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Methanol (methyl alcohol)
Methanol (methyl alcohol)
Chemicals-organic
Y - Indicates information is in the hazardous materials information resource system (hmirs).
PMICA - Item does not contain precious metal.
CRITL- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.
042690 - Alcohol amyl etc
530 - Toiletries, cologne, perfumes, antiseptics (flammable)
9 - Other or no special handling required (sh)
A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.
C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp
R - Flammable liquids, un class 3 (flammable liquids label)
W - Rating variable
Questions & Answers: |
|
| What are the historical prices recorded for this stock number? | |
| Historical data shows pricing from $48.15 to $80.26.. | |
| Does NSN 6810-00-687-8056 have a shelf life? | |
| No. There is no shelf life applicable for this NSN. | |
| What NATO entities are users of this NSN? | |
| Department Of The Army, Department Of The Air Force, Department Of The Navy, Bureau Of Mines, Brazil, Republic Of Korea, Greece, and Turkey | |
| What is the NIIN of NSN 6810-00-687-8056? | |
| 006878056 or 00-687-8056 | |
| Does NSN 6810-00-687-8056 require demilitarization? | |
| Yes - ITAR Controlled | |
| What is the most recent solicitation for NSN 6810-00-687-8056? | |
| No solicitations for this NSN. | |
| When was this national stock number assigned to the federal catalog? | |
| Jan 01, 1963 | |
Effects of overexposure: eyes: irrit.May cause
blindness;skin: irritates,dries/dermatitis;inhal: head,nausea,narcosi
s-see suppl
First aid: skin: wash w.Soap & h*2o eyes: flush w. H*2o. Ingested: give 2
glasses h*2o; induce vomiting.Call a physician. Inhale: remove to
fresh air. Give cpr/oxygen if need. Keep warm & quiet. Remove
contaminated clothing. If uncons do not take anything by mouth.
Hcc: f2
boiling pt: b.P. Text: 148f/65c
vapor pres: 100
vapor density: 1.11
spec gravity: 0.792
solubility in water: complete
appearance and odor: colorless liquid with faint alcohol odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizing agents.
stability condition to avoid: heat, ignition sources
hazardous decomposition products: incompletely burned carbon products,
co*2, co.
Waste disposal methods: keep in covered drums,pending disposal. Handle &
dispose in full compliance with all applicable
international,federal,state, & local regulations. Rcra hazardous
waste #u154
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 100%
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Effects of overexposure: vapors: harmful. Ingestion: fatal
First aid: ingestion: induce vomiting. Call a physician. Inhalation:
remove to fresh air,give artifical respiration if needed,call a
physician.
Hcc: f2
boiling pt: b.P. Text: 149f/65c
vapor pres: 100
vapor density: 1.1
spec gravity: 0.79
evaporation rate & reference: >1(ether)
solubility in water: complete
appearance and odor: colorless liquid
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
Waste disposal methods: dispose of by means as to comply with all
local,state & federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: ld50 oral rat=5628 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: toxic by ingestion & inhalation.
affects central nervous system,especially optic nerve. Causes
dizziness,nausea,muscle weakness,narcosis,respiratory failure.
ingestion can produce blindness. 100 ml ca n be fatal. Can be toxic
by skin absorption. Prolonged or repeated skin contact may cause
irritation.
effects of overexposure: see health hazards.
medical cond aggravated by exposure: none noted.
First aid: eyes: immediately flush with large amounts of water;skin: wash
thoroughly with soap & water;inhalation: remove to fresh air,give
cpr if breathing has stopped;ingestion: do not induce vomit,get
immediate m edical attention. Remove contaminated clothing & wash
before reuse.
