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Methylchloroform (1, 1, 1-trichloroethane)
Saturated chlorinated derivatives of acyclic hydrocarbons, n.E.S.
Chemicals-organic
Y - Indicates information is in the hazardous materials information resource system (hmirs).
PMICA - Item does not contain precious metal.
CRITL- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.
045615 - Poisonous/toxic matls, group a
635 - Chemicals, other than drugs or sundries
9 - Other or no special handling required (sh)
A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.
C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp
V - Miscellaneous hazardous materials, un class 9 (no label)
W - Rating variable
Questions & Answers: |
|
| What are the historical prices recorded for this stock number? | |
| Historical data shows pricing from $28.35 to $47.25.. | |
| Does NSN 6810-00-930-6311 have a shelf life? | |
| No. There is no shelf life applicable for this NSN. | |
| What NATO entities are users of this NSN? | |
| Defense Threat Reduction Agency, Federal Aviation Administration, Bulgaria, Brazil, Spain, Singapore, Kuwait, Republic Of Korea, Portugal, Italy, Greece, Turkey, and Nato Maintenance and Supply Agency | |
| What is the NIIN of NSN 6810-00-930-6311? | |
| 009306311 or 00-930-6311 | |
| Does NSN 6810-00-930-6311 require demilitarization? | |
| Yes - ITAR Controlled | |
| What is the most recent solicitation for NSN 6810-00-930-6311? | |
| No solicitations for this NSN. | |
| When was this national stock number assigned to the federal catalog? | |
| Jul 13, 1966 | |
Effects of overexposure: drowsiness, nausea, vomiting, unconsciousness;
death in extreme cases
First aid: remove to fresh air. Remove contaminated clothing. Give
artificial respiration if necessary.Keep warm and quiet. For eye
contact wash with large amounts of water. Call physician. Never
administer adre naline.
Hcc: t4
Stability indicator/materials to avoid: yes
stability condition to avoid: contact with open flame, hot surfaces,
welding arc emission
hazardous decomposition products: hydrogen chloride, phosgene, other
highly toxic substances.
Waste disposal methods: consult manufacturer or local pollution control
agency.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
Effects of overexposure: possible dizziness or nausea
First aid: inhalation: remove to fresh air, call physician. Eye: flush
thoroughly with water. Call doctor
Hcc: v2
Stability indicator/materials to avoid: yes
stability condition to avoid: do not store above 120f
hazardous decomposition products: open flame: fumes may contain co &
toxic chlorides & fluorid
Waste disposal methods: in accordance with federal, state, & local regs
for chemicals involved. Do not incinerate cans.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 65%
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: dichlorodifluoromethane (sara iii)
cas: 75-71-8
rtecs #: pa8200000
fraction by wt: 35%
osha pel: 1000 ppm
acgih tlv: 1000 ppm; 9192
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ozone depleting chemical: 1
Routes of entry: inhalation: yes skin: yes ingestion: yes
health hazards acute and chronic: acute: irritation of eyes(corneal
injury possible)skin and resp.System;dizziness,drowsiness,throat
irritation;cns depression,cardiac sensitization,unconsciousness at
high concentrations. Chronic: defatt ing of skin,dermatitis,liver or
kidney damage possible.
explanation of carcinogenicity: diethylene dioxide(dioxane) is suspected
animal carcinogen.Ntp/iarc used as stablizer in small amounts.
effects of overexposure: can cause: vomit,nausea,drowsiness,
unconsciousness & even death in extreme cases.
medical cond aggravated by exposure: pre-existing conditions may be
worsen;acute and chronic liver disease rhythm disorders of the
heart.
First aid: skin: wash w.Soap & h2o. Eyes: flush w. H2o. Ingested: don't
induce vomiting. Inhaled: remove to fresh air. Give cpr/ oxygen if
need. Keep warm & quiet. Remove contaminated clothing. Never give
anything b y mouth to unconscious person.
Hcc: v2
boiling pt: b.P. Text: 165f/74c
vapor pres: 100
vapor density: 4.6
spec gravity: 1.32
evaporation rate & reference: (ether =1) =0.4
solubility in water: negligible
appearance and odor: colorless clear liquid,mildly sweet
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong alkalies,oxidizers,& reactive materials.
stability condition to avoid: contact with open flame,hot surfaces or
emissions frm.Weld a
hazardous decomposition products: hydrogen chloride,phosgene, & other
highly toxic substance
Waste disposal methods: recovered liquids may be sent to licensed
reclaimer or incineration facility. Contaminated material must be
disposed of in a permitted waste management facility. Consult
federal,state,or local disposa l authorities for approved
procedures.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 96.5%
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: 1,4-dioxane (diethylene dioxide) (sara iii)
cas: 123-91-1
rtecs #: jg8225000
fraction by wt:
osha pel: s, 100 ppm
acgih tlv: s, 25 ppm; 9293
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
Routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: inhalation: headache,dizziness
and nausea.May also have some anesthetic effect.
eyes: burning,irritation. Skin: drying,defatting.
chronic: dermatitis.
effects of overexposure: eye irritation, drying of skin, excessive
inhalation causes headache, dizziness, & nausea
medical cond aggravated by exposure: breathing conditions.
First aid: eyes: flush with large amounts of water;skin: wash with soap
and water;inhalation: remove to fresh air.Apply artificial
respiration,if necessary;ingestion: do not induce vomit.Call
doctor.If any symptoms persist,see doctor.
Hcc: v2
boiling pt: b.P. Text: 220f/104c
vapor pres: 6.2
vapor density: >1.0
spec gravity: 0.932
solubility in water: negligible
appearance and odor: amber liquid, pleasant odor
percent volatiles by volume: 76
Stability indicator/materials to avoid: yes
strong oxidizing agent
stability condition to avoid: heat,ignition sources.
hazardous decomposition products: thermal decomposition: hcl,cl*2,co and
possibly phosgene.
Waste disposal methods: partially used or full aerosols are hazardous
wastes if discarded. Dispose of in accordance with federal,state
and local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: petroleum distillate (distillates,hydrotreated light)
cas: 64742-47-8
fraction by wt: 42.0%
other rec limits: 200ppm
ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 29.0%
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: inhibited paraffinic oil (tlv as oil mist =5mg/cum)
fraction by wt: 25.0%
acgih tlv: 5mg/cum (mist)
ingred name: carbon dioxide
cas: 124-38-9
rtecs #: ff6400000
fraction by wt: 4.0%
osha pel: 5000 ppm
acgih tlv: 5000ppm/30000stel;93
Ld50 lc50 mixture: oral ld50 (rat) = 10,300 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: product is irritating to body tissues,
and is a central nervous system depressant, causing nausea and
dizziness. Chronic over exposure may cause dermatitis, liver
and/or kidney damage.
explanation of carcinogenicity: the product contains no ingredient that
is listed by iarc, ntp or osha as a carcinogen.
effects of overexposure: headache, dizziness, drowsiness, nausea,
tingling or numbness of the extremities, senses of fullness in the
head, sense of warmth, stupor or dullness, lethargy and
drunkenness. Very high concentration s may lead to unconsciousness
or even death in confined or poorly ventilated areas.
medical cond aggravated by exposure: none given by manumacturer.
First aid: eye: flush w/water 15 min, hold lids open. skin: wash with
soap & water. Remove contaminated clothing and launder before
reuse. inhaled: remove to fresh air. Restore breathing if
necessary. Ingested: d o not induce vomiting. Give 2 large glasses
of milk or water and get immediate medical care. Give nothing by
mouth if unconscious. if irritation persists or is severe,see a
doctor.
Hcc: v2
boiling pt: b.P. Text: 165f,74c
melt/freeze pt: m.P/f.P text:
vapor density: 4.55
spec gravity: 1.306
evaporation rate & reference: 6.0 (butyl acetate = 1)
solubility in water: negligible
appearance and odor: clear, colorless, volitile liquid, slightly sweet
odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizing agents,strong bases,reducing agents,aluminum and other
active metals.
stability condition to avoid: high temperatures, and open flames
hazardous decomposition products: when involved in fire, product emits
highly toxic and irritating fumes of hydrogen chloride and
phosgene.
Waste disposal methods: dispose i/a/w all federal, state and local
regulations. do not incinerate containers.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: >95%
other rec limits: none specified
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: propellant (type not specified)
other rec limits: none specified
Effects of overexposure: irritating to eyes & skin;oral toxicity is
low;anesthetic eff seen at low level,higher "see supp"
First aid: skin: wash w.Soap & h2o. Eyes: flush w. H2o. Ingested: don't
induce vomiting. Inhaled: remove to fresh air. Give cpr/ oxygen if
need. Keep warm & quiet. Remove contaminated clothing. Never give
anything b y mouth to unconscious person.
Hcc: v2
boiling pt: b.P. Text: 165f/74c
vapor pres: 100
vapor density: 4.55
spec gravity: 1.321
solubility in water: 0.07 wt%
appearance and odor: colorless liquid,irritating odor.
Stability indicator/materials to avoid: yes
water-slow hydrolysis producing corrosive acid.
stability condition to avoid: open flame,welding arc,high temp.
hazardous decomposition products: hcl,phosgene & chlorine.
Waste disposal methods: to licensed reclaimer, or permitted
incinerators; disposal practice must be in compliance with
federal,state & local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 96.5%
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: 1,4-dioxane (diethylene dioxide) (sara iii)
cas: 123-91-1
rtecs #: jg8225000
fraction by wt: 2.5%
osha pel: s, 100 ppm
acgih tlv: s, 25 ppm; 9293
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
ingred name: 1,2-butylene oxide (sara iii)
cas: 106-88-7
rtecs #: ek3675000
fraction by wt: 0.47%
epa rpt qty: 1 lb
dot rpt qty: 1 lb
ingred name: nitromethane
cas: 75-52-5
rtecs #: pa9800000
fraction by wt: 0.34%
osha pel: 100 ppm
acgih tlv: 100 ppm; 9192
Ld50 lc50 mixture: not specified by manufacturer.
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eye irritation, transient corneal
damage, skin irritation, defatting, dermatitis. May be rapidly
absorbed by the lungs causing asphyxiation.
explanation of carcinogenicity: this compound contains no ingredients at
concentrations of 0.1% or greater that are carcinogens or suspect
carcinogens.
effects of overexposure: eye irritation, skin irritation, dermatitis,
asphyxiation
medical cond aggravated by exposure: none specified by manufacturer.
First aid: eyes: wash with water a minimum of 15 minutes. Seek medical
attention. Skin: wash with soap and water. Ingestion: do not induce
vomiting. Keep victim quiet and call physician immediately.
inhalation: remove to fresh air. If not breathing use mouth to
mouth resuscitation.
Hcc: v2
boiling pt: b.P. Text: 165f,74c
melt/freeze pt: m.P/f.P text: not given
decomp temp: decomp text: 385f,196c
vapor pres: 60-80 psi
vapor density: 4.55
spec gravity: 1.32
evaporation rate & reference: > 1 (butyl acetate=1)
solubility in water: negligible
appearance and odor: clear liquid, sharp chlorine smell, dispersed in
aerosol
Stability indicator/materials to avoid: yes
alkali metals such as aluminum and zinc powdered metals. Exposure to
water will cause hydrolysis producing corrosives
stability condition to avoid: avoid sources of heat
hazardous decomposition products: hydrogen chloride and minuteamounts of
phosgene and chlorine.
Waste disposal methods: prevent waste from contaminating surrounding
environment. Discard any product, residue, disposal container or
liner in accordance with all federal, state and local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 94.57%
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: 1,4-dioxane (diethylene dioxide) (sara iii)
cas: 123-91-1
rtecs #: jg8225000
fraction by wt: 2.45%
osha pel: s, 100 ppm
acgih tlv: s, 25 ppm; 9293
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
ingred name: 1,2-butylene oxide (sara iii)
cas: 106-88-7
rtecs #: ek3675000
fraction by wt: 0.46%
epa rpt qty: 1 lb
dot rpt qty: 1 lb
ingred name: nitromethane
cas: 75-52-5
rtecs #: pa9800000
fraction by wt: 0.33%
osha pel: 100 ppm
acgih tlv: 100 ppm; 9192
ingred name: carbon dioxide
cas: 124-38-9
rtecs #: ff6400000
fraction by wt: 2.00%
osha pel: 5000 ppm
acgih tlv: 5000ppm/30000stel;93
Ld50 lc50 mixture: oral ld50 (rat) = 10,300 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: product is irritating to body tissues,
and is a central nervous system depressant, causing nausea and
dizziness. Chronic over exposure may cause dermatitis, liver
and/or kidney damage.
explanation of carcinogenicity: the product contains no ingredient that
is listed by iarc, ntp or osha as a carcinogen.
effects of overexposure: headache, dizziness, drowsiness, nausea,
tingling or numbness of the extremities, senses of fullness in the
head, sense of warmth, stupor or dullness, lethargy and
drunkenness. Very high concentration s may lead to unconsciousness
or even death in confined or poorly ventilated areas.
medical cond aggravated by exposure: none given by manumacturer.
First aid: eye: flush w/water 15 min, hold lids open. skin: wash with
soap & water. Remove contaminated clothing and launder before
reuse. inhaled: remove to fresh air. Restore breathing if
necessary. Ingested: d o not induce vomiting. Give 2 large glasses
of milk or water and get immediate medical care. Give nothing by
mouth if unconscious. if irritation persists or is severe,see a
doctor.
Hcc: v2
boiling pt: =74.C, 165.2f
melt/freeze pt:
vapor density: 4.55
spec gravity: 1.306
evaporation rate & reference: 6.0 (butyl acetate = 1)
solubility in water: negligible
appearance and odor: clear, colorless, volitile liquid, slightly sweet
odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizing agents,strong bases,reducing agents,aluminum and other
active metals.
stability condition to avoid: high temperatures, and open flames
hazardous decomposition products: when involved in fire, product emits
highly toxic and irritating fumes of hydrogen chloride and
phosgene.
Waste disposal methods: dispose i/a/w all federal, state and local
regulations. do not incinerate containers.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 75%
other rec limits: none specified
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: dichlorodifluoromethane (sara iii)
cas: 75-71-8
rtecs #: pa8200000
fraction by wt: 24%
other rec limits: none specified
osha pel: 1000 ppm
acgih tlv: 1000 ppm; 9192
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ozone depleting chemical: 1
ingred name: carbon dioxide
cas: 124-38-9
rtecs #: ff6400000
fraction by wt: 1%
other rec limits: none specified
osha pel: 5000 ppm
acgih tlv: 5000ppm/30000stel;93
Ld50 lc50 mixture: oral ld50 (rat) = 10300 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: contact may cause eye irritation with
temporary corneal injury or skin irritation. May cause respiratory
tract irritation, central nervous system depressant, loss of
consciousness and even death can o ccur at high levels of exposure.
prolonged or repeated exposure may cause skin irritation. May cause
drying or flaking.
explanation of carcinogenicity: not listed as a carcinogen by ntp, iarc
or osha
effects of overexposure: incoordination and impaired judgment may occur
at vapor exposures from 500-1000 ppm. Dizziness, drowsiness, and
general anestethic effects may occur in ranges of 1000 ppm and
higher.
medical cond aggravated by exposure: over exposure may cause increased
sensitivity to adrenaline. Over exposure with an insufficient
supply of oxygen may temporarily increase cardiac irritability.
symtomatic amines may cause arrhythmias.
First aid: inhalation: remove to fresh air. If not breathing,
resuscitate. If breathing is difficult, give oxygen. Call a
physician. Eye: flush immediately with large amounts of water for
15 minutes. Get medical attention. Skin: remove contaminated
clothing. Wash with soap and water promptly. Ingestion: do not
induce vomiting. Get immediate medical attention. Give nothing by
mouth if victim is unconscious.
Hcc: g1
boiling pt: b.P. Text: 165f,74c
melt/freeze pt: m.P/f.P text: -23f,-31c
decomp temp: decomp text: >130f,>54c
vapor pres: 100
vapor density: 4.55
spec gravity: 1.321
evaporation rate & reference: 6.0 (n-butyl acetate=1)
solubility in water: negligible
appearance and odor: clear, colorless liquid. Mild, chloroform-like
odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
prolonged contact with aluminum and related alloys. This can form
hydrochloric acid gas.
stability condition to avoid: high temperatures, sparks, open flames and
welding arcs which induce thermal decomposition.
hazardous decomposition products: when involved in fire,
1,1,1-trichloroethane emits highly toxic and irritating hydrogen
chloride and phosgene fumes.
Waste disposal methods: dispose of i/a/w federal, state & local
regulations. Preferred option is to send to licensed reclaimer. Do
not puncture or incinerate can.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 96-98%
other rec limits: none specified
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: carbon dioxide
cas: 124-38-9
rtecs #: ff6400000
fraction by wt: 2-4%
other rec limits: none specified
osha pel: 5000 ppm
acgih tlv: 5000ppm/30000stel;93
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: fatalities following severe acute
exposure to various chlorinated solvents have been attributed to
venticular fibrillation.
explanation of carcinogenicity: the epa's science advis board concluded
there is no evidence to suggest carcinogenic activity for 1,1,1
trichloroethane.
effects of overexposure: inhalation: dizziness,headaches,narcosis,
anesthesia,suffocation,circulatory system depress,central nerve
system damage/death.Skin: irrit & dermatitis.Eye: irrit.Oral: irrit of
the mouth/gi tract w/other effects listed above for
inhalation.Vomiting/subsequent aspiration into lungs may lead to
chem pneumonia/pulmona edema.
medical cond aggravated by exposure: cardiovascular disease.
First aid: inhaled: move to fresh air.If necessary,give cpr/oxygen.Do not
give epinephrine/similar drugs as may induce vertricular
arrythmia.Pyrolized fumes inhalation: recover 1-2days.Eye: flush
w/h2o 15 min.If ir rit occurs,consult
physician.Skin: flushw/soap/h2o 15 min while removing contamin
clothes/shoes.If irrit occurs,consult a doctor.Oral: if
conscious,drink lots of water.Do not induce vomit.Take to hosp
Hcc: v2
boiling pt: b.P. Text: 165.4
vapor pres: 120 mm hg
vapor density: 4.54 @ 68f
spec gravity: 1.31 g/cc
ph: 6-7.5
evaporation rate & reference: 1.4 (cc14=1)
solubility in water: negligible
appearance and odor: clear, colorless, liquid, ethereal odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
finely divided reactive metals and strong caustics.
stability condition to avoid: avoid spraying near open flames or red hot
surfaces. Do not heat aerosol containers above 49c/120f.
hazardous decomposition products: can be decomp by high
temperatures(open flames,glowing surface,etc.)forming halogen acids
and phosgene in smaller amts.
Waste disposal methods: comply with federal, state and local
regulations. Remove to a permitted waste disposal facility. Do not
puncture or incinerate aerosol cans.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 96.8%
other rec limits: none specified
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: carbon dioxide
cas: 124-38-9
rtecs #: ff6400000
fraction by wt: 3.2%
other rec limits: none specified
osha pel: 5000 ppm
acgih tlv: 5000ppm/30000stel;93
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: reports have associated repeated and
prolonged overexposure to solvents with permanent brain and nervous
system damage, also kidney and liver damage.
explanation of carcinogenicity: this product is not considered to be a
carcinogen by the ntp, iarc, osha or niosh.
effects of overexposure: in a confined area vapors in high
concentrations are anesthetic. Irritant to skin and upper
respiratory system. Overexposure may result in light-headedness,
staggering gait, giddiness and possible nau sea. Harmful or fatal
if swallowed.
medical cond aggravated by exposure: none established
First aid: breathing: remove patient to fresh air. Eyes: flush with water
for at least 15 minutes. Skin: wash with soap and water.
swallowing: call physician immediately. Do not induce vomiting.
Hcc: v2
boiling pt: b.P. Text:
vapor density: > air
evaporation rate & reference: faster than ether
appearance and odor: organic solvents
Stability indicator/materials to avoid: yes
none
stability condition to avoid: do not store above 120f.
hazardous decomposition products: by open flame: carbon monoxide, carbon
dioxide, hydrogen chloride and phosgene gas.
Waste disposal methods: do not incinerate. Dispose in accordance with
federal, state and local regulations regarding pollution.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 80%
other rec limits: *lel: 7.5
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: isobutane
cas: 75-28-5
rtecs #: tz4300000
fraction by wt: 10%
other rec limits: *lel: 1.8
osha pel: 1000 ppv
acgih tlv: 1000ppm/1800.00mg/m3
ingred name: propane
cas: 74-98-6
rtecs #: tx2275000
fraction by wt: 10%
other rec limits: *lel: 2.3
osha pel: 1000 ppm
acgih tlv: asphyxiant; 9192
Ld50 lc50 mixture: oral-rat ld50=10,300 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: irritating to skin and eyes. Excessive
inhalation or ingestion may produce cns depression. May cause
ventricular fibrillation. Aspiration into lungs may lead to
chemical pneumonia. High doses have pro duced mild liver effects in
animals.
effects of overexposure: irritation and redness to skin and eyes.
coughing, headache, dizziness, drowsiness and nausea. Depression,
fatigue, loss of appetite, and vomiting.
medical cond aggravated by exposure: cuts, abrasions, dermatitis,
respiratory or heart ailments.
First aid: eyes: flush with water for 15 min. See a physician
immediately. Skin: remove contaminated clothing. Wash skin with
mild soap and water. Consult a physician if irritation develops or
persists. Inhalati on: remove to fresh air. Administer oxygen or
artificial respiration if needed. Call a physician immediately.
ingestion: do not induce vomiting. Call a physician immediately.
Hcc: v2
boiling pt: b.P. Text: 165f,74c
vapor pres: 100 mm hg
vapor density: 4.55
spec gravity: 1.320
evaporation rate & reference: 0.4 (ether=1)
solubility in water: insoluble
appearance and odor: clear water-white liquid, ether-like odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizers, metals such as sodium and potassium.
stability condition to avoid: avoid extreme temperatures.
hazardous decomposition products: carbon monoxide, carbon dioxide,
hydrochloric acid, and phosgene.
Waste disposal methods: this product may be dissolved or mixed with a
combustible solvent and burned in a chemical incinerator equipped
with an afterburner and scrubber. Dispose of in accordance with
local, state, and federa l regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
other rec limits: none specified
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: 1,4-dioxane (diethylene dioxide) (sara iii)
cas: 123-91-1
rtecs #: jg8225000
other rec limits: none specified
osha pel: s, 100 ppm
acgih tlv: s, 25 ppm; 9293
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: dizziness,drowness and throat
irriration. Eyes;irritation,temporary corneal
injury.Skin;irritation,defatting and dermititis.Ingestion.If
vomiting occurs liquid can be aspirated into the lung.
effects of overexposure: inhalation;unconsciousness and death,blood
pressure,depression,cardiac sensitaziation and ventricular
arrythmia can result.Skin;absorbent through intact skin.
ingestion;human psychotropic,gastrointest inal and central nervous
system effectspossible.
medical cond aggravated by exposure: liver diseases and rhythm disorders
of the heart.
First aid: inhalation;remove to fresh air;if breathing has
stoppedadminister cpr,seek medical atention.Eyes;flush for at least
15 minutes with clear water,if irritation persists seek medical
attention.Skin;remov e contaminated clothing and shoes,wash exposed
area with soap and water,wash contaminated clothing before reuse.
ingestion;do not induce vomiting,give 2 glasses of water and
immediatelyseek medical av
Hcc: g3
boiling pt: b.P. Text: 165f,74c
vapor pres: na
vapor density: 4.55
spec gravity: 1.306
evaporation rate & reference: na
solubility in water: 0
appearance and odor: clear liquid,mildly sweet odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong bases,oxidizers,reducing agents,aluminum and other metals.
stability condition to avoid: contact with open flames,heat
hazardous decomposition products: hydrogen
chloride,phosgene,chlorene,carbon dioxide and carbon monoxide.
Waste disposal methods: by a liscensed reclaimer or incineration
facility,consult local,state and federal diposal authorities for
approved procedures. Do not incinerate aerosol cans.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 79-84%
other rec limits: none specified
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: chlorodifluoromethane
cas: 75-45-6
rtecs #: pa6390000
fraction by wt: 15-20%
other rec limits: none specified
osha pel: 1000 ppm
acgih tlv: 1000ppm; 9192
ozone depleting chemical: 2
ingred name: carbon dioxide
cas: 124-38-9
rtecs #: ff6400000
fraction by wt: 1%
other rec limits: none specified
osha pel: 5000 ppm
acgih tlv: 5000ppm/30000stel;93
Ld50 lc50 mixture: ld50 rats.
routes of entry: inhalation: yes skin: yes ingestion: yes
health hazards acute and chronic: eye: liq painful/slight transient
irrit w/ corneal injury. Vapor-irrit. Skin: prolong/repeat
expos-irrit/drying/ flaking. Inhal: irrit/central nerv sys effects:
dizzy/weakness/fatigue/ nausea/headache /poss unconsious/death.
ingest: aspir in lungs-chem pneumonitis, poss fatal. If aspired
rapidly-injury to other body sys
explanation of carcinogenicity: this product not considered to be a
carcinogen.
effects of overexposure: possible effects are cardiac abnormalities,
liver abnormalities, kidney damage. May produce minimal
anesthetic/narcotic effects. High conc over 1000ppm:
dizziness/drunkenness. 10,000 ppm: unconsciousn ess/death. May also
cause: blood press depress/ cardiac sensitization/ventricular
arrhythmias. In confined/poor vent
medical cond aggravated by exposure: n/k area: unconsciousness/death. In
lab animal studies: 1,1,1-trichloroethane (aerosol form) more
acutely toxic than 1,1,1-trichloroethane (vapor).
First aid: skin: wash w/soap & wtr. Rmv contam cloth/ launder before
reuse. Eye: flush w/lg amts of wtr, lift lids. Get med aid. Ingest:
dont vomit. Immed drink 2 glasses wtr. No mouth-unconscious. Call
dr/take to emerg rm. Inhal: rmv to fresh air. If breath difficult:
admin oxygen, if stopped: artif resp. Keep warm/quiet. Do not give
stimulants/ epinehrine/ephedrine, may adversely affect heart
w/fatal resul
Hcc: v3
boiling pt: b.P. Text:
vapor density: >than air
evaporation rate & reference: faster than ether
appearance and odor: organic solvents
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
water/reactive metals (alum/magnesium)/open flame/ welding
arcs/resistance heaters/etc, which can result in thermal
stability condition to avoid: liquid oxygen or other strong oxidants may
form explosive mixtures with 1,1,1-trichloroethane.
hazardous decomposition products: n/k decomp releasing hydrogen chloride
& small amounts of phosgene & chlorine/strong oxidizing
agents/strong alkalies
conditions to avoid polymerization: do not store above 120f
Waste disposal methods: do not incinerate-dispose in accordance with
federal, state and local regulations regarding pollution. Epa haz
waste code - 1. Epa haz waste no. - f002, d001. Rq - 1000 for
1,1,1- trichloroethane.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (sara 313) (lel 7.5)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 80%
other rec limits: none specified
osha pel: 350 ppm
acgih tlv: 350 ppm/1900.00mg/m3
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: isobutane (lel 1.8)
cas: 75-28-5
rtecs #: tz4300000
fraction by wt: 10%
other rec limits: none specified
osha pel: 1000 ppm
acgih tlv: 1000ppm/1800.00mg/m3
ingred name: propane (lel 2.3)
cas: 74-98-6
rtecs #: tx2275000
fraction by wt: 10%
other rec limits: none specified
osha pel: 1000 ppm
acgih tlv: 1000ppm/1800.00mg/m3
Ld50 lc50 mixture: oral ld50 (rat) = 10300 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: may cause eye & skin
irritation. May cause respiratory tract irritation. Central nervous
system depressant. Loss of consciousness and even death can occur
at high levels of exposure.
explanation of carcinogenicity: not listed as a carcinogen by ntp, iarc
or osha
effects of overexposure: uncoordination and impaired judgment may occur
at vapor exposures from 500-1000 ppm. Dizziness, drowsiness, and
general anestethic effects may occur in ranges of 1000 ppm and
higher.
medical cond aggravated by exposure: increased sensitivity to adrenaline
may be caused by over exposure.
First aid: inhalation: remove to fresh air. If not breathing, give
artificial respiration. If breathing is difficult, give oxygen.
call a physician. Eye: flush immediately with large amounts of
water for 15 minu tes. Get medical attention. Skin:
removecontaminated clothing. Wash with soap and water promptly.
ingestion: do not induce vomiting. Give milk or usp mineral oil.
get immediate medical attention.
Hcc: v2
boiling pt: =23.3c, 74.F
melt/freeze pt: =-30.6c, -23.F
vapor pres: 127 mm hg
vapor density: 4.55 air=1
evaporation rate & reference: 12.8 (n-butyl acetate=1)
solubility in water: slight
appearance and odor: colorless, volatile liquid with sweetish
chloroform- like odor.
percent volatiles by volume: 16.7
Stability indicator/materials to avoid: yes
strong oxidizing agents
stability condition to avoid: high heat, open flames and other sources
of ignition
hazardous decomposition products: when involved in fire,
1,1,1-trichloroethane emits highly toxic and irritating hydrogen
chloride and phosgene fumes.
Waste disposal methods: dispose of in accordance with local, state and
federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 100%
other rec limits: none recommended
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9293
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
Ld50 lc50 mixture: ld50 oral (rat) >10,000 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute; eye: may cause pain, slight
transient irritation w/slight transient corneal injury, irritate.
ingestion: if aspirated, may be absorbed thru lungs, injure other
body systems. Inhal: minimal anest hetic/narcotic effects,
dizziness, drunkeness, unconsciousness, death. Cardiac arrhythmias.
effects of overexposure: chronic; skin: prolonged or repeated exposure
may cause skin irritation. Repeated contact may cause drying or
flaking of skin.
First aid: eye: flush immed w/wtr 5 min.Skin: wash in flow
water/shower.Ingest: dont induce vomit.Call dr/transprt to emerg rm
immed.Inhal: remove to fresh air.If no breath,give artif resp.If
breath diffclt,give oxy gen.Call dr.Note to dr: rapid absorpt thru
lungs(aspiratd- sys effects).If lavage,endotracheal/esophageal
control.Weigh danger w/ toxicity.Exposure increases myocardial
irrit.Dont give sympathomimetic
Hcc: t4
boiling pt: b.P. Text: 165f,74c
vapor pres: 100 @ 20c
vapor density: 4.55
spec gravity: 1.321 @ 25c
solubility in water: 0.007 g/100 g @ 25c
appearance and odor: colorless liquid, irritating odor at high
concentrations
Prolonged contact w/free water, prolonged contact/ storage in
aluminum/alloys/metallic aluminum/zinc powders.
stability condition to avoid: open flames, welding arcs or other high
temperature sources which induce thermal decomposition.
hazardous decomposition products: hydrogen chloride & very small amounts
of phosgene and chlorine
Waste disposal methods: when disposing of unused contents, preferred
options are to send to licensed reclaimer. Do not incinerate can.
any disposal practice must be in compliance with federal, state &
local regulations. Dont dump into sewers, on ground or into
waterbodies.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: 1,1,1-trichloroethane (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 93-95%
other rec limits: none specified
osha pel: 350 ppm
acgih tlv: 350 ppm
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: diethylene dioxide (1,4-dioxane) (sara iii)
cas: 123-91-1
rtecs #: jg8225000
fraction by wt: 2.5%
other rec limits: none specified
osha pel: s, 100 ppm
acgih tlv: s, 25 ppm; 9293
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
ingred name: 1,2-butylene oxide (sara iii)
cas: 106-88-7
rtecs #: ek3675000
fraction by wt: .47%
other rec limits: 40ppm/excursn 100ppm
epa rpt qty: 1 lb
dot rpt qty: 1 lb
ingred name: nitromethane
cas: 75-52-5
rtecs #: pa9800000
fraction by wt: .34%
other rec limits: none specified
osha pel: 100 ppm
acgih tlv: 100 ppm
ingred name: carbon dioxide (propellant)
cas: 124-38-9
rtecs #: ff6400000
fraction by wt: 2-4%
other rec limits: none specified
osha pel: 5000 ppm
acgih tlv: 5000ppm/30000stel;93
Ld50 lc50 mixture: oral ld50 (rat) = 10300 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eyes: may cause irritation and
transcient corneal damage.Skin: may cause irritation.Overexposuremay
cause defatting and dermatitis.Inhal: this item is rapidly absorbed
by the lungs,causing asphyxiation.
explanation of carcinogenicity: 1,1,1-trichloroethane has been studied
by iarc and ntp,but the results are inconclusive.
effects of overexposure: incoordination and impaired judgment may occur
at vapor exposures from 500-1000 ppm. Dizziness, drowsiness, and
general anestethic effects may occur in ranges of 1000 ppm and
higher. Irritation, trans ient corneal damage to the eyes.
defatting and dermatitis to the skin.
medical cond aggravated by exposure: increased sensitivity to adrenalin
may be caused by over exposure.
First aid: inhalation: remove to fresh air. If not breathing, give
artificial respiration. If breathing is difficult, give oxygen.
call a physician. Eye: flush immediately with large amounts of
water for 15 minu tes. Get medical attention. Skin:
removecontaminated clothing. Wash with soap and water promptly.
ingestion: do not induce vomiting. Give milk or mineral oil. Get
immediate medical attention.
Hcc: v2
boiling pt: b.P. Text: 165f,74c
decomp temp: decomp text: 385f,196c
vapor pres: 60-80
vapor density: 4.55
spec gravity: 1.32
evaporation rate & reference:
solubility in water: neglig 0.07gm/100gm
appearance and odor: clear liquid with sharp chlorine smell
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
alkali metals(eg. Aluminum and zinc powdered metals).
stability condition to avoid: high temperatures.
hazardous decomposition products: hydrogen chloride and phosgene fumes.
Waste disposal methods: dispose of i/a/w federal, state & local
regulations. Do not allow to reach sewer, storm drains or ground
water systems. Toxic to aquatic life.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl chloroform (1,1,1-trichloroehane) (sara iii)
cas: 71-55-6
rtecs #: kj2975000
fraction by wt: 94.57%
osha pel: 350 ppm/450 stel
acgih tlv: 350 ppm/450stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: carbon dioxide
cas: 124-38-9
rtecs #: ff6400000
fraction by wt: 2.00%
osha pel: 10000ppm/30000stel
acgih tlv: 5000ppm/30000stel;92
ingred name: proprietary inhibitor package(from dow chem,usa)
fraction by wt: 4.5%
other rec limits: none recommended
Hcc: v2
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: 111 trichloro ethane
cas: 71-55-6
rtecs #: kj2975000
fraction by wt:
other rec limits: none recommended
osha pel: 350 ppm
acgih tlv: 350 ppm
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: carbon dioxide (propellant)
cas: 124-38-9
rtecs #: ff6400000
other rec limits: none recommended
Ld50 lc50 mixture: not provided
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation: above 1000 ppm: dizziness,
drowsiness & throat irritation. Above 10000 ppm: unconsciousness &
death. Blood pressure depression, cardiac sensitization,
ventricular arrhythmia. Skin: prolong ed/repeated contact can cause
irritation, skin defatting & dermatitis. Absorbtion through intact
skin is possible. Eyes: temporary irritation with slight corneal
injury. Vapors irritate eyes. Ingestio n. Single dose toxicity is
low to moderate. If vomiting occurs 1,1,1-trichloroethane can be
aspirated in lungs causing chemical pneumonia & systemic effects.
explanation of carcinogenicity: available data indicates
1,1,1-trichloroethane not carcinogenic in lab animals.
effects of overexposure: dizziness, drowsiness, throat irritation, blood
pressure depression, cardiac sensitization, ventricular arrhythmia.
medical cond aggravated by exposure: acute & chronic liver disease &
rhythm disorders of the heart
First aid: inhalation: remove to fresh air. If breathing has stopped,
administer artificial respiration. Call physician. Skin: remove
contaminated clothing & shoes. Wash exposed area with soap & water.
wash cont aminated clothing before reuse. Eyes: flush eyes
immediately with water for at least 15 minutes. If irritation
persists, call a physician. Ingestion: do not induce vomiting.
contact physician or emerg ency mediacl facility immediately. Note
to physician: adrenalin should never be given to persons
overexposed to 1,1,1-trichloroethane.
Hcc: t4
boiling pt: =73.9c, 165.F
vapor pres: 100 mg hg @ 20c
vapor density: 4.6
spec gravity: 1.32
evaporation rate & reference: 0.4, ether = 1
solubility in water: 0.07 gm/100 gm @ 25c
appearance and odor: clear, colorless liquid, mildly sweet odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong alkalies, oxidizers & reactive metals (i.E. Aluminum, potassium,
sodium, etc.)
stability condition to avoid: contact with open flame, electric arcs or
other hot surfaces which can cause thermal decomposition.
hazardous decomposition products: hydrogen chloride, phosgene, chlorine
Waste disposal methods: ecovered liquids may be sent to licensed
reclaimer or incineration facility. Contaminated material must be
disposed of in a permitted waste management facility. Consult
federal, state or local disposa l authorities for approved
procedures.
Ingred name: 1,1,1-trichloroethane
cas: 71-55-6
rtecs #: kj2975000
= wt: 96.5
osha pel: 1900 mg/m3;350 ppm
acgih tlv: 1910 mg/m3;350 ppm
acgih stel: 2460 mg/m3;450 ppm
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ozone depleting chemical: 1
ingred name: 1,4-diethylene dioxide
cas: 123-91-1
rtecs #: jg8225000
< wt: 3.
osha pel: 360 mg/m3;100 ppm
acgih tlv: 90 mg/m3;25 ppm
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
ingred name: 1,2-butylene oxide
cas: 106-88-7
rtecs #: ek3675000
< wt: .5
epa rpt qty: 1 lb
dot rpt qty: 1 lb