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Carbon dioxide
Inorganic oxygen compounds of nonmetals, n.E.S.
Chemicals-inorganic
Y - Indicates information is in the hazardous materials information resource system (hmirs).
PMICA - Item does not contain precious metal.
CRITL- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.
040730 - Carbon dioxid (dry ice)
635 - Chemicals, other than drugs or sundries
9 - Other or no special handling required (sh)
A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.
C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp
Q - 70.0
V - Miscellaneous hazardous materials, un class 9 (no label)
Questions & Answers: |
|
| What are the historical prices recorded for this stock number? | |
| Historical data shows pricing from $4.62 to $7.70.. | |
| Does NSN 6830-01-165-6174 have a shelf life? | |
| No. There is no shelf life applicable for this NSN. | |
| What NATO entities are users of this NSN? | |
| Department Of The Air Force, Department Of The Navy, and National Institutes Of Health | |
| What is the NIIN of NSN 6830-01-165-6174? | |
| 011656174 or 01-165-6174 | |
| Does NSN 6830-01-165-6174 require demilitarization? | |
| Yes - ITAR Controlled | |
| What is the most recent solicitation for NSN 6830-01-165-6174? | |
| No solicitations for this NSN. | |
| When was this national stock number assigned to the federal catalog? | |
| Nov 01, 1983 | |
Ld50 lc50 mixture: none specified by manufacturer.
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: nervous system control of resp if
dependent on co*2 level brthd in air. By reducing o*2 level in air,
co*2 can cause suffocation. Symps of overexp include hdch, dizz,
shortness of breath, muscular wea kness, drowsiness, & ringing in
ears. High conc produce a faint acid taste & can cause paralysis of
(efts of overexp)
explanation of carcinogenicity: not relevant
effects of overexposure: hlth haz: brthg control centers of nervous
system: 2% by volume in atmosphere will cause a 50% increase in
brthg rate; 3%, a 100% rate increase; >4% produce labored brthg &
is dangerous for even a few min of exposure; >12% causes rapid
uncon; a few houts exposure at 25% results in death.
summary: inhal: low(see ingred 7)
medical cond aggravated by exposure: none specified by manufacturer.
First aid: prompt med attention is mandatory in all cases of overexp to
co*2. Rescue pers should be equipped w/niosh/msha apprvd scba.
inhal: conscious persons should be assisted to uncontam area &
inhale fresh a ir. Quick removal from contam area is most
important. Uncon pers should be removed to uncotam area, given
mouth to mouth resuscitation & supplemental o*2. Assure that vomit
matl does not (see ing 13)
Boiling pt: b.P. Text: see ingred
vapor pres: see ingred
solubility in water: see ingred
appearance and odor: white opaque solid; colorless, odorless gas.
Stability indicator/materials to avoid: yes
explosion can occur when co*2 contacts mixtures of sodium peroxide
w/aluminum or magnesium. Reactive metals (see ing 4)
stability condition to avoid: co*2 is stable under ordinary cndtns of
use/stor. Does not polymerize. Does cause violent polymerization of
(see ing 2)
hazardous decomposition products: co.
Waste disposal methods: allow gas to bleed off at moderate rate or solid
to sublime to a well vent area. The insulated stor cntnr should be
located in area where there is adequate vent so as to pvnt
accumulation of co*2 vaps above co*2 vaps above twa. Co*2 vaps
(see ing 20)
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: carbon dioxide
cas: 124-38-9
rtecs #: ff6400000
osha pel: 5000 ppm
acgih tlv: 5000ppm/30000stel;93
ingred name: cndtn to avoid: acrylaldehyde or ethyleneimine. It
decomposes to co & 0*2 when heated above 1700c. This weakly(see ing
3)
rtecs #: 9999999zz
ingred name: ing 2: acidic material will react w/alkaline matls to form
carbonates/bicarbonates.
rtecs #: 9999999zz
ingred name: ing 3: matls to avoid: (such as alkali metals, magnesium,
aluminum, titanium,/zirconium), their hydrides, & (see ing 5)
rtecs #: 9999999zz
ingred name: ing 4: like diethyl magnesium, moist cesium oxide/ithium
acetylide w/ammonia can ignite in co*2 atmosphere. (see ing 6)
rtecs #: 9999999zz
ingred name: ing 5: dry ice can form shock sensitive mixtures w/sodium,
potassium, or sodium-potassium alloy.
rtecs #: 9999999zz
ingred name: efts of overexp: conc (3-5 molar %) cause increased
resp/hdch. Eight to 15 molar % conc can cause hdch, naus,(see ing
8)
rtecs #: 9999999zz
ingred name: ing 7: vomit which may lead to uncon if not moved to open
air or give o*2. Higher conc cause rapid circulatory(see ing 9)
rtecs #: 9999999zz
ingred name: ing 8: insufficiency leading to coma/death. When
refrigerated liq co*2 is vaporized through orifice, it can (see ing
10)
rtecs #: 9999999zz
ingred name: ing 9: form solis particles of co*2 ("snow"/"dry ice"
powder). Continuous dermal contact w/this cold snow (see ing 11)
rtecs #: 9999999zz
ingred name: ing 10: result in frostbite or cyrogenic (freeze) "burns".
contact w/liquid or solid can produce frostbite (see ing 12)
rtecs #: 9999999zz
ingred name: ing 11: & freeze burns.
rtecs #: 9999999zz
ingred name: ing 12: first aid proc: obstruct the airway by use of
positional drainage. Med assistance should be sought (see ing 14)
rtecs #: 9999999zz
ingred name: ing 13: immed. Frostbite: flush affected areas w/lukewarn
water. Do not use hot water. Md should be seen (see ing 15)
rtecs #: 9999999zz
ingred name: ing 14: promptly if cyrogenic "burn" has resulted in
blistering of dermal surface or deep tissue freezing.
rtecs #: 9999999zz
ingred name: ing 15: spill proc: customers in kraft-paper-wrapped blocks
which weigh approx 50 lbs & are approx 1/2 cubic (see ing 17)
rtecs #: 9999999zz
ingred name: ing 16: foot in volume. It is also shipped in form of
indivudial pellets (extrusions). Prod should be stored (see ing 18)
rtecs #: 9999999zz
ingred name: ing 17: in insulated cntnrs which open from top having
loose-fitting lids so that co*2 vap from sublimination(see ing 19)
rtecs #: 9999999zz
ingred name: ing 18: of solid may be allowed to escape into atmosphere.
rtecs #: 9999999zz
ingred name: ing 19: waste disp method: are approx one & one half times
heavier than air. Do not put dry ice in clsd cntnr(see ing 21)
rtecs #: 9999999zz
ingred name: ing 20: where evolved gas cannot escape! Remove scrap solid
("snow/"dry ice") to a hood with forced vent (see ing 22)
rtecs #: 9999999zz
ingred name: ing 21: or to a remote outside area. Allow solid to sublime.
rtecs #: 9999999zz
other rec limits: none specified
Ld50 lc50 mixture: none specified by manufacturer.
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: co*2 does not support life & may prdce
immed haz atms. At conc in excess of 1.5% co*2 may prdce hypervent,
hdchs, visual disturbances, tremor, loss of consciousness & death.
symps of expos in the conc ranges of 1.5-5% may be highly
variable, but typical symps of co*2 intoxication include the (efts
of overexpos)
explanation of carcinogenicity: not relevant
effects of overexposure: hlth haz: following: 3-6% - hdchs, dyspnea,
perspiration; 6-10% - hdch, dyspnea, perspiration, tremors, visual
disturbance, uncon; over 10% - uncon. If conc of co*2 exceeds 10%,
uncon can occur w/out warning, preventing self-rescue. At much
higher conc, co*2 displaces o*2 in air < lvls nec to support life.
(supp data)
medical cond aggravated by exposure: none specified by manufacturer.
First aid: inhal: pers suffering from tox eft of co*2 shld be moved to
areas w/norm atm.Niosh/msha apprvd scba may be nec to pvnt tox
expos/asphy of rescue workers. Assisted respiration & supplemental
o*2 shld be given if not brthg. Eye/skin: frozen tiss shld be
flooded/soaked w/tepid water (105-115f;41-46c). Do not use hot
water. Cryogenic burns which rslt in blistering/deeper tiss
freezing (supp data)
Boiling pt: b.P. Text: -109f,-78c
melt/freeze pt: m.P/f.P text: supp data
vapor pres: supp data
vapor density: supp data
spec gravity: supp data
solubility in water: 87.8% @ 68f
appearance and odor: colorless & odorless as gas/liq.
Stability indicator/materials to avoid: yes
if moisture is present, materials must resist carbonic acid.
stability condition to avoid: none
hazardous decomposition products: none
Waste disposal methods: do not attempt to dispose of residual co*2 in
compressed gas cylinders. Return cylinders to air prods w/residual
press, the cylinder valve tightly closed, & the valve cap in place.
when disposing of b ulk qtys of co*2 from refrigerated (ing4)
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: carbon dioxide
cas: 124-38-9
rtecs #: ff6400000
osha pel: 5000 ppm
acgih tlv: 5000ppm/30000stel;93
ingred name: supp data: eyes: immediately flush w/potable water for a
minimdm of 15 minutes, seek assistance from md .
rtecs #: 9999999zz
ingred name: spill proc: will remain in low spots without assisted
ventilation.
rtecs #: 9999999zz
ingred name: waste disp meth: stor tanks,always dispose of co*2 outside,
in well ventd location away from work areas,where vaps(ing 5)
rtecs #: 9999999zz
ingred name: ing 4: can disperse.Vent to atm slowly since rapid
depressurization of cntnr will cause formation of solid co*2 (ing
6)
rtecs #: 9999999zz
ingred name: ing 5: (dry ice) internally, requiring longer periods to
vaporize. Disp must be i/a/w applic fed/state & loc regs .
rtecs #: 9999999zz
ingred name: hndlg/stor prec: accidental knocking over/dam from
passing/falling objects. Valve caps shld remain on cylinders (ing
8)
rtecs #: 9999999zz
ingred name: ing 7: not connected for use. Segregate full & empty
cylinders. Stor areas shld be free of combust matl. Avoid (ing 9)
rtecs #: 9999999zz
ingred name: ing 8: expos to areas where salt/other corr chems are
present. Store co*2 cylinders w/valve end up. See (ing 10)
rtecs #: 9999999zz
ingred name: ing 9: compressed gas association pamphlet p-1 for
additional storage recommendations.
rtecs #: 9999999zz
ingred name: other prec: use a press-reducing regulator when connecting
to lower press piping sys. Secure cylinders when in (ing 12)
rtecs #: 9999999zz
ingred name: ing 11: use. Never use direct flame to heat a compressed gas
cylinder. Use a check valve to pvnt backflow into (ing 13)
rtecs #: 9999999zz
ingred name: ing 12: stor cntnr.Avoid dragging, rolling/sliding
cylinders, even for short distance. Use suitable hand truck. (ing
14)
rtecs #: 9999999zz
ingred name: ing 13: see compressed gas assocn pamphlet p-1 for
additional stor recommendations. In applications where temps (ing
15)
rtecs #: 9999999zz
ingred name: ing 14:
& other matls which become brittle at low temps. (ing 16)
rtecs #: 9999999zz
ingred name: ing 15: compressed gas cylinders shld not be refilled except
by qualified producers of compressed gases. Shipment(ing 17)
rtecs #: 9999999zz
ingred name: ing 16: of compressed gas cylinder filled w/out permission
of owner is a violation of fed law.Atm in areas in (ing 18)
rtecs #: 9999999zz
ingred name: ing 17: which co*2 gas may be vented & collect shld be
tested w/portable or continuous monitoring co*2 gas analyzer.
rtecs #: 9999999zz
ingred name: vent: mech (gen): where low lying areas are not naturally
ventilated. Other: vents shld be situated to avoid (ing 16)
rtecs #: 9999999zz
ingred name: ing 15: higher than normal concentrations of carbon dioxide
in work areas.
rtecs #: 9999999zz
ingred name: prot gloves: impermeable material such as leather when
working with cold liquid, solid or vapor.
rtecs #: 9999999zz
Ld50 lc50 mixture: none specified by manufacturer.
routes of entry: inhalation: yes skin: no ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: a simple asphyxiant. High concs of
carbon dioxide in ambient air can reduce oxygen content nec to
support life. In solid phase (dry ice), cont w/body tiss will prdce
cold burns/frostbt w/in sev sec. A ccrd to cga phamplet#g-6, the
max exposlim of a hlthy male under exercising cndtns in air having
a 7% conc of (supdat)
explanation of carcinogenicity: not relevant
effects of overexposure: shortness of breath, headache, dizziness,
weakness, drowsiness and ringing in ears. Dry ice in contact with
body tissue produces a "burning" sensation; and frostbite occurs
within several seconds.
medical cond aggravated by exposure: any condition that would be
aggravated by a reduced quantity of normal quality breathing air.
First aid: inhal: do not attempt to remove an individual from scene of
an overexp w/o utilizing proper rescue equip or you may become a
casualty. Remove victim from carbon dioxide, provide plenty of
fresh air wh ile keeping such person warm/dry/quiet.If brthg has
stopped, perform artf resp. Get immed med attn. Ingest: call md
immed . Eyes: immed flush w/potable water for a minimum of 15 min,
(supdat)
Boiling pt: b.P. Text: -109f,-79c
vapor pres: 838 psig
vapor density: supdat
spec gravity: 1.5240 (air=1)
solubility in water: very soluble(supdat)
appearance and odor: in solid phase-translucent white/odorless. In
gas/liq phase-colorless/odorless.
Stability indicator/materials to avoid: yes
no data available.
hazardous decomposition products: heating above 1700c causes
decompositon to co and o*2.
Waste disposal methods: allow carbon dioxide to release, sublime or
dissipate in the open air. Avoid releasing in courtyards or indoors
or any areas where heavy carbon dioxide vapors can accumulate.
disposal must be i/a/w fe deral, state, and local regulations
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: carbon dioxide
cas: 124-38-9
rtecs #: ff6400000
fraction by wt: 1/0.5%
osha pel: 5000 ppm
acgih tlv: 5000ppm/30000stel;93
Ld50 lc50 mixture: none specified by manufacturer.
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: nervous sys control of resp is
dependent on co*2 level breathed in air. By reducing o*2 level in
air, co*2 can cause suffocation. Symp of overexp incl hdch, dizz,
shortness of breath, musc weak, drow & ringing in ears. Inhal: low
conc (3-5 molar %) cause incr resp & hdch. 8-15 molar % conc cause
hdch, (efts of overexp)
explanation of carcinogenicity: not relevant
effects of overexposure: hlth haz: naus & vomit which may lead to uncon
if not moved to open air/given o*2. High conc cause rapid
circulatory insufficiency leading to coma & death. When
refrigerated liq co*2 is vaporized thru an orifice, it can form
solid particlesof co*2 ("snow"/"dry ice" pwdr). Continuous dermal
cntct w/cold snow (ing 5)
medical cond aggravated by exposure: none specified by manufacturer.
First aid: ingest: call md immed. Eyes: immed flush w/potable water for
min of 15 min, seek assistance from md. Inhal: if conscious, assist
to uncontamd area & inhale fresh air. Quick removal from area is
most important. If uncon, move to uncontamd area, give
mouth-to-mouth resuscitation & supplemental o*2. Assure that
vomited matl does not obstruct airway by use of positional
drainage. (ing 9)
Boiling pt: b.P. Text: -109f,-79c
melt/freeze pt: m.P/f.P text: -70f,-57c
vapor pres: 844.7 psia
vapor density: 0.1144
solubility in water: coefficient = 0.8704
appearance and odor: white opaque solid; colorless, odorless gas.
Stability indicator/materials to avoid: yes
explo can occur when cntcts mix of sodium peroxide
w/aluminum/magnesium. Reactive metals (such as alkali metals (ing
2)
stability condition to avoid: decomposes to co & o*2 when heated above
1700c. Will react w/alkaline matls to form carbonates &
bicarbonates.
hazardous decomposition products: carbon monoxide. Forms carbonic acid
in the presence of water.
Waste disposal methods: disp must be i/a/w fed, state & local regs.
allow gas to bleed off at mod rate/solid to sublime to well vent
area. Insulated stor cntnr should be in area w/adeq vent to pvnt
accum of co*2 vaps a bove twa. Co*2 vap are approx 1 1/2 times (ing
13)
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: carbon dioxide
cas: 124-38-9
rtecs #: ff6400000
osha pel: 10000ppm; 30000 stel
acgih tlv: 5000 ppm; 30000 stel
ingred name: matls to avoid: magnesium, aluminum, titanium/zirconium),
their hydrides & matls like diethyl magnesium, moist (ing 3)
rtecs #: 9999999zz
ingred name: ing 2: cesium oxide/lithium acetylide w/ammonia can ignite
in co*2 atm. Dry ice can form shock sensitive mix with (ing 4)
rtecs #: 9999999zz
ingred name: ing 3: sodium, potassium or sodium-potassium alloy.
rtecs #: 9999999zz
ingred name: efts of overexp: could rslt in frostbt/cryogenic (freeze)
"burns." cntct w/liq/solid can prdce frostbt & freeze (ing 5)
rtecs #: 9999999zz
ingred name: ing 5: burns. Efts are change in color of skin to gray/white
poss followed by blistering. Co*2 is most powerful (ing 7)
rtecs #: 9999999zz
ingred name: ing 6: cerebral vasodialtor known. Inhal lg conc causes
rapid circulatory insufficiency leading to coma & death. (ing 8)
rtecs #: 9999999zz
ingred name: ing 7: chronic, harmful efts are not known from rptd inhal
of low (3-5 molar %) conc.
rtecs #: 9999999zz
ingred name: first aid proc: med assistance should be sought immed.
skin: frostbt: flush affected areas w/lukewarm water. Do (ing 10)
rtecs #: 9999999zz
ingred name: ing 9: not use hot water. Md should see promptly if
cryogenic "burn" has rsltd in blistering of dermal surf/deep (ing
11)
rtecs #: 9999999zz
ingred name: ing 10: tiss freezing. Prompt med attn mandatory in all
cases of overexp. Rescue pers should be equipped with (ing 12)
rtecs #: 9999999zz
ingred name: ing 11: niosh/msha self-contained breathing apparatus.
rtecs #: 9999999zz
ingred name: waste disp meth: hvr/air. Do not put dry ice in clsd cntnr
where evolved gas cannot escape! Remove scrap solid (ing 14)
rtecs #: 9999999zz
ingred name: ing 13: ("snow" or "dry ice") to hood w/forced vent or to a
remote outside area. Allow solid to sublime.
rtecs #: 9999999zz
ingred name: hndlg/stor prec: which open from top having loose-fitting
lids so co*2 vapor from sublimation of solid may be (ing 16)
rtecs #: 9999999zz
ingred name: ing 15: allowed to escape into atm. For addnl hndlg & stor
recom see cga pamphlets p-1 & g-6.
rtecs #: 9999999zz
ingred name: other prec: w/most plastics & elastomers. Also see cga
pamphlet g-6.3.
rtecs #: 9999999zz
ingred name: other prot equip: temp) to pvnt freeze burns & frostbt if
more than momentary cntct w/co*2 at low temp is poss.
rtecs #: 9999999zz
Ld50 lc50 mixture: none specified by manufacturer.
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhal: low concs (3-5% by vol) cause
incr resp & hdch. Concs of 8-15% cause hdch, naus & vomit which may
lead to uncon if not moved to open air/given oxygen. Higher concs
cause rapid circulatory insuff iciency leading to coma & death.
when refrigerated liq carbon dioxide is vaporized thru orifice, it
can(efts of overexp)
explanation of carcinogenicity: not relevant
effects of overexposure: hlth haz: form solid particles of carbon dioxide
("snow"/"dry ice" pwdr). Continuous dermal cont w/this cold snow
could rslt in frostbite/cryogenic (freeze) "burns". Cont
w/liq/solid can prdce frostbit e & freeze burns. Note: except where
specified, hlth haz data & most of other data in this msds are for
gaseous (supdat)
medical cond aggravated by exposure: none specified by manufacturer.
First aid: prompt med attn is mandatory in all cases of overexp to
carbon dioxide. Rescue pers should be equipped w/niosh/msha apprvd
scba. Ingest: call md immed . Inhal: conscious pers should be
assisted to uncontam area & inhale fresh air. Quick removal from
contam area is most important. Uncon pers should be moved to
uncontam area, given mouth-to-mouth resuscitation & supp oxygen.
further (ing 3)
Boiling pt: b.P. Text: -109f,-79c
melt/freeze pt: m.P/f.P text: -70f,-57c
vapor pres: 856 psia
spec gravity: 1.65 (air=1)
solubility in water: very soluble
appearance and odor: colorless, odorless gas; white solid.
Stability indicator/materials to avoid: yes
none.
stability condition to avoid: none.
hazardous decomposition products: none.
Waste disposal methods: disp must be i/a/w fed, state & loc regs . Allow
solid to sublime to well ventilated area. Insulated stor cntnr
should be located in area where there is adeq vent so as to pvnt
accum of carbon d ioxide vaps above tlv. Carbon dioxide vaps(ing
10)
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: carbon dioxide; (solid carbon dioxide, dry ice)
cas: 124-38-9
rtecs #: ff6400000
osha pel: 5000 ppm
acgih tlv: 5000 ppm;30000 stel
ingred name: supp data: possibly followed by blistering.
rtecs #: 9999999zz
ingred name: first aid proc: treatment should be symptomatic &
supportive. Treat areas expos to liq as for frostbite.
eye: immed(ing 4)
rtecs #: 9999999zz
ingred name: ing 3: flush w/tepid water in lg qtys, for at lst 15 mins,
or w/sterile saline soln. Seek med attn. Skin: flush (ing 5)
rtecs #: 9999999zz
ingred name: ing 4: affected area w/lukewarm water. Do not use hot water.
md should see patient promptly if cryogenic "burn" (ing 6)
rtecs #: 9999999zz
ingred name: ing 5: has resulted in blistering of dermal surface or deep
tissue freezing.
rtecs #: 9999999zz
ingred name: spill proc: approx 50 lbs & are approx one half cubic foot
in vol. Prod should be stored in insulated cntnrs which(ing 8)
rtecs #: 9999999zz
ingred name: ing 7: open from top having loose-fitting lids so that
carbon dioxide vap from sublimation of solid may be allowed(ing 9)
rtecs #: 9999999zz
ingred name: ing 8: to escape into the atmosphere.
rtecs #: 9999999zz
ingred name: waste disp meth: are approx one & one half times hvr/air. Do
not put dry ice in clsd cntnr where evolved gas (ing 11)
rtecs #: 9999999zz
ingred name: ing 10: cannot escape! Remove scrap solid ("snow"/"dry ice")
to hood w/forced vent/to remote outside area. Allow (ing 12)
rtecs #: 9999999zz
ingred name: ing 11: solid to sublime.
rtecs #: 9999999zz
ingred name: other prec: compressed gas assoc pamphlets g-6. Also see
pamphet g-6.3 carbon dioxide cyl filling & hndlg proc.
rtecs #: 9999999zz
ingred name: eye prot: & full length faceshield .
rtecs #: 9999999zz
ingred name: other prot equip: (apron) which are resist to low temps to
pvnt freezeburns & frostbite, if more than momentary (ing 16)
rtecs #: 9999999zz
ingred name: ing 15: contact w/co*2 at low temperature is possible.
rtecs #: 9999999zz
Ld50 lc50 mixture: none specified by manufacturer.
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: this matl is relatively inert. It can
cause asphy by displacing oxygen. Symps of expos depend on degree &
duration of oxygen deficiency. Symps of overexp incl hdch, dizz,
shortness of breath, muscular weak, drow & ringing in ears. High
concs prdce faint "acidic" taste & can cause paral of resp control
(efts of overexp)
explanation of carcinogenicity: not relevant
effects of overexposure: hlth haz: center of nerv sys: 2% (20,000 ppm) by
vol in atm will cause 50% incr in rate of brthg; 3%, 100% rat incr;
>4% prdces labored brthg & is dangerous for even few mins of expos;
>12% causes rapi d uncon. Cont w/liq or solid co*2 can prdce
frostbite & freeze burns. Because co*2 is asphy, primary entry is
by (ing 8)
medical cond aggravated by exposure: none specified by manufacturer.
First aid: ingest: call md immed . Eyes: immed flush w/potable water for
min of 15 min, seek assistance from md . Skin: promptly flush areas
affected w/lots of tepid water to reduce freezing of tiss. (d o not
apply direct heat to affected area!) loosely apply dry, sterile,
bulky dressings to prot area from infection & from further injury.
get med assistance - in plant, paramedic, community. (ing 9)
Boiling pt: b.P. Text: -109f,-78c
vapor pres: 1 @ 20c
vapor density: 1.5
solubility in water: 90 @ 20c ml/100 ml.
appearance and odor: colorless gas, clear, colorless, volat liq/white
solid; odorless. (at (supdat)
Stability indicator/materials to avoid: yes
co*2 can cause violent polymer of acryaldehyde/ethylenimine. This
weakly acidic matl will react w/alkaline (ing 4)
stability condition to avoid: none specified by manufacturer.
hazardous decomposition products: it decomposes to carbon monoxide (co)
& oxygen (o*2) when heated >3092f (1700c).
Waste disposal methods: disp must be i/a/w fed, state & loc regs .
remove scrap solid ("snow"/dry ice), take leaking cyl
outdoors/place it into hood w/good forced vent. Allow gas to be
discharged at mod rate. Defective cyls should be tagged to
indicate defect.(ing 14)
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: carbon dioxide
cas: 124-38-9
rtecs #: ff6400000
fraction by wt: >99.5%
osha pel: 5000 ppm
acgih tlv: 5000 ppm;30000 stel
ingred name: supdat: their own oxygen supply(i.E., cellulose nitrate); or
on fires involving reactive metals(such as potassium,(ing 3)
rtecs #: 9999999zz
ingred name: ing 2: sodium, magnesium, aluminum, titanium & zirconium);
or their hydrides, as these matls can decomp carbon dioxide.
rtecs #: 9999999zz
ingred name: matls to avoid: matls to form carbonates & bicarbonates.
explo can occur when co*2 conts sodium peroxide mixed w/ (ing 5)
rtecs #: 9999999zz
ingred name: ing 4: aluminum/magnesium. Reactive metals (such as alkali
metals, magnesium, aluminum, titanium/zirconium); their(ing 6)
rtecs #: 9999999zz
ingred name: ing 5: hydrids & matls like diethyl magnesium, moist cesium
oxide/lithium acetylide w/ammonia can ignite in co*2 (ing 7)
rtecs #: 9999999zz
ingred name: ing 6: atmosphere. Dry ice can form shock-sensitive mixtures
w/sodium, potassium or sodium-potassium alloy.
rtecs #: 9999999zz
ingred name: efts of overexp: inhalation. Acute effect is asphyxiation.
rtecs #: 9999999zz
ingred name: first aid proc: get med help for further treatment,
observation & support after first aid. Inhal: (caut! Would-be (ing
10)
rtecs #: 9999999zz
ingred name: ing 9: rescuers need to be concerned w/their own safety in
oxygen-deficient areas. Use niosh/msha apprvd self- (ing 11)
rtecs #: 9999999zz
ingred name: ing 10: contained brthg equip.) remove victim to fresh air.
quickly restore &/or support his brthg as reqd, admin(ing 12)
rtecs #: 9999999zz
ingred name: ing 11: oxygen if avail. Get med assistance - in plant,
paramedic, community. Get med help for further treatment,(ing 13)
rtecs #: 9999999zz
ingred name: ing 12: observation & support after first aid.
rtecs #: 9999999zz
ingred name: waste disp meth: close valve & return defective cylinder to
supplier.
rtecs #: 9999999zz
ingred name: other prec: holds, where fermentation processes may deplete
oxygen w/carbon dioxide.
rtecs #: 9999999zz
ingred name: vent: carbon dioxide is heavier than air & accumulates along
the floor & in depressions.
rtecs #: 9999999zz
ingred name: other prot equip: resp-prot pers enter haz carbon
dioxide-enriched area. (standby worker should have niosh/msha (ing
18)
rtecs #: 9999999zz
ingred name: ing 17: apprvd scba immed avail.) those working w/carbon
dioxide should wear other prot clthg, as reqd by cndtns (ing 19)
rtecs #: 9999999zz
ingred name: ing 18: of use, to prevent any skin contact w/carbon
dioxide. Safety shoes are rec for those hndlg cyls of gases.
rtecs #: 9999999zz
Ld50 lc50 mixture: none specified by manufacturer.
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: because nervous sys ctl of resp
depends on co*2 content of air, incr expos to co*2 rslts in incr
resp vol. By reducing o*2 level in air, co*2 can cause suffocation.
symps of overexp incl incr brthg ra te, hdch, dizz, shortness of
breath, musc weak, drow & ring in ears. Nose & throat irrit &
watery eyes (efts of overexp)
explanation of carcinogenicity: not relevant
effects of overexposure: hlth haz: may be caused by form of carbonic
acid, very weak acid. High concs cause faint acid taste & can cause
paralysis of brthg ctl ctrs of nervous sys. Reduction of o*2 concs
which usually accompa ny higher co*2 concs can reduce co*2 conc
reqd to prdce symps. Inhal: low concs (3-5 molar %) cause incr resp
& (ing 7)
medical cond aggravated by exposure: persons with respiratory diseases
or heart disorders should avoid breathing excessive carbon dioxide.
First aid: ingest: call md immed. Eyes: immed flush w/potable water for
minimum of 15 min, seek assistance from md. Inhal: conscious pers
should be assisted to uncontamd area & inhale fresh air. Quic k
removal from contamd area is most important. Uncon pers should be
moved to uncontamd area, given mouth-to-mouth or other (such as
mech) resuscitation & supplemental o*2. Assure vomited matl (ing
11)
Boiling pt: b.P. Text: -109f,-79c
vapor pres: 844.7 psia
appearance and odor: white opaque solid; colorless, odorless gas.
Stability indicator/materials to avoid: yes
explo can occur when co*2 cntcts mixs of sodium peroxide
w/aluminum/magnesium. Reactive metals (such as alkali (ing 4)
stability condition to avoid: co*2 causes violent polym of
acrylaldehyde/ethyleneimine. Decomp to co & o*2 when heated above
1700c. This (ing 3)
hazardous decomposition products: carbon monoxide when heated above
3092f (1700c).
Waste disposal methods: disp must be i/a/w fed, state & local regs.
allow solid to sublime (evap from solid/gas) in well vent &
isolated area. Insulated stor cntnr should be located in area where
there is adeq vent so as to pvnt accum of co*2 vaps above twa.
(ing 17)
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: carbon dioxide
cas: 124-38-9
rtecs #: ff6400000
osha pel: 5000 ppm
acgih tlv: 5000 ppm; 30000 stel
ingred name: explo haz: prdce highly incendiary sparks of 5-15 mj at
10-20 kv by electrostatic discharge.
rtecs #: 9999999zz
ingred name: cndtns to avoid: weakly acidic matl will react with
alkaline matls to form carbonates & bicarbonates.
rtecs #: 9999999zz
ingred name: matl to avoid: metals, magnesium, aluminum,
titanium/zirconium), their hydrides & matls like diethyl magnesium,
(ing 5)
rtecs #: 9999999zz
ingred name: ing 4: moist cesium oxide/lithium acetylide w/ammonia can
ignite in co*2 atm. Dry ice can form shock sensitive (ing 6)
rtecs #: 9999999zz
ingred name: ing 5: mixs w/sodium, potassium/sodium-potassium alloy &
w/acryaldehyde, aziredien, metal acetylides & sodium peroxide.
rtecs #: 9999999zz
ingred name: efts of overexp: hdch. Concs @ 8%/higher cause hdch, naus &
vomit; may lead to uncon if not moved to open air or (ing 8)
rtecs #: 9999999zz
ingred name: ing 7: given o*2 promptly. Concs @ 10%/higher cause rapid
circulatory insufficiecy leading to coma & death. Solid (ing 9)
rtecs #: 9999999zz
ingred name: ing 8: co*2 ("snow"/"dry ice" pwdr)is very cold. Continuous
dermal cntct could rslt in frostbt/cryogenic(freeze) (ing 10)
rtecs #: 9999999zz
ingred name: ing 9: "burns." frostbt efts are chg in color of skin to
gray/white poss followed by blisters.
rtecs #: 9999999zz
ingred name: first aid proc: does not obstruct airway by use of
positional drain. Med assistance should be sought immed. Skin: (ing
12)
rtecs #: 9999999zz
ingred name: ing 11: frostbt: immerse affected area in lukewarm, not hot,
water. Md should see promptly if cryogenic "burn" (ing 13)
rtecs #: 9999999zz
ingred name: ing 12: rslts in blister of dermal surf/deep tiss freezing.
prompt med attn mandatory in all cases of overexp to (ing 14)
rtecs #: 9999999zz
ingred name: ing 13: co*2. Rescue pers should be equipped with
niosh/msha apprvd self-contained breathing apparatus.
rtecs #: 9999999zz
ingred name: spill proc: weigh approx 50 lbs & approx 1/2 cubic ft vol.
also delivered as sm pellets in bulk form. Should be (ing 16)
rtecs #: 9999999zz
ingred name: ing 15: stored in insulated cntnrs which open from top
w/loose-fit lids so co*2 vap from sublimation of solid may escape.
rtecs #: 9999999zz
ingred name: waste disp meth: co*2 vaps are approx 1 & 1/2 times hvr/air.
do not put dry ice in clsd cntnr where evolved gas (ing 18)
rtecs #: 9999999zz
ingred name: ing 17: cannot escape! Remove scrap solid ("snow"/"dry ice")
to hood w/forced vent/to remote outside area. Allow (ing 19)
rtecs #: 9999999zz
ingred name: ing 18: solid to sublime.
rtecs #: 9999999zz
ingred name: hndlg/stor: stainless steels may be used & hastelloy a,b&c &
monel. Ferrous nickel alloys are slighlty corroded. (ing 21)
rtecs #: 9999999zz
ingred name: ing 20: at norm temps, co*2 is compat w/most plastics &
elastomers. Also see cga pamphlet g-6.3.
rtecs #: 9999999zz
ingred name: other prec: higher. Have standby pers w/rescue equip if work
reqd @ 9%/higher co*2 in air. Gloves & addnl prot (ing 23)
rtecs #: 9999999zz
ingred name: ing 22: clthg (apron, fshld, etc, resistant to low temps) to
pvnt freeze burns & frostbt if more than momentary (ing 24)
rtecs #: 9999999zz
ingred name: ing 23: cntct w/co*2 @ low temp poss. Pers w/hlth that would
be aggravated by expos to co*2 should not work/hndl prod.
rtecs #: 9999999zz
ingred name: eye prot: & full length faceshield .
rtecs #: 9999999zz
ld50 lc50 mixture: none specified by manufacturer.
route of entry inds - inhalation: yes
skin: yes
ingestion: no
carcinogenicity inds - ntp: no
iarc: no
osha: no
effects of exposure: acute: inhal: at 2-3% conc symps of simple asphxyia occur,
3-5% causes increased respiration & headache; up to 15% causes headache,
nausea, vomiting & unconsciousness. Higher concentrations cause rapid
circulatory insufficiency leading to coma & death. Co*2 is the most
powerful cerebral vasodilator (effects of overexp)
explanation of carcinogenicity: not relevant.
signs and symptions of overexposure: hlth haz: known. Skin: continuous dermal
cont w/solid co*2 could cause frostbite or cryogenic "burns". Persons in ill
health where such illness would be aggravated by exposure to solid carbon
dioxide sh ould not be allowed to work with or handle this product.
medical cond aggravated by exposure: persons in ill health where such illness
would be aggravated by expos to solid carbon dioxide should not be allowed to
work with or handle this product.
first aid: ingest: call md immediately (fp n). Eyes: immediately flush w/potable
water for minimum of 15 minutes, seek assistance from md (fp n).
inhal: conscious persons should be assisted to uncontamd area & inha le
fresh air. If uncon, provide assisted respiration & supplemental oxyg.
further treatment should be symptomatic & supportive. Niosh/msha apprvd
scba should be avail for rescue pers. (supdat)
vapor density: 1.65 @ 70f
solubility in water: vapor is soluble
appearance and odor: white, opaque solid emitting colorless gas with slight,
pungent odor.
percent volatiles by volume: 100
product id: carbon dioxide, solid
cage: 00qg4
company name: liquid carbonic industries corp
street: 810 jorie blvd
city: hinsdale il
zipcode: 60521-2216
health emergency phone: 800-424-9300 (chemtrec)
label required ind: y
date of label review: 06/23/1995
status code: c
label date: 06/23/1995
origination code: g
eye protection ind: yes
skin protection ind: yes
signal word: warning
respiratory protection ind: yes
health hazard: slight
contact hazard: moderate
fire hazard: none
=======================================================
responsible party cage: 00qg4
trans id no: 112466
product id: carbon dioxide, solid
msds prepared date: 04/01/1994
review date: 05/14/1996
mfn: 1
multiple kit number: 0
review ind: y
unit of issue: ea
container qty: 0
Hazard and precautions: acute: inhal: at 2-3% conc symps of simple asphxyia
occur, 3-5% causes increased respiration & headache; up to 15% causes
headache, nausea, vomiting & unconsciousness. Higher concentrations cause
rapid circulatory insufficiency leading to coma & death. Co*2 is the
most powerful cerebral vasodilator known. Skin: continuous dermal cont w/solid
co*2 could cause frostbite/cryogenic "burns". Chronic: none specified by
manufacturer.
spill release procedures: be certain there is adeq vent. Place outside in
protected area w/good vent & allow to sublime. Avoid prlngd contact with
skin.
neutralizing agent: none specified by manufacturer.
waste disposal methods: see spill release procedures. Disposal must be i/a/w
federal, state & local regulations (fp n).
handling and storage precautions: solid co*2 is generally delivered to
customers in draft-paper-wrapped blocks which weigh approx. 50 pounds one
half cubic foot in volume.
other precautions: prods should be stored in insulated cntnrs which open from
top having loose-fitting lids so that co*2 vap from sublimation of solid may
be allowed to escape into atm. Insulated stor cntnr should be lo cated in
area where there is (supdat)
Ld50 lc50 mixture: none specified by manufacturer.
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: no adverse efts from gas. Vapors
may cause dizziness or suffocation. Contact w/liquid may cause
frostbite. In vapor form: may cause frostbite, same as skin. Liquid
or solid may cause frostbite. C hronic: if environ contains
0.03-0.06% carbon dioxide gas & no adverse efts are expected from
prlng expos as this level.
explanation of carcinogenicity: not relevant
effects of overexposure: headache, increased breathing rate, difficult
breathing, perspiration, dizziness, ringing in ear, lips blue,
tremors & weakness, visual disturbance, drowsiness,
unconsciousness.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: ingest: call md immediately . Eyes: immediately flush w/potable
water for a minimum of 15 minutes, seek assistance from md .
skin: flush w/copious amounts of water. Call md . Inhal: remo ve from
exposure area to fresh air immediately. If breathing has stopped
give artf resp. Maintain airway & blood pressure. Get medical
attention immediately.
Boiling pt: b.P. Text: -109f,-78c
melt/freeze pt: m.P/f.P text: -94f,-70c
vapor pres: 569 @ -82c
vapor density: 1.5
spec gravity: 1.56 (h*2o=1)
evaporation rate & reference: high (butyl acetate=1)
solubility in water: 1.6%
appearance and odor: extremely cold, white snow-like flakes or cubes
which sublime at room temp.
Stability indicator/materials to avoid: yes
acrylaldehyde: exothermic rxn & violent polymerization.
aluminum(pwdr): ignites when heated; presence of aluminum (supdat)
stability condition to avoid: stable under normal temperatures &
pressures. Container may explode in heat of fire.
hazardous decomposition products: temperatures >1700c may cause
decomposition & release of oxygen & carbon monoxide.
Waste disposal methods: disposal must be i/a/w federal, state & local
regulations . Provide local exhaust ventilation &/or general
dilution ventilation to meet pels. Slowly release into atmosphere
outdoors.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: carbon dioxide; (dry ice)
cas: 124-38-9
rtecs #: ff6400000
osha pel: 5000 ppm
acgih tlv: 5000 ppm;30000 stel
ingred name: supdat: sodium peroxide: explo haz. Aziridine: violent
polymerization. Barium peroxide: incandescent rxn. Beryllium (ing 3)
rtecs #: 9999999zz
ingred name: ing 2: (pwdr) & nitrogen: ignit on heating. Cerium (pwdr) &
nitrogen: ignit on heating. Cesium oxide: ignit. Chromium(ing 4)
rtecs #: 9999999zz
ingred name: ing 3: (heated): ignit & explo. Diethyl magnesium &
air: ignit. Dimethyl ether & aluminum hydride: violent decomp. (ing
5)
rtecs #: 9999999zz
ingred name: ing 4: lithium: vigorous rxn. Lithium & oxyg: ignit. Lithium &
water: ignit. Lithium acetylene carbide diammino: (ing 6)
rtecs #: 9999999zz
ingred name: ing 5: ignit. Magnesium(dust): ignit & explo. Magnesium
aluminum alloys: ignit & explo. Magnesium & sodium peroxide: (ing 7)
rtecs #: 9999999zz
ingred name: ing 6: explo haz. Manganese(heated): ignit & explo.
monolithium acetylide: ignit. Potassium: explo haz when subjected(ing
8)
rtecs #: 9999999zz
ingred name: ing 7: to shock. Potassium acetylene carbide: incandescent
rxn. Potassium-sodium alloy: mixt w/solid carbon dioxide (ing 9)
rtecs #: 9999999zz
ingred name: ing 8: is explo. Rubidium acetylide: ignit on heating.
sodium: ignit. Sodium acetylide: incandescent rxn. Sodium (ing 10)
rtecs #: 9999999zz
ingred name: ing 9: carbide: incandescent rxn. Sodium peroxide: highly
exothermic rxn. Sodium peroxide & aluminum(pwdr) & water: (ing 11)
rtecs #: 9999999zz
ingred name: ing 10: ignit. Sodium peroxide & cotton wool: ignit. Sodium
peroxide & magnesium (pwdr) & water: ignit. Sodium (ing 12)
rtecs #: 9999999zz
ingred name: ing 11: peroxide & tin (pwdr) & water: ignit. Thorium (pwdr)
& nitrogen: ignit on heating. Titanium: burns >550c. (ing 13)
rtecs #: 9999999zz
ingred name: ing 12: uranium: finely divided metal ignites at 750c;
massive metal ignites at 800c. Uranium (pwdr) & nitrogen: (ing 14)
rtecs #: 9999999zz
ingred name: ing 13: ignit on heating. Zirconium & nitrogen: ignit on
heating. Zirconium: ignition & explosion.
rtecs #: 9999999zz
Ld50 lc50 mixture: tlv=5000ppm
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: co2 doesn't support life,produce immed
haz atm.Conc >1.5% hyperventil,head,visual disturb,tremor,loss of
consc,death.3-6% conc head,dyspnea,perspiration;6-10% conc
head,dyspnea,perspiration,tremors,vi sual disturb,unconsc.>10% conc
unconsc w/o warning preventing self-rescue.High conc displaces oxy
in air.
effects of overexposure: hyperventilate, headaches, visual disturbances,
tremoer, loss of consciousness, death, dyspnea, persipiration.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: persons suffering form toxi ceffect should be moved to areas
w/normal atm.Scba may be necesasry to prevent toxic
expo/asphyxiation of rescue worker.Assist resp/supplem oxy given if
not breath.Frozen t issues should be flooded/soaked
w/tepidwater(105-115f).Do not use hot water.Cryogenic burns result
in blister/depp tiss freezing should be seen by dr immed.
Hcc: d2
boiling pt: b.P. Text: -109f @1atm
melt/freeze pt: m.P/f.P text: -70f,-57c
decomp temp: decomp text: np
vapor pres: 831 @68f
vapor density: 0.115 @68f
spec gravity: 1.53 @68f,1atm
ph: np
viscosity: np
evaporation rate & reference: np
solubility in water: 87.8% @1atm, 68f.
appearance and odor: colorless,odorless gas/liqi,store under own vap
pressure.
percent volatiles by volume: np
corrosion rate: np
Stability indicator/materials to avoid: yes
if moisture is present matls must resist carbonic acid.
stability condition to avoid: none.
hazardous decomposition products: none.
Waste disposal methods: don't attemp dipso of residual gas in
cyl.Returen to air prod w/residual pressure/val tightly clsd/cap in
place.Dispo bulk quant from refrig storage tks always dispo outside
in well venti loc away fro m workarea.Vent to atm slowly.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: carbon dioxide
cas: 124-38-9
rtecs #: ff6400000
fraction by wt: 100%
other rec limits: none recommended
osha pel: 5000 ppm
acgih tlv: 5000ppm/30000stel;96
ld50 lc50 mixture: none specified by manufacturer.
route of entry inds - inhalation: yes
skin: yes
ingestion: no
carcinogenicity inds - ntp: no
iarc: no
osha: no
effects of exposure: acute: inhalation: low (3-5%) concentrations in inhaled air
cause increased respiration & headache. Higher concentrations cause
nausea, vomiting, eventual unconsciousness leading to coma & death.
skin: c ontinuous dermal cont w/solid co*2 could cause frostbite/cryogenic
"burns".
explanation of carcinogenicity: not relevant.
signs and symptions of overexposure: see health hazards.
medical cond aggravated by exposure: persons in ill health where such illness
would be aggravated by exposure to solid carbon dioxide should not be allowed
to work with or handle this product.
first aid: ingest: call md immediately (fp n). Eyes: immediately flush w/potable
water for minimum of 15 minutes, seek assistance from md (fp n). Inhal: remove
to fresh air. If uncon/brthg is dfclt admin artf resp w/supplemental oxygen.
keep warm & at rest. Skin: flush affected area with tepid (105-115f)
water. Seek medical help for thermal injury.
b.P. Text: supdat
vapor density: 1.6 @ 59f
solubility in water: vapor is soluble
appearance and odor: white, opaque solid emitting colorless, odorless gas.
percent volatiles by volume: 100
product id: carbon dioxide, solid
cage: 36517
company name: liquid carbonic corp
street: 135 s la salle street
city: chicago il
zipcode: 60603-4101
health emergency phone: 800-424-9300 (chemtrec)
label required ind: y
date of label review: 04/15/1997
status code: c
label date: 04/15/1997
origination code: g
eye protection ind: yes
skin protection ind: yes
signal word: caution
respiratory protection ind: yes
health hazard: slight
contact hazard: slight
fire hazard: none
Hazard and precautions: acute: inhalation: low (3-5%) concentrations in inhaled
air cause increased respiration & headache. Higher concentrations cause
nausea, vomiting, eventual unconsciousness leading to coma & death.
skin: c ontinuous dermal contact with solid co*2 could cause frostbite or
cryogenic "burns". Chronic: none listed by manufacturer.
spill release procedures: be certain there is adequate ventilation. Place
outside in a protected area with good ventilation and allow to sublime. Avoid
prolonged contact with skin.
neutralizing agent: none specified by manufacturer.
waste disposal methods: disposal must be i/a/w federal, state & local
regulations (fp n).
handling and storage precautions: co*2 is generally delivered to customers in
draft-paper-wrapped blocks which weigh approx 50 pounds & are approx 1/2
cubic foot in volume.
other precautions: prods should be stored in insulated cntnrs which open from
top having loose-fitting lids so that co*2 vap from sublimation of solid may
be allowed to escape into atm. Insulated stor cntnr should be lo cated in
area where there is (supdat)
Ld50 lc50 mixture: d
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhal: low concen(3-5 molar%)cause incr
resp,head.8-15 moral% cause head,nau,vomit which may lead to
unconsc if nto move to opn air/give oxy.Higher concen cause rapid
circulatory insufficiency leading to coma,death.Skin: cont derm
contact w/dry ice could result in frostbite or
cryogenic(freeze)"burns".
explanation of carcinogenicity: per msds: carcinogen: iarc/ntp: no.
effects of overexposure: nervous sys cntrl of resp is dependent on co2
level breathed in air.By reducing oxy level in air co2 can cause
suffocation.Headahce,dizz,shortness of breath,muscular
weakness,drows,ringing in ears.Hi conc produce faint acid
taste,paralysisof breath cntrl cntr of nerv sys.2%vol in atm cause
50%incr breath rate(supple)
medical cond aggravated by exposure: none specified by manufacturer.
First aid: prompt med attn mandatory in all cases of overexpo to
co2.Inhal: consc person should be assist to uncontam area.Inhal
fresh air.Quick rmoveal from contam area most important.Uncosnc
person shuld be mov e to uncontam area give mouth-to-mouth
resuscit,supplem oxy.Assure vomit matl doesnt obstruct airway by
use of positional drainage.Med assist should be sought
immed.Frostbite: flush area w/(supplmenta)
Hcc: v1
boiling pt: b.P. Text: np
melt/freeze pt: =-56.7c, -70.F
decomp temp: decomp text: np
vapor pres: 856 psia
vapor density: .1144lb/ft
spec gravity: 1.65
ph: np
viscosity: np
evaporation rate & reference: np
solubility in water: 0.874
appearance and odor: white opaque solid, colorless, odorless gas
percent volatiles by volume: np
corrosion rate: np
Stability indicator/materials to avoid: yes
this weakly acidic matl will rx w/alkaline matls-forms
carbonates/bicarbonates.Na2o2+zl/mg.Rx metals & hydrides(oth pre)
stability condition to avoid: none specified by manufacturer.
hazardous decomposition products: decomposes to co & o2 when heated
>1700c. Carbon monoxide.
Waste disposal methods: allow solid to subime in well venti area.Locate
insulate storage cntnr in area w/adequ venti-prevent co2 vap
accumul.Vap approx 1.5 times heaveir than air.Dont put dry ice in
clsd cntnr-gas cant escap e.Remove scrap solid to hood w/force
venti/outdrs.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: carbon dioxide
cas: 124-38-9
rtecs #: ff6400000
fraction by wt: 100%
other rec limits: none recommended
osha pel: 5000 ppm
acgih tlv: 5000ppm/30000stel;96
Ld50 lc50 mixture: none specified by manufacturer.
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: inhal: high concs can cause
oxygen-deficient environ. Pers brthg such atm may experience symps
which incl hdch, ringing in ears, dizz, shortness of breath, drow,
uncon, naus, vomit & depress of all senses. Death may occur. Efts
assoc w/various levels of oxygen are: 12-16% oxygen: brthg & pulse
(efts of overexp)
explanation of carcinogenicity: not relevant.
effects of overexposure: hlth haz: rate incrd, musc coord slightly
disturbed; 10-14% oxygen: emotional upset, abnorm fatg, disturbed
resp; 6-10% oxygen: naus & vomit, collapse/loss of consciousness;
carbon dioxide reaches 10% or more, suffocation can occur w/in min.
(ing 4)
medical cond aggravated by exposure: none specified by manufacturer.
First aid: rescuers should not attempt to retrieve victims w/out adeq
pers prot equip. At min, wear niosh apprvd scba & pers prot equip.
inhal: remove to fresh air, as quickly as poss. Trained pers should
admin supp oxygen &/or cpr, if nec. Only trained pers should admin
supp oxygen. Skin: place frostbitten skin in warm water. Do not use
hot water. If warm water is not avail/is impractical to use, (ing
11)
Boiling pt: b.P. Text: -109f,-79c
vapor pres: 844.7 psia
vapor density: 1.833kg/m3
spec gravity: sup dat
solubility in water: 0.90% @ 20c
appearance and odor: whitish, odorless, solid/colorless, odorless
gas/colorless odorless liquid
Stability indicator/materials to avoid: yes
powdered aluminum, beryllium, cerium alloys, chromium, manganese,
titanium, zirconium. Cont nehc for more info .
stability condition to avoid: avoid exposing cylinders of carbon dioxide
to extremely high temperatures, which could cause cylinders to
rupture/burst.
hazardous decomposition products: carbon dioxide gas in elec discharge
yields carbon monoxide & oxygen. In presence of moisture, it forms
carbonic acid.
conditions to avoid polymerization: carbon dioxide acts to catalyze the
polymerization of acryladehyde and aziridine.
Waste disposal methods: waste disposal must be in accordance with
appropriate federal, state, and local regulations. Return cylinders
with any residual product to air gas. Do not dispose of locally.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: carbon dioxide
cas: 124-38-9
rtecs #: ff6400000
fraction by wt: >99.8%
osha pel: 5000 ppm
acgih tlv: 5000 ppm/30000 stel
ingred name: impurities; (maximum impurities)
fraction by wt:
osha pel: n/k
acgih tlv: n/k
ingred name: sup dat: w/moisture, cesium oxide ignites on cont w/carbon
dioxide. Metal acetylides/hydrides will also ignite/explode.
rtecs #: 9999999zz
ingred name: efts of overexp: at concs 2-10%, carbon dioxide can cause
naus, dizz, hdch, mental confusion, incrd blood press (ing 5)
rtecs #: 9999999zz
ingred name: ing 4: & resp rate. Cont w/liq/rapidly expanding gases may
cause frostbt. Symps of frostbt change in skin color (ing 6)
rtecs #: 9999999zz
ingred name: ing 5: to white/grayish-yellow. Pain after cont can quickly
subside. Moisture in air could lead to form of (ing 7)
rtecs #: 9999999zz
ingred name: ing 6: carbonic acid, which can be irrit to eyes. Symps of
oxygen-deficiency are those which precede asphyxia, (ing 8)
rtecs #: 9999999zz
ingred name: ing 7: namely, resp dfclty, ringing in ears, hdch,
shortness of breath, wheezing, dizz, indigestion, naus, &, (ing 9)
rtecs #: 9999999zz
ingred name: ing 8: at high concs, uncon/death may occur. Skin may have
blue color. Cont may cause frostbt. Symps of frostbt (ing 10)
rtecs #: 9999999zz
ingred name: ing 9: incl change in skin color to white/grayish-yellow;
eye irrit, perm tiss dmg. Cont nehc for more info .
rtecs #: 9999999zz
ingred name: first aid proc: wrap affected parts gently in blankets.
alternatively, if fingers/hands are frostbitten, place (ing 12)
rtecs #: 9999999zz
ingred name: ing 11: affected area in armpit. Encourage victim to gently
exercise affected part while being warmed. Seek (ing 13)
rtecs #: 9999999zz
ingred name: ing 12: immed med attn. Victims must be taken to med attn.
rescuers should be taken to med attn, if nec. Take (ing 14)
rtecs #: 9999999zz
ingred name: ing 13: copy of label & msds to md/other hlth professional
w/vistims. Eyes: flush w/potable water for at least (ing 15)
rtecs #: 9999999zz
ingred name: ing 14: 15 minutes. See md . Ingestion: call md immediately
.
rtecs #: 9999999zz
ingred name: spill proc: atm must have at least 19.5% oxygen before pers
can be allowed in area w/out niosh apprvd scba. (ing 17)
rtecs #: 9999999zz
ingred name: ing 16: attempt to close main source valve prior to
entering area. If this does not stop release (or if it is (ing 18)
rtecs #: 9999999zz
ingred name: ing 17: not poss to reach valve), allow gas to release
in-place/remove it to safe area & allow gas to be (ing 19)
rtecs #: 9999999zz
ingred name: ing 18: released there. Contact nehc for more specific
information .
rtecs #: 9999999zz
ingred name: hygiene practices: exposures to fatal concentrations of
product could occur without any significant warning symptoms.
rtecs #: 9999999zz
ingred name: other prec: that carbon dioxide vap from sublimation of
solid may be allowed to escape into atm. Insulated stor (ing 22)
rtecs #: 9999999zz
ingred name: ing 21: contr should be located in area where there is adeq
vent as to pvnt accum of carbon dioxide vaps above (ing 23)
rtecs #: 9999999zz
ingred name: ing 22: twa. Protect cyls against physical dmg. Store in
cool, dry, well-ventilated, fireproof area, away from (ing 24)
rtecs #: 9999999zz
ingred name: ing 23: flam matls & corr atms. Store away from heat &
ignit sources & out of direct sunlight. Do not store near(ing 25)
rtecs #: 9999999zz
ingred name: ing 24: elevators, corridors/loading docks. Store cyls in
temps not exceeding 51c (125f). Cont nehc for more info.
rtecs #: 9999999zz