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Technical Trichloromonofluoromethane

NSN: 6830-01-040-3656 | Model: FREON 11
NSN Properties and Flags
NATO Stock Number
6830-01-040-3656
DEMIL
NO
Physical Form
Gas
Composition And Percentage
Any acceptable
Cylinder National Stock Number
Any acceptable
Supplied Cylinder
Supply item
Nondefinitive Specification/std Data
11 type

Pricing and Availability

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NSN 6830-01-040-3656 Datasheet

Supply Class (FSC):
Gases: Compressed And Liquefied
Cross Reference:
  • FREON 11
  • IROSO
  • BB-F-1421
  • BB-F-1421 TY11
  • KC5283P
Cage Codes:
  • Du Pont E I De Nemours and Co Inc (CAGE 18873)
  • Federal Specifications (CAGE 81348)
  • General Services Administration (CAGE 80244)
  • Kaiser Aluminum and Chemical Corp (CAGE 10383)
Identification:
HMIC

Y - Indicates information is in the hazardous materials information resource system (hmirs).

PMIC

A - Item does not contain precious metal.

CRITL

- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.

Questions & Answers:

What are the historical prices recorded for this stock number?
No pre-dated pricing for this NSN could be found.
Does NSN 6830-01-040-3656 have a shelf life?
No. There is no shelf life applicable for this NSN.
What NATO entities are users of this NSN?
Brazil, Spain, and Turkey
What is the NIIN of NSN 6830-01-040-3656?
010403656 or 01-040-3656
Does NSN 6830-01-040-3656 require demilitarization?
Yes - ITAR Controlled
What is the most recent solicitation for NSN 6830-01-040-3656?
No solicitations for this NSN.
When was this national stock number assigned to the federal catalog?
May 06, 1977
MSDS

Material Safety

MSDS BGHBS F-11,FREON 11,IROSO

Hazards

Ld50 lc50 mixture: tlv 1000 ppm (c)
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eyes, cns, lungs. Acute-
may cause eye irritation & blurring vision. Repeated skin contact
can dry skin casing rash. Overexposure by inhalation may cause cns
depression with anesthetic e ffects & irregular pulse. Ingestion
maycause headache, nausea, weakness. Chronic- unknown.

explanation of carcinogenicity: none
effects of overexposure: irritation, discomfort, rash, coldness, drying,
tearing, blurring of vision, coughing, irregular pulse, drowsiness,
confusion, headache, incoordination, loss of consciousness,
palpitation, inadequate circulation, nausea
medical cond aggravated by exposure: pre-existing diseases of the
central nervous system or cardiovascular system

First Aid

First aid: get medical attention if symptoms persist. Eye/skin: flush
with water for 15 minutes. Hold eyelids open. Inhaled: remove to
fresh air & provide oxygen/cpr if needed. Oral: no specific
intervention is ind icated as the compound is not likely tobe
hazardous by ingestion. However, consult a physician if necessary.

Chemical Properties

Hcc: t6
nrc/state lic num: not relevant
boiling pt: b.P. Text: 75.0f,23.9c
decomp temp: decomp text: >1100f,593c
vapor pres: 760 @ 77f
vapor density: 4.9
spec gravity: 1.48
evaporation rate & reference: >1 (ccl4=1)
solubility in water: 0.1% @ 77f (25c)
appearance and odor: clear, colorless liquid with faint ethereal odor
percent volatiles by volume: 100

Reactivity

Stability indicator/materials to avoid: yes
aluminum powder, zinc powder, alkali, alkaline earth metals
stability condition to avoid: open flames, excessive heat, arcs, glowing
metal surface
hazardous decomposition products: hydrochloric acid, hydrofluoric acid
and possibly carbonyl halides such as phosgene

Proper Disposal

Waste disposal methods: reclaim by distillation or remove to a permitted
waste disposal facility. Comply with local, state and federal
regulations. Do not vent to the atmosphere. Reportable quantity is
5000 pounds.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: trichlorofluoromethane (cfc-11) (sara 313) (cercla)
cas: 75-69-4
rtecs #: pb6125000
fraction by wt: 100%
other rec limits: none recommended
osha pel: 1000 ppm
acgih tlv: c, 1000 ppm; 9495
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ozone depleting chemical: 1

MSDS BKMYQ TRICHLOROFLUOROMETHANE, R11

Hazards

Ld50 lc50 mixture: ald: (oral rat)>3725 mg/kg
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhal: vap is hvr/air/can cause
suffocation by reducing o*2 avail for brthg. Brthg high conc of vap
may cause light-headedness/giddiness/shortness of brth/may lead to
narcos/card irregularities/uncon/d eath. Lc50 rats 26,200 ppm/4
hrs. Note: in screening test w/exptl animals, expos at approx 5000
ppm (see efts of overexp)
explanation of carcinogenicity: not relevant.

effects of overexposure: hlth haz: (v/v)/above/followed by a lge iv
epinephrine challenge/has induced serious card irregularities.

chlorocarbon/chlorofluorocarbon (cfc) matls have prdced sensit of
the myocardium to ephinephrin e in lab animals/could have a similar
eft in humans. Adrenomimetics (i.E., ephinephrine) may be
contra-(see ingred 6)
medical cond aggravated by exposure: skin disease:
trichlorofluoromethane can dissolve the natural oil of skin,
therefore dermat may be expected to result from rptd cont. Persons
w/pre-existing skin disorders may be more (see supp data)

First Aid

First aid: inhal: remove to fresh air/call md. If not brthg/give artf
resp/pref mouth to mouth. If brthg is dfclt/give o*2. Do not give
epinephrine/similar drugs. Note to md: because of poss incrd risk of
elicitin g card dysrythmias/catecholamine drugs/such as
epinephrine/should be considered only as a last resort in life
threatening emer. Eye: immed flush w/plenty of water for at least 15
mins. (see supp data)

Chemical Properties

Boiling pt: b.P. Text: 75.0f,23.9c
vapor pres: 7.0 (20c)
vapor density: 4.9
ph: neut
evaporation rate & reference: 0.1 (cc*4=1)
solubility in water: 0.1% by wt @ 77f
appearance and odor: clear; slight ethereal odor.

percent volatiles by volume: 100

Reactivity

Stability indicator/materials to avoid: yes
alkali or alkaline earth metals-powdered al, zn, be, etc.

stability condition to avoid: avoid open flames and high temperatures.

hazardous decomposition products: can be decomp by high temp (open
flames/glowing surf/etc) forming hydrochloric/hydrofluoric
acids-poss (see ingred 4)

Proper Disposal

Waste disposal methods: disposal must be in accordance with federal,
state and local regulations . Hazard substance under cercla.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: trichlorofluoromethane (cfc-11) (sara iii)
cas: 75-69-4
rtecs #: pb6125000
fraction by wt: 100%
other rec limits: see ingredient name
osha pel: 1000 ppm
acgih tlv: c, 1000 ppm; 9293
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ozone depleting chemical: 1

ingred name: see supp data: by ingest. Consult md if nec. Do not induce
vom as the haz of aspirating the matl into the lungs (ing 3)
rtecs #: 9999999zz

ingred name: see ing 2: is a greater haz than allowing it to progess
through the intestinal tract.

rtecs #: 9999999zz

ingred name: haz decomp prod: carbonyl halides; chlorides, fluorides, and
phosgene .

rtecs #: 9999999zz

ingred name: other prec: caution may displace oxygen in enclosed/confined
spaces. Gas/vapors may accumulate in low areas .

rtecs #: 9999999zz

ingred name: efts of overexp: indicated except for life-sustaining uses
in humans acutely/chronically expos to (see ing 7)
rtecs #: 9999999zz

ingred name: ing 6: chlorocarbons/cfcs . Skin: not a corr/irrit.

rptd/prlngd liq cont can cause defatting. Eye: test (see ing 8)
rtecs #: 9999999zz

ingred name: ing 7: in rabts rsltd in no observable dam. Ingest: although
oral tox is low/ingest of trichlorofluoromethane (see ing 9)
rtecs #: 9999999zz

ingred name: ing 8: is to be avoided.

rtecs #: 9999999zz

MSDS BPFHG RACON 11

Hazards

Ld50 lc50 mixture: none specified by manufacturer.

routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: inhal: cfc-11 is relatively
non-toxic following acute expos. Although no long-term
comprehensive studies have specifically investigated acute
overexpos of humans to cfc-11, exper indicates card iovascular/resp
sys are the primary sysaffected. The eft on resp sys is a reduction
in minute volume. (efts of overexp)
explanation of carcinogenicity: not relevant
effects of overexposure: hlth haz: humans exposed to lge area of spilled
cfc-11 exper varying narcotic efts incl in one case, uncon, &
another case, rapid heartbeat (tachycardia). Skin: test on skin of
mice indicated no rxns, but a retarding in the healing of wounds,
burns & regrowth of hair was noticed. There is poss of frostbt if
(ing 3)
medical cond aggravated by exposure: none specified by manufacturer.

First Aid

First aid: inhal: move to fresh air. Keep warm/at rest. If brthg is
dfclt (labored), give o*2. If not brthg, give artf resp/check for
pulse. If no pulse, start cpr. Do not give stimulants (adrenaline/
epinephrin e/hand-held asthma aerosols). Call 911 (if avail)/md.

keep patient at rest for 24hrs after overexp. No long-term efts
expected. Eyes &/or skin: vap cont - flush w/fresh h*2o for @ lst
20 min. (ing 18)

Chemical Properties

Boiling pt: b.P. Text: 75.0f,23.9c
vapor pres: supp data
vapor density: 0.39
spec gravity: 1.48 @ 77f
solubility in water: insoluble
appearance and odor: colorless liquid, very slight ethereal odor to
odorless.

percent volatiles by volume: 100

Reactivity

Stability indicator/materials to avoid: yes
incompat w/certain elastomers/alkali or alkaline earth metals/pwdrd
aluminum/zinc/beryllium/etc. The mfg (supp data)
stability condition to avoid: cfc-11 is stable & relatively non
reactive. Avoid contact w/open flames or extremely hot metal
surfaces.

hazardous decomposition products: product may decompose to form hf, hcl
and traces of carbonyl halides (i.E., phosgene).

Proper Disposal

Waste disposal methods: prod is designated by cercla as haz substance, &
has a reportable qty (rq) of 5,000 lbs. Shld substance be
spilled/relsd to environ in qty >/= 5,000 lbs, notify natl response
ctr. Epa haz waste# is u1 21. Disposal must be i/a/w fed/state/loc
regs.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: methane, trichlorofluoro-; (trichlorofluoromethane
(cfc-11)) (sara iii)
cas: 75-69-4
rtecs #: pb6125000
osha pel: 1000 ppm
acgih tlv: c, 1000 ppm; 9293
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ozone depleting chemical: 1

ingred name: supp data: when finely ground, metals such as
magnesium/aluminum in pwdrd form may also react, especially at high
temp.

rtecs #: 9999999zz

ingred name: efts of overexp: prod is stored/shpd in pressurized contr.

eyes: test of cfc-11 sol in rabbit's eyes showed mild (ing 4)
rtecs #: 9999999zz

ingred name: ing 3: irrit of muc memb which persisted for 48 hrs but did
not rslt in perm dmg. Ingest: liq may cause irrit (ing 5)
rtecs #: 9999999zz

ingred name: ing 4: to gastric/digest tracts if taken in lg qtys. Human
poisoning potntl: sniffing of fluorocarb propellants (ing 6)
rtecs #: 9999999zz

ingred name: ing 5: for their intoxicating efts has prdced over 100
deaths. Fluorocarb exhibit very toxic properties (asphy/ (ing 7)
rtecs #: 9999999zz

ingred name: ing 6: cardiac arrhythmias) when sniffed. However, because
of variations in individual response, it is very dfclt(ing 8)
rtecs #: 9999999zz

ingred name: ing 7: to predict which symps will be exhibited following
exposure. It is poss that individuals w/heart or resp (ing 9)
rtecs #: 9999999zz

ingred name: ing 8: disorders may prove especially susceptible. Two
cases of phosgene poisoning from disintegration of cfc-11(ing 10)
rtecs #: 9999999zz

ingred name: ing 9: propellant in an open flame in an enclosure have
been reported. Chronic efts: inhal: human volunteers (ing 11)
rtecs #: 9999999zz

ingred name: ing 10: exposed to 1000ppm exhibited minor coordination
symptoms which were considered not meaningful. (ing 12)
rtecs #: 9999999zz

ingred name: ing 11: skin: slight inflammatory rxn was observed when
test done in older rats. Cfc-11, at high conc, has been (ing 13)
rtecs #: 9999999zz

ingred name: ing 12: shown to be capable of sensitizing the heart to
injected epinephrine, rsltg in serious & sometimes fatal(ing 14)
rtecs #: 9999999zz

ingred name: ing 13: irregular heartbeats (cardiac arrhythmias).

chlorofluorocarbon (cfc) matls have prdced sensitization of (ing
15)
rtecs #: 9999999zz

ingred name: ing 14: the myocardium to epinephrine in lab animals & may
have similar effect in humans. Adrenomimetics (ing 16)
rtecs #: 9999999zz

ingred name: ing 15: (i.E., epinephrine) may be contra-indicated except
for life-sustaining uses in humans acutely or (ing 17)
rtecs #: 9999999zz

ingred name: ing 16: chronically exposed to chlorofluorocarbon (cfcs) .

rtecs #: 9999999zz

ingred name: first aid proc: liq cont - because of defat efts of this
prod, skin/eye irrit may occur. Flush exposed skin/eyes(ing 19)
rtecs #: 9999999zz

ingred name: ing 18: thoro (minimum of 15 min) w/lukewarm water or
balanced saline soln. If eye irrit persists, see md. (ing 20)
rtecs #: 9999999zz

ingred name: ing 19: cfc-11 will remove natural oils from contacted skin
& can irrit dry/sensitive skin. Ingest: in most cases,(ing 21)
rtecs #: 9999999zz

ingred name: ing 20: ingest is expected to be accidental & qtys ingested
very sml, therefore, stom emptying is not likely to (ing 22)
rtecs #: 9999999zz

ingred name: ing 21: be nec. However, if lg qtys are ingest, (i.E.,>1-2
ounces), gastric emptying might be recommended. Call md.

rtecs #: 9999999zz

ingred name: other prec: use in gen vicin of arc welding/open flames/hot
surf. Heat &/or uv radiation may cause formation of (ing 24)
rtecs #: 9999999zz

ingred name: ing 23: chlorides, fluorides or phosgene .

rtecs #: 9999999zz

MSDS CJDMH TRICHLOROFLUOROMETHANE

Hazards

Routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: chlorofluorocarbon (cfc) matls
have prdced sensit of myocardium to epinephrine in lab animals &
could have similar eft in humans. Adrenomimetics (e.G.,epinephrine)
may be contraindicated except for life-sustaining uses in humans
acutely/chronically exposed to cfc's . Inhal may cause asphy due to
dilution of avail oxyg in air. Symps include rapid resp, muscular
incoor, fatigue, naus, v omiting & uncon. Skin contact may cause
defatting of tissue. Vapors have littleeffect on eyes. Press drop
thru valves & piping may cause extreme cold & frostbite on contact.

chronic: eyes, lung & live r damage.

effects of overexposure: see health hazards.

medical cond aggravated by exposure: none known.

First Aid

First aid: inhalation: immediately remove victim to fresh air. If
breathing has stopped, give artificial respiration. If breathing is
difficult, give oxygen. eye contact: immediately flush with
copious amounts of water for at least 15 minutes. Skincontact:
if frostbite occurs, flush affected areas with lukewarm water.

ingestion: none. in event of exposure, consult a physician. Note
to physician: monito r arterial blood gases, eng, and vital signs.

dilantin improves artrio-ventricular conduction and may be useful
in the management of ventricular arrythmias.

Chemical Properties

Boiling pt: =23.7c, 74.8f
vapor pres: @ 25 deg c: 796 mm hg
vapor density: 5.0 air=1
spec gravity: gas (h20=1)
evaporation rate & reference: gas
solubility in water: insoluble.

appearance and odor: colorless gas with slight ethereal odor.

Reactivity

Stability indicator/materials to avoid: yes
alkali and alkaline earth materials. Mg and al may also be reactive.

stability condition to avoid: storage in poorly ventilated areas.

storage near a heat source.

hazardous decomposition products: chlorides and fluorides. carbonyl
halides. Phosgene.

Proper Disposal

Waste disposal methods: waste disposal method: dispose of
non-refillable cylinders in accordance with federal, state and
local regulations. Allow gas to vent slowly to atmosphere in an
unconfined area or exhaust hood. if t he cylinders are the
refillable type, return cylinders to supplier w/ any valve outlet
plugs/caps se cured & valve protection caps in place.

Ingredients List

Ingred name: trichlorofluoromethane; (other stel 1000 c ( mfr))
cas: 75-69-4
rtecs #: pb6125000
> wt: 99.

other rec limits: mac 1000 ppm (mfr)
osha pel: 5600 mg/m3;1000 ppm
acgih stel: c5620 mg/m3
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ozone depleting chemical: 1