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Herbicides, antisprouting products and plant-growth regulators
Herbicides (weed killers), antisprouting products and plant-growth regulators, put up or packed for retail sale or as preparations or articles
Chemicals-fertilizers
Y - Indicates information is in the hazardous materials information resource system (hmirs).
PMICA - Item does not contain precious metal.
CRITL- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.
Questions & Answers: |
|
| What are the historical prices recorded for this stock number? | |
| Historical data shows pricing from $594.58 to $990.97.. | |
| Does NSN 6840-00-664-7060 have a shelf life? | |
| No. There is no shelf life applicable for this NSN. | |
| What NATO entities are users of this NSN? | |
| Department Of The Army, U.s. Marine Corps, and Department Of The Navy | |
| What is the NIIN of NSN 6840-00-664-7060? | |
| 006647060 or 00-664-7060 | |
| Does NSN 6840-00-664-7060 require demilitarization? | |
| Yes - ITAR Controlled | |
| What is the most recent solicitation for NSN 6840-00-664-7060? | |
| No solicitations for this NSN. | |
| When was this national stock number assigned to the federal catalog? | |
| Dec 17, 1997 | |
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: yes iarc: yes osha: yes
health hazards acute and chronic: prolonged or repeated exposure may
cause skin irritation & burns. Causes severe eye irritation & eye
damage. Teratogen: suspect (5) mutagen/suspect carcinogen (3) cns
effects: (7) (osha industrial hyg iene manual).
explanation of carcinogenicity: iarc carc: animal indef '77. Human indef
'77. Skin abs: ld50(rabbit) 1400 mg/kg. Ingest: acute: human ldlo:
80mg/kg
effects of overexposure: weakness, lethargy, possibly anorexia,
myotomia. Slightly toxic, may cause irritation or ulceration.
medical cond aggravated by exposure: note to physician: this product
will cause severe eye irritation & damage. No time should be lost
in washing eyes thoroughly. The chlorophenoxy compounds are
absorbed across the gut wall, lung & skin.
First aid: excretion occurs within hours, though. Ingestion in large
amounts has resulted in severe metabolic acidosis in humans.
emergency: induce vomiting if swallowed. Follow w/water & milk. See
md. Wash w/so ap & water & remove contaminated clothing (contact).
inhalation: remove to fresh air. Eyes: wash imm. W/running water 15
minutes.
Boiling pt: b.P. Text: >100c
vapor pres: 16.5
spec gravity: @20c=1.245
solubility in water: infinite
appearance and odor: dark straw liquid w/characteristic odor.
Stability indicator/materials to avoid: yes
strong oxidants and acids.
stability condition to avoid: avoid strong oxidants & acids.
hazardous decomposition products: noxious fumes, including hydrogen
chloride and nitrogen oxide, possible upon exposure to heat.
Waste disposal methods: dispose in an approved landfill following all
applicable federal,state and local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: 2-4d amine - 2,4-dichlorophenoxyacetic acid, dimethylamine
salt
cas: 2008-39-1
rtecs #: ag8400000
fraction by wt: 47.42%
osha pel: none listed
acgih tlv: none listed
Ld50 lc50 mixture: ld50 (oral rat) is about 1675 mg/kg.
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: skin: may cause irritation; ingested:
low single dose oral toxicity; eye: causes burns, may cause corneal
injury. Stain for evidence of corneal injury.
effects of overexposure: systemic effect: may cause neurologic signs and
symptoms. Human effects not established at this time. Information
based on analogy to similar chemical. No specific antidote.
medical cond aggravated by exposure: n/r.
First aid: inhalation: remove to fresh air. Get medical attention.
eyes: immediately flush with plenty of water for 15 minutes. Get
medical attention. Skin: wash with soap ansd water,remove
contaminated clothing. launder before resue the clothing; ingest:
toxic by ingestion. Induce vomiting immediately and consult
medical.
Hcc: v7
vapor pres: 17 mmhg
spec gravity: 1.244
solubility in water: infinite
appearance and odor: amber liquid.
percent volatiles by volume: 40
Stability indicator/materials to avoid: yes
bases, oxidizing materials.
hazardous decomposition products: noxious fumes under fire conditions -
hydrogen chloride.
Waste disposal methods: bury in a non-crop area away from water
supplies. Disposal should be made in accordance with all applicable
federal, state and local laws and regulations.
Ingred name: (2,4-dichlorophenoxy)acetic acid dimethylamine
cas: 2008-39-1
rtecs #: ag8400000
fraction by wt: 59.7%
other rec limits: none established
osha pel: none established
acgih tlv: none established
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 40.3%
other rec limits: none established
Ld50 lc50 mixture: oral ld50 rats: 1150 mg/kg *
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: unknown iarc: yes
health hazards acute and chronic: ingest: harmful. May be fatal if
absorbed thru skin. Inhalation: may be harmful, cause irrit to resp
tract. Eye: irreversible eye damage, seen as corneal opacity.
repeated overexpos may cause liver, k idney, gastrointestinal &
muscular effects. Rare cases of peripheral nerve damage have been
reported.
explanation of carcinogenicity: phenoxyacetic acid herbicides are listed
as class 2b carcinogen.
effects of overexposure: swallowing, skin absorption & inhalation:
nausea, mytonia, muscle weakness and fall in blood pressure.
swallowing: vomiting, abdominal pain. Eye: vapors or sprays (mists)
are irritating to eyes. *d ermal rabbits: 1530 mg/kg. Skin
effectsrabbits: minimal irritation. Eye effects rabbits: severe
irrit.
medical cond aggravated by exposure: skin irritation may be aggravated
in person with existing skin lesions. Breathing of vapor, dust or
sprays (mists) may aggravate asthma and inflammatory or fibrotic
pulmonary disease.
First aid: remove from expos. Ingest: if conscious/alert give 2-3 glass
water/milk. Induce vomiting (finger back of throat/ipecac--1
tblspoon. If no vomit in 20 min, 1 tblspoon more).
unconscious--don't induce v omit. Call dr. Skin: wash skin w/soap
&wtr, removing contam cloth & shoes. Inhal: remove to fresh air.
not breathing--artif resp. Admin oxygen if needed. Call dr. Eyes:
flush w/water 15 min. Call dr.
Hcc: t5
melt/freeze pt: m.P/f.P text: 21.2f,-6.0c
spec gravity: 1.16 @ 20/20c
ph: 7.5-10
solubility in water: 100% @ 25 c
appearance and odor: clear, brown to black liquid. Characteristic
phenoxy odor.
Stability indicator/materials to avoid: yes
oxidizing agents and acids.
stability condition to avoid: avoid excessive heat.
hazardous decomposition products: hydrogen chloride and nitrogen oxides
may be produced upon decomposition.
Waste disposal methods: dispose of in an approved landfill or
incinerator following all applicable federal, state & local
regulations. Note: 2,4-d salts are a rcra hazardous waste (u240)
when disposed. Spills are subject to cerlca reporting
requirements: report qty 100 lbs.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: acetic acid (2, 4-dichlorophenoxy) compound with
n-methylmethanamine (1: 1) 2, -4 d, dimehylamine salt
cas: 2008-39-1
rtecs #: ag8400000
fraction by wt: 46.8%
other rec limits: * 2, 4-free acid
osha pel: 10 mg/m3 *
acgih tlv: 10 mg/m3 *
Ld50 lc50 mixture: oral ld50 (rat) is 1670 mg/kg.
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: may be fatal if swallowed or
absorbed through skin. May cause central nervous system effects if
inhaled or ingested. Chronic: liver or kidney damage or central
nervous system effects.
explanation of carcinogenicity: none of the ingredients of 0.1% or
greater concentration are listed as a carcinogen or suspected
carcinogen.
effects of overexposure: inhalation/ingestion/skin: loss of appetite,
nausea, vomiting, general tenseness, or muscular weakness.
medical cond aggravated by exposure: preexisting skin or respiratory
disorders may be aggravated by exposure to this product.
First aid: ingestion: drink 1 or 2 glasses of water. Do not induce
vomiting or give anything by mouth to an unconscious person. Keep
head lower than chest to avoid aspiration into lungs. Call
physician immediate ly. Eyes: flush with running water for at least
15 min while holding eyelids open to help flush out material. Get
medical attention. Skin: remove all contaminated clothing. Wash
skin and hair thorough ly with soap and water. If irritation
persists, get medical attention. Inhalation: remove to fresh air.
if breathing is difficult, administer oxygen; if breathing stops
administer artificial respirati on. Get medical attention
immediately.
Hcc: v7
boiling pt: =100.C, 212.F
vapor pres: 20.7
vapor density: 0.021
spec gravity: 1.158-1.168
ph: 7.5-9.0
viscosity: 11.5-13.0 centipoise
evaporation rate & reference: < butyl acetate
solubility in water: miscible
appearance and odor: amber to nearly black liquid with "fishy"
amine-like odor.
percent volatiles by volume: approx 50%
Stability indicator/materials to avoid: yes
strong oxidizers, acids.
stability condition to avoid: excessive heat.
hazardous decomposition products: ammonia, oxides of nitrogen,
chlorine-containing compounds and other unknown hazardous
materials. Incomplete combustion may lead to formation of carbon
monoxide and/or other asphyxiants.
Waste disposal methods: dispose of in accordance with local, state and
federal regulations.
