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The last inventory check on this NSN was done on 04/16/2024. Due to rapid changes in inventory this may not be the current stock qty.
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Methanol (methyl alcohol)
Methanol (methyl alcohol)
Chemicals-organic
Y - Indicates information is in the hazardous materials information resource system (hmirs).
PMICA - Item does not contain precious metal.
CRITL- The item does not have a nuclear hardened feature or any other critical feature such as tolerance, fit restriction or application.
042690 - Alcohol amyl etc
530 - Toiletries, cologne, perfumes, antiseptics (flammable)
9 - Other or no special handling required (sh)
A - Shipment is not a consolidation and does not exceed 84 inches in any dimension.
C - Chemical corps items and all other chemicals not covered in other classificatons. note: when an item has a chemical proper shipp
R - Flammable liquids, un class 3 (flammable liquids label)
W - Rating variable
Questions & Answers: |
|
| What are the historical prices recorded for this stock number? | |
| Historical data shows pricing from $123.04 to $205.07.. | |
| Does NSN 6810-00-275-6010 have a shelf life? | |
| No. There is no shelf life applicable for this NSN. | |
| What NATO entities are users of this NSN? | |
| Department Of The Army, Department Of The Air Force, U.s. Marine Corps, Department Of The Navy, U.s. Coast Guard, Poland, Brazil, Spain, Singapore, Malaysia, Australia, Canada, Germany, Republic Of Korea, United Kingdom, Portugal, Greece, and Turkey | |
| What is the NIIN of NSN 6810-00-275-6010? | |
| 002756010 or 00-275-6010 | |
| Does NSN 6810-00-275-6010 require demilitarization? | |
| Yes - ITAR Controlled | |
| What is the most recent solicitation for NSN 6810-00-275-6010? | |
| No solicitations for this NSN. | |
| When was this national stock number assigned to the federal catalog? | |
| Jan 01, 1963 | |
Effects of overexposure: eyes: burns vision
failure.Skin: irritant,defatting agent.Inhal: irrit skin,mucous,resp
sys,headache
First aid: inhale: remove to fresh air, give cpr/o*2 if
need;eyes/skin: flush w lg amts h*2o for 15 min;ingest: rinse mouth;
get medical attention for eyes, breathing difficulty, or other
symptoms of overexposure.
Hcc: f2
boiling pt: b.P. Text: 148.5/64.7c
vapor pres: 100
vapor density: 1.11
spec gravity: 0.590
evaporation rate & reference: 12 (but acetat=1)
solubility in water: miscible
appearance and odor: clear,colorless,flammable,mobile,highly polar liq.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizing materials,chromic anhydrides,per chloric ac
stability condition to avoid: sparks,flames
hazardous decomposition products: formaldehyde,co,formic acid
Waste disposal methods: consult local authorities.Incineration or
disposal must be in accordance with local,state and federal
regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 99.8%
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: 5628 mg/kg oral rat.
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute-ingestion: harmful or fatal.
aspiration into lungs can cause chemical pneumonia and can be
fatal. Inhalation of mist may cause irritation of nose & throat.
eye: irritation. Skin: irritation. Chron ic-prolonged/repeated skin
contact may cause irritation, dermatitis.
explanation of carcinogenicity: none stated.
effects of overexposure: inhhaltion: excessive breathing of vapors may
cause nasal and respiratory irritation. Eyes: causes severe
irritation and blurred vision; skin: causes irritation. May be
harmful if absorbed through ski n. May cause an allergic skin
reaction on prolonged and repeated contact; ingestion: may be
harmful.Causes gi irritation
medical cond aggravated by exposure: individuals with kidney, eye, or
skin disorder may be at increased risk from exposure of this
material.
First aid: eye: flush with water 15 min. Skin: wash with soap & water.
inhaled: remove to fresh air. Give artificial respiration or oxygen
as needed. Ingested: do not induce vomiting. Give large quantity of
milk or water.(nothing by mouth if unconscious.)get immediate
medical attention. If any irritation persists or is severe,get
prompt medical care.
Hcc: f5
boiling pt: b.P. Text: 149f,65c
decomp temp: decomp text: 725f,385c
vapor pres: 97mmhg@20c
vapor density: 1.11
spec gravity: 0.792
evaporation rate & reference:
solubility in water: complete
appearance and odor: clear,colorless liquid
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizers.
stability condition to avoid: heat,sparks,flame.
hazardous decomposition products: chloroform,formaldehyde
Waste disposal methods: consult local authorities.Disposal must be in
accordance with local, state and federal regulations. See epa
disposal code for methanol for disposal procedures.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: >99%
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Effects of overexposure: eye: irrit. Skn: defatting.
inh: hdch,dizz,weak,gastro-intest/sight problems.
ing: drunk,drows,blindness
First aid: skin: wash w water.Eyes: flush w water.Inhaled: giv cpr/oxygen
if necessary.Ingest: immediately induce vomiting by having victim
drink soapy water.For all routes keep paticnt warm/cover eyes.Seek
medical attention.
Hcc: f2
boiling pt: b.P. Text: 148f,64c
vapor pres: 92
vapor density: 1.1
spec gravity: 0.79
evaporation rate & reference: 6.3(ether=1)
solubility in water: complete
appearance and odor: colorless liquid,mild alcohol odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidants,active metals,isocyanates.
stability condition to avoid: heat,ignition sources
hazardous decomposition products: combustion reported to yield co*2 &
co.
Waste disposal methods: eliminate ignition sources.Notify
authorities.Package and dispose in accordance with local,state and
federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 99.9%
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Effects of overexposure: weakness,headache,nausea,vomiting,abdominal
pain,dimness of vision,narcosis,coma,delirium,cyanosis
First aid: eyes: flush with water for minimum of 15 minutes.Skin
contact: remove all cntaminated clothing.Wash with soap &
water.Ingestion: induce vomiting,call doctor
immediately.Inhalation: remove to fresh air.If not
breathing,administer artificial respiration..
Hcc: f2
boiling pt: b.P. Text: 148f,64c
vapor pres: 92
vapor density: 1.11
spec gravity: 0.7924
evaporation rate & reference: 2.0,butyl acetate
solubility in water: complete
appearance and odor: clear,colorless liquid,slight alcoholic odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
all sources of ignition,oxidizing agents
stability condition to avoid: keep away from flames,sparks,electrical
shorts.
hazardous decomposition products: co,co*2
Waste disposal methods: may be incinerated in accordance with all local,
state, & federal regulations. Do not discharge into sewer systems.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 99.9%
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Effects of overexposure: eyes: mod irrit/burning;skin: absorbs thru.Causes
irrit/dermtits;inh: dizz brthg diff;ingest: see suppl
First aid: skin: wash w.Soap & h*2o eyes: flush w. H*2o. Ingested: give 2
glasses h*2o; induce vomiting.Call a physician. Inhale: remove to
fresh air. Give cpr/oxygen if need. Keep warm & quiet. Remove
contaminated clothing. If uncons do not take anythingby mouth.
Hcc: f2
boiling pt: b.P. Text: 149f
vapor pres: 96
vapor density: 1.11
spec gravity: 0.79
evaporation rate & reference: (ethyl ether=1).5
solubility in water: complete
appearance and odor: clear colorless liq.Faint alcohol odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizing agents.
stability condition to avoid: heat, ignition sources
hazardous decomposition products: incompletely burned carbon products,
co*2, co.
Waste disposal methods: incinerate in approved incinerator or dispose of
in approved chemical dump in accordance with local,state & federal
regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: >99%
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: oral rat: 6.2g/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
health hazards acute and chronic: acute: poisonous if swallowed;causes
blindness,narcosis,headache,nausea.
inhalation: narcosis,headache,nausea,giddiness & loss of
consciousness. Skin: drying,brittleness,cracking & irritation.
eyes: irrit ation,tearing & burning sensation. Chronic: systemic
poisoning,cns depression,blindness.
effects of overexposure: see health hazards data. Systemic effects may
cause liver or kidney damage.
medical cond aggravated by exposure: pre-existing conditions may be
worsen.
First aid: ingestion: induce vomiting of conscious patient;call a
physician immediately. Inhalation: remove to fresh air.Give cpr and
seek medical help immediately. Skin and eyes: flush with plenty of
water for abo ut 15 minutes and call a physician immediately.
Hcc: f5
boiling pt: =64.4c, 148.F
vapor pres: 96.0
vapor density: 1.11
spec gravity: 0.79
evaporation rate & reference: 1 (ether=1)
solubility in water: complete
appearance and odor: water-white liquid with a mild odor
percent volatiles by volume: 100.0
Stability indicator/materials to avoid: yes
none noted
stability condition to avoid: sparks,heat & flame
hazardous decomposition products: co and/or co*2
Waste disposal methods: dispose of collected material in accordance with
local,state & federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 99.85%
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: severe eye damage (blindness),
irritation, cns effects.
effects of overexposure: eye: irritation, burns, blindness, visual
disturbances. Skin: irritation. Inhalation: headache, drowsiness,
light headeness, inebriation. Ingestion: nausea, vomiting, gi tract
irritation.
medical cond aggravated by exposure: any preexisting allergy,
sensitivity, or organ dysfunction.
First aid: eye: flush 15 min w/ample water. Skin: wash soap & water.
inhalation: remove to fresh air, give oxygen or artificial resp as
required. Ingestion: if conscious, induce vomiting then give two
tablespoon baking soda in water. Call physician immediately and in
all exposures if symptoms persist.
Hcc: f5
boiling pt: =63.9c, 147.F
vapor pres: 96
vapor density: 1.1
spec gravity: 0.7925
evaporation rate & reference: 2.0 buac=1
solubility in water: complete
appearance and odor: water-white liquid, characteristic odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
oxidizers, aluminum, zinc, hydrogen forming metals; some plastics,
rubbers, coatings.
stability condition to avoid: excess heat & ignition sources
hazardous decomposition products: carbon oxides, formaldehyde.
Waste disposal methods: reclaim or incinerate iaw all laws & regs.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 99.85%
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: ld50=5628 mg/kg (rat)
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: cns & optic nerve
effects;headache,nausea,vomiting,dizziness;swallowing 100-250ml can
be fatal;visual disturbances;irritation of eyes &
skin.Chronic: dermatitis,systemic effects.
effects of overexposure: inhalation: headache,nausea,vomiting
dizziness,visual disturbances,giddiness.Sleepiness.
ingestion: 100-250ml can be fatal,can cause
blindness,dizziness,headache,nausea. Eyes: irritation,burns.
skin: irri tation;drying or defat
medical cond aggravated by exposure: pre-existing conditions may be
worsen.
First aid: eyes: flush w/plenty of water and call a physician
immediately.Skin: wash with soap and water. Inhalation: remove to
fresh air;call a physician. Ingestion: if conscious;induce
vomiting,get medical attenti on at once.
Hcc: f5
boiling pt: =64.4c, 148.F
vapor pres: 44.6
vapor density: 1.1
spec gravity: 0.79
solubility in water: complete
appearance and odor: clear & colorless
Stability indicator/materials to avoid: yes
strong oxidizing agennts,aluminum,zinc,metal,plastic,rubber,acids &
alkalies.
stability condition to avoid: heat,sparks,open flames.
hazardous decomposition products: co,co*2,formaldehyde and
unidentified,organic compound,black smoke.
conditions to avoid polymerization: unidentified
Waste disposal methods: dispose of collected material in accordance with
local,state and federal regs.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: >99%
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Effects of overexposure: irritation to the eyes,headache,fatigue &
drowsiness,central nervous system depression,death/eye dam
First aid: inhal: rmv to fresh air. If not brthng give cpr; if brthng
diff give oxygen. Eye: immed flush w/plenty of water. Skin: wash
w/soap&water. Rmv contam clthg&shoes. Ingest: induce vomit. Rpt
until vomit is c lear. Nothg by mouth if unconsc. Get medical attn.
Hcc: f5
boiling pt: =64.4c, 148.F
vapor pres: 130
vapor density: 1.11
spec gravity: 0.792
evaporation rate & reference:
solubility in water: complete
appearance and odor: colorless liquid-faintly sweet odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
matls reactg w/active h*2 will react w/ch*30h;anhydrides,na
stability condition to avoid: heat,ignition sources
hazardous decomposition products: form co on incomplete combustion
Waste disposal methods: wastes should be burned iaw local,state,federal
regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 99.9%
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: oral ld50 (rat) is 7.5 g/kg
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: ingest-can effect the optic
nerve & cause severe illness, possibly death. Inhale-can cause
unconsciousness. Skin-essentially non irritating. Eye-can cause
irritation & injury. Chronic: irritati on.
explanation of carcinogenicity: none of the chemicals in this product is
listed by iarc, ntp or osha as a carcinogen.
effects of overexposure: inhale-may cause stupor, headache, nausea,
dizziness. Ingest-can cause mental sluggishness, nausea, vomiting.
skin-may cause drying, brittleness, cracking. Eye-can cause tearing
& burning sensation.
medical cond aggravated by exposure: none
First aid: ingest-if conscious, induce vomiting. Give victim 2 glasses
of water & stick finger down throat. Call a doctor immediately.
inhale-move to fresh air. If stopped breathing, give cpr & oxygen
if needed. Call a doctor. Eyes/skin-immediately flush area with
plenty of cool water. Flush eyes for at least 15 min. Remove soiled
clothes. Call a doctor.
Hcc: f2
boiling pt: b.P. Text: 147f,64c
vapor pres: 96
vapor density: 1.11
spec gravity: 0.7925
evaporation rate & reference: 2.0, butyl acetate
solubility in water: complete
appearance and odor: clear, colorless, mobile liquid with mild alcohol
odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
sulfuric acid; oxidizing agents such as hydrogen peroxide, nitric acid,
perchloric acid & chromium trioxide.
stability condition to avoid: heat, sparks, flames.
hazardous decomposition products: carbon monoxide.
Waste disposal methods: incinerate or biological treatment in
federal/state approved facility in accordance with local, state and
federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 99.85%
other rec limits: none specified
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Effects of overexposure: inhalation harmful. Ingestion may be fatal or
cause blindness.May irritate eyes & skin.
First aid: skin & eyes: flush wuth water 15 min. If inhaled, remove to
fresh air & aid breathing if necessary. Ingestion: induce comiting
& see physician.
Hcc: f2
boiling pt: b.P. Text: 148f
vapor pres: 96
vapor density: 1.11
spec gravity: 0.7913
evaporation rate & reference:
solubility in water: complete
appearance and odor: colorless liquid with faint alcoholic odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizers
Waste disposal methods: flush to chemical sewer or incinerate.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 100%
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Effects of overexposure: irrit to skin &
eyes.Drowsy,li-head,nau,vomit,vis dist,eye burns,digestive
dist,failure of vision.
First aid: remove victim from exposure & apply artif. Rest. If
needed.Ingest: induce vomit,then give 2 teaspoons of baking soda in
glass of water;call md. Skin/eyes: flush with water for 15 min.
Hcc: f2
boiling pt: b.P. Text: 148f,64.5c
vapor pres: 97
vapor density: 1.11
spec gravity: 0.7928
evaporation rate & reference: 2.0 (bu ac)=1
solubility in water: appreciable
appearance and odor: clear,colorless liquid,alcohol odor
percent volatiles by volume: 100.
Stability indicator/materials to avoid: yes
al, mg, strong oxidizers
stability condition to avoid: heat, moisture
hazardous decomposition products: co, formaldehyde and other toxic gases
Waste disposal methods: inject into an incinerator under approved
operating procedures.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 99.9%
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Effects of overexposure: eyes: eye burns,failure of vision.Inhal: eye
irrit,headache,nause vomit.Ingest: poison.Skin: defat,irrit
First aid: if swallowed-give tablespoon of warm salt water,repeat until
vomit is clear give two teaspoonfuls of baking soda in glass of
water.Have patient lie down and keep warm.Cover eyes to exclude
light.Call doctor.
Hcc: f2
boiling pt: b.P. Text: 148f,64.5c
vapor pres: 96
vapor density: 1.1
spec gravity: 0.79
evaporation rate & reference: 2.0 (bu ac=1)
solubility in water: complete
appearance and odor: colorless liquid,alcohol or pungent odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
al, mg, strong oxidizers
stability condition to avoid: heat, moisture
hazardous decomposition products: co, formaldehyde and other toxic gases
Waste disposal methods: absorb in vermiculite,dry sand, earth or similar
material. Dispose in secured sanitary landfill in accordance w/fed.
state. State & local regs. Or can atomize suitable combustion
chamber.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 100%
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: ld50 is about 5800 mg/kg (rat)
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eyes: can cause severe irritation.
skin: prolonged or repeated contact can cause moderate irritation.
inhalation: respiratory irritation, central nervous system effects,
death. Ingestion: may cause ga strointestinal irritation,
blindness, death.
explanation of carcinogenicity: methanol is not currently listed as
carcinogenic by ntp, iarc or osha.
effects of overexposure: eyes: redness, tearing, blurred vision. Skin:
defatting, dermatitis. Inhalation: nasal irritation, dizziness,
weakness, fatigue, nausea, vomiting, diarrhea, unconsciousness,
death. Ingestion: nausea, vomiting, diarrhea, blindness, death.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: if on skin: thoroughly wash exposed area with soap and water.
remove contaminated clothing. Launder contaminated clothing before
reuse. If in eyes: flush with large amounts of water, lifting upper
and lower lids. Get medical attention. If swallowed: immediately
drink 2 glasses of water and induce vomiting. Never give anything
by mouth to an unconscious person. If inhaled: remove to fresh air.
Hcc: f2
boiling pt: b.P. Text: 147f,64c
vapor pres: 97.68@ 68f
vapor density: 1.1
spec gravity: .793@ 68f
evaporation rate & reference: 5.91 (n-butyl acetate=1)
solubility in water: appreciable
appearance and odor: clear colorless liquid
percent volatiles by volume: 100 %
Stability indicator/materials to avoid: yes
avoid contact with strong oxidizing agents.
stability condition to avoid: none specified with manufacturer.
hazardous decomposition products: may form toxic materials, carbon
dioxide, carbon monoxide, various hydrocarbons, etc.
Waste disposal methods: allow volatile portion to evaporate in hood.
allow sufficient time for vapors to completely clear hood duct
work. Dispose of contaminated absorbent in accordance with local,
state and federal regulati ons. Incinerate liquid iaw local, state&
fed regs
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 100% %
other rec limits: none specified
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: ld50 oral rat=5628mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: see signs & symptoms of
overexposure chronic: marked impairment of vision and enlargement of
the liver has been reported.Repeated or prolonged exposure may
cause skin irritation
effects of overexposure: eyes: irritant,eye lesion;skin: defatting,
dryness,cracking;skin absorption: symptoms similar to
inhalation;inhalation: irritant,toxic to nervous system & optic
nerve,headache,drowsiness,nausea, vomit,bl urred
vision,blindness,coma,death,ingestion: symptoms similar to
inhalation,can cause blindness.Fatal dose=100-125ml
medical cond aggravated by exposure: person with pre-existing skin
First aid: eyes: flush with plenty of water.See docto
immediate;skin*remove contaminated clothing.Wash with plenty soap &
water if irritation persists,see doctor;inhalation: remove to fresh
air.Give cpr/ oxygen ne eded.See doctor;ingestion: give 2 glassesof
water & induce vomit immediately.See doctor immediately.Nothing by
mouth if unconscious.
Hcc: f5
boiling pt: =64.4c, 148.F
melt/freeze pt: =-97.8c, -144.F
vapor pres: 97
vapor density: 1.1
spec gravity: 0.8
evaporation rate & reference: 5.9 (butyl acetate=1)
solubility in water: complete
appearance and odor: clear,colorless liquid.Characteristic odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizing agents. Will attack some forms of plasti
rubber,coating. May react with metallic al to form haz gas.
stability condition to avoid: heat,sparks,open flames.
hazardous decomposition products: co,co*2,formaldhyde
Waste disposal methods: dispose as hazardous waste in a rca approved
facility.Not flush to sewer.Comply with all applicable
federal,state & local envirinmental regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 100%
other rec limits: none
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: oral ld50 (rat) is 5.6 g/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: ingest-can effect the optic
nerve & cause severe illness, possibly death. Inhale-can cause
unconsciousness. Skin-essentially non irritating. Eye-can cause
irritation & injury. Chronic: irritati on.
explanation of carcinogenicity: none of the chemicals in this product is
listed by iarc, ntp or osha as a carcinogen.
effects of overexposure: inhale-may cause stupor, headache, nausea,
dizziness. Ingest-can cause mental sluggishness, nausea, vomiting.
skin-may cause drying, brittleness, cracking. Eye-can cause tearing
& burning sensation.
medical cond aggravated by exposure: none
First aid: ingest-if conscious, induce vomiting. Give victim 2 glasses
of water & stick finger down throat. Call a doctor immediately.
inhale-move to fresh air. If stopped breathing, give cpr & oxygen
if needed. Call a doctor. Eyes/skin-immediately flush area with
plenty of cool water. Flush eyes for at least 15 min. Remove soiled
clothes. Call a doctor.
Hcc: f2
vapor pres: 96
vapor density: 1.11
spec gravity: 0.7925
evaporation rate & reference: 2.0, butyl acetate
solubility in water: complete
appearance and odor: clear, colorless, liquid with mild alcohol odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
sulfuric acid; oxidizing agents such as hydrogen peroxide, nitric acid,
perchloric acid & chromium trioxide.
stability condition to avoid: heat, sparks, flames.
hazardous decomposition products: carbon monoxide.
Waste disposal methods: incinerate or biological treatment in federal/
state approved facility in accordance with local, state and federal
regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 99.85%
other rec limits: none specified
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
hcc: f5
b.P. Text: 149f,65c
m.P/f.P text: -144f,-98c
decomp text: unknown
vapor pres: 98
vapor density: 1.1
spec gravity: 0.79
evaporation rate & reference: unknown
solubility in water: appreciable
appearance and odor: colorless liquid with alcohol odor
corrosion rate: unknown
product id: methanol, technical
cage: lo084
assigned ind: y
company name: bought to spec by defense general supply center
street: 8000 jefferson davis hwy
city: richmond va
zipcode: 23297-5680
label required ind: y
date of label review: 09/02/1992
status code: c
label date: 09/02/1992
origination code: f
chronic hazard ind: y
eye protection ind: yes
skin protection ind: yes
signal word: danger
respiratory protection ind: yes
health hazard: severe
contact hazard: moderate
fire hazard: severe
=======================================================
responsible party cage: lo084
trans id no: 65167
product id: methanol, technical
msds prepared date: 09/02/1992
review date: 02/29/1996
mfn: 1
net unit weight: 32.9 lbs
multiple kit number: 0
review ind: y
unit of issue: cn
container qty: 1
type of container: can
Hazard and precautions: poisonous; may be fatal if inhaled, swallowed or
absorbed through skin. Contact may cause irritation to skin and eyes. Runoff
from fire control or dilution water may cause pollution. Flammable materia l.
container may explode in heat of fire. Store in a cool dry area away from
sources of ignition. First aid: inhalation: remove to fresh air. Eyes: flush
with lots of water for 15 minutes. See doctor. skin: wash with soap and
water. Ingestion: rinse mouth, get immediate medical attention.
Ld50 lc50 mixture: tlv 200 ppm (ceiling limit)
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: none specified by manufacturer.
explanation of carcinogenicity: this compound contains no ingredients at
concentrations of 0.1% or greater that are carcinogens or suspect
carcinogens.
effects of overexposure: poisioning, headache, nausea, bilndness.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: eye and skin: immediately and continuously flush with flowing
water.
Hcc: f5
boiling pt: =63.9c, 147.F
melt/freeze pt: =-97.2c, -143.F
vapor pres: 97 mmhg
vapor density: 1.11
spec gravity: 0.8
evaporation rate & reference: 5 (n-butyl acetate=1)
solubility in water: complete
appearance and odor: colorless liquid, clear, slight alcohol odor.
percent volatiles by volume: 100%
Stability indicator/materials to avoid: yes
oxidizing materials: perchloric acid; sodium hydroxide and chloroform.
hazardous decomposition products: combustion may produce carbon
monoxide.
Waste disposal methods: incinerate or landfill in accordance with local,
state and federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
other rec limits: none recommended
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: oral ld50 (rat) is 5628 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eyes: irritation, stinging, tearing,
and redness. Skin: irritation, redness, burning, and drying.
inhalation; irritation of nose, throat, and signs of nervous system
depression. Ingestion: irritation of digestive tract, nervous
system depression, visual disturbances (including blindness),
convulsions, coma, and death.
effects of overexposure: eyes: irritation, stinging, tearing, redness.
skin: irritation, burning, drying, cracking. Inhalation: irritation
of nose and throat, headache, drowsiness, dizziness, loss of
coordination. Ingestion: irritation of gi tract, headache,
drowsiness, dizziness, visual disturbances, blindness, convulsions,
coma, and death.
medical cond aggravated by exposure: individuals with pre-existing
disease involving the eyes, skin, respiratory tract may be at
increased risk from exposure.
First aid: eyes: flush with large amounts of water. If symptoms persist
get medical attention. Skin: remove contaminated clothing. Wash
area with mild soap and water. If irritation persist get medical
attention. Inhalation: move to fresh air. If not breathing give
cpr. If breathing difficult give oxygen. Get medical attention.
ingestion: induce vomiting. Get medical attention.
Hcc: f2
boiling pt: b.P. Text: 148f,64c
vapor pres: 96
vapor density: 1.1
spec gravity: 0.792
evaporation rate & reference: 3.5 (n-butyl acetate=1)
solubility in water: complete
appearance and odor: clear liquid. Little if any color. Characteristic
odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizers, strong acids and bases.
stability condition to avoid: avoid all sources of ignition; sparks,
heat, fire. Avoid oxidizing conditions.
hazardous decomposition products: carbon monoxide, carbon dioxide.
conditions to avoid polymerization: will not occur.
Waste disposal methods: dispose of waste product in accordance with
local, state and federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 100%
other rec limits: none specified
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: tlv: 200 ppm (ceiling limit)
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: swallowing: coma and death. Ingestion
of as little as 10 ml has caused blindness, with massive overdoses,
liver, kidney and heart muscle injury. Skin: may cause defatting of
the skin. Eye: may cause t ransient superficial injury of the
cornea.
explanation of carcinogenicity: this compound contains no ingredients at
concentrations of 0.1% or greater that are carcinogens or suspect
carcinogens.
effects of overexposure: swallowing: nausea, abdominal pain, vomiting,
headache, dizziness, shortness of breath, weakness, fatigue, leg
cramps, restlessness, confusion, druken behavior. Inhalation: may
cause dizziness, drowsi ness, pains in arm & hands. Skin: may cause
reddening. Eye: may cause mild redness & swelling of the
conjunctive.
medical cond aggravated by exposure: due to the defatting properties,
methanol may aggravate an existing skin condition, .Eg.Exzema. Due
to its liver and kidney-injuring potential, may excerbate existing
liver and/or kidney disease.
First aid: swallowing-if conscious & has a gag reflex, give 2 glasses of
water, induce vomiting. Call a physician urgently. Give ethanol
(whiskey, brandy, etc) 30 ml every 3 hrs. Skin-remove clothing.
flush skin with water. Inhalation-remove to freshair. Perform cpr,
if not breathing. Oxygen give by medical personnel if hard to
breath. Eyes-flush with water for several minutes. See physician.
Hcc: f5
boiling pt: b.P. Text: 147f,64c
melt/freeze pt: m.P/f.P text: -143f,-97c
vapor pres: 96 mmhg
vapor density: 1.1
spec gravity: 07922
evaporation rate & reference: 5 (n-butyl acetate=1)
solubility in water: 100%
appearance and odor: water-white liquid; characteristic odor.
percent volatiles by volume: 100%
Stability indicator/materials to avoid: yes
alkali metals, concentrated nitric acid, sulfuric acids, aldehydes,
octyl chlorides.
stability condition to avoid: ignition sources.
hazardous decomposition products: burning can produce carbon monoxide
and/or carbon dioxide.
Waste disposal methods: incinerate in a furnance where permitted under
appropiate local, state and federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 100%
other rec limits: none recommended
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: none specified by manufacturer.
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eyes: can cause severe irritation.
skin: prolonged contact can cause reddening and defatting of the
skin. Inhalation: may cause dizziness, drowsiness, disturbances of
vision, numbness. Ingestion: mode rate quantities can produce
metabolic acidosis. Onset of symptoms may be delayed up to 48
hours. 60-200 ml is fatal dose
explanation of carcinogenicity: none specified by manufacturer.
effects of overexposure: eyes: redness, tearing, blurred vision. Skin:
defatting, dermatitis. Inhalation: nasal irritation, dizziness,
weakness, fatigue, nausea, vomiting, diarrhea, unconsciousness,
death. Ingestion: nausea, vomiting, diarrhea, blindness, death.
medical cond aggravated by exposure: existing skin condition, liver
and/or kidney diseases.
First aid: if on skin: thoroughly wash exposed area with soap and water.
remove contaminated clothing. Launder contaminated clothing before
reuse. If in eyes: flush with large amounts of water, lifting upper
and lower lids. Get medical attention. If swallowed: immediately
drink 2 glasses of water and induce vomiting. Never give anything
by mouth to an unconscious person. Inhalation: remove to fresh air.
Hcc: f2
boiling pt: =63.9c, 147.F
vapor pres: 96 @ 20c
vapor density: 1.1
spec gravity: .7925
evaporation rate & reference: 5.8 (butyl acetate=1)
solubility in water: complete
appearance and odor: clear colorless mobile liquid with mild alcohol
odor.
Stability indicator/materials to avoid: yes
alkali metals, concentrated nitric and sulfuric acids, aldehydes, acyl
chlorides.
stability condition to avoid: ignition sources
hazardous decomposition products: carbon dioxide and carbon monoxide
Waste disposal methods: incinerate in a furnace where permitted under
appropriate federal, state and local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 100% %
other rec limits: none specified
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: oral ld50 (rat) is 9100 mg/kg.
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: eyes: irritation but usually no
permanent tissue damage. Skin: irritation, dryness, dermatitis,
arythema, same symptoms as inhalation. Inhalation: dizziness,
nausea, visual impairment, respiratory fai lure, incoordination,
narcosis, liver damage, death. Ingestion: blindness, dizziness,
headache, death.
explanation of carcinogenicity: this chemical is not listed as having
any evidence of being carcinogenic.
effects of overexposure: eyes: irritation. Skin: irritation, dryness,
dermatitis, arythema, same symptoms as inhalation. Inhalation:
dizziness, nausea, visual impairment, respiratory failure,
incoordination, narcosis, liver d amage, death. Ingestion:
blindness, dizziness, headache, death.
medical cond aggravated by exposure: persons with pre-existing disease
involving the eyes, skin, respiratory system, kidney and liver may
be at increased risk from exposure to this material.
First aid: eyes: flush with large amounts of water. If irritation
persists get medical attention. Skin: remove contaminated clothing.
wash area with soap and water. Inhalation: move to fresh air. Give
oxygen or cpr as needed. Get medical attention. Ingestion: drink
large amounts of water, milk, or sodium bicarbonate to dilute
material in stomach. Induce vomiting. Get medical attention.
Hcc: f3
boiling pt: b.P. Text: 148f,64c
vapor pres: 96 mm hg
vapor density: 1.11
spec gravity: 0.79
evaporation rate & reference: 4.5 (bu ac=1)
solubility in water: total
appearance and odor: clear, colorless liquid. Faint alcohol odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
avoid strong oxidizing agents.
stability condition to avoid: excessive heat, open flames and other
sources of ignition.
hazardous decomposition products: carbon monoxide, carbon dioxide,
formaldehyde and other toxic gases may be formed in a fire.
conditions to avoid polymerization: will not occur.
Waste disposal methods: dispose of waste in accordance with local, state
and federal regulations. Waste should be disposed of by a licensed
waste disposal company. If permitted, waste liquid may be burned in
an approved inci nerator.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 99.9%
other rec limits: none specified
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 94
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: oral ld50 (rats) = 9100 mg/kg
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: prolonged inhalation of vapors causes
central nervous system disturbances, respiratory failure, narcosis,
liver damage, death. Repeated or prolonged skin contact causes
drying, brittleness, cracking, irritation. May cause eye temporary
eyeinjury. Poisonous if swallowed. Can effect the optic nerve
resulting in blindnes
explanation of carcinogenicity: this compound contains no ingredients at
concentrations of 0.1% or greater that are carcinogens or suspect
carcinogens.
effects of overexposure: dizziness, nausea, visual impairment,
respiratory failure, muscular incoordination, narcosis, death,
liver damage, skin irritation/dryness/brittleness/cracking, eye
irritation/tearing/burning, blindne ss, mental sluggishness,
nausea, vomiting.
medical cond aggravated by exposure: methanol exposure may aggravate
existing eye, skin, kidney and liver disorders.
First aid: inhalation: remove from exposure. Restore breathing. Keep
warm and quiet. Get medical attention. Skin: wash affected area
thoroughly with soap and water. If irritation persists, get medical
attention. Eyes: flush with large amounts of water for 15 minutes.
get medical attention. Ingestion: induce vomiting of conscious
patient immediately. Call physician immediately.
Hcc: f5
boiling pt: b.P. Text: 148f,65c
melt/freeze pt: m.P/f.P text: not given
vapor pres: 138
vapor density: 1.1
spec gravity: 0.791
evaporation rate & reference: > 1 (no reference given)
solubility in water: complete
appearance and odor: clear, colorless liquid
percent volatiles by volume: 100 %
Stability indicator/materials to avoid: yes
strong oxidizing agents, chromic anhydride, lead perchlorate,
perchloric acids.
stability condition to avoid: sparks, heat, open flames, ignition
sources
hazardous decomposition products: none specified by manufacturer.
Waste disposal methods: prevent waste from contaminating surrounding
environment. Discard any product, residue, disposal container or
liner in accordance with all federal, state and local regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 99.9%
other rec limits: none recommended
osha pel: s,200ppm
acgih tlv: s,200ppm/250stel; 94
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ingred name: non hazardous ingredient
fraction by wt: 0.1%
other rec limits: none recommended
Ld50 lc50 mixture: oral ld50 (rat) is 13000 mg/kg
routes of entry: inhalation: yes skin: no ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute: inhalation may cause
respiratory irritation; higher concentrations may cause cns
effects. Eye contact may cause irritation. Swallowing may cause
blindness, headache, nausea; 1-4 ounces may caus e death. Chronic:
prolonged or repeatedexposure may cause dermatitis.
explanation of carcinogenicity: methanol is not listed ny ntp or iarc as
a carninogen or suspected carcinogen.
effects of overexposure: inhaled: sneezing, sore throat, wheezing,
shortness of breath, headache, nausea. Skin: redness, dryness,
cracking. Eyes: redness, tearing, burning/stinging sensation.
ingested: nausea, vomiting, diarr hea, blindness, dizziness,
headache.
medical cond aggravated by exposure: inhalation may worsen the effects
of emphysema and bronchitis.
First aid: eyes-flush with lots water for 15 minutes while holding
eyelids open.Get medical attention.Skin-wash with soap & water.If
irritation occurs,get medical attention.Inhalation-remove to fresh
air.Restore breathing as required.Get medical
attention.Ingestion-if conscious,give water or milk to drink &
induce vomiting. Transport to medical attention immediately.
Hcc: f5
boiling pt: b.P. Text: 148f,65c
melt/freeze pt: m.P/f.P text: -144f,-98c
vapor pres: 96mmhg@20c
vapor density: 1.105
spec gravity: 0.792
evaporation rate & reference: 4.6 (n-butyl acetate=1)
solubility in water: complete
appearance and odor: clear, colorless, liquid with no suspended matter.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizing agents.
stability condition to avoid: avoid excessive heat, sources of ignition
and strong oxidizing agents.
hazardous decomposition products: carbon monoxide, carbon dioxide and
formaldehyde.
conditions to avoid polymerization: will not occur.
Waste disposal methods: waste must be disposed of in accordance with
local,state and federal regulations.Contact proper authorities for
instructions or agcl's emergency number (403-527-8141 in
canada).Dla-hmis: epa/rcra waste numbers d001 & u154 may apply to
unusedproduct.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 99.85%
other rec limits: none recommended
osha pel: s,200ppm
acgih tlv: s,200ppm/250stel; 94
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: ld50 (orl rat) is 5628 mg/kg (rtecs).
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: eye, skin, cns,
respiratory & gi tracts. Acute- toxic. Can cause eyes, skin,
respiratory tract irritation & cns depression. Aspiration damage
lungs. Skin absorption can occur. Ingestion of only 1-4 ounces may
cause death/blindness. Chronic- methanol is slowly eliminated from
body causing toxicity.
explanation of carcinogenicity: methanol has been reported to cause
birth defects in rats exposed to very high concentrations (20,000
ppm), per msds.
effects of overexposure: irritation, tearing. Burning sensation, drying
skin, defatting, dizziness, nausea, vomiting, drowsiness, headache,
fatigue, convulsions, unconsciousness, death, blindness, swelling
of eyes and redness
medical cond aggravated by exposure: individuals with pre-existing
diseases of the eye, skin, respiratory tract, liver, kidney, cns
may have increased susceptibility to the toxicity of excessive
exposures.
First aid: eye: immediately flush with water for 15 minutes. Hold eyelids
open. See physician. Skin: wash affected area with soap & water. If
irritation persists, see doctor. Inhaled: remove to fresh air.
provide c pr/oxygen if needed. Obtain emergency medical help.
oral: if conscious, immediately induce vomiting by drinking water &
pressing finger down throat. Call a physician/poison control center
immediately.
Hcc: f5
nrc/state lic num: not relevent
boiling pt: b.P. Text: 148f,65c
melt/freeze pt: m.P/f.P text: -144f,-98c
decomp temp: decomp text: not known
vapor pres: 96 @ 68f
vapor density: 1.1
spec gravity: 0.79
viscosity: 1 cps @ 86f
evaporation rate & reference: 5.9 (n-butyl acetate=1)
solubility in water: 100%
appearance and odor: clear, colorless liquid - alcoholic odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizing agents, aluminum, zinc (galvanized), any other
reactive metal which displace h2, some plastics/rubber
stability condition to avoid: heat, flame, sparks, other ignition
sources
hazardous decomposition products: carbon monoxide, carbon dioxide and
perhaps formaldehyde
Waste disposal methods: dispose in accordance with all applicable local,
state and federal regulations. Epa hazardous waste number is u154
(toxic waste). Rq for methanol is 5000 lbs. Preferred method is
incineration or biolo gical treatment in an approved facility.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara 313) (cercla)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 99.9%
other rec limits: none recommended
osha pel: s, 200 ppm
acgih tlv: s,200ppm/250stel; 95
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: osha twa 200ppm, 260mg/m3
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: ingest: may be fatal.Cannot be made
non-poisonous.Swallowing liq causes inebriation, headache, nausea,
vomiting leading to severe illness, blindness & perhaps death.
eye: liq causes irrit. Inhal: breathi ng vap may cause drowsiness,
nau, vomiting. Skin: repeated contact may irritate skin.
effects of overexposure: fatal if ingested. Inebriation, headache,
nausea, vomiting. Severe illness. Blindness. Death. Eye/skin
irritation. Drowsiness.
medical cond aggravated by exposure: none specified by manufacturer.
First aid: ingest: if consc give 1 or 2 glasses of water to drink.Induce
vomit by placing finger down throat.Repeat til vomit fluid is
clear.Call dr immed.Never give anything by mouth to unconsc
person.Inhal: remo ve to fresh air.Not breath give arti
resp(mouth-to-mouth)breath diffi give oxy by trained personnel.Call
dr.Eye: flush w/plenty of water for @least 15mins lifting
eyelids.Get med attn immed.(supplemen)
Hcc: f5
boiling pt: b.P. Text: 148f,65c
melt/freeze pt: m.P/f.P text: -144f,-98c
vapor pres: 96 @20c
vapor density: 1.11
spec gravity: 0.7913
evaporation rate & reference: 12.5% (n-butyl acetate=1)
solubility in water: complete
appearance and odor: clear, colorless liquid, alcohol odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
strong oxidizing agents. Particularly perchloric acid & lead
perchlorate, sulfuric & nitric acids, chromic anhydride.
stability condition to avoid: sparks, excessive heat, sources of
ignition, open flame, static charge.
hazardous decomposition products: thermal decomposition or burning will
produce carbon dixoide &/or carbon monoxide.
Waste disposal methods: discharge/treatment/disposal may be subject to
fed/state/loc laws.These disposal guidelines are intended for
disposal of catalog-size quant only.Dispose of in an approved
incinerator or contract w/lic ensed solvent waste disposal service.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 100%
other rec limits: none recommended
osha pel: s,200ppm
acgih tlv: s,200ppm/250stel; 94
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: ld50 (orl rat) is 5628 mg/kg (rtecs).
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: liver. Acute: human
health effects of overexposure by inhalation, ingestion, or skin or
eye contact may include nonspecific discomfort; and temporary
nervous system depression with ane sthetic effects. Higher
exposures may lead to abnormal liver function. Ingestion of as
little as 60 ml may cause blindness or fatality. Skin permeation
can occur in amounts capable of producting syste ms toxicity.
effects of overexposure: human health effects of overexposure by
inhalation, ingestion, or skin or eye contact may include
nonspecific discomfort such as nausea, or weakness; and temporary
nervous system depression with anest hetic effects such as
dizziness, headache, confusion, incoordination, and loss of
consciousness; or blindness.
medical cond aggravated by exposure: individuals with preexisting
diseases of the retina or liver may have increased susceptibiltiy
to toxicity of excessive exposure.
First aid: eye: immediately flush with water for 15 minutes. Hold eyelids
open. See physician. Skin: wash affected area with soap & water. If
irritation persists, see doctor. Inhaled: remove to fresh air.
provide c pr/oxygen if needed. Obtain emergency medical help.
oral: if conscious, immediately induce vomiting by drinking water &
pressing finger down throat. Call a physician/poison control center
immediately.
Hcc: f5
boiling pt: =64.7c, 148.3f
b.P. Text: at 760 mm hg
melt/freeze pt: =-97.7c, -143.8f
vapor pres: 127 mmhg @ 77 deg f
vapor density: 1.1(air=1)
spec gravity: 0.791 @ 68 deg f
evaporation rate & reference: >1 (n-butyl acetate=1)
solubility in water: 100 wt %
appearance and odor: liquid, colorless or clear, faint alcoholic
Stability indicator/materials to avoid: yes
do not store or mix with strong oxidizers, chronic anhydride, lead
perchlorate, or perchloric acid (reacts vigorously).
stability condition to avoid: none provided by mfr.
hazardous decomposition products: none provided by mfr. (mfr stated:
occurs from heat and reaction with above stated materials)
Waste disposal methods: cleaned up material may be an rcra hazardous
waste. The rcra hazardous waste number for methanol is u154. Comply
with federal, state, and local regulations on disposal. If approved
incineration, bio-o xidation, subsurface injection, or a licensed
disposal contractor may be used.
Ingred name: methyl alcohol (methanol) (sara 313) (cercla)
cas: 67-56-1
rtecs #: pc1400000
= wt: 100.
other rec limits: none recommended
osha pel: s, 200 ppm
acgih tlv: s,200ppm/250stel; 95
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: methyl alcohol is toxic mainly to the
nervous system, particularly optic nerves, where damage can
progress to permanent blindness. Poisoning in metabolic acidosis.
methyl alcohol oxidizes in the body to form formaldehyde & formic
acid. These derivatives are believed responsible for many of methyl
alcohol's poisonous & toxic effects. Since it is eliminated slowly
from the body, methyl alcohol is c onsidered a cumulative poison.
the fatal ingestion dose is 100-250 ml, although death is reported
from less than 33ml. Target organs: eyes,central nervous sys,skin,
digestive tract.
explanation of carcinogenicity: in 1990 reports, the iarc, ntp & osha do
not list methyl alcohol as a carcinogen.
effects of overexposure: inhal: eye/nose irrit,head,ftg,nau,visual
impair(optic nerve neuropathy,visual field
changes),blind,acidosis,convul,circul collapse,resp
failure,death.Ingest: gi irrit,kidney impair.Skin: coldness feel,d
ryness,crack,derm.Absorb thru skin,head,ftg,visual
disturb.Eye: irrit,watering,inflamm lids,pain sens to light.
medical cond aggravated by exposure: none reported.
First aid: eye: lift eyelids & flush immediately & continuously with
flooding amounts of water until transported to an emergency medical
facility. Do not let victim rub or keep eyes tightly shut.Consult a
physici an immediately. Skin: quickly remove contaminated clothing.
rinse w/flooding amts of water for at least 15mins. For
red/blistered skin, see physician. Wash w/soap & water.
inhalation: remove to fresh air & support breath as needed.
ingestion: never give anything by mouth to an unconscious or
convulsing person. Conscious & alert give 1-2 glasses of water then
induce vomiting.
Hcc: f3
boiling pt: =64.4c, 148.F
melt/freeze pt: =-97.6c, -144.F
decomp temp: decomp text: np
vapor pres: 29mm @68f
vapor density: 1.11
spec gravity: 0.7924 @68f
ph: np
viscosity: 0.00593p @68f
evaporation rate & reference: np
solubility in water: soluble.
appearance and odor: clear,colorless,volatile liq w/slight alcohol odor
when pure,disagreeably(suppl
Stability indicator/materials to avoid: yes
beh2,metals,oxidants,(ch3)3cok,ccl4+metals,chcl3+heat,zn(c2h5)2,alkyl
al salts,ch3cobr,chcl3+naoh,c3n3cl3,hno3.
stability condition to avoid: avoid vapor inhalatiion & contact with
oxidiziers & other incompatibles. Hmis: all ignition
sources,flame,etc.
hazardous decomposition products: thermal oxidative decomposition of
methyl alcohol can produce carbon oxides(co,co2),possible
formaldehyde, acrid smoke, and irritating fumes.
Waste disposal methods: contact supplier or a licensed contractor for
detailed recommendations. Follow applicable federal, state, local
regulations. Rcra haz waste#u154. Air contaminant (20cfr1910.1000
table z-1-a).
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol
cas: 67-56-1
rtecs #: pc1400000
= wt: 100.
code: f
other rec limits: none recommended
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: ld50(oral rat) 5628 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: no
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: acute exposure: methanol is a
poisonous, narcotic chemical that may exert its effects through
inhalation, skin absorption or ingestion. Body elimination of
methanol is slow, and the toxic effects can be compounded by
repeated excessive exposures over several days. Chronic