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Sulfuric acid and oleum
Sulfuric acid; oleum
Chemicals-inorganic
Y - Indicates information is in the hazardous materials information resource system (hmirs).
PMICA - Item does not contain precious metal.
CRITL- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.
043940 - Chemicals noi
450 - Acids, liquid, corrosive
9 - Other or no special handling required (sh)
A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.
C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp
W - Rating variable
W - Corrosive materials, un class 8 (corrosive label)
Questions & Answers: |
|
| What are the historical prices recorded for this stock number? | |
| Historical data shows pricing from $333.32 to $555.53.. | |
| Does NSN 6810-00-823-8007 have a shelf life? | |
| No. There is no shelf life applicable for this NSN. | |
| What NATO entities are users of this NSN? | |
| Department Of The Army, Department Of The Air Force, U.s. Marine Corps, Department Of The Navy, U.s. Coast Guard, National Aeronautics and Space Administration, Brazil, Spain, Republic Of Korea, Philippines, Greece, and Turkey | |
| What is the NIIN of NSN 6810-00-823-8007? | |
| 008238007 or 00-823-8007 | |
| Does NSN 6810-00-823-8007 require demilitarization? | |
| Yes - ITAR Controlled | |
| What is the most recent solicitation for NSN 6810-00-823-8007? | |
| No solicitations for this NSN. | |
| When was this national stock number assigned to the federal catalog? | |
| Jan 01, 1963 | |
Ld50 lc50 mixture: ld50 oral rat = 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: **corrosive** eyes: may cause
irritation or burns.Skin: may cause irritation or burns.Ingest: may
cause gi tract irritation.Inhal: may cause respiratory
irritation.Chronic: may damage kidneys and cause too th erosion.
explanation of carcinogenicity: sulfuric acid mists are classified
iarc-2b
effects of overexposure: causes severe burns to eyes, skin, and mucousa.
can be fatal if ingested. Respiratory irritation if inhaled.
medical cond aggravated by exposure: persons with pre-existing
respiratory ailments may be at increased risk from exposure.
First aid: eyes and skin: flush with water. See doctor immediately.
remove contaminated clothing and shoes. Inhalation: remove to fresh
air. Give cpr/oxygen if needed. See doctor. Ingestion: give milk or
water, followed by 2 ounces of milk of magnesia or water (no
carbonates). See doctor immediately.
Hcc: c1
boiling pt: b.P. Text: 590f,310c
spec gravity: 1.400
solubility in water: complete
appearance and odor: colorless to slight yellow, clear to turbid, oily
liquid.
Stability indicator/materials to avoid: yes
nitro compounds, carbides, dienes, alcohols, oxidizing agents, allyl
compounds, aldehydes, alkalies, amines,
stability condition to avoid: temperature over 572f(300c), moisture
hazardous decomposition products: sulfur trioxide, sulfur dioxide,
hydrogen sulfide, hydrogen gas
Waste disposal methods: disposal is subject to federal, state, and local
regulations. Users should review their operations for compliance,
then consult with the appropriate regulatory agencies before
discharging or disposing of material.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 50%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 50%
Ld50 lc50 mixture: oral ld50 (rat) is 2140mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: **corrosive** eyes: may cause
irritation or burns.Skin: may cause irritation or burns.Ingest: may
cause gi tract irritation.Inhal: may cause respiratory
irritation.Chronic: may damage kidneys and cause too th erosion.
explanation of carcinogenicity: sulfuric acid mists are cleassified
iarc-2b.
effects of overexposure: may injure lungs. Swallowing may cause severe
injury or death. Contact with skin and eyes causes severe burns.
medical cond aggravated by exposure: persons with pre-existing
respiratory ailments may be at increased risk from exposure.
First aid: **get prompt medical attention** eyes and skin: wash with
large amounts of water for at least 15 minutes. Do not use oils or
ointments in eyes. Treat skin burns. Inhalation: observe victim for
delayed pulmonary reaction. Ingestion: have victim drink water. Do
not induce vomiting.
Hcc: c1
boiling pt: b.P. Text: 250f,121c
vapor pres: 0.2
spec gravity: 1.4
solubility in water: complete
appearance and odor: oily, colorless, odorless liquid.
percent volatiles by volume: 50.0
Stability indicator/materials to avoid: yes
metals, alkalies, combustibles, carbides, chlorates, nitrates,
fulminates
stability condition to avoid: high heat, moisture
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: add slowly to a large amount of solution of soda
ash and slaked lime by stirring. Discharge into an approved
disposal area.Dispose of in accordance with federal,state and local
regulations.Rcra code i s d002(corrosive).
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 50.0%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: oral ld50 (rat) is 2140mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: **corrosive** eyes: may cause
irritation or burns.Skin: may cause irritation or burns.Ingest: may
cause gi tract irritation.Inhal: may cause respiratory
irritation.Chronic: may damage kidneys.May erode too th enamel.
explanation of carcinogenicity: sulfuric acid mists are classified
iarc-2b.
effects of overexposure: severe burns to skin or eyes. Inhalation of
mist from hot sulfuric acid can be injurious to lungs.
medical cond aggravated by exposure: persons with pre-existing
respiratory ailments may be at increased risk from exposure.
First aid: irrigate eyes with water for at least 15 minutes. For eyes or
skin burns, get immediate medical attention. Wash contaminated
areas of body with soap and water. Stomach wash, if swallowed.
inhalation: oxygen with use of intermittent positive pressure
breathing apparatus.
Hcc: c1
boiling pt: b.P. Text: 625f,329c
vapor pres: 0
spec gravity: 1.4042
evaporation rate & reference: < 1 (ether = 1)
solubility in water: complete
appearance and odor: slightly viscous, clear to slightly cloudy liquid.
Stability indicator/materials to avoid: yes
carbides, chlorates, fulminates, nitrates, picrates, powdered metals
stability condition to avoid: high heat, moisture
hazardous decomposition products: sulfur trioxide, sulfur dioxide,
hydrogen sulfide, hydrogen gas
Waste disposal methods: neutralize acid with large amounts of water,
soda ash and slaked lime. Store in approved storage container for
corrosive liquids. Dispose of in accordance with federal,ststae and
local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 50.0%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: oral ld50 (rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: **corrosive** eyes: may cause
irritation or burns.Skin: may cause irritation or burns.Ingest: may
cause gi tract irritation.Inhal: may cause respiratory
irritation.Chronic: may cause kidney damage and eros ion of tooth
enamel.
explanation of carcinogenicity: sulfuric acid mists are classified
iarc-2b.
effects of overexposure: severe burns to skin or eyes. Inhalation of
mists from hot sulfuric acid can be injurious to lungs.
medical cond aggravated by exposure: persons with pre-existing
respiratory ailments may be at increased risk from exposure.
First aid: eyes: irrigate with water for at least 15 minutes. Get
immediate medical attention. Skin: wash contaminated areas of body
with soap and water. Get immediate medical attention. Ingestion:
stomach wash. inhalation: oxygen with use of intermittent positive
pressure breathing apparatus
Hcc: c1
boiling pt: b.P. Text: 203f,95c
vapor pres: 10
vapor density: 1.0
spec gravity: 1.399
solubility in water: complete
appearance and odor: clear liquid with a sharp acid like odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
carbides, chlorates, fulminates, nitrates, picrates, powdered metals
stability condition to avoid: high heat, moisture
hazardous decomposition products: sulfur trioxide, sulfur dioxide,
hydrogen sulfide, hydrogen gas
Waste disposal methods: neutralize acid with large amount of water, soda
ash and slaked lime by stirring. Store in approved storage
containers for corrosive liquids.Dispose of in accordance with
federal,state and local regul ations.Rcra code is d002(corrosive).
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 50.0%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: oral ld50 (rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: 88corrosive** eyes: may cause
irritation and burns.Skin: may cause irritation and burns.Ingest: may
cause gi tract irritation.Inhal: may cause respiratory
irritation.Chronic: may damage kidney and cause to oth enamel
erosion.
explanation of carcinogenicity: sulfuric acid mists are classified
iarc-2b.
effects of overexposure: corrosive to all body tissue. Can cause severe
acid burns. Inhalation and ingestion of fumes of sulfur trioxide -
lung damage.
medical cond aggravated by exposure: persons with pre-existing
respiratory ailments may be at increased risk from exposure.
First aid: eyes and skin: flush with copious amounts of water.
inhalation: get fresh air. See aphysician. Ingestion: see
physician. Administer copious amounts of water, milk, and egg
whites before arrival of the physician. Do not induce vomiting.
Hcc: c1
boiling pt: b.P. Text: 640f(decomp
vapor density: 2.8
spec gravity: 1.40
solubility in water: appreciable
appearance and odor: clear colorless, syrupy liquid. Odorless.
Stability indicator/materials to avoid: yes
water, carbides, chlorates, fulminates, nitrates, picrates, powdered
metals
stability condition to avoid: high heat, moisture
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: add very slowly to large volume of agitated
solution of soda ash and slaked lime. Add neutralized solution to
excess running water. Dispose of in accordance with federal,ststae
and local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 50.0%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: oral ld50 (rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: **corrosive** eyes: may cause
irritation and burns.Skin: may cause irritation and burns.Ingest: may
cause gi tract irritation.Inhal: may cause respiratory
irritation.Chronic: may damage kidneys and cause e rosion of tooth
enamel.
explanation of carcinogenicity: sulfuric acid mists are classified
iarc-2b.
effects of overexposure: skin: severe burns. Damages tissues. Eyes:
burns, damages cornea, blindness. Ingestion: gastrointestinal tract
perforation, diarrhea.
medical cond aggravated by exposure: persons with pre-existing
respiratory ailments may be at increased risk from exposure.
First aid: inhalation: remove to fresh air. If not breathing give cpr.
if breathing is difficult give oxygen. Eye: immediately flush with
plenty of water. Skin: wash with soap and water. Remove
contaminated clot hing and shoes. Ingestion: do not induce
vomiting. Nothing by mouth if unconscious. Get medical attention.
Hcc: c1
solubility in water: complete
appearance and odor: clear, colorless to cloudy liquid. No odor.
percent volatiles by volume: 96%
Stability indicator/materials to avoid: yes
strong oxidizing agents
stability condition to avoid: avoid elevated tempatures, moisture
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: keep in covered drums, pending disposal. Handle
and dispose of in full compliance with all applicable
international, federal, state, and local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 50.0%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water; cas #7732-18-5
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt:
Ld50 lc50 mixture: oral ld50 (rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: acute: corrosive to all body tissues.
severe burns or redness to eyes and skin. Irritation to mucous
membranes, respiratory, and gastrointestinal tract. Ingestion may
be fatal. Chronic: severe irritat ion, dermatitis.
explanation of carcinogenicity: sulfuric acid mists are classified
iarc-2b.
effects of overexposure: inhalation: can damage lung tissue, loss of
consciousness. Skin: can cause severe burns. Eyes: burns.
medical cond aggravated by exposure: persons with pre-existing
respiratory ailments may be at increased risk from exposure.
First aid: skin: remove contaminated clothing. Use large amounts of
water or deluge-type shower. Get immediate medical aid. Eyes: flood
with copious amounts of water and get immediate medical aid. Speed
is of th e utmost importance.
Hcc: c1
boiling pt: b.P. Text: 535f,279c
vapor pres: < 0.5
spec gravity: 1.83
ph: < 2
evaporation rate & reference: < 1.0 (butyl acetate = 1)
solubility in water: complete
appearance and odor: off white to straw colored liquid.
percent volatiles by volume: 57.0
Stability indicator/materials to avoid: yes
organic materials, combustibles, chlorates, nitrates, powderes metals.
stability condition to avoid: high heat, moisture
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: avoid contact with sulfur wastes(in sewers).Add
slowly to a solution of soda ash and slaked lime;stir;discharge the
solution with a large amount of water into an approved disposal
area.Dispose of in a ccordance with federal,state amd local regs.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 50.0%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
Ld50 lc50 mixture: oral ld50 (rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: **corrosive** eyes: may cause
irritation and burn.Skin: may cause irritation and burns.Ingest: may
cause gi tract irritation.Inhal: may cause respiratory
irritation.Chronic: may damage kidneys and cause er osion of tooth
enamel.
explanation of carcinogenicity: sulfuric acid mists are classified
iarc-2b.
effects of overexposure: severe burns to eyes and skin, respiratory
irritation.
medical cond aggravated by exposure: persons with pre-existing
respiratory ailments may be at increased risk from exposure.
First aid: eyes: flush with copious amounts of water. Skin: wash with
soap and water. Inhalation: remove to fresh air. Give artficial
respiration if needed. Skin: remove contaminated clothing.
ingestion: give la rge amounts of water, then milk with egg whites.
do not induce vomiting. See a doctor immediately.
Hcc: c1
boiling pt: b.P. Text: 234f,112c
vapor pres: 11
spec gravity: 1.2809
evaporation rate & reference: < 1 (butyl acetate = 1)
solubility in water: complete
appearance and odor: clean, colorless liquid. No odor.
percent volatiles by volume: 0
Stability indicator/materials to avoid: yes
most metals, particularly powdered metals because of the generation of
hydrogen gas.
stability condition to avoid: high heat, moisture
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: dispose of in accordance with local, state, and
federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 37%.
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water,cas#7732-18-5
cas: 7732-18-5
rtecs #: zc0110000
Ld50 lc50 mixture: ld50 (oral rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: acute: inhalation of vapors may cause
severe irritation or burns of the respiratory system, pulmonary
edema, or lung inflammation. May cause severe burns to skin or
eyes. Ingestion may cause severe bu rns to mouth, throat, and
stomach. May affect kidney function. Chronic: may damage lungs.
explanation of carcinogenicity: sulfuric acid mists as classified
iarc-2b.
effects of overexposure: severe irritation or burns to eyes, nose and
throat. Pulmonary edema, bronchial emphysema, conjunctivitis,
stomatitis, dental erosion, nausea and vomiting.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the respiratory tract may
be at increased risk from exposure.
First aid: inhalation: remove to fresh air. Resuscitate if not
breathing. Get medical attention. Eyes: immediately flush with
water for at least 15 minutes holding eyelids open. Get medical
attention. Skin: remo ve contaminated clothing. Wash with water for
at least 15 minutes. Get medical advice. Ingestion: do not induce
vomiting. Give nothing by mouth if unconscious. Get immediate
medical attention.
Hcc: c1
ph: < 1
evaporation rate & reference: < 1 (butyl acetate = 1)
solubility in water: complete
appearance and odor: oily, clear to turbid, colorless to light gray
liquid. Odorless.
Stability indicator/materials to avoid: yes
strong oxidizing agents
stability condition to avoid: high temperatures, sparks, and open flames
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state, and local environmental regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 50%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: oral ld50 (rat) is 2140mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: acute: eyes: severe burns, corneal
damage and blindness. Skin: severe irritation, burns and
ulceration. Inhalation: severe respiratory irritation, inflammation
of broncheal membranes. Ingestion: sever e burns and ulceration of
mouth, throat, esophagus, and stomach, kidney and intestinal
damage. Chronic: see supplemental
explanation of carcinogenicity: sulfuric acid mists are classified iarc
2b.
effects of overexposure: coughing, increased respiratory rate and
impaired ventilary capacity. Stinging and burning sensation to the
skin. Irritation and damage to the eyes. Discoloration of the
teeth.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the respiratory tract may
be at increased risk from exposure.
First aid: inhalation: remove to fresh air. Resuscitate if not
breathing. Get medical attention. Eyes: immediately flush with
water for at least 15 minutes holding eyelids open. Get medical
attention. Skin: remo ve contaminated clothing. Wash with water for
at least 15 minutes. Get medical advice. Ingestion: do not induce
vomiting. Give nothing by mouth if unconscious. Get immediate
medical attention.
Hcc: c1
boiling pt: b.P. Text: 237f,114c
melt/freeze pt: m.P/f.P text: -94f,-70c
vapor pres: 9.95
vapor density: > 1
spec gravity: 1.28
evaporation rate & reference: < 1 (ether = 1)
solubility in water: complete
appearance and odor: colorless gel with a sharp, penetrating, pungent
odor.
percent volatiles by volume: 0
Stability indicator/materials to avoid: yes
strong oxidizing agents, hydrogen peroxide, many metals and non-metals.
stability condition to avoid: moisture, high heat
hazardous decomposition products: hydrogen gas, hydrogen sulfide, oxides
of sulfur
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state, and local environmental regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 39.1%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: ld50 (oral rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: chronic: inhalation of vapors may
cause severe irritation or burns of the respiratory system,
pulmonary edema, or lung inflammation. May cause severe burns to
skin or eyes. Ingestion may cause severe burns to mouth, throat,
and stomach. May affect kidney function. Chronic: may damage lungs.
explanation of carcinogenicity: sulfuric acid mists are classified
iarc-2b.
effects of overexposure: severe irritation or burns to eyes, nose and
throat. Pulmonary edema, bronical emphysema, conjunctivitis,
stomatitis, dental erosion, nausea and vomiting.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the respiratory tract may
be at increased risk from exposure.
First aid: inhalation: remove to fresh air. Resuscitate if not
breathing. Get medical attention. Eyes: immediately flush with
water for at least 15 minutes holding eyelids open. Get medical
attention. Skin: remo ve contaminated clothing. Wash with water for
at least 15 minutes. Get medical advice. Ingestion: do not induce
vomiting. Give nothing by mouth if unconscious. Get immediate
medical attention.
Hcc: c1
boiling pt: b.P. Text: 535f,279c
vapor pres: < 0.5
spec gravity: 1.8354
evaporation rate & reference: 1.0 (n-butyl acetate = 1)
solubility in water: complete
appearance and odor: clear to slightly turbid liquid. Usually odorless.
Stability indicator/materials to avoid: yes
alkaline materials, combustible and organic materials.
stability condition to avoid: high temperatures, moisture
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state, and local environmental regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 60-100%
other rec limits: none specified
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt:
other rec limits: none specified
Ld50 lc50 mixture: ld50 (oral rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: acute - inhalation: severe irritation
and burns of the respiratory system, pulmonary edema, lung
inflammation. Skin and eyes: severe burns. Ingestion: severe burns
to mouth, throat, and stomach. May a ffect kidney function.
chronic: erosionof teeth, skin lesions, bronchitis.
explanation of carcinogenicity: sulfuric acid mists are classified
iarc-2b.
effects of overexposure: severe irritation or burns to eyes, nose and
throat. Pulmonary edema, bronical emphysema, conjunctivitis,
stomatitis, dental erosion, nausea and vomiting.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the respiratory tract may
be at increased risk from exposure.
First aid: inhalation: remove to fresh air. Resuscitate if not
breathing. Get medical attention. Eyes: immediately flush with
plenty of water for 15 minutes holding eyelids open. Get medical
attention. Skin: rem ove contaminated clothing. Wash with plenty of
water for 15 minutes. Get medical advice. Ingestion: do not induce
vomiting. Give nothing by mouth if unconscious. Get immediate
medical attention.
Hcc: c1
boiling pt: b.P. Text: 193f,89c
vapor pres: < 0.5
spec gravity: 1.42
ph: 0.9
solubility in water: complete
appearance and odor: clear to slightly yellow liquid with a sharp acid
odor.
Stability indicator/materials to avoid: yes
alkaline materials, combustible and organic materials, nitro compounds,
carbides, and oxidizing agents.
stability condition to avoid: high temperatures, moisture
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state, and local environmental regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 50%
other rec limits: none specified
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 50%
other rec limits: none specified
Ld50 lc50 mixture: oral ld50 (rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: third degree burns. Severe
respiratory, skin, and eye irritant. Bronchitis, laryngeal and
pulmonary edema may result.
explanation of carcinogenicity: sulfuric acid mists are classified
iarc-2b.
effects of overexposure: prickling or burning sensation of skin and
mucous membranes. Coughing, sneezing, tightness of chest,
difficulty in breathing.
medical cond aggravated by exposure: any pre-existing respiratory
disease, for example emphysema.
First aid: inhalation: remove to fresh air. Give mouth- to-mouth
resuscitation if not breathing. Give oxygen if breathing is
difficult. Get medical attention. Eyes: flush with running water
for 15 minutes while holding eyelid. Get medical attention. Skin:
wash with plenty of soap and water. Remove contaminated clothing.
get medical attention. Ingested: do not induce vomiting. Get
medical attention immediatel
Hcc: c1
boiling pt: b.P. Text: 260f,127c
vapor pres: < 1
vapor density: 3.4 (air=1
spec gravity: 1.400 (water=1)
ph: < 1
solubility in water: complete
appearance and odor: clear, colorless liquid.
percent volatiles by volume: unk.
Stability indicator/materials to avoid: yes
metals, organics, nitrates, carbides, chlorates, allyl compounds, and
aldehydes
stability condition to avoid: contact with metals, organics.
hazardous decomposition products: sulfur dioxide, sulfur trioxide,
hydrogen sulfide, hydrogen gas
Waste disposal methods: neutralize with lime or soda ash. Consult
regulations. Epa hazardous waste d0002- corrosive and
d0003-reactive if discarded without prior neutralization.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara 302/313) (cercla)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 48-50%
other rec limits: none specified
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3/3 stel; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 50-52%
other rec limits: none specified
Ld50 lc50 mixture: ld50,oral,rat= 2140mg/kg.
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: direct contact w/matl may cause severe
eye/ skin irrit.Corr to skin/eyes.Conc acid corr to nose/mucous
membranes/resp & gi tracts.Vap/mist inhal cause pulm
edema,emphysema,perm changes in pulm functio n.Chronic: derm,chronic
bronchitis,gastritis,dental enamel errosion, conj,increased
frequency of resp tract infections(su
explanation of carcinogenicity: sulfuric acid mists are classified
iarc-2b.
effects of overexposure: severe eye/skin irrit. Corrosive to nose/
mucous membranes/resp & gi tracts. Pulmonary edema, emphysema, perm
changes in pulmonary function. Derm, chronic bronchitis, gastritis,
dental enamel errosion , conjunctivitis, increased frequrency of
resp tract infections & cancer of larynx, lungs & upper resp tract.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: skin: remove contamin cloth w/o delay. Cleanse skin thoroughly
w/soap & water including hair & under fingernails if contaminated.
eye: immed irrigate w/plenty of water for 15mns. Obtain med attn w/o
del ay. Inhal: remove from exposure. Administer oxy if difficulty in
breathing. Give art resp if not breathing & cont til normal
breathing is established. Obtain med attn w/o delay.
Hcc: c1
boiling pt: b.P. Text: 640f,338c
melt/freeze pt: m.P/f.P text: 37f,98%acid
vapor pres: supplement
spec gravity: 1.4-1.8
ph: supple
evaporation rate & reference: not available
solubility in water: complete
appearance and odor: clear to slightly cloudy, oily liquid; odorless to
slightly pungent odor.
percent volatiles by volume: 0-20
Stability indicator/materials to avoid: yes
water,many metals,strong alkali;carbides,chlorates,
fulminates,nitrates,picrates.Org matls(org
acids,acetates,anhydrides
stability condition to avoid: none known.
hazardous decomposition products: therm decomp/combust may proudce
sulfur trioxide &/or sulfur dioxide.Toxic/explo hydrogen sulfide
form under conditions.
Waste disposal methods: disposal must be made in accordance with
applicable governmental regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 80-100%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: rat,lc50: 510mg/m3/2h;ld50: 2140mg/kgrtecs
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eye, skin, respiratory &
gi tracts. Acute- corrosive! Causes severe eyes & skin burns. Mist
is extremely irritating to respiratory tract. Contact with eyes may
result in blindness. Swall owing may be fatal. Inhalation may
damage respiratory tract. Chronic- may cause dental erosion,
dermatitis, bronchitis.
explanation of carcinogenicity: none
effects of overexposure: severe irritation and burning, visual
impairment, dental erosion, cough, possible charring of skin, pain,
blindness
medical cond aggravated by exposure: open wounds and sores, respiratory
ailments such as emphysemia and bronchitis
First aid: get medical attention immediately. Eye/skin: immediately
flush with water for 15-20 minutes. Hold eyelids open. Continue
rinsing with normal saline until ph=7. Inhaled: remove to fresh air.
provide oxy gen/cpr if needed. Oral: do not induce vomiting. If
conscious, drink large amount of water/milk. Ingested acid must be
diluted about 100 folds. If vomiting occurs, keep head below hips.
Hcc: c1
nrc/state lic num: not relevant
boiling pt: b.P. Text: 640f,338c
vapor pres: variable
spec gravity: 1.3945 - 1.4042
ph: 1.0
solubility in water: soluble
appearance and odor: clear liquid - practically odorless
Stability indicator/materials to avoid: yes
acetaldehyde, alcohols, strong bases, chlorates, nitrates, carbides,
most metals, organic materials, water, picrates
stability condition to avoid: adding water to acid (always add acid
slowly to water)
hazardous decomposition products: toxic oxides of sulfur
Waste disposal methods: dispose of spilled, neutralized, or waste
product, contaminated soil, and other materials in accordance with
all local, state, and federal regulations. Epa hazardous waste
number d002. Reportable quan tity (rq): 1000 lbs. Do not flush acid
to sewer.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara 302/313) (cercla)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 50-51%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3/3 stel; 9495
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
other rec limits: none recommended
osha pel: not relevant
acgih tlv: not relevant
Ld50 lc50 mixture: ld50 sulfuric acid 2140mg/kg (rat,oral)
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: acute: fume/mist inhal can cause
irrit/corro burns to upper resp syst.Lung irrit/pulm edema can
occur.Ingest can cause irrit/corro burns to
throat/mouth/stomach.Can be fatal if ingest.Causes severe bur
ns/irrit on skin contact.Liq contact w/eye can cause irrit,corneal
burns,blindness.Mist contact may irrit/burn.Chronic: long term expo
to hi levels of acid fumes may cause erosion of teeth followed by
jaw necrosis,bronchial irrit,cough,bronchial pneumonia,gi
disturbances.
explanation of carcinogenicity: iarc has classified "strong inorganic
acid mists containing sulfuric acid"as carcinogenic to humans.This
classification does not apply to sulfuric acid or sulfuric acid
solutions.Warning: this product cntains a chemcal known to state of
california to cause cancer.
effects of overexposure: inhal fumes/mists cn cause irrit/corro burns to
upper resp syst.Lung irrit/pulm edema can occur.Ingest can cause
irrit/corro burns to throat/mouth/stomach.Can be fatal if
swallowed.Causes wevere burns /irrit on skin contact.Liq contact
w/eye can cause irrit,corneal burns,blindness.Mist contact may
irrit/burn.Long term expo to hi levels of acid fumes may cause
erosion of teeth followed by jaw necros is,bronchial irrit, cough,
bronchial pneumonia or gastrointestinal disturbances.
medical cond aggravated by exposure: acute and chronic respiratory
diseases.
First aid: inhal: remove from exposure.Place individual under care of
physician.Ingst: drink large amts of water(or milk if available)to
dilute acid.Dont induce vomit.Skin/eye: immed flush w/plenty of wate
for @lea st 15mins.Remove contam clothing.Get prompt med attn.
Hcc: c1
boiling pt: b.P. Text: 276-281c
melt/freeze pt: m.P/f.P text: 93.19%@-29c;98%@-1c
vapor pres: 90%@20c=.005;95%@35=.0015
vapor density: not applic
spec gravity: h20=1 1.835-1.844
ph: 1% solution=0.9
solubility in water: complete
appearance and odor: oily, colorless to slight yellow, clear to turbid
liquid. Odor -1mg/cu
Stability indicator/materials to avoid: yes
not flamm but highly reactive,capable of ign finely divided combust
matls on contact.Rxs violently w/h2o & org matls w/evolution of
heat.Extemely haz in contact w/many matls, particularly
carbides,chlorates,fulminates,nitra
hazardous decomposition products: sulfur trioxide mists
Waste disposal methods: must comply w/fed/state/loc dispo/discharge
laws.If haz under 40cfr261 subparts b&c matl must be treated/disp
in facil meeting reqmts 40cfr264/265.If nonhaz, matl should be
dispo in facil meeting reqm ts 40cfr257.Epa haz waste: d002-corro.If
discarded in unalter form,matl should be tested to determine if
its classified as haz waste for(see other)
Ingred name: sulfuric acid
cas: 7664-93-9
rtecs #: ws5600000
minumum % wt: 93.
maxumum % wt: 99.
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3
acgih stel: 3 mg/m3
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: oral ld50 (rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: eyes: will cause severe irritation and
burns to the eyes.Skin: will cause severe irritation and
burns.Inhalation: will cause irritation and possibly burns to the
nose,throat and upper respiratory tract.A lso may cause shortness
of breath and wheezing.May cause chronic dental
erosion.Ingestion: will cause nausea, vomiting,pain, irritation and
burns to the mouth, throat and lower h.I.Tract.
explanation of carcinogenicity: sulfuric acid mists are classified
iarc-2b.This product contains sulfuric acid which is reportable
under sara iii section 313 supplier notification requirements.
effects of overexposure: inhalation: can damage lung tissue,,burns to
the nose and throat. Skin: can cause severe burns. Eyes:
burns.Ingestion: nausea,vomiting,pain,burns to the mouth, throart
and lower g.I.Tract.
medical cond aggravated by exposure: may aggravate respiraory ailments
such as emphysemia & bronchitis. Also, may aggravate pre-existing
skin disorders.
First aid: eyes: flood with water for at least 15 minutes while holding
eye lids open.Get medical attention immediately. Skin: flush
exposed area with water for at least 15 minutes. Wrap burns in dry,
sterile dr essing.Inhalation: move victim to fresh air. If
breathing is difficult, give oxygen. If breathing has stopped
administer cpr. Seek medical attention at once.Ingestion: do not
induce vomiting.Administe r large quantities of water if victim is
conscious. Do not try to neutralize because of possible exothermic
reaction.
Hcc: c1
boiling pt: =279.4c, 535.F
vapor pres: < 0.5
vapor density: 17mmhg
spec gravity: 1.4042(water=1)
ph: < 2
evaporation rate & reference: < 1.0 (butyl acetate = 1)
solubility in water: complete
appearance and odor: clear to slightly turbid: off white to straw color:
usually odorless.
percent volatiles by volume: nil
Stability indicator/materials to avoid: yes
alkaline materials; salts of other acids: hydrated materials;
combustible and organic materials.
stability condition to avoid: addition of water causes large temperature
increase.
hazardous decomposition products: if heated sufficiently, sulfur
dioxide(s02) and sulfur trixoide (s03)
Waste disposal methods: dispose of waste in compliance with local, state
and federal regulations. Waste may be classified as corrosive
(d002)under rcra. Recycle waste where applicable.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 50.0%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3
acgih stel: 3 mg/m3
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance