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Fluoride Reagent

NSN: 6810-01-010-3168 | Model: 444-49
NSN Properties and Flags
NATO Stock Number
6810-01-010-3168
DEMIL
NO
General Description
1 pint bottle

Pricing and Availability

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NSN 6810-01-010-3168 Datasheet

Supply Class (FSC):
Chemicals
Cross Reference:
  • 444-49
  • 444-11
  • 444-11
  • 444-11
  • 444-49
  • 444-11
  • 444-49
  • 444-11
  • 444-49
  • 444-11
  • 444-49
  • 444-11
  • 444-49
  • 444-11
  • 444-49
  • 444-11
  • 444-49
  • 444-11
Cage Codes:
  • Hach Company (CAGE 91224)
Identification:
HMIC

Y - Indicates information is in the hazardous materials information resource system (hmirs).

PMIC

A - Item does not contain precious metal.

CRITL

- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.

Freight Information:
  • NMFC:

    043940 - Chemicals noi

  • WCC:

    635 - Chemicals, other than drugs or sundries

  • SHC:

    9 - Other or no special handling required (sh)

  • ADC:

    A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.

  • ACC:

    C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp

  • LTL:

    W - Rating variable

  • TCC:

    W - Corrosive materials, un class 8 (corrosive label)

NSN Management Codes:
  • SOS
    Sms
  • AAC
    H
  • Quantity per pack
    No qup
  • Unit of Measure
    Pt
  • Shelf Life
    N/A
  • Classification Control
    U
  • MGMT_CTL
    R2200x-
  • Repariability
    This is a nonreparable item. if condemned or economically unserviceable, then dispose at the level authorized replace the item.

Questions & Answers:

What are the historical prices recorded for this stock number?
Historical data shows pricing from $110.65 to $184.41..
Does NSN 6810-01-010-3168 have a shelf life?
No. There is no shelf life applicable for this NSN.
What NATO entities are users of this NSN?
Department Of The Army, Department Of The Air Force, and Department Of The Navy
What is the NIIN of NSN 6810-01-010-3168?
010103168 or 01-010-3168
Does NSN 6810-01-010-3168 require demilitarization?
Yes - ITAR Controlled
What is the most recent solicitation for NSN 6810-01-010-3168?
No solicitations for this NSN.
When was this national stock number assigned to the federal catalog?
Sep 25, 1975
MSDS

Material Safety

MSDS BGDBZ 444-11 SPADNS REAGENT FOR FLUORIDE

Hazards

Ld50 lc50 mixture: oral rat ld5o 540 mg/kg
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: yes iarc: yes osha: yes
health hazards acute and chronic: corrosive to eyes, skin & respiratory
tract. Cause burns. If swallowed causes sedation, twitching.

chronic: not determined.

explanation of carcinogenicity: contains inorganic arsenic which is
listed by ntp and iarc and regulated by osha as a carcinogen.

effects of overexposure: eye: severe irritation,burns. Skin:
irritation,burns. Inhalation: severe irritation, coughing.

ingestion: g/i irritation, burns, also sedation,twitching.

medical cond aggravated by exposure: persons with a history of
respiratory problems may be at increased risk from fumes.

First Aid

First aid: eye-flush with water 15 minutes.Get medical care. Skin-remove
contaminated clothing.Wash with soap & water. Inhalation-remove to
fresh air.Restore breathing.Get immediate medical care.

ingestion-do no t induce vomiting.Give milk of magnesia,plus a
large quantity of water.Give nothing by mouth if unconscious.Get
immediate medical care.

Chemical Properties

Hcc: c1
boiling pt: b.P. Text: 221f,105c
spec gravity: 1.015
ph:
evaporation rate & reference: 0.64 (reference unknown)
solubility in water: miscible
appearance and odor: dark red liquid, no odor
corrosion rate: 0.207ipy

Reactivity

Stability indicator/materials to avoid: yes
strong oxidizing agents,acids,active metals.

stability condition to avoid: extreme heat or flames,contact with strong
oxidizing agents,acids,active metals such as iron,aluminum or
zinc,alkaliies.

hazardous decomposition products: toxic fumes of arsenic and chlorides.

conditions to avoid polymerization: will not occur.

Proper Disposal

Waste disposal methods: dispose of in accordance with local, state and
federal environmental regulations. This product contains a
chemical/chemicals subject to sara 313 (40cfr372). Product contains
a chemical known to state of california to cause cancer.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: hydrogen chloride (hydrochloric acid) (sara 302/313)
(cercla)
cas: 7647-01-0
rtecs #: mw4025000
fraction by wt:
osha pel: c 5 ppm
acgih tlv: c 5 ppm; 9495
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs

ingred name: sodium arsenite (sara 302/313) (cercla)
cas: 7784-46-5
rtecs #: cg3675000
fraction by wt:
osha pel: see 1910.1018
acgih tlv: 0.01 mg(as)/m3,a1;95
epa rpt qty: 1 lb
dot rpt qty: 1 lb

ingred name: other components (type not specified)
fraction by wt:

ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: to 100%

MSDS BNMPF 10113/10114/7769-SPADNS REAGENT FOR FLUORID

Hazards

Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: yes iarc: yes osha: yes
health hazards acute and chronic: product is corrosive to body tissues.

toxicity is by corrosivity in all three routes of entry. Causes
burns on contact. Chronic contact in dilute form may cause
ulceration. It contains arsenic in low concentration which is
toxic if ingestedor if contact is prolonged or repeated.

explanation of carcinogenicity: this product contains inorganic arsenic
which is listed by iarc, ntp, and osha as a carcinogen.

effects of overexposure: eye: severe irritation, burns. Skin: irritation,
burns. Inhalation: severe irritation, coughing. Chronic inhalation
may cause ulceration. Ingestion: g/i irritation, burns, also
sedation, twitching, corro sion of living tissue.

medical cond aggravated by exposure: persons with a history of
respiratory problems or skin conditions may be at increased risk
from exposure.

First Aid

First aid: get medical attention immediately.Eye/skin: immediately flush
with water for at least 15 minutes.Hold eyelids open.Inhaled: remove
to fresh air & provide oxygen/cpr if needed.Oral: do not induce
vomiting .If conscious,drink large amount of water/milk.Drink at
least 1 ounce of milk of magnesia in an equal amount of water or
the white of three eggs.Call a physician immediately.

Chemical Properties

Hcc: c1
boiling pt: b.P. Text: 221f,105c
spec gravity: 1.015
ph:
solubility in water: miscible
appearance and odor: dark red liquid, no odor

Reactivity

Stability indicator/materials to avoid: yes
strong alkalis, reactive metals, strong oxidizers
stability condition to avoid: fire
hazardous decomposition products: fumes of chlorine may form.

Proper Disposal

Waste disposal methods: dispose of in accordance with all local, state
and federal regulations.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: hydrogen chloride (hydrochloric acid) (sara iii)
cas: 7647-01-0
rtecs #: mw4025000
fraction by wt:
other rec limits: none specified
osha pel: c 5 ppm
acgih tlv: c 5 ppm; 9192
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs

ingred name: sodium arsenite (sara iii)
cas: 7784-46-5
rtecs #: cg3675000
fraction by wt:
other rec limits: none specified
osha pel: see 1910.1018
acgih tlv: 0.2 mg as/m3; 9192
epa rpt qty: 1 lb
dot rpt qty: 1 lb

ingred name: zirconium chloride oxides octahydrate/zirconyl chloride
cas: 13520-92-8
rtecs #: zh7250000
fraction by wt:
other rec limits: none specified
osha pel: 5 mg/m3 (zr)
acgih tlv: 5 mg/m3 (zr)

MSDS BXYDQ SPADNS REAGENT FOR FLUORIDE,444-11

Hazards

Ld50 lc50 mixture: ld50 (oral, rat) is 540 mg/kg.

routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eyes, skin, teeth,
respiratory & gi tracts. Acute- corrosive. Inhale: may cause
inflammation, chocking, coughing, lung damage. Eye/skin: severe
burns. May cause permanent eye damage. Oral: immediate pain & burns
of mouth, throat, esophagus & gi tract. May be fatal. Chronic-
erosion of teeth.

explanation of carcinogenicity: none
effects of overexposure: irritation, burns, coughing, difficult
breathing, chest pain, abdominal pain, nausea, vomiting, dental
erosion, chocking, skin redness or discoloration, deep ulceration,
eye damage, death, sedation
medical cond aggravated by exposure: damaged skin, eye disorders,
lung/respiratory system diseases

First Aid

First aid: get medical care immediately in all cases.

eyes/skin: immediately flush with water for at least 15 minutes.

keep eyelids open. Treat for chemical burns if necessary.

inhalation: remove to fresh air. Pro vide cpr/oxygen if needed.

ingestion: ifconscious, drink large amount of milk/water. Do not
induce vomiting.

Chemical Properties

Hcc: c1
nrc/state lic num: not relevant
boiling pt: b.P. Text: 221f,105c
spec gravity: 1.015
ph:
evaporation rate & reference: 0.64 (ref unknown)
solubility in water: miscible
appearance and odor: dark red solution - sharp, irritating odor
corrosion rate: 0.207

Reactivity

Stability indicator/materials to avoid: yes
strong oxidizing agents, acids, alkalies, active metals such as iron,
aluminum or zinc, cyanides, sulfides
stability condition to avoid: excessive heat, flames
hazardous decomposition products: may emit hydrogen chloride vapors or
gas, arsenic and chlorides.

Proper Disposal

Waste disposal methods: observe federal, state and local environmental
regulators for proper disposal. Consider recycling.

Ingredients List

Ingred name: hydrogen chloride (hydrochloric acid) (sara 302/313)
(cercla)
cas: 7647-01-0
rtecs #: mw4025000
fraction by wt:
other rec limits: none recommended
osha pel: c 5 ppm
acgih tlv: c 5 ppm; 9495
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs

ingred name: sodium arsenite (sara 302/313) (cercla)
cas: 7784-46-5
rtecs #: cg3675000
fraction by wt:
other rec limits: none recommended
osha pel: see 1910.1018
acgih tlv: 0.01 mg(as)/m3,a1;95
epa rpt qty: 1 lb
dot rpt qty: 1 lb

ingred name: other components
fraction by wt:
other rec limits: none recommended

ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
other rec limits: none recommended
osha pel: not relevant
acgih tlv: not relevant

MSDS CHVWY SPADNS REAGENT FOR FLUORIDE

Hazards

Ld50 lc50 mixture: oral ld50 (rat) is =540 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eye-causese eye burns. Skin-causes
burns. Ingestion-causes burns, ulcerations of the digestive tract.

explanation of carcinogenicity: not carcinogenic.

effects of overexposure: ingestion-abdominal pain, nausea, vomiting,
sedation, muscular twitching. Inhalation-causes burns, choking,
teeth erosion, difficulty breathing.

medical cond aggravated by exposure: preexisting eye conditions, skin
conditions, respiratory conditions, impaired puolmonary functions
such as obstructive airwat disease.

First Aid

First aid: eye-immediately flush eyes with water for 15 min. Call a
physician. Skin-wash skin with plenty of water for 15 min. Remove
contaminated clothes. Call physician immediately. Ingestion-do not
induce vom iting. Give 1-2 glasses of water. Call a physician
immediately. Never give anything by mouth to an unconscious person.

inhale-remove to fresh air. Give artificial respiration if needed.

call physician

Chemical Properties

Hcc: c1
boiling pt: b.P. Text: 221f,105c
spec gravity: 1.015
ph:
evaporation rate & reference: 0.64 (water=1)
solubility in water: soluble
appearance and odor: dark red liquid. Acidic odor.

Reactivity

Stability indicator/materials to avoid: yes
may react violently if contact with strong bases, oxidizers.

incompatible with metals.

stability condition to avoid: evaporation. Heating to decomposition.

hazardous decomposition products: heating to decomposition releases
toxic and/or corrosive fumes of: arsenic compounds, chlorides.

Proper Disposal

Waste disposal methods: epa waste id number: d002, d004.

Ingredients List

Ingred name: hydrogen chloride (hydrochloric acid) (sara 302/313)
(cercla)
cas: 7647-01-0
rtecs #: mw4025000
fraction by wt: 30-40%
other rec limits: none recommended
osha pel: c 5 ppm
acgih tlv: c 5 ppm; 9596
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs

ingred name: other components
fraction by wt:
other rec limits: none recommended

ingred name: sodium arsenite (sara 302/313) (cercla)
cas: 7784-46-5
rtecs #: cg3675000
fraction by wt: .01-.1%
other rec limits: none recommended
osha pel: see 1910.1018
acgih tlv: 0.01 mg(as)/m3,a1;95
epa rpt qty: 1 lb
dot rpt qty: 1 lb

ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 60-70%
other rec limits: none recommended
osha pel: not relevant
acgih tlv: not relevant

MSDS CLGZG 444, SPADNS REAGENT FOR FLUORIDE

Hazards

Ld50 lc50 mixture: ora, rat, ld50: 540 mg/kg.

routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: eye contact: causes eye burns. Skin
contact: causes burns. Skin absorption: none reported. Ingestion:
causes burns, ulceration of the digestive tract, abdominal pain,
nausea, vomiting, sedation, muscul ar twitching. Inhalation: causes
burns, choking, teeth erosion, difficult breathing. Chronic
effects: chronic overexposure may cause erosion of the teeth.

explanation of carcinogenicity: this product does not contain any osha
listed carcinogens. Sodium arsenite ingredient is an iarc group 3
carcinogen; " the agent is not classifiable as to its
carcinogenicity to humans". This product does not contain any ntp
listed chemicals.

effects of overexposure: eye contact: burns. Skin contact: burns.

ingestion: burns, ulceration of digestive tract, abdominal pain,
nausea, vomiting, sedation, muscular twitching. Inhalation: burns,
choking, teeth erosion, dif ficult breathing.

medical cond aggravated by exposure: preexisting: eye conditions, skin
conditions, respiratory conditions, impaired pulmonary functions
such as obstructive airway diseases.

First Aid

First aid: eye contact: immediately flush eyes with water for 15
minutes. Call a physician. Skin contact: wash skin with plenty of
water for 15 minutes. Remove contaminated clothing. Call physician
immediately. ingestion: do not induce vomiting. Give 1-2 glasses
of water. Call a physician immediately. Never give anything by
mouth to an unconscious person. Inhalation: remove to fresh air.

give artificial resp iration if needed. Call physician.

Chemical Properties

Hcc: c1
boiling pt: =105.C, 221.F
melt/freeze pt: m.P/f.P text: n/d
vapor pres: n/d
vapor density: n/d
spec gravity: 1.015 (h2o=1)
ph:
evaporation rate & reference: 0.64 (water=1)
solubility in water: soluble.

appearance and odor: dark red liquid. Acidic odor.

Reactivity

Stability indicator/materials to avoid: yes
may react violently if contact with: strong bases, oxidizers.

incompatible with: metals.

stability condition to avoid: stable when stored under proper
conditions. avoid , heating to decomposition.

hazardous decomposition products: contact with metals may release
flammable hydrogen gas. Heating to decomposition releases toxic
and/or corrosive fumes of: arsenic compounds, chlorides.

conditions to avoid polymerization: will not occur.

Proper Disposal

Waste disposal methods: epa waste id number: d002, d004. Dispose of
material in an epa approved hazardous waste facility. These
disposal guidelines are based on federal regulations and may be
superseded by more stringent sta te and local requirements. Please
consult local environmental regulators for more information.

Ingredients List

Ingred name: hydrochloric acid
cas: 7647-01-0
rtecs #: mw4025000
minumum % wt: 30.

maxumum % wt: 40.

osha pel: c 5 ppm
acgih tlv: c 5 ppm
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs

ingred name: other components
rtecs #: 1003292oc
< wt: .1

ingred name: sodium arsenite
cas: 7784-46-5
rtecs #: cg3675000
minumum % wt: .01
maxumum % wt: .1
osha pel: 0.01 mg(as)/m3
acgih tlv: 0.2 mg (as)/m3
epa rpt qty: 1 lb
dot rpt qty: 1 lb

ingred name: demineralized water
cas: 7732-18-5
rtecs #: zc0110000
minumum % wt: 60.

maxumum % wt: 70.

other rec limits: none recommended