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Y - Indicates information is in the hazardous materials information resource system (hmirs).
PMICA - Item does not contain precious metal.
CRITL- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.
085880 - Gases/mixture noi o/t poison
5 - Low sensitivity, category iv, aa&e, unclassified
634 - Cylinders, compressed gas, filled or empty
A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.
C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp
G - Nonflammable compressed gas, un class 2 (nonflammable gas label; except: (1) oxygen which requires an oxidizer label, and (2) fl
Q - 70.0
Questions & Answers: |
|
| What are the historical prices recorded for this stock number? | |
| Historical data shows pricing from $0.04 to $0.07.. | |
| Does NSN 6830-00-281-3036 have a shelf life? | |
| No. There is no shelf life applicable for this NSN. | |
| What NATO entities are users of this NSN? | |
| Department Of The Army, Department Of The Air Force, U.s. Marine Corps, Department Of The Navy, U.s. Coast Guard, General Services Administration, Brazil, Spain, Republic Of Korea, and Greece | |
| What is the NIIN of NSN 6830-00-281-3036? | |
| 002813036 or 00-281-3036 | |
| Does NSN 6830-00-281-3036 require demilitarization? | |
| Yes - ITAR Controlled | |
| What is the most recent solicitation for NSN 6830-00-281-3036? | |
| No solicitations for this NSN. | |
| When was this national stock number assigned to the federal catalog? | |
| Jan 01, 1961 | |
Ld50 lc50 mixture: ld50 (mouse): 1743mg/kg.
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhal: vap slightly irrit lung.Breath
conc approaching 10% in air cause dizz,diffi
breath,drowsiness,possibly narcosis.Ingest: upset,irrit gi
tract.Estimated to have moderate toxicity.Same symptoms as i
nhal.Skin: excessive contact may cause irrit(defat action),possible
frostbite(refrig effect of evaporation).Eye: liq(supp)
explanation of carcinogenicity: per msds: a ncl-sponsored bioassay on
carcinogenicity (rats) gave negative results.
effects of overexposure: slightly irrit lung. Dizziness, difficult
breath, drowsiness, narcosis. Upset, irrit gi tract. Skin irrit,
frostbite. Ye: irrit.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: inhal: immed remove to fresh air.Stop breath give
mouth-to-mouth resusc.Give oxy by qual person if available.Call
dr.Don't give adrenalin(epinephrine).Eye: rpomptly flush w/lg amts
of water.Lift eyelids .Irrit consult dr.Skin: promptly wash
w/soap/water then flush w/water til chem removed.Remove contamin
cloth.Ingest: unlikely expo route.Not expected to be haz.Do not
induce vomit unless instructed(sup)
Hcc: n1
boiling pt: b.P. Text: 74.8f,23.8c
melt/freeze pt: m.P/f.P text: -168f,-111c
decomp temp: decomp text: np
vapor pres: 13.4 psia
vapor density: 5.06 @30c
spec gravity: 1.49 @21.1c liq
ph: n/dete
viscosity: np
evaporation rate & reference: 0.4, ether=1
solubility in water: 0.11 @25c slight
appearance and odor: liquid, colorless, with faint ether-like odor.
percent volatiles by volume: 100
corrosion rate: np
Stability indicator/materials to avoid: yes
al/al powder,granular ba,lithium shavings,chem active
metals(na,k,ca,powdered mg,zn).
stability condition to avoid: flames, lighted cigarettes, hot spots,
welding (decomposes, liberating hazardous gases).
hazardous decomposition products: halogens, halogen acids, & possibly
carbonyl halides such as phosgene.
Waste disposal methods: rq: 5000.Prod used as solvnt subj to
fed/state/loc regs when dispo(epa spent halogenated
solvnt-f001,f002).Unused u121.Users should review operations in
terms of applicable fed/state/loc law/reg.Consul t approp reg
agencies bef dischar/dispo.Destroy o3
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: trichlorofluoromethane (cfc-11) (sara 313) (cercla)
cas: 75-69-4
rtecs #: pb6125000
fraction by wt: 100%
other rec limits: none recommended
osha pel: 1000 ppm
acgih tlv: c 1000 ppm; 9596
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ozone depleting chemical: 1
Effects of overexposure: contact with tissues may cause
frostbite.Breathing conc approaching 10% in air-dizziness,drowsy
First aid: flush frosted areas with warm water.If inhaled in high
concs,move to fresh air.
Hcc: n1
boiling pt: b.P. Text: 74.8f
vapor pres: 13
vapor density: 4.7
spec gravity: 1.49
evaporation rate & reference: 63,butyl acetate
solubility in water: 0.11 %
appearance and odor: water-white liquid;chlorinated solvent odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
none
stability condition to avoid: none
hazardous decomposition products: hcl,hf,co,and/or co*2 thru thermal
decompostion.
Waste disposal methods: landfill or mix in small proportion with
burnable liquid & incinerate under approved controlled procedures
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: trichlorofluoromethane (cfc-11) (sara iii)
cas: 75-69-4
rtecs #: pb6125000
fraction by wt: 100%
osha pel: 1000 ppm
acgih tlv: c, 1000 ppm; 9293
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ozone depleting chemical: 1
Effects of overexposure: inhalation: narcosis and anesthesia have been
reported.Also published animal studies report that this
First aid: remove to fresh air. If breathing has stopped,give artificial
respiration.Call a dr.Use oxygen as required.Do not give
epinephrine(adrenaline).Skin or eye: flush thoroughly with water.
Hcc: n1
boiling pt: b.P. Text: 74.9
vapor pres: 13.
vapor density: 5.06
spec gravity: 1.46
evaporation rate & reference: 0.4
solubility in water: negligible
appearance and odor: colorless, slight ethereal odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
hot: reactive metals.Decomposes in fires.
hazardous decomposition products: halogens,halogen acids,carbonyl
halides,including phosgene
Waste disposal methods: small spill or leak: (n.A.(will disperse
itself).For moderate quantities. With permission of
authorities,permit to evaporate in air at slow rate so as not to
exceed a safe level. See section v.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: trichlorofluoromethane (cfc-11) (sara iii)
cas: 75-69-4
rtecs #: pb6125000
fraction by wt: >99%
osha pel: 1000 ppm
acgih tlv: c, 1000 ppm; 9293
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ozone depleting chemical: 1
Ld50 lc50 mixture: pel (osha): 1000ppm, 5600mg/m3, 8 hr twa
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhal: vapor reduces oxygen available
for breathing. Is heavier than air. Overexposure may cause
temporary cns depression w/anesthetic effects. Ingest: nonspecific
discomfort. Eye: irrit. Skin: drying of skin, repeated contact
results in mild irrit.
explanation of carcinogenicity: trichlorofluoromethane (freon 11) is not
listed as a carcinogen by iarc, ntp or osha.
effects of overexposure: eye: discomfort, tearing, blurring of vision.
skin: discomfort, rash. Inhal: heart irregularities, unconsciousness,
death, dixxiness, headache, confusion, incoordination, temporary
alteration of heart's electrical activity w/irregular pulse,
palpitations, inadequate circulation. Ingest: nausea, headache,
weakness.
medical cond aggravated by exposure: individuals w/pre-existing diseases
of the central nervous or cardiovascular system may have increased
susceptibility to the toxicity of excessive exposures.
First aid: inhal: immed remove to fresh air. Keep person calm. If not
breath give artifi resp. If breath diffic give oxygen. Call doctor.
skin: flush w/lots of water for 15mins. Get med attn if irrit is
present. E ye: immed flush w/lots of water for 15mins. Call doctor.
ingest: no specific intervention is indicated as cmpd is not likely
to be haz by ingest. However consult doctor if necessary. See
supplemental.
Hcc: n1
boiling pt: b.P. Text: 75.0f,23.9c
decomp temp: decomp text: >1099f,>593
vapor pres: 14.7 psia
vapor density: 4.9 air=1
spec gravity: 1.48
ph: neutrl
evaporation rate & reference: >1, ccl4=1
solubility in water: 0.1%
appearance and odor: clear, colorless liquid with a slight ethereal
odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
alkali or alkaline earth meatls-powdered aluminum, berylium, zinc, etc.
stability condition to avoid: open flames, high temperatures, glowing
metal surfaces, other sources of ignition.
hazardous decomposition products: decomposes @ hi temp(open
flames,glowing metal surfaces,etc)forming hydrochloric &
hydrofluoric acids & carbonyl halides
Waste disposal methods: reclaim by distillation or remove to a permitted
waste disposal facility. Comply with local, state and federal
regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: trichlorofluoromethane (cfc-11) (sara iii)
cas: 75-69-4
rtecs #: pb6125000
fraction by wt: 100%
other rec limits: none specified
osha pel: 1000 ppm
acgih tlv: c, 1000 ppm; 9293
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ozone depleting chemical: 1
Ld50 lc50 mixture: ld 50 oral rat 45mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation: vapors heavier than air
and can cause suffocation by reducing oxygen available for
breathing. Breathing high concentrations of vapor cause heavyness
in the head,drowsiness, giddiness,short ness of breath,and may lead
to narcosis,cardiac irregularities,unconsciousness or death.
skin: may defat.Eyes: irritation.
explanation of carcinogenicity: freon 12 is not listed as a carcinogen
by iarc, ntp or osha.
effects of overexposure: inhalation: breathing high concentrations of
vapor may cause headedness,giddiness, shortness of breath, and may
lead to narcosis, cardiac irregularities, unconsciousness or death.
skin: irritant. Exces sive contact may defat skin. Eyes: vapor- mild
irritant; liq - irritant; ingestion: low toxicity.
medical cond aggravated by exposure: skin disease - freon 113 is a
defatting agent and can cause dermatitis on prolonged exposure.
persons with pre- existing skin disorders may be more susceptible
to the effects of this agent.
First aid: inhalation: remove to fresh air, call a physician. If not
breathing, give artificial respiration.If breathing is difficult,
give oxygen. Do not give epinephrine or similar drugs. Eye: flush
with water . Skin: flush with water. If irritationpersists, get
medical attention. Oral: get medical attention immediately. Induce
vomiting by giving two glasses of water. Call a physician.
Hcc: n1
boiling pt: b.P. Text: 29.0f,-1.7c
vapor pres: 0.6psia@21
vapor density: 0.39@77f
spec gravity: 1.48
solubility in water: negligible
appearance and odor: colorless liquid with slight ethereal odor
Stability indicator/materials to avoid: yes
strong oxidizing agents, finely divided barium,and lithium.Powdered
aluminum,magnesium and zinc.
stability condition to avoid: high heat, open flames and other sources
of ignition
hazardous decomposition products: decomposed by high temperatures to
form halogens, halogen acids, and carbonyl halides, including
phosgene.
Waste disposal methods: comply with federal, state and local
regulations. Remove to a permitted waste disposal facility.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: trichlorofluoromethane (cfc-11) (sara iii)
cas: 75-69-4
rtecs #: pb6125000
fraction by wt: 100%
other rec limits: none specified
osha pel: 1000 ppm
acgih tlv: c, 1000 ppm; 9293
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ozone depleting chemical: 1
Ld50 lc50 mixture: lc 50 ihl mouse 10 pph/30m
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation: may induce narcosis in
concentrations above 1000 ppm. May cause asphyxiation in high
concentrations. Skin and eyes: not readily absorbed through skin,
mucous membranes or tissue of eye. Ma y cause frostbite if exposed
to direct spray. Ingestion: not likely; low toxicity.
explanation of carcinogenicity: freon 11 is not listed as a carcinogen
by iarc, ntp or osha.
effects of overexposure: breathing high concentrations of vapor may
cause light-headedness, giddiness, shortness of breath, and may
lead to narcosis, cardiac irregularities, unconsciousness or death.
liquid is irritating to s kin and eyes, and may cause frostbite.
medical cond aggravated by exposure: persons with known history of heart
disease or irregularities of heartbeat should be particulary
careful to avoid overexposure to these vapors.
First aid: inalation: remove to fresh air, call a physician. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Do not give epinephrine or similar drugs. Eye: flush
with water for at least 15 minutes. Get medical attention. Skin:
wash with soap and water. If frostbite, warm skin slowly. Get
medical attention.
Hcc: g3
boiling pt: b.P. Text: 74.8f,23.8c
melt/freeze pt: m.P/f.P text: -168f,-111c
vapor pres: 699
vapor density: 4.7
spec gravity: 1.470
evaporation rate & reference: gas above 75f
solubility in water: negligible
appearance and odor: colorless to water-white, nearly odorless liquid or
gas.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
slight hydrolysis with water.
stability condition to avoid: open flames
hazardous decomposition products: decomposed by high temperatures (open
flames, glowing metal surfaces, etc.) forming hydrochloric and
hydrofluoric acids.
Waste disposal methods: best to recycle or reclaim, if possible. Consult
federal, state, or local authorities for proper disposal
procedures.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: trichlorofluoromethane (cfc-11) (sara iii)
cas: 75-69-4
rtecs #: pb6125000
fraction by wt: 100%
other rec limits: none specified
osha pel: 1000 ppm
acgih tlv: c, 1000 ppm; 9293
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ozone depleting chemical: 1
Routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation: vapor is heavier than air
and can cause suffocation by reducing oxygen available for
breathing. Breathing high concentrations of vapor may cause
light-headedness, giddiness, shortness of b reath, and may lead to
narcosis, cardiac irregularities, unconsciousness or death.
skin/eye: irritation and frostbite.
explanation of carcinogenicity: freon 11 is not listed as a carcinogen
by iarc, ntp or osha.
effects of overexposure: breathing high concentrations of vapor may
cause light-headedness, giddiness, shortness of breath, and may
lead to narcosis, cardiac irregularities, unconsciousness or death.
liquid is irritating to s kin and eyes, and may cause frostbite.
medical cond aggravated by exposure: persons with known history of heart
disease or irregularities of heartbeat should be particulary
careful to avoid overexposure to these vapors.
First aid: inalation: remove to fresh air, call a physician. If not
breathing, give artificial respiration. If breathing is difficult,
give oxygen. Do not give epinephrine or similar drugs. Eye: flush
with water for at least 15 minutes. Get medical attention. Skin:
wash with soap and water. If frostbite, warm skin slowly. Get
medical attention.
Hcc: n1
boiling pt: b.P. Text: 75.0f,23.9c
vapor pres: 0.6 psi
vapor density: 0.39
spec gravity: 1.48 @ 77f
solubility in water: insoluble
appearance and odor: colorless liquid, slight ehtereal odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
alkali or alkaline earth metals, powdered aluminum,zinc amd berylium.
stability condition to avoid: high temperatures, hot metal surfaces,
open flames.
hazardous decomposition products: decomposed by high temperatures (open
flames, glowing metal surfaces, etc.) forming hydrochloric and
hydrofluoric acids.
Waste disposal methods: best to recycle or reclaim, if possible. May be
incinerated in oil-fired furnace, but toxic and corrosive
combustion gases must be handled. Consult federal, state, or local
authorities for proper disp osal procedures. Listed as haz waste.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: trichlorofluoromethane (cfc-11) (sara iii)
cas: 75-69-4
rtecs #: pb6125000
fraction by wt: 100%
other rec limits: none specified
osha pel: 1000 ppm
acgih tlv: c, 1000 ppm; 9293
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ozone depleting chemical: 1
Ld50 lc50 mixture: orl: >3725mg/kg-rat;lc50 rat 26200ppm/4hr
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation: vapor is heavier than air
and can cause suffocation by reducing oxygen available for
breathing. Breathing high concentrations of vapor may cause
light-headedness, giddiness, shortness of b reath, & may lead to
narcosis, cardiac irregularities, unconsciousness or death. Skin:
not a corrosive or irritant;
effects of overexposure: however, repeated or prolonged liquid contact
can cause defatting of skin.
medical cond aggravated by exposure: skin disease: product can dissolve
the natural oil of the skin, therefore dermatitis may be expected
to result from repeated contact. Pre-existing skin disorders.
First aid: inhalation: remove to fresh air, call physician. If not
breathing, give cpr, preferably mouth-to-mouth. If breathing is
difficult, give oxygen. Do not give epinephrine or similar drugs.
eye: in case o f contact, immediately flush eyes w/plenty of water
for at least 15 minutes. Call a physician. Skin: cleanse after use.
Hcc: g3
boiling pt: b.P. Text: 75.0f,23.9c
vapor pres: .7psig@77f
vapor density: 4.9
ph: neutrl
evaporation rate & reference: 0.1 (cc14=1)
solubility in water: 0.1% by wt @ 77 f
appearance and odor: colorless liquid; slight etheral odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
alkali or alkaline earth metals - powdered al, zn, be, etc.
stability condition to avoid: avoid open flames and high temperatures.
hazardous decomposition products: high temps (open flames, glowing
surfaces, etc.) forming hydrochloric & hydrofluoric acids-possible
carbonyl halides.
Waste disposal methods: epa hazardous waste no. U121; f001; f002. Comply
with federal, state and local regulations. Reclaim by distillation
or remove to a permitted waste disposal facility.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: trichlorofluoromethane (cfc-11) (sara iii)
cas: 75-69-4
rtecs #: pb6125000
other rec limits: none specified
osha pel: 1000 ppm
acgih tlv: c, 1000 ppm; 9293
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ozone depleting chemical: 1
ld50 lc50 mixture: lc50 inhal mouse=10 pph/30m
route of entry inds - inhalation: yes
skin: yes
ingestion: yes
carcinogenicity inds - ntp: no
iarc: no
osha: no
effects of exposure: eyes: may cause frostbite.Skin: may cause frostbite.Liquid
is not injurous if promptly washed off.Inhal: above 100ppm, may cause
narcosis.High concentrations may cause asphyxiation.Ingest: no hazard expec
ted.
explanation of carcinogenicity: there are no ingredients above 0.1% which are
identified as carcinogens by ntp,iarc or osha.
signs and symptions of overexposure: breathing high concentrations of vapor may
cause light-headedness, giddiness, shortness of breath, and may lead to
narcosis, cardiac irregularities, unconsciousness or death. Liquid is
irritating to s kin and eyes, and may cause frostbite.
medical cond aggravated by exposure: persons with cardiac arrythmias may be at
increased risk from exposure.
first aid: eyes: flush with water for 15 minutes.Call physician if irritation
persists.Skin: flush with water.Call physician if reddening
develops.Inhal: remove from exposure.Give oxygen or artificial respiration i f
needed and get medical attention.Ingest: get prompt qualified medical
attention.
hcc: g3
b.P. Text: 74.8f,23.8c
m.P/f.P text: -168f,-111c
vapor pres: 694
vapor density: 5.1
spec gravity: 1.46
evaporation rate & reference: 0.4 et2o=1
solubility in water: negligible .011%
appearance and odor: colorless to water-white, nearly odorless liquid or gas.
percent volatiles by volume: 100
product id: r-11;cfc-11;refrigerant 11
cage: larch
company name: laroche chemicals inc
street: unknown
po box: 5500
city: gramercy la
zipcode: 70052
health emergency phone: 504-356-8565 800-424-9300(chemtrec)
label required ind: y
date of label review: 05/07/1998
status code: c
mfg label no: unknown
label date: 05/07/1998
origination code: f
eye protection ind: yes
skin protection ind: yes
signal word: caution
health hazard: slight
contact hazard: slight
fire hazard: none
=======================================================
responsible party cage: larch
trans id no: 65787
product id: r-11;cfc-11;refrigerant 11
msds prepared date: 08/15/1991
review date: 05/07/1998
mfn: 1
tech entry nos shipping nm: trichlorofluoromethane,>99.9%
net unit weight: 200 lbs
af mmac code: nr
multiple kit number: 0
review ind: y
unit of issue: dr
container qty: 1
additional data: thickness of drum material is as
follows: top=1.5mm/body=0.9mm/bottom=1.5mm.Rq for this item is 5000 lbs.
Hazard and precautions: eyes: may cause frostbite.Skin: may cause
frostbite.Liquid is not injurous if promptly washed off.Inhal: above 100ppm,
may cause narcosis.High concentrations may cause asphyxiation.Ingest: no
hazard expec ted. Store in well-ventilated, dry areabelow 125f. Protect
containers from physical damage and keep tightly closed. Avoid contact with
flames or high heat first aid: eyes: flush with water for 15 minut es.Call
physician if irritation persists.Skin: flush with water.Call physician if
reddening develops.Inhal: remove from exposure.Give oxygen or artificial
respiration if needed and get medical attention .Ingest: get prompt qualified
medical attention.
spill release procedures: stop discharge.Evacuate personnel.Avoid contact with
the liquid.Isolate and remove the discharged material.Spills must be reported
to the national response center,800-424-8802.For transportation emerg encies
call 800-424-9300(chemtrec).
neutralizing agent: none
waste disposal methods: this product is classified as hazardous waste
u121.Dispose of in accordance with federal,state and local regulations.Do not
vent into atmosphere or discharge to ground or water.Recycling/ reclamation
is preferred.
handling and storage precautions: store in well-ventilated, dry area below
125f. Protect containers from physical damage and keep tightly closed. Avoid
contact with flames or high heat
other precautions: high pressure cylinders should not be exposed to high
temperatures or pressures because of the increased risk of cylinder
explosion.
Ld50 lc50 mixture: 4 hr ld50 (rat) = 26,200 ppm
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhaling high concentrations of vapor
is harmful & may cause light headedness, shortness of breath, heart
irregularities, unconsciousness or death. Vapor is heavier than air
& may reduce oxygen availa ble for breathing. Intentional misuse
can be fatal. Chemical is a mild skin & eye irritant.
explanation of carcinogenicity: not listed as a carcinogen by iarc, ntp,
osha or acgih.
effects of overexposure: light headedness, shortness of breath, heart
irregularities, unconsciousness or death. Mild skin & eye
irritation.
medical cond aggravated by exposure: individuals with preexisting
diseases of the central nervous system or cardiovascular system may
have increased susceptibility to the toxicity of excessive
exposures.
First aid: if irritation occurs or is severe, see a doctor.
inhalation: remove to fresh air, keep calm. Aid or restore breathing
as needed. Skin: flush skin w/plenty of water. Eye: immediately flush
w/plenty of wat er. Swallowed: no specific intervention is indicated
as the compound is not likely to be hazardous by ingestion. Do not
induce vomiting. Call physician.
Hcc: n1
nrc/state lic num: none
boiling pt: b.P. Text: 75.0f,23.9c
decomp temp: decomp text: >1100f,>593
vapor pres: 14.7 psia
vapor density: 4.9
ph: neut.
evaporation rate & reference: >1 (ccl4=1)
solubility in water: 0.1%
appearance and odor: clear colorless liquid, slightly etheral odor.
percent volatiles by volume: 100
corrosion rate: unknownn
Stability indicator/materials to avoid: yes
mfr gave no information on msds.
stability condition to avoid: mfr gave no information on msds.
hazardous decomposition products: mfr gave no information on msds.
conditions to avoid polymerization: mfr gave no information on msds.
Waste disposal methods: comply w/federal, state and local regulations.
remove to a permitted waste disposal facility.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: trichlorofluoromethane (cfc-11) (sara 313) (cercla)
cas: 75-69-4
rtecs #: pb6125000
fraction by wt: 100%
other rec limits: none specified
osha pel: 1000 ppm
acgih tlv: c, 1000 ppm; 9495
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ozone depleting chemical: 1
Ld50 lc50 mixture: orl rat: >3725mg/kg;lc50 rat 26200ppm/4hr
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation: vapor is heavier than air
and can cause suffocation by reducing oxygen available for
breathing. Breathing high concentrations of vapor may cause
light-headedness, giddiness, shortness of b reath, & may lead to
narcosis, cardiac irregularities, unconsciousness or death. Skin:
irritation.
effects of overexposure: skin: irritation, defatting. Inhalation: light
headedness, shortness of breath, cardiac irregularities,
unconsciousness.
medical cond aggravated by exposure: pre-existing cns and cardiovascular
diseases.
First aid: inhalation: remove to fresh air, call physician. If not
breathing, give cpr, preferably mouth-to-mouth. If breathing is
difficult, give oxygen. Do not give epinephrine or similar drugs.
eye: in case o f contact, immediately flush eyes w/plenty of water
for at least 15 minutes. Call a physician. Skin: flush with plenty
of water. Ingestion: do not induce vomting. Call physician.
Hcc: n1
boiling pt: b.P. Text: 75.0f,23.9c
vapor pres: 14.7psi77f
vapor density: 4.9 @77f
ph: neutrl
evaporation rate & reference: >1 (cc14=1)
solubility in water: 0.1% by wt @ 77 f
appearance and odor: colorless liquid; slight etheral odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
alkali or alkaline earth metals - powdered al, zn, be, etc.
stability condition to avoid: avoid open flames and high temperatures.
hazardous decomposition products: high temps (open flames, glowing
surfaces, etc.) forming hydrochloric & hydrofluoric acids-possible
carbonyl halides.
Waste disposal methods: comply with federal, state and local
regulations. Send to mfr for reclaim or remove to a permitted waste
disposal facility.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: trichlorofluoromethane (cfc-11) (sara 313) (cercla)
cas: 75-69-4
rtecs #: pb6125000
fraction by wt: 100%
other rec limits: none recommended
osha pel: 1000 ppm
acgih tlv: c, 1000 ppm; 9495
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ozone depleting chemical: 1
Ld50 lc50 mixture: oral ld50(rats): >3725 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eyes: mildly irritating. Inhalation:
exposure to high concentrations may affect the nervous system &
produce rapid anesthetic effect. Prolonged exposure to an oxygen
deficient atomosphere may be fatal & may cause an increase in the
sensitivity of the heart to adrenaline which can result in reduced
heart function.
explanation of carcinogenicity: none
effects of overexposure: dryness, redness, irritation, headache,
dizziness, drowsiness, cyanosis, lack of muscle control, collapse,
irregular/rapid heartbeats.
First aid: ingestion: don't induce vomiting. Give water to drink. Never
give anything by mouth to an unconscious person. Skin: flush
w/lukewarm/use other means to warm slowly. Eyes: immediately flush
w/plenty of water for 15 mins. Inhalation: remove to fresh air.
give cpr/oxygen if needed. Obtain medical attention in all cases.
Boiling pt: b.P. Text: 74.8f
melt/freeze pt: m.P/f.P text: -168f
vapor pres: 13.3
vapor density: 4.74
spec gravity: 1.46
solubility in water: slight
appearance and odor: colorless liquid & gas w/faint ethereal odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong alkali/alkaline earth metals, powdered metals, aluminum,
magnesium, zinc, strong oxidizers.
stability condition to avoid: flames, hot metal surfaces, heating
elements, temps >800f.
hazardous decomposition products: thermal: hydrogen fluoride, hydrogen
chloride, co, co2, chlorine.
Waste disposal methods: recycle/reclaim iaw/federal, state & local
regulations. Reclaimed material may be incinerated but toxic &
corrosive combustion products must be handled appropriately.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: fluorotrichloromethane, freon 11, trichlorofluoromethane,
trichloromonofluoromethane
cas: 75-69-4
rtecs #: pb6125000
fraction by wt: 100%
other rec limits: 1000 ppm msha
osha pel: 1000 ppm
acgih tlv: c 5600 mg/cum
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ozone depleting chemical: 1