Hcc: f5
boiling pt: =68.9c, 156.F
melt/freeze pt: =-97.8c, -144.F
vapor pres: 97
vapor density: 1.1
spec gravity: 0.791
evaporation rate & reference: 5.91 (bu ac=1)
solubility in water: miscible
appearance and odor: colorless liquid with characteristic alcoholic
odor.
percent volatiles by volume: 99.9+
Stability indicator/materials to avoid: yes
oxidizer,reactive metals.
stability condition to avoid: heat,ignition sources.
hazardous decomposition products: formaldehyde,co,co*2
Waste disposal methods: dispose of iaw federal,state & local
regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 100%
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: ld50 (orl rat): 5628mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute-inhale: is harmful & may be
fatal.May cause
headache,nausea,vomiting,dizziness,narcosis,respiratory failure,low
blood pressure,cns
depression.Skin: irritation,dermatitis.Eyes: irritation,may cause
temporary corneal damage.Oral: symptoms similar to
inhalation,blindness,hearing loss.Chronic-kidney & liver damage.
effects of overexposure: inhalation is harmful & may be fatal. May cause
headache, nausea, vomiting, dizziness, narcosis, respiratory
failure, low blood pressure, cns depression.May cause skin
irritation & dermatitis. May cau se eye irritation & temporary
corneal damage. Oral symptoms are similar to inhalation, blindness,
hearing loss.
medical cond aggravated by exposure: eye, skin, liver or kidney disorder
First aid: call a doctor in all cases.Eye/skin: immediately flush with
water for 15 minutes.Hold eyelids open.Inhalation: remove to fresh
air.Provide cpr/oxygen if needed.Ingestion: if conscious,drink large
amount of water.Induce vomiting.Call a physician/poison control
center immediately.
Hcc: f5
boiling pt: =65.C, 149.F
vapor pres: 96 @ 20c
vapor density: 1.11
spec gravity: 0.79
evaporation rate & reference: 4.6 (n-butyl acetate=1)
solubility in water: complete
appearance and odor: clear, colorless liquid - pungent odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizing agents, strong acids, zinc, aluminum, magnesium
stability condition to avoid: heat, flame, other ignition sources
hazardous decomposition products: carbon monoxide, carbon dioxide,
formaldehyde
Waste disposal methods: dispose in accordance with all applicable local,
state and federal regulations. Epa hazardous waste number is u154
(toxic waste). Rq for methanol is 5000 lbs.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 90- 100%
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Effects of overexposure: weakness,headache,nausea,vomiting,abdominal
pain,dimness of vision,sometimes unconsciousness
First aid: inhalation-remove to fresh air,remove contaminated
clothing-wash body with soap & water.Ingestion-induce
vomiting,eyes-wash with water for at least 15 minutes.Get medical
attention
Hcc: f2
boiling pt: =63.9c, 147.F
vapor pres: 92
vapor density: 1.1
spec gravity: 0.8
solubility in water: complete
appearance and odor: clear,colorless liquid characteristic odor
Stability indicator/materials to avoid: yes
oxidizers,corrosives
stability condition to avoid: keep away from open flame
Waste disposal methods: place absorbed material in container suitable
for shipment to disposal area
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 100%
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: ld50 (oral rat) is 5628 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: inhale: mild intoxication.
toxic effects are exerted on the cns, especially the optic nerve.
eye: liquid and mists will irritate and may burn the eyes. Skin:
irritation, dermatitis, and systemi c changes. Ingest: 100-150 ml.
may be fatal! Lesser amounts- blindness, dizziness, headaches, or
nausea.
explanation of carcinogenicity: none of the chemicals in this product is
listed by iarc, ntp or osha as a carcinogen.
effects of overexposure: see health hazards. Chronic hazards: prolonged
or repeated exposure may result in cns damage, blindness, damage to
pancreas, or death.
medical cond aggravated by exposure: none reported.
First aid: inhalation: remove subject to fresh air. Maintain breathing
and get dr. Eye: flush with plenty of water for 15 minutes. Get
immediate medical attention. Skin: wash with soap and water. Remove
contamin ated clothing. See dr. If irritaion persists. Ingestion:
immediately induce vomiting. Get immediate medical attention.
Hcc: f2
boiling pt: b.P. Text: 148f,64c
melt/freeze pt: m.P/f.P text: -144f,-98c
vapor pres: 96
vapor density: 1.1
spec gravity: 0.79
evaporation rate & reference: >2 (butyl acetate=1)
solubility in water: 100
appearance and odor: colorless liquid, mild alcohol odor
Stability indicator/materials to avoid: yes
strong oxidizing agents, aluminum, zinc, any metal that displaces
hydrogen, certain plastics, rubbers, acids, alkalis.
stability condition to avoid: high temperatures, sparks, and open flames
hazardous decomposition products: carbon dioxide, carbon monoxide,
formaldehyde and unidentified organic compounds in black smoke.
Waste disposal methods: dispose of in accordance with all applicable
federal, state and local laws and regulations. Note: empty
containers can have residues, gases and mists and are subject to
proper waste disposal.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: >99%
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: ld50 (oral rat) is 5628 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: inhale: mild intoxication.
toxic effects are exerted on the cns, especially the optic nerve.
eye: liquid and mists will irritate and may burn the eyes. Skin:
irritation, dermatitis, and systemi c changes. Ingest: 100-150 ml.
may be fatal! Lesser amounts- blindness,dizziness, headaches, or
nausea.
explanation of carcinogenicity: none of the chemicals in this product is
listed by iarc, ntp or osha as a carcinogen.
effects of overexposure: see health hazards. Chronic hazards: prolonged
or repeated exposure may result in cns damage, blindness, damage to
pancreas, or death.
medical cond aggravated by exposure: none reported.
First aid: inhalation: remove subject to fresh air.Maintain breathing
and get dr. Eye: flush with plenty of water for 15 minutes.Get
immediate medical attention. Skin: wash with soap and water. Remove
contaminat ed clothing. See dr. If irritaion persists.
ingestion: immediately induce vomiting. Get immediate medical
attention.
Hcc: f2
boiling pt: b.P. Text: 148f,64c
melt/freeze pt: m.P/f.P text: -144f,-98c
vapor pres: 96
vapor density: 1.1
spec gravity: 0.79
evaporation rate & reference: >2 (butyl acetate=1)
solubility in water: 100
appearance and odor: colorless liquid, mild alcohol odor
Stability indicator/materials to avoid: yes
strong oxidizing agents, aluminum, zinc, any metal that displaces
hydrogen, certain plastics, rubbers, acids, alkalis.
stability condition to avoid: high heat, open flames and other sources
of ignition
hazardous decomposition products: carbon dioxide, carbon monoxide,
formaldehy and unidentified organic compounds in black smoke.
Waste disposal methods: dispose of in accordance with all applicable
federal,state and local laws and regulations. Note: empty
containers can have residues gases and mists and are subject to
proper waste disposal.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 100%
other rec limits: none specified
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: none specified by manufacturer.
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation: 25,000 ppm dangerous to
life and health. Ingestion: headache, tinnitus, anorexia, narcosis,
apathy, dimmed vision, shallow respiration, cerebral and pulmonary
edema, liver and kidney damag e, death due to respiratory failure
or circulatory collapse. Skin: lethal amounts may be absorbed
through intact skin.
explanation of carcinogenicity: none specified by manufacturer.
effects of overexposure: defatting of skin resulting in eczematoid
dermatitis. Eye: irritation, corneal opacity. Ingestion: same
symptoms as inhalation listed in health hazards.
medical cond aggravated by exposure: persons with chronic respiratory,
liver, kidney, eye, or skin diseases.
First aid: inhalation: remove subject to fresh air. Maintain breathing.
get medical help. Eye: flush with copius amounts of water for 15
minutes. Get medical attention. Skin: wash with soap and water.
call a ph ysician. Ingestion: if ingestion is discovered within 2
hours, give syrup of ipecac. Lavage throughly with 2-4 glasses of
tap water with sodium bicarbonate (20g/liter) added. Get medical
attention.
Hcc: f2
boiling pt: b.P. Text: 149f,65c
melt/freeze pt: m.P/f.P text: -137f,-94c
vapor pres: 97.25
vapor density: 1.11
spec gravity: 0.79
evaporation rate & reference: 4.6 (butyl acetate=1)
solubility in water: complete
appearance and odor: clear colorless liquid with a characteristic
alcoholic odor.
Stability indicator/materials to avoid: yes
acetyl bromide, alkylaluminum, aluminum, lead perchlorate, magnesium,
sulfuric acid, zinc.
stability condition to avoid: high temperatures, sparks, and open flames
hazardous decomposition products: toxic oxides of carbon.
Waste disposal methods: dispose of in accordance with all applicable
federal, state and local laws and regulations. Note: empty
containers can have residues. Epa hazardous waste # u154
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 60%
other rec limits: none recommended
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: oral ld50 (rat) is 5628 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: inhalation- irritation of
mucous membranes, and lungs. Eyes- irritation. Skin- irritation.
ingestion- death, cns effects, severe abdominal distress,
blindness. Chronic: kidney damage, liver dam age, blindness.
explanation of carcinogenicity: methanol is not listed by ntp, iarc, or
osha as a carcinogen.
effects of overexposure: inhalation: drowsiness, headach, nausea,
vomiting, chest pain. Eyes: burning sensation, stinging. Skin:
redness, itching. Ingestion: severe stomach cramps, nausea,
vomiting, dizziness, convulsions.
medical cond aggravated by exposure: pre-existing skin or eye problem,
impaired liver or kidney function may be aggravated by exposure.
First aid: inhalation: remove to fresh air. Eyes: flush with lots of
water for 15 minutes, hold lids open. See doctor. Skin: remove
contaminated clothes. Wash with soap and water. Ingestion: rinse
mouth, get imm ediate medical attention. If conscious and medical
attention not readily available, induce vomiting.
Hcc: f3
boiling pt: b.P. Text: 149f,65c
melt/freeze pt: m.P/f.P text: -144f,-98c
vapor pres: 97 mm hg
vapor density: 1.1(air=1)
spec gravity: 0.79 (water=1)
evaporation rate & reference: 5.9 (method unknown)
solubility in water: appreciable
appearance and odor: colorless liquid with alcohol odor
percent volatiles by volume: 99.9
Stability indicator/materials to avoid: yes
strong mineral acids, acid anhydrides, acid chlorides, strong oxidizing
agents, reducing agents, alkali metals.
stability condition to avoid: flames, sparks, and other sources of
ignition. Contact with incompatible materials.
hazardous decomposition products: 0xides of carbon
Waste disposal methods: contact local environmental manager.
manufacturer says incinerate, fuels, blending or recycle. Dispose
of in accordance with local, state and federal regulations. Epa
waste #s u154 d001 applies.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 100%
other rec limits: none recommended
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: ld50 (orl rat): 5628mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute-inhal: harmful & may be fatal.
skin: irritation, dermatitis. Eyes: irritation, may cause temporary
corneal damage. Oral: symptoms similar to inhalation, blindness,
hearing loss. Chronic-kidney & liv er damage.
effects of overexposure: may cause headache, nausea, vomiting,
dizziness, narcosis, respiratory failure, low blood pressure, cns
depression. Skin: irritation, dryness. Eye: irritation & temporary
corneal damage. Oral symptoms are similar to inhalation,
blindness, hearing loss.
medical cond aggravated by exposure: eye, skin, liver or kidney
disorders.
First aid: call a doctor in all cases. Eye/skin: immediately flush with
water for 15 minutes. Hold eyelids open. Inhalation: remove to
fresh air. Provide cpr/oxygen if needed. Ingestion: if conscious,
drink large amount of water. Induce vomiting. Calla
physician/poison control center immediately.
Hcc: f2
boiling pt: =64.C, 147.2f
vapor pres: 96 @ 20c
vapor density: 1.11
spec gravity: 0.79
evaporation rate & reference: 4.6 (n-butyl acetate=1)
solubility in water: complete
appearance and odor: clear, colorless liquid - pungent odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizing agents, strong acids, zinc, aluminum, magnesium
stability condition to avoid: heat, flame, other ignition sources
hazardous decomposition products: carbon monoxide, carbon dioxide,
formaldehyde
Waste disposal methods: dispose in accordance with all applicable local,
state and federal regulations. Epa hazardous waste number is u154
(toxic waste). Rq for methanol is 5000 lbs.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 90- 100%
other rec limits: none specified by m.
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: oral ld50: 9100mg/kg in rats.
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: liq/vap can penetrate skin/mucous
membrane therfore control of inhal may not be sufficient to tpevnet
excessive dose.Harmful if inhal/absorbed thru skin,causes dmg to
liver/kidney/nervous syst.Causes eye/skin/nose/throat irrit.May be
fatal/cause blindness if swallowed.Can't be made non-poisonous.
explanation of carcinogenicity: per msds: listed as carcinogen
in: iarc/ntp/osha: no.
effects of overexposure: acute: non-spec discomft(nau,weak),temp cns
depress w/anethetic
effects(dizz,head,confusion,incoord,unconsc),blindness.Hig
expo: abnor liver/kidney function detected by lab test,fatality from
gross expo .Ingest(as little as 60ml)may cause
blindness,fatality.Skin permeation can occur in amts-produces sys
toxicity.
medical cond aggravated by exposure: individuals w/pre-existing diseases
of retina or liver may have increased susceptibility to toxicity of
excessive exposures.
First aid: eye: flush immed/thoroughly for 15mins w/water.Irrit persists
get med attn.Skin: immed flush w/plenty of water for @least 15mins
while removing contamin cloth/shoes.Call dr.Inhal: immed move to
fresh air .Not breathing give art resp;breathing difficult give
oxy.Call dr.Ingest: as little as 60ml may cause
blindness/fatality.Immed give 2 glasses of water.Induce vomit.Call
dr.Never give anything (supplem)
Hcc: f5
boiling pt: b.P. Text: 148f,65c
melt/freeze pt: m.P/f.P text: -144f,-98c
decomp temp: decomp text: np
vapor pres: 127mm
vapor density: 1.1
spec gravity: 0.791 @20c
ph: np
evaporation rate & reference: >1,butyl acetate=1.0.
solubility in water: 100%,complete.
appearance and odor: liquid, colorless or clear, faint alcoholic.
percent volatiles by volume: np
corrosion rate: np
Stability indicator/materials to avoid: yes
don't store or mix w/strong oxidziers,chronic anhydride,lead
perchlorate,or perchloric acid(rxs vigorously).
stability condition to avoid: keep away from heat/sparks/flame.
hazardous decomposition products: occurs from heat & reaction w/above
stated materials.
Waste disposal methods: rq: 5000lbs/2270kg.Toxic chem under sec 313 title
iii of sara/40cfr372.Cmpd has very low aqu toxicity.Cleaned up matl
may be rcra haz waste.Rcra haz waste #: u154.Comply w/fred/state/loc
regs on dispo.I f approved incineration,bio-oxidation,(other prec)
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara 313) (cercla)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 100%
other rec limits: none recommended
osha pel: s, 200 ppm
acgih tlv: s,200ppm/250stel; 96
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: ld50: (oral,rat) 5628 mg/kg.
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: irrit/narc/neurotoxin. Acute: inhal: may
cause irrit of muc membs, cough, oppression in chest, tracheitis,
bronch, tinnitus, unsteady gait, twitch, colic, constip, nystagmus,
blepharospasm, paresthesias , numb & shooting pains in hands &
forearms, metabolic acidosis & efts on eyes & cns as detailed in
(efts of overexp)
explanation of carcinogenicity: not relevant
effects of overexposure: hlth haz: acute ingest. Skin: may cause irrit.
absorp may cause metabolic acidosis & efts on eyes & cns as
detailed in acute ingest. Eye: vaps may cause irrit. High
concs: violent inflamm of conj & epithe lial defects on cornea.
ingest: may cause mild & transient inebriation & subsequent drow
followed by asymptomatic (ing 8)
medical cond aggravated by exposure: persons w/kidney, eye/skin
disorders are at increased risk from exposure.
