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Reagent Tetrahydrofuran

NSN: 6810-01-271-4835 | Model: A-A-59282
NSN Properties and Flags
NATO Stock Number
6810-01-271-4835
DEMIL
NO
Physical Form
Liquid
Supplementary Features
Butylated hydroxytoluene added as a stabilizer

Pricing and Availability

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NSN 6810-01-271-4835 Datasheet

Supply Class (FSC):
Chemicals
Cross Reference:
  • A-A-59282
  • 1261A0308
  • O-C-265
  • 1261A0308
Cage Codes:
  • Federal Commercial Item Description (CAGE 58536)
  • Lockheed Martin Corporation (CAGE 03538)
  • Federal Specifications (CAGE 81348)
  • Martin Marietta Technologies Inc (CAGE 54497)
Schedule B & Trade:
  • Schedule B: 3822000002 (NAICS 325413)

    Diagnostic or lab reagents on a backing, prepared diag/lab reagents whether or not on a backing, not of heading 3002 or 3006; certified ref materials

  • SITC: 59869

    Composite diagnostic or laboratory reagents, n.E.S.

  • End Use: 12550

    Chemicals-other

Identification:
HMIC

Y - Indicates information is in the hazardous materials information resource system (hmirs).

PMIC

A - Item does not contain precious metal.

CRITL

- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.

Freight Information:
  • NMFC:

    045615 - Poisonous/toxic matls, group a

  • WCC:

    635 - Chemicals, other than drugs or sundries

  • SHC:

    9 - Other or no special handling required (sh)

  • ADC:

    A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.

  • ACC:

    C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp

  • TCC:

    R - Flammable liquids, un class 3 (flammable liquids label)

  • LTL:

    W - Rating variable

NSN Management Codes:
  • SOS
    Sms
  • AAC
    H
  • Quantity per pack
    No qup
  • Unit of Measure
    Bt
  • Shelf Life
    N/A
  • Classification Control
    U
  • MGMT_CTL
    9b----f
  • Repariability

Questions & Answers:

What are the historical prices recorded for this stock number?
Historical data shows pricing from $400.34 to $667.24..
Does NSN 6810-01-271-4835 have a shelf life?
No. There is no shelf life applicable for this NSN.
What NATO entities are users of this NSN?
Department Of The Navy, Brazil, Spain, Canada, and Turkey
What is the NIIN of NSN 6810-01-271-4835?
012714835 or 01-271-4835
Does NSN 6810-01-271-4835 require demilitarization?
Yes - ITAR Controlled
What is the most recent solicitation for NSN 6810-01-271-4835?
No solicitations for this NSN.
When was this national stock number assigned to the federal catalog?
Jan 26, 1988
MSDS

Material Safety

MSDS BMDWV TETRAHYDROFURAN

Hazards

Ld50 lc50 mixture: ld50 oral rat is 3000 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: irritation, defatting action,
narcotic and systemic effects, moderately toxic by ingestion.

chronic: irritation. thf itself does not cause internal injury.

however, if furan is present, it may cause liver and kidney
damage.

effects of overexposure: eyes: irritation, burns. Skin: irritation,
allergic sensitization. Inhalation: irritation of nose and
respiratory tract, nausea, dizziness, headache, narcosis.

medical cond aggravated by exposure: none specified by manufacturer.

First Aid

First aid: eyes: flush with plenty of water for at least 15 minutes, get
medical attention. Skin: flush with water while removing
contaminated clothing. If irritation persists, see doctor.

inhalation: remove to fresh air. Give cpr/oxygen if needed. See
doctor. Ingestion: give milk or water. Do not induce vomiting. See
doctor. Nothing by mouth if unconscious or having convulsions.

Chemical Properties

Hcc: f2
boiling pt: =66.1c, 151.F
melt/freeze pt: =-108.3c, -163.F
m.P/f.P text: fz pt
vapor pres: 143 @ 68f
vapor density: 2.5
spec gravity: 0.888
evaporation rate & reference: 8.0 (butyl acetate = 1)
solubility in water: complete
appearance and odor: colorless, mobile liquid with an ether-like odor,
detactable above 50 ppm in ai
percent volatiles by volume: 100

Reactivity

Stability indicator/materials to avoid: yes
strong oxidizing agents, lithium aluminum hydride, sodium or potassium
hydroxide.

stability condition to avoid: high heat, open flames and other sources
of ignition
hazardous decomposition products: irritating fumes, carbon monoxide,
carbon dioxide.

conditions to avoid polymerization: it may polymerize in presence of
cationic initiators such as selected lewis acids or strong proton
acids.

Proper Disposal

Waste disposal methods: notify your local environmental officer. Keep in
covered containers pending disposal. Dispose of in accordance with
federal.State and local regulations. Manufacturer recommends
incineration. Epa hazar dous waste code is u213.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: tetrahydrofuran (sara iii)
cas: 109-99-9
rtecs #: lu5950000
= wt: 100.

other rec limits: none specified
osha pel: 200 ppm/250 stel
acgih tlv: 200 ppm/250stel;9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs

MSDS BPZLS TETRAHYDROFURAN

Hazards

Ld50 lc50 mixture: none specified by manufacturer.

routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhal: thf is an anesthetic agent in
high concentrations. Overexposure may cause irritation of the nose
& throat, dizziness & headache. Ingest: irritating to mucous
membranes. May cause sore throat & ab dominal pain. May cause
liver/kidney injury. Skin: causes irritation w/redness & pain.

eye: irritating (efts of overexp)
explanation of carcinogenicity: not relevant
effects of overexposure: hlth haz: to eye tissue.

medical cond aggravated by exposure: persons w/pre-existing skin
disorders or eye problems or impaired liver or kidney function may
be more susceptible to effects of substance.

First Aid

First aid: inhal: remove to fresh air. If not brthg,give artf resp. If
brthg dfclt,give o*2. Call md. Ingest: get immed med attn. If md not
immed avail, induce vomit by giving 2 glasses of water & sticking
finger down throat. Never give anything by mouth to uncon person.

skin: immed flush w/plenty of water for at least 15 min while
removing contamd clthg/shoes. Wash clthg before reuse.Call md
immed. (supp data)

Chemical Properties

Hcc: f2
boiling pt: b.P. Text: 151f,66c
melt/freeze pt: m.P/f.P text: -163f,-108c
vapor pres: 114 @ 59f
vapor density: 2.5
spec gravity: 0.88
evaporation rate & reference: 14.5 (butyl acetate = 1)
solubility in water: miscible with water
appearance and odor: colorless, mobile liquid, ether-like odor.

Reactivity

Stability indicator/materials to avoid: yes
reacts violently w/air on standing. Lialh*2, strong oxidizers, naalh*2
& potassium hydroxide.

stability condition to avoid: stable in closed cntnrs w/o*2 & light
excluded. Distillation/evaporation can concentrate peroxides to
create explo haz.

hazardous decomposition products: emits irritating fumes & toxic gases &
vapors (such as co) when heated to decomposition.

Proper Disposal

Waste disposal methods: ensure compliance with local, state and federal
regulations.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: tetrahydrofuran
cas: 109-99-9
rtecs #: lu5950000
osha pel: 200 ppm;250 ppm stel
acgih tlv: 200 ppm;250 ppm stel
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs

ingred name: other prec: static sparks. Stor & use areas should be no
smoking areas. Use non-sparking type tools & equipment. (ing 3)
rtecs #: 9999999zz

ingred name: ing 2: do not use compressed air for filling,
discharging/handling. Peroxides can be removed by treatment
w/strong(ing 4)
rtecs #: 9999999zz

ingred name: ing 3: ferrous sulfate solution made slightly acidic
w/sodium bisulfite. Keep away from heat, sparks & flame. (ing 5)
rtecs #: 9999999zz

ingred name: ing 4: keep cntnr closed. Use w/adeq vent. Avoid brthg vap.

avoid cntct w/eyes, skin & clthg.

rtecs #: 9999999zz

ingred name: vent: it can control emissions of contaminant at source,
pvntg dispersion of it into gen work area. Please refer (ing 7)
rtecs #: 9999999zz

ingred name: ing 6: to acgih document, "industrial ventilation, a manual
of recommended practices", most recent edition, for details.

rtecs #: 9999999zz

MSDS BSVRC TETRAHYDROFURAN

Hazards

Ld50 lc50 mixture: ld50 oral rat is unknown.

routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: eyes: irritation. Skin:
irritation, redness, pain. Inhalation: thf is an anesthetic agent.

may cause irritation of nose and throat, dizziness, and headache.

ingestion: irritating to mucous memb ranes. May cause sore throat
and abdominal pain. May also cause liver or kidney injury. Chronic:
no information found.

explanation of carcinogenicity: none
effects of overexposure: eyes: irritation. Skin: irritation, redness,
pain. Inhalation: anesthetic effects, nose and throat irritation,
dizziness, headache. Ingestion: mucous membrane irritation, sore
throat, abdominal pain, liver and kidney injury.

medical cond aggravated by exposure: persons with pre-existing eye
problems or skin disorders or impaired liver or kidney function may
be more susceptible to the effects of exposure to this product.

First Aid

First aid: eyes: flush with plenty of water. Get medical attention.

skin: remove contaminated clothing. Flush area with large amounts
of water. Get medical attention. Inhalation: move to fresh air. If
not breath ing, give cpr. If breathing difficult, give oxygen. Get
medical attention. Ingestion: if physician not immediately
available give two glasses of water and induce vomiting. Get
medical attention.

Chemical Properties

Hcc: f2
boiling pt: b.P. Text: 151f,66c
melt/freeze pt: m.P/f.P text: -163f,-108c
vapor pres: 114
vapor density: 2.5
spec gravity: 0.88
evaporation rate & reference: 14.5 (butyl acetate =1)
solubility in water: miscible with water.

appearance and odor: colorless, mobile liquid. Ether-like odor.

Reactivity

Stability indicator/materials to avoid: yes
strong oxidizers,lithium aluminum hydride,sodium aluminum
hydride,potassium hydroxide.Reacts violently w/air on standing
stability condition to avoid: heat, sparks, flames. Stable in closed
containers with oxygen and light excluded.

hazardous decomposition products: emits irritating fumes and toxic gases
and vapors (such as carbon monoxide) when heated to decomposition.

conditions to avoid polymerization: this substance does not polymerize.

Proper Disposal

Waste disposal methods: contact local environmental officer. Dispose of
waste in accordance with local, state and federal regulations.If
permitted atomize in rcra approved combustion chamber or absorb
with absorbent for disp osal as hazardous waste. Rq=1000 lbs.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: tetrahydrofuran (sara iii)
cas: 109-99-9
rtecs #: lu5950000
other rec limits: none recommended
osha pel: 200 ppm
acgih tlv: 200 ppm/250stel;9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs

MSDS BWCZS TETRAHYDROFURAN

Hazards

Ld50 lc50 mixture: oral ld50 (rat) is 2815 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: inhalation may cause
respiratory irritation, cns depression, asphyxiation. Contact may
cause eye irritation. Ingestion may cause gi tract irritation;
aspiration may cause severe lund irritation /chemical pneumonitis.

chronic: prolonged or repeated exposure may cause kidney/liver
damage,conjunctivitis,dermatitis.

explanation of carcinogenicity: tertahydrofuran is not listed as a
carcinogen or suspected carcinogen by ntp, iarc, or osha.

effects of overexposure: inhaled: headaches, dullness, sore throat,
coughing, vomiting, nausea, weakness, fatigue, unconsciousness,
death. Eyes: redness, tearing, blurred vision, burns. Skin: drying,
defatting, rash. Ingested : sore throat, abdominal pain, nausea,
vomiting, diarrhea, dullness.

medical cond aggravated by exposure: persons with impaired liver,
kidney, or pulmonary function; eye or skin disorders.

First Aid

First aid: get medical attention immediately.Eyes-flood with water for
15 minutes.Skin-flush with water for 15 minutes.If irritation
occurs/persist,see doctor.Inhaled-move to fresh air.If breathing
difficult,giv e oxygen.If breathing stopped,give artificial
respiration.Ingested-if conscious,good gag reflex,& no
drooling,give syrup of ipecac followed by water.

Chemical Properties

Hcc: f2
boiling pt: b.P. Text: 153f,67c
melt/freeze pt: m.P/f.P text: -162f,-108c
vapor pres: 145 mm hg
vapor density: 2.5
spec gravity: 0.8892
viscosity: 0.5 cps @ 20c
evaporation rate & reference: 14.5 (n-butyl acetate=1)
solubility in water: complete
appearance and odor: colorless, volatile, mobile liquid; ether-like
odor.

Reactivity

Stability indicator/materials to avoid: yes
acids,bromine,metallic
hydrides,oxidizers,plastics/rubber/coatings,potassium & sodium
hydroxide,lithium-aluminum alloys.

stability condition to avoid: normally is inhibitied; if uninhibited or
distilled or dryed, may form explosive organic peroxides on
exposure to air.

hazardous decomposition products: thermal decomposition products may
include toxic oxides of carbon.

conditions to avoid polymerization: may polymerize exothermically in
contact with some acids.

Proper Disposal

Waste disposal methods: disposal must be in accordance with standards
applicable to generators of hazardous waste, 40 cfr 262. Epa
hazardous waste number u213.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: tetrahydrofuran (sara iii)
cas: 109-99-9
rtecs #: lu5950000
fraction by wt: >99%
other rec limits: none recommended
osha pel: 200 ppm
acgih tlv: 200 ppm/250stel;9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs

ingred name: peroxidation inhibitor
fraction by wt:
other rec limits: none recommended