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Technical Sodium Fluoride

NSN: 6810-00-680-1079 | Model: AWWA B-701
NSN Properties and Flags
NATO Stock Number
6810-00-680-1079
DEMIL
NO
Physical Form
Powder
Quantity Within Each Unit Package
50.000 pounds
Composition And Percentage
42.9 by weight fluorine
Specification Data
06768-awwa b-701 professional/industrial association standard

Pricing and Availability

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NSN 6810-00-680-1079 Datasheet

Supply Class (FSC):
Chemicals
Cross Reference:
  • AWWA B-701
  • AWWAB701-60
Cage Codes:
  • American Water Works Association (CAGE 06768)
Schedule B & Trade:
  • Schedule B: 2826191500 (NAICS 325180)

    Flourides of ammonium or of sodium

  • SITC: 52310

    Fluorides; fluorosilicates, fluoroaluminates and other complex fluorine salts

  • End Use: 12530

    Chemicals-inorganic

Identification:
HMIC

Y - Indicates information is in the hazardous materials information resource system (hmirs).

PMIC

A - Item does not contain precious metal.

CRITL

- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.

Freight Information:
  • NMFC:

    046340 - Sodiu (soda) fluoride

  • WCC:

    635 - Chemicals, other than drugs or sundries

  • SHC:

    9 - Other or no special handling required (sh)

  • ADC:

    A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.

  • ACC:

    C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp

  • TCC:

    P - Poison, class b, un class 6 (poison label)

  • LTL:

    W - Rating variable

NSN Management Codes:
  • SOS
    Sms
  • AAC
    H
  • Quantity per pack
    1
  • Unit of Measure
    Bg
  • Shelf Life
    N/A
  • Classification Control
    U
  • MGMT_CTL
    R2200x-
  • Repariability
    This is a nonreparable item. if condemned or economically unserviceable, then dispose at the level authorized replace the item.

Questions & Answers:

What are the historical prices recorded for this stock number?
Historical data shows pricing from $597.78 to $996.30..
Does NSN 6810-00-680-1079 have a shelf life?
No. There is no shelf life applicable for this NSN.
What NATO entities are users of this NSN?
Department Of The Army, Department Of The Air Force, U.s. Marine Corps, Department Of The Navy, and Greece
What is the NIIN of NSN 6810-00-680-1079?
006801079 or 00-680-1079
Does NSN 6810-00-680-1079 require demilitarization?
Yes - ITAR Controlled
What is the most recent solicitation for NSN 6810-00-680-1079?
No solicitations for this NSN.
When was this national stock number assigned to the federal catalog?
Jan 01, 1963
MSDS

Material Safety

MSDS BFLFL SODIUM FLUORIDE POWDER

Hazards

Effects of overexposure: inh/ing harmful,possibly fatal.Irritates
skin,eyes,mucous membranes.May cause fluorosis.

First Aid

First aid: inhal: rmv to fresh air. If not brthng give cpr; if brthng
diff give oxygen. Eye: immed flush w/plenty of water. Skin: wash
w/soap&water. Rmv contam clthg&shoes. Ingest: induce vomit. Rpt
until vomit is c lear. Nothg by mouth if unconsc. Get medical attn.

Chemical Properties

Hcc: c3
solubility in water: moderate
appearance and odor: white powder.Odorless

Reactivity

Stability indicator/materials to avoid: yes
avoid contact with acids.

stability condition to avoid: avoid contact with acids.Avoid stg.Under
moist conditions.

hazardous decomposition products: highly toxic.Corrosive hf.

Proper Disposal

Waste disposal methods: landfill iaw all applicable local,state & fed
regs.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium fluoride (sara iii)
cas: 7681-49-4
rtecs #: wb0350000
fraction by wt: 97%.

osha pel: 2.5 ppm f
acgih tlv: 2.5 mg f/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs

MSDS BFLFM SODIUM FLUORIDE POWDER

Hazards

Effects of overexposure: inh/ing harmful,possibly fatal.Irritates
skin,eyes,mucuous membranse.May cause fluorosis.

First Aid

First aid: inhal: rmv to fresh air. If not brthng give cpr; if brthng
diff give oxygen. Eye: immed flush w/plenty of water. Skin: wash
w/soap&water. Rmv contam clthg&shoes. Ingest: induce vomit. Rpt
until vomit is c lear. Nothg by mouth if unconsc. Get medical attn.

Chemical Properties

Hcc: c3
solubility in water: moderate
appearance and odor: white powder.Odorless.

Reactivity

Stability indicator/materials to avoid: yes
avoid contact with acids
stability condition to avoid: avoid contact with acids.Avoid stg.Under
moist conditions.

hazardous decomposition products: highly toxic.Corrosive hf.

Proper Disposal

Waste disposal methods: landfill iaw all applicable
local,state,fed.Regs.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium fluoride (sara iii)
cas: 7681-49-4
rtecs #: wb0350000
fraction by wt: 97%.

osha pel: 2.5 ppm f
acgih tlv: 2.5 mg f/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs

MSDS BFLFN SODIUM FLUORIDE

Hazards

Effects of overexposure: poison: may be fatal if inhaled or swallowed.

First Aid

First aid: give as soon as possible,saturated solution of calcium
hydroxide, 1% calcium chloride or milk. Call a physician.

Chemical Properties

Hcc: c3
boiling pt: b.P. Text: 3090f
spec gravity: 1.24
solubility in water: slight
appearance and odor: white,crystal,or powder colored blue or identifon

Reactivity

Stability indicator/materials to avoid: yes
none
stability condition to avoid: none specified.

hazardous decomposition products: none

Proper Disposal

Waste disposal methods: dispose in chemical dump- or flush to approved
sewer with large quantities of water according to local,state &
federal regulations.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium fluoride (sara iii)
cas: 7681-49-4
rtecs #: wb0350000
fraction by wt: 100%
osha pel: 2.5 ppm f
acgih tlv: 2.5 mg f/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs

MSDS BFLFP SODIUM FLUORIDE,TECHNICAL

Hazards

Effects of overexposure: irritates tissue by inhalation or
swallowing.Acute: nausea,vomiting,diarrhea,coma,weakness,tremor

First Aid

First aid: move victim to fresh air;call emergency medical care.Remove &
isolate contaminated clothing & shoes.In case of contact with
material,immediately flush skin or eyes with running water for at
least 15 m inutes

Chemical Properties

Hcc: c3
boiling pt: b.P. Text: >3000f
spec gravity: 2.78
solubility in water: moderate
appearance and odor: fine white crystals & powder w/no odor

Reactivity

Stability indicator/materials to avoid: yes
acids
stability condition to avoid: acids will generate hydrofluoric acid.

Proper Disposal

Waste disposal methods: fluoride salts are poisonous & disposal by a
disposal contractor may be necessary.Contact local,county or state
regulations for permissible disposal methods in your area,or remove
slowly into a large container of water-add soda ash slightly &
6m-hcl.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium fluoride (sara iii)
cas: 7681-49-4
rtecs #: wb0350000
osha pel: 2.5 ppm f
acgih tlv: 2.5 mg f/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs

MSDS BFLFQ SODIUM FLUORIDE

Hazards

Ld50 lc50 mixture: 180 mg/kg /rat/
health hazards acute and chronic: gastrointestinal symptoms. Burns to
eyes & mucous membranes. Skin irritation,nose bleeds,weakness, &
dermatitis.

effects of overexposure: see health hazards

First Aid

First aid: skin & eyes-flush w/water 15 min & call a physician.

ingest-drink lge quant water. Induce vomiting by sticking finger
down throat. Call a physician.

Chemical Properties

Hcc: c3
boiling pt: b.P. Text: 3099f
melt/freeze pt: m.P/f.P text: 1818f
spec gravity: 2.8
ph: 6.5
solubility in water: 4.4%
appearance and odor: white,odorless powder or crystalline solid

Reactivity

Stability indicator/materials to avoid: yes
acids
hazardous decomposition products: hydrogen fluoride

Proper Disposal

Waste disposal methods: consult approp. Fed,state & local regulatory
agencies.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium fluoride (sara iii)
cas: 7681-49-4
rtecs #: wb0350000
osha pel: 2.5 ppm f
acgih tlv: 2.5 mg f/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs

MSDS BFLFR SODIUM FLUORIDE,POWDER

Hazards

Ld50 lc50 mixture: 80mg/kg (rat)
routes of entry: inhalation: yes skin: unknown ingestion: yes
health hazards acute and
chronic: acute: eyes: corrosive,pain,redness,blurred vision.

inhalation: irritation,sore throat,coughing,difficulty in breathing.

skin: may cause formation of large,open,boil-like sores(in presence
of water). Inge stion: chronic poisoning,internal bleeding due to
stomach acids.

effects of overexposure: acute tox effec
poss.Eye,skn: irrt,burns.Inhl: chron tox
poss.Ing: naus,vomit,diarr,itch,-see suplmnt
medical cond aggravated by exposure: pre-existing conditions may be
worsen.

First Aid

First aid: eye,skn: flush 15 min w/ample water. Inhl: remove to fresh
air.Ingest: do not induce vomit;if consc, give ample water, 1%
cacl*2 sln,or lime water. Obtain prompt med attn all cases.

Chemical Properties

Hcc: c3
decomp temp: decomp text: 1695c/3083f
vapor pres:
spec gravity: 2.56
evaporation rate & reference: 0.0
solubility in water: moderate
appearance and odor: white powdery solid
percent volatiles by volume: 0

Reactivity

Stability indicator/materials to avoid: yes
none specified by the mfr.

stability condition to avoid: keep away from acids.

hazardous decomposition products: hydrogen fluoride (hf)produce if mixed
with acid.

Proper Disposal

Waste disposal methods: dispose of iaw local,state,and federal
regulations.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium fluoride (sara iii)
cas: 7681-49-4
rtecs #: wb0350000
fraction by wt: 100.0%
osha pel: 2.5 ppm f
acgih tlv: 2.5 mg f/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs

MSDS BLLVR SODIUM FLUORIDE

Hazards

Ld50 lc50 mixture: ld50 (oral rat) is 64 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute-eyes/skin: may cause severe
irritation/burns.Inhalation: dust may cause severe irritation of
respiratory system.Ingestion: may cause
headache,nausea,vomiting,gastrointestinal irritation,convulsions ,&
burns to mouth,throat & stomach.Chronic-calcium deposits in
ligaments,increased bone density & mottled tooth enamel.

effects of overexposure: severe irritation and burns of eye and skin.

inhalation of dust may cause severe irritation of respiratory
tract. Ingestion may cause headache, nausea, vomiting,
gastrointestinal irritation, convulsio ns, & burns to mouth, throat
& stomach.

medical cond aggravated by exposure: none identified

First Aid

First aid: call a physician in all cases.Inhalation: remove to fresh
air.Give cpr/oxygen if needed.Eyes: immediately flush with water for
15 minutes holding eyelids open.Skin: remove contaminated
clothing.Flush ski n with water.Ingestion: if conscious,immediately
induce vomiting.

Chemical Properties

Hcc: t4
nrc/state lic num: not relevant
boiling pt: =1703.9c, 3099.F
melt/freeze pt: =992.8c, ######f
spec gravity: 2.78
solubility in water: appreciable (>10%)
appearance and odor: white odorless crystals or powder
percent volatiles by volume: 0

Reactivity

Stability indicator/materials to avoid: yes
strong acids, glass
stability condition to avoid: heat
hazardous decomposition products: hydrogen fluoride

Proper Disposal

Waste disposal methods: disposal should be made in accordance with all
applicable federal, state and local laws and regulations.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium fluoride (sara iii)
cas: 7681-49-4
rtecs #: wb0350000
fraction by wt: 99- 100%
other rec limits: none specified
osha pel: 2.5 ppm f
acgih tlv: 2.5 mg f/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs

MSDS BRSTN SODIUM FLUORIDE, COARSE

Hazards

Ld50 lc50 mixture: ld50 oral 180 mg/kg (rat)
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation may cause severe mucous
membrane irritation, repeated exposure to excessive concentrations
of fluoride over a period of years may cause crippling fluorosis.

skin irritation, eye irritation , gastrointestinal disturbances.

explanation of carcinogenicity: product contains no ingredients
currently classified as carcinogenic by ntp, iarc or osha.

effects of overexposure: coughing, sore throat, shortness of breath,
labored breathing, skin redness/pain, corrosive burns, eye
redness/pain/blurred vision, nausea, vomiting, diarrhea, abdominal
pain, thirst. Serious poisonin g may include weakness, tremors,
convulsions, collapse, low blood calcium levels, coma, death,
weight loss, amenia.

medical cond aggravated by exposure: none specified by manufacturer.

First Aid

First aid: eyes: flush with large amount of water for at least 15
minutes. Skin: remove contaminated clothing. Wash exposed areas
with soap and water. Inhalation: remove to fresh air. Treat
symptomatically. Inge stion: if conscious, drink large quantities
of water, 1% calcium chloride solution or calcium gluconate. Do not
induce vomiting. In all cases, get immediate medical attention.

Chemical Properties

Hcc: c3
boiling pt: b.P. Text: 3099f,1704c
melt/freeze pt: m.P/f.P text: not given
vapor pres: not given
vapor density: not given
spec gravity: not given
evaporation rate & reference: not given
solubility in water: moderate
appearance and odor: white granular solid, little or no odor

Reactivity

Stability indicator/materials to avoid: yes
acids, glass, aluminum
stability condition to avoid: when dissolved in water, sodium fluoride
forms a corrosive solution which may attack glsaa or aluminum.

hazardous decomposition products: thermal decomposition may release
hazardous fumes of hydrogen fluoride and sodium oxides.

Proper Disposal

Waste disposal methods: prevent waste from contaminating surrounding
environment. Discard any product, residue, disposal container or
liner in accordance with all federal, state and local regulations.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium fluoride (sara iii)
cas: 7681-49-4
rtecs #: wb0350000
fraction by wt: 97-100%
other rec limits: none recommended
osha pel: 2.5 ppm f
acgih tlv: 2.5 mg f/m3; 9293
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs

ingred name: sodium silicofluoride
cas: 16893-85-9
rtecs #: vv8410000
fraction by wt: 0-2.5%
other rec limits: none recommended

MSDS BWCDP SODIUM FLUORIDE

Hazards

Ld50 lc50 mixture: tolerance as (fl)=2.5mg/m3.

routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: toxic by inhal or ingest. Tolerance as
(fl)=2.5 mg/ms. Inhal: strong irrit to muc memb. Skin: irrit to moist
skin. May cause ulcers. Eye: severe irrit. Ingest: irrit to digestive
tract. Antidote: antacid, lime water or milk.

explanation of carcinogenicity: per msds: suspected carcer agent: no.

effects of overexposure: irrit to muc memb, skin, eye, gi tract.

medical cond aggravated by exposure: none specified by mfg.

First Aid

First aid: inhal: remove to fresh air. Skin: wash w/soap & water. Apply
antiseptic ointment. Eye: flush w/water for 15mins. Ingest: induce
vomit. Give large quantities of water. Antidote: antacid, lime water
or milk. recommendations to doctor: treat symptomatically.

Chemical Properties

Hcc: t4
boiling pt: b.P. Text: 3083f,1695c
melt/freeze pt: m.P/f.P text: 1819f,993c
spec gravity: 2.78
solubility in water: soluble
appearance and odor: white crystalline powder, odorless.

Reactivity

Stability indicator/materials to avoid: yes
strong acids.

stability condition to avoid: glass or enameled equipment.

hazardous decomposition products: hydrogen fluoride.

Proper Disposal

Waste disposal methods: neutralize w/lime. Flush w/lg vol of water tru
waste water system. Dispose of all wastes in accordance with local,
state and federal regulations.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium fluoride (sara iii)
cas: 7681-49-4
rtecs #: wb0350000
fraction by wt: 98.9%
other rec limits: none recommended
osha pel: 2.5 ppm (f)
acgih tlv: 2.5 mg (f)/m3; 9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs

ingred name: inert materials (salts)
fraction by wt: 1.1%
other rec limits: none recommended

MSDS CDZFX SODIUM FLUORIDE

Hazards

Ld50 lc50 mixture: ld50 (oral, rat) is 52 mg/kg (rtecs).

routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eye, skin, respiratory &
gi tracts. Acute- may cause eye and skin irritation. Harmful if
ingested. Inhalation of dust may cause irritation of mucous
membranes. Chronic- unknown.

explanation of carcinogenicity: none
effects of overexposure: irritation, pain, tearing, nausea, vomiting,
diarrhea, burning sensation, headache, coughing, wheezing
medical cond aggravated by exposure: any skin, respiratory or mucous
membrane conditions

First Aid

First aid: call physician if symptoms persist. Eye: immediately flush
with water for 15 minutes. Hold eyelids open. Call physician.

skin: wash with soap & water. Inhaled: remove to fresh air. Provide
cpr/oxygen if needed. Oral: if conscious, wash mouth thoroughly.

drink milk/water & induce vomiting. Call a physician immediately.

never give fluid or induce vomiting if patient is unconscious or
has convulsions.

Chemical Properties

Hcc: t4
nrc/state lic num: not relevant
boiling pt: b.P. Text: 3099f,1704c
melt/freeze pt: m.P/f.P text: 1819f,993c
spec gravity: 2.56
ph: 7.4sat
viscosity: not relevant
evaporation rate & reference: not relevant
solubility in water: 4% @ 25c/77f
appearance and odor: white fine crystals - odorless

Reactivity

Stability indicator/materials to avoid: yes
strong acids
stability condition to avoid: excessive heat
hazardous decomposition products: may form hydrogen fluoride, fluorine
and sodium oxide.

Proper Disposal

Waste disposal methods: dispose of in accordance with local, state and
federal regulations. Reportable quantity (rq): 1000 pounds.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: sodium fluoride (cercla)
cas: 7681-49-4
rtecs #: wb0350000
fraction by wt: 97% min.

other rec limits: none recommended
osha pel: 2.5 ppm (f)
acgih tlv: 2.5 mg (f/)m3; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs

MSDS CJQBF SODIUM FLUORIDE

Hazards


ld50 lc50 mixture: ld50 = 180 mg/kg (rat)
route of entry inds - inhalation: yes
skin: yes
ingestion: yes
carcinogenicity inds - ntp: no
iarc: no
osha: no
effects of exposure: acute: inhalation of dust or mist may cause severe mucous
membrane irritation and burns. Effects may not be immediately apparent,
especially with dilute solutions. Chronic: causes severe skin irritati on and
burns. Ingestion or inhalation may be harmful and possibly fatal depending on
severity and length of over exposure. Chronic over exposure may cause
fluorosis. Product may be absorbed through th e skin and produce signs of
fluorosis such as weight loss, brittleness of bones,anemia, weakness and
stiffness of joints. Internal bleeding may develop.

explanation of carcinogenicity: none listed.

signs and symptions of overexposure: irritation, burns. Chronic over exposure
may cause fluorosis.

medical cond aggravated by exposure: any skin, respiratory or mucous membrane
conditions.

first aid: inhale: remove to fresh air. If breathing has stopped, perform
artificial respiration. Keep this person warm and at rest. Get medical
attention. Eye: flush with large amounts of water, lifting the upp er and
lower lids at periodic intervalsto insure contact of water with all
accessible tissue of the eyes and lids. Immediate medical attention. Skin:
use soap and mild detergent and water to wash cont aminated skin. Remove
contaminated clothing. Ingest: if conscious, give large quantities of water
immediately. Do not induce vomiting. Several glasses of milk may be given for
soothing effect. Call a physician.

Chemical Properties


hcc: t4
boiling point: =1704.C, 3099.2f
melt/freeze pt: =992.C, ######f
spec gravity: 2.56
ph: ~7
solubility in water: 4g/100g ofh20
appearance and odor: white,crystalline powder;no odor

HAZCOM Label


product id: sodium fluoride
cage: to289
assigned ind: y
company name: lci ltd.

street: unk
po box: 49000
city: jacksonville beach fl
zipcode: 32240-9000
health emergency phone: 904-241-1200
label required ind: y
date of label review: 10/15/1999
status code: a
origination code: f
eye protection ind: yes
skin protection ind: yes
signal word: warning
respiratory protection ind: yes
health hazard: moderate
contact hazard: slight
fire hazard: none

Transportation

=======================================================
responsible party cage: to289
trans id no: 149265
product id: sodium fluoride
msds prepared date: 03/01/1999
review date: 10/15/1999
mfn: 1
net unit weight: 100 lb bag
multiple kit number: 0
unit of issue: bg
container qty: 1
type of container: bag

Reactivity

Hazard and precautions
precautions: inhalation: if a person breathes in chemical dust or mist, remove
exposed person to fresh air. Eye contact: flush with large amounsts of water,
lifting eyelids at periodic intervals to in sure contact of water with all
accessible tissue of the eye and eyelids. Skin: wash contaminated skin using
soap or mild detergent and water. Ingest: if conscious, give the exposed
person large quanti ties of water immediately. Do not induce vomiting. See
msds for additional information. Store the material in a cool, dry place and
away from acids. Use only with adequate ventilation.

Proper Disposal


spill release procedures: any personnel in area should wear a niosh approved
protective clothing and breathing apparatus. Isolate product spill area.

carefully shovel material and place in clean, dry container and cover. Remov
e container from spill site and disposeof in accordance with federal, state,
and local regulations.

waste disposal methods: contact chemtrec at 1-800-424-9300 for 24-hour
emergency assistance. Follow all federal, state, and local regulations.

handling and storage precautions: store in a cool, dry place and away from
acids. Use only with adequate ventilation, dust mask or self-contained
breathing apparatus. Protective clothing should always be worn. Avoid contact
with eyes, skin, and clothing. Keep bag or containers closed when not in
use.

other precautions: avoid breathing dust or mist.

MSDS CKSVQ SODIUM FLUORIDE (SEE SUPPL DATA)

Hazards

Ld50 lc50 mixture: oral rat ld50: 52 mg/kg
routes of entry: inhalation: yes skin: unknown ingestion: yes
health hazards acute and chronic: inhalation: causes severe irritation
to the respiratory tract. May be absorbed through inhalation of
dust. Irritation effects may not appear immediately. Ingestion:
toxic ! May cause brain & kidney da mage. Affects heart &
circulatory system. Death may occur from respiratory paralysis.

estmiated lethal dost = 5 to 10 grams. skin: causes irritation.

solutions are corrosive. Effects may not appear i mmediately. Eye:
irritant ! May cause irritation & serious eye damage. Effects may
not immediately appear. Chronic: may cause mottling of teeth & bone
damage (osteroclerosis) & fluorosis.

explanation of carcinogenicity: none provided by mfr.

effects of overexposure: inhalation: coughing, sore throat & labored
breathing. May parallel those from ingestion exposure. Ingestion:
may cause salivation, nausea, vomiting, diarrhea, & abdominal pain.

symptoms of weakness, tremors, shallow respiration, cardopedal
spasm, convulsions, & coma may follow. Skin: redness & pain.

chronic: symptoms of fluorisis include brittle bones, weight loss,
anemia, calcified ligaments, g eneral ill health & joint stiffness.

medical cond aggravated by exposure: populations that appear to be at
increased risk from the effects of fluoride are individuals that
suffer from diabetes insipidus or some forms of renal impairment.

First Aid

First aid: inhalation: remove to fresh air. If not breathing, give
artificial respiration. If breathing is difficult, give oxygen.

call a physician immediately. Ingestion: administer milk, chewable
calcium carbo nate tablets or milk of magnesia. Never give anything
my mouth to an unconscious person. Call a physician immediately.

skin: wipe off any excess material from skin & then immediately
flush skin with l g amounts of soapy water. Remove contaminated
clothing & shoes. Wash clothing before re-use. Apply bandages
soaked in magnesium sulfate. Call a physician immediately.

Chemical Properties

Hcc: t4
boiling pt: =1700.C, 3092.F
melt/freeze pt: =992.8c, ######f
decomp temp: decomp text: none provided by mfr.

vapor pres: 1 @ 1077c(1971f) (mm hg)
vapor density: no info
spec gravity: 2.78
ph: no info found
viscosity: none provided by mfr.

evaporation rate & reference: no information found
solubility in water: 4 g/100 ml water @ 15c
appearance and odor: white crystals, odorless
percent volatiles by volume: 0 @ 21c(70f)
corrosion rate: none provided by mfr

HAZCOM Label

Schedule ; s2.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Reactivity

Stability indicator/materials to avoid: yes
reacts with acids to form hydrogen fluoride
stability condition to avoid: stable under ordinary conditions of use &
storage
hazardous decomposition products: burning may produce hydrogen fluoride
vapors
conditions to avoid polymerization: will not occur

Proper Disposal

Waste disposal methods: whatever cannot be saved for recovery or
recycling should be managed in an appropriate & approved waste
disposal facility. Processing, use or contamination of this product
may change the waste managem ent options. State & local disposal
regulations may differ from federal disposal regualtions.

Ingredients List

Ingred name: sodium fluoride
cas: 7681-49-4
rtecs #: wb0350000
= wt: 100.

epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs