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Technical Dichlorodifluoromethane

NSN: 6830-00-264-5913 | Model: FRE0N12
NSN Properties and Flags
NATO Stock Number
6830-00-264-5913
DEMIL
NO
Department Of Transportation Cylinder Identifying Number
4ba300 or 4bw300 or 4e300
Physical Form
Liquid
Supplied Amount
45.000 pounds
Cylinder National Stock Number
8120-01-337-1816
Supplied Cylinder
Supply item
Special Features
GASO-NL-YNS-N683
Nondefinitive Specification/std Data
12 type

Pricing and Availability

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NSN 6830-00-264-5913 Datasheet

Supply Class (FSC):
Gases: Compressed And Liquefied
Cross Reference:
  • FRE0N12
  • A-A-58060
  • BB-F-1421
Cage Codes:
  • Du Pont E I De Nemours and Co Inc (CAGE 18873)
  • Federal Commercial Item Description (CAGE 58536)
  • Federal Specifications (CAGE 81348)
Schedule B & Trade:
  • Schedule B: 2903770050 (NAICS 325120)

    Dichlorodifluoromethane

  • SITC: 51138

    Halogenated derivatives of acyclic hydrocarbons containing two or more different halogens

  • End Use: 12540

    Chemicals-organic

Identification:
HMIC

Y - Indicates information is in the hazardous materials information resource system (hmirs).

PMIC

A - Item does not contain precious metal.

CRITL

- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.

Freight Information:
  • NMFC:

    085880 - Gases/mixture noi o/t poison

  • WCC:

    634 - Cylinders, compressed gas, filled or empty

  • SHC:

    9 - Other or no special handling required (sh)

  • ADC:

    A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.

  • ACC:

    C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp

  • TCC:

    G - Nonflammable compressed gas, un class 2 (nonflammable gas label; except: (1) oxygen which requires an oxidizer label, and (2) fl

  • LTL:

    Q - 70.0

NSN Management Codes:
  • SOS
    Sms
  • AAC
    D
  • Quantity per pack
    1
  • Unit of Measure
    Cy
  • Shelf Life
    N/A
  • Classification Control
    U
  • MGMT_CTL
    J2200x-
  • Repariability
    This is a nonreparable item. if condemned or economically unserviceable, then dispose at the level authorized replace the item.

Questions & Answers:

What are the historical prices recorded for this stock number?
Historical data shows pricing from $0.04 to $0.07..
Does NSN 6830-00-264-5913 have a shelf life?
No. There is no shelf life applicable for this NSN.
What NATO entities are users of this NSN?
Department Of The Army, Department Of The Air Force, U.s. Marine Corps, Department Of The Navy, U.s. Coast Guard, Poland, Spain, Republic Of Korea, Greece, and Turkey
What is the NIIN of NSN 6830-00-264-5913?
002645913 or 00-264-5913
Does NSN 6830-00-264-5913 require demilitarization?
Yes - ITAR Controlled
What is the most recent solicitation for NSN 6830-00-264-5913?
No solicitations for this NSN.
When was this national stock number assigned to the federal catalog?
Jan 01, 1963
MSDS

Material Safety

MSDS BDQLH GENETRON 12

Hazards

Effects of overexposure: depresses cns,irritats respir tract;high concs
cause cardiac arrythmia,asphyxiation and death.

Chemical Properties

Hcc: g3
boiling pt: b.P. Text: -22f,-30c
melt/freeze pt: m.P/f.P text: -252f,-158c
vapor pres: 35 psi
vapor density: 4.26
spec gravity: 1.325
solubility in water: slight
appearance and odor: colorless liquefied gas with faint ethereal odor
percent volatiles by volume: 100

Reactivity

Stability indicator/materials to avoid: yes
powdered al,mg. Attacks mg and its alloys.

stability condition to avoid: decomposes at gas flame temperature give
halogens,halo-acids
hazardous decomposition products: toxic substances by high
heat,e.G.Fluorides,carbonyl halides

Proper Disposal

Waste disposal methods: for moderate quantities permit to evaporate in
air at slow rate,so as not to exceed tlv.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: dichlorodifluoromethane (sara iii)
cas: 75-71-8
rtecs #: pa8200000
fraction by wt: 100%
osha pel: 1000 ppm
acgih tlv: 1000 ppm; 9192
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ozone depleting chemical: 1

MSDS BDQLJ FREON 12 FLUOROCARBON

Hazards

Ld50 lc50 mixture: tlv is 1000 ppm, 4950 mg/m3.

routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute-inhale: may cause tingling
sensation,humming in the air,slurred speech,amnesia,irregular heart
beat,unconsciousness or death.Misuse can be
fatal.Eye: tearing,irritation.Skin: liquid may cause frost
bite.Oral: liquid may cause necrosis of lips & tongs,blanching of
skin,pain & tenderness.Chronic-may cause cns effects.

effects of overexposure: inhalation may cause tingling sensation,
humming in the air, slurred speech, amnesia, irregular heart beat,
unconsciousness or death. Misuse can be fatal. Eye irritation &
blurred vision. Skin exposur e to liquid may cause frostbite.

orallyliquid may cause necrosis of lips & tongs, blanching of skin,
pain & tenderness.

medical cond aggravated by exposure: individuals with pre-existing
diseases of the central nervous or cardiovascular system may have
increased susceptibility to the toxicity of excessive exposures.

First Aid

First aid: get medical attention in all cases. Eye: flush with water for
15 minutes. Hold eyelids open. Skin: flush with water. Treat for
frostbite if necessary. Inhaled: remove to fresh air & provide
oxygen/cpr if needed. Oral: ingestion is not considered a potential
route of exposure.

Chemical Properties

Hcc: g3
boiling pt: b.P. Text: -22f,-30c
vapor pres: 4888 @ 25c
vapor density: 4.26
spec gravity: 1.315
solubility in water: negligible
appearance and odor: clear, colorless liquefied gas - slight ethereal
odor
percent volatiles by volume: 100

Reactivity

Stability indicator/materials to avoid: yes
alkali or alkaline earth metals, powdered aluminum, zinc, beryllium,
etc.

stability condition to avoid: fire, temperatures above 125f
hazardous decomposition products: may form hydrogen fluoride, hydrogen
chloride and traces of carbonyl halides.

Proper Disposal

Waste disposal methods: for discharge or disposing of waste material,
consult local, state and federal authorities.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: dichlorodifluoromethane (sara iii)
cas: 75-71-8
rtecs #: pa8200000
fraction by wt: 100%
osha pel: 1000 ppm
acgih tlv: 1000 ppm; 9192
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ozone depleting chemical: 1

MSDS BKBKH NATIONAL REFRIGERANT 12

Hazards

Ld50 lc50 mixture: inhalation 30 min lc50 800,000 ppm (rat)
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation: heart irregularities,
unconsciousness, or death. Vapor reduces oxygen for breathing.

eyes: mild irritant.

effects of overexposure: liquid contact can cause frostbite. temporary
nervous system depression with anaesthetic effects.

medical cond aggravated by exposure: none specified by manufacturer.

First Aid

First aid: inhalation: remove to fresh air. If not breathing, give
artificial respiration. If breathing is difficult give oxygen.

skin: flush with water. Treat with frostbite if necessary. Eyes:
immediately fl ush eyes with plenty of water. Call a physician.

ingestion: consult a physician. *physicians: catecholamine drugs,
such as epinephrine, should be used with special precaution.

Chemical Properties

Hcc: g3
boiling pt: b.P. Text: -22f,-30c
vapor pres: 94.5 psia
vapor density: 4.26
solubility in water: insoluble
appearance and odor: colorless liquified gas with slight ethereal odor.

Reactivity

Stability indicator/materials to avoid: yes
alkali or alkaline earth metals, powdered al, zn, be, etc.

stability condition to avoid: open flames and high temperatures.

hazardous decomposition products: hydrochloric and hydrofluoric acids
and carbonyl halides.

Proper Disposal

Waste disposal methods: comply with federal, state, and local
regulations. reclaim by distillation or remove to a permitted
waste facility.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: dichlorodifluoromethane (sara iii)
cas: 75-71-8
rtecs #: pa8200000
fraction by wt: 100%
other rec limits: none specified
osha pel: 1000 ppm
acgih tlv: 1000 ppm; 9192
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ozone depleting chemical: 1

MSDS BPBKV REFRIGERANT 12,FREON 12,GENETRON 12,R-12,CF

Hazards

Ld50 lc50 mixture: lc 50 rat 800,000 ppm/30 min
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation of high concentrations of
vapor is harmful and may cause heart irregularities,
unconsciousness, asphyxiation and death. Intentional misuse can be
fatal. Liquid contact can cause frosbite. M ay cause eye
irritation.

explanation of carcinogenicity: data per msds
effects of overexposure: eye irritation with discomfort, tearing, or
blurring of vision. Skin contact may result in frostbite. Inhaling
may cause temporary nervous system depression with dizziness,
headache, confusion, incoor dination, and loss of consciousness.

excessive exposures may cause heart and circulatory irregularities.

medical cond aggravated by exposure: individuals with preexisting
diseases of the central nervous or cardiovascular system may have
increased susceptibility to the toxicity of excessive exposures.

First Aid

First aid: eyes: immediately flush with plenty of water for at least 15
minutes.See doctor. Skin: flush with water.Treat for frostbite if
necessary. Inhalation: remove to fresh air. Give cpr/oxigen if
needed. Get m edical help. Ingestion: get med help. Note to
physician: because of possible cardiac disturbance, catecholamine
drugs, such as epinephrine should be used with special caution.

Chemical Properties

Hcc: g3
boiling pt: b.P. Text: -21.6f/-29c
vapor pres: 79.8 psig
vapor density: 2.32lb/ft3
spec gravity: 1.31 of liquid
solubility in water: insoluble
appearance and odor: clear, colorless liquefied gas; slight ethereal
odor
percent volatiles by volume: 100

Reactivity

Stability indicator/materials to avoid: yes
alkali or alkaline earth metals-powdered al, zn, be, etc.

stability condition to avoid: high temperatures and open flames
hazardous decomposition products: hydrochloric and hydrofluoric
acids-possibly carbonyl halides. Decomposed by high
temperatures(open flames, hot metal)

Proper Disposal

Waste disposal methods: contact your local environmental officer.

reclaim or remove to a permitted facility. Dispose of in accordance
with all applicable federal, state and local regulations.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: dichlorodifluoromethane (sara iii)
cas: 75-71-8
rtecs #: pa8200000
fraction by wt: 100%
osha pel: 1000 ppm
acgih tlv: 1000 ppm; 9192
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ozone depleting chemical: 1

MSDS BPTXV R-12; CFC-12; REFRIGERANT 12; DICHLORODIFLU

Hazards


ld50 lc50 mixture: oral ld50 (rat) is unknown
route of entry inds - inhalation: yes
skin: yes
ingestion: yes
carcinogenicity inds - ntp: no
iarc: no
osha: no
effects of exposure: acute-inhalation: may cause narcosis in concentration
>1000 ppm. May cause asphyxiation in high concentration. Eye/skin: may
cause frostbite if exposed to direct spray. Ingestion: not likely due to lo w
toxicity. Chronic-none.

signs and symptions of overexposure: none specified by manufacturer.

medical cond aggravated by exposure: persons with acrdiac arrhyythmia may be at
increased in severe exposure.

first aid: eyes/skin: flush with water for at least 15 minutes. If irritation
persists, see doctor. Inhalation: remove to fresh air. Give oxygen/cpr if
needed. Call a physician. Ingestion: compound not normally considered
hazardous.Get medical attention as necessary.

Chemical Properties


hcc: g3
b.P. Text: -22f,-30c
m.P/f.P text: none
decomp text: unknown
vapor pres: 4389 mmhg
vapor density: 4.2
spec gravity: 1.29
evaporation rate & reference: >1 (n-butyl acetate=1)
solubility in water: 0.028 %
appearance and odor: colorless liquefied compressed gas - faint ethereal odor
percent volatiles by volume: 100
corrosion rate: unknown

HAZCOM Label


product id: r-12; cfc-12; refrigerant 12; dichlorodiflu
cage: 0rau5
company name: laroche chemicals inc
street: airline hwy
po box: 1031
city: baton rouge la
zipcode: 70821
health emergency phone: 504-356-8467
label required ind: y
date of label review: 01/19/1993
status code: c
mfg label no: unknown
label date: 01/19/1993
origination code: f
eye protection ind: yes
skin protection ind: yes
signal word: danger
respiratory protection ind: yes
health hazard: severe
contact hazard: slight
fire hazard: none

Transportation

=======================================================
responsible party cage: 0rau5
trans id no: 63116
product id: r-12; cfc-12; refrigerant 12; dichlorodiflu
msds prepared date: 08/15/1991
review date: 03/06/1996
mfn: 1
tech entry nos shipping nm: dichlorodifluoromethane
net unit weight: 45 lbs
af mmac code: nr
multiple kit number: 0
review ind: y
unit of issue: cy
container qty: 0
type of container: cylinder

Reactivity

Hazard and precautions: store in well-ventilated, dry area (below 125f),
contact with flames or high temperatures should be avoided. May decompose to
form halogen acid and/or phosgene at temperatures above 600c. First aid: e
yes/skin: flush with water for at least15 minutes. If irritation persists,
see doctor. Inhalation: remove to fresh air. Give oxygen/cpr if needed. Call
a physician. Ingestion: compound not normally co nsidered hazardous.Get
medical attention as necessary.

Proper Disposal


spill release procedures: stop discharge if possible. Keep people away. Should
a spill occur into the air, water or onto land, notification to the the
national response center, 800-424-8802 will be required if the spill exceed s
the reportable quantity value.

neutralizing agent: none
waste disposal methods: used or unused products should be tested to determine
hazard status and disposal requirements under local, state and federal
regulations.

handling and storage precautions: store in well-ventilated, dry area (below
125f), contact with flames or high temperatures should be avoided.

other precautions: none

MSDS BTHTL FREON 12(R) (0-2300 PPM) IN AIR

Hazards

Ld50 lc50 mixture: tlv = 1000 ppm
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation of very high concentration
may cause irregular heart beat, angina, death. No chronic effects
reported.

explanation of carcinogenicity: this product is not listed by iarc, ntp
or osha as a carcinogen, mutagen, teratogen or neurotoxin.

effects of overexposure: irregular heartbeat, angina, death.

medical cond aggravated by exposure: cardiovascular disease

First Aid

First aid: inhalation: provide fresh air or oxygen and consult a
physician.

Chemical Properties

Hcc: g3
boiling pt: b.P. Text: not given
melt/freeze pt: m.P/f.P text: not given
vapor pres: not given
vapor density: 1.0-1.01
spec gravity: not given
evaporation rate & reference: not given
solubility in water: slight
appearance and odor: gas

Reactivity

Stability indicator/materials to avoid: yes
sodium, potassium, barium, magnesium or aluminum powders, oil in high
pressure equipment
stability condition to avoid: none specified by manufacturer.

hazardous decomposition products: hydrogen fluoride, hydrogen chloride,
phosgene, carbonyl fluoride

Proper Disposal

Waste disposal methods: empty containers may be discarded as metal
refuse observing federal, state and local regulations. Do not
incinerate.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: dichlorodifluoromethane (sara iii)
cas: 75-71-8
rtecs #: pa8200000
fraction by wt: < 0.23%
other rec limits: none recommended
osha pel: 1000 ppm
acgih tlv: 1000 ppm; 9394
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ozone depleting chemical: 1

ingred name: air, refrigerated liquid; air compressed (un1002, dot); air
refrigerated liquid (cryogenic liquid) (un1003) (dot)
rtecs #: ax5271000
fraction by wt: balance
other rec limits: none recommended

MSDS BTJBX DICHLORODIFLUOROMETHANE

Hazards

Ld50 lc50 mixture: not given
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation may cause asphyxiation due
to dilution of available oxygen in the air. Skin or eye contact
with liquid may cause frostbite.

explanation of carcinogenicity: this product is not listed by iarc, ntp
or osha as a carcinogen, mutagen, teratogen or neurotoxin.

effects of overexposure: lightheadedness, giddiness, disorientation,
shortness of breath, possible cardiac arrhythmias. Frostbite to
contacted tissue.

medical cond aggravated by exposure: none specified by manufacturer.

First Aid

First aid: inhalation: remove to fresh air, call a physician. If not
breathing, give artificial respiration.If breathing is difficult,
give oxygen. Do not give epinephrine or similar drugs. Eye: flush
with water . Skin: flush with water. If irritationpresists, get
medical attention.

Chemical Properties

Hcc: g3
boiling pt: b.P. Text: -22f,-30c
melt/freeze pt: m.P/f.P text: not given
vapor pres: 94.5 psia
vapor density: 4.26
spec gravity: 1.315
evaporation rate & reference:
solubility in water: negligible
appearance and odor: colorless, clear liquefied gas with slight etheral
odor
percent volatiles by volume: 100.0

Reactivity

Stability indicator/materials to avoid: yes
alkali or alkaline earth metals, powdered al, zn, be, etc.

stability condition to avoid: stable under normal conditions
hazardous decomposition products: hydrochloric acid, hydrofluoric acids,
toxic fumes of phosgene and fluorides. Also, halogens and carbonyl
halides.

Proper Disposal

Waste disposal methods: return cylinders to supplier for proper disposal
with any valve outlet plugs or caps secured and valve protection
cap in place.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: dichlorodifluoromethane (sara iii)
cas: 75-71-8
rtecs #: pa8200000
fraction by wt: 100% %
other rec limits: none recommended
osha pel: 1000 ppm
acgih tlv: 1000 ppm; 9394
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ozone depleting chemical: 1

MSDS CKMMC GENETRON 12

Hazards

Reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: skin: irritation, defatting. Liquid
may cause frostbite. eyes: liquid can cause severe frostbite. Mist
may irritate. ingestion: is an unlikely route of exposure because
of its low boiling point. Sho uld it occur, discomfort in the gi
tract would result from the rapid evaporation of the liquid.

necrosis from freezing of tissue could occur. inhalation: genetron
12 is low in toxicity in animals eve n at a concentration of 5%
(50,000 ppm); however, when oxygen level is reduced to 12-14%,
symptoms of asphyxiation, loss of coordination, increased pulse
rate and deeper respiration will occur. At hig h levels, cardiac
arrhythmia may occur.

explanation of carcinogenicity: not listed by ntp, iarc, osha.

effects of overexposure: inhalation: symptoms of asphyxation, loss of
coordination, increased pulse rate and deeper respiration, cardiac
arrhythmia. Ingestion: gastrointestinal tract dicomfort, necrosis.

skin: irritation, def atting, frostbite. Eyes: frostbite,
irritation.

medical cond aggravated by exposure: none provided by mfr.

First Aid

First aid: skin: flush with plenty of water. For frostbite, bathe (do
not rub) with lukewarm (not hot) water. If no water, cover with
clean, soft wool or similar covering. Call a physician. Eyes: flush
with luke warm water for at least 15 minutes. Lifting eyelids
occasionally. Get medical attention if symptoms persist. Ingestion:
unlikely route of exposure. Do not induce vomiting unless
instructed by physicia n. Inhalation: move to fresh air. If not
breathing, give artificial respiration. Use oxygen as required if a
qualified operator is available. Call a physician. Do not give
epinephrine (adrenaline).

Chemical Properties

Hcc: g3
boiling pt: =-29.6c, -21.6f
b.P. Text: @ 760 mm hg
melt/freeze pt: =-158.C, -252.4f
decomp temp: decomp text: none provided by mfr.

vapor pres: 84.9 psia 70 deg f
vapor density: 4.2(air=1)
spec gravity: 1.34 @ 86 deg f (water=1)
ph: neutral
viscosity: none provided by mfr.

evaporation rate & reference: >1 compared to cci(4)
appearance and odor: clear colorless liquid and vapor, faint ethereal
odor.

percent volatiles by volume: 100 @ 68 f
corrosion rate: none provided by mfr

Reactivity

Stability indicator/materials to avoid: yes
freshly abraded aluminum surfaces (may cause strong exothermic
reaction). Chemically active metals; sodium, potassium, powdered
aluminum, magnesium and zinc.

stability condition to avoid: ignition sources, such as lighted
cigarettes, flames, hot spots welding. May yield toxic and/or
corrosive decomposition products. Avoid mixing with air or oxygen
above atmos. Press.

hazardous decomposition products: halogens, halogen acids, and possibly
carbonyl halides. These are toxic and corrosive.

conditions to avoid polymerization: will not occur.

Proper Disposal

Waste disposal methods: waste disposal must comply with federal, state,
and local disposal or discharge laws. Disposal of waste genetron 12
(dichlorodifluoromethane) is subject to federal regulations. Users
should review the ir operations, then consult with appropriate
regulatory agencies before discharging or disposing of waste
material.

Ingredients List

Ingred name: dichlorodifluoromethane
cas: 75-71-8
rtecs #: pa8200000
= wt: 100.

osha pel: 4950 mg/m3;1000 ppm
acgih tlv: 4950 mg/m3;1000 ppm
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ozone depleting chemical: 1