Ingred name: 2,4-d (dichlorylphenoxyacetic acid) (sara iii)
cas: 94-75-7
rtecs #: ag6825000
other rec limits: none specified
osha pel: 10 mg/m3
acgih tlv: 10 mg/m3; 9192
epa rpt qty: 100 lbs
dot rpt qty: 100 lbs
ingred name: dimethylamine (sara iii)
cas: 124-40-3
rtecs #: ip8750000
other rec limits: none specified
osha pel: 5 ppm/stel15ppm;9293
acgih tlv: 10 ppm
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: 2,4-d acid, dimethylamine salt
cas: 2008-39-1
other rec limits: none specified
ingred name: 2,4-d acid (cas: 94-75-7), dimethylamine (cas: 124-40-3),
2,4-d acid dimethylamine salt (cas: 2008-30-1)
= wt: 46.5
other rec limits: see each ingred
ingred name: inert ingredients
= wt: 53.5
ld50 lc50 mixture: oral ld50 (rat) is 1391 mg/kg
route of entry inds - inhalation: no
skin: no
ingestion: no
carcinogenicity inds - ntp: no
iarc: no
osha: no
effects of exposure: acute: contact may cause corneal damage to eye which may
cause permanent damage or blindness. Ingestion may cause gi tract irritation.
inhalation of vapors is not likely to be hazardous. Chronic: prol onged or
repeated exposure may cause burns or skin irritation, liver, kidney,
gastrointestinal & muscular effects.
explanation of carcinogenicity: no ingredient of a concentration of 0.1% or
greater is listed as a carcinogen or suspected carcinogen.
signs and symptions of overexposure: eyes: blurred vision, tearing, burning
sensation, stinging. Skin: redness, discomfort, burning sensation. Swallowed:
nausea, vomiting, diarrhea, abdominal cramps.
medical cond aggravated by exposure: none specified by manufacturer.
first aid: inhaled: remove to fresh air if effects occur. See a doctor. Eyes:
flush with lots of water for 15 minutes. See doctor. Skin: wash off with
flowing water or shower. Ingested: if conscious, drink a lot of milk, egg
whites, gelatin solution,or water. Induce vomiting. Avoid alcohol. Get
immediate medical attention.
hcc: v7
vapor pres: 17 mm hg
vapor density: unknown
spec gravity: 1.24 @ 68f
evaporation rate & reference: unknown
solubility in water: complete
appearance and odor: amber liquid; no odor
corrosion rate: unknown
disclaimer (provided with this information by the compiling agencies): this
information is formulated for use by elements of the department of defense.
the united states of america in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the department of defense
nor any person or persons contracting with any instrumentality of the united
states of america and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
united states of america should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding department
of defense or other government situation.
=======================================================
responsible party cage: 0tnr0
trans id no: 81553
product id: 37930 formula 40 herbicide (vertac)
msds prepared date: 06/07/1992
review date: 01/12/1999
mfn: 2
tech entry nos shipping nm: 2,4-d (dichlorylphenoxyacetic acid)
net unit weight: 51.7 lbs
multiple kit number: 0
review ind: y
unit of issue: bx
container qty: 1
type of container: container
additional data: dot (surface): not regulated. Dot (water): regulated. Proper
shipping name is: environmentally haza rdous substance, liquid, n.O.S.
(2,4-dichlorophenoxy-acetic acid, water soluble), hazard class: 9; un 3082;
label: class 9. Dot or iata(air): not regulated.
=======================================================
stability indicator: yes
stability condition to avoid: avoid conditions near or above flash point. Avoid
incompatible materials.
materials to avoid: strong alkalis, strong oxidizing agents.
hazardous decomposition products: hydrogen chloride
hazardous polymerization indicator: no
conditions to avoid polymerization: none
spill release procedures: absorb with inert material. Dike in case of large
spills. Keep out of irrigation ditches and water supplies.
neutralizing agent: none specified by manufacturer.
waste disposal methods: dispose of in accordance with local, state and federal
regulations. Epa waste number u240 may apply.
handling and storage precautions: keep ot of reach of children. Do not get on
skin, in eyes or on clothing. Do not swallow.
other precautions: do not store near fertilizers, seed, fungicides, or
insecticides. Do not contaminate irrigation ditches or water used for
domestic purposes.
Ld50 lc50 mixture: oral ld50 (rat) is 375-500mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: **poison-corrosive** eyes: may cause
damage.Skin: may cause irritation or sensitization.May be dermally
absorbed in harmful amounts.Ingest: toxic.Chlorophenoxy compounds
are absorbed through the gut wall ,but are non-fat
soluble.Inhal: may causerespiratory irritation.Chronic: damage to
kidneys,blood,gi tract,blood,muscles.
explanation of carcinogenicity: there are no ingredients above 0.1%
which are identified as carcinogens by ntp,iarc or osha.
effects of overexposure: inhal: intoxication,nausea,loss of balance.
medical cond aggravated by exposure: persons with pre-existing
liver,kidney,blood,gi,muscular or respiratory ailments may be at
increased risk from exposure.
First aid: skin: remove contaminated clothing;wash with soap and
water.Eyes: flush with water for 15 minutes.Inhal: remove to fresh
air.Give oxygen or artificial respiration if needed.Ingest: get
prompt qualified me dical attention.If conscious,give 1-2 glasses
of water and induce vomiting.
Hcc: v7
spec gravity: 1.16
solubility in water: complete
appearance and odor: liquid;amber;phenolic odor
Stability indicator/materials to avoid: yes
mineral acids and strong bases.
stability condition to avoid: high heat,sources of ignition.
hazardous decomposition products: carbon dioxide,carbon
monoxide,hydrogen chloride.
Waste disposal methods: dispose of in accordance with federal,state and
local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: 2,4-d acid, dimethylamine salt
cas: 2008-39-1
rtecs #: ag8400000
fraction by wt: 46.88%
other rec limits: none recommended
ingred name: inert ingredients
fraction by wt: 53.12%
other rec limits: none recommended
Ld50 lc50 mixture: ld50 949 mg/kg.(oral)
routes of entry: inhalation: no skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: yes
health hazards acute and chronic: eye: may cause severe irritation
w/corneal injury. Skin: prolonged exposure may cause skin
irritation. Ingestion: moderate to low oral toxicity ld50 949
mg/kg.
explanation of carcinogenicity: 2,4-d acid
effects of overexposure: moderate weakness, lethargy, anorexis under
extreme exposure conditions.
medical cond aggravated by exposure: na
First aid: flush eyes or skin repeatedly w/water. For ingestion drink
promptly milk, egg whites, gelatin solution, or large amounts
water. Seek medical aid.
Boiling pt: b.P. Text: 214f,101c
melt/freeze pt: m.P/f.P text: na
vapor pres: na
vapor density: na
spec gravity: 1.161
evaporation rate & reference: na
solubility in water: 100%
appearance and odor: dark amber liquid, amine odor
Stability indicator/materials to avoid: yes
strong oxidizers.
stability condition to avoid: none
hazardous decomposition products: noxious fumes when exposed to extreme
fire condions.
Waste disposal methods: wastes are toxic. Dispose in accordance w/all
federal, state, local regulations concerning health & polution.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: 2,4-dichlorophenoxyacetic acid, dimethylamine salt
(equivalent to 2,4-dichlorophenoxyacetic acid 39.3% @ 3.8 lbs/gl)
cas: 2008-39-1
fraction by wt: 47.3%
other rec limits: none recommended
osha pel: 10 mg/m3
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 52.7%
other rec limits: none recommended
Ld50 lc50 mixture: *
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: inhalation: vapor/spray mists may
irritate resp tract, cause nausea/myotonia/muscle weakness/falling
bp. Eye: severe irrit. Causes irreversible eye damage seen as
corneal opacity. Vapors/spray mists i rrit eyes. May cause
permanent impairment/blindness. Skin: minimal irrit. May be harmful
if absorbed. Ingest: harmful**
explanation of carcinogenicity: phenoxyacetic acid herbicides listed as
class 2b carcinogen limited evidence of carcinogenicity in humans.
effects of overexposure: **may cause gi irrit/ulceration. Amts ingested
incidental to industrial handling/not likely to injure.
First aid: inhalation: get fresh air. If not breathing give artificial
resp. Give oxygen if needed. Get med aid. Eye: hold lids open. Wash
w/steady gentle stream water >15 min. Get med aid
(ophthalmologist). Ski n: immed wash w/lots soap & water. Remove
contam clothes/shoes/wash before reuse. If irrit persists get med
aid. Inhal: if conscious give 2-3 glasses water/milk. Don't induce
vomiting. Get med aid.
Boiling pt: b.P. Text: >212f,>100c
melt/freeze pt: m.P/f.P text: -6f,-21c
vapor pres: 25c
vapor density: na
spec gravity: 1.16 @ 22c
ph: 7.5-10
solubility in water: 100% @ 25c
appearance and odor: clear, brown to black liquid, characteristic
phenoxy odor
Stability indicator/materials to avoid: yes
oxidizing agents, acids.
stability condition to avoid: excessive heat
hazardous decomposition products: hydrogen chloride, nitrogen oxides may
be produced on decomposition.
Waste disposal methods: dispose of in an approved landfill or
incinerator following all applicable federal, state, local regs.
tripple rinse all containers. Puncture/crush/offer for
recycling/reconditioning if possible.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: 2,4-d acid, dimethylamine salt
cas: 2008-39-1
fraction by wt: 46.6%
other rec limits: none recommended
osha pel: 10 mg/m3 free acid
acgih tlv: 10 mg/m3 free acid
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
other rec limits: none recommended
ingred name: dimethylamine (cercla)
cas: 124-40-3
rtecs #: ip8750000
other rec limits: none recommended
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs
ingred name: inert ingredients
other rec limits: none recommended
osha pel: not relevant
acgih tlv: not relevant
Ld50 lc50 mixture: ld50 (oral) is 1,000 mg/kg.
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eye, skin, respiratory &
gi tracts. Acute- may cause severe eye irritation & damage. Skin
contact may cause minimal irritation. Inhalation may cause
irritation. May cause muscle weakness , fall in blood pressure if
ingested. Can be fatal in extreme exposure. Chronic- liver, kidney,
gi or muscle effects.
explanation of carcinogenicity: none
effects of overexposure: severe irritation, dizziness, nervousness,
headache, weakness, abdominal pain, diarrhea, nausea, vomiting,
sweating, tearing, blurred vision, muscle twitching,
incoordination, coma, death
medical cond aggravated by exposure: individuals with pre-existing
diseases of the eye, skin, respiratory tract, liver, kidney,
muscles may have increased susceptibility to the toxicity of
excessive exposures.
First aid: get medical help if symptoms persist. Inhaled: move to fresh
air. Provide cpr/oxygen if needed. Eyes: immediately flush with
water for 15 minutes. Hold eyelids open. Skin: wash with soap &
water. Oral: i f conscious, drink large amount of milk,egg white,
gelatin or water. Seek medical attention. Avoid alcohol. Do not
induce vomiting or give anything by mouth to an unconscious person.
Hcc: v7
nrc/state lic num: not relevant
boiling pt: >100.C, 212.F
melt/freeze pt: =0.C, 32.F
spec gravity: 1.161
ph: 7.5 - 8.5
solubility in water: infinite
appearance and odor: dark brown liquid - mild amine odor
Stability indicator/materials to avoid: yes
strong oxidizing agents, strong acids
stability condition to avoid: heat
hazardous decomposition products: carbon monoxide, carbon dioxide,
hydrogen chloride, nitrogen oxides may be formed.
Waste disposal methods: dispose of in accordance with local, state and
federal regulations. Avoid contamination of ground and surface
water. Contract with a licensed disposal agency. Reportable
quantity (rq): approximately 2 6 gallons.
Ingred name: dimethylamine salt of 2,4-dichlorophenoxyacetic acid
cas: 2008-39-1
rtecs #: ag8400000
= wt: 47.3
other rec limits: none recommended
osha pel: 10 mg/m3
ingred name: other ingredients including water
cas: 7732-18-5
rtecs #: zc0110000
= wt: 52.7
other rec limits: none recommended
osha pel: not relevant
acgih tlv: not relevant
Ld50 lc50 mixture: acute oral ld50: 1000mg/kg
routes of entry: inhalation: no skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: inhal: avoid inhal vap/mist.May
irrit resp tract or cause dizz.Eye: direct/prol expo to conc product
may cause corneal opacity,irreversible eye dmg.Skin: considered min
skin irrit,not dermal sensit izer.Harmful if absorbed thru
skin.Rep/prol expo may cause effects similar to those caused by
ingest.Ingest: may (supple)
explanation of carcinogenicity: per msds: ntp/iarc osha: no.Epa class
d(not classificable as to human carc)for 2,4-d.
effects of overexposure: nonspecific: muscle weakness,lethargy,loss of
appetite,abdominal pains,headache,or shortness of breath.
chronic: rep/prol overexpo to phenoxy herbicides may cause
liv/kid/gi/muscular sys effects.
medical cond aggravated by exposure: skin exposure may aggravate
exisitng skin conditions.Exposure to mist may aggravate existing
respiratory conditions.
First aid: eye: hold eyelids opn,flush w/steady gently h2o stream for
15mins.Get med attn prefer ophthalmologist.Inhal: remove to fresh
air.Not breath give art resp prefer mouth-to-mouth.Get med
attn.Ingest: drink promptly lg quant of milk/egg whites/gelatin
soln;not avai lg quant of h2o.Get med attn.Avoid alcohol.Dont
induce vomit or give anything by mouth if unconsc.Skin: wash
w/soap/h2o.Irrit persists(supple)
Hcc: v7
boiling pt: b.P. Text: 214f,101c
melt/freeze pt: m.P/f.P text: 32.0f,0.0c
decomp temp: decomp text: np
vapor pres: equiv h2o
vapor density: np
spec gravity: 1.084
ph: appear
viscosity: np
evaporation rate & reference: np
solubility in water: infinite in water
appearance and odor: dark brown liquid,mild amine odor; ph: 7.5-8.5
percent volatiles by volume: np
corrosion rate: np
Stability indicator/materials to avoid: yes
strong oxidizers or acids.
stability condition to avoid: avoid heat conditions.
hazardous decomposition products: may include but not limited
to: hcl,nitrogen oxies under extreme fire conditions.
Waste disposal methods: toxic to aquatic invertebrates.Drift/runoff
adversely affect aquatic invertebrates/nontarget
plants.Toxic.Improper dispo excess/rinsate dispo fed law
violation-contam groundh2o.Unable to dipso per lab el call state
pest/enviro agen/epa.3xrinse(neutra)
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: 2,4-d acid, dimethylamine salt; dimethylamine salt of
2,4-dichlorophenoxyacetic acid (dma salt of 2,4-d)
cas: 2008-39-1
rtecs #: ag8400000
fraction by wt: 25.50%
other rec limits: none recommended
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 74.50%
other rec limits: none recommended
Ld50 lc50 mixture: acute oral ld50: 1000 mg/kg
routes of entry: inhalation: no skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: inhal: avoid inhal vap/mist. May
irritate respiratory tract or cause dizziness. Eye: direct/prolonged
exposure to concentrated product may cause corneal opacity,
irreversible damage. Skin: minimum irritation, not a dermal
sensitizer. Harmful if absorbed thru skin. Repeated/prolonged
exposure may cause effects similar to those caused by ingestion.
ingestion: can be fatal. May cause muscle weakn ess,
nausea,vomit,abdom pain,fall in blood pressure or myotonia under
extreme exposure conditions.
explanation of carcinogenicity: per msds: ntp/iarc osha: no.Epa class
d(not classificable as to human carc)for 2,4-d.
effects of overexposure: nonspecific: muscle weakness,lethargy,loss of
appetite,abdominal pains,headache,or shortness of breath.
ingestion: muscle weakness, nausea,vomit,abdom pain,fall in blood
pressure or myotonia under ex treme exposure conditions.
chronic: rep/prol overexpo to phenoxy herbicides may cause
liver/kidney/gi/muscular system effects.
medical cond aggravated by exposure: skin exposure may aggravate
existing skin conditions. Exposure to mist may aggravate existing
respiratory conditions.
First aid: eye: hold eyelids opn,flush w/steady water stream for 15mins.
get med attention. Inhal: remove to fresh air. If not breath give
cpr. Get med attn. Ingest: drink large quantity of milk/egg
whites/gelatin soln or water. Get med attn. Avoid alcohol. Dont
induce vomiting or give anything by mouth if unconscious. Skin: wash
w/soap and water. Irritation persists get medical help. Note to dr:
probable mucas al damage may contraindicate gastric lavage. If
large amts ingested stomach should be emptied by gastric
intubation.
Hcc: v7
boiling pt: >100.C, 212.F
melt/freeze pt: =0.C, 32.F
decomp temp: decomp text: np
vapor pres: nd
vapor density: np
spec gravity: 1.161
ph: 7.5-8.5
voc grams/liter: 9.6
viscosity: np
evaporation rate & reference: np
solubility in water: infinite in water
appearance and odor: dark brown liquid,mild amine odor
percent volatiles by volume: np
corrosion rate: np
Stability indicator/materials to avoid: yes
strong oxidizers or acids.
stability condition to avoid: avoid heat conditions.
hazardous decomposition products: may include, but not limited to
hydrogen chloride and nitrogen oxides.
conditions to avoid polymerization: will not occur
Waste disposal methods: pesticide wastes are toxic. Improper disposal
excess spray mixture or rinsate disposal is a violation of fed
law, may contaminate groundwater. If unable to dipose per label,
dispose of in accordance w/local, state & federal regulations.
Ingred name: 2,4-d acid, dimethylamine salt; dimethylamine salt of
2,4-dichlorophenoxyacetic acid (dma salt of 2,4-d)
cas: 2008-39-1
rtecs #: ag8400000
fraction by wt: 47.30%
other rec limits: none recommended
osha pel: 10 mg/m3
ingred name: other ingreds including water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: 52.70%
other rec limits: none recommended
ld50 lc50 mixture: oral ld50 - 50%spec> 2.06 mg/1/4 hr, rat
route of entry inds - inhalation: yes
skin: yes
ingestion: yes
carcinogenicity inds - ntp: yes
iarc: yes
osha: yes
effects of exposure: eye: causes corneal opacity, irreversible eye damage,
vapors & mists can cause irritation. Skin: may cause slight transient
irritation, toxic if absorbed through skin. May produce symptoms similar to
those from inhalation & ingestion. May cause decreased blood pressure,
muscle weakness, muscle spasms. Inhalation: harmful if inhaled. May cause
upper respiratory tract irritation, nausea, decreased b lood pressure, muscle
weakness, muscle spasms. Ingestion: harmful if ingested. May cause nausea,
vomiting, abdominal pain, decreased blood pressure, muscle weakness, muscle
spasms.
explanation of carcinogenicity: chronic effects; this product contains
ingredients that are considered to be probable or suspected human
carcinogens. Substances considered: chlorophenoxy herbicides listed as class
2b carcinogens, (l imited evidence for carcinogenicity in humans) by intl
agency for research on cancer (iarc). Science advisory panel of usepa has
given a class d classification.
signs and symptions of overexposure: this product contains a phenoxy herbicide.
myotoxic effects may include muscle fibrillations, myotonia, & muscular
weakness. Ingestion of massive does may result in persistent fall of blood
pressure. myoglobin and hemoglobin may be found in urine. Elevations in
lactate dehydrogenase (ldh), sgot, sgpt & aldolase indicate the extent of
muscle damage. In humans may affect both central & nervous syste m
resembling effects of alcohol or sedative drugs. Causes eye irritation &
irreversible damage. Slight transient irritation on skin. If absorbed through
skin, inhaled or ingested, muscle weakness, mus cle spasms vomiting,
abdominal pain.
medical cond aggravated by exposure: inhalation of product may aggravate
existing chronic respiratory problems such as asthma, emphysema or
bronchitis. Skin contact may aggravate existing skin disease.
first aid: eyes: holds eyelids open & flush with steady, gentle stream of
water for at least 15 minutes. Skin: immediately wash w/plenty of soap &
water for at least 15 minutes. Remove contaminated clothing & sh oes
while washing. Remove victim from immediate source of exposure & ensure
victim is breathing. If breathing difficult, administer oxygen, if available.
if victim not breathing, administer cpr (cardi o-pulmonary resuscitation). If
victim conscious & alert, give 2-3 glasses water to drink & induce
vomiting. Do not induce vomiting or give anything by mouth to an unconscious
person. Seek medical atte ntion in all cases.
hcc: v7
b.P. Text: not available
melt/freeze pt: =-6.1c, 21.F
m.P/f.P text: freezing point range
decomp text: not available
vapor pres: not available
spec gravity: 1.1589 at 25c (77f).
ph: 4.81 at 1 wt/%.
solubility in water: soluble
appearance and odor: reddish brown / liquid. Characteristic odor.
disclaimer (provided with this information by the compiling agencies): this
information is formulated for use by elements of the department of defense.
the united states of america in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the department of defense
nor any person or persons contracting with any instrumentality of the united
states of america and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
united states of america should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding department
of defense or other government situation.
=======================================================
responsible party cage: fo325
trans id no: 150077
product id: weedar (r) brand 64 herbicide
msds prepared date: 11/09/1999
review date: 11/17/1999
mfn: 1
net unit weight: 48 lbs
multiple kit number: 0
unit of issue: bx
container qty: 1
type of container: container
=======================================================
stability indicator: yes
stability condition to avoid: elevated temperatures.
materials to avoid: strong acids, strong oxidizing agents.
hazardous decomposition products: thermal: hydrogen chloride, oxides of
nitrogen, and oxides of carbon.
hazardous polymerization indicator: no
conditions to avoid polymerization: will not occur.
spill release procedures: wear appropriate protective gear for situation. Dike
spill using absorbent or impervious matls such as earth, sand or clay.
collect & contain, contaminated absorbent & dike matl for disposal.
pump an y free liquid into appropriate closed container. Collect washings for
disposal. Decontaminate tools & equipment following cleanup.
neutralizing agent: none specified by manufacturer.
waste disposal methods: do not flush to drain. Prevent material from entering
public sewer system or any waterways. If spilled on ground, affected area
should be removed to depth of one or two inches & placed in appropriate
container for disposal. Dispose of as hazardous waste. Spills may be
reportable to natl response cen ter (800-424-8802). & to state/local
agencies.
handling and storage precautions: min/max storage temperatures: not available.
do not breathe vapors & mists. Do not get on skin or in eyes. Do not
ingest. Store in an area that is away from food, feedstuffs, fertilizers
& seed.
other precautions: none specified by manufacturer.
ld50 lc50 mixture: 1161 mg/kg, oral-rat
carcinogenicity inds - ntp: no
iarc: yes
osha: no
effects of exposure: acute eye: causes corneal opacity, irreversible eye
damage. Vapors and mists can cause irritation. Skin: may cause slight
transient irritation. Toxic if absorbed through the skin, may produce
symptoms similar to those from inhalation and ingestion. May cause decreased
blood pressure, muscle weakness, muscle spasms. Inhalation: harmful if
inhaled. May cause upper respiratory tract irritation, nause a, decreased
blood presssure, muscle weakness, muscle spasms. Ingestion: harmful if
ingested. May cause nausea, vomiting, abdominal pain, decreased blood
pressure, muscle weakness, muscle spasms.
explanation of carcinogenicity: product contains ingredients considered
probable/suspected human carcinogens. iarc 2b. Epa class d, not
classificable as to human carcinogenity. Requires additional tests. Various
animal tests show n o positive association between 2,4-d exposure &
cancer. Recent results from lifetime study in lab animals do not show
evidence of carcinogenic effects by 2,4-d.
signs and symptions of overexposure: acute eye: causes corneal opacity,
irreversible eye damage. Vapors and mists can cause irritation. Skin: may
cause slight transient irritation. Toxic if absorbed through the skin, may
produce symptoms similar to those from inhalation and ingestion. May cause
decreased blood pressure, muscle weakness, muscle spasms. Inhalation: harmful
if inhaled. May cause upper respiratory tract irritation, nause a, decreased
blood presssure, muscle weakness, muscle spasms. Ingestion: harmful if
inggested. May cause nausea, vomiting, abdominal pain, decreased blood
pressure, muscle weakness, muscle spasms.
medical cond aggravated by exposure: inhalation of this product may aggravate
existing chronic respiratory problems such as asthma or bronchitis. Skin
contact may aggravate existing skin disease.
first aid: eye: hold eyelids open & flush with steady, gentle stream of
water for at least 15 min. Get immediate medical help. Skin: immediately wash
with plenty soap & water for at least 15 min. Get medical hel p. Remove
contaminated clothing & shoes before re-use. Discard if cannot be
cleaned. Inhalation: move from exposure. Assure victim is breathing. If
breathing difficult, give oxygen, if available. If n ot breathing, give cpr.
get medical help. Ingestion: give 2-3 glasses water, induce vomiting if
conscious. Prevent aspiration into lungs by laying on side with head lower
than waist. If unconscious, d on't induce vomiting.
hcc: v5
b.P. Text: not available
melt/freeze pt: =-6.C, 21.2f
spec gravity: 1.1589
ph: 4.81
solubility in water: soluble
appearance and odor: reddish brown liquid; characteristic odor.
disclaimer (provided with this information by the compiling agencies): this
information is formulated for use by elements of the department of defense.
the united states of america in no manner whatsoever expressly or implied
warrants, states, or intends said information to have any application, use or
viability by or to any person or persons outside the department of defense
nor any person or persons contracting with any instrumentality of the united
states of america and disclaims all liability for such use. Any person
utilizing this instruction who is not a military or civilian employee of the
united states of america should seek competent professional advice to verify
and assume responsibility for the suitability of this information to their
particular situation regardless of similarity to a corresponding department
of defense or other government situation.
=======================================================
responsible party cage: 9z675
trans id no: 153201
product id: weedar brand 64 herbicide
msds prepared date: 11/13/1998
review date: 05/25/2000
mfn: 1
multiple kit number: 0
unit of issue: bx
container qty: 1
type of container: container
=======================================================
stability indicator: yes
stability condition to avoid: elevated temperatures
materials to avoid: strong acids; strong oxidizing agents
hazardous decomposition products: hydrogen chloride, oxides of nitrogen; oxides
of carbon
hazardous polymerization indicator: no
spill release procedures: dike spill using absorbent or impervious materials
such as earth, sand or clay. Collect and contain contaminated absorbent and
dike material for disposal. Pump any free liquid into appropriate contain er.
collect washings for disposal. Decontaminate tools and equipment following
cleanup.
neutralizing agent: not provided
waste disposal methods: chemical additions, processing or otherwise altering
material may make information presented in msds incomplete, inaccurate or
otherwise inappropriate. State & local requirements for waste disposal ma
y be more restrictive or otherwise different from federal laws &
regulations regarding proper dispo sal of this material.
handling and storage precautions: do not breathe vapors and mists. Do not get
on skin or in eyes. Do not ingest. Store in an area that is away from food,
feedstuffs, fertilizers and seed.
other precautions: not provided
Routes of entry: inhalation: no skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: inhalation-this product contains
petroleum distillates. Excessive inhalation may cause respiratory
irritation, dizziness, weaknes, nausea, headache, or possible
unconsciousness. Eyes- may cause slight eye irritation. Skin-may
cause mild skin irritation or dermal sensitization reactions in
some individuals. Harmful if absorbed through skin. Prolonged or
repeated overexposure may result in effects s imilar to those
caused by ingestion. Ingestion-may cause muscle weakness, nausea,
diarrhea, & abdominal pain. Fall in blood pressure or myotonia
(prolonged muscular spasm) may occur under extreme expo sure
conditions. Can be fatal.
explanation of carcinogenicity: the current scientific consenses is that
there is no proven causal association between 2,4-d & cancer.
recent studies have not shown 2,4-d to be a mutagen or teratogen.
effects of overexposure: nonspecific: muscle weakness, lethargy, loss of
appetite, abdominal pains, headaches, or shortness of breath.
medical cond aggravated by exposure: skin exposure may aggravate
existing skin conditions. Exposure to mist may aggravate existing
respiratory conditions.
First aid: eye-hold eyelids open & flush entire eye with a steady,
gentle stream of water for 15 mins. Get medical attention.
inhalation-remove to fresh air. If not breathing, give artificial
respiration. If bre athing is difficult, give oxygen. Get medical
attention immediately. Ingestion-call a physician or poison control
center. Do not induce vomiting. Drink promptly a large quantity of
milk, egg whites, g elatin solutin, or if these are not available,
drink large quantities of water. Avoid alcohol. Do not give
anything by mouth to an unconscious person. Skin-wash affected area
with soap & water. If irr itation persists, get medical aid.
Hcc: v4
boiling pt: >204.4c, 400.F
melt/freeze pt: m.P/f.P text: n/d
vapor pres: (mm hg @ 20c):
spec gravity: 1.034
ph: n/d
solubility in water: 100% emulsifiable (can be
appearance and odor: dark amber liquid, aromatic (solvent) odor
Stability indicator/materials to avoid: yes
strong oxidizers or acids.
stability condition to avoid: avoid heat conditions.
hazardous decomposition products: none
conditions to avoid polymerization: will not occur.
Waste disposal methods: pesticide wastes are toxic. Improper disposal of
excess pesticide spray mixtures or rinsate is a violation of
federal law & may contaminate groundwater. If product cannot be
disposed of by use accordi ng to the label, contact your state
pesticide or environmental control agency or the hazardous waste
representative at the nearest epa regional office
Ingred name: isoctyl (2-ethylhexyl) ester of 2,4-dichlorophenoxyacetic
acid
cas: 1928-43-4
rtecs #: ag8525000
= wt: 67.2
osha pel: 10 mg/m3 (2,4-d acid
ingred name: kerosene and emulsifier
cas: 8008-20-6
rtecs #: oa5500000
= wt: 32.8