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4-dichlorophenoxyacetic Acid 2 Herbicide

NSN: 6840-00-577-4194 | Model: A-A-197
NSN Properties and Flags
NATO Stock Number
6840-00-577-4194
DEMIL
NO
Physical Form
Liquid
Special Features
Two 2-1/2 gl co/box' type iii, class 2

Pricing and Availability

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NSN 6840-00-577-4194 Datasheet

Supply Class (FSC):
Pest Control Agents And Disinfectants
Cross Reference:
  • A-A-197
Cage Codes:
  • Federal Commercial Item Description (CAGE 58536)
Replacements:
  • 6840-00-577-4194 replaces 6840-00-577-4195
Schedule B & Trade:
  • Schedule B: 3808930000 (NAICS 325320)

    Herbicides, antisprouting products and plant-growth regulators

  • SITC: 59130

    Herbicides (weed killers), antisprouting products and plant-growth regulators, put up or packed for retail sale or as preparations or articles

  • End Use: 12510

    Chemicals-fertilizers

Identification:
HMIC

Y - Indicates information is in the hazardous materials information resource system (hmirs).

PMIC

A - Item does not contain precious metal.

CRITL

- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.

NSN Management Codes:
  • SOS
    Sms
  • AAC
    H
  • Quantity per pack
    1
  • Unit of Measure
    Bx
  • Shelf Life
    N/A
  • Classification Control
    U
  • MGMT_CTL
    R2200x-
  • Repariability
    This is a nonreparable item. if condemned or economically unserviceable, then dispose at the level authorized replace the item.

Questions & Answers:

What are the historical prices recorded for this stock number?
Historical data shows pricing from $824.66 to $1,374.44..
Does NSN 6840-00-577-4194 have a shelf life?
No. There is no shelf life applicable for this NSN.
What NATO entities are users of this NSN?
Department Of The Army, U.s. Marine Corps, and Department Of The Navy
What is the NIIN of NSN 6840-00-577-4194?
005774194 or 00-577-4194
Does NSN 6840-00-577-4194 require demilitarization?
Yes - ITAR Controlled
What is the most recent solicitation for NSN 6840-00-577-4194?
No solicitations for this NSN.
When was this national stock number assigned to the federal catalog?
Feb 24, 1997
MSDS

Material Safety

MSDS BLRDX 2,4-D LOW VOLATILE ESTER

Hazards

Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: skin: irritation. Ingestion: harmful,
& toxic. Inhalation: moderate weakness, lethargy, & anorexia.

explanation of carcinogenicity: none
effects of overexposure: skin: irritation. Ingestion: toxic, & harmful.

inhalation: moderate weakness, lethargy, & anorexia.

First Aid

First aid: eyes/skin: flush w/water. Ingestion: don't induce vomiting.

obtain medical attention in all cases.

Chemical Properties

Boiling pt: b.P. Text: 350f
melt/freeze pt: m.P/f.P text: liquid
spec gravity: 1.032
solubility in water: emulsifiable
appearance and odor: amber liquid, w/aromatic odor.

Reactivity

Stability indicator/materials to avoid: yes
stability condition to avoid: heat & fire
hazardous decomposition products: noxious fumes, hydrogen chloride

Proper Disposal

Waste disposal methods: waste is toxic. Dispose of in accordance w/all
federal, state & local regulations. Concerning health & pollution.

combustible liquid.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: 2,4-d esters (sara iii)
cas: 25168-26-7
rtecs #: ag8575000
fraction by wt: 67.2%
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs

ingred name: n-butyl alcohol (sara iii)
cas: 71-36-3
rtecs #: eo1400000
fraction by wt:
other rec limits: 300 mg/cum
osha pel: 100 ppm
acgih tlv: s, c 50 ppm; 9293
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs

ingred name: kerosene, kerosine
cas: 8008-20-6
rtecs #: oa5500000
fraction by wt: 29.3%
other rec limits: 100 mg/cum niosh

ingred name: emulsifying agent
fraction by wt:

MSDS BPPBN ESTERON (R) BRAND 99 CONCENTRATE

Hazards

Ld50 lc50 mixture: oral ld50 rat: 1792 mg/kg, dermal ld50**
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: unknown iarc: yes
health hazards acute and chronic: ingest: harmful. Nausea, vomit, abdom
pain, diarrhea, pinpoint pupils, blurred vision, profuse sweating,
salivation, tremor, muscle twitching, & temp paralysis. In severe
poisoning respiratory depress & convulsions may occur. Product
contains petroleum distillates. Aspiration may occur after
swallowing, may result ***
explanation of carcinogenicity: iarc classifies chlorophenoxy herbicides
as 2b carcinogen, limited evidence in humans. Science advisory of
epa: class d.

effects of overexposure: ** rabbits: >2,000 mg/kg.

*** in chemical pneumonitis. Skin absorption: harmful. Skin:
irritation. Eye: moderate irritation. Repeated overexposure: liver,
kidney, gastrointestin al & muscular effects. Rare: peripheralnerve
damage. Repeated exposure: dry & defat skin, irritation,
dermatitis, burn.

medical cond aggravated by exposure: skin irritation may be aggravated
in person w/preexisting skin lesions. Breathing of vapor/spray
mists may aggravate acute or chronic asthma & chronic pulmonary
disease.

First Aid

First aid: remove from immed source of exposure. Assure that individual
breathing. Ingest: if patient conscious & alert, give 2-3 glasses
water to drink. Dont induce vomit. Get med aid. Prevent aspiration
of swa llowed product, lay patient on side w/head lower than waist.

skin: immed wash w/soap & water, removing contam cloth & shoes.

inhal: remove to fresh air. If not breath, give cpr/artif resp if
breath***

Chemical Properties

Hcc: v4
boiling pt: b.P. Text: >302f,>150c
vapor pres: 0.4 *
vapor density: 4.7 *
spec gravity: 1.03 @ 20/20 c
evaporation rate & reference: n/k * (kerosene)
solubility in water: emulsifiable
appearance and odor: amber liquid; hydrocarbon odor

Reactivity

Stability indicator/materials to avoid: yes
acids, bases, strong oxidizers.

stability condition to avoid: do not store near heat, sparks, open flame
or other ignition sources.

hazardous decomposition products: may include hydrogen chloride, the
oxides of carbon, and hydrocarbons.

Proper Disposal

Waste disposal methods: dispose in accord w/local, state & fed regs.

rcra hazardous waste # d001, ignitable. Spill subject to cerlca
report: rq = 100 lbs. # waterways. Wear
protect cloth & equip during cleanup. Use non spark tools.

decontam equip/tools
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: 2,4-dichlorophenoxacetic acid, 2-ethylhexyl ester (sara
iii) (no exposure limits have been established for the active
cas: 1928-73-3
rtecs #: ag7700000
fraction by wt: 65.9%
other rec limits: none specified

ingred name: # ingredient in this formulation. However, for the free
acid 2,4-d, the following applies
rtecs #: 9999999zz
other rec limits: none specified
osha pel: 10 mg/cubic m twa
acgih tlv: 10 mg/cubic m twa

ingred name: kerosene
cas: 8008-20-6
rtecs #: oa5500000
other rec limits: none specified

ingred name: proprietary emulsifiers
other rec limits: none specified

MSDS BTPKM CLEAN CROP LV-4 ESTER WEED KILLER

Hazards

Ld50 lc50 mixture: oral ld50 (rat): 300 mg/kg see supp
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: product is moderately toxic. May be
harmful if swallowed/inhaled. Irritation of eyes, nasal passages,
throat & skin may become severe & lead to an allergic skin
reaction.

explanation of carcinogenicity: none
effects of overexposure: nausea/vomiting/tenseness/muscular
weakness/diarrhea/stomach cramps/irritation.

First Aid

First aid: ingestion: drink 1-2 glasses of water. Don't induce vomiting.

aspiration hazard. Eyes: flush w/running water for 15 mins. Skin:
wash thoroughly w/soap & water. Inhalation: remove to fresh air.

obtain medical attention in all cases. Note tophysician: if
swallowed stomach lavage may be indicated. Treat symptomatically.

Chemical Properties

Boiling pt: b.P. Text: see supp
spec gravity: 1.03-1.04
evaporation rate & reference: (bu ac=1):
solubility in water: emulsifies
appearance and odor: amber liquid w/an alcohol-like odor.

Reactivity

Stability indicator/materials to avoid: yes
strong oxidizers.

stability condition to avoid: excessive heat.

hazardous decomposition products: chlorine-containing compounds

Proper Disposal

Waste disposal methods: triple rinse containers & offer for
recycling/reconditioning/puncture & dispose of in an approved
sanitary landfill. Don't contaminate water supplies by disposal of
wastes/containers. Dispose of in ac cordance w/federal, state &
local regulations.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: 2-ethylhexyl ester of 2,4-dichlorophenoxyacetic acid
cas: 1928-43-4
rtecs #: ag8525000
fraction by wt: 65.5%

ingred name: kerosene, kerosine
cas: 8008-20-6
rtecs #: oa5500000
fraction by wt:
other rec limits: 100 mg/cum niosh

ingred name: hydrosulfurized kerosine
cas: 64742-81-0
rtecs #: oa5510000
fraction by wt:

ingred name: aliphatic petroleum distillate *93-4*
cas: 64742-38-7
fraction by wt:

ingred name: petroleum mid-distillate, aliphatic petroleum naphtha
*93-1*no 2 diesel fuel
cas: 68476-34-6
fraction by wt:

ingred name: petroleum mineral oil *93-4*
cas: 64742-06-9
fraction by wt:

ingred name: heavy aromatic solvent naphtha petroleum
cas: 64742-94-5
rtecs #: wf3100000
fraction by wt:

ingred name: 2,4-dichlorophenoxy) acetic acid; (2,4-d)
cas: 94-75-7
rtecs #: ag6825000
fraction by wt: 43.4%
osha pel: 10 mg/cum
acgih tlv: 10 mg/cum
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs

ingred name: inert ingredients (type not specified)
fraction by wt: 8-9%

MSDS BVTLZ LV 4 ESTER WEED KILLER

Hazards

Ld50 lc50 mixture: oral ld50 (rat): 1.25 g/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: ingestion: harmful. Respiratory
depression in severe poisoning. Aspiration of material may cause
chemical pneumonitis. Skin: harmful if
absorbed/irritation/dermatitis/burns. Inhalation: harmful, irrit
ation of respiratory tract. Eyes: moderate irritation. 2,4-d
herbicides: may cause liver/kidney/gi/muscular effects.

explanation of carcinogenicity: none
effects of overexposure: irritation, nausea, vomiting, abdominal pain,
diarrhea, pinpoint pupils, blurred vision, profuse sweating,
salivation, tremor, muscle twitching, temporary paralysis,
convulsions, dizziness, headaches, defatting, dryness, burns.

medical cond aggravated by exposure: pre-existing skin/respiratory
disorders, acute/chronic asthma/other lung diseases.

First Aid

First aid: ingestion: drink 1-2 glasses of water to dilute. Don't induce
vomiting. Aspiration hazard. Eyes: flush w/water for 15 mins.

skin/hair: wash thoroughly w/soap & water. Inhalation: remove to
fresh air. Obtain medical attention in all cases. Note to
physician: no specific antidote/treat symptomatically. Contains
petroleum distiallates. (see supplemental data)

Chemical Properties

Boiling pt: b.P. Text: 338-356f
spec gravity: 1.03-1.04
evaporation rate & reference: (bu ac =1):
solubility in water: emulsifies
appearance and odor: amber liquid w/alcohol like odor

Reactivity

Stability indicator/materials to avoid: yes
strong oxidizers
stability condition to avoid: excessive heat
hazardous decomposition products: chlorine containing compounds, co,
other asphyxiants

Proper Disposal

Waste disposal methods: material which can't be used at site should be
disposed of in an approved waste disposal facility iaw/federal,
state & local regulations. Triple rinse containers/offer for
recycling/reconditioning/pun cture/dispose. Don't contaminate water
supplies.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: 2-ethylhexyl ester of 2,4-dichlorophenoxyacetic acid
cas: 1928-43-4
rtecs #: ag8525000
fraction by wt: 65.5%

ingred name: kerosene, kerosine
cas: 8008-20-6
rtecs #: oa5500000
fraction by wt:
other rec limits: 100 mg/cum niosh

ingred name: hydrosulfurized kerosine
cas: 64742-81-0
rtecs #: oa5510000
fraction by wt:

ingred name: aliphatic petroleum distillate *94-3*
cas: 64742-38-7
fraction by wt:

ingred name: petroleum mid-distillate, aliphatic petroleum naphtha
*94-3*no 2 diesel fuel
cas: 68476-34-6
fraction by wt:

ingred name: petroleum mineral oil *94-3*
cas: 64742-06-9
fraction by wt:

ingred name: heavy aromatic solvent naphtha petroleum
cas: 64742-94-5
rtecs #: wf3100000
fraction by wt:

ingred name: inert ingredients (type not specified)
fraction by wt: 8-9%

MSDS CCKXL WEED PRO, 4 LB, LOW VOLUME

Hazards

Ld50 lc50 mixture: ld50 rat 1792mg/kg ingest/skin 200mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhal: avoid breathing spray
mists/vapors.Chlorophenoxy compounds absorbed through lungs. Excess
exposure may irrit upper resp tract. May cause myotonia/muscle
weakness/falling bp.May cause eye irrit/ corneal injury. Skin:
absorption of harmful amts. Causes allerg react in susceptible
people. May cause nausea/diarrhea/*
effects of overexposure: *stomach cramps/gi distress/myotonia/muscle
weakness/falling bp. Ingest: nausea/abdomin pain/diarrhea/stomach
cramps/gi distress/mytonia/muscle weakness/falling bp. Contains
petroleum distillates. Aspi ration may result in chemical
pneumonia.

First Aid

First aid: inhalation: get fresh air. If not breathing give artificial
resp. Give oxygen if needed. Get med aid. Eye: hold lids open.

flush w/steady gentle stream water >15 min. Get med aid if irrit
persists. Sk in: immed wash w/lots soap & water. Remove contam
clothes/shoes/wash before reuse. If irrit persists get med aid.

ingest: if conscious/allert give 2-3 glasses water. Don't induce
vomiting. Get med aid

Chemical Properties

Boiling pt: b.P. Text: 300f,149c
melt/freeze pt: m.P/f.P text: -6f,-21c
vapor pres:
vapor density: na
spec gravity: 1.03 @ 20c
ph: 7.5-10
evaporation rate & reference: lower than buac
solubility in water: 100%emulsifiable@25c
appearance and odor: amber liquid, phenolic-like odor
percent volatiles by volume: 30-35

Reactivity

Stability indicator/materials to avoid: yes
oxidizing agents, acids.

stability condition to avoid: excessive heat.

hazardous decomposition products: hydrogen chloride/nitrogen oxides may
be produced on combustion.

Proper Disposal

Waste disposal methods: if can't be used according to label dispose of
in approved landfill or incinerator according to all applicable
state, federal, local regs. Tripple rinse all containers.

puncture/crush/offer for recycl ing/reconditioning if possible.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: 2,4-d isooctyl ester (cercla)(limits for free acid pel/tlv
10 mg/m3)(2,4-d acid equiv + 42.8%--3.8 lb/gl)
cas: 25168-26-7
rtecs #: ag8575000
fraction by wt: 64.5%
other rec limits: none recommended
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs

ingred name: kerosene (total percent of ingredients other than 2,4-d =
35.5)
cas: 8008-20-6
rtecs #: oa5500000
other rec limits: none recommended

ingred name: isooctyl alcohol (total percent of ingredients other than
2,4-d = 35.5)
cas: 26952-21-6
rtecs #: ns7700000
other rec limits: none recommended

ingred name: inert ingredients (nonhaz)(total percent of ingredients
other than 2,4-d = 35.5)
other rec limits: none recommended
osha pel: not relevant
acgih tlv: not relevant

MSDS CFMQS WEEDAR BRAND 64 HERBICIDE

Hazards

Ld50 lc50 mixture: ld50 (oral, rat) 1161 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eye, skin, respiratory &
gi tracts. Acute- causes irreversible eye damage. Skin contact may
cause irritation. Harmful if inhaled, ingested or absorbed through
skin. may cause respirator y tract irritation, abdominal pain,
muscle weakness. Chronic- unknown.

explanation of carcinogenicity: none
effects of overexposure: irritation, discomfort, tearing, pain,
decreased blood pressure, muscle weakness

First Aid

First aid: call physician if symptoms persist. Eye: immediately flush
with water for 15 minutes. Hold eyelids open. Call physician.

skin: wash with soap & water. Inhaled: move to fresh air. Provide
cpr/oxygen if ne eded. Oral: if conscious, drink water & induce
vomiting. Call a physician/poison control center immediately. Never
give fluid or induce vomiting if patient is unconscious or has
convulsions.

Chemical Properties

Hcc: t5
nrc/state lic num: not relevant
melt/freeze pt: m.P/f.P text: 21.0f,-6.1c
spec gravity: 1.1589
ph: 4.81
viscosity: not relevant
solubility in water: soluble
appearance and odor: reddish brown liquid - characteristic odor

Reactivity

Stability indicator/materials to avoid: yes
strong acids, strong oxidizing agents
stability condition to avoid: excessive heat
hazardous decomposition products: carbon monoxide, carbon dioxide,
oxides of nitrogen, hydrogen chloride

Proper Disposal

Waste disposal methods: dispose of in an appropriate disposal facility
in compliance with local, state and federal regulations. Spills may
be reportable to the national response center (800-424-8802).

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: 2,4-d acid, dimethylamine salt
cas: 2008-39-1
rtecs #: ag8400000
fraction by wt: 46.8%
other rec limits: none recommended

ingred name: other ingredients (trade secret)
fraction by wt: 53.2%
other rec limits: none recommended

MSDS CFVWH WEEDAR BRAND 64 HERBACIDE

Hazards

Ld50 lc50 mixture: oral ld50 (rat) is 1161 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: acute: ingestion may be harmful. Skin
absorption may be fatal. Contact with eye causes irreversible eye
damage, irritation. Inhalation of vapors may cause irritation; may
be harmful. Chronic: prolonge d or repeated exposure may cause
liver,kidney, gastroinestinal, muscular effects; may also cause
nerve damage.

explanation of carcinogenicity: per mfr-iarc lists phenoxyacetic acid
herbicides as class 2b carcinogens (limited human evidence).

effects of overexposure: igested-nausea, vomiting, abdiminal pain,
myotonia, mucle weakness, fall in blood pressure. Skin
absorption-nausea, myotonia, muscle weakness, fall in blood
pressure. Inhaled-nausea, myotonia, muscle weakness, fall in blood
pressure. Eyes-corneal opacity, irritation.

medical cond aggravated by exposure: existing skin lesions, asthma and
inflammatory or fibrotic pulmonary disease.

First Aid

First aid: eyes-flush with water for 15 minutes, lift lids. Get medical
attn. Skin-remove contaminated clothes. Wash with mild soap &
water. Inhaled-remove to fresh air. Administer oxygen or artificial
respirati on as needed. Get medical attn. Ingested-if conscious,
2-3 glasses water or milk; then induce vomiting. Get immediate
medical attention.

Chemical Properties

Hcc: t5
nrc/state lic num: none
spec gravity: 1.16
ph: 4.8@1%
evaporation rate & reference: none specified by mfr.

solubility in water: soluble
appearance and odor: reddish brown/liquid with a characteristic odor.

Reactivity

Stability indicator/materials to avoid: yes
acids and oxidizing agents.

stability condition to avoid: avoid excessive heat.

hazardous decomposition products: decomposition products may be
hazardous. These may include hydrogen chloride and nitrogen oxides.

conditions to avoid polymerization: will not occur.

Proper Disposal

Waste disposal methods: 2,4-d salts are a rcra hazardous waste (u240)
when disposed. Spills are subject to cercla reporting requirements;
rq=100 lbs. Dispose of in accordance with local, state and federal
environmental regul ations.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: 2,4-d acid, dimethylamine salt or acetic acid, (2,4-
dichlorophenoxy)-compound with n-methylmethanamine
cas: 2008-39-1
rtecs #: ag8400000
fraction by wt: 46.8%
other rec limits: 5 mg/m3 twa(mfr-rel)

ingred name: other ingredients
fraction by wt: balance
other rec limits: none recommended

MSDS CGXBQ 2,4-D L V 4 ESTER,WEEDAR 64 HERBICIDE,D 139 R

Hazards

Ld50 lc50 mixture: ld50 (oral) 1250 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eye, skin, cns,
respiratory & gi tracts. Acute- may cause slight eye/skin
irritation. Can be absorbed through skin. Excessive inhalation may
cause respiratory irritation & cns effects. I ngestion can be
fatal. May cause muscleweakness, fall in blood pressure. Chronic-
liver, kidney, gi/muscle effects.

explanation of carcinogenicity: none
effects of overexposure: irritation, nausea, headache, vomiting,
diarrhea, tearing, difficult breathing, dizziness, unconsciousness,
drowsiness, dry skin, blurred vision, muscle weakness
medical cond aggravated by exposure: persons with pre-existing skin
disorders, eye problems or impaired liver, kidney or respiratory
function may be more susceptible to the effects of this product.

First Aid

First aid: get medical help if symptoms persist. Inhaled: move to fresh
air. Provide cpr/oxygen if needed. Eyes: immediately flush with
water for 15 minutes, holding eyelids open. Skin: wash with soap &
water. Oral : do not induce vomiting. Seek prompt medical attention.

if conscious, drink large amount of milk, egg whites, gelatin
solution or water. Do not give anything by mouth to an unconscious
person.

Chemical Properties

Hcc: v4
nrc/state lic num: not relevant
boiling pt: b.P. Text: >400f,>204c
melt/freeze pt: m.P/f.P text: not known
vapor pres:
spec gravity: 1.034
solubility in water: emulsifiable
appearance and odor: dark amber liquid, aromatic (solvent) odor

Reactivity

Stability indicator/materials to avoid: yes
strong oxidizing agents, strong acids
stability condition to avoid: excessive heat, open flames
hazardous decomposition products: may form smoke, carbon monoxide,
carbon dioxide, fumes, nitrogen oxides, hydrogen chloride.

Proper Disposal

Waste disposal methods: dispose of in accordance with local, state and
federal regulations. Incineration, reusing or recycling is
recommended. Do not contaminate environment. Reportable quantity
(rq) of this product is 26 ga llons.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: isooctyl(2-ethylhexyl)ester of 2,4-dichlorophenoxyacetic
acid
cas: 1928-43-4
fraction by wt: 67.20%
other rec limits: none recommended
osha pel: 10 mg/m3(2,4-d a)mfr

ingred name: kerosene and emulsifier/aliphatic petroleum solvent
cas: 8008-20-6
rtecs #: oa5500000
fraction by wt: 32.80%
other rec limits: none recommended
osha pel: 5 mg/m3 as oil mist
acgih tlv: 5 mg/m3 as oil mist

MSDS CJSTX 2,4-D L.V.4 ESTER

Hazards

Ld50 lc50 mixture: acute oral ld50 - 1250 mg/kg
routes of entry: inhalation: no skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation: this product contains
petroleum distillates. Excessive inhalation may cause respiratory
irritation, dizziness, weakness, nausea, headache, or possible
unconsciousness. Eye: may cause sligh t eye irritation. Skin: may
cause mild skin irritation or dermal sensitization reactions in
some individuals. Harmful if absorbed through skin. Prolonged or
repeated overexposure may result in effects similar to those
caused by ingestion. Ingestion: may cause muscle weakness, nausea,
darrhea, and abdominal pain. Fall in blood pressure or myotonia
(prolonged muscular spasm) may occur under extreme exposure
conditions. Can be fatal.

explanation of carcinogenicity: repeated or prolonged overexposure to
phenoxy herbicides may cause liver, kidney, gastrointestinal or
muscular system effects. The epa's science advisory panel has given
2,4-d a class d classification (not classifiable as to human
carcinogenicity). Various epidemiological studies yielded
conflicting results with majority being negative.No proven
association.

effects of overexposure: nonspecific muscle weakness, lethargy, loss of
appetite, abdominal pain, headache, or shortness of breath. Note to
physician: this product contains petroleum distillates. If large
amounts have been in gested, empty the stomach by gastric
intubation with the aid of a cuffed endotracheal tube to prevent
aspiration and possible chemical pneumonia.

medical cond aggravated by exposure: skin exposure may aggravate
existing skin conditions. Exposure to mist may aggravate existing
respiratory conditions.

First Aid

First aid: eyes: hold eyelids open & flush entire eye with a steady,
gentle stream of water for 15 minutes. Get medical attention.

inhalation: remove to fresh air. If not breathing, give artificial
respiration. if breathing is difficult, give oxygen. Get medical
attention immediately. Ingestion: call a physician or poison
control center. Do not induce vomiting. Drink promptly, large
quantity of milk, egg whi tes, gelatin solution, or if not
available, drink large quantities of water. Avoid alcohol. Do not
give anything by mouth to unconscious person. Wash affected area
with soap & water. If irritation per sists, get medical attention.

Chemical Properties

Hcc: v4
boiling pt: >204.4c, 400.F
melt/freeze pt: m.P/f.P text: not determined
vapor pres:
spec gravity: 1.034(h20=1)
ph: n/d
voc grams/liter: 8.5
solubility in water: 100%emulsifiable w/water
appearance and odor: dark amber liquid, aromatic (solvent) odor

Reactivity

Stability indicator/materials to avoid: yes
strong oxidizers or acids.

stability condition to avoid: avoid heat conditions.

hazardous decomposition products: may include, but are not limited to;
hydrogen chloride and nitrogen oxides.

conditions to avoid polymerization: will not occur.

Proper Disposal

Waste disposal methods: container: triple rinse(or equivalent)& offer for
recycling, or puncture & dispose of in sanitary landfill. Plastic
containers disposable by incineration, if allowed by state & local
authorities, by bu rning. If burned, stay out of smoke.

Ingredients List

Ingred name: isooctyl (2-ethylhexy) ester of 2,4-dichlorophenoxyacetic
acid
cas: 1928-43-4
code: f
rtecs #: ag8525000
= wt: 67.2
osha pel: 10 mg/m3 2,4-d acid

ingred name: kerosene and emulsifier
cas: 8008-20-6
rtecs #: oa5500000
= wt: 32.8

MSDS CLGQY D139R, 2,4-D L.V. 4 ESTER

Hazards

Ld50 lc50 mixture: not provided
routes of entry: inhalation: no skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: inhalation: contains petroleum
distillates. Excessive inhalation may cause respiratory irritation,
dizziness, weakness, nausea, headache/possible unconsciousness.

eye: may cause slight irritati on. Skin: may cause mild
irritation/dermal sensitization in some individuals. Harmful if
absorbed through skin. Prolonged/repeated overexposure may result
in effects similar to those caused by ingesti on. Ingestion: may
cause muscle weakness, nausea, diarrhea, abdominal pain. Fall in
blood pressure may occur under extreme exposure conditions. Can be
fatal. Chronic: may cause liver, kidney, gastroin testinal/muscular
system effects.

explanation of carcinogenicity: repeated/prolonged overexposure to
phenoxy herbicides may cause liver, kidney,
gastrointestinal/muscular system effects. Epa's science advisory
panel has given 2,4-d a class d classification (not huma n
carcinogen). Various epidemiological studies yielded conflicting
results with majority being negative. Not a mutagen or teratogen.

effects of overexposure: not provided
medical cond aggravated by exposure: skin exposure may aggravate
existing skin conditions. Exposure to mist may aggravate existing
respiratory conditions.

First Aid

First aid: eye contact: hold eyelids open and flush entire eye with a
steady, gentle stream of water for 15 minutes. Get medical
attention. Inhalation: remove to fresh air. If not breathing, give
artificial resp iration. If breathing is difficult, give oxygen.

get medical attention immediately. Ingestion: call a physician or
poison control center. Do not induce vomiting. Drink promptly,
large quantity of milk , egg whites, gelatin solution, or water.

avoid alcohol. Do not give anything by mouth to an unconscious
person. Skin contact: wash affected area with soap and water. If
irritation persists, get medic al attention.

Chemical Properties

Hcc: v4
nrc/state lic num: not relevant
boiling pt: >204.4c, 400.F
melt/freeze pt: m.P/f.P text: not determined
decomp temp: decomp text: not provided
vapor pres:
spec gravity: 1.034(h20=1)
voc grams/liter: 8.5
viscosity: not provided
evaporation rate & reference: not provided
solubility in water: 100% emulsifiable (mix)
appearance and odor: dark amber liquid, aromatic (solvent) odor
percent volatiles by volume: not provided
corrosion rate: not provided

Reactivity

Stability indicator/materials to avoid: yes
strong oxidizers or acids.

stability condition to avoid: heat conditions.

hazardous decomposition products: may include, but are not limited to;
hydrogen chloride and nitrogen oxides.

Proper Disposal

Waste disposal methods: pesticide wastes are toxic. Improper disposal is
a violation of federal law and may contaminate groundwater. If
product cannot be disposed of by use according to label, contact
your state pesticide or environmental control agency or hazardous
waste representative at nearest epa regional office for g uidance.

Ingredients List

Ingred name: isooctyl (2-ethylhexyl) ester of 2,4-dichlorophenoxyacetic
acid
cas: 1928-43-4
code: f
rtecs #: ag8525000
= wt: 67.2
other rec limits: not provided
osha pel: 10 mg/m3 2,4-d acid
acgih tlv: not available

ingred name: kerosene and emulsifier
cas: 8008-20-6
rtecs #: oa5500000
= wt: 32.8
other rec limits: not provided
osha pel: not available
acgih tlv: not available

MSDS CLJQT D139R, 2,4-D L.V. 4 ESTER(SEE SUPPL)

Hazards

Ld50 lc50 mixture: acute oral ld50 - 1250 mg/kg
routes of entry: inhalation: no skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation: this product contains
petroleum distillates. Excessive inhalation may cause respiratory
irritation, dizziness, weakness, nausea, headache, or possible
unconsciousness. Eye: may cause sligh t eye irritation. Skin: may
cause mild skin irritation or dermal sensitization reactions in
some individuals. Harmful if absorbed through skin. Prolonged or
repeated overexposure may result in effects similar to those
caused by ingestion. Ingestion: may cause muscle weakness, nausea,
darrhea, and abdominal pain. Fall in blood pressure or myotonia
(prolonged muscular spasm) may occur under extreme exposure
conditions. Can be fatal.

explanation of carcinogenicity: repeated/prolonged overexposure to
phenoxy herbicides may cause liver, kidney,
gastrointestinal/muscular system effects. Epa`s science advisory
panel has given 2,4-d a class d classification (not human
carcinogen). Various epidemiological studies yielded conflicting
results with majority being negative. Not a mutagen or teratogen.

effects of overexposure: nonspecific muscle weakness, lethargy, loss of
appetite, abdominal pain, headache, or shortness of breath.

medical cond aggravated by exposure: skin exposure may aggravate
existing skin conditions. Exposure to mist may aggravate existing
respiratory conditions.

First Aid

First aid: eye contact: hold eyelids open and flush entire eye with a
steady, gentle stream of water for 15 minutes. Get medical
attention. inhalation: remove to fresh air. If not breathing,
give artificial respiration. If breathing is difficult, give
oxygen. Get medical attention immediately. Ingestion: call a
physician or poison control center. Do not induce vomiting. Drink
promptly, large quanti ty of milk, egg whites, gelatin solution,
or water. Avoid alcohol. Do not give anything by mouth to an
unconscious person. Skin contact: wash affected area with soap
and water. If irritation per sists, get medical attention.

Chemical Properties

Hcc: v4
nrc/state lic num: not relevant
boiling pt: >204.4c, 400.F
melt/freeze pt: m.P/f.P text: not determined
decomp temp: decomp text: not provided
vapor pres:
spec gravity: 1.034(h20=1)
ph: not determined
voc grams/liter: 8.5
viscosity: not provided
evaporation rate & reference: not provided
solubility in water: 100%emulsifiable w/water
appearance and odor: dark amber liquid, aromatic (solvent) odor
percent volatiles by volume: not provided
corrosion rate: not provided

Reactivity

Stability indicator/materials to avoid: yes
strong oxidizers or acids.

stability condition to avoid: avoid heat conditions.

hazardous decomposition products: may include, but are not limited to;
hydrogen chloride and nitrogen oxides.

Proper Disposal

Waste disposal methods: pesticide wastes are toxic. Improper disposal is
a violation of federal law and may contaminate groundwater. If
product cannot be disposed of by use according to label, contact
your state pesticid e or environmental control agency or
hazardous waste representative at nearest epa regional offi ce
for guidance.

Ingredients List

Ingred name: isooctyl (2-ethylhexy) ester of 2,4-dichlorophenoxyacetic
acid
cas: 1928-43-4
code: f
rtecs #: ag8525000
= wt: 67.2
other rec limits: not provided
osha pel: 10 mg/m3 2,4-d acid
acgih tlv: not available

ingred name: kerosene and emulsifier
cas: 8008-20-6
rtecs #: oa5500000
= wt: 32.8
other rec limits: not provided
osha pel: not available
acgih tlv: not available