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Acs Butyl Alcohol

NSN: 6810-00-939-5390 | Model: A399
NSN Properties and Flags
NATO Stock Number
6810-00-939-5390
DEMIL
NO
Physical Form
Liquid
Quantity Within Each Unit Package
500.000 milliliters

Pricing and Availability

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NSN 6810-00-939-5390 Datasheet

Supply Class (FSC):
Chemicals
Cross Reference:
  • A399
  • A399-500
Cage Codes:
  • Fisher Scientific Worldwide (CAGE 94480)
  • Fisher Scientific Company L.l.c. (CAGE 22527)
Schedule B & Trade:
  • Schedule B: 2905130000 (NAICS 325199)

    Butan-1-ol (n-butyl alcohol)

  • SITC: 51213

    Butanols

  • End Use: 12540

    Chemicals-organic

Identification:
HMIC

Y - Indicates information is in the hazardous materials information resource system (hmirs).

PMIC

A - Item does not contain precious metal.

CRITL

- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.

NSN Management Codes:
  • SOS
    Sms
  • AAC
    J
  • Quantity per pack
    No qup
  • Unit of Measure
    Bt
  • Shelf Life
    N/A
  • Classification Control
    U
  • MGMT_CTL
    9b----f
  • Repariability

Questions & Answers:

What are the historical prices recorded for this stock number?
Historical data shows pricing from $77.64 to $129.40..
Does NSN 6810-00-939-5390 have a shelf life?
No. There is no shelf life applicable for this NSN.
What NATO entities are users of this NSN?
Department Of The Navy
What is the NIIN of NSN 6810-00-939-5390?
009395390 or 00-939-5390
Does NSN 6810-00-939-5390 require demilitarization?
Yes - ITAR Controlled
What is the most recent solicitation for NSN 6810-00-939-5390?
No solicitations for this NSN.
When was this national stock number assigned to the federal catalog?
Nov 16, 1965
MSDS

Material Safety

MSDS BLWCJ BUTANOL, A-399

Hazards

Ld50 lc50 mixture: ld50: (oral,rat)790 mg/kg.

routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhal: irritant/narcotic. 8000ppm idlh.

acute: vap concs of 25ppm may cause mild irrit to resp tract & nose.

substance quite odorous which usually provides adeq warning but
olfactory senses readily beco me fatigued. Expos to 50ppm may cause
hdch & vertigo; higher concs may cause marked irrit, sore
throat,(efts of overexp)
explanation of carcinogenicity: not relevant
effects of overexposure: hlth haz: nervous sys depress w/hdch, dizz, dull
& drows. Expos to 6600ppm produced giddiness,
prostration,narcosis,ataxia & death in some animals.

chronic: long-term study on humans expsd to butyl alco hol revealed
little/no irrit/complications occurred at 100ppm/below. However,
prlngd inhal at this level caused (ing 5)
medical cond aggravated by exposure: persons w/a history of chronic
respiratory, skin, or eye disease may be at an increased risk from
exposure.

First Aid

First aid: inhal: remove to fresh air immed.If brthg stopped, give artf
resp.Keep warm/at rest.Get md immed. Skin: remove contamd
clthg/shoes immed. Wash affected area w/soap/mild detergent & lg
amts of water unti l no evid of chem remains (approx 15-20min). Get
md immed. Eye: wash immed w/lg amts of water/normal saline,occasnly
lifting lids until no evid of chem remains(approx 15-20 min).Get md
immed. (ing 23)

Chemical Properties

Boiling pt: b.P. Text: 243f,117c
melt/freeze pt: m.P/f.P text: -128f,-89c
vapor pres: 6.5 @ 25c
vapor density: 2.55
spec gravity: 0.8098
evaporation rate & reference: 0.5 (butyl acetate = 1)
solubility in water: 7.7%
appearance and odor: clear,mobile,colorless liq, w/strong, pungent
charact odor similar to fuel oil.

percent volatiles by volume: 100

Reactivity

Stability indicator/materials to avoid: yes
alkali metals, aluminum, t-butanol, chromic anhydride, strong
oxidizers. See original msds for addl info .

stability condition to avoid: may be ignited by heat, sparks or flames.

hazardous decomposition products: thermal decomposition products may
include toxic co*x.

Proper Disposal

Waste disposal methods: disposal must be i/a/w standards applicable to
generators of haz waste, 40 cfr 262. Epa haz waste no u031. Observe
all federal, state & local regs when storing/disposing substance.

for assistance, cnt ct district director of epa.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: 1-butanol; (n-butyl alcohol)
cas: 71-36-3
rtecs #: eo1400000
fraction by wt: 100%
osha pel: 100 ppm
acgih tlv: s, c 50 ppm; 9293
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs

ingred name: supp data: flow can be stopped. Use water in flooding amts
as fog. Solid streams may not be eftive. Cool cntnrs (ing 3)
rtecs #: 9999999zz

ingred name: ing 2: w/flooding amts of water. Apply from as far a
distance as possible. Avoid breathing toxic vapors. Keep upwind.

rtecs #: 9999999zz

ingred name: explo haz: mixtures are explosive above flash point.

rtecs #: 9999999zz

ingred name: efts of overexp: auditory nerve & vestibular injury in
workers resulting in severe vertigo & hearing loss. Lung (ing 6)
rtecs #: 9999999zz

ingred name: ing 5: hemorrhage, reduced erythrocyte count, lymphocytosis,
albuminuria, early degenerative changes of liver, & (ing 7)
rtecs #: 9999999zz

ingred name: ing 6: cortical & tubular degeneration in kidneys were
reported in animals following prlngd expos to 100ppm. (ing 8)
rtecs #: 9999999zz

ingred name: ing 7: skin: irritant. Acute: liq cntct may cause irrit
w/redness & dryness. Substance may be absorbed thru intact (ing 9)
rtecs #: 9999999zz

ingred name: ing 8: skin. Single applications to skin of rabbits resulted
in slight-mod irrit. Chronic: rptd/prlngd cntct has (ing 10)
rtecs #: 9999999zz

ingred name: ing 9: been reported to cause drying,cracking & eczematoid
derm of fingers & hands due to defatting action of (ing 11)
rtecs #: 9999999zz

ingred name: ing 10: liq. Application of 42-55 ml/kg/day for 1-4
consecutive days to rabbits resulted in 100% mortality. (ing 12)
rtecs #: 9999999zz

ingred name: ing 11: eye: irritant. Acute: vap concs of 25ppm may cause
slight irrit. Application of 1 drop of liq to rabbit (ing 13)
rtecs #: 9999999zz

ingred name: ing 12: eyes caused mod temporary injury which was rated 7
on scale of 10. Chronic: rptd/prlngd expos to vaps may (ing 14)
rtecs #: 9999999zz

ingred name: ing 13: result in conjunct.Vacuolar keratitis, charact by
very fine transparent vacuoles resembling tiny bubbles (ing 15)
rtecs #: 9999999zz

ingred name: ing 14: of gas in epithelial layers of cornea has been
reported in workers expsd to butyl alcohol & other solvs. (ing 16)
rtecs #: 9999999zz

ingred name: ing 15: expos to >200ppm for 10 yrs caused conjunctival &
corneal edema resulting in lacrimation, blurring of (ing 17)
rtecs #: 9999999zz

ingred name: ing 16: vision, corneal inflamm, photophobia & burning
sensation w/inflammation clearing w/i a few days w/no (ing 18)
rtecs #: 9999999zz

ingred name: ing 17: residual dmg. Ingest: narcotic. Acute: may cause abdom
pain,nausea,vomit & diarrhea. Ingest of high doses (ing 19)
rtecs #: 9999999zz

ingred name: ing 18: of butyl alcohol caused complete
paralysis,constriction of pupils,reduction in corneal,pupillary &
(ing 20)
rtecs #: 9999999zz

ingred name: ing 19: ciliary reflexes,nystagmus,salivation, reduction of
body temp & resp, deep narcosis, marked hepatic (ing 21)
rtecs #: 9999999zz

ingred name: ing 20: hyperemia, degeneration of liver & kidneys & death
in animals. Chronic: prlngd ingest of n-butyl alcohol (ing 22)
rtecs #: 9999999zz

ingred name: ing 21: in drinking water resulted in liver damage in rats.

rtecs #: 9999999zz

ingred name: first aid proc: ingest: remove ingested matl by gastric
lavage or emesis. Give artf resp w/o*2 if resp depressed. (ing 24)
rtecs #: 9999999zz

ingred name: ing 23: get md immed. No specific antidote. Treat
symptomatically and supportively.

rtecs #: 9999999zz

ingred name: spill proc: area! Keep unnecessary people away; isolate
hazard area and deny entry.

rtecs #: 9999999zz

MSDS CDXBL 1-BUTANOL, A399

Hazards

Ld50 lc50 mixture: ld50: (oral,rat) 790 mg/kg.

routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: inhal: narc: may cause mild irrit
of resp tract; hdch, vertigo; higher concs-marked irrit, sore
throat, cough, naus, shortness of breath, pulm injury & cns depress
w/hdch, dizz, dull & drow. Gidd, prostration, narcos, ataxia &
death insome animals. Skin: may cause irrit; redness, dryness. May
be (efts of overexp)
explanation of carcinogenicity: not relevant
effects of overexposure: hlth haz: absorbed. Rabbits: slight to mod irrit.

eye: rabbit: mod temporary injury. Ingest: narc. May cause abdom pain,
naus, vomit, diarr. High doses-complete paral, constriction of
pupils, reduction in corneal, pupillary & ciliary reflexes,
nystagmus, salivation. Reduction of body temp & resp. Deep narcos.

marked (ing 8)
medical cond aggravated by exposure: persons w/chronic respiratory, skin
or eye diseases are at increased risk from exposure.

First Aid

First aid: ingest: call md immed . Inhal: remove to fresh air. Support
breathing (give o*2/artf resp) . Eyes: immediately flush w/potable
water for a minimum of 15 minutes, seek assistance from md (fp n ).

skin: flush w/copious amounts of water. Call md . Antidote: no
specific antidote. Treat symptomatically & supportively. For more
specific info regarding first aid treatment cont nehc .

Chemical Properties

Boiling pt: b.P. Text: 243f,117c
melt/freeze pt: m.P/f.P text: -128f,-89c
vapor pres: 6.5 @ 25c
vapor density: 2.55
spec gravity: 0.8098
evaporation rate & reference: 0.5 (butyl acetate=1)
solubility in water: 7.7%
appearance and odor: clear, mobile, colorless liq; strong, pungent
charact odor similar to fused oil
percent volatiles by volume: 100

Reactivity

Stability indicator/materials to avoid: yes
alkali metals, aluminum, strong oxidizers, plastics, rubber. For a
complete listing of matls to avoid cont nehc .

stability condition to avoid: avoid contact w/heat, sparks, flames or
other sources of ignition.

hazardous decomposition products: thermal decomposition products may
include toxic oxides of carbon.

Proper Disposal

Waste disposal methods: observe all federal, state & local regulations
when disposing of this substance. Disposal must be i/a/w standards
applicable to generators of hazardous waste, 40 cfr 262. Epa
hazardous waste number d0 31.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: butyl alcohol; (1-butanol) (sara 313) (cercla)
cas: 71-36-3
rtecs #: eo1400000
fraction by wt: 100%
osha pel: 100 ppm
acgih tlv: 50 ppm, s, c
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs

ingred name: supdat: well after fire is out. Stay away from ends of
tanks. For massive fire in cargo area, use unmanned hose (ing 3)
rtecs #: 9999999zz

ingred name: ing 2: holder/monitor nozz; if this is imposs, w/draw from
area & let fire burn. W/draw immed in case of rising (ing 4)
rtecs #: 9999999zz

ingred name: ing 3: sound from venting sfty device/any discoloration of
tank due to fire. Isolate for 1/2 mile in all (ing 5)
rtecs #: 9999999zz

ingred name: ing 4: directions if tank, rail car/tank truck is involved
in fire. Exting only if flow can be stopped. Use water (ing 6)
rtecs #: 9999999zz

ingred name: ing 5: in flooding amts as fog. Solid streams may not be
eftive. Cool cntnrs w/flooding amts of water; apply from (ing 7)
rtecs #: 9999999zz

ingred name: ing 6: as far a distance as possible. Avoid breathing toxic
vapors. Keep upwind. Water may be ineffective.

rtecs #: 9999999zz

ingred name: efts of overexp: hepatic hyperemia, degeneration of liver &
kidneys & death in animals. Chronic: inhal: may affect (ing 9)
rtecs #: 9999999zz

ingred name: ing 8: light-sensitivity of dark-adapted eyes & elec
activity of brain. Auditory nerve & vestibular injury rsltg (ing
10)
rtecs #: 9999999zz

ingred name: ing 9: in sev vertigo & hearing loss. Animals: lung hemorr.

reduced erythrocyte count, lymphocytosis, (ing 11)
rtecs #: 9999999zz

ingred name: ing 10: albuminuria, early degenerative changes of liver &
cortical & tubular degeneration in kidneys. Repro (ing 12)
rtecs #: 9999999zz

ingred name: ing 11: efts. Skin: drying, cracking & eczematoid derm of
fingers & hands due to defat action. Eye: may rslt in (ing 13)
rtecs #: 9999999zz

ingred name: ing 12: conj, vacuolar keratitis, charact by very fine
transparent vacuoles resembling tiny bubbles of gas in (ing 14)
rtecs #: 9999999zz

ingred name: ing 13: epithelial layers of cornea. Conj & corneal edema
rsltg in lacrim, blurring of vision, corneal inflamm, (ing 15)
rtecs #: 9999999zz

ingred name: ing 14: photophobia & burning sensation w/inflamm clearing
w/in a few days w/no residual dmg. Ingest: liver dmg in(ing 16)
rtecs #: 9999999zz

ingred name: ing 15: rats. Target efts: cns depressant. Pois may also
affect liver & kidneys. Alcohol may enhance toxic efts. (ing 17)
rtecs #: 9999999zz

ingred name: ing 16: for more specific information contact nehc .

rtecs #: 9999999zz

ingred name: resp prot: facepiece & org vap cartridge(s). 1250 ppm-any
supplied-air resp operated in continuous flow mode. (ing 19)
rtecs #: 9999999zz

ingred name: ing 18: 2500 ppm-any air-purifying full facepiece resp (gas
mask) w/chin-style or front- or back-mounted org vap (ing 20)
rtecs #: 9999999zz

ingred name: ing 19: canister; any scba w/full facepiece; any
supplied-air resp w/full facepiece. 8000 ppm-any supplied-air (ing
21)
rtecs #: 9999999zz

ingred name: ing 20: resp w/full facepiece & operated in
press-demand/other pos press mode. Escape-any air-purifying full
(ing 22)
rtecs #: 9999999zz

ingred name: ing 21: facepiece resp (gas mask) w/chin-style or front- or
back-mounted org vap canister; any approp escape-type(ing 23)
rtecs #: 9999999zz

ingred name: ing 22: self-contained breathing apparatus.

rtecs #: 9999999zz

MSDS CHHPS A399-500 1-BUTANOL

Hazards

Ld50 lc50 mixture: oral,rat: ld50=790mg/kg.

routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eye: may cause moderate irrit.May
result in corneal injury vap may cause irrit.Skin: causes irrit.May
be absorbed thru skin in harmful amts.Prol &/or resp contact may
cause defatting of skin,derm.Ingest : may cause syst toxicity
w/acidosis.Maycause liv/kid dmg.May cause cns
depress(head,dizz,drows,nau.Adv stage-(sign/sym)
explanation of carcinogenicity: per msds: carcinogenicity: not listed by
acgih,iarc,niosh,ntp,osha.

effects of overexposure: health: collapse,unconsc,coma,death-resp
failure).May be harmful.Inhal: hi conc may cause cns
effects(head,dizz,unconsc,coma).Cause resp tract irrit,liver/kid
dmg.Chronic: rep eye expo cause visual abnor malities include blur
vision,photosensitivity.

medical cond aggravated by exposure: none specified by manufacturer.

target organs: kidneys,central nervous system,liver.

First Aid

First aid: eye: immed flush w/lots of h2o @least 15mis,lift lids.Get med
aid.Dont allow to rub or keep eyes clsd.Skin: flush w/lots of
soap/h2o @least 15mins.Remove contam cloth/shoe.Irrit dvlps/persist
get emd ai d.Ingest: consc/alert give 2-4cup of milk/h2o.Never give
anything by mouth if unconsc.Gete med aid immed.Inhal: move to fresh
air.Not breath give art resp;breath diffi give oxy.Get med
aid.(supple)

Chemical Properties

Hcc: f3
boiling pt: =117.2c, 243.F
melt/freeze pt: =-90.C, -130.F
decomp temp: decomp text: n/avai
vapor pres: 6.5
vapor density: 2.6
spec gravity: 0.8
ph: n/avai
viscosity: 2.94 cp @20c
evaporation rate & reference: 0.46, butyl acetate=1
solubility in water: 9.1ml/10ml h20,appre
appearance and odor: colourless liquid, sweetish odor,putrid
odor,banana-like
percent volatiles by volume: np
corrosion rate: np

Reactivity

Stability indicator/materials to avoid: yes
aluminum,chromium trioxide,organic peroxides,strong oxidizers.

stability condition to avoid: high temperatures, incompatible
matls,ignition sources.

hazardous decomposition products: carobn monoxide,carbon dioxide.

Proper Disposal

Waste disposal methods: when release to soil expected to
biodegrade,leach to ground h2o or volatilize;in h2o-biodegrade or
volatilize.Bioconc pot predicted to be low.Subst moderately-hi
mobile.Subst rxs w/air w/hydroxyl radi
cals(1/2life-2.3days).Dispose of in manner(suppe)
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: n-butyl alcohol (sara 313) (cercla)
cas: 71-36-3
rtecs #: eo1400000
fraction by wt: >99%
other rec limits: none recommended
osha pel: 100 ppm
acgih tlv: s, c 50 ppm; 9596
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs

MSDS CLDWM 84-9790, BUTYL ALCOHOL

Hazards

Routes of entry: inhalation: yes skin: unknown ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
explanation of carcinogenicity: this material is not listed as cancer
causing agent.

effects of overexposure: harmful if inhaled or swallowed; causes
headache, nausea, gastrointestinal disturbances. Vapor irritating
to eyes and respiratory passages. Large concentrations or continued
overexposure may cause hea ring loss, kidney or liver injury.

irritating on contact with eyes or skin.

medical cond aggravated by exposure: kidney and liver conditions.

First Aid

First aid: get medical assistance for all cases of overexposure. Skin:
wash thoroughly with soap and water. Eyes: immediately flush
thoroughly with water for at least 15 minutes. Inhaltion: remove to
fresh air; give artificial respiration if breathing is stopped.

ingestion: if conscious, drink water and induce vomiting
immediately as directed by medical personnel. Never give anything
by mouth to an unconscio us person. Remove contaminated clothing
and wash before reuse.

Chemical Properties

Hcc: f2
boiling pt: =117.7c, 243.9f
melt/freeze pt: =-89.C, -128.2f
vapor pres: 420c
vapor density: 2.55
spec gravity: 0.810
evaporation rate & reference: 0.46 (buac=1)
solubility in water: 7.7%
appearance and odor: clear, colorless liquid with characteristic alcohol
odor.

percent volatiles by volume: 99+%

Reactivity

Stability indicator/materials to avoid: yes
acids, oxidizers, other: halogens, aluminum, alkali metals.

stability condition to avoid: heat, contact with ignition sources.

hazardous decomposition products: cox.

Proper Disposal

Waste disposal methods: epa waste numbers: u031, d001. Treatment:
incineration, fuels blending or recycle. Contact your local
permitted waste disposal site (tsd) for permissible treatment
sites. Always contact a permitted wa ste disposer (tsd) to assure
compliance with all current, local, state and federal regulations.

Ingredients List

Ingred name: butyl alcohol
cas: 71-36-3
rtecs #: eo1400000
= wt: 100.

osha pel: 300 mg/m3;100 ppm
acgih stel: c152 mg/m3;c50 ppm
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs