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Methanal (formaldehyde)
Acyclic aldehydes without other oxygen function
Chemicals-organic
Y - Indicates information is in the hazardous materials information resource system (hmirs).
PMICA - Item does not contain precious metal.
ADPE- Represents items with no adp components
CRITL- The item does not have a nuclear hardened feature but does have other critical featur (s) such as tolerance, fit restrictions or application.
044155 - Chem: corrosive matls, group a
635 - Chemicals, other than drugs or sundries
9 - Other or no special handling required (sh)
A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.
C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp
W - Rating variable
W - Rating variable
Z - No special type of cargo code applicable
Questions & Answers: |
|
| What are the historical prices recorded for this stock number? | |
| Historical data shows pricing from $68.85 to $114.75.. | |
| Does NSN 6810-01-017-3542 have a shelf life? | |
| No. There is no shelf life applicable for this NSN. | |
| What NATO entities are users of this NSN? | |
| Department Of The Navy, and Turkey | |
| What is the NIIN of NSN 6810-01-017-3542? | |
| 010173542 or 01-017-3542 | |
| Does NSN 6810-01-017-3542 require demilitarization? | |
| Yes - ITAR Controlled | |
| What is the most recent solicitation for NSN 6810-01-017-3542? | |
| No solicitations for this NSN. | |
| When was this national stock number assigned to the federal catalog? | |
| Mar 06, 1976 | |
Routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: yes iarc: yes osha: yes
health hazards acute and chronic: acute: eyes: can cause sev
irri,redness, tearing,blurred vision.Liq can cause sev/perm eye
dmg. Skin: can cause mod injury-reddening, swelling. Sensitizer
(allergic reaction poss).Liq causes drying, c racking, scaling.
rptd/prlng cont causes hardening (tanning). Inhal: highly irri to
nasal passages. (see efts of overexp
explanation of carcinogenicity: formaldehyde: osha regulated, iarc class
2a, ntp class 2.
effects of overexposure: hlth haz: can cause inflamm of nose, throat,
lung linings, pneum/abnorm accum of fluid in lungs. Sensit. Ingest:
toxic. Causes sev irrit/inflamm of mouth, throat, stom. Sev stom
pains follow, w/ poss loss of consciousness. Causes blindness,
stupor, naus, vomit leading to sev illness, poss death. Chronic:
eye dmg.Sensit
medical cond aggravated by exposure: none specified by manufacturer.
First aid: eyes: wash with copious qtys of water for at least 15 min.
call md. Skin: wash with soap & water. Remove contam clthg. If
irrit occurs or persists, seek md. Inhal: remove to fresh air.
administer appr oved oxygen supply if breathing is difficult.
administer artf resp or cpr if breathing has ceased. Call md.
ingest: induce vomiting. Call md. Never give anything by mouth to
an unconscious person.
Hcc: f3
vapor density: 1.01
evaporation rate & reference:
solubility in water: 100%
appearance and odor: colorless liquid with pungent odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
avoid contact with strong acids, bases, and oxidizing agents. Nox @
about 180 degrees, reaction becomes explosive.
stability condition to avoid: heat, sparks and flame
hazardous decomposition products: carbon dioxide and carbon monoxide.
gaseous formaldehyde on heating.
conditions to avoid polymerization: trioxymethylene precipitate can be
formed on long standing at very low temperatures.
Waste disposal methods: dispose in accordance with local, state and
federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: formaldehyde (sara iii)
cas: 50-00-0
rtecs #: lp8925000
fraction by wt:
other rec limits: adptd tlv stel: 2ppm
osha pel: see 1910.1048
acgih tlv: c 0.3 ppm; a2; 9293
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 1.5%
other rec limits: 250 ppm stel
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
Ld50 lc50 mixture: none specified by manufacturer.
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: yes iarc: yes osha: yes
health hazards acute and chronic: acute: inhal & ingest are harmful & may
be fatal. Inhal of vaps may cause hdch/naus, vomit, dizz, drow,
irrit of resp tract, & loss of consciousness. Cont w/skin/eyes may
cause sev irrit/burns. Prlngd cont may cause skin sensit.
substance is readily absorbed thru skin. Ingest may cause
blindness. (efts of overexp)
explanation of carcinogenicity: formaldehyde: group 2a(iarc), anticipated
to be a carcinogen (ntp), osha regulated.
effects of overexposure: hlth haz: ingest may cause naus, vomit, gi
irrit & burns to mouth & throat. Chronic: chronic effects of
overexp may cause kidney &/or liver damage.
medical cond aggravated by exposure: none identified.
First aid: ingest: give lage amounts of water. Induce vomiting. Inhal:
remove to fresh air. If not breathing, give artf resp. If breathing
is dfclt, give oxygen. Eyes: immed flush with plenty of water for
at lea st 15 min. Skin: immed flush with plenty of water for at
least 15 min.
Hcc: f7
boiling pt: b.P. Text: 212f,100c
solubility in water: complete
appearance and odor: colorless liquid. Slightly pungent odor.
Stability indicator/materials to avoid: yes
strong oxidizing agents/strong acids, strong bases, alkalies, alkali
metals amines & ammonia, phenol, strong (supp data)
stability condition to avoid: heat, flame, other sources of igniton.
hazardous decomposition products: formaldehyde, carbon monoxide, carbon
dioxide.
Waste disposal methods: dispose i/a/w all applicable federal, state, and
local environmental regulation.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: formaldehyde
cas: 50-00-0
rtecs #: lp8925000
fraction by wt:
osha pel: see 1910.1048
acgih tlv: c 0.3 ppm; a2; 9293
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
ingred name: methanol; (methyl alcohol)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt:
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 95%
Ld50 lc50 mixture: oral ld50 (rat) is 800 mg/kg.
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: yes iarc: yes osha: yes
health hazards acute and chronic: acute: eyes: irritation,damage.
skin: irritation,burns,absorbtion with same symptoms as ingestion.
inhalation: respiratory tract irritation,injury,death.
ingestion: irritation,vomiting,diarrhea,blindness,
unconsciousness,death. Chronic: dermatitis,allergic reaction,vision
impairment,liver enlargement,suspected carcinogen.
explanation of carcinogenicity: contains f [50-00-0] which is
listed by ntp and iarc and regulated by osha as a carcinogen.
effects of overexposure: eyes: irritation,pain,blurred vision,damage.
skin: irritation, pain,burns,absorbtion with same symptoms as
ingestion. Inhalation: sore throat,respiratory tract
irritation,injury,pulmonary edema,pneumonit is,death.
ingestion: pain,vomiting,headache,diarrhea,gi tract pain,weak
irregular pulse,blindness,unconsciousness,death.
medical cond aggravated by exposure: persons with pre-existing skin and
eye problems,impaired liver,kidney or respiratory function may be
at increased risk from exposure.Previously exposure may cause
allergic reaction to future exp0sure.
First aid: eyes: flush with large amounts of water. Get medical
attention. Skin: remove contaminated clothing. Flush area with
large amounts of water. Get medical attention. Inhalation: move to
fresh air. If not breathing, give cpr. If breathing difficult,
give oxygen. Get medical attention. Ingestion: induce vomiting by
giving two glasses of water/milk and sticking finger down throat.
get medical attention.
Hcc: f6
boiling pt: b.P. Text: 205f,96c
melt/freeze pt: m.P/f.P text: 5f,-15c
vapor density: 1.04
spec gravity: 1.08
solubility in water: infinite
appearance and odor: clear, colorless liquid. Pungent odor.
Stability indicator/materials to avoid: yes
reacts explosively with nitrogen dioxide at 356f; violently with
perchloric acid,nitromethane,perchacid-aniline mixture.
stability condition to avoid: extremes in temperature, sparks, and
flame. Avoid oxidizing agents and alkalies.
hazardous decomposition products: if involved in fire, irritating
gaseous formaldehyde and cabon monoxide may be released.
conditions to avoid polymerization: trioxymethylene precipitate can form
on standing at very low temperatures. Paraformaldehyde may form at
low temperature.
Waste disposal methods: dispose in accordance with local, state, and
federal regulations. If permitted, may be disposed in approved
facility or dissolved in appropriate combustible solvent and
atomized in a rcra approved che mical incinerator equipped with an
afterburner.
Ingred name: formaldehyde (sara iii)
cas: 50-00-0
rtecs #: lp8925000
fraction by wt: 4%
other rec limits: mfr, tlv stel: 2ppm
osha pel: 1 ppm,see 1910.1048
acgih tlv: c 0.3 ppm; a2; 9394
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 1.0-1.5%
other rec limits: 250 ppm stel
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 94
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
other rec limits: none recommended
Ld50 lc50 mixture: see ingredients
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: yes iarc: yes osha: yes
health hazards acute and chronic: acute: may be fatal by ingest,
inhal/skin absorption. Corr. Sev lachrymator. 100ppm is idlh.
target organs: cns, liver, kidneys, spleen, eyes, skin, lungs,
pancreas & gi, resp, repro & periphereal nerv ous systems. Eye: vaps
& mist cause tearing & sev irrit. Liq causes sev burns. Cntct can
rslt in corneal(efts of overexp)
explanation of carcinogenicity: formaldehyde: iarc mono, vol 62, pg 217,
1995: group 2a. Ntp 7th annual rpt on carcins, 1994: antic to be
carcin. (supdat)
effects of overexposure: hlth haz: dmg/blindness. Skin: liq cntct causes
drying, scales & cracking. Prlngd & rptd cntct causes hardening or
tanning eft. May cause allergic derm. Liq can be absorbed in tox
amts thru intact skin (massive skin cntct can cause visual
impairment & death). Inhal: highly tox. Vaps & mists extremely irrit
to (ing 4)
medical cond aggravated by exposure: none specified by manufacturer.
First aid: eyes: immed first aid needed to pvnt dmg. Immed flush
w/copious qtys of water for at lst 20 min holding lids apart to
ensure flushing of entire surf. Seek immed med attn. Skin: immed
first aid needed to pvnt dmg. Immed flush w/plenty of water for at
lst 20 min while removing contam clthg & shoes. Seek immed med
attn. Wash contamd clthg before reuse. Inhal: remove to fresh air.
admin apprvd (ing 12)
Boiling pt: b.P. Text: >194f,>90c
melt/freeze pt: m.P/f.P text: supdat
vapor pres: 40 @ 39c
vapor density: 0.62-1.16
spec gravity: supdat
ph: supdat
solubility in water: miscible
appearance and odor: clear, colorless liquid with strong formaldehyde
odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
may react violently w/acids, oxidizing agents, oxides, amines, bases.
cntct nehc for more info on matls to avoid .
stability condition to avoid: heat, sparks and flame, temperatures below
20c.
hazardous decomposition products: not available. Rxn w/hydrochloric acid
may form bis-chloromethyl ether, a human carcin according to acgih
& iarc.
Waste disposal methods: according to all applicable federal, state and
local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: formaldehyde (sara 302/313) (cercla). Lel: 7%; uel: 73% (for
formaldehyde gas). Ld50: (oral, rat) 100 mg/kg.
cas: 50-00-0
rtecs #: lp8925000
fraction by wt: 30-40%
osha pel: n/k
acgih tlv: 0.3 ppm, c
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
ingred name: methanol (sara 313) (cercla). ld50: (oral, rat) 5628
mg/kg.
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 5-15%
osha pel: 200 ppm, s
acgih tlv: 200 ppm; 250 stel, s
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
osha pel: n/k
acgih tlv: n/k
ingred name: efts of overexp: nose, throat, lungs & muc membs. Bronch,
bronchopneum, pulm edema & chem pneumit may occur. (ing 5)
rtecs #: 9999999zz
ingred name: ing 4: prlngd expos may rslt in more sev irrit & tiss dmg.
methanol can cause cns depress (w/hdch, dizz, naus, (ing 6)
rtecs #: 9999999zz
ingred name: ing 5: vomit, drow & incoord), cough, chest pain & dyspnea.
can affect optic nerve rsltg in blindness. Ingest: (ing 7)
rtecs #: 9999999zz
ingred name: ing 6: highly tox. Vaps, mists & liq extremely irrit to
mouth, throat & stom. Swallowing liq inflames tiss w/sev (ing 8)
rtecs #: 9999999zz
ingred name: ing 7: abdom pain, naus, vomit, hematuria, proteinuria,
anuria, acidosis & poss uncon. Methanol can affect optic (ing 9)
rtecs #: 9999999zz
ingred name: ing 8: nerve rsltg in blindness. Chronic: poss repro
disorders from prlngd expos (embryotox). Mutagen. Passes thru(ing
10)
rtecs #: 9999999zz
ingred name: ing 9: placental barrier in animal. May cause sensit by
inhal(asthma) & skin cntct (derm). Can cause cns depress.(ing 11)
rtecs #: 9999999zz
ingred name: ing 10: may cause dmg to cns, resp sys, lungs, eyes, skin,
gi tract, liver, spleen & kidneys.
rtecs #: 9999999zz
ingred name: first aid: oxygen supply if brthg dfclt. Admin artf
resp/cpr if brthg ceases. Seek immed med attn. Ingest: if (ing 13)
rtecs #: 9999999zz
ingred name: ing 12: conscious, wash out mouth w/water. Have conscious
person drink several glasses of water to dilute. Seek (ing 14)
rtecs #: 9999999zz
ingred name: ing 13: immed med attn. Never give anything by mouth to
uncon or convulsing person.
rtecs #: 9999999zz
ingred name: spill proc: use non-spkg tools. Wash spill site after matl
pick up is complete. Do not empty into drains. Do not(ing 16)
rtecs #: 9999999zz
ingred name: ing 15: touch spilled matl. Runoff to sewer may create fire
or explosion hazard.
rtecs #: 9999999zz
ingred name: hndlg/stor: do not wash down drain. Do not breathe
gas/fumes/vap/spray. If insufficient vent, wear suitable niosh(ing
18)
rtecs #: 9999999zz
ingred name: ing 17: apprvd resp. Keep cntnr tightly clsd. Manipulate
under adeq fume hood. Take precs against electrostatic (ing 19)
rtecs #: 9999999zz
ingred name: ing 18: discharges. Ground cntnr while dispensing. Ground
all equip containing matl. Use only explo proof equip. (ing 20)
rtecs #: 9999999zz
ingred name: ing 19: use non-spkg tools. Watch for accum in low confined
areas. Do not use press to dispense.
rtecs #: 9999999zz
ingred name: other precs: incandescent light. Empty cntnrs may cntn haz
residue. Hndl & open cntnr w/care. Prod must be (ing 22)
rtecs #: 9999999zz
ingred name: ing 21: manipulated by qualified pers. I/a/w good stor &
hndlg practs. Harmful to aquatic life at low concs. (ing 23)
rtecs #: 9999999zz
ingred name: ing 22: can be dangerous if enters drinking water intakes.
do not contam water supplies, lakes, streams, ponds or rivers.
rtecs #: 9999999zz
ingred name: eye prot: & full length faceshield . Do not wear contact
lenses.
rtecs #: 9999999zz
ingred name: other prot equip: as approp: fshlds, rub suits & boots.
ensure eyewash & sfty shower proximal to work station location.
rtecs #: 9999999zz
Ld50 lc50 mixture: formaldehyde oral ld50: 100 mg/kg (rat)
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: yes iarc: yes osha: yes
health hazards acute and chronic: effects of acute exposure: may be
fatal by ingestion, inhalation or skin absoption. Corrosive. Severe
lachrymator. 100 ppm is immediately dangerous to life or health.
target organs: central nervous sy stem, liver, kidneys, spleen,
eyes, skin, gastrointestinal system, respiratory system, lungs,
reproductive system, peripheral nervous system, pancreas. eye:
vapors and mist causes tearing and severe irritation. Liquid
causes severe burns. Can result in corneal damage or blindness.
irritation: eye-rabbit 750 ug/24h severe. Skin: contact with liquid
causes drying, scaling and cracking. Prolonged an d (signs and
symptoms of overexposure)
explanation of carcinogenicity: formaldehyde: iarc, group 2a, vol. 62,
p. 217, 1995. ntp reasonably anticipated carcinogen, ntp ninth
report on carcinogens, 1998. osha regulated 29 cfr 1910.1048.
effects of overexposure: health hazards acute and chronic
(cont): -repeated contact causes hardening or tanning effect. May
cause allergic dermatitis. Liquid can be absorbed in toxic amounts
through intact skin (massive skin c ontact can cause visual
impairment and death). Irritation: skin-rabbit 2mg/24h severe.
inhalation: highly toxic. Vapors and mists are extremely irritating
to the nose, throat, lungs, mucous membranes. bronchitis,
bronchopneumonia, pulmonary edema and chemical pneumonitis may
occur. Prolonged exposure may result in more severe irritation and
tissue damage. Methanol can cause severe central nervous system
(ecological info)
First aid: eye contact: immediate first aid is needed to prevent eye
damage. Immediately flush eyes with copious quantities of water for
at least 20 minutes holding lids apart to ensure flushing of entire
surfac e. Seek immediate medical attention. Skin: immediate first
aid is needed to prevent skin damage. Immediately flush skin with
plenty of water for at least 20 minutes while removing contaminated
clothin g and shoes. Seek immediate medical attention. Wash
contaminated clothing before reuse. Inhalation: remove patient to
fresh air. Administer approved oxygen supply if breathing
difficult. Administer ar tificial respiration or cpr (sara iii)
Boiling pt: =90.C, 194.F
b.P. Text: 90-100c
melt/freeze pt: m.P/f.P text: insoluble polymer forms
vapor pres: 40 mmhg @39c (approx)
vapor density: 0.62-1.16
spec gravity: 1.08-1.0975 (water=1)
ph: 2.8 - 4.0 (25c)
evaporation rate & reference: not available
solubility in water: miscible
appearance and odor: clear, colorless liquid with strong formaldehyde
odor.
percent volatiles by volume: 100% (v/v)
Stability indicator/materials to avoid: yes
may react violently with: acids, alkalis, anhydrides, isocyantaes,
urea, phenol, oxidizing agents, oxides, organic oxides, reducing
agents, ammonia, aniline, magnesium carbonate, performic acid,
alkali metals, amines, (stab
stability condition to avoid: heat, sparks and flame, temperatures below
20c. materials to avoid (cont): hydrogen peroxide, nitromethane,
nitrogen dioxide, perchloric acid, (conditions to avoid
polymerization)
hazardous decomposition products: not available. reaction products:
reaction with hydrochloric acid may form bis-chloromethyl ether, a
confirmed human carcinogen according to acgih and carcinogenic to
humans according to iarc.
conditions to avoid polymerization: will not occur. stability conds
to avoid (cont): bases, monomers, water reactive materials,
magnesium carbonate hydroxide.
Waste disposal methods: according to all applicable regulations.
Ingred name: formaldehyde
cas: 50-00-0
rtecs #: lp8925000
minumum % wt: 30.
maxumum % wt: 40.
other rec limits: 0.016 ppm, c 0.1 ppm
acgih stel: 0.3 ppm, .37 mg/m3 c
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
ingred name: methanol
cas: 67-56-1
rtecs #: pc1400000
minumum % wt: 5.
maxumum % wt: 15.
acgih tlv: 200 ppm, 262 mg/m3,s
acgih stel: 250 ppm, 328 mg/m3,s
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance