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Sodium hydroxide in aqueous solution (soda lye or liquid soda)
Sodium hydroxide in aqueous solution (soda lye or liquid soda)
Chemicals-inorganic
Y - Indicates information is in the hazardous materials information resource system (hmirs).
PMICA - Item does not contain precious metal.
CRITL- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.
044155 - Chem: corrosive matls, group a, sub3
635 - Chemicals, other than drugs or sundries
9 - Other or no special handling required (sh)
A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.
B - Construction materials: includes paint and related materials, prefabricated building, wood products, metal and composition mater
M - 85.0
W - Corrosive materials, un class 8 (corrosive label)
Questions & Answers: |
|
| What are the historical prices recorded for this stock number? | |
| Historical data shows pricing from $1,027.04 to $1,711.73.. | |
| Does NSN 6810-01-051-3050 have a shelf life? | |
| No. There is no shelf life applicable for this NSN. | |
| What NATO entities are users of this NSN? | |
| Department Of The Air Force, National Security Agency, Department Of The Navy, National Aeronautics and Space Administration, and Turkey | |
| What is the NIIN of NSN 6810-01-051-3050? | |
| 010513050 or 01-051-3050 | |
| Does NSN 6810-01-051-3050 require demilitarization? | |
| Yes - ITAR Controlled | |
| What is the most recent solicitation for NSN 6810-01-051-3050? | |
| No solicitations for this NSN. | |
| When was this national stock number assigned to the federal catalog? | |
| Nov 25, 1977 | |
Ld50 lc50 mixture: ld50 (oral, rat) is unknown.
routes of entry: inhalation: no skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: **corrosive** eyes: may cause
irritation,burns,possibly blindess.Skin: may cause
irritation.Ingest: may cause delayed gi tract irritation and
burns.Inhal: may cause respiratory irritation,burns,possibly c
hemical pneumonia.
explanation of carcinogenicity: there are no ingredients above 0.1%
which are identified as carcinogens by ntp,iarc or osha.
effects of overexposure: severe burns, pain, nausea, vomiting.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: skin: remove contaminated clothing;wash with cool water.Get
medical attention if needed.Eyes: flush with water for 15
minutes.Get immediate medical attention.Inhal: remove to fresh
air.Give oxygen or art ificial respiration if needed.Get immediate
medical attention.Ingest: do not induce vomiting.Get prompt
qualified medical attention.If conscius,give milk or water.Keep
airway clear.
Hcc: b1
boiling pt: =143.9c, 291.F
melt/freeze pt: =12.C, 53.5f
decomp temp: decomp text: not known
vapor pres: 13mm/60c
spec gravity: 1.53
ph: 14
solubility in water: not available
appearance and odor: clear liquid with no distinct odor.
percent volatiles by volume: 0
corrosion rate: corrosiv
Stability indicator/materials to avoid: yes
air,water,acids and metals(sn,al,zn),leather,wool,organic
halogens,organic nitro compounds.
stability condition to avoid: avoid direct contact with water.
hazardous decomposition products: co(gas) may be formed when this
product contacts reducing sugars,foods,beverages;use caution in
confined spaces.
Waste disposal methods: discharge, treatment or disposal is subject to
federal, state or local regulations. Flush neutralized solution to
sewer with large amount of water, if permitted.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 48.5-91%
other rec limits: none recommended
osha pel: not relevant
acgih tlv: not relevant
ingred name: sodium hydroxide (cercla)
cas: 1310-73-2
rtecs #: wb4900000
fraction by wt: 9- 51.5%
other rec limits: none recommended
osha pel: 2 mg/m3
acgih tlv: c 2 mg/m3; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: sodium chloride
cas: 7647-14-5
rtecs #: vz4725000
fraction by wt: 0 - 1.3%
other rec limits: none recommended
ingred name: sodium chlorate
cas: 7775-09-9
rtecs #: fo0525000
fraction by wt: 0 - 0.3%
other rec limits: none recommended
Effects of overexposure: severe irritnt to eyes,skin,by inhal,
ingestion.Matl is extremely corrosive.Some effects delayed.
First aid: eyes: immediately flush w/h2o 15 min.Skin: immed flush under
safety shower.Remove contaminted clothes.Inhaled: remove to fresh
air.Ingest: do not induce vomiting.Give lg amts h2o or milk.Follow
with dilu te vinegar or fruit juice.Get medical attention.
Hcc: b1
boiling pt: b.P. Text: 298f,148c
spec gravity: 1.525
solubility in water: complete
appearance and odor: colorless, viscous liquid. Odorless.
Stability indicator/materials to avoid: yes
avoid acids,metals,oxidizers,organics,water ractv matl.
hazardous decomposition products: at bp(148c)hazardous mist,at dryness
caustic residue left.
Waste disposal methods: disposal subject to federal,state & local
regulations.Users should review operations for regulatory
compliance. Consult with appropriate agency before disposal.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sodium hydroxide (sara iii)
cas: 1310-73-2
rtecs #: wb4900000
fraction by wt: 50%
osha pel: 2 mg/m3
acgih tlv: c 2 mg/m3; 9293
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 50%
Health hazards acute and chronic: eye-severe burns;sml qty can result in
perm damage/sight loss. Skin-burns,deep ulceration,ultimate
scarring-destroys tissue,mist-dermatitis. Inhal-can range fm mild
irrit of mucous membranes to severe pneumonitis. Ingest-can cause
serious damage to mouth,esophagus, stomach,other tissues, can be
fatal.
effects of overexposure: see health hazards
First aid: eyes-flush w/water 15 min;see physician. Skin-remove contam
cloth,shoes;immed flush w/water-continue til slick feeling is gone.
inhal-get to fresh air;give artifi respir if reqd;call physician.
ingest -if conscious give qt water;do not induce vomit. Immed take
to phys/hospital.
Hcc: b1
boiling pt: b.P. Text: 288f,142c
melt/freeze pt: m.P/f.P text: 45.0f,7.2c
vapor pres: < 1
spec gravity: 1.530
solubility in water: complete
appearance and odor: clear to slightly turbid, odorless liquid.
percent volatiles by volume: 50
Stability indicator/materials to avoid: yes
organic matls & conc acids,metals like magnesium,zinc,
tin,chromium,brass,bronze
hazardous decomposition products: reaction w/food sugars may form carbon
monoxide.
Waste disposal methods: use approved haz waste facility. Use care to
prevent envir contam. Comply w/all fed,state & local laws & regs.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sodium hydroxide (sara iii)
cas: 1310-73-2
rtecs #: wb4900000
fraction by wt: 50%
osha pel: 2 mg/m3
acgih tlv: c 2 mg/m3; 9293
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Effects of overexposure: skin/eyes: severe burns,possible blindnes.
inhalation: mists,severe irritnt.Ingest: burns.(see supp data
First aid: remove to fresh air; get medical attention; give cpr or
oxygen if need. If contact,flush w. H2o for 15 min. Speed of
removal is critical. Remove & isolate contaminated clothing. Keep
warm & quiet.Effe cts may be delayed; observe victim.
Hcc: b1
boiling pt: b.P. Text: 293f,145c
spec gravity: 1.52
solubility in water: complete
appearance and odor: colorless, clear, odorless liquid.
Stability indicator/materials to avoid: yes
acids,al,zn,tin,copper: release h2.Organic material.
stability condition to avoid: none
hazardous decomposition products: toxic fumes when heated
Waste disposal methods: wear rubber cloves,scba, protect clthg. Add
slowly to lg vol of agitated soln of na2 co2 & ca(oh)2. Add this
soln to lg excess of h20. Elim ign sources or keep in covd drs.
hdle & dispose lw all appl intern, fed, state & local regs.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sodium hydroxide (sara iii)
cas: 1310-73-2
rtecs #: wb4900000
fraction by wt: 50%
osha pel: 2 mg/m3
acgih tlv: c 2 mg/m3; 9293
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: aqueous solution,hazard unknown,unidentified
fraction by wt: 50%
Routes of entry: inhalation: no skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute-corrosive.Destructive to
tissue,mucous membranes,eyes,skin.Inhaled: mist/vapor may damage
upper respiratory tract & lung tissue which may lead to chemical
pneumonia.Eye/skin: can cause severe burn s.Blindness may
occur.Oral: severe burnsto
mouth,throat,esophagus,stomach.Chronic-dermatitis & respiratory
illness.
effects of overexposure: skin: causes severe damage. Skin: causes burns.
inhal: respiratory damage. Ingest: dam. Mucous membr
medical cond aggravated by exposure: persons with pre-existing skin
disorders or eye problems or impaired respiratory function may be
more susceptible to the effects of the substance.
First aid: skin: flush area w/h2o for 15 min. See dr. Eyes: flush w/water
for 15 min. Call dr. Ingest: do not induce vomiting. Dilute by
giving water. Give milk of magnesia. Keep warm,quiet; call dr.
immediately.
Hcc: b1
boiling pt: =142.2c, 288.F
vapor pres: 3.0
vapor density: 71.0
spec gravity: 1.525
evaporation rate & reference: < 1.0, ether
solubility in water: appreciable
appearance and odor: liquid
percent volatiles by volume: 50.0
Stability indicator/materials to avoid: yes
strong mineral acids,reactive metals such as al,mg, acids,cu
stability condition to avoid: high heat, flame
hazardous decomposition products: toxic oxides of carbon, zinc
Waste disposal methods: small spill: dissolve in large amt of h2o &
neutralize w/6m-hc1.Large spill: pour into large tank of water &
neutralize. Fluxh to an approved disposal area.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sodium hydroxide (sara iii)
cas: 1310-73-2
rtecs #: wb4900000
fraction by wt: 50.0%
osha pel: 2 mg/m3
acgih tlv: c 2 mg/m3; 9293
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: oral rabbits ld50 = 500 mg/kg
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: compound is corrosive to body
tissues,and is toxic bu its corrosivity.
effects of overexposure: eyecorrosive,burns skin: irritation,burns,
ulceration. Inhaled: irritation,burns,pneumonitis. Ingested: g/i
corrosion, severe abdominal pain,vomiting.
medical cond aggravated by exposure: none
First aid: eyeflush with water 15min. Skin: wash with soap & water.
inhaled: remove to fresh air.Give artifical respiration or oxygen as
needed. Ingested: do not induce vomiting give large amount of milk
or water.( nothing by mouth if unconscious.) get immediate medical
attention. If any irritation persists or is severe,get prompt
medical care.
Hcc: b1
boiling pt: b.P. Text: 286f,141c
melt/freeze pt: m.P/f.P text: 46.0f,7.8c
spec gravity: 1.5
solubility in water: complete
appearance and odor: viscous, colorless liquid with no odor.
percent volatiles by volume: 50
Stability indicator/materials to avoid: yes
acid,water,chlorinated hydrocarbons,alcohols, aldehydes,aluminum. May
react exothermically or explosively.
stability condition to avoid: heat
hazardous decomposition products: sodium oxide
conditions to avoid polymerization: may cause hazardous polymerization
in acrylics and acetaldehyde.
Waste disposal methods: dispose i/a/w federal,state,local,regulations.
hmis suggests neutralize and flush to drain.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sodium hydroxide (sara iii)
cas: 1310-73-2
rtecs #: wb4900000
fraction by wt: 50%
osha pel: 2 mg/m3
acgih tlv: c 2 mg/m3; 9293
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 50%
Ld50 lc50 mixture: ld 50 in rabbit is 500mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: corrosive ro all body
tissue,corneal burns or deep skin burns;irritation of respiratory
tract;perforation of g. I. Tract;blindness of eyes;ulceration and
scarring of skin: tissue damage. Chronic : dermatitis,tissue damage.
explanation of carcinogenicity: no data available
effects of overexposure: dusts or concentrated mist may cause damage to
upper respiratory tract & lungs,tissue damage,irrit.
First aid: eyes: immediately flush with water for 30 min.Remove
contaminated clothing immed. Call dr. Inhal: move to fresh air. Call
dr. Ingest: corrosive.Do not induce vomit.Give large amts. Of water
or milk.See d r.
Hcc: b1
boiling pt: b.P. Text: 293f,145c
vapor pres: 1.5
spec gravity: 1.52
solubility in water: appreciable
appearance and odor: colorless to slightly colored liquid. No odor.
percent volatiles by volume: low
Stability indicator/materials to avoid: yes
h2o & acid.Product is strong caustic alkali,al,htd h2o.
hazardous decomposition products: none
Waste disposal methods: disposal of caustic soda must meet all federal,
state & local regulations.Contact the dow chemical co.For
additional information.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sodium hydroxide (sara iii)
cas: 1310-73-2
rtecs #: wb4900000
fraction by wt: 50%
osha pel: 2 mg/m3
acgih tlv: c 2 mg/m3; 9293
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc1100000
fraction by wt: balance
Routes of entry: inhalation: no skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: product is corrosive to body tissues.
it is toxic by corrosivity. As a solution of a solid unlikely to be
inhaled, but will also attack the respiratory system if inhaled as
a mist. Harmful if swallowe d.
explanation of carcinogenicity: sodium hydroxide is not listed by iarc,
ntp, or osha as a carcinogen.
effects of overexposure: eye: severe irritation,burning. Skin: slippery
feeling,burns. Inhaled: (unlikely) respiratory irritation,pulmonary
edema. Ingested: severe irritation of g/i tract,burns,g/i
distress,nausea,vomiting.
medical cond aggravated by exposure: persons with a history of ailments
or with a pre-existing disease involving the eyes, skin, or
respiratory tract may be at increased risk from exposure.
First aid: eye: flush w/water 15 min, hold lids open. Skin: wash with soap
& water. Remove contaminated clothing and launder before reuse.
inhaled: remove to fresh air. Restore breathing if necessary.
ingested: do n ot induce vomiting. Give 2 large glassesof milk or
water and get immediate medical care. Give nothing by mouth if
unconscious. If irritation persists or is severe,see a doctor.
Hcc: b1
boiling pt: =146.1c, 295.F
melt/freeze pt: =12.8c, 55.F
vapor pres: 18
spec gravity: 1.53
ph: > 12
solubility in water: complete
appearance and odor: viscous colorless liquid. No odor.
percent volatiles by volume: 50%
Stability indicator/materials to avoid: yes
acids, many nitro compounds, chlorinated hydrocarbons, peroxide,
aluminum
stability condition to avoid: none given by manufacturer (supplier).
hazardous decomposition products: contact with some metals will liberate
flammable hydrogen.
Waste disposal methods: for small quantities: cautiously add to a large
stirred excess of water. Adust the ph to neutral, separate out
solids and package for disposal. Disposal should be made in
accordance with all applicabl e federal, state and local laws and
regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sodium hydroxide (sara iii)
cas: 1310-73-2
rtecs #: wb4900000
fraction by wt: 50%
other rec limits: none specified
osha pel: 2 mg/m3
acgih tlv: c 2 mg/m3; 9293
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 50%
other rec limits: none specified
Ld50 lc50 mixture: oral ld50 (rat) is 140-340 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: corrosive solid/liquid will burn
eyes/skin/ respiratory tract. Can cause blindness. Causes
destructive tissue damage and scarring. May lead to skin
dermatitis. Ingestion of liquid or mist will cause s evere burning
and irritation to mucous membranes, mouth, throat and
gastrointestinal tract. Can cause severe pneumonitis
explanation of carcinogenicity: the components of this product have not
shown any evidence of being carcinogenic.
effects of overexposure: overexposure may lead to respiratory
irritation, nausea, fatigue, dizziness, headaches, unconsciousness,
dermatitis and eye irritation. Material is corrosive and will burn
exposed tissue. Ingestion ma y result in asthma-like reactions
(wheezing, coughing and shortness of breath).
medical cond aggravated by exposure: persons with a skin disorder, eye
disorders, or impared respiratory function should use caution when
handling or using this product.
First aid: skin: remove contaminated clothing. Wash with soap and water.
get medical attention if irritation persists. Inhalation: remove to
fresh air & restore breathing if necessary. Get medical attention.
eye : immediately flush with water for 15 minutes while holding
eyelids open. Get medical attention. Ingestion: drink water/milk to
dilute. Do not induce vomiting. Nothing by mouth if
unconscious.Call dr.
Hcc: b1
boiling pt: b.P. Text: 289f,143c
melt/freeze pt: m.P/f.P text: 54.0f,12.2c
vapor pres: 13
spec gravity: 1.54
ph: 14
solubility in water: complete
appearance and odor: clear liquid with no distinct odor.
Stability indicator/materials to avoid: yes
water, acids, halogenated organics, metals such as aluminum, tin, zinc,
aldehydes, organic nitro compounds.
stability condition to avoid: anything other than normal conditons;
direct contact with acids; metals
hazardous decomposition products: liberates flammable hydrogen gas on
contact with active metals such as zn,al,sn.
Waste disposal methods: waste diluted and neutralized liquid could be
flushed to a waste water treatment system via the sewer or given to
a licensed disposal contractor. Conform to all applicable
regulations. Undiluted mater ial is a rcra hazardous waste (code =
d002).
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sodium hydroxide (sara iii)
cas: 1310-73-2
rtecs #: wb4900000
fraction by wt: 50%
other rec limits: none specified
osha pel: 2 mg/m3
acgih tlv: c 2 mg/m3; 9293
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 50%
other rec limits: none specified
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute-corrosive.Causes severe burns to
skin and eyes.May cause loss of vision &
dermatitis.Inhalation: mists can damage the respiratory tract &
lungs,severe pneumonitis.Ingestion: very serious damage to the
mouth,esophagus & stomach.Chronic-unknown.
effects of overexposure: corrosive. Causes severe burns to skin and
eyes. May cause loss of vision & dermatitis. Inhalation of mists
can damage the respiratory tract & lungs, severe pneumonitis.
ingestion can very serious dam age the mouth, esophagus & stomach.
medical cond aggravated by exposure: none known.
First aid: get medical assistance for all cases of overexposure.Skin:
flush with plenty of water until skin does not feel
slippery.Eyes: flush with water for at least 15 minutes.Hold eyelids
open. Inhalation: remo ve to fresh air.Give cpr/oxygen if
needed.Ingestion: do not induce vomiting.If conscious,drink large
amount of water or acidic beverage(tomato/orange juice.Note to
physician: treat symtomatically.
Hcc: b1
boiling pt: =142.2c, 288.F
melt/freeze pt: =-17.2c, 1.F
vapor pres: 1
spec gravity: 1.530
ph: > 13
solubility in water: complete
appearance and odor: clear to slightly turbid liquid. No odor.
percent volatiles by volume: 50
Stability indicator/materials to avoid: yes
organic materials and concentrated acids, magnesium, aluminum,
zinc(galvanized),tin,chromium,brass,bronze & food sugar.
stability condition to avoid: high heat, open flames
hazardous decomposition products: reaction with various food sugar may
form carbon monoxide.
Waste disposal methods: waste disposal to be performed in compliance
with all current local, state and federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sodium hydroxide (sara iii)
cas: 1310-73-2
rtecs #: wb4900000
fraction by wt: 50%
other rec limits: none specified
osha pel: 2 mg/m3
acgih tlv: c 2 mg/m3; 9293
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: sodium hydroxide is a strong
alkali and is destructive of all human tissue it contacts, giving
severe burns. Eye contact will produce severe or permanent injury.
inhalation of mist or spray can injure the entire respiratory
tract. Chronic: manufacturer did not specify.
explanation of carcinogenicity: not applicable.
effects of overexposure: eyes: severe burns. Possible permanent tissue
damage and possible blindness. Skin: severe irritation. Possible
chemical burns and possible permanent tissue damage. Inhalation:
severe irritation and po ssible permanent damage to upper
respiratory tract.
medical cond aggravated by exposure: none.
First aid: eyes: immediately flush with large amounts of water for at
least 15 minutes. See doctor immediately. Skin: flush with large
amounts of water for at least 15 minutes while removing
contaminated clothin g and shoes. See doctor. Inhalation: remove to
fresh air. Give oxygen/cpr if needed. See doctor immediately.
ingestion: do not induce vomiting. Drink large amounts of water.
see doctor immediately.
Hcc: b1
boiling pt: b.P. Text: 284f,140c
vapor pres: 13 @ 140f
spec gravity: 1.53
ph: > 12.5
solubility in water: complete
appearance and odor: clear liquid, no odor.
Stability indicator/materials to avoid: yes
acids, many organic chemicals, especially nitrocarbons & halocarbons,
leather, wool, aluminum, tin, zinc, & their alloys
stability condition to avoid: none noted.
hazardous decomposition products: none.
Waste disposal methods: notify your local environmental officer. Waste
caustic must never be discharged to sewers or surface waters. First
convert to neutral salts and dilute well with water. Sodium
hydroxide waste exhibits the epa characteristic of corrosivity.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sodium hydroxide (sara iii)
cas: 1310-73-2
rtecs #: wb4900000
fraction by wt: >48.5%
other rec limits: none specified
osha pel: 2 mg/m3
acgih tlv: c 2 mg/m3; 9293
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: ld 50 in rabbit is 500mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: corrosive to all body tissue,
corneal burns or deep skin burns; irritation of respiratory tract;
perforation of gastrointestinal tract; blindness of eyes;
ulceration and scarring of skin: tissue damage.
chronic: dermatitis, tissue damage.
explanation of carcinogenicity: no data available
effects of overexposure: dusts or concentrated mist may cause damage to
upper respiratory tract & lungs, tissue damage, irritation.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: eyes: immediately flush with water for 30 min. Remove
contaminated clothing immediately. Call physician. Inhalation: move
to fresh air. Call physician. Ingestion: corrosive. Do not induce
vomit. Give large amts. Of water or milk. See physician.
Hcc: b1
boiling pt: b.P. Text: 288f,142c
melt/freeze pt: m.P/f.P text: 53.6f,12.0c
vapor pres: 1.6
spec gravity: 1.525
solubility in water: complete
appearance and odor: colorless to slightly colored liquid. No odor.
percent volatiles by volume: low
Stability indicator/materials to avoid: yes
h2o & acid. Product is strong caustic alkali, al.
stability condition to avoid: avoid rapid temperature rise when making
water dilutions. Never add water to caustic soda, add caustic soda
to water.
hazardous decomposition products: none
Waste disposal methods: disposal of caustic soda must meet all federal,
state & local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sodium hydroxide (sara iii) *
cas: 1310-73-2
rtecs #: wb4900000
fraction by wt: 50%
osha pel: c 2 mg/m3 *
acgih tlv: c 2 mg/m3; 9192 *
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc1100000
fraction by wt: balance
Ld50 lc50 mixture: ld50 (oral, rat) is unknown.
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eye, skin, respiratory &
gi tracts. Acute- corrosive to all body tissues. Skin contact can
cause destruction. Inhaling mist may cause severe respiratory tract
irritation. Can cause sever e eye/skin burns. If ingested, severe
mouth, throat, esophagus, stomach burns. Chronic- dermatitis,
respiratory illness.
explanation of carcinogenicity: none
effects of overexposure: severe burns to eyes, skin, mouth, throat,
esophagus, stomach; upper respiratory tract and lung damage;
possibly blindness
First aid: get immediate medical help for all cases of exposure.
eyes/skin: flush with water for at least 15 minutes. Hold eyelids
open. Inhaled: remove to fresh air. Provide cpr/oxygen if necessary.
oral: do not i nduce vomiting. If conscious, drink large amount of
milk/water. Never give anything by mouth to an unconscious person.
if vomiting occurs spontaneously, keep airway clear.
Hcc: b1
nrc/state lic num: not relevant
boiling pt: b.P. Text: 288f,142c
melt/freeze pt: m.P/f.P text: 53.6f,12.0c
decomp temp: decomp text: not known
vapor pres: 1.6 @ 68f
spec gravity: 1.525
solubility in water: complete
appearance and odor: water white, clear to slightly turbid liquid -
essentially odorless
percent volatiles by volume: 50
Stability indicator/materials to avoid: yes
water, acids, aluminum, tin, zinc, alloys of these metals, wool,
organic halogen compounds and organic nitro compounds
stability condition to avoid: product absorbs carbon dioxide from the
air. Keep contaienrs tightly closed.
hazardous decomposition products: will react with some metals such as
aluminum, tin or zinc to form explosive hydrogen gas.
Waste disposal methods: waste disposal to be performed in compliance
with all current local, state and federal regulations. Small
quantities may be dissolved in water and neutralized with acid. The
neutralized solution can b e flushed down the drain if permitted.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 50%
other rec limits: none recommended
ingred name: sodium hydroxide (sara iii)
cas: 1310-73-2
rtecs #: wb4900000
fraction by wt: 50%
other rec limits: none recommended
osha pel: 2 mg/m3
acgih tlv: c 2 mg/m3; 9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ld50 lc50 mixture: ld 50 in rabbit is 500mg/kg
route of entry inds - inhalation: yes
skin: yes
ingestion: yes
carcinogenicity inds - ntp: no
iarc: no
osha: no
effects of exposure: acute: corrosive to all body tissue, corneal burns or deep
skin burns; irritation of respiratory tract; perforation of gastrointestinal
tract; blindness of eyes; ulceration and scarring of skin: tissue damage.
chronic: dermatitis, tissue damage.
explanation of carcinogenicity: product contains no ingredients currently
classified as carcinogenic by ntp, iarc or osha.
signs and symptions of overexposure: dusts or concentrated mist may cause
damage to upper respiratory tract & lungs, tissue damage, irritation.
medical cond aggravated by exposure: none specified by manufacturer.
first aid: inhalation: remove from exosure. Get medical help. Skin: remove
contaminated clothing. Wash with water. Eyes: flush with water for 15 minutes
including under the eyelids. Get medical help. Ingesstion: drink plenty of
water or fruit juice. Do not induce vomiting. Get immediate medical help.
note: a simple water rinse is not adequate to remove this product from skin.
hcc: b1
b.P. Text: 280f,138c
m.P/f.P text: 45.0f,7.2c
decomp text: unknown
vapor pres: 1.1
vapor density: not given
spec gravity: 1.530
ph: 14
evaporation rate & reference: nil
solubility in water: complete
appearance and odor: colorless, viscous liquid, no odor.
percent volatiles by volume: 50 %
corrosion rate: unknown
product id: caustic soda liquid - 50%
cage: do415
assigned ind: y
company name: lcp chemicals, div of hanlin group, inc.
street: raritan plaza ii, raritan center
po box: 484
city: edison nj
zipcode: 08837
health emergency phone: 800-624-6938
label required ind: y
date of label review: 03/30/1993
status code: c
mfg label no: none
label date: 03/30/1993
origination code: f
eye protection ind: yes
skin protection ind: yes
signal word: danger
health hazard: moderate
contact hazard: severe
fire hazard: slight
=======================================================
responsible party cage: do415
trans id no: 103220
product id: caustic soda liquid - 50%
msds prepared date: 08/01/1991
review date: 03/30/1993
mfn: 2
net unit weight: 700.7 lbs
multiple kit number: 0
review ind: y
unit of issue: dr
container qty: 0
type of container: drum
additional data: reportable quantity for sodium hydroxide is 1000 pounds.
solution is approximately 50% sodium hydrox ide.
Hazard and precautions: prevent eye & skin contact. Do not breathe dusts or
mists. Avoid storing next to strong acids. Dissolving in water & other
substances generates heat. First aid: inhalation: remove from exosure. Get me
dical help. Skin: remove contaminated clothing. Wash with water. Eyes: flush
with water for 15 minutes including under the eyelids. Get medical help.
ingesstion: drink plenty of water or fruit juice. do not induce vomiting.
get immediate medical help. Note: a simple water rinse is not adequate to
remove this product from skin.
spill release procedures: only trained & properly protected personnel
should undertake spill clean up. Acting cautiously, dilute & neutralize
with dilute with acid, preferable acetic acid.
neutralizing agent: dilute acetic acid.
waste disposal methods: disposal of caustic soda must meet all federal, state
& local regulations.
handling and storage precautions: prevent eye & skin contact. Do not
breathe dusts or mists. Avoid storing next to strong acids. Dissolving in
water & other substances generates heat.
other precautions: also, dissolving in water generates spattering, and mists.
solutions of greater than 45% are viscous & very slippery.
Ld50 lc50 mixture: 140-340 mg/kg acute oral ld50 (rat)
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: corrosive to all body tissues with
which it comes in contact. Superficial destruction of skin,
dermatitis. Inhalation of dust, spray or mist may result in varying
degrees of irritation or damage to re spiratory tract.
explanation of carcinogenicity: product contains no ingredients
currently classified as carcinogenic by ntp, iarc or osha.
effects of overexposure: skin burns/irritation, dermatitis, respiratory
tract irritation/burns, chemical pneumonia, eye burns/injury,
severe burns and complete tissue perforation of mucous membranes of
the mouth, throat, esop hagus and stomach.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: skin: immediately wash contaminated areas with plenty of
water for at least 15 minutes. Remove contaminated clothing and
footwear. Seek medical attention. Inhalation: remove to fresh air.
if breathing is difficult, administer oxygen. Seek medical
attention. Ingestion: never give anything by mouth to an
unconscious person. If swallowed, do not induce vomiting. Give
water or milk. Seek medical attn.
Hcc: b1
boiling pt: b.P. Text: 2530f,1388c
melt/freeze pt: m.P/f.P text: 604f,318c
vapor pres: not given
vapor density: not given
spec gravity: 2.13
ph: 12.0
viscosity: not given
evaporation rate & reference: nil
solubility in water: complete
appearance and odor: clear white solid with no distinct odor
percent volatiles by volume: nil
Stability indicator/materials to avoid: yes
acids, aluminum, tin, zinc and alloys containing these metals.
stability condition to avoid: avoid contact with water
hazardous decomposition products: none specified by manufacturer.
Waste disposal methods: prevent waste from contaminating surrounding
environment. Discard any product, residue, disposal container or
liner in accordance with all federal, state and local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sodium hydroxide (sara iii)
cas: 1310-73-2
rtecs #: wb4900000
fraction by wt: 97-98.2%
other rec limits: none recommended
osha pel: 2 mg/m3
acgih tlv: c 2 mg/m3; 9293
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: sodium carbonate
cas: 497-19-8
rtecs #: vz4050000
fraction by wt: 0.40-1%
other rec limits: none recommended
ingred name: sodium chloride
cas: 7647-14-5
rtecs #: vz4725000
fraction by wt: 0.9-1.2%
other rec limits: none recommended
Ld50 lc50 mixture: not specified by manufacturer.
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: may cause severe eye irritation with
corneal injury and result in permanent impairment of vision, even
blindness. May cuase severe skin burns. May cause gastrointestinal
irritation or ulceration and s evere burns of mouth and throat.
inhalation may cause severe irritation to upper respiratory tract.
explanation of carcinogenicity: product contains no ingredients
currently classified as carcinogenic by ntp, iarc or osha.
effects of overexposure: eye irritation, corneal injury, vision
impairment, blindness, severe skin burns, gastrointestinal
irritation, severe burns of mouth and throat, upper respiratory
tract irritation.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: eyes: wash eyes immediatley and continuously for 30 minutes.
call for medical assistance immediately. Skin: immediate continued
and thorough washing in flowing water for 30 minutes is imperative.
prom pt medical consultation is essential. Ingestion: do not induce
vomiting. Give large amounts of water or milk and transport to
medical facility. Inhalation: remove to fresh air. Consult
physician.
Hcc: b1
boiling pt: b.P. Text: 293f,145c
melt/freeze pt: m.P/f.P text: 54.0f,12.2c
vapor pres: 1.5
vapor density: not given
spec gravity: 1.52
ph: 14
viscosity: not given
evaporation rate & reference: not given
solubility in water: complete
appearance and odor: colorless to slightly colored liquid, no odor
Stability indicator/materials to avoid: yes
water and acid. Aluminum, tin, zinc, bronze, brass.
stability condition to avoid: product absorbs water and carbon dioxide
from the air. Keep containers closed and sealed.
hazardous decomposition products: none specified by manufacturer.
Waste disposal methods: prevent waste from contaminating surrounding
environment. Discard any product, residue, disposal container or
liner in accordance with all federal, state and local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sodium hydroxide (sara iii)
cas: 1310-73-2
rtecs #: wb4900000
fraction by wt: 48.5-50%
other rec limits: none recommended
osha pel: 2 mg/m3
acgih tlv: c 2 mg/m3; 9293
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: sodium carbonate
cas: 497-19-8
rtecs #: vz4050000
fraction by wt:
other rec limits: none recommended
ingred name: sodium chloride
cas: 7647-14-5
rtecs #: vz4725000
fraction by wt:
other rec limits: none recommended
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
other rec limits: none recommended
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: severe respiratory tract irritation,
severe pneumonitis, gastrointestinal burns/irritation, skin
irritation/burns, severe eye burns, blindness.
explanation of carcinogenicity: product contains no ingredients
currently classified as carcinogenic by ntp, iarc or osha.
effects of overexposure: effects from inhalation of mist vary from mild
irritation to serious damage of upper respiratory tract depending
on severity of exposure. Swallowing may cause severe burns of
mouth, throat, and stomac h. Severe scarring of tissue may
result.Skin contact can cause severe burns and scarring. Eye
contact - burns/blindness
medical cond aggravated by exposure: persons with pre-existing skin
disorders or eye problems or impaired respiratory function may be
more susceptible to the effects of substance.
First aid: inhalation: remove to fresh air. If not breathing, give
artificial respiration. If breathing is difficult, give oxygen.
call a physician. Ingestion: do not induce vomiting. Give large
quantities of wa ter or milk if available. Get medical attention
immediately. Skin/eyes: immediately flush with water for 15
minutes. Call physician immediately.
Hcc: b1
boiling pt: =145.C, 293.F
melt/freeze pt: m.P/f.P text: not given
vapor pres: 13
vapor density: not given
spec gravity: 1.53
ph: 14
viscosity: not given
evaporation rate & reference: not given
solubility in water: complete
appearance and odor: clear, colorless solution, no odor
Stability indicator/materials to avoid: yes
acids, organic halogen compounds, especially trichloroethylene,
nitromethane, aluminum, tin, zinc
stability condition to avoid: moisture, water
hazardous decomposition products: sodium oxide. Contact with aluminum,
tin and zinc cause formation of flammable hydrogen gas.
Waste disposal methods: prevent waste from contaminating surrounding
environment. Discard any product, residue, disposal container or
liner in accordance with all federal, state and local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sodium hydroxide (sara iii)
cas: 1310-73-2
rtecs #: wb4900000
fraction by wt: 50% %
other rec limits: none recommended
osha pel: 2 mg/m3
acgih tlv: c 2 mg/m3; 9293
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
other rec limits: none recommended
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation- severely irritating or
corrosive to the nose, mouth, throat and lungs. May cause burns to
the respiratory tract w/ the production of lung edema. High
concentrations may result in permanent lung damage.
eye/skin/ingestion- can cause severe irritation and/or burns. May
cause permanent damage.
effects of overexposure: inhalation- shortness of breath, sneezing,
choking, chest pain and impairment of lung function. Eyes- corneal
damage w/ impairment of vision. Skin- redness, swelling and scab
formation. May cause dest ruction of the dermis w/ impairment of
the skin at site of contact to regenerate. Ingestion- nausea,
vomiting, diarrhea.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: get immediate medical help for all cases of exposure.
eyes/skin: flush with water for at least 15 minutes. Hold eyelids
open. Inhaled: remove to fresh air. Provide cpr/oxygen if necessary.
oral: do not i nduce vomiting. If conscious, drink large amount of
milk/water. Never give anything by mouth to an unconscious person.
Hcc: c2
boiling pt: b.P. Text: 288f,142c
melt/freeze pt: m.P/f.P text: 54.0f,12.2c
spec gravity: 1.525
ph: 14
solubility in water: complete
appearance and odor: clear to slightly turbid colorless liquid with no
doro
Stability indicator/materials to avoid: yes
acids, aluminum, zinc, magnesium and halogenated organics
stability condition to avoid: excessive heat, flame (if hydrogen gas has
been generated)
hazardous decomposition products: when heated to decomposition, it emits
toxic sodium oxide (na2o).
Waste disposal methods: waste disposal to be performed in compliance
with all current local, state and federal regulations. Small
quantities may be dissolved in water and neutralized with acid. The
neutralized solution can b e flushed down the drain if permitted.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sodium hydroxide (sara iii)
cas: 1310-73-2
rtecs #: wb4900000
fraction by wt: 49 - 51%
other rec limits: none recommended
osha pel: 2 mg/m3
acgih tlv: c 2 mg/m3; 9293
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: single dose oral ld50 hasnt been determd
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eye: may cause severe irrit w/corneal
injury,result in in perm impairment of vision,even blindness.Dust
may irrit.Skin: short single expo may cause severe skin burns.Skin
absorpt: single prol expo not li kely to result in absorption of
harmfulamts.Ingest: may cause gi irrit/ulceration,severe burns of
mouth/throat(sign/sym)
explanation of carcinogenicity: this compound contains no ingredients at
concentrations of 0.1% or greater that are carcinogens or suspect
carcinogens.
effects of overexposure: health: inhal: dust/mist may cause severe irrit t
upper respiratory tract.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: eye: h2o only accepted method of removal of prod from
eye/skin.May have 10sec/less to avoid serious perm injury.Immed
1staid must be given aft any injurious expo.Moving victim frm h2o
access for transp o to med aid should be done only on advice of
qual med person.While transf cont w/wash.Wash eye immed,cont for
30mins.Call for med assist immed.Skin: immed cont,thorough wash in
flowing h2o for (suppl)
Hcc: b1
boiling pt: b.P. Text: 293f,145c
melt/freeze pt: m.P/f.P text: 58.0f,14.4c
decomp temp: decomp text: np
vapor pres: 1.5
vapor density: na
spec gravity: 1.52g/ml
ph: np
viscosity: np
evaporation rate & reference: np
solubility in water: water solution
appearance and odor: colorless to slightly colored liquid, no odor
percent volatiles by volume: np
corrosion rate: np
Stability indicator/materials to avoid: yes
h2o,acid.Prod strong caustic alkali.May rx violently w/h2o,acid,number
of org cmpds.Rxs rapidly w/al,sn,zn.Also w/(supp)
stability condition to avoid: product absorbs carbon dioxide from the
air.Keep containers closed & sealed.
hazardous decomposition products: none
Waste disposal methods: disp of caustic soda must meet all local, state
and federal regulations.Contact manufacturer or vendor for addn
info.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sodium hydroxide (cercla) (naoh), 40.5-50.5%.
cas: 1310-73-2
rtecs #: wb4900000
fraction by wt: see ing
other rec limits: none recommended
osha pel: 2 mg/m3
acgih tlv: c 2 mg/m3; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: sodium carbonate (na2co3)
cas: 497-19-8
rtecs #: vz4050000
fraction by wt:
other rec limits: none recommended
ingred name: sodium chloride (nacl)
cas: 7647-14-5
rtecs #: vz4725000
fraction by wt:
other rec limits: none recommended
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
other rec limits: none recommended
Ld50 lc50 mixture: none specified by manufacturer.
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eye contact: causes severe burns that
result in damage and possibly blindness. Skin: contact produces
severe burns and destroys tissues. Irritation may be delayed.
inhalation: breathing dust, mist or spray may cause damage to the
upper respiratory system. Ingestion: causes severe burns to mucous
membranes.
explanation of carcinogenicity: no data available
effects of overexposure: corrosive to all body tissues by all routes of
exposure. Dermal exposure may consist of multiple areas of
dermatitis. Similarly, inhalation of dust, spray or mist may result
in varying degrees of irri tation or damage to the respiratory
tract tissues and increased susceptibility to respiratory illness.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: eyes: immediately flush with large amounts of water for 15
minutes. Immediately get medical attention. Skin: immediately wash
with plenty of water for at least 15 minutes. Remove contaminated
clothing and shoes. Get medical attention immediately. Inhalation:
remove to fresh air. Get medical attention. Ingestion: do not
induce vomiting. Give large quantities of water. Get medical
attention immed.
Hcc: b1
boiling pt: =143.9c, 291.F
vapor pres: 13 @ 60c
spec gravity: 1.53
solubility in water: complete
appearance and odor: clear liquid with no distinct odor.
Stability indicator/materials to avoid: yes
water, aluminum, tin, zinc, and alloys containing these metals. Do not
mix with strong acids without dilution.
stability condition to avoid: none specified by manufacturer.
hazardous decomposition products: none specified by manufacturer.
Waste disposal methods: disposal of caustic soda must meet all federal,
state & local regulations. Appropriate disposal will depend on the
nature of each waste material and should be performed by competent
and properly permi tted contractors.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 48-91%
other rec limits: none recommended
ingred name: sodium hydroxide (sara iii)
cas: 1310-73-2
rtecs #: wb4900000
fraction by wt: 9-52%
other rec limits: none recommended
osha pel: 2 mg/m3
acgih tlv: c 2 mg/m3; 9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: sodium chloride
cas: 7647-14-5
rtecs #: vz4725000
fraction by wt: 0-1.3%
other rec limits: none recommended
ingred name: sodium chlorate
cas: 7775-09-9
rtecs #: fo0525000
fraction by wt: 0-0.3%
other rec limits: none recommended
Ld50 lc50 mixture: (10% sol)oral ld50 (rat) is 500 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eye-may cause tissue injury and loss
of vision. Skin-corrosive to all tissue. Inhalation-inhalation of
concentrated mist may cause damage to respiratory tract; mist is a
strong respiratory irritant. I ngestion-moderately toxic by
ingestion.
explanation of carcinogenicity: no
effects of overexposure: ingestion-ingestion may cause vomiting,
prostation or collapse.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: eye-hold eyelids open and flush with plenty of water; get
medical attention. Skin-flush affected area with water for at least
15 minutes. Do not use soap. Inhalation-move to fresh air; if
breathing ha s stopped, give artficial respiration; if breathing is
difficult give oxygen; get medical attention. Ingestion-if
swallowed & victim is conscious, have victim drink water or milk;
do not induce vomit.
Hcc: b1
boiling pt: =142.2c, 288.F
vapor pres: none
vapor density: none
spec gravity: 1.5
evaporation rate & reference: none
solubility in water: soluble
appearance and odor: none specified by manufacturer.
percent volatiles by volume: 0.0
Stability indicator/materials to avoid: yes
attacks metals; combination with water will release heat and may steam
and splatter.
stability condition to avoid: generally considered to be stable.
hazardous decomposition products: none
Waste disposal methods: sodium hydroxide solution, as commercially
produced is a charcartersitic hazardous waste. Disposal of this
product must be in accordance with the appropiate local, state and
federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sodium hydroxide (sara iii)
cas: 1310-73-2
rtecs #: wb4900000
fraction by wt: 49.5%
other rec limits: none recommended
osha pel: 2 mg/m3
acgih tlv: c 2 mg/m3; 9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: when improperly handled this strong
alkali is dangerous. It is destructive of all human tissue it
contacts giving severe burns. Eye contact will produce severe or
permanent injury. Inhalation of mist or spray can injure the
entire respiratory tract.
effects of overexposure: destruction of human tissue, severe burns,
severe or permanent eye injury. Injury to respiratory tract.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: eye: wash immed w/lots of running water for 15mins under
eyelids.Speed in rinsing out eyes is important so to avoid perm
injury.Get med attn immed.Skin: quickly wash w/lots of water.Dil
acetic acid or v inegar can be used to neutralize.Removecontamin
cloth under shower.Get med attn for serious exousre.Ingest: immed
drink water or milk to dilute.Neutralize w/dil vinegar.Don't induce
vomit.Inhal: remove
Hcc: b1
boiling pt: =140.C, 284.F
vapor pres: 13 @60c
spec gravity: 1.53
solubility in water: complete.
appearance and odor: a clear liquid, no odor.
Stability indicator/materials to avoid: yes
leather;wool;al,sn,zn & alloys having these metals;acids;organic chem
especially nitrocarbons & halocarbons.
stability condition to avoid: none specified by manufacturer.
hazardous decomposition products: none specified by manufacturer.
Waste disposal methods: dispose of scrap iaw/pre-emergency planning &
local,state & fed regs. Waste caustic must never be discharged
directly to sewers or surface waters. First convert to neutral
salts & dilute well w/water. inform legal authorities to
uncontrolled spills.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sodium hydroxide (sara iii)
cas: 1310-73-2
rtecs #: wb4900000
fraction by wt: >48.5%
other rec limits: none recommended
osha pel: 2 mg/m3
acgih tlv: c 2 mg/m3; 9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: carbonate as sodium bicarbonate
cas: 144-55-8
rtecs #: vz0950000
fraction by wt:
other rec limits: none recommended
ingred name: chlorate as sodium chlorate
cas: 7775-09-9
rtecs #: fo0525000
fraction by wt:
other rec limits: none recommended
ingred name: chloride as sodium chloride
cas: 7647-14-5
rtecs #: vz4725000
fraction by wt:
other rec limits: none recommended
ingred name: sulfate as sodium sulfate
cas: 7757-82-6
rtecs #: we1650000
fraction by wt:
other rec limits: none recommended
ingred name: silica as silicon dioxide
cas: 7631-86-9
fraction by wt:
other rec limits: none recommended
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
other rec limits: none recommended
Ld50 lc50 mixture: acute dermal ld50 (rabbit) 1350 mg/kg.
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eye, skin, respiratory &
gi tracts. Acute- corrosive to all body tissues. Skin contact can
cause destruction & dermatitis. Inhaling mist/dust may cause
irritation & rrespiratory illness. Can cause severe eye/skin
burns. If ingested, severe burns to mouth, throat, esophagus,
stomach. Chronic- unknown.
explanation of carcinogenicity: none
effects of overexposure: severe burns to eyes, skin, mouth, throat,
esophagus, stomach; upper respiratory tract and lung damage;
possibly blindness
First aid: get immediate medical help for all cases of exposure.
eyes/skin: flush with water for at least 15 minutes. Hold eyelids
open. Inhaled: remove to fresh air. Provide cpr/oxygen if necessary.
oral: do not i nduce vomiting. If conscious, drink large amount of
milk/water. Never give anything by mouth to an unconscious person.
if vomiting occurs spontaneously, keep airway clear.
Hcc: b1
nrc/state lic num: not relevant
boiling pt: b.P. Text: 230f - 291f
melt/freeze pt: m.P/f.P text: 14f - 54f
decomp temp: decomp text: not known
vapor pres: 13-135@60c
vapor density: 9.27-12.76
spec gravity: 1.11 - 1.53
ph: 14, 8%
solubility in water: complete
appearance and odor: clear liquid with no distinct odor
Stability indicator/materials to avoid: yes
water, acids, aluminum, tin, zinc, alloys of these metals, wool,
organic halogen compounds and organic nitro compounds
stability condition to avoid: product absorbs carbon dioxide from the
air. Keep contaienrs tightly closed.
Waste disposal methods: waste disposal to be performed in compliance
with all current local, state and federal regulations. Small
quantities may be dissolved in water and neutralized with acid. The
neutralized solution can b e flushed down the drain if permitted.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 48.5-91%
other rec limits: none recommended
ingred name: sodium hydroxide (sara iii)
cas: 1310-73-2
rtecs #: wb4900000
fraction by wt: 9- 51.5%
other rec limits: none recommended
osha pel: 2 mg/m3
acgih tlv: c 2 mg/m3; 9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: sodium chloride
cas: 7647-14-5
rtecs #: vz4725000
fraction by wt: 0 - 1.3%
other rec limits: none recommended
ingred name: sodium chlorate
cas: 7775-09-9
rtecs #: fo0525000
fraction by wt: 0 - 0.3%
other rec limits: none recommended
ld50 lc50 mixture: ld50 (oral rat) is 500 mg/kg (10%)
route of entry inds - inhalation: no
skin: no
ingestion: yes
carcinogenicity inds - ntp: no
iarc: no
osha: no
effects of exposure: target organs: eyes, skin, respiratory & gi tracts.
acute- inhale: mist may cause damage to respiratory tract & severe
irritation. Eye: corrosive. May cause injury & loss of vision.
skin: corrosive. Cause s burns. Oral: moderately toxic. May cause vomiting,
collapse. Chronic- unknown.
explanation of carcinogenicity: none
signs and symptions of overexposure: severe eye irritation, severe skin burns,
severe gastrointestinal irritation or ulceration, severe burns of mouth and
throat, severe upper respiratory tract irritation, impaired vision, even
blindness
medical cond aggravated by exposure: persons with pre-existing skin disorders
or eye problems or impaired respiratory function may be more susceptible to
the effects of the substance.
first aid: get immediate medical help for all cases of exposure.
eyes/skin: flush with water for 30 minutes. Hold eyelids open. Inhaled: remove
to fresh air. Provide cpr/oxygen if necessary. Oral: do not induce vom iting.
if conscious, drink large amountof milk/water. Never give anything by mouth
to an unconscious person.
hcc: b1
nrc/state lic no: not relevant
boiling point: =142.2c, 288.F
vapor pres: none
vapor density: none
spec gravity: 1.5
ph: >13
evaporation rate & reference: none (ccl4=1)
solubility in water: complete
appearance and odor: colorless liquid with no doro
percent volatiles by volume: 0
corrosion rate: unknown
product id: caustic soda 50%
cage: 0yfw2
company name: laroche chemicals inc
street: 1134 jefferson hwy
po box: 5500
city: gramercy la
zipcode: 70052
health emergency phone: 504-869-2365/800-424-9300(chemtrec)
label required ind: y
date of label review: 03/01/1995
status code: c
mfg label no: not relevant
label date: 03/01/1995
origination code: f
eye protection ind: yes
skin protection ind: yes
signal word: danger
health hazard: severe
contact hazard: severe
fire hazard: none
=======================================================
responsible party cage: 0yfw2
trans id no: 103221
product id: caustic soda 50%
msds prepared date: 09/01/1992
review date: 03/01/1995
mfn: 1
net unit weight: 687.0 lbs
multiple kit number: 0
review ind: y
unit of issue: dr
container qty: 0
type of container: drum
additional data: 50% solution of sodium hydroxide.
Hazard and precautions: target organs: eyes, skin, respiratory & gi tracts.
acute- corrosive. Inhale: mist may damage respiratory tract. Eye: may cause
injury & loss of vision. Skin: causes burns. Oral: moderately toxic.
chronic- unknown. Store away from incompatibles. Pick up spill. Transfer
into plastic lined steel containers. First aid- get immediate medical help
for all cases of exposure. Eyes/skin: flush with water for 30 minutes. Hold
eyelids open. Inhaled: remove to fresh air. Provide cpr/oxygen ifnecessary.
oral: do not induce vomiting. If conscious, drink large amount of milk/water.
never give anything by mouth to a n unconscious person.
spill release procedures: ventilate area. Wear rubber overclothing and gloves.
remove ignition sources (h2). Contain spill if possible. Pick up bulk of
liquid. Transfer into plastic lined steel containers. Dilute residual mate
rial with water and neutralize with weakacid.
neutralizing agent: acetic acid
waste disposal methods: dispose of in compliance with all current local, state
and federal regulations. Small quantities may be diluted and neutralized with
acid. Neutralized solution may be flushed down drain if permitted. call nrc
at 800-424-8802 if needed.
handling and storage precautions: store away from incompatible materials. Keep
containers sealed. Add caustic soda liquid 50% to water with adequate
agitation to prevent boiling.
other precautions: do not get in eyes or on skin. Do not generate mists. Do not
breathe mists. Keep out of reach of children. Do not take internally. For
industrial use only. Wash thoroughly after handling. Do not store in
aluminum, tin, lead/zinc containers.
Ld50 lc50 mixture: tlv 2 mg/m3 ceiling
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: this material is extremely corrosive
to all body tissue. Skin contact will result in severe burns and
frequently with deep ulceration. Eye contact will produce severe
and painful injury. Inhalation of mist will cause irritation and
possiblydamage to respiratory tract. Symptoms may not be
immediately painful or visible
explanation of carcinogenicity: this compound contains no ingredients at
concentrations of 0.1% or greater that are carcinogens or suspect
carcinogens.
effects of overexposure: skin burns, ulceration, eye burns, eye injury,
respiaratory tract irritation, respiratory tract damage.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: eyes: flush with water for 15 minutes while holding eyelids
open. Get medical attention. Skin: remove contaminated clothing.
wash with soap and water. If irritation persist, get medical
attention. Inh alation: remove to fresh air. Restore breathing. Get
medical attention. Ingestion: do not induce vomiting. Drink water
or citrus juices. Get medical attention.
Hcc: b1
boiling pt: b.P. Text: 298f,148c
melt/freeze pt: m.P/f.P text: not given
vapor pres: 19
vapor density: not given
spec gravity: 1.49
ph: >14
evaporation rate & reference: not given
solubility in water: complete
appearance and odor: colorless to gray, syrupy liquid
percent volatiles by volume: 50 %
Stability indicator/materials to avoid: yes
chlorinated hydrocarbons, leather, wool, alumiunum, zinc or materials
galvanized with zinc.
stability condition to avoid: water, moisture
hazardous decomposition products: none specified by manufacturer.
Waste disposal methods: hazardous waste. Epa hazardous waste number:
d002 (if ph is greater than 12.5). Managge waste in a permitted
hazardous waste facility. See 40 cfr 261.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: no ingredient for this formulation_ingredient
Ld50 lc50 mixture: ld50 (oral, rat) is unknown.
routes of entry: inhalation: no skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: **corrosive** eyes: may cause
irritation,burns,possibly blindess.Skin: may cause
irritation.Ingest: may cause delayed gi tract irritation and
burns.Inhal: may cause respiratory irritation,burns,possibly c
hemical pneumonia.
explanation of carcinogenicity: there are no ingredients above 0.1%
which are identified as carcinogens by ntp,iarc or osha.
effects of overexposure: severe burns, pain, nausea, vomiting.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: skin: remove contaminated clothing;wash with cool water.Get
medical attention if needed.Eyes: flush with water for 15
minutes.Get immediate medical attention.Inhal: remove to fresh
air.Give oxygen or art ificial respiration if needed.Get immediate
medical attention.Ingest: do not induce vomiting.Get prompt
qualified medical attention.If conscius,give milk or water.Keep
airway clear.
Hcc: b1
boiling pt: b.P. Text: 291f,144c
melt/freeze pt: m.P/f.P text: 53.6f,12.0c
decomp temp: decomp text: not known
vapor pres: 13mm/60c
spec gravity: 1.53
ph: 14
solubility in water: not available
appearance and odor: clear liquid with no distinct odor.
percent volatiles by volume: 0
corrosion rate: corrosiv
Stability indicator/materials to avoid: yes
air,water,acids and metals(sn,al,zn),leather,wool,organic
halogens,organic nitro compounds.
stability condition to avoid: avoid direct contact with water.
hazardous decomposition products: co(gas) may be formed when this
product contacts reducing sugars,foods,beverages;use caution in
confined spaces.
Waste disposal methods: discharge, treatment or disposal is subject to
federal, state or local regulations. Flush neutralized solution to
sewer with large amount of water, if permitted.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 48.5-91%
other rec limits: none recommended
osha pel: not relevant
acgih tlv: not relevant
ingred name: sodium hydroxide (cercla)
cas: 1310-73-2
rtecs #: wb4900000
fraction by wt: 9- 51.5%
other rec limits: none recommended
osha pel: 2 mg/m3
acgih tlv: c 2 mg/m3; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: sodium chloride
cas: 7647-14-5
rtecs #: vz4725000
fraction by wt: 0 - 1.3%
other rec limits: none recommended
ingred name: sodium chlorate
cas: 7775-09-9
rtecs #: fo0525000
fraction by wt: 0 - 0.3%
other rec limits: none recommended
Ld50 lc50 mixture: oral ld50 (rat) is 1350 mg/kg (naoh)
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: corrosive to all body tissues
with which it comes in contact. Superficial destruction of skin,
dermatitis. Inhalation of dust, spray or mist may result in varying
degrees of irritation or damag e to respiratory tract. Chronic: no
known chronic effects.
explanation of carcinogenicity: product contains no ingredients
currently classified as carcinogenic by ntp, iarc or osha.
effects of overexposure: skin burns/irritation, dermatitis, respiratory
tract irritation/burns, chemical pneumonia, eye burns/injury,
severe burns and complete tissue perforation of mucous membranes of
the mouth, throat, esop hagus and stomach.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: eyes/skin-immediately wash with plenty of water for at least
15 minutes. Remove contaminated clothing. Seek medical attention.
inhalation-remove to fresh air. If breathing is difficult, give
oxygen. S eek medical attention. Ingestion-do notinduce vomiting.
if conscious, give water or milk. Seek medical attention.
Hcc: b1
boiling pt: b.P. Text: 144f,62c
melt/freeze pt: m.P/f.P text: 12f,-11c
vapor pres: 13
spec gravity: 1.53
ph: 14.0
solubility in water: complete
appearance and odor: clear liquid with no distinct odor.
Stability indicator/materials to avoid: yes
water,aluminum,zinc,tin,alloys containing these metals.Strong
acids,leather,wool,organic halogen cmpds,organic nitro cmd
stability condition to avoid: avoid contact with water
hazardous decomposition products: none known.
conditions to avoid polymerization: material is not known to polymerize.
Waste disposal methods: prevent waste from contaminating surrounding
environment. Discard any product, residue, disposal container or
liner in accordance with all federal, state and local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 49-91%
other rec limits: none recommended
ingred name: sodium hydroxide (cercla)
cas: 1310-73-2
rtecs #: wb4900000
fraction by wt: 9-51.5%
other rec limits: none recommended
osha pel: 2 mg/m3
acgih tlv: c 2 mg/m3; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: sodium chloride
cas: 7647-14-5
rtecs #: vz4725000
fraction by wt:
other rec limits: none recommended
ingred name: sodium chlorate
cas: 7775-09-9
rtecs #: fo0525000
fraction by wt:
other rec limits: none recommended
Routes of entry: inhalation: no skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eyes- contact may cause eye damage.
skin- may cause skin damage. Inhalation- may cause irritation,
tissue damage & chemicl pneumonia. Ingestion- may cause tissue
damage and even death.
effects of overexposure: eyes- may cause burns, tissue destruction,
blindness. Skin- may cause burns, tissue ulceration. Effects may
be delayed. inhalation- nausea, headache, dizziness, pain,
decreased breathing capacity. A spiration into lungs can cause
bleedingand even death. ingestion- may cause diarrhea, vomiting,
burns, bleeding.
First aid: get medical help if symptoms persist. Inhaled: remove to fresh
air. Provide cpr/oxygen if needed. Eyes: flush with water for 15
minutes, holding eyelids open. Skin: wash with soap & water. Oral: do
not in duce vomiting. If conscious, rinse mouthwith water. Seek
immediate medical attention. If spontaneous vomiting occurs, keep
head below hips to prevent aspiration of vomitus into lungs.
Hcc: b1
boiling pt: b.P. Text: 289f,143c
melt/freeze pt: m.P/f.P text: 55.0f,12.8c
vapor pres: 6.3
spec gravity: 1.54
ph: 13
solubility in water: complete
appearance and odor: colorless to lightly colored liquid.
percent volatiles by volume: 50
Stability indicator/materials to avoid: yes
amphoteric metals, halogenated hydrocarbons, inorganic acids, organic
acids.
stability condition to avoid: contact with some metals can generate
explosive hydrogen gas.
Waste disposal methods: solids must be disposed of in a permitted waste
management facility. Recovered liquids may be reprocessed or
incinerated. Incinerated must be handled in a permitted hazardous
waste management facility . Dispose in accordance with
applicablelaws.
Ingred name: sodium hydroxide (cercla)
cas: 1310-73-2
rtecs #: wb4900000
fraction by wt: 50%
other rec limits: none recommended
osha pel: 2 mg/m3
acgih tlv: c 2 mg/m3; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: ld50 (oral, rat) is unknown.
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eye, skin, respiratory &
gi tracts. Acute- corrosive to all body tissues. Skin contact can
cause destruction. Inhaling mist may cause severe respiratory tract
irritation. Can cause sever e eye/skin burns. If ingested, severe
mouth, throat, esophagus, stomach burns. Chronic- unknown.
explanation of carcinogenicity: none
effects of overexposure: severe burns, possibly blindness, severe
irritation, pain
First aid: get immediate medical help for all cases of exposure.
eyes/skin: immediately flush with water for at least 15 minutes.
hold eyelids open. Inhaled: move to fresh air. Provide cpr/oxygen if
necessary. Ora l: do not induce vomiting. If conscious,drink large
amount of milk/water. Never give anything by mouth to an
unconscious person. If vomiting occurs spontaneously, keep airway
clear.
Hcc: b1
nrc/state lic num: not relevant
boiling pt: =145.C, 293.F
melt/freeze pt: =14.4c, 58.F
decomp temp: decomp text: not known
vapor pres: 1.5 @ 68f
spec gravity: 1.52
ph: 14
solubility in water: complete
appearance and odor: colorless to slightly hazy liquid - odorless
Stability indicator/materials to avoid: yes
water, acids, aluminum, tin, zinc, brass, wool, organic halogen
compounds, organic nitro compounds, reducing sugars
stability condition to avoid: exposure to air, temperature below 85f
hazardous decomposition products: none
Waste disposal methods: waste disposal to be performed in compliance
with current local, state and federal regulations. Small quantities
may be diluted with water and neutralized with acid. The
neutralized solution may be fl ushed down the drain if permitted.
rq: 1000 lbs.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sodium hydroxide (cercla)
cas: 1310-73-2
rtecs #: wb4900000
fraction by wt: 49 - 51%
other rec limits: none recommended
osha pel: 2 mg/m3
acgih tlv: c 2 mg/m3; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: sodium carbonate
cas: 497-19-8
rtecs #: vz4050000
fraction by wt:
other rec limits: none recommended
ingred name: sodium chloride
cas: 7647-14-5
rtecs #: vz4725000
fraction by wt:
other rec limits: none recommended
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
other rec limits: none recommended
osha pel: not relevant
acgih tlv: not relevant
Ld50 lc50 mixture: single dose oral ld50 hasnt been determd
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eye: may cause severe irrit w/corneal
injury which may result in perm impairment of vision,even
blindness.Mists may cause irrit.Skin: corro according to dot.Short
single expo may cause severe skin burns .Single prol expo not
likely to result in absorption of harmful amts.Ingest: may cause
severe burns of mouth,(signs/symp)
explanation of carcinogenicity: per msds: no relevant info found.
effects of overexposure: health: throat.May cause gi
irrit/ulceration.Inhal: mists may cause severe irrit of upper resp
tract(nose,throat). Notice: use of naoh cntnr free prod will
occasionally remian on ext of pkg.Haz to anyone coming in contact
w/it.When dry can become airborne,cause severe haz for
employees/drivers,passers by.Clean exterior.
medical cond aggravated by exposure: none specified by manufacturer.
target organs: no relevant info found.
First aid: eye: wash immed,cont til assist arrives for transpo to med
fac.Wash enroute if possible.Med assist not immed avai wash for
30mins;seek med attn immed.Skin: immed cont/thorough wash for 30mins
imperative while remove contam cloth.Prompt med consultation
essential.Ingest: dont induce vomit.Give lg amts of water/milk if
avai.Transpo to med fac.Inhal: remove to fresh air.Consult
physician.Dr: may (supplem)
Hcc: b1
boiling pt: =145.C, 293.F
melt/freeze pt: =14.4c, 58.F
vapor pres: 1.5
vapor density: na
spec gravity: 1.52g/ml
ph: 14
viscosity: np
evaporation rate & reference: np
solubility in water: water solution
appearance and odor: colorless to slightly hazy liquid, odorless
percent volatiles by volume: np
corrosion rate: np
Stability indicator/materials to avoid: yes
heat when mix w/h2o(spatter/boil).Flamm h2 contact
w/metal(al,brass,sn,zn).Acid,halogenated org,org nitro
cmpds,(polyme)
stability condition to avoid: avoid temps below 85f.
hazardous decomposition products: haz combust prod: na.Does not
decompose.
conditions to avoid polymerization: incompat: glycols.Rxs readily w/var
red sugars(fructose,glactose,maltose,dry whey solids)gives
co.Monitor tank atm for co
Waste disposal methods: no biocon expect-rel hi h2o sol.Slgihtly toxic
to aqu org on acute basis.Ph shifts outside 5-10;change may be
toxic to aqu org.Dont dump into sewer/ground/body h2o.In complai
w/fed/state/prov/loc law/ regs.Send to lic permit: recycler.Call dow
for list
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sodium hydroxide (cercla)
cas: 1310-73-2
rtecs #: wb4900000
fraction by wt: 49-51%
other rec limits: none recommended
osha pel: 2 mg/m3
acgih tlv: c 2 mg/m3; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: sodium carbonate
cas: 497-19-8
rtecs #: vz4050000
fraction by wt:
other rec limits: none recommended
ingred name: sodium chloride
cas: 7647-14-5
rtecs #: vz4725000
fraction by wt:
other rec limits: none recommended
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
other rec limits: none recommended
osha pel: not relevant
acgih tlv: not relevant
Ld50 lc50 mixture: ld50 (oral, rat) is unknown.
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eye, skin, respiratory &
gi tracts. Acute- extremely corrosive to all body tissues. Skin
contact can cause severe burns & ulceration. Inhaling mist may
cause severe irritation & lung dam age. Can cause severe eye
injury. If ingested, severe mouth, throat, esophagus, stomach
burns. Chronic- unknown.
explanation of carcinogenicity: none
effects of overexposure: severe burns, possibly blindness, severe
irritation, pain
First aid: get immediate medical help. Eyes/skin: immediately flush with
water for at least 15 minutes. Hold eyelids open. Inhaled: move to
fresh air. Provide cpr/oxygen if necessary. Oral: do not induce
vomiting. if conscious, drink milk/water, then neutralize with
diluted vinegar or fruit juice. Never give anything by mouth to an
unconscious person. If vomiting occurs spontaneously, keep airway
clear.
Hcc: c2
nrc/state lic num: not relevant
boiling pt: b.P. Text: 298f,148c
decomp temp: decomp text: not known
vapor pres: 19 @ 150f
spec gravity: 1.49
ph: >14
solubility in water: complete
appearance and odor: colorless to gray syrupy liquid - mild, slightly
pungent odor
percent volatiles by volume: 50
Stability indicator/materials to avoid: yes
water, acids, aluminum, tin, zinc, brass, wool, organic halogen
compounds, organic nitro compounds, reducing sugars
stability condition to avoid: exposure to air
hazardous decomposition products: none
Waste disposal methods: waste disposal to be performed in compliance
with current local, state and federal regulations. Small quantities
may be diluted with water and neutralized with acid. The
neutralized solution may be fl ushed down the drain if permitted.
epa #: d002
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sodium hydroxide (cercla)
cas: 1310-73-2
rtecs #: wb4900000
fraction by wt: 50%
other rec limits: none recommended
osha pel: 2 mg/m3
acgih tlv: c 2 mg/m3; 9596
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
Ld50 lc50 mixture: oral rat ld50: 1350 mg/kg (naoh)
routes of entry: inhalation: yes skin: unknown ingestion: yes
health hazards acute and chronic: target organs: eyes, skin, respiratory
tract, gastrointestinal tract. Acute: inhalation: exposure to vapor,
mist or liquid can produce burns of the respiratory tract. Severe
exposures could result in c hemical pneumonia. Eyes: contact can
cause severe damage including burns & blindness. The severeity
depends on concentration & how soon after exposure the eyes are
washed. Skin: corrosive. Contact can c ause burns & tissue
destruction. Prolonged or repeated contact can cause a high degree
of tissue destruction. Ingestion: corrosive. Severe burns and
complete tissue perforation of mucous membranes of mouth, throat &
stomach.
explanation of carcinogenicity: none known.
effects of overexposure: inhalation: burns, chemical pneumonia. Eyes:
burns, blindness. Skin: severe irritation, burns, tissue
destruction. Ingestion: severe burns of mucous membranes of mouth,
throat and stomach.
medical cond aggravated by exposure: none known.
First aid: eyes: immediately flush w/water for 15 minutes, holding lids
open. Get medical attn immediately. Skin: flush thoroughly with cool
water under shower while removing contaminated clothes. Discard
non-rubb er shoes. Get medical attn asap. Inhalation: remove to
fresh air. If breathing is difficult, have trained person
administer oxygen. If respiration stops, have trained person give
artificial respiration . Get immediate medical attn. Ingested:
nothing by mouth if unconscious. Do not induce vomiting! Give large
quantity water or milk if available. If vomitng occurs, keep airway
clear & give more water. get immediate medical attn.
Hcc: b1
boiling pt: =144.C, 291.2f
melt/freeze pt: =12.C, 53.6f
vapor pres: 13 mm hg @ 60c
spec gravity: 1.53
ph: 14 (7.5% soln)
evaporation rate & reference: not known
solubility in water: not available
appearance and odor: clear liquid with no distinct odor.
Stability indicator/materials to avoid: yes
water, air, acids, metals (especially aluminum, zinc& alloys containing
these metals), other (leather, wool, organic nitro compounds,
organic halogen compounds.
stability condition to avoid: no data provided by responsible party.
hazardous decomposition products: hazardous carbon monoxide gas can form
upon contact with reducing sugars, food and beverage products in
enclosed spaces and can cause death.
conditions to avoid polymerization: will not occur.
Waste disposal methods: recovery or reuse, rather than disposal should
be gosl. Dispose of in accordance with all applicable federal,
state and local health and environmental regulations. Shipments of
waste materials may be subject to manifesting requirements per
applicable regulations. Materials from spill clean-up may be
hazardous wastes & suject to regulations.
Ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
minumum % wt: 48.5
maxumum % wt: 94.5
ingred name: sodium hydroxide (na(oh))
cas: 1310-73-2
rtecs #: wb4900000
minumum % wt: 5.5
maxumum % wt: 51.5
osha pel: 2 mg/m3
acgih stel: c2 mg/m3
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: sodium chloride (nacl)
cas: 7647-14-5
rtecs #: vz4725000
minumum % wt: 0.
maxumum % wt: 1.3
ingred name: chloric acid, sodium salt
cas: 7775-09-9
rtecs #: fo0525000
minumum % wt: 0.
maxumum % wt: .3
Ld50 lc50 mixture: no data
routes of entry: inhalation: yes skin: yes ingestion: yes
health hazards acute and chronic: eye: can cause permanent eye injury.
can injure the cornea and cause blindness. Skin: can cause
permanent skin damage. Swallowing: swallowing this material may be
harmful or fatal. Inhalation: breathi ng of vapor or mist is
possible. Breathing this material may be harmful or fatal.
explanation of carcinogenicity: no data.
effects of overexposure: eye: stinging, tearing, redness, and swelling
of eyes. Can injure the cornea and cause blindness. Skin: redness,
burning and swelling of skin, burns, and other skin damage.
swallowing: severe stomach and intestinal irritation (nausea,
vomiting, diarrhea), abdoninal pain, and vomiting of blood.
swallowing this material may cause burns and destroy tissue in the
mouth, throat, and digestive tract. Lo w blood pressure and shock
may occur as a result of severe issue injury. Inhalation: severe
irritation and burns to the nose, throat, and respiratory tract.
medical cond aggravated by exposure: preexisting disorders of the
following organs (or organ systems) may be aggravated by exposure
to this material: skin, lung (for example, asthma-like conditions).
First aid: eyes: immediately flush gently with water for at least 15
minutes while holding lids apart. If symptoms develop as a result
of vapor exposure, immediately move individual away from exposure &
into fre sh air before flushing as recommended above. Seek
immediate medical attention. skin: immediately flush with water
for at least 15 minutes while removing contaminated clothing &
shoes. Seek immediate medical attention. Wash clothing before
reuse & discard contaminted shoes. Swallowing: seek immediate
medical attention. Do not induce vomiting. If victim
conscious/alert, give milk or water to drink. do not leave person
unattended.
Hcc: b1
boiling pt: =142.2c, 288.F
vapor pres: 3.000 mmhg @100.00f
vapor density:
spec gravity: 1.526@68.00f
ph: n/d
evaporation rate & reference: slower than ether
appearance and odor: clear & colorless homogeneous liquid solution
percent volatiles by volume: 50.0
Stability indicator/materials to avoid: yes
avoid contact: copper, organic materials, reactive materials, reactive
metals (aluminum, zinc, magnesium, copper), strong mineral acids,
strong organic acids, water.
stability condition to avoid: no data provided by manufacturer.
hazardous decomposition products: no data.
conditions to avoid polymerization: product will not undergo hazardous
polymerization
Waste disposal methods: pour into a large tank of water and neutralize.
flush to drain with large excess of water in accordance with
applicable regulations. For assistance with your waste management
needs-including disposal, recycling & waste stream reduction,
contact ashland distribution company, ic&s environmental servic es
group at 800-637-7922.
Ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
minumum % wt: 48.
maxumum % wt: 52.
ingred name: sodium hydroxide
cas: 1310-73-2
rtecs #: wb4900000
minumum % wt: 48.
maxumum % wt: 52.
osha pel: 2 mg/m3
acgih stel: c2 mg/m3
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs