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Sulfuric acid and oleum
Sulfuric acid; oleum
Chemicals-inorganic
Y - Indicates information is in the hazardous materials information resource system (hmirs).
PMICA - Item does not contain precious metal.
ADPE- Represents items with no adp components
CRITL- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.
044155 - Chem: corrosive matls, group a
450 - Acids, liquid, corrosive
9 - Other or no special handling required (sh)
A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.
C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp
W - Rating variable
W - Corrosive materials, un class 8 (corrosive label)
Questions & Answers: |
|
| What are the historical prices recorded for this stock number? | |
| Historical data shows pricing from $374.91 to $624.85.. | |
| Does NSN 6810-01-418-1697 have a shelf life? | |
| No. There is no shelf life applicable for this NSN. | |
| What NATO entities are users of this NSN? | |
| Department Of The Navy | |
| What is the NIIN of NSN 6810-01-418-1697? | |
| 014181697 or 01-418-1697 | |
| Does NSN 6810-01-418-1697 require demilitarization? | |
| Yes - ITAR Controlled | |
| What is the most recent solicitation for NSN 6810-01-418-1697? | |
| No solicitations for this NSN. | |
| When was this national stock number assigned to the federal catalog? | |
| Aug 21, 1995 | |
Ld50 lc50 mixture: product's ld50 (oral rat) was not stated
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: third degree burns. Severe
respiratory, skin, and eye irritant. Bronchitis, laryngeal and
pulmonary edema may result.
explanation of carcinogenicity: iarc lists a possible link between
sulfuric acid exposure & laryngeal cancer w/insufficient data for
confirmation.
effects of overexposure: prickling or burning sensation of skin and
mucous membranes. Coughing, sneezing, tightness of chest,
difficulty in breathing.
medical cond aggravated by exposure: any pre-existing respiratory
disease, for example emphysema.
First aid: see supp data. Get immediate medical attention!! Eye: flush
w/water for 15 min. Skin: wash w/soap & water. Remove contaminated
clothing & launder before reuse. Inhaled: remove from exposure. Aid
or resto re breathing as needed. Ingested: do notinduce vomiting.
give large quantities of milk, milk of magnesia, table oil, eggs or
water to drink. Get immediate medical attention. Rinse mouth often.
Hcc: c1
nrc/state lic num: none
boiling pt: b.P. Text: 260f,127c
vapor pres: < 1
vapor density: 3.4 (air=1
spec gravity: 1.400 (water=1)
ph: < 1
solubility in water: complete
appearance and odor: clear, colorless liquid.
percent volatiles by volume: unk.
Stability indicator/materials to avoid: yes
metals, organics, nitrates, carbides, chlorates, allyl compounds, and
aldehydes
stability condition to avoid: contact with metals, organics.
hazardous decomposition products: sulfur oxides at high temperature.
reacts w/above to form hydrogen cyanide & hydrogen cyanide.
conditions to avoid polymerization: will not occur. avoid all contact
with organic substances and most metals.
Waste disposal methods: neutralize w/lime or soda ash. Consult
regulations. Epa hazardous waste d002- corrosive & d003-reactive if
discarded w/o prior neutralization.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara iii)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 34-36%
other rec limits: none specified
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3; 9192
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 64-66%
other rec limits: none specified
Ld50 lc50 mixture: rat,lc50: 510mg/m3/2h;ld50: 2140mg/kgrtecs
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eye, skin, respiratory &
gi tracts. Acute- corrosive! Causes severe eyes & skin burns. Mist
is extremely irritating to respiratory tract. Contact with eyes may
result in blindness. Swall owing may be fatal. Inhalation may
damage respiratory tract. Chronic- may cause dental erosion,
dermatitis, bronchitis.
explanation of carcinogenicity: none
effects of overexposure: severe irritation and burning, visual
impairment, dental erosion, cough, possible charring of skin, pain,
blindness
medical cond aggravated by exposure: open wounds and sores, respiratory
ailments such as emphysemia and bronchitis
First aid: get medical attention immediately. Eye/skin: immediately
flush with water for 15-20 minutes. Hold eyelids open. Continue
rinsing with normal saline until ph=7. Inhaled: remove to fresh air.
provide oxy gen/cpr if needed. Oral: do not induce vomiting. If
conscious, drink large amount of water/milk. Ingested acid must be
diluted about 100 folds. If vomiting occurs, keep head below hips.
Hcc: c1
nrc/state lic num: not relevant
boiling pt: b.P. Text: 640f,338c
vapor pres: variable
spec gravity: 1.2085 - 1.2185
solubility in water: soluble
appearance and odor: clear to slightly cloudy, oily liquid; odorless to
slightly pungent odor.
Stability indicator/materials to avoid: yes
acetaldehyde, alcohols, strong bases, chlorates, nitrates, carbides,
most metals, organic materials, water, picrates
stability condition to avoid: adding water to acid (always add acid
slowly to water)
hazardous decomposition products: toxic oxides of sulfur
Waste disposal methods: dispose of spilled, neutralized, or waste
product, contaminated soil, and other materials in accordance with
all local, state, and federal regulations. Epa hazardous waste
number d002. Reportable quan tity (rq): 1000 lbs. Do not flush acid
to sewer.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: sulfuric acid (sara 302/313) (cercla)
cas: 7664-93-9
rtecs #: ws5600000
fraction by wt: 29-30%
other rec limits: none recommended
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3/3 stel; 9495
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: balance
other rec limits: none recommended
osha pel: not relevant
acgih tlv: not relevant
Ld50 lc50 mixture: acute oral ld 2,140 mg/kg (rabbit)
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: 3d degree burns. Severe
respiratory, skin and eye irritant. Bronchitis, laryngeal and
pulmonary edema may result.
explanation of carcinogenicity: iarc: a limited study of refinery
workers suggested a possible link between sulfuric acid exposure &
laryngeal cancer. However, due to the small number of workers
involved & the mixed exposure to seve ral other materials including
diethylsulfate (listed carcinogen by iarc & ntp) there is no
cause-effect relationship inferred.
effects of overexposure: prickling or burning sensation of skin and
mucous membranes. Coughing, sneezing, tightness of chest.
difficulty in breathing.
medical cond aggravated by exposure: individuals with preexiting disease
of the lungs may have increased susceptibility to the toxicity of
excessive exposure.
First aid: inhalation: remove from exposure. Cpr if indicated. Give
oxygen. Eyes: flush immediately with large amounts of water for at
least 15 minutes. Hold lids open. Skin: flush immediately with
large amounts of water. Remove contaminated clothing & shoes.
ingestion: do not induce vomiting! Give large amounts of milk, milk
of magnesia or table oil or fresh eggs. Use water if nothing else
available. Rinse mouth often.
Hcc: c1
boiling pt: =135.C, 275.F
melt/freeze pt: =-62.2c, -80.F
vapor pres:
vapor density: 3.4(air=1)
spec gravity: 1.265 (water=1)
ph:
solubility in water: soluble in all proportion
appearance and odor: clear, colorless liquid
Stability indicator/materials to avoid: yes
strong corrosive agent will attack most metals. Contact with organics,
nitrates, carbides, chlorates, etc. May cause ignition. Allyl
compounds and aldehydes undergo polymerization - possible violent.
stability condition to avoid: contact with metals, organics.
hazardous decomposition products: sulfur oxides at high temperature.
reacts with above to form hydrogen cyanide and hydrogen sulfide.
conditions to avoid polymerization: all contact with organic substances
and most metals.
Waste disposal methods: flush as above. Neutralize with lime or soda
ash, (a minimum of 5.2 pounds soda ash per gallon of battery fluid,
electrolyte). Consult regulations. Epa hazardous waste d002 -
corrosive and d003 - reac tive if discarded without prior
neutralization.
Ingred name: sulfuric acid
cas: 7664-93-9
rtecs #: ws5600000
minumum % wt: 34.
maxumum % wt: 36.
osha pel: 1 mg/m3
acgih tlv: 1 mg/m3
acgih stel: 3 mg/m3
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
minumum % wt: 64.
maxumum % wt: 66.