ethereal odor.
Stability indicator/materials to avoid: yes
water-long term cont can deplete stabilziers followed by slow
hydrolysis prdcg corr acid. Avoid prlngd cont w/(supdat)
stability condition to avoid: open flames, welding arcs/other high temp
sources which induce thermal decomposition.
hazardous decomposition products: hcl, phosgene,dichloroacetylene
chlorine (ge msds ref) co*2
Waste disposal methods: mfr recommends to dispose as a solid waste.
disposal method must be iaw federal, state and local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 100%
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
Routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute or chronic overexposure - can
cause vomiting, nausea, drowsiness, unconsciousness and in extreme
cases, death.
explanation of carcinogenicity: contains diethylene ether(1,4-dioxane).
1,4- dioxane is listed by ntp and iarc as an animal carcinogen
11,4-d.
effects of overexposure: acute or chronic overexposure can cause
vomiting, nausea, drowsiness, unconsciousness and in extreme cases,
death.
medical cond aggravated by exposure: pre-existing skin disorders may be
more susceptible to this material.
First aid: get medical attention in all cases. Skin: wash with soap and
water. Inhalation: remove to fresh air & provide oxygen/ cpr if
necessary. Eye: immediately flush with water for 15 minutes while
holding e yelids open. Ingestion: do not induce vomiting. Call a
physician.
Hcc: t4
boiling pt: b.P. Text: 162f,72c
melt/freeze pt: m.P/f.P text: 36.0f,2.2c
vapor pres: 100
vapor density: 4.6
spec gravity: 1.3
evaporation rate & reference: 0.4 ?
solubility in water: moderate
appearance and odor: colorless, clear liquid - mildly sweet odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
none known.
stability condition to avoid: open flames, hot surfaces or welding
emissions
hazardous decomposition products: hydrogen chloride, phosgene and other
highly toxic substances.
Waste disposal methods: disposed of in accordance with all applicable
local, state and federal laws and regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroethane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 90 - 95%
other rec limits: none recommended
osha pel: 350 ppm
acgih tlv: 350 ppm/450stel;9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhale: dizziness,drowsiness,thrt
irritation. Skin: irritation,defatting,dermatitisabsorption of liq
thru intact skin is poss.Eyes: slight temp irritation,slight temp
corneal injury.Vapors can irritate e yes.Ingest: if vomiting
occurs,can be aspirated into lungs, causing chemical pneumonia and
systemic effects.
effects of overexposure: blood pressure depression,unconsciousness,
cardiac sensitization,ventricular arrhythmia,chronic kidney/liver
damage,death.
medical cond aggravated by exposure: acute and chronic liver diseases
and rhythm disorders of the heart.
First aid: inhale: remove victim to fresh air and if needed, immediately
begin cpr.Give oxygen if breathing is labored.Get emergency medical
help.Ingest: do not induce vomiting,get immediate medical
attention.Eyes : flush eyes with water for 15 min. Get medical
advice.Skin: wash skin with water and soap.Get medical attention if
symptoms develop and persist.
Hcc: t4
boiling pt: b.P. Text: 165 f.
vapor pres: 100mm@20c
vapor density: (air=1)4.6
spec gravity: 1.32 @ 25/25 c
evaporation rate & reference: (ether=1),0.4
solubility in water: 0.07 gm @ 25 c.
appearance and odor: clear, colorless liquid with mildly sweet odor.
Stability indicator/materials to avoid: yes
strong alkalies,oxidizers,,and reactive metals(i.E.
aluminum,potassium,sodium,magnesium, etc).
hazardous decomposition products: from fire: smoke,carbon dioxide,carbon
monoxide,hydrogen chloride,phosgene, and chlorine.
Waste disposal methods: epa approved hazardous waste disposal
site.Follow applicable local,state, and federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: diethylene ether
cas: 123-91-1
osha pel: s, 100 ppm
acgih tlv: s, 25 ppm; 9293
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: blood press depress,cardiac
sensitization/ventricular arrhythmia can result from the expos to
near anesthetic levels.Secondary butanol as pure substance has
caused severe corneal injury in rabbits/is absorbed readily from
the gastrointestinal tract & can cause central nerve system
depress.Liver toxic effects in animals
explanation of carcinogenicity: 1,1,1trichloroethane,glycol methylene
ether,secondary butylene oxide are not listed on osha,iarc,or ntp
carcinogen list
effects of overexposure: inhaled: dizziness,drowsiness,& throat irrit at
levels above 1,000ppm.Unconsciousness & death possible above
10,000ppm.Skin: irrit,defatting of skin & dermatitis.Absorption is
poss if contact is prolong ed.Eyes: irrit w/slight temp corneal
injury.Ingestion: can be aspirated into lungs causing chem
pneumonia/systemic effects
medical cond aggravated by exposure: acute and chronic liver disease and
rhythm disorders of the heart.
First aid: inhaled: remove to fresh air.If breathing stopped,give art
rsprtn.Call doctor.Skin: remove contamin clothing/shoes.Wash area
w/soap/water.Wash contamin clothes before reuse.Eyes: flush w/water
for 15 min utes.If irrit persists,call doctor.Ingested: do not
induce vomit.Contact doctor/emerg med facility immed.Note to
physician: adrenalin should never be given to persons overexpos to
1,1,1,trichloroethane.
Hcc: t4
boiling pt: b.P. Text: 165f,74c
vapor pres: 100 mm hg
vapor density: 4.6
spec gravity: 1.30 @ 25/c
evaporation rate & reference: 0.4 (ether=1)
solubility in water: 0.07 gm/100 gm @ 25c
appearance and odor: clear, colorless liquid, mildly sweet odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong alkalies, oxidizers, aluminum and other reactive metals.
stability condition to avoid: avoid contact with open flame, electric
arcs, or other hot surfaces which can cause thermal decomposition.
hazardous decomposition products: hydrogen chloride, phosgene, chlorine.
Waste disposal methods: recovered liquids may be sent to a licensed
reclaimer or incineration facility. Contaminated material must be
disposed of in a permitted waste management facility. Consult
federal, state or local disp osal authorities for approved
procedures.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: > 95%
other rec limits: odor threshold100ppm
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: glycol methylene ether
cas: 646-06-0
rtecs #: jh6760000
fraction by wt: < 3%
other rec limits: none specified
ingred name: sec-butyl alcohol (sara iii)
cas: 78-92-2
rtecs #: eo1750000
fraction by wt: < 2%
other rec limits: none specified
osha pel: 150 ppm
acgih tlv: 100 ppm; 9293
ingred name: 1,2-butylene oxide (sara iii)
cas: 106-88-7
rtecs #: ek3675000
fraction by wt: < 5%
other rec limits: none specified
epa rpt qty: 1 lb
dot rpt qty: 1 lb
Routes of entry: inhalation: yes skin: no ingestion: yes
health hazards acute and chronic: overexposure if accompanied by anoxia
may temporarily increase cardiac irritability. Avoid administering
adrenalin, epimephriline which may precipitate arhythmias. Based on
available data, repeated ex posure not likely to cause significant
adverse effects. Birth defects are unlikely.
effects of overexposure: eyes: may cause pain, slight irritations with
temporary corneal injury. Skin: prolonged or repeated exposure may
cause skin irritation. May cause drying or flaking. Not likely to
result in absorption of harmful amounts. Inhalation: can cause
anesthetic effect, dizziness, unconsciousness & death at high
concentrations.
First aid: eyes: irrigate immediately with water at least 5 minutes.
skin: wash off in flowing water. Ingestion: do not induce vomiting.
call doctor. Inhalation: remove to fresh air. Administer oxygen or
mouth-to-mo uth resuscitation if not breathing.
Hcc: t4
boiling pt: b.P. Text: 165f,74c
vapor pres: 100 @ 20c
vapor density: 4.55
spec gravity: 1.321 @ 25/25c
solubility in water: 0.07 g/100 g @ 25c
appearance and odor: colorless liquid. Irritating odor at high
concentrations.
Stability indicator/materials to avoid: yes
prolonged contact w/aluminum & related alloys(zinc powder)this can
cause hydrochloric acid gas to form & rupture *
stability condition to avoid: high temperature sources. Avoid open
flame. Welding arcs & other sources which induce thermal
decomposition.
hazardous decomposition products: hydrogen chloride & possible traces of
phosgene. *container. Also contact w/caustic soda or other
oxidizing materials
Waste disposal methods: preferred options are to send to licensed
reclaimer or to permitted incinerators. Disposal must be in
compliance with federal, state & local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 100%
other rec limits: 450 ppm stel
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eye and skin irritation.
explanation of carcinogenicity: none of the chemicals in this product is
listed by iarc, ntp or osha as a carcinogen.
effects of overexposure: eyes-irritation. Skin-irritation if prolonged
contact. Inhalation-anesthetic effect at 500-1000 ppm.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: eyes-flush with water. Skin-flush with water.
ingestion-induce vomiting. No antidote known. Inhalation-remove to
fresh air, give artificial respiration if breathing stops. Keep
warm & quiet. Get medic help for all of the above. See
supplemental data.
Hcc: t4
boiling pt: b.P. Text: 165f (74c)
vapor pres: 100
vapor density: 4.55
spec gravity: 1.321
solubility in water: 0.07g/100g
appearance and odor: colorless liquid
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
water-slow hydrolysis produces corrosive acid
stability condition to avoid: open flames,welding arcs.High temp cause
decomposition
hazardous decomposition products: hydrogen chloride, small amounts
phosgene & chlorine
Waste disposal methods: place absorbed material in container suitable
for shipment to disposal area.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroethane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 94.5%
other rec limits: none recommended
osha pel: 350 ppm
acgih tlv: 350 ppm/450stel;9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
Ld50 lc50 mixture: ld50 rats-10,000 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: yes iarc: yes osha: yes
health hazards acute and chronic: eye: liq may cause pain/slight
temporary irrit w/slight corneal injury. Vapors may irrit. Skin:
prolong/repeat expos may cause irrit/drying/flaking. Inhal: inhal
of conc of 500-1000 ppm may produce mi nimal anesthetic/narcotic
effects. Concof 1000 ppm may cause dizziness/drunkenness. Conc of
10,000 ppm can cause
explanation of carcinogenicity: 1.4 dioxane is listed by ntp as an
animal carcinogen.
effects of overexposure: unconsciousness/death/blood press depress/
cardiac sensititzation/ventricular arrhythmias. In confined/poorly
vent areas, vapors can cause unconsciousness/death. Aerosol form is
more toxic than vapor. ingest: single dose oral toxicity is low.
aspir of matl into lungs rapidly absorbed can cause chem
pneumonitis-fatal.
First aid: skin: wash w/soap & wtr. Rmv contam cloth/ launder before
reuse. Discard shoes. Eye: flush w/lg amts wtr, lift lids- get med
aid. Ingest: do not induce vomiting. Immed drink 2 glasses wtr.
never give anything by mouth to unconscious person. Call dr/take
to emergency room. Inhal: move to fresh air. If breath
difficult-admin oxygen, if stopped-artif resp. Keep warm/quiet-get
med aid. Do not give+
Hcc: t4
boiling pt: b.P. Text: 162f,79c
melt/freeze pt: m.P/f.P text: 36.0f,2.2c
vapor pres: 100 mm/hg
spec gravity: 1.3
viscosity: (water=1) .86
evaporation rate & reference: ethyl ether =1 / 2.60
solubility in water: moderate
appearance and odor: colorless, clear liquid, mildly sweet odor
percent volatiles by volume: 100
corrosion rate: not corr
Stability indicator/materials to avoid: yes
water/reactive metals (aluminum/magnesium)/open flame/ welding
arcs/resistance heaters, etc which can result in thermal
stability condition to avoid: n/k by high energy spark/flame, etc vapors
are heavier than air/will collect in low areas.
hazardous decomposition products: liquid oxygen or other strong oxidants
may form explosive mixtures with 1,1,1-trichloroethane.
Waste disposal methods: dispose of in accord w/all local/state/federal
government. Humans: cardiac/liver abnormalities/kidney damage.
+stimulants. Epinephrine or ephedrine may adversely affect the
heart with fatal results.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: 1,1,1-trichloroethane (sara 313)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: >95%
other rec limits: none specified
osha pel: 350 ppm
acgih tlv: 350 ppm
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: contains a proprietary inhibitor pkg-includes diethylene
ether (1.4 dioxane) cas 123-91-1, at a level of 2.5% (sara 313)
rtecs #: 9999999zz
other rec limits: none specified
Ld50 lc50 mixture: oral ld50 (rat) = 10300 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: eyes- severe irritation,
redness, tearing, blurred vision. Skin- moderate irritation,
defatting, dermatitis. Inhale- nasal and respiratory irritation,
cns effects including dizziness, weakness, fatigue. Ingest-
nausea, vomiting,diarrhea. Chronic: cardiac, liver, kidney
abnormalities.
explanation of carcinogenicity: not listed as a carcinogen by ntp, iarc
or osha
effects of overexposure: incoordination and impaired judgment may occur
at vapor exposures from 500-1000 ppm. Dizziness, drowsiness, and
general anestethic effects may occur in ranges of 1000 ppm and
higher.
medical cond aggravated by exposure: increased sensitivity to adrenalin
may be caused by over exposure.
First aid: inhalation: remove to fresh air. If not breathing, give cpr.
if breathing is difficult, give oxygen. Call a physician. Eye:
flush immediately with large amounts of water for 15 minutes. Get
medical at tention. Skin: remove contaminated clothing. Wash with
soap and water promptly. Ingestion: do not induce vomiting. Give
milk or usp mineral oil. Get immediate medical attention.
Hcc: t4
nrc/state lic num: none
boiling pt: b.P. Text: 162f,72c
vapor pres: 100
vapor density: 4.5
spec gravity: 1.3
evaporation rate & reference: 2.6 (ethyl ether=1)
solubility in water: 0.07g/100g
appearance and odor: clear, apha color 15 max, liquid, homogeous
solution
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
water, reactive metals such as aluminum and magnesium.
stability condition to avoid: high temperatures, sparks, and open flames
hazardous decomposition products: when involved in fire,
1,1,1-trichloroethane emits highly toxic and irritating hydrogen
chloride and phosgene fumes.
Waste disposal methods: disopse of i/a/w federal, state & local
regulations
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 100%
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
Ld50 lc50 mixture: inhale: lc50, rat-14250 ppm/7 hr; *
health hazards acute and chronic: acute: irritate; skin/eyes. Excessive
inhale/ingest; produce cns depressions-lightheaded/death.
ventricular fibrillation. Vomiting/aspiration into lungs-chemical
pneumonia. High doses have produced mi ld liver effects in animal.
chronic: headache/depression/fatigue/loss of
appetite/nausea/vomiting.
explanation of carcinogenicity: this product is not considered to be
carcinogenic to humans or animals.
effects of overexposure: irritation/redness to skin/eyes.
coughing/headache/dizziness/nausea.
medical cond aggravated by exposure: cuts, abrasions, dermatitis,
respiratory or heart ailments
First aid: eye: flush w/water 15 min. See a physician immediately. Skin:
remove contaminated clothing. Wash skin w/mild soap/water. Consult
physician if irritation develops or persists. Inhale: move to fresh
air . Administer oxygen/artificial respiration if needed. Call a
physician immediately. Ingest: do not induce vomiting. Call a
physician immediately.
Hcc: t4
boiling pt: b.P. Text: 165f,74c
vapor pres: 100 @ 68f
vapor density: 4.55@60.9f
spec gravity: 1.320 @ 75f
evaporation rate & reference: .4 (ether=1)
solubility in water: insoluble
appearance and odor: clear water-white liquid, ether-like odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizers, metal such as sodium and potassium.
hazardous decomposition products: carbon monoxide, hydrochloric acid,
phosgene during combustion.
Waste disposal methods: in accordance with local, state and federal epa
regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (sara 313)
cas: 71-55-6
rtecs #: kj2975000
other rec limits: none specified
osha pel: 350 ppm
acgih tlv: 350 ppm
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: 1,4 dioxane (sara 313)
cas: 123-91-1
rtecs #: jg8225000
other rec limits: none specified
osha pel: s, 100 ppm
acgih tlv: s, 25 ppm; 9293
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
Ld50 lc50 mixture: ld50 oral, rat: >10,000 mg/kg;
routes of entry: inhalation: yes skin: yes ingestion: yes
health hazards acute and chronic: eye: pain. Slight transient irritation
with slight transient corneal injury. Irritation. Skin: prolonged
or repeated contact may cause irritation, drying, flaking.
ingestion: aspirated product may res ult in injury to other body
systems. Inhal: high concentrations (10000): unconsciousness,
death. Cardiac arthythmias.
explanation of carcinogenicity: in long term animal studies, did not
cause cancer
effects of overexposure: n/k ld50 dermal rabbit: 15,000 mg/kg.
First aid: eye: irrigate immed w/wtr at least 5 min. Skin: wash in flow
wtr/shower.Ingest: don't induce vomit.Call dr/take to emerg rm
immed.Inhal: remv to frsh air.If no breath,mouth-mouth resusctn.If
breath diffic lt,oxygen.Call dr.Note to dr: rapid absorptn may occur
thru lungs(aspirtd).Induce vomit at dr's instruct.If
lavage,endotracheal/ esophogeal control.No sympathomiatic drugs-w/o
absolute need.No antidote
Hcc: t4
boiling pt: b.P. Text: 165f,74c
vapor pres: 100 @ 20c
vapor density: 4.55
spec gravity: 1.821 @ 25c
solubility in water: 0.07 g/100 g @ 25c
appearance and odor: colorless liquid, irritating odor at high
concentrations
Prolonged contact w/free water. Aluminum, zinc powdered, reactive
metals &hydroxides (sodium, lithium, beryllim).Avoid
stability condition to avoid: avoid open flames, welding arcs or other
high temperature sources which induce thermal decomposition.
hazardous decomposition products: hydrogen chloride and very small
amounts of phosgene and chlorine.
Waste disposal methods: preferred options: send to licensed reclaimer,or
to permitted incinerator.Disposal of product & containers must be
in compliance w/fed,state,& local laws & regs. Don't dump into
sewers,on ground,or int o any body of water.Don't cut/weld on
containers.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: 1,1,1-trichloroethane (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 96.5%
other rec limits: none recommended
osha pel: 350 ppm
acgih tlv: 350 ppm;stel 450 ppm
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: diethylene ether (1,4-dioxane) (sara iii)
cas: 123-91-1
rtecs #: jg8225000
fraction by wt: 2.5%
other rec limits: none recommended
osha pel: 25 ppm (skin)
acgih tlv: 25 ppm (skin)
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
ingred name: 1,2-butylene oxide
cas: 106-88-7
rtecs #: ek3675000
fraction by wt: 0.47%
other rec limits: none recommended
osha pel: stel 2 ppm
epa rpt qty: 1 lb
dot rpt qty: 1 lb
ingred name: nitromethane
cas: 75-52-5
rtecs #: pa9800000
fraction by wt: 0.34%
other rec limits: none recommended
osha pel: 100 ppm
acgih tlv: 100 ppm
Ld50 lc50 mixture: oral ld50 (rat) = 10300 mg/kg
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: contact may cause eye & skin
irritation. Inhalation may cause respiratory tract irritation,
central nervous system (cns) depression. Ingestion may cause cns
depression, gi tract irritation, asp iration. Chronic: prolonged or
repeatedexposure may cause skin irritation or dermatitis;liver &
nervous system damage.
explanation of carcinogenicity: not listed as a carcinogen by ntp, iarc
or osha
effects of overexposure: inhaled: headache, drowsiness, dizziness, loss
of coordination, and fatigue, coughing, shortness of breath. Eyes:
redness, tearing, blurred vision, stinging. Skin: redness, burning,
drying, and cracki ng. Ingested: nausea, vomiting,
diarrhea,dizziness, headache, drowsiness, loss of coordination,
fatigue.
medical cond aggravated by exposure: re-existing skin disorders, lung
disorders.
First aid: inhalation: remove to fresh air. If not breathing, give
respiration. If breathing is difficult, give oxygen. Call a
physician. Eye: flush immediately with lots of water for 15
minutes. Get medical att ention. Skin: remove contaminated
clothing. Wash with soap and water promptly. Ingestion: do not
induce vomiting. If vomiting occurs, keep head below knees. Get
immediate medical attention.
Hcc: t4
boiling pt: b.P. Text: >160f,>71c
vapor pres: 134 mm hg
vapor density: 4.6(air=1)
spec gravity: 1.29 (water=1)
evaporation rate & reference: 6.0 (n-butyl acetate=1)
solubility in water: negligible
appearance and odor: clear liquid; characteristic odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong mineral acids, strong alkalis, strong oxidizing agents, selected
amines, reactive metals.
stability condition to avoid: avoid high pressure in aluminum systems.
hazardous decomposition products: phosgene, hydrogen chloride, carbon
monoxide and carbon dioxide
Waste disposal methods: dispose of in accordance with local, state and
federal regulations. Epa reportable quantity (rq)=1000 pounds. If
spill greater than epa rq; call national response center at
800-424-8802.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 100%
other rec limits: none recommended
osha pel: 350 ppm
acgih tlv: 350 ppm/450stel;9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
Ld50 lc50 mixture: oral ld50 (rat) = 10300 mg/kg
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: contact may cause eye & skin
irritation. Inhalation may cause respiratory tract irritation,
central nervous system (cns) depression. Ingestion may cause cns
depression, gi tract irritation, asp iration. Chronic: prolonged or
repeatedexposure may cause skin irritation or dermatitis;liver &
nervous system damage.
explanation of carcinogenicity: not listed as a carcinogen by ntp, iarc
or osha
effects of overexposure: inhaled: headache, drowsiness, dizziness, loss
of coordination, and fatigue, coughing, shortness of breath. Eyes:
redness, tearing, blurred vision, stinging. Skin: redness, burning,
drying, and cracki ng. Ingested: nausea, vomiting,
diarrhea,dizziness, headache, drowsiness, loss of coordination,
fatigue.
medical cond aggravated by exposure: pre-existing skin disorders, lung
disorders.
First aid: inhalation: remove to fresh air. If not breathing, give
respiration. If breathing is difficult, give oxygen. Call a
physician. Eye: flush immediately with lots of water for 15
minutes. Get medical att ention. Skin: remove contaminated
clothing. Wash with soap and water promptly. Ingestion: do not
induce vomiting. If vomiting occurs, keep head below knees. Get
immediate medical attention.
Hcc: t4
boiling pt: b.P. Text: >160f,>71c
vapor pres: 134 mm hg
vapor density: 4.6
spec gravity: 1.29
evaporation rate & reference: 6.0 (n-butyl acetate=1)
solubility in water: negligible
appearance and odor: clear liquid; characteristic odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong mineral acids, strong alkalis, strong oxidizing agents, selected
amines, reactive metals.
stability condition to avoid: avoid high pressure in aluminum systems.
hazardous decomposition products: phosgene, hydrogen chloride, carbon
monoxide and carbon dioxide
Waste disposal methods: dispose of in accordance with local, state and
federal regulations. Epa reportable quantity (rq)=1000 pounds. If
spill greater than epa rq; call national response center at
800-424-8802.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 94-98%
other rec limits: none recommended
osha pel: 350 ppm
acgih tlv: 350 ppm/450stel;9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: 1,4-dioxane (diethylene dioxide) (sara iii)
cas: 123-91-1
rtecs #: jg8225000
fraction by wt: 1-4%
other rec limits: none recommended
osha pel: s, 100 ppm
acgih tlv: s, 25 ppm; 9394
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eyes: mild
irrit.Skin: irrit.Prolong/repeat expo may dry skin.Inhal: expo to
vap/mist is possible.Short-term inhal toxicity is moderate.Expo may
be harmful.Ingest: single dose oral toxicity is low.Ingest sm amts
during normal handling not likely to cause harmful effects;ingest
lg amts may be harmful.Aspiration can occur.
explanation of carcinogenicity: per msds: this material is not listed as
a carcinogen by iarc/ntp/osha.
effects of
overexposure: eye: stinging,tearing,redness.Skin: redness,burning,dryi
ng,cracking,skin burn/damage.Inhal: gi
irrit(nau,vomit,diarr),mouth/throat irrit,cns
depres(dizz,drow,weak,ftg,nau,head,unconsc),low blood pressure
,reversible behavioral changes,impairedcoordination,irreg
heartbeat,resp failure,death.Ingest: gi irrit,cns depres.
medical cond aggravated by exposure: pre-existing skin & liver disorders
may be aggravated by exposure to this matl.Individuals
w/pre-existing heart disorders may be more susceptible to
arrhythmias(irreg heartbeat)if expo to hi concen.
First aid: skin: remove contamin cloth.Flush w/lg amts of water.Get immed
med attn if damag/symp persist.Eyes: move to fresh air.Flush gently
w/water holding eyelids open.Symp persist/visual diff get med
attn.Inge st: do not induce vomit-aspiration haz.If drowsy/unconsc
place on left side w/head down.Get med attn.If possi do not leave
alone.Inhal: move to fresh air.Get med attn immed.(see supplemental)
Hcc: t4
boiling pt: b.P. Text: 161f,72c
vapor pres: 100 @68f
vapor density: 4.55
spec gravity: 1.300-1.320 @77
evaporation rate & reference: 2.60 (ethyl ether=1)
appearance and odor: clear & colorless liquid, homog soln
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizing agents,amines,strong alkalies,reactive metals(al,mg).
stability condition to avoid: gross contamin w/water can cause
hydrolysis producing sm amts of hydrochloric acid.Open flame/weld
arc/resist heater/etc
hazardous decomposition products: toxic matl: carbon dioxide,carbon
monoxide,hydrogen chloride,phosgene,chlorine,various hydrocarbons,
etc.
Waste disposal methods: dispose of in accordance with all applicalble
local, state and federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: >95%
other rec limits: none recommended
osha pel: 350 ppm
acgih tlv: 350 ppm/450stel;9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: inhibitor package, proprietary, which includes ingreds 3 &
4.
other rec limits: none recommended
ingred name: 1,3-dioxolane
cas: 646-06-0
rtecs #: jh6760000
fraction by wt:
other rec limits: none recommended
ingred name: sec-butyl alcohol (sara iii)
cas: 78-92-2
rtecs #: eo1750000
fraction by wt:
other rec limits: none recommended
osha pel: 150 ppm
acgih tlv: 100 ppm; 9394
Hcc: t4
viscosity: 0.86 cp@ 20c
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara 313)
(cercla)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: >95.0%
other rec limits: niosh stel 350 ppm
osha pel: 350 ppm/stel 450
acgih tlv: 350 ppm/stel 450
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: t-butyl alcohol (sara 313)
cas: 75-65-0
rtecs #: eo1925000
fraction by wt: 1.9%
other rec limits: niosh 100/stel 150
osha pel: 100 ppm/stel 150
acgih tlv: 100 ppm
ingred name: voc = 11.0 lb/gl 1319 g/l
rtecs #: 9999999vo
fraction by wt: na
other rec limits: none recommended
osha pel: not relevant
acgih tlv: not relevant
Ld50 lc50 mixture: none specified by manufacturer.
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: yes iarc: yes osha: yes
health hazards acute and chronic: defat skin causing
irrit,redness,dryness,scaling.Eye: irrit,mild conjunctivitis.Vap
inhal: head,dizz,equilibrium disturbances,high conc lead to cns
depress,unconsc,coma.Mild live/kidney dysfunction aft cns depress
recovery.Ingest: unlikely ifso nau,vomit,diarr,possible esophageal
burns.Chronic effects: none reported.
explanation of carcinogenicity: per msds: iarc/ntp/osha list component
1,1,1-trichloroethane as suspected carcinogen.
effects of overexposure: inhal: lightheadnedness,impaired
coordination,dizziness,drowsiness.Eye: blurning,stinging,watering,co
njunctival inflamm,possible corneal injury.Skin: mild
irrit,dryness(defatting effect),cold feeling.Ing est: depression of
cns,throat irrit,dizz,drowsiness,unconsc,death.
medical cond aggravated by exposure: none reported. Target
organs: skin,eye,central nervous
system(cns),cardiovascular(cvs)system.
First aid: inhal: remove to fresh air.Breath diff admin oxy.Eye: don't
allow to rub or keep tightly shut.Foush w/lg amts of wter.Consult
dr.Skin: quickly remove contamin cloth.Rinse w/lg amts of water.Wash
w/soap/w ater.Red/blisted skin consult dr.Ingest: do not induce
vomit.Give 1 or 2 glasses of water to drink.Never give anything by
mouth if unconsc.Contact pois cntrl cntr/med person.Dr: avoid use of
(supplemen)
Hcc: t4
boiling pt: =76.7c, 170.F
melt/freeze pt: =-37.2c, -35.F
decomp temp: decomp text: np
vapor pres: 100 @20c
vapor density: 4.6
spec gravity: 1.319
ph: na
viscosity: 0.86cp @20c
evaporation rate & reference: 35, ether=1.
solubility in water: 0.07g/100g @25c.
appearance and odor: liquid, clear, particle free liquid w/sweet aroma.
percent volatiles by volume: 100
corrosion rate: na
Stability indicator/materials to avoid: yes
water,reactive metals such as aluminum/magnesium,strong oxidizing
agents, strong alkalies.
stability condition to avoid: open flames, sparks, high temperatures,
ignition sources.
hazardous decomposition products: haz combust prod: hydrogen
chloride,dichloroacetylene,phosgene,chlorine gas.
Waste disposal methods: contact supplier/licd contractor for detailed
recommendations.Any dispo must be in compliance w/fed/state/loc
regs.Empty cntnr retain prod residue.Don't distribute/make
avai/furnish/reuse empty cntr e xcept for storage/ship org
prod.Remove (oth preca)
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara 313)
(cercla)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: >95%
other rec limits: none recommended
osha pel: 350 ppm
acgih tlv: 350 ppm/450stel;9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: tert-butyl alcohol (sara 313)
cas: 75-65-0
rtecs #: eo1925000
fraction by wt: 1.9%
other rec limits: none recommended
osha pel: 100 ppm
acgih tlv: 100 ppm, a4; 9596
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: inhal: major potntl rte of expos.
min efts observed
olfactory fatg); dizz, drow & throat irrit at levels >1000 ppm.
blood press depress, card sensi t & ventricular arrhy can rslt from
expos to near-anesth levels. Studies in lab animals have shown
1,1,1-trichloroethane in aerosol form to be more acutely tox than
1,1,1-trichloroethane vap. Eye cont : liq can cause slight temporary
irrit w/slight temporary corneal injury. Vaps can irrit eyes. Skin
cont: rptd/prlng cont can cause irrit, defat of skin & derm.
absorption thru intact skin is poss if co nt w/liq is prlng. (efts
of overexp)
explanation of carcinogenicity: the available data indicates that
1,1,1-trichloroethane and this mixture are not carcinogenic in lab
animals. 1,1,1-trichloroethane is not listed on the osha, iarc or
ntp carcinogen lists.
effects of overexposure: hlth haz: 1,4-diethylene dioxide as pure
substance is readily absorbed thru skin. Ingest: single dose tox is
low to mod. If vomit occurs, 1,1,1-trichloroethane can be aspirated
into lungs, which can cau se chem pneum & systemic efts.
chronic: chlorocarbon matls have prdcd sensit of myocardium to
epinephrine in lab animals & could have similar eft in humans.
adrenomimetics (e.G.,epinephrine) may be con traindicated except
for life-sustaining uses in humans acutely/chronically exposto
chlorocarbons . Finding of chronic tox efts in lab animals may
indicate tox to humans. Overexp should be avoide d, failure to do
so could (supp data)
medical cond aggravated by exposure: acute and chronic liver disease and
rhythm disorders of the heart.
First aid: inhalation: remove patient to fresh air. If not breathing,
give artificial respiration, call md. Eyes: immediately flush with
water for at least 15 minutes if irritation persists, call md.
skin: immed iately flush with water for at least 15minutes if
irritation persists. Call md. Remove contaminated clothing and
shoes. Wash exposed area with soap and water. Wash contaminated
clothing before reuse. ingestion: do not induce vomiting. Contact
md or emergency medical facility immediately. Note to md (including
antidotes): adrenaline should never be given to persons overexposed
to 1,1,1-trichloroeth ane.
Boiling pt: =73.9c, 165.F
b.P. Text: @ 760 mm hg
vapor pres: 100 mm hg @ 20c
vapor density: 4.6(air=1)
spec gravity: 1.32 @ 25/25c (h*2o=1)
evaporation rate & reference: 0.4 (ether=1)
solubility in water: 0.07 g/100 g @ 25c
appearance and odor: clear, colorless liquid; mild, sweet odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong alkalis, oxidizers, and reactive metals (i.E. Aluminum,
potassium, sodium, etc). Refer to handling and storage section for
additional information on aluminum.
stability condition to avoid: avoid contact with flames, electric arcs,
or other hot surfaces that can cause thermal decomposition.
hazardous decomposition products: hydrogen chloride, chlorine, phosgene.
conditions to avoid polymerization: will not occur.
Waste disposal methods: contaminated material must be disposed of in a
permitted hazardous waste managment facility. Recovered liquids may
be sent to a licensed reclaimer or incineration facility. Consult
federal, state, or local disposal authorities for
approvedprocedures.
Ingred name: 1,1,1-trichloroethane
cas: 71-55-6
rtecs #: kj2975000
= wt: 96.5
osha pel: 1900 mg/m3;350 ppm
osha stel: 450 ppm stel
acgih tlv: 1910 mg/m3;350 ppm
acgih stel: 2460 mg/m3;450 ppm
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: 1,4-diethylene dioxide
cas: 123-91-1
rtecs #: jg8225000
< wt: 3.
osha pel: 360 mg/m3;100 ppm
acgih tlv: 90 mg/m3;25 ppm
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
ingred name: 1,2-butylene oxide
cas: 106-88-7
rtecs #: ek3675000
< wt: .5
epa rpt qty: 1 lb
dot rpt qty: 1 lb
Effects of overexposure: inhalation: major route of exposure-low
systemic toxicity; acute exposure in the
1000ppm range cause narcosis. Overexposure can cause
dizziness,drunkenness and
drosiness, unconsciousness and even deat h at extreme doses. Skin
contact/absorption: prolonged or repeated skin contact can cause
dermatitis
through defatting of skin. Ingestion: unlikely route of exposure,
ingestion of small
quantities is not likely be toxic.
First aid: eyes and skin: remove contaminated clothing and flush exposed
areas with water
for 5 to 15 minutes. Inhalation: remove to fresh air . If breathing has
stopped,
administer respiration or oxygen if avai lable. Ingestion: do not
induce vomiting.
call physician and obtain medical attention.
Boiling pt: =87.8c, 190.F
vapor pres: (mm hg) @20%c 100
vapor density: (air=1)4.6
spec gravity: (h20=1): 1.3
evaporation rate & reference: (ether=1): 0.4
solubility in water: 0.07g/100g @ 25%c
appearance and odor: colorless cleanliquid; mildly sweet odor.
Stability indicator/materials to avoid: yes
strong alkalies, oxidizing materials.
stability condition to avoid: contact with open flames, hot surfaces or
electric arcs.
hazardous decomposition products: hydrogen chloride, phosgene (small
amounts)
Waste disposal methods: recovered liquids may be sent to a licensed
reclaimed or incinerated. Contaminated
absorbent material must be disposed of in a permitted waste management
facility.
consult federal, state and local dis posal authorities for approved
procedures.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: 1,1,1 trichloromethane (stabilized)
= wt: 100.
osha pel: 350 ppm