Adhesive

Hazards

Effects of overexposure: irritating eyes & respiratory passages. Can
cause a depressant action on the central nervous sys.

First Aid

First aid: in all cases of overexposure, call a phys. Remove from
exposure to well ventilated area. If skin contact: wash thoroughly
w/soap/water. In case of eye contact, flush w/water. If take
internally, don't induce vomiting. If resp problems arise oxygen.

Chemical Properties

Boiling pt: b.P. Text: 295f
vapor pres: 20c
vapor density: >air
evaporation rate & reference: slower than ether
appearance and odor: clear amber liquid.

percent volatiles by volume:

Reactivity

Stability indicator/materials to avoid: yes
peroxides and strong oxidizing agents and strong acids
stability condition to avoid: prolonged exposure to heat & sunlight
hazardous decomposition products: co2 and co2, low molecular weight
hydrocarbons.

conditions to avoid polymerization: sunlight/open
flames/contamination/prolonged storage >100f.

Proper Disposal

Waste disposal methods: dispose of materials and soaked rags in flame
proof containers in accordance with local state and federal
regulations.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: styrene, monomer (sara iii)
cas: 100-42-5
rtecs #: wl3675000
fraction by wt:
osha pel: 100 ppm
acgih tlv: s,50ppm/100stel;9293
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs

ingred name: unsaturated polyester
fraction by wt: >50%

Hazards

Effects of overexposure: inhalation: irrit to all parts resp tract. Eye:
extremely irrit. Skin: moderate irritation.

First Aid

First aid: inhal: remove to fresh air,give artif resp if needed.Skin: wash
w/soap & water,remove contaminated cloth.Eye: flush w/water 15
min,hold eyelid away from eyeball,see md.Ingest: see md immed.

Chemical Properties

Hcc: f4
boiling pt: b.P. Text: 293f,145c
melt/freeze pt: m.P/f.P text: -24f,-31c
vapor pres:
vapor density: 3.6
spec gravity: 1.09-1.28
evaporation rate & reference:
solubility in water: slight
appearance and odor: colorless-yellow, refractive oily liquid; sweet
aromatic odor
percent volatiles by volume: 29-43

Reactivity

Stability indicator/materials to avoid: yes
strong oxidizers.

conditions to avoid polymerization: mixing promoters & catalysts
together,mix into prod seperate

Proper Disposal

Waste disposal methods: containerize waste for disposal.Dispose or
recycle waste materials iaw,local,state and federal regs.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: unsaturated polyester
fraction by wt:

ingred name: styrene monomer
cas: 57-11-4
rtecs #: wi2800000
fraction by wt:
acgih tlv: 100 ppm (mfr)

ingred name: phosphonate ester
fraction by wt:

Hazards

Effects of overexposure: inhalation: irrit to all parts resp tract.

eye: extremely irrit. Skin: moderate irrit.

First Aid

First aid: inhalation: remove to fresh air,give artif resp if
needed.Skin: wash with soap & water,remove contaminated
cloth.Eye: flush w/water 15 min,hold eyelid away from eyeball,see
md. Ingestion: see md immed.

Chemical Properties

Hcc: f4
boiling pt: b.P. Text: 145c/293f
vapor pres:
vapor density: 3.6
spec gravity:
evaporation rate & reference:
solubility in water: slight
appearance and odor: clear liquid with mild odor
percent volatiles by volume:

Reactivity

Stability indicator/materials to avoid: yes
handling equip must be resist to monomer or organic chem con
stability condition to avoid: flammable liquid
conditions to avoid polymerization: mixing promoters &catalysts
together,mix into prod seperate

Proper Disposal

Waste disposal methods: containerize waste for disposal. Dispose or
recycle waste materials iaw, local,state and federal regs.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: unsaturated polyester
fraction by wt:

ingred name: styrene monomer
cas: 57-11-4
rtecs #: wi2800000
fraction by wt:
acgih tlv: 100ppm(mfr)

ingred name: phosphonate ester
fraction by wt:

Hazards

Effects of overexposure: inhal: irrit to all parts resp
tract.Eye: extremely irrit.Skin: moderate irrit.

First Aid

First aid: inhal: remove to fresh air,give artif resp if needed.Skin: wash
w/soap & water,remove contaminated cloth.Eye: flush w/water 15
min,hold eyelid away from eyeball see md.Ingest: see md immed.

Chemical Properties

Hcc: f4
boiling pt: b.P. Text: 145c/293f
vapor pres:
vapor density: 3.6
spec gravity: 1.30
evaporation rate & reference:
solubility in water: slight
appearance and odor: amber,clear liquid,with odor of styrene monomer
percent volatiles by volume: 31

Reactivity

Stability indicator/materials to avoid: yes
handling equip must be resist to monomer or organic chem con
stability condition to avoid: flammable liq
conditions to avoid polymerization: mixing promoters & catalysts
together,mix into prod seperate

Proper Disposal

Waste disposal methods: containerize waste for disposal. Dispose or
recycle waste materials iaw, local,state and fed regs.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: unsaturated polyester
fraction by wt: 67%

ingred name: styrene monomer
cas: 57-11-4
rtecs #: wi2800000
fraction by wt: 29%
acgih tlv: 100ppm (mfr)

ingred name: phosphonate ester
fraction by wt: 4%

Hazards

Effects of overexposure: irritating to all parts of respiratory
tract.Both liquid styrene and vapor can be extremely irritati

First Aid

First aid: inhalation: move subject to fresh air,keep warm,give oxygen or
artificial respiration as required.Skin contact: wash with soap and
water.Eyes: flush promptly with compious amounts of water for 15
minutes and consults phys.Ingestion: consult physician pro

Chemical Properties

Hcc: f4
boiling pt: b.P. Text: >150 f
vapor pres: 5.2
vapor density: 3.6
spec gravity: 1.1
evaporation rate & reference: viscous liquid wit
solubility in water: insoluble
appearance and odor: h sharp odor (styrene)
percent volatiles by volume: 35

Reactivity

Stability indicator/materials to avoid: yes
strong acids,peroxides and other oxidizing agents.

stability condition to avoid: sunlight,open flames,contamination and
prolonged storage abo
hazardous decomposition products: carbon monoxide and dioxide,low
molecular weight hydrocarbon
conditions to avoid polymerization: sunlight,open flames, contamination
and prolonged storage ab

Proper Disposal

Waste disposal methods: resin mixed with peroxide initators before
spill,should be mixed with inert filler and remove to open
area.Allow time to gel cure. Use sanitary landfill or
incineration.Do not incinerate closed contai ners.Disposal must be
carried out in accordance.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: polyester resin

ingred name: vehicle
fraction by wt: 35%
acgih tlv: 100ppm

Hazards

Ld50 lc50 mixture: oral ld50 (rat) is 5000 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: yes iarc: yes osha: no
health hazards acute and chronic: vapors/mists are extremely
irritating.Eyes: may cause irritation.Skin: may cause irritation.May
be dermally absorbed in harmful amounts.Ingest: may cause gi tract
irritation.Inhal: may cause respiratory i rritation and cns
depression.Chronic: may cause liver and kidney damage.

explanation of carcinogenicity: iarc has classified styrene as a
possible human carcinogen (class 2-b). This is based on new
classification scheme.

effects of
overexposure: skin: rash.Inhal: narcosis,nausea,vomitng,headache.Inges
t: nausea,vomiting,headache,narcosis.

medical cond aggravated by exposure: persons with a history of skin,
kidney, respiratory or liver disorders may be at increased risk
when using this material.

First Aid

First aid: skin: remove contaminated clothing;wash with soap and
water.Eyes: flush with water for 15 minutes.Inhal: remove to fresh
air.Give oxygen or artificial respiration if needed.Ingest: do not
induce vomiting. Get prompt qualified medical attention.

Chemical Properties

Hcc: d2
boiling pt: b.P. Text: 293f,145c
vapor pres:
vapor density: 3.6
spec gravity: 1-1.1
evaporation rate & reference: 3.1 (n-butyl acetate=1)
solubility in water: very slight
appearance and odor: liquid,viscous;sweet pungent odor.Color not
reported.

Reactivity

Stability indicator/materials to avoid: yes
strong oxidizing agents,acids,metal halides,peroxides.

stability condition to avoid: sunlight, high heat above 75f, open flames
and other sources of ignition, prolonged storage.

hazardous decomposition products: carbon monoxide, carbon dioxide,
uninhibited vapors may form polymers.

conditions to avoid polymerization: sunlight, elevated temperatures(such
as in fire conditions).

Proper Disposal

Waste disposal methods: dispose of contaminated product and materials
used in cleaning up spills or leaks in accordance with all
applicable federal, state, and local regulations. Note: empty
containers can have residues subj ect to proper waste disposal.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: styrene monomer (sara iii)
cas: 100-42-5
rtecs #: wl3675000
fraction by wt: 33%
other rec limits: none recommended
osha pel: 100 ppm
acgih tlv: s,50ppm/100stel;9394
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs

Hazards

Ld50 lc50 mixture: oral ld50 (rat) is 484 mg/kg (ingred 1)
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eyes: may cause severe
irritation.Skin: may cause severe irritation.May be dermally
absorbed in harmful amounts(rtecs-cheminfo).Ingest: may cause gi
tract irritation.Inhal: may cause respiratory irritatio n and cns
effects.

explanation of carcinogenicity: mek peroxide has been studied, and has
been shown to promote tumorigenisis,but results are inconclusive.

effects of
overexposure: inhal: narcosis,dizziness.Ingest: nausea,vomiting,headac
he,narcosis.

medical cond aggravated by exposure: persons with pre-existing
respiratory ailments may be at increased risk from exposure.

First Aid

First aid: skin: remove contaminated clothing;wash with soap and
water.Eyes: flush with water for 15 minutes.Inhal: remove to fresh
air.Give oxygen or artificial respiration if needed.Ingest: do not
induce vomiting. Get prompt qualified medical attention.If
conscious,give water to dilute stomach contents.

Chemical Properties

Hcc: d2
vapor density:
spec gravity: 1.1
solubility in water: slight
appearance and odor: liquid,;water white;slight odor.

Reactivity

Stability indicator/materials to avoid: yes
promoters(eg.Dimethylanaline,cobalt naphtenate),accelerators,reducing
agents.

stability condition to avoid: sunlight, high heat above 80f, open flames
and other sources of ignition, prolonged storage.

hazardous decomposition products: not reported.

conditions to avoid polymerization: avoid contamination with
incompatible materials.

Proper Disposal

Waste disposal methods: dispose of in accordance with federal,state and
local regulations.Rcra code for mek peroxide is u160, dimethyl
phthalate is u102.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: methyl ethyl ketone peroxide (mekp) (sara iii)
cas: 1338-23-4
rtecs #: el9450000
fraction by wt: 34%
other rec limits: none recommended
osha pel: c 0.7 ppm
acgih tlv: c 0.2 ppm ; 9394
epa rpt qty: 10 lbs
dot rpt qty: 10 lbs

ingred name: dimethylphthalate (sara iii)
cas: 131-11-3
rtecs #: ti1575000
fraction by wt: 58%
other rec limits: none recommended
osha pel: 5 mg/m3
acgih tlv: 5 mg/m3; 9394
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs

ingred name: 2-thylhexyl acetate
fraction by wt: 7%
other rec limits: none recommended

ingred name: hydrogen peroxide (sara iii)
cas: 7722-84-1
rtecs #: mx0900000
fraction by wt: 1%
other rec limits: none recommended
osha pel: 1 ppm
acgih tlv: 1 ppm; 9394

Hazards

Chemical Properties

hcc: f3
boiling point: =146.1c, 295.F
vapor density: >air
spec gravity: 1.15-1.20
evaporation rate & reference: slower n-butyl acetate
appearance and odor: liquid with pungent odor.

percent volatiles by volume: 40

HAZCOM Label

product id: dion iso 33-597-00
cage: 0dr81
company name: reichhold chemicals inc
street: 9 woodlawn green suite 208
city: charlotte nc
zipcode: 28217
health emergency phone: 800-424-9300 (chemtrec)
label required ind: y
date of label review: 12/16/1998
status code: c
label date: 12/16/1998
origination code: g

Transportation

=======================================================
responsible party cage: 0dr81
trans id no: 80346
product id: dion iso 33-597-00
msds prepared date: 10/06/1993
review date: 10/26/1995
mfn: 2
net unit weight: 9.6 lbs
af mmac code: nr
multiple kit number: 0
review ind: y
unit of issue: gl
container qty: 4

Reactivity

=======================================================
stability indicator: yes
stability condition to avoid: heat & direct sunlight.

materials to avoid: strong acids & oxidizing agent.

Proper Disposal

Hazards

Ld50 lc50 mixture: oral ld50 (rat): 5 gm/kg
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: prolonged or frequent skin contact may
cause defatting and dryness resulting in dermatitis. Eye contact
may cause irritation. Inhalation may cause mucous membrane
irritation and upper respiratory trac t irritation. Liquid splashes
may resultin more serious injury. Ingestion may cause gi tract
disturbances, pain.

explanation of carcinogenicity: this compound contains no ingredients at
concentrations of 0.1% or greater that are carcinogens or suspect
carcinogens.

effects of overexposure: skin irritation/defatting/dryness/dermatitis.

eye irritatio, tearing. Mucous membrane irritation, upper
respiratory tract irritation, gi tract disturbances, pain,
discomfort.

medical cond aggravated by exposure: none specified by manufacturer.

First Aid

First aid: eyes: flush with water for 15 minutes while holding eyelids
open. Get medical attention. Skin: remove contaminated clothing.

wash with soap and water. If irritation persist, get medical
attention. Inh alation: remove to fresh air. Restore breathing. Get
medical attention. Ingestion: do not induce vomiting. If occurs,
keep head below hips. Get medical attention.

Chemical Properties

Hcc: f3
boiling pt: =146.1c, 295.F
melt/freeze pt: m.P/f.P text: n/given
vapor pres: not given
vapor density: not given
spec gravity: 1.140
evaporation rate & reference: < 1 (n-butyl acetate=1)
solubility in water: not given
appearance and odor: amber liquid, pungent odor
percent volatiles by volume: 30-35%

Reactivity

Stability indicator/materials to avoid: yes
strong oxidizing agents
stability condition to avoid: high temperatures, sparks, open flames,
direct sunlight
hazardous decomposition products: irritating, acrid fumes
conditions to avoid polymerization: may occur. Avoid elevated
temperatures.

Proper Disposal

Waste disposal methods: prevent waste from contaminating surrounding
environment. Discard any product, residue, disposal container or
liner in accordance with all federal, state and local regulations.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: no ingredient for this formulation_ingredient

Hazards

Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: yes osha: no
health hazards acute and chronic: skin: defating, dryness, irritation,
dermatitis, toxic absorption. Eye: irritation, serious injury,
lachrymation. Inhal: mucous membrane irritation, upper respiratory
tract discomfort, headache, nause a, insensibility, cns effects,
liver/kidney damage. Ingest: gi disturbances, pain, discomfort.

explanation of carcinogenicity: styrene oxide is a possible carcinogen.

First Aid

First aid: skin: wash w/soap and water. Eye: flush w/copious amounts of
water for 15 minutes. Get immed med aid. Inhal: remove to fresh
air. If unconscious give artificial respiration and/or oxygen as
needed. Ge t med aid. Ingest: dont induce vomit. Get immed med aid.

Chemical Properties

Boiling pt: b.P. Text: 295f,146c
vapor density: >air
spec gravity: 1.14
evaporation rate & reference: slower than buac
appearance and odor: amber clear liquid, pungent odor.

percent volatiles by volume: 30-35

Reactivity

Stability indicator/materials to avoid: yes
strong oxidizing agents and strong acids.

stability condition to avoid: heat & direct sunlight
hazardous decomposition products: irritating acrid fumes.

Proper Disposal

Waste disposal methods: comply w/applicable labeling, packaging, record
keeping standards. Dispose only in permited facility. For further
info call local solid waste agency or u.S. Epa rcra 1 (800)
424-9346.

disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.

Ingredients List

Ingred name: polyester resin
fraction by wt: 53.0%
other rec limits: none recommended

ingred name: styrene monomer (sara 313), oral rat ld50 5 g/kg, dermal
ld50 2820 g/kg rabbit, inhal lc50 24 g/m3/4 hr rat
cas: 100-42-5
rtecs #: wl3675000
fraction by wt: 50.0%
other rec limits: none recommended
osha pel: 50 ppm/stel 100
acgih tlv: 50 ppm/stel 100
epa rpt qty: 1000 lbs
dot rpt qty: 1000 lbs