First aid: ingest: call md immed . Inhal: remove to fresh air. Support
brthg (give o*2/artf resp) . Eyes: immed flush w/potable water for
at lst 15 mins, seek med attn . Skin: flush w/copious amts of
water. Call md . Antidote: decision as to whether severity of pois
reqs admin of antidote & actual dose reqd should be made by
qualified med pers. Methanol pois: give ethanol, 50% (100 (supdat)
Boiling pt: b.P. Text: 149f,65c
melt/freeze pt: m.P/f.P text: -137f,-94c
vapor pres: 97.25 @20c
vapor density: 1.11
spec gravity: 0.7914
evaporation rate & reference: 4.6 (butyl acetate=1)
solubility in water: very soluble
appearance and odor: clear, colorless liquid w/characteristic alcoholic
odor.
Stability indicator/materials to avoid: yes
aluminum, chlorine, metals, strong oxidizers, sulfuric acids, zinc. For
complete list of matls to avoid cont nehc.
stability condition to avoid: avoid cont w/heat, spks, flames/other
ignit sources. Vaps may be explo. Matl is pois; avoid inhal of
vaps/cont w/skin.
hazardous decomposition products: thermal decomposition products may
include toxic oxides of carbon.
Waste disposal methods: observe all federal, state & local regulations
when disposing of this substance. Disposal must be i/a/w standards
applicable to generators of hazardous waste, 40 cfr 262. Epa
hazardous waste #u154.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methanol; (methyl alcohol) (sara 313) (cercla)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 100%
osha pel: 200 ppm, s
acgih tlv: 200 ppm;250 stel, s
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ingred name: supp data: & has been used effectively as antidote for
methanol or ethylene glycol poisoning.
rtecs #: 9999999zz
ingred name: fire fight proc: matl. Apply cooling water to sides of
cntnrs that are expos to flames well after fire is out. (ing 4)
rtecs #: 9999999zz
ingred name: ing 3: stay away from ends of tanks. W/draw immed if rising
sound from venting sfty device/any discoloration of (ing 5)
rtecs #: 9999999zz
ingred name: ing 4: tank due to fire. Isolate for 1/2 mile in all
directions if tank, rail car/tank truck is involved in fire. (ing
6)
rtecs #: 9999999zz
ingred name: ing 5: exting only if flow can be stopped; use water in
flooding amts as fog, solid streams may not be eftive. (ing 7)
rtecs #: 9999999zz
ingred name: ing 6: cool cntnrs w/flooding qtys of water, apply from as
far dist as poss. Avoid brthg toxic vapors, keep upwind.
rtecs #: 9999999zz
ingred name: efts of overexp: period (8-48 hrs). Following delay, cough,
dysp, hdch, dullness, weak, vertigo/dizz, naus, vomit,(ing 9)
rtecs #: 9999999zz
ingred name: ing 8: occas diarr, anorexia, violent pain in back, abdom &
extrems, restlessness, apathy/delirium, & rarely (ing 10)
rtecs #: 9999999zz
ingred name: ing 9: excitement & mania. Rapid, shallow resp due to
metabolic acidosis, cold & clammy skin, hypotension, (ing 11)
rtecs #: 9999999zz
ingred name: ing 10: cyanosis, opisthotonos, convls, mild tachycardia,
card depress, peripheral neuritis, cerebral & pulm (ing 12)
rtecs #: 9999999zz
ingred name: ing 11: edema, uncon & coma poss. Efts on eye incl optic
neuritis, blurred/dimmed vision, dilated, unresponsive (ing 13)
rtecs #: 9999999zz
ingred name: ing 12: pupils, ptosis, pain, concentric constriction of
visual fields, diplopia, change in color perception, (ing 14)
rtecs #: 9999999zz
ingred name: ing 13: photophobia, optic nerve atrophy, partial
blindness/poss delayed transient/perm blindness. Bilateral (ing 15)
rtecs #: 9999999zz
ingred name: ing 14: sensorineural deafness. Liver, kidney, heart, stom,
intest & pancreatic dmg. Death may be due to resp (ing 16)
rtecs #: 9999999zz
ingred name: ing 15: failure/rarely from circulatory collapse. 15 ml
caused blindness; 60-240 ml-fatal dose. Prlng asthenia & (ing 17)
rtecs #: 9999999zz
ingred name: ing 16: irreversible efts on nerv sys incl dfclty in speech,
motor dysfunc w/rigidity, spasticity & hypokinesis. (ing 18)
rtecs #: 9999999zz
ingred name: ing 17: chronic: inhal: efts as in acute ingest. 200-375 ppm
caused recurrent hdchs in workers. 1200-8000 ppm for 4(ing 19)
rtecs #: 9999999zz
ingred name: ing 18: yrs - rsltd in marked diminution of vision &
enlargement of liver in workers. Animals: repro efts. Skin: (ing 20)
rtecs #: 9999999zz
ingred name: ing 19: defat rsltg in erythema, scaling & eczematoid derm.
absorption - metabolic acidosis & efts as detailed in(ing 21)
rtecs #: 9999999zz
ingred name: ing 20: acute ingest. Eye: conj. Ingest: visual impairment &
blindness & other systemic efts as detailed in acute (ing 22)
rtecs #: 9999999zz
ingred name: ing 21: ingestion. Animals: reproductive effects. Target
effects: central nervous system depressant; neurotoxin.
rtecs #: 9999999zz
ingred name: resp prot: mode. 10,000 ppm-any scba w/full facepiece; any
supplied-air resp w/full facepiece; any supplied-air (ing 24)
rtecs #: 9999999zz
ingred name: ing 23: resp that has tight-fitting facepiece & is operated
in continuous-flow mode. 25,000 ppm-any supplied-air (ing 25)
rtecs #: 9999999zz
ingred name: ing 24: resp w/full facepiece & operated in
press-demand/other pos press mode. Escape-any approp escape-type,
scba.
rtecs #: 9999999zz
Ld50 lc50 mixture: ld50 (oral, rat) = 5,628 mg/kg
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eyes: may cause moderate irritation
and painful sensitization to light. Skin: may cause irritaion. May
be absorbed through skin in harmful amounts. Ingestion: may cause
irritation of digestive tract a nd respiratory failure. May cause
vascular collapse, damage and kidney failure. Inhalation: may cause
respiratory irritation, liver and kidney damage. May cause adverse
cns effects including headache, convulsions, and possible death.
may cause visual impairment, possible permanent blindness. Chronic:
may cause dermatitis. Chronic inhalation and ingestion may cause
effects similar to those of acute inhalation and ingestion.
explanation of carcinogenicity: none
effects of overexposure: eyes: may cause moderate irritation and painful
sensitization to light. Skin: may cause irritaion. Ingestion: may
cause irritation of digestive tract and respiratory failure. May
cause vascular collap se, damage and kidney failure. Inhalation:
may cause respiratory irritation, liver and kidney damage. May
cause adverse cns effects including headache, convulsions, and
possible death. May cause visua l impairment, possible permanent
blindness.
medical cond aggravated by exposure: not provided
First aid: eyes: flush with water for at least 15 minutes, occasionally
lifting upper and lower lids. Get medical aid immediately. Do not
allow victim to rub/keep eyes closed. Skin: flush with plenty of
soap and water while removing contaminated clothing and shoes. Get
medical aid if irritaion develops/persists. Ingestion: if victim is
conscious and alert, give 2-4 cupfuls of milk/water. Get medical
aid imme diately. Induce vomiting by giving 1 teaspoon of syrup of
ipecac. Inhalation: get medical aid immediately. Remove from
exposure to fresh air immediately. If not breathing, give
artificial respiration. if breathing is difficult, give oxygen.
Hcc: f5
nrc/state lic num: not relevant
boiling pt: =64.8c, 148.6f
melt/freeze pt: =-98.C, -144.4f
decomp temp: decomp text: not available
vapor pres: 29 mm hg (20c/68f)
vapor density: 1.1
spec gravity: 0.7910q/cm3
viscosity: 0.006 p at 68f
evaporation rate & reference: none known
solubility in water: misicible with water
appearance and odor: clear colorless liquid, slight alcohol-like odor
percent volatiles by volume: 99-100
corrosion rate: not provided
Stability indicator/materials to avoid: yes
oxidants (such as baium perchlorate, bromine, chlorine, hydrogen
peroxide, lead perchlorate, perchloric acid, sodium hypochlorite).
active metals (potassium and magnesium). See nfpa fire protection
guide.
stability condition to avoid: high temperatures, incompatible materials,
ignition sources.
hazardous decomposition products: carbon monoxide, carbon dioxide,
formaldehyde.
Waste disposal methods: dispose of in a manner consistent with local,
state and federal regulations. Rcra u-series: waste number u154
(ignitable waste). This material is banned from land disposal
according to rcra.
Ingred name: methyl alcohol
cas: 67-56-1
rtecs #: pc1400000
minumum % wt: 99.
maxumum % wt: 100.
other rec limits: 200 ppm (niosh)
osha pel: 260 mg/m3;200 ppm
acgih tlv: 262 mg/m3;200 ppm
acgih stel: 328 mg/m3;250 ppm
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute- eyes: mild irritation. Direct
contact with liquid, conjunctivitis & corneal burns may occur. Main
toxic effect is exerted upon the nervous system, particularly optic
nerves & possibly the retin a can progress to permanent blindness.
skin: upon prolonged repeated exposure, absorption may occur &
produce toxic effects similar to those of inhalation. respiratory
system: may cause dizziness, dr owsiness, headache or nausea.
massive overexposure may cause unconsciousness. chronic- repeated
skin contact may cause persistent irritation or dermatitis.
explanation of carcinogenicity: this product is not currently listed as
a carcinogen by ntp, osha, or iarc.
effects of overexposure: headache, dizziness, drowsiness, nausea,
unconsciousness, and coma.
First aid: eyes: flush thoroughly w/ water for at least 15 mins. skin:
wash exposed area w/ soap & water. Remove & clean contaminated
clothing. ingestion: call a doctor immediately. If person is
conscious, imm ediately give 2 glasses of water & induce vomiting.
do not make an unconscious person vomit. Never give anything by
mouth to an unconscious or convulsing person. Inhalation: remove to
fresh air. If no t breathing, give mouth-to-mouth artificial
respiration. If breathing is difficult, qualified personnel may
administer oxygen. Get medical attention for all modes of exposure.
Hcc: f5
boiling pt: =64.4c, 148.F
vapor pres: (mm hg): 96 @ 68f (20c)
vapor density: 1.11
spec gravity: 0.796 @ 60f(15.6c)
ph: 7.2
viscosity: no information found
evaporation rate & reference: no information found
solubility in water: infinite
appearance and odor: colorless, characteristic odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizers, strong acids
stability condition to avoid: heat
hazardous decomposition products: carbon monoxide and carbon dioxide may
be formed on burning.
conditions to avoid polymerization: does not occur.
Waste disposal methods: incinerate or place in rcra permitted waste
management facility.
Ingred name: methanol
cas: 67-56-1
rtecs #: pc1400000
= wt: 99.9
osha pel: 260 mg/m3;200 ppm
acgih tlv: 262 mg/m3;200 ppm
acgih stel: 328 mg/m3;250 ppm
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs