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Sulfuric acid and oleum
Sulfuric acid; oleum
Chemicals-inorganic
Y - Indicates information is in the hazardous materials information resource system (hmirs).
PMICA - Item does not contain precious metal.
CRITL- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.
043940 - Chemicals noi
635 - Chemicals, other than drugs or sundries
9 - Other or no special handling required (sh)
A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.
H - Instruments/equipment/supplies for radio, communications, electrical, laboratory, etc. (includes signal corps)
W - Rating variable
W - Corrosive materials, un class 8 (corrosive label)
Questions & Answers: |
|
| What are the historical prices recorded for this stock number? | |
| Historical data shows pricing from $1,566.82 to $2,611.37.. | |
| Does NSN 6810-01-031-4652 have a shelf life? | |
| No. There is no shelf life applicable for this NSN. | |
| What NATO entities are users of this NSN? | |
| Department Of The Army, Department Of The Navy, Tennessee Valley Authority, and Republic Of Korea | |
| What is the NIIN of NSN 6810-01-031-4652? | |
| 010314652 or 01-031-4652 | |
| Does NSN 6810-01-031-4652 require demilitarization? | |
| Yes - ITAR Controlled | |
| What is the most recent solicitation for NSN 6810-01-031-4652? | |
| No solicitations for this NSN. | |
| When was this national stock number assigned to the federal catalog? | |
| Nov 24, 1976 | |
Ld50 lc50 mixture: ld50: (oral rat) 2140 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: skin: severe burns, dermatitis. Eyes:
loss of vision. Inhalation: respiratory tract irritation or damage,
burns. Ingestion: may be fatal.
explanation of carcinogenicity: not relevant
effects of overexposure: hlth haz: conc of the soln & duration of
exposure. Contact w/eyes may result in perm visual loss unless
removed quickly by thorough irrigation w/water. Swallowing may be
fatal. Inhalation of concentrat ed vapor/mist may damage
respiratory tract. Rptd skin contact w/dilute soln may cause derm.
may cause dental erosion.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: eyes: flush immed with water for at least 15 minutes holding
eyelids apart. Skin: flush immed with water for at least 15
minutes. Remove contaminated clothing. Wash clothing before reuse.
ingestion: d rink copious amounts of water or milk. Do not induce
vomiting. Inhalation: get fresh air. If not breathing, give
artificial respiration. Get immediate medical attention in all
cases.
Hcc: c1
boiling pt: b.P. Text: 535f,279c
spec gravity: 1.835
evaporation rate & reference: < 1 (butyl acetate = 1)
solubility in water: complete
appearance and odor: clear to slightly cloudy, oily liquid. Odorless to
slightly pungent odor.
Stability indicator/materials to avoid: yes
metals, metal oxides, hydroxides, nitrates, amines, carbonates,
alkaline materials
stability condition to avoid: open flames, sparks, high heat, moisture
hazardous decomposition products: explosive hydrogen gas is generated by
the action of acid on most metals and may accumulate in metal
containers.
Waste disposal methods: dispose of spilled, neutralized, waste product,
contaminated soil, and other materials in acordance wiht all local,
state, and federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 75-100%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 1-25%
ingred name: supp data: concentrated acid is a strong oxidizing agent.
may cause ignit of combust matls on cont w/generation (ing 4)
rtecs #: 9999999zz
ingred name: ing 3: of sulfur dioxide fumes. Avoid open flames or sparks.
rtecs #: 9999999zz
ingred name: first aid proc: remove to fresh air. If not breathing,
perform artificial respiration. Get medical attention.
rtecs #: 9999999zz
ingred name: spill proc: w/water i/a/w applic regs. Spills of 1000 lbs or
more must be reported to natl response ctr (800-424-8802).
rtecs #: 9999999zz
ingred name: vent: for design of exhaust systems.
rtecs #: 9999999zz
ingred name: other prot equip: hood & full body suit recommended.
rtecs #: 9999999zz
Ld50 lc50 mixture: none specified by manufacturer.
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: chronic: inhalation of vapors may
cause severe irritation or burns of the respiratory system,
pulmonary edema, or lung inflammation. May cause severe burns to
skin or eyes. Ingestion may cause severe burns to mouth, throat,
and stomach. May affect kidney function. Chronic: may damage lungs.
explanation of carcinogenicity: this product is not listed by iarc, ntp,
or osha as a carcinogen.
effects of overexposure: severe irritation or burns to eyes, nose and
throat. Pulmonary edema, bronical emphysema, conjunctivitis,
stomatitis, dental erosion, nausea and vomiting.
medical cond aggravated by exposure: open woundws and sores. Respiratory
ailments such as emphysemia and bronchitis.
First aid: inhalation: remove to fresh air. Resuscitate if not
breathing. Get medical attention. Eyes: immediately flush with
water for at least 15 minutes holding eyelids open. Get medical
attention. Skin: remo ve contaminated clothing. Wash with water for
at least 15 minutes. Get medical advice. Ingestion: do not induce
vomiting. Give nothing by mouth if unconscious. Get immediate
medical attention.
Hcc: c1
boiling pt: b.P. Text: 535f,279c
vapor pres: < 0.5
spec gravity: 1.8357
evaporation rate & reference:
solubility in water: complete
appearance and odor: clear to slightly turbid liquid; off white to straw
color; usually odorless.
Stability indicator/materials to avoid: yes
alkaline materials;combustible and organic materials;salts of other
acids; hydrated materials.
stability condition to avoid: addition of water causes large temperature
increase.
hazardous decomposition products: oxides of sulfur
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state, and local environmental regulations.
waste may qualify as hazardous waste under rcra (corrosive-d002).
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93-95%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
other rec limits: none recommended
Ld50 lc50 mixture: ld50 (oral rat) is 2140 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation- vapors cause severe
irritation or burns of the respiratory system, pulmonary edema, or
lung inflammation. Eyes- severe damage and possible blindness.
skin- causes burns and possible deep u lceration. Ingestion- severe
burns to mouth, throat, and stomach.
explanation of carcinogenicity: this chemical is not listed by iarc,
ntp, or osha as a carcinogen.
effects of overexposure: severe irritation or burns to eyes, nose and
throat. Pulmonary edema, bronical emphysema, conjunctivitis,
stomatitis, dental erosion, nausea and vomiting.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the respiratory tract may
be at increased risk from exposure.
First aid: inhalation: remove to fresh air. Resuscitate if not breathing.
get medical attention. Eyes: immediately flush with plenty of water
for 15 minutes holding eyelids open. Get prompt medical attention.
skin : remove contaminated clothing. Wash with plenty of water for
15 minutes. Get medical advice. ingestion: do not induce vomiting.
give nothing by mouth if unconscious. Get immediate medical
attention.
Hcc: c1
nrc/state lic num: none
boiling pt: b.P. Text: 529f,276c
decomp temp: decomp text: 644f,340c
vapor density: 3.38
spec gravity: 1.8354
ph: acid
solubility in water: complete
appearance and odor: clear, odorless liquid. No odor.
Stability indicator/materials to avoid: yes
strong oxidizing agents, metal powders, combustible materials.
stability condition to avoid: high heat, open flames and other sources
of ignition
hazardous decomposition products: oxides of sulfur and hydrogen gas.
Waste disposal methods: disposal should be made in accordance with all
applicable federal, state and local environmental regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara 302/313) (cercla)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93.2%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3/3 stel; 9495
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: rat,lc50: 510mg/m3/2h;ld50: 2140mg/kgrtecs
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eye, skin, respiratory &
gi tracts. Acute- corrosive! Causes severe eyes & skin burns. Mist
is extremely irritating to respiratory tract. Contact with eyes may
result in blindness. Swall owing may be fatal. Inhalation may
damage respiratory tract. Chronic- may cause dental erosion,
dermatitis, bronchitis.
explanation of carcinogenicity: none
effects of overexposure: severe irritation and burning, visual
impairment, dental erosion, cough, possible charring of skin, pain,
blindness
medical cond aggravated by exposure: open wounds and sores, respiratory
ailments such as emphysemia and bronchitis
First aid: get medical attention immediately. Eye/skin: immediately flush
with water for 15-20 minutes. Hold eyelids open. Continue rinsing
with normal saline until ph=7. Inhaled: remove to fresh air. Provide
oxyg en/cpr if needed. Oral: do not induce vomiting. If conscious,
drink large amount of water/milk. Ingested acid must be diluted
about 100 folds. If vomiting occurs, keep head below hips.
Hcc: c1
nrc/state lic num: not relevant
boiling pt: b.P. Text: 640f,338c
vapor pres: variable
spec gravity: 1.3945 - 1.4042
ph: 1.0
solubility in water: soluble
appearance and odor: clear liquid - practically odorless
Stability indicator/materials to avoid: yes
acetaldehyde, alcohols, strong bases, chlorates, nitrates, carbides,
most metals, organic materials, water, picrates
stability condition to avoid: adding water to acid (always add acid
slowly to water)
hazardous decomposition products: toxic oxides of sulfur
Waste disposal methods: dispose of spilled, neutralized, or waste
product, contaminated soil, and other materials in accordance with
all local, state, and federal regulations. Epa hazardous waste
number d002. Reportable quan tity (rq): 1000 lbs. Do not flush acid
to sewer.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara 302/313) (cercla)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 49 - 51%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3/3 stel; 9495
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
other rec limits: none recommended
osha pel: not relevant
acgih tlv: not relevant
Ld50 lc50 mixture: rat,lc50: 510mg/m3/2h;ld50: 2140mg/kgrtecs
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eye, skin, respiratory &
gi tracts. Acute- corrosive! Causes severe eyes & skin burns. Mist
is extremely irritating to respiratory tract. Contact with eyes may
result in blindness. Swall owing may be fatal. Inhalation may
damage respiratory tract. Chronic- may cause dental erosion,
dermatitis, bronchitis.
explanation of carcinogenicity: none
effects of overexposure: severe irritation and burning, visual
impairment, dental erosion, cough, possible charring of skin, pain,
blindness
medical cond aggravated by exposure: open wounds and sores, respiratory
ailments such as emphysemia and bronchitis
First aid: get medical attention immediately. Eye/skin: immediately flush
with water for 15-20 minutes. Hold eyelids open. Continue rinsing
with normal saline until ph=7. Inhaled: remove to fresh air. Provide
oxyg en/cpr if needed. Oral: do not induce vomiting. If conscious,
drink large amount of water/milk. Ingested acid must be diluted
about 100 folds. If vomiting occurs, keep head below hips.
Hcc: c1
nrc/state lic num: not relevant
boiling pt: b.P. Text: 529f (93%)
melt/freeze pt: m.P/f.P text: -20f (93%)
vapor pres:
vapor density: 3.4
spec gravity: 1.8357
ph:
evaporation rate & reference:
solubility in water: soluble
appearance and odor: clear to turbid, oily liquid - practically odorless
percent volatiles by volume: 0
Stability indicator/materials to avoid: yes
acetaldehyde, alcohols, strong bases, chlorates, nitrates, carbides,
most metals, organic materials, water
stability condition to avoid: adding water to acid (always add acid
slowly to water)
hazardous decomposition products: toxic oxides of sulfur
Waste disposal methods: dispose of spilled, neutralized, or waste
product, contaminated soil, and other materials in accordance with
all local, state, and federal regulations. Epa hazardous waste
number d002. Reportable quan tity (rq): 1000 lbs. Do not flush acid
to sewer.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara 302/313) (cercla)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93 - 98%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3/3 stel; 9495
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 2 - 7%
other rec limits: none recommended
osha pel: not relevant
acgih tlv: not relevant
Ld50 lc50 mixture: rat,lc50: 510mg/m3/2h;ld50: 2140mg/kgrtecs
routes of entry: inhalation: no skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eye, skin, respiratory &
gi tracts. Acute- corrosive! Causes severe eyes & skin burns. Mist
is extremely irritating to respiratory tract. Contact with eyes may
result in blindness. Swall owing may be fatal. Inhalation may
damage respiratory tract. Chronic- may cause dental erosion,
dermatitis, bronchitis.
explanation of carcinogenicity: none
effects of overexposure: severe irritation and burning, visual
impairment, dental erosion, cough, possible charring of skin, pain,
blindness, rapid destruction of all tissues contacted, chocking,
headache, dizziness
medical cond aggravated by exposure: open wounds and sores, respiratory
ailments such as emphysemia and bronchitis
First aid: get medical attention immediately. Eye/skin: immediately flush
with water for 15-20 minutes. Hold eyelids open. Continue rinsing
with normal saline until ph=7. Inhaled: remove to fresh air. Provide
oxyg en/cpr if needed. Oral: do not induce vomiting. If conscious,
drink large amount of water/milk. Ingested acid must be diluted
about 100 folds. If vomiting occurs, keep head below hips.
Hcc: c1
nrc/state lic num: not relevant
boiling pt: b.P. Text: 495f - 621f
melt/freeze pt: m.P/f.P text: -27f,-33c
vapor pres:
spec gravity: 1.82 - 1.84
ph:
solubility in water: complete
appearance and odor: oily liquid - practically odorless
Stability indicator/materials to avoid: yes
acetaldehyde, alcohols, strong bases, chlorates, nitrates, carbides,
most metals, organic materials, water
stability condition to avoid: adding water to acid (always add acid
slowly to water)
hazardous decomposition products: toxic oxides of sulfur
Waste disposal methods: dispose of spilled, neutralized, or waste
product, contaminated soil, and other materials in accordance with
all local, state, and federal regulations. Epa hazardous waste
number d002. Reportable quan tity (rq): 1000 lbs. Do not flush acid
to sewer.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara 302/313) (cercla)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 90- 100%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3/3 stel; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: see ingredient 1.
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: danger-corrosive. Causes severe burns
to eyes & skin on contact. Vapor extremely irritating to
respiratory tract. Contact w/liquid, mist or vapor can cause
immediate irritation or corrosive burns to a ll human tissue.
severity of burn is generally determined by concentration of
solution & duration of (efts of overexp)
explanation of carcinogenicity: sulfuric acid: iarc monographs on eval of
carcin risk of chems to man, vol 54, pg 41, 1992: grp 1. Animal: pulm
irrit.
effects of overexposure: hlth haz: expos. Contact w/eyes may result in
permanent visual loss unless removed quickly by thorough irrigation
w/water. Swallowing may be fatal. Inhalation of concentrated vapor
or mist may damage r espiratory tract. Repeated skin
contactw/dilute solutions may cause dermatitis. May cause dental
erosion.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: call pois ctl ctr/md immed. Eyes: flush immed w/water for at
lst 15 mins. Forcibly hold eyelids apart to ensure complete
irrigation of eye/lid tiss. Get immed med attn. Skin: wipe off
excess. Flush imme d w/water for at lst 15 mins while removing
contam clthg. Get immed med attn. Wash clthg before reuse. Destroy
contam shoes. Ingest: drink copious amts of water/milk. Do not
induce vomit. Get (ing 7)
Boiling pt: b.P. Text: supp data
melt/freeze pt: m.P/f.P text: supp data
spec gravity: supp data
evaporation rate & reference:
solubility in water: completely miscible
appearance and odor: clear to slightly cloudy, oily liquid; odorless to
slightly pungent.
Stability indicator/materials to avoid: yes
highly reactive w/matls such as metals, metal oxides, hydroxides,
nitrates, amines, carbonates & other alkaline (ing 4)
stability condition to avoid: material is stable when properly handled.
avoid open flames of sparks.
hazardous decomposition products: explo hydrogen gas is generated by
action of acid on most metals & may accum in metal cntnrs. Release
sulfur (ing 6)
Waste disposal methods: dispose of spilled, neutralized or waste
product, contaminated soil & other materials i/a/w all local, state
& federal regulations. Us clean water act reportable quantity -
1000 lbs.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara 302/313) (cercla). Ld50: (oral,rat) 2140
mg/kg.
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 25-100%
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3;3 stel
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 1-75%
osha pel: n/k
acgih tlv: n/k
ingred name: exting media: farthest possible distance.
rtecs #: 9999999zz
ingred name: matls to avoid: matls. Rxns can generate great deal of heat
as does dilution of acid w/water. Concentrated acid is(ing 5)
rtecs #: 9999999zz
ingred name: ing 4: strong oxidizing agent. May cause ignit of combust
matls on cont w/generation of sulfur dioxide fumes.
rtecs #: 9999999zz
ingred name: haz decomp prod: dioxide at extremely high temperatures.
rtecs #: 9999999zz
ingred name: first aid proc: immed med attn. Never give anything by mouth
to uncon pers. Inhal: remove to fresh air. If not (ing 8)
rtecs #: 9999999zz
ingred name: ing 7: breathing, perform artificial respiration. Get
medical attention.
rtecs #: 9999999zz
ingred name: spill proc: water i/a/w applic regs spills of 1000 lbs or
more must be reported to the nrc, (800) 424-8802.
rtecs #: 9999999zz
ingred name: vent: design of exhaust systems.
rtecs #: 9999999zz
ingred name: eye prot: & full length faceshield .
rtecs #: 9999999zz
ingred name: other prot equip: rubber footwear should be used.
acid-resistant hood & full body suit recommended.
rtecs #: 9999999zz
Ld50 lc50 mixture: product's ld50 (oral rat) was not stated
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eye: irritation, corneal burns,
conjunctivis, blindness. Skin: can cause severe burns or irritation.
inhalation: can cause irritation or corrosive burns to respiratory
tract. Ingestion: can cause irritati on, corrosive burns to mouth &
g/i tract. May be fatal if swallowed. Chronic-tooth erosion,
lesions, conjunctivitis.
explanation of carcinogenicity: manufacturer gave no information about
carcinogenicity. Hmis found no listing & does not expect it to be
carcinogenic.
effects of overexposure: eye: irritation, corneal burns, conjunctivis,
blindness. Skin: severe burns or irritation. Inhalation: irritation
or corrosive burns to respiratory tract. Ingestion: irritation,
corrosive burns to mouth & g/i tract. May be fatal if swallowed.
medical cond aggravated by exposure: mfr gave no information of msds.
First aid: if irritation persists or is severe, get medical attention.
eye: flush w/water for 15 min. Skin: wash w/soap & water. Remove
contaminated clothing & launder before reuse. Inhaled: remove from
exposure. A id or restore breathing as needed. Ingested: do not
induce vomiting. Give large amounts of milk or water to drink. Get
immediate medical attention. Nothing by mouth if unconscious.
Hcc: c1
nrc/state lic num: none
boiling pt: b.P. Text: 534f,279c
melt/freeze pt: m.P/f.P text: n/a.
vapor pres: negligible
vapor density: n/a.
spec gravity: 1.835
evaporation rate & reference: n/a.
solubility in water: 100%
appearance and odor: oily, colorless to slightly yellow to turbid
liquid, odorless
percent volatiles by volume: n/a.
Stability indicator/materials to avoid: yes
nitro compounds, carbides dienes, alcohols (when heated) cause
explosions. Oxidizing agents cause fires & possible explo
stability condition to avoid: temperatures >300c yield so3 gas which is
toxic, corrosive & an oxidizer.
hazardous decomposition products: so3 gas. Also fire risk w/organic
materials.
conditions to avoid polymerization: will not occur.
Waste disposal methods: cautiously dilute & neutralize waste acid.
dispose of i/a/w federal, state & local regulations. Waste may have
to be disposed of by an approved coantractor.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara 302/313) (cercla)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 93-99.5%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3/3 stel; 9495
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ld50 lc50 mixture: ld50 (oral rat) is 2140 mg/kg
route of entry inds - inhalation: yes
skin: yes
ingestion: yes
carcinogenicity inds - ntp: no
iarc: no
osha: no
effects of exposure: concentrated sulfuric acid is a strong mineral acid, an
oxidizing agent and a dehydrating agent that is rapidly damaging to all human
tissue on contact. Ingestion may cause severe injury or death. Eye contact
produces severe or permanent injury. Inhalation of mists can damage both
upper respiratory tract and lungs.
explanation of carcinogenicity: this product is not considered a carcinogen by
ntp, iarc or osha.
signs and symptions of overexposure: concentrated sulfuric acid is a strong
mineral acid, an oxidizing agent, and a dehydrating agent that is rapidly
damaging to all human tissue with which it comes in contact. Ingestion may
cause severe injury or death. Eye contact produces severe or permanent
injury. Inhalation of mists can damage both the upper respiratory tract and
the lungs.
medical cond aggravated by exposure: none specified by manufacturer. Dla-:
persons with a history of ailments or with a pre-existing disease involving
the respiratory tract may be at increased risk from exposure.
first aid: eye contact: immediately flush with plenty of running water for at
least 15 minutes. Obtain medical help as soon as possible. Skin: immediately
flush areas with water, removing contaminated clothes wh ile under a safety
shower. Continue washing with water and get medical attention. Inhalation:
remove to fresh air. Restore breathing. Call a physician immediately.
ingestion: dilute acid immediately w ith large amounts of milk or water, then
milk of magnesia. Never give anything by mouth if victim unconscious. Do not
induce vomiting! Get immediate medical attention.
hcc: c1
boiling point: =138.3c, 281.F
melt/freeze pt: =-36.5c, -34.F
vapor pres: <1
vapor density: 66 be
spec gravity: 1.8354
solubility in water: complete
appearance and odor: clear, colorless, oily liquid; no odor.
percent volatiles by volume: 100
product id: sulfuric acid, concentrated
cage: 75656
company name: los angeles chemical co
street: 4545 ardine st
po box: 1987
city: south gate ca
zipcode: 90280
health emergency phone: 213-562-9500
label required ind: y
date of label review: 03/28/2000
status code: c
label date: 05/22/1997
year procured: 2000
origination code: f
chronic hazard ind: y
eye protection ind: yes
skin protection ind: yes
signal word: danger
respiratory protection ind: yes
health hazard: slight
contact hazard: severe
fire hazard: none
=======================================================
responsible party cage: 75656
trans id no: 100391
product id: sulfuric acid, concentrated
msds prepared date: 06/18/1993
review date: 03/28/2000
mfn: 1
net unit weight: 840.6 lbs
multiple kit number: 0
review ind: y
unit of issue: dr
container qty: 1
type of container: 1a1 steel
additional data: psn is mfr msds. Container shall conform to a un certified 1a1
steel or un certified 1h1 plastic 55 gallon drum. Paper labels are not
allowed. Drum certification shall be embossed in drum. Mark iaw all un
requirements.
Hazard and precautions: corrosive! Sulfuric acid is rapidly damaging to all
human tissue on contact.Ingestion may cause severe injury or death.Eye
contact produces severe or permanent injury.Inhalation of mists can damage bo
th upper respiratory tract& lungs. Firstaid: inhalation-remove to fresh
air.Restore breathing if needed.Get medical attn.Eyes-flush with lots of
water for 15 minutes,lift lids.Get medical attn.Skin-rem ove contaminated
clothing.Wash with lots of water for 15 minutes.Get medical
advice.Ingestion-do not induce vomiting!If conscious,give milk or water,then
milk of magnesia.Get immediate medical attn. T arget organs: none given.
spill release procedures: notify safety personnel. Provide ventilation. Stop
leak if can be done without risk. Clean-up personnel need protection against
contact. Keep upwind. Contain spill. Dilute with water then neutralize w ith
soda ash or lime. If no water available, cover contaminated area with sand,
ashes or gravel and neutralize cautiously with soda ash or lime.
neutralizing agent: sodium bicarbonate or a soda ash.
waste disposal methods: follow federal, state and local regulations. Runoff to
sewer may create hydrogen gas, which is a fire or explosion hazard. Epa (cwa)
rq=1000 lbs (40 cfr 117).
handling and storage precautions: sulfuric acid in carboys or drums should be
stored in a clean, ventilated storage area having acid-resistant floors. Keep
out of direct sunlight. Do not store above 89.6f (32c). Store away from
incomp atible materials. Soda ash, sand or lime should be kept available for
emergency use.
other precautions: protect containers against physical damage.Glass bottles
need extra protection.Do not add water to sulfuric acid.Drums may contain
hydrogen gas,open cautiously.Use nonsparking tools free of oil,dirt &
grit;vapor-proof electrical fixtures.Avoid breathing mist or vapors.Avoid
contact with skin or eyes .Do not ingest.
Ld50 lc50 mixture: none specified by manufacturer.
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eye: will cause severe
irrit,burns.Skin: will cause severe irrit,partial-to-full thickness
burns.Inhal: will cause irrit,possibly burns to nose/throat/upper
resp tract.Also may cause shortness of breath, wheezing.May cause
chronic dental erosion.Ingest: will cause nau,vomit,pain,irrit/burns
to mouth/throat/lower gi tract.
explanation of carcinogenicity: per msds: this product contains
carcinogens(ntp/iarc/osha): no.
effects of overexposure: severe eye irrit,burns. Severe skin
irrit,partial to full thickness burns. Irrit/burn nose/throat/upper
resp tract.Shorntess of breath, wheezing, chronic dental erosion,
nausea, vmiting, pain,irrit/bu rn to mouth/throat/lower gi tract.
medical cond aggravated by exposure: may aggravate respiratory ailments
such as emphysemia & bronchitis.Also may aggravate pre-existing
skin disorders.
First aid: eye: flood w/water for @least 15mins while holding eyelids
open.Get med attn.Skin: flush expo skin areas w/water for @least
15mins.Wrap burns in dry,sterile dressings.Get immed med
attn.Inhal: move to fr esh air.Breath diffi give oxy;stop breath
admin art resp(mouht-to-mouth prefer)if trained.Get immed med
attn.Ingest: dont induce vomit.Amin lg quant of water if consc.Dont
try to neutra-possible(suppl)
Hcc: c1
boiling pt: b.P. Text: 535f,279c
melt/freeze pt: m.P/f.P text: np
decomp temp: decomp text: np
vapor pres:
vapor density: 17mm
spec gravity: 1.4042
ph: np
viscosity: np
evaporation rate & reference:
solubility in water: complete
appearance and odor: clear to slightly turbid;off white to straw color;
usually odorless
percent volatiles by volume: nil
corrosion rate: np
Stability indicator/materials to avoid: yes
alkaline matls;salts of other acids;hydrate matls;combustible & organic
matls.
stability condition to avoid: addnition of water causes large
temeprature increase.
hazardous decomposition products: if heated sufficiently sulfur dioxide
(so2) and sulfur trioxide (so3).
Waste disposal methods: dispose of waste in compliance w/loc/state/fed
regs.Waste may be classified as corro (doo2) under rcra.Recycle
waste where applicable.Reportable under sara iii sec 313 supplier
notification reqmts.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara 302/313) (cercla)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 50%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3/3 stel; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
other rec limits: none recommended