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Sulfuric acid and oleum
Sulfuric acid; oleum
Chemicals-inorganic
Y - Indicates information is in the hazardous materials information resource system (hmirs).
PMICA - Item does not contain precious metal.
CRITL- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.
044155 - Chem: corrosive matls, group a, sub1
635 - Chemicals, other than drugs or sundries
9 - Other or no special handling required (sh)
A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.
B - Construction materials: includes paint and related materials, prefabricated building, wood products, metal and composition mater
W - Corrosive materials, un class 8 (corrosive label)
Z - No rating
Questions & Answers: |
|
| What are the historical prices recorded for this stock number? | |
| Historical data shows pricing from $292.29 to $487.15.. | |
| Does NSN 6810-00-975-0707 have a shelf life? | |
| No. There is no shelf life applicable for this NSN. | |
| What NATO entities are users of this NSN? | |
| Department Of The Army, Department Of The Air Force, and Department Of The Navy | |
| What is the NIIN of NSN 6810-00-975-0707? | |
| 009750707 or 00-975-0707 | |
| Does NSN 6810-00-975-0707 require demilitarization? | |
| Yes - ITAR Controlled | |
| What is the most recent solicitation for NSN 6810-00-975-0707? | |
| No solicitations for this NSN. | |
| When was this national stock number assigned to the federal catalog? | |
| Jan 01, 1962 | |
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
effects of overexposure: skin: irritation, corrosive burns. Eyes:
irritation, corneal burns, conjuctivitis. Ingestion: irritation,
corrosive burns to mouth, throat, and stomach. Can be fatal if
swallowed. Inhalation: irritati on and burns to upper respiratory
system and lungs.
First aid: inhalation: remove to fresh air. If not breathing, give cpr.
if breathing is difficult, give oxygen. Eyes: immediately flush
with plenty of water for at least 15 minutes. Skin: wash with soap
and wate r. Remove contaminated clothing and shoes. Ingestion:
dilute with water or milk. Do not induce vomiting. Get medical
attention in all cases.
Hcc: c1
boiling pt: b.P. Text: 534f,279c
spec gravity: 1.835
solubility in water: complete
appearance and odor: oily, colorless to slightly yellow, clear to turbid
liquid.
Stability indicator/materials to avoid: yes
oxidizers, flammable materials, reducing materials, carbides,
chlorates, sulfides, allyl compounds, aldehydes
stability condition to avoid: heating >300c,572f, moisture
hazardous decomposition products: sulfur trioxide, sulfur dioxide,
hydrogen sulfide, hydrogen gas
Waste disposal methods: dilute w/water,neutralize w/alkali & flush to
sewer with plenty of water if permitted by applicable disposal
regulations. Neutralized waste may have to be disposed of by an
approved contractor. Dispos er must comply w/fed,state & local
disposal regs.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93.0%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water; cas #7732-18-5
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 07.0%
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
effects of overexposure: eyes and skin: causes burns. Inhalation:
irritation. Ingestion: severe damage, can be fatal.
First aid: remove to fresh air. Get medical attention. Eyes and skin:
flush with water. remove contaminated clothing. Keep warm and
quiet. Give cpr/oxygen if needed. Stay upwind. Keep unprotected
persons away f rom area.
Hcc: c1
boiling pt: b.P. Text: 580f,304c
vapor pres: < 1
spec gravity: 1.843
evaporation rate & reference: < 1 (butyl acetate = 1)
solubility in water: complete
appearance and odor: colorless to brownish oily liquid with no odor.
percent volatiles by volume: 0
Stability indicator/materials to avoid: yes
combustibles, reducing agents, water, powdered metals
stability condition to avoid: high heat, moisture
hazardous decomposition products: hydrogen, sulfur dioxide, sulfur
trioxide, hydrogen sulfide
Waste disposal methods: after adding a large excess of a mixed solution
of sodium hydroxide and calcium hypochlorite, let it stand for 24
hours, then neutralize, dilute and discharge into the sewer. Handle
and dispose iaw al l applicable federal, state, and local
regulations
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 96%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 4%
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
effects of overexposure: burns to skin, tissue dehydration. May cause
third degree burns. Inhalation of mist may cause bronchitis
hyperemia, epithelial degeneration of the larynx, trachea, and
bronchi with laryngeal or bronch ial spasms.
First aid: eyes: flush for at least 15 minutes with water, lifting
eyelids. Call a physician. Skin: wash with excess amounts of water.
remove contaminated clothing under shower. Call a physician.
inhalation: rem ove from exposure. Get immediate medical attention.
ingestion: do not induce vomiting. Drink large quantities of water.
get medical attention.
Hcc: c1
boiling pt: b.P. Text: 529f,276c
vapor density: 3.38
spec gravity: 1.8354
solubility in water: complete
appearance and odor: clear, colorless liquid.
Stability indicator/materials to avoid: yes
metal powders
stability condition to avoid: high heat, moisture
hazardous decomposition products: sulfur dioxide, sulfur trioxide,
hydrogen sulfide, hydrogen gas
Waste disposal methods: small spill: dilute with excess water to drain.
large spill: neutralize with soda ash. Dilute with water and
remove to authorized landfill.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93%
other rec limits: twa=1 mg/cum
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
effects of overexposure: ingestion: may cause severe injury or death.
eyes: damage by burns. Skin: burns, irritation of respiratory
tract.
First aid: call a doctor immediately. Ingestion: do not induce vomiting.
immediately give large quantities of water or milk, if available.
eyes: flush eyes with large quantities of water for at least 15
minutes. skin: flush with water for at least 15minutes.
inhalation: remove to fresh air.
Hcc: c1
spec gravity: 1.8347
solubility in water: complete
appearance and odor: colorless, clear to hazy, odorless, oily-looking
liquid.
Stability indicator/materials to avoid: yes
powdered metals, organic materials, carbides, chlorates, fulminates,
nitrates, picrates
stability condition to avoid: high heat, moisture
hazardous decomposition products: hydrogen, sulfur dioxide, sulfur
trioxide, hydrogen sulfide
Waste disposal methods: sulfuric acid that cannot be used or chemically
reprocessed should be disposed of in an approved landfill-in such a
manner that it will not adversely affect the environment.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 98.0%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: oral rat: 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: burning sensation upon contact
with skin and eyes. Chronic: chronic bronchitis, asthma and other
upper respiratory ailments.
effects of overexposure: eyes and skin: severe burns. Chronic exposure
will cause severe ulceration wich is irreversible.
medical cond aggravated by exposure: pre-existing conditions may be
worsened. (respiratory ailments).
First aid: inhalation: remove to fresh air. If not breathing give cpr.
if breathing is difficult give oxygen. Eyes: immediately flush with
plenty of water. Skin: wash with soap and water. Remove
contaminated clo thing and shoes. Ingestion: do not induce
vomiting. Nothing by mouth if unconscious. Get medical attention.
Hcc: c1
boiling pt: b.P. Text: 535f,279c
vapor pres: < 1
spec gravity: 1.835
solubility in water: complete
appearance and odor: clear to slight turbid, off-white to straw yellow.
Stability indicator/materials to avoid: yes
alkaline metals, salts of other acids, hydrated metals, combustible,
organic materials
stability condition to avoid: high heat, moisture
hazardous decomposition products: sulfur dioxide, sulfur trioxide,
hydrogen sulfide, hydrogen gas
Waste disposal methods: comply with all federal, state, and local
regulations. Waste may qualify as a hazardous waste under rcra.
spilled material may be reportable under the clean water act.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: >93.0%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
Ld50 lc50 mixture: ld50 (oral rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation of vapors causes severe
irritation or burns of the respiratory system, pulmonary edema, and
lung inflammation. Eye contact causes severe damage and possible
blindness. Skin contact causes b urns and possible deep ulceration.
ingestion causes severe burns to mouth, throat, and stomach.
explanation of carcinogenicity: this chemical is not listed by iarc,
ntp, or osha as a carcinogen. This substance may contain trace
amounts of as,cd)
effects of overexposure: severe irritation and burns to eyes, nose, and
throat. Pulmonary edema, bronical emphysema, conjunctivitis,
stomatitis, dental erosion, nausea, and vomiting.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the respiratory tract may
be at increased risk from exposure.
First aid: inhalation: remove to fresh air. Resuscitate if not
breathing. Get medical attention. Eyes: immediately flush with
plenty of water for 30 minutes holding eyelids open. Get prompt
medical attention. Sk in: remove contaminated clothing. Wash with
plenty of water for 30 minutes. Get medical advice. Ingestion: do
not induce vomiting. Give nothing by mouth if unconscious. Get
immediate medical attention
Hcc: c1
boiling pt: b.P. Text: 529f,276c
melt/freeze pt: m.P/f.P text: -20f,-29c
spec gravity: 1.835
ph: < 1
evaporation rate & reference: < 1 (n-butyl acetate = 1)
solubility in water: complete
appearance and odor: colorless to pale yellow, oily liquid. Odorless.
Stability indicator/materials to avoid: yes
strong oxidizing or reducing agents, strong alkalis, cyanides,
sulfides, metals, water, combustible materials
stability condition to avoid: high heat, moisture
hazardous decomposition products: oxides of sulfur, carbon dioxide,
carbon monoxide, hydrogen sulfide, hydrogen gas
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state, and local environmental regulations.
unneutralized material will be a corrosive hazardous waste (code
d002).
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93%
other rec limits: none specified
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: arsenic (sara iii)
cas: 7440-38-2
rtecs #: cg0525000
fraction by wt:
other rec limits: none specified
osha pel: 0.5 mg/m3 (as)
acgih tlv: 0.01,a1 mg/m3; 9394
epa rpt qty: 1 lb
dot rpt qty: 1 lb
ingred name: cadmium (sara iii)
cas: 7440-43-9
rtecs #: eu9800000
fraction by wt:
other rec limits: none specified
osha pel: see 1910.1027
acgih tlv: 0.01 mg/m3 dust;9394
epa rpt qty: 10 lbs
dot rpt qty: 10 lbs
ingred name: lead (sara iii)
cas: 7439-92-1
rtecs #: of7525000
fraction by wt:
other rec limits: none specified
osha pel: 0.05 mg/m3;1910.1025
acgih tlv: 0.15 mg/m3;dust 9192
epa rpt qty: 1 lb
dot rpt qty: 1 lb
Ld50 lc50 mixture: ld50 oral rat = 2140 mg/kg body weight
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute - ingestion: mouth, throat,
esophagus, stomach burns, gastric perforation, death. Inhalation:
severe irritation of respiratory tract, sneezing, coughing, and
lung damage. Skin: burning and charr ing. Eyes: irreversible damage
and possibly blindness. Chronic - dermatitis, bronchitis, chronic
runny nose and bleeds
effects of overexposure: spray and mists are severely irritating to the
eyes and respiratory tract, causing tickling of the nose and
throat. Causes charring of the skin as a result of the great
affinity for, and strong exothe rmic reaction with water.
medical cond aggravated by exposure: skin irritation may be aggravated
in persons with existing skin lesions. Breathing of sprays
(sulfuric acid mists) may aggravate acute or chronic asthma and
other chronic pulmonary disease.
First aid: speed is essential. Start first aid. Get medical care at
once. Eyes: hold eyelid open and flush with water for at least 15
minutes. Skin: wipe excess with a dry cloth. Then wash with plenty
of water a nd soap. Inhalation: remove to fresh air. Give
cpr/oxygen if needed. Ingestion: if conscious, drink 2 to 3 glasses
of water. Do not induce vomiting.
Hcc: c1
boiling pt: b.P. Text: 380f,193c
melt/freeze pt: m.P/f.P text: 12f,-11c
vapor pres: < 1
vapor density: 3.4
spec gravity: 1.7 - 1.8
ph: < 1
solubility in water: complete
appearance and odor: clear, colorless to cloudy, oily liquid. Odorless.
Stability indicator/materials to avoid: yes
organics, chlorates, carbides, fulminates, picrates, metals, water
stability condition to avoid: high heat, moisture
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: dispose of in accordance with all applicable
local, state, and federal regulations. This material is rcra
hazardous waste d002, corrosive and d003, reactive. Spills are
subject to cerlca reporting req uirements: reportable quantity =
1000 pounds.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 78- 100%
other rec limits: none specified
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: oral ld50 (rat) = 2140 mg/kg body weight
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute - ingestion: mouth, throat,
esophagus, stomach burns, gastric perforation, and even death.
inhalation: damage to nasal and respiratory passages. Skin:
burning, charring, and deep ulcerations. Ey es: severe damage and
even blindness very rapidly. Chronic - bronchitis, laryngeal and
pulmonary edema may result.
effects of overexposure: ingestion: mouth, throat, esophagus, stomach
burns, gastric perforation and even death. Inhalation: damage to
nasal and respiratory passages. Skin: burning, charring, and deep
ulceration of skin. Eyes : severe eye damage and even blindness
very rapidly.
medical cond aggravated by exposure: skin irritation may be aggravated
in persons with existing skin lesions. Breathing of sprays
(sulfuric acid mists) may aggravate acute or chronic asthma and
other chronic pulmonary disease.
First aid: speed is essential.Start first aid and get medical care at
once. Eyes and skin: flush with water for at least 15 minutes. Hold
eyelids open. Inhalation: remove to fresh air. Provide cpr/oxygen
if need ed. Ingestion: do not induce vomiting. If conscious, take
large amounts of milk, milk of magnesia, table oil, or fresh eggs.
drink water if nothing else is available. Rinse mouth often.
Hcc: c1
boiling pt: b.P. Text: 535f,279c
melt/freeze pt: m.P/f.P text: -29f,-34c
vapor pres: 1 @ 145c
vapor density: > 1
spec gravity: 1.84
ph: < 2
solubility in water: complete
appearance and odor: colorless to brownish oily liquid with no odor.
Stability indicator/materials to avoid: yes
strong bases, combustible materials, powdered metals, organic
materials, water
stability condition to avoid: high heat, open flames, moisture
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: dispose of in accordance with all applicable
local, state, and federal regulations. This material is rcra
hazardous waste d002, corrosive and d003, reactive. Spills are
subject to cerlca reporting req uirements: reportable quantity=
1000 pounds.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93 - 98%
other rec limits: none specified
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: ld50 oral rat = 2140 mg/kg body weight
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute - ingestion: causes mouth,
throat, esophagus, stomach burns, gastric perforation and death.
inhalation: severe irritation of the respiratory tract, lung
damage. Skin: severe burns. Eyes: irrever sible damage and possibly
blindness. Chronic - dermatitis, bronchitis, ulceration.
effects of overexposure: irritation to the eyes and respiratory tract.
ulceration and severe burns to all tissues, pain and discomfort.
medical cond aggravated by exposure: existing skin lesions, breathing of
sprays (sulfuric acid mists) may aggravate asthma and other chronic
pulmonary diseases.
First aid: start first aid and get medical care at once. Eyes: hold
eyelid open and flush with water for at least 15 minutes. Skin:
wipe excess with a dry cloth, then wash with plenty of water and
soap. Inhalati on: remove to fresh air. Give cpr/oxygen if needed.
ingestion: if conscious, drink 2 to 3 glasses of water. Do not
induce vomiting.
Hcc: c1
boiling pt: b.P. Text: 535f,279c
vapor pres: < 0.01
spec gravity: 1.836
ph: < 1
evaporation rate & reference: < 1 (ether = 1)
solubility in water: complete
appearance and odor: clear, colorless to cloudy, oily liquid. Odorless.
percent volatiles by volume: 5-10
Stability indicator/materials to avoid: yes
strong alkalies, combustibles, powdered metals, organic materials.
stability condition to avoid: when diluting, acid should be added to
diluent. Do not add diluent to sulfuric acid.
hazardous decomposition products: oxides of sulfur, hydrogen sulfide,
hydrogen gas
Waste disposal methods: dispose of in accordance with all applicable
local, state, and federal regulations. This material is rcra
hazardous waste d002, corrosive and d003, reactive. Spills are
subject to reporting requiremen ts of section 313 of sara title
iii. Rq= 1000 lbs
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93%
other rec limits: none specified
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: ld50 oral = 2140 mg/kg (rat)
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: product is a strong mineral acid, an
oxidizing agent, and a dehydrating agent that is rapidly damaging
to all human tissue with which it comes in contact. Ingestion may
cause severe injury or death. E ye contact produces severe or
permanentinjury. Inhalation of mists can damage both upper
respiratory tract and lungs.
explanation of carcinogenicity: this compound contains no ingredients at
concentrations of 0.1% or greater that are carcinogens or suspect
carcinogens.
effects of overexposure: skin: irritation, corrosive burns. Eyes:
irritation, corneal burns, conjuctivitis. Ingestion: irritation,
corrosive burns to mouth, throat, and stomach. Can be fatal if
swallowed. Inhalation: irritati on and burns to upper respiratory
systemand lungs.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: inhalation: remove to fresh air. If not breathing, give cpr.
if breathing is difficult, give oxygen. Eyes: immediately flush
with plenty of water for at least 15 minutes. Skin: wash with soap
and wate r. Remove contaminated clothing and shoes. Ingestion:
dilute with water or milk. Do not induce vomiting. Get medical
attention in all cases.
Hcc: c1
boiling pt: =281.1c, 538.F
melt/freeze pt: =-33.9c, -29.F
vapor pres: < 1 @ 100f
spec gravity: 1.835
solubility in water: complete
appearance and odor: oily, colorless, hygroscopic, oily liquid with no
odor. .
percent volatiles by volume: 100 %
Stability indicator/materials to avoid: yes
oxidizers, flammable materials, reducing materials, carbides,
chlorates, sulfides, allyl compounds, aldehydes
stability condition to avoid: heating >300c,572f, moisture
hazardous decomposition products: sulfur trioxide, sulfur dioxide,
hydrogen sulfide, hydrogen gas
Waste disposal methods: prevent waste from contaminating surrounding
environment. Discard any product, residue, disposal container or
liner in accordance with all federal, state and local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93-98% %
other rec limits: none specified
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
other rec limits: none specified
Ld50 lc50 mixture: ld50 (oral rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: causes severe burns to eyes, skin, and
all body tissue. Eye damage may be permanent. Destruction of tissue
may result from direct chemical reaction with tissue, from thermal
burns and from dehydration (removal of water) of the tissue.
explanation of carcinogenicity: this chemical is not listed by iarc,
ntp, or osha as a carcinogen.
effects of overexposure: inhaled-coughing, wheezing, shortness of
breath, tightness in chest, chest pain. Eyes-pain, blurred vision,
redness, tearing. Skin-redness, pain, burns, swelling. Ingested:
nausea, vomiting, stomach p ain, burns to mouth/throat/esophagus.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: in all cases get immediate medical attention.
inhalation: remove to fresh air.Resuscitate if not breathing.
eyes: immediately flush with plenty of water for 15 minutes,hold
lids open. Skin: remove contam inated clothing.Wash with plenty of
water for 15 minutes. Ingestion: do not induce vomiting.If
conscious,give several glasses of milk or water.
Hcc: c1
boiling pt: b.P. Text: 534f,279c
melt/freeze pt: m.P/f.P text: -31f,-35c
decomp temp: decomp text: not given
vapor pres:
vapor density: not given
spec gravity: 1.835
ph: < 1
evaporation rate & reference: not given
solubility in water: complete
appearance and odor: oily, clear to turbid liquid, colorless to light
gray, odorless.
Stability indicator/materials to avoid: yes
water, alkaline solutions, metals, metal powder, carbides, chlorates,
fuminaates, nitrates, picrates, strong oxidizers.
stability condition to avoid: reacts violently with water and organic
materials with evolution of heat.
hazardous decomposition products: sulfur dioxide gas.
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state and local environmental
regulations.Dla-hmis: epa/rcra waste number d002 (corrosive) may
apply to unused/uncontaminated product .
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: >93%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: ld50 (oral rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: inhalation of vapors may cause
severe irritation or burns of the respiratory system, pulmonary
edema, or lung inflammation. May cause severe burns to skin or
eyes. Blindness may result. Ingesti on may cause severe burns to
mouth, throat, and stomach. May affect kidney function. Chronic:
may damage lungs.
explanation of carcinogenicity: this product is not listed by iarc, ntp,
or osha as a carcinogen.
effects of overexposure: severe irritation or burns to eyes, nose and
throat. Pulmonary edema, bronchial emphysema, conjunctivitis,
stomatitis, dental erosion, nausea and vomiting.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the respiratory tract may
be at increased risk from exposure.
First aid: eyes/skin: immediately flush with plenty of water for at
least 15 minutes while removing contaminated clothing. Inhalation:
remove to fresh air. Observe for possible delayed reaction. Give
oxygen/cpr if needed. Ingestion: do not induce vomiting. Give
several glasses of milk (preferred) or water. For all exposures,
get immediate medical attention.
Hcc: c1
boiling pt: b.P. Text: 529f,276c
melt/freeze pt: m.P/f.P text: -20f,-29c
decomp temp: decomp text: >572f,>300c
vapor pres:
vapor density: 3.4
spec gravity: 1.8
ph:
solubility in water: complete
appearance and odor: oily, colorless to slightly yellow, clear to turbid
liquid. Odorless.
Stability indicator/materials to avoid: yes
nitro compounds, carbides, alcohols (when heated), oxidizing agents,
alkyl compounds, aldehydes.
stability condition to avoid: avoid temperatures greater than 572f
(300c).
hazardous decomposition products: sulfur trioxide which is toxic,
corrosive and an oxidizer.
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state and local environmental regulations. Epa
hazardous waste number, d0002(corrosive) and d003(reactive).
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93.19%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: oral,rat ld50=2140 mg/kg.
routes of entry: inhalation: no skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: vap/mist/liq extrem corr to
nose/throat/muc memb,eyes,skin,mouth.Inhal: bron,pulm edema,chem
pneuitis.Prolon expo more severe irrit/tissue damage.Breath high
conc result in death.Eye: seve damage from b rief contact;prolon
perm injury/blindness.Skin: sever irrit/burn.Prolon burn/destroy
tissue & death.Ingest: burns(supplem)
explanation of carcinogenicity: per msds: matl not considered to bew
carcinogen by ntp,iarc,osha.
effects of overexposure: inhal: bron,pulm edema,chem
pneuitis,irrit,cough,chest pain,diffi in breath.Eye: severely
irrit,eye damage,blindness.Skin: burns,severely irrit,tissue
destruction.Ingest: tissue burns,severe abdominal pai
n,nausea,vomiting,collapse. Death. Chronic effects of expo: erosion
of teeth,skin lesions,bronchial irrit,cough,pneumonia
medical cond aggravated by exposure: acute and chronic respiratory
diseases.
First aid: inhal: remove to fresh air. Give artificial respiration if not
breathing. Get immed med attn. Eye: immed flush w/lots of running
water for 30mins lifting upper/lower eyelids occasionally. Get
immed med attn. Skin: immed flush w/lots of runningwater for
30mins. Remove contaminated clothing/shoes. Get immed med attn.
ingest: do not induce vomit. If consc give lots of water or milk.
get immed med attn.
Hcc: c1
boiling pt: b.P. Text: 529f,276c
melt/freeze pt: m.P/f.P text: -20f,-29c
vapor pres: nil
spec gravity: 1.835
evaporation rate & reference:
solubility in water: complete
appearance and odor: less to pale yellow, oily liquid, odorless.
Stability indicator/materials to avoid: yes
alkalis, oxidizing & reducing matl, cyanides, sulfides, combust
matl.React w/metals. Conc acid react violently w/water,
stability condition to avoid: none per msds.
hazardous decomposition products: may liberate oxides of sulfur, carbon
monoxide and carbon dioxide
Waste disposal methods: dipsoe of contaminated prod/matl used in
cleaning spills/leaks in manner approved for this matl.Consult
appropriate fed/state/loca reg agencies to ascertain proper
disposal procedures.Comply w/governt regs on disposal of waste.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: >93%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
other rec limits: none recommended
ld50 lc50 mixture: ld50 (oral, rat): 2140 mg/m3
route of entry inds - inhalation: yes
skin: yes
ingestion: yes
carcinogenicity inds - ntp: no
iarc: no
osha: no
effects of exposure: concentrated sulfuric acid is a strong mineral acid, an
oxidizing agent and a dehydrating agent that is rapidly damaging to all
human tissue on contact. Ingestion may cause severe injury or death. eye
contact produces severe or permanent injury. Inhalation of mists can damage
both upper respiratory tract and lungs.
explanation of carcinogenicity: this product is not considered a carcinogen by
ntp, iarc or osha.
first aid: eye contact: immediately flush with plenty of running water for at
least 15 minutes. Obtain medical help as soon as possible. Skin contact:
immediately flush areas with water, removing contaminatd clothes while
under a safety shower. Continue washing with water and get medical
attention. Inhalation: remove to fresh air. Restore breathing. Call a
physician immediately. Ingestion: dilute a cid immediately with large
amounts of milk or water, then milk of magnesia. Never give anything by
mouth if victim unconscious. Do not induce vomiting! Get immediate medical
attention.
hcc: c1
boiling point: =281.C, 537.8f
melt/freeze pt: =-33.7c, -29.F
vapor pres: <1 mm hg @ 100f
vapor density: 66 deg be
spec gravity: 1.8354 - 1.84
ph: <1
solubility in water: completely miscible
appearance and odor: clear, colorless, hygroscopic, oily liquid; odorless
percent volatiles by volume: 100
product id: sulfuric acid,concentrated
cage: 75656
company name: los angeles chemical co
street: 4545 ardine st
po box: 1987
city: south gate ca
zipcode: 90280
health emergency phone: 213-562-9500
label required ind: y
date of label review: 03/28/2000
status code: c
year procured: 2000
origination code: f
chronic hazard ind: y
eye protection ind: yes
skin protection ind: yes
signal word: danger
respiratory protection ind: yes
health hazard: slight
contact hazard: severe
fire hazard: none
=======================================================
responsible party cage: 75656
trans id no: 96064
product id: sulfuric acid,concentrated
msds prepared date: 06/18/1993
review date: 03/28/2000
mfn: 1
net unit weight: 199 lbs
multiple kit number: 0
review ind: y
unit of issue: dr
container qty: 0
type of container: drum
additional data: sulfuric acid concentrations: 93-98%. Un number, per msds.
Hazard and precautions: corrosive! Sulfuric acid is rapidly damaging to all
human tissue on contact.Ingestion may cause severe injury or death.Eye
contact produces severe or permanent injury.Inhalation of mists can damag e
both upper respiratory tract& lungs.Firstaid: inhalation-remove to
fresh air.Restore breathing if needed.Get medical attn.Eyes-flush with lots
of water for 15 minutes,lift lids.Get medical at tn.Skin-remove
contaminated clothing.Wash with lots of water for 15 minutes.Get medical
advice.Ingestion-do not induce vomiting!If conscious,give milk or
water,then milk of magnesia.Get immediate medical attn. Target organs:
none given.
spill release procedures: notify safety personnel. Provide ventilation. Stop
leak if can be done without risk. Clean-up personnel need respiratory
protection and protection against contact. Keep upwind. Contain spill. Dilu
te with water then neutralize with soda ash or lime. If no water, cover
contaminated area with sand, ashes or gravel and neutralize cautiously with
soda ash or lime.
neutralizing agent: sodium bicarbonate or a soda ash.
waste disposal methods: follow federal, state and local regulations. Runoff to
sewer may create hydrogen gas, which is a fire or explosion hazard. Epa
(cwa) rq=1000 lbs (40 cfr 117).
handling and storage precautions: sulfuric acid in carboys or drums should be
stored in a clean, ventilated storage area having acid-resistant floors.
keep out of direct sunlight. Do not store above 89.6f (32c). Store away
from incompatible materials. Soda ash, sand or lime should be kept
available for emergency use.
other precautions: protect containers against physical damage.Glass bottles
need extra protection.Do not add water to sulfuric acid.Drums may contain
hydrogen gas,open cautiously.Use nonsparking tools free of oil,di rt &
grit;vapor-proof electrical fixtures.Avoid breathing mist or vapors.Avoid
contact with skin /eyes.Do not ingest.
Ld50 lc50 mixture: rat,lc50: 510mg/m3/2h;ld50: 2140mg/kgrtecs
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eye, skin, respiratory &
gi tracts. Acute- corrosive! Causes severe eyes & skin burns. Mist
is extremely irritating to respiratory tract. Contact with eyes may
result in blindness. Swall owing may be fatal. Inhalation may
damage respiratory tract. Chronic- may cause dental erosion,
dermatitis, bronchitis.
explanation of carcinogenicity: none
effects of overexposure: severe irritation and burning, visual
impairment, dental erosion, cough, possible charring of skin, pain,
blindness, vomiting of blood, low blood pressure, shock, tearing,
swelling, tissue injury, dea th
medical cond aggravated by exposure: open wounds and sores, respiratory
ailments such as emphysemia and bronchitis
First aid: get medical attention immediately. Eye/skin: immediately flush
with water for 15-20 minutes. Hold eyelids open. Continue rinsing
with normal saline until ph=7. Inhaled: remove to fresh air. Provide
oxyg en/cpr if needed. Oral: do not induce vomiting. If conscious,
drink large amount of milk or water. If possible, do not leave
individual unattended.
Hcc: c1
nrc/state lic num: not relevant
boiling pt: b.P. Text: 534f - 590f
decomp temp: decomp text: 572f,300c
spec gravity: 1.835 - 1.842
ph: 0.9 1%
evaporation rate & reference: not relevant
solubility in water: 100%
appearance and odor: oily, colorless to slightly yellow to turbid liquid
- odorless
Stability indicator/materials to avoid: yes
strong oxidizing agents, strong bases, nitro compounds, carbides
dienes, alcohols (when heated), water, organic material
stability condition to avoid: adding water to acid (always add acid
slowly to water), high temperatures (300c/572f)
hazardous decomposition products: toxic oxides of sulfur, acid vapors or
mists
Waste disposal methods: dispose of spilled, neutralized, or waste
product, contaminated soil, and other materials in accordance with
all local, state, and federal regulations. Epa hazardous waste
number d002. Reportable quan tity (rq): 1000 lbs. Do not flush acid
to sewer.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara 302/313) (cercla)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93-99.5%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3/3 stel; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
other rec limits: none recommended
osha pel: not relevant
acgih tlv: not relevant
Ld50 lc50 mixture: oral ld50 (rat): 2140 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation may cause lung irritation &
pulmonary edema. Ingestion may be fatal. Skin contact may cause
severe irritation. Eye contact with liquid may cause irritation.
chronic exposure may cause erosi on of teeth, lesions of skin,
tracheo-bronchitis, mouth inflammation, conjunctivitis, etc.
explanation of carcinogenicity: iarc classified "strong inorganic mists
container sulfuric acid" as a category 1 carcinogen, carcinogenic
to humans.
effects of overexposure: corrosive burns to upper respiratory system,
corrosive burns to mouth/throat/stomach, severe skin burns, corneal
burns, conjunctivitis, blindness, severe or permanent injury may
result.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: eyes: immediately flush with water for 15 minutes while
holding eyelids open. Get medical attention. Skin: remove
contaminated clothing. Wash with soap and water. If irritation
persist, get medical at tention. Inhalation: remove to fresh air.
restore breathing. Get medical attention. Ingestion: drink large
amounts of water. Do not induce vomiting. Get medical attention.
Hcc: c1
boiling pt: b.P. Text: 193f,89c
melt/freeze pt: m.P/f.P text: not given
decomp temp: decomp text: not given
vapor pres: negligible
vapor density: not given
spec gravity: 1.706
ph: 0.9
evaporation rate & reference: not given
solubility in water: complete
appearance and odor: oily, colorless to slightly yellow to turbid
liquid, no odor
Stability indicator/materials to avoid: yes
nitro compounds, carbides, dienes, alcohols (when heated), oxidizing
agents, such as chlorates/permanganate
stability condition to avoid: temperatures of 300c or higher yield
sulfuric trioxide gas, which is toxic, corrosive and an oxidizer.
hazardous decomposition products: sulfur trioxide gas. Also this is a
fire risk if in contact with organic materials.
Waste disposal methods: prevent waste from contaminating surrounding
environment. Discard any product, residue, disposal container or
liner in accordance with all federal, state and local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara 302/313) (cercla)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93-99.5%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3/3 stel; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: inhalation-can cause irritation
or corrosive burns to the upper respiratory system. Lung irritation
and pulmonary edema can occur. Ingestion-can cause irritation and
corrosive burns to throat, mouth and stomach. Can be fatal if
swallowed. Skin-causes severe burns or irritation on skin contact.
eyes-can cause irritation, corneal burns and blindness. Mist
contact may irritate or burn. Chronic : long term exposure to high
levels of acid fumes may cause erosion of teeth followed by jaw
necrosis, bronchial irritation, coughing and bronchial pneumonia or
gastrointestinal disturbances.
explanation of carcinogenicity: the international agency for research on
cancer (iarc) has classified strong inorganic acid mists containing
sulfuric acid as carcinogenic to humans. This classification does
not apply to sulfuric aci d or sulfuric acid solutions. Warning:
this product contains a chemical known to the state of california
to cause cancer
medical cond aggravated by exposure: acute and chronic respiratory
disease.
First aid: inhalation-remove from exposure, place individual under care
of a physician. Ingestion-drink large amounts of water (or milk if
available) to dilute the acid. Do not induce vomiting. Skin or
eye-immed iately flush with plenty of water for at least 15 min.
remove contaminated clothing. Get prompt medical attention.
Hcc: c1
spec gravity: 1.835-1.844 (h20=1)
ph: 1% sol ph=0.9
solubility in water: complete
appearance and odor: oily, colorless to slightly yellow,clear to tribid
liquid, odod threshold~1 mu
Stability indicator/materials to avoid: yes
reacts violently with water and organic materials with evolution of
heat. Extremely hazardous in contact with many materials,
particulary carbides, chlorates, fuminates, picrates, powdered
materials and other combustible ma
stability condition to avoid: sulfuric acid is not flammable but highly
reactive and capable of igniting finely divided combustible
materials on contact.
hazardous decomposition products: sulfur trioxide mists.
Waste disposal methods: if hazardous under 40cfr 261, subpart b and c,
material must be treated or disposed in a facility meeting the
requirements of 40 cfr 264 or 265. If nonhazardous, material should
be disposed in a facil ity meeting requirements of 40 cfr 257. Epa
hazardous waste number: d002 (corrosive).
Ingred name: sulfuric acid
cas: 7664-93-9
rtecs #: ws5600000
minumum % wt: 93.
maxumum % wt: 99.
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3
acgih stel: 3 mg/m3
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Routes of entry: inhalation: yes skin: yes ingestion: yes
health hazards acute and chronic: target organs: n/p. Eyes, skin,
respiratory system, teeth (hmis). Eye contact: "danger" corrosive.
skin contact: "danger" corrosive. Inhalation: harmful if inhaled.
ingestion: harmful if swallowed. effects of overexposure: causes
severe eye and skin irritation or burns. Harmful if swallowed.
explanation of carcinogenicity: n/p. (hmis: not listed.)
First aid: eyes: immediately flush eyes with plenty of clean running
water for at least 15 minutes, lifting the upper and lower lids
occasionally. Call a physician immediately. External: in case of
contact, imme diately flush skin with plenty of clean running water
for at least 15 minutes, while removing contaminated clothing and
shoes. If burns or irritation occurs, call a physician. Internal:
if swallowed, do not induce vomiting. Immediately drink a large
quantity of milk or water and call a physician. Never give anything
by mouth to an unconscious person.
Hcc: c1
boiling pt: =279.C, 534.2f
melt/freeze pt: m.P/f.P text: nda
spec gravity: 1.835 @ 20c
ph:
solubility in water: complete
appearance and odor: clear, colorless to pale yellow liquid with a
slight acidic odor.
percent volatiles by volume: nda
Stability indicator/materials to avoid: yes
caustic, alkali, organic materials, aluminum, magnesium and zinc.
stability condition to avoid: none.
hazardous decomposition products: when heated to decomposition, it emits
toxic oxides of sulfur and sulfuric acid fumes.
Waste disposal methods: this product, if disposed as shipped, meets epa
criteria of a hazardous waste as specified in 40 cfr 261 on the
basis of its corrosivity. Dispose of product in a licensed
hazardous waste disposal faci lity in accordance with all
applicable laws. When empty, thoroughly rinse container with water
befor e disposal or return to manufacturer.
Ingred name: sulfuric acid
cas: 7664-93-9
rtecs #: ws5600000
= wt: 95.
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3
acgih stel: 3 mg/m3
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: eyes: severe burns,
corneal/irreversible damage. Skin: severe burns/irritating/damage.
inhalation: severe irritation/burns of the nose, throat/respiratory
tract. Ingestion: harmful/fatal. Severe irrit ation/burns of the
mouth, throat & digestive tract.
explanation of carcinogenicity: sulfur dioxide: a4 group; sulfuric acid:
a2 for mist.
effects of overexposure: irritation, burns, stinging, tearing, redness,
swelling. Note to physician: ingestion- long term complications may
include esophageal, gastric/pyloric strictures & stenosis. Case
studies suggest that acid ingestion may increase the risk
ofstomach cancer.
medical cond aggravated by exposure: pre-existing skin & lung disorders.
First aid: eyes: move to fresh air. Flush w/clean water for 30 mins.
skin: flush w/large amounts of water. If damaged, apply a clean
dressing. If not damaged, wash w/mild soap/water. Inhalation: move
to fresh ai r. Apply cpr/oxygen if necessary. Ingestion: don't
induce vomiting. If conscious rinse mouth w/water & dilute w/glass
of milk/water. Don't leave unattended. Obtain medical attention in
all cases.
Hcc: c1
boiling pt: b.P. Text: 260-538f
vapor density: 3.4
spec gravity: 1.82-1.84
evaporation rate & reference: (n-bu ac=1):
solubility in water: 100%
appearance and odor: extremely slippery clear viscous liquid w/odorless
to sharp pungent.
percent volatiles by volume: negli
Stability indicator/materials to avoid: yes
water/carbides/chlorates/fulminates/nitrates/picrates/metals/hypochlori
tes/sulfides/cyanides. Alkaline/organic materials,
combustibles/strong oxidizing agents.
stability condition to avoid: heat
hazardous decomposition products: oxides of sulfur.
Waste disposal methods: use water spray to reduce vapors. Sulfuric acid
is extremely slippery. Dispose in accordance w/local, state &
federal regulations. Corrosive un1830.
Ingred name: sulfuric acid
cas: 7664-93-9
rtecs #: ws5600000
minumum % wt: 93.
maxumum % wt: 99.
osha pel: 1 mg/cum
acgih tlv: 1 mg/cum=ic
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: sulfur dioxide
cas: 7446-09-5
rtecs #: ws4550000
other rec limits: 2 ppm
osha pel: 13 mg/cum
acgih tlv: 5.2 mg/cum
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
minumum % wt: 1.
maxumum % wt: 7.
Ld50 lc50 mixture: oral rat ld50=2.140 mg/kg
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation: exposure to vapor/mists
can cause severe irritation and burns to respiratory tract
andpermanent lung damage. Eyes: exposure to vapor/mists/liquid can
cause severe eye irritation or burns,c orneal damage, vision
impairment. Skin: exposure can cause severe skin irritation or
burns,destruction of the dermis with impairment of skin to
regenerate. Ingestion: severe irritation or burns to the
gastrointestional tract. Chronic: repeated inhalation can cause
bronchitis, impairment of lung function, and permanent lung damage.
repeated inhalation/ingestion can cause erosion of tooth enamel.
explanation of carcinogenicity: iarc group 1. Acgih appendix a: listed,
a2 suspected human: yes(strong acid mist). This applys to inorganic
acid mists only and does not apply to sulfuric acid of sulfuric
acid solutions.
effects of overexposure: inhalation: shortness of breath, wheezing,
choking, coughing, chest pain, impairment of lung function. Eyes:
tearing, redness, swelling, mucous discharge, pain, corneal damage,
visual impairment. Ski n: redness, swelling, burning sensation.
ingestion nausea, vomiting, diarrhea, abdominal pain, bleeding and
tissue ulceration.
medical cond aggravated by exposure: skin, respiratory, cardiovascular
disorders.
First aid: inhalation: move to fresh air. If not breathing, do not use
mouth-to-mouth cpr, use holger-nielsen method (back pressure, arm
lift) or proper respiratory device. If breathing difficult, give
oxygen. C all physician. Eyes: immediately flush with plenty of
clean water for 15 minutes, lift upper and lower lids occasionally.
remove contacts. Get medical attention. Skin: flush with running
water for 15 minutes and remove contaminated clothing and shoes.
if irritation/burn call physician. Ingestion: do not induce
vomiting. Get medical attention. If conscious, give plenty of water
to drink.
Hcc: c1
boiling pt: =281.C, 537.8f
melt/freeze pt: =-34.C, -29.2f
vapor pres: no data
vapor density: >1
spec gravity: 1.8279
ph:
evaporation rate & reference:
solubility in water: complete
appearance and odor: clear, colorless liquid with no characteristic
odor.
percent volatiles by volume: 100%
Stability indicator/materials to avoid: yes
alkalis, organic material, powdered metal, chlorine releasers,
sulfides, cyanides, oxidizers, amines, combustible materials, and
anhydrides.
stability condition to avoid: avoid excessive hot and cold temperatures.
hazardous decomposition products: when heated to dryness and
decomposition, this product emits toxic oxides of sulfur.
conditions to avoid polymerization: will not occur.
Waste disposal methods: if this product is disposed of as shipped, it
meets criteria of hazardous waste due to its corrosivity. As a
waste it is subject to land disposal restrictions under 40 cfr 268.
as hazardous liquid was te, it must be disposed of in accordance
with local, state, and federal regulations in a permitted w aste
treatment/storage/disposal facility.
Ingred name: sulfuric acid
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93% minimum
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3
acgih stel: 3 mg/m3
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: not provided
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eye: corrosive. May cause severe
irritation, burns and permanent damage. Skin: corrosive. May cause
severe irritation, burns and permanent damage. No information
regarding skin absorption, however, co rrosivity of material
suggests significant skin absorption will occur. Inhalation:
corrosive and highly toxic. May cause severe irritation and burns
of nose, throat and respiratory tract. Ingestion: c orrosive and
toxic. Harmful if swallowed. May cause severe irritation and burns
of mouth, throat and digestive tract. Prolonged or repeated
overexposure to acid mists has been reported to cause erosio n of
tooth enamel.
explanation of carcinogenicity: this material has not been identified as
a carcinogen by ntp, iarc or osha.
effects of overexposure: effects of overexposure may include severe
irritation and burns of the nose and throat, irritation of
digestive tract, coughing, nausea, vomiting, abdominal pain, chest
pain, pneumonitis (inflammation of the lungs), pulmonary edema
(accumulation of fluids in the lungs) and perforation of the
stomach.
medical cond aggravated by exposure: conditions aggravated by exposure
may include skin and respiratory (asthma-like) disorders.
First aid: eye: immediately hold eyelids apart and flush affected eyes
with clean water for at least 30 minutes. Seek immediate medical
attention. Skin: immediately flush affected area with large amount
of water while removing contaminated clothing. If skin is damaged,
apply a clean dressing and seek immediate medical attention.
inhalation: remove to fresh air. If not breathing, give artificial
respiration. if breathing is difficult, give oxygen. Seek
immediate medical attention. Ingestion: do not induce vomiting! If
conscious, immediately rinse mouth and give one glass of milk or
water. Call a physician or poison control center immediately.
Hcc: c1
nrc/state lic num: not relevant
boiling pt: =157.2c, 315.F
melt/freeze pt: m.P/f.P text: no data
decomp temp: >340.C, 644.F
vapor pres: 1@145.8f
vapor density: 3.4
spec gravity: 1.82
ph: no data
viscosity: not provided
evaporation rate & reference:
solubility in water: 100%
appearance and odor: extremely slippery, clear, viscous liquid; odorless
to sharp pungent odor.
percent volatiles by volume: negligible
corrosion rate: not provided
Hazardous decomposition products: material will not burn but if involved
in a fire may generate oxides of sulfur. Decomposes to water and
sulfur trioxide above 644f.
Waste disposal methods: this material, as produced, is not a rcra
"listed" or "characteristic" hazardous waste. Contamination may
subject it to regulation. Consult state and local regulations for
disposal. Container contents should be completely used and should
be emptied prior to discard. Drums should be returned to the d
istributor or a drum reconditioner.
Ingred name: sulfuric acid
cas: 7664-93-9
rtecs #: ws5600000
= wt: 93.
other rec limits: not provided
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3
acgih stel: 3 mg/m3
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: sulfur dioxide
cas: 7446-09-5
rtecs #: ws4550000
fraction by wt: present
other rec limits: not provided
osha pel: 13 mg/m3;5 ppm
acgih tlv: 5.2 mg/m3;2 ppm
acgih stel: 13 mg/m3;5 ppm
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
= wt: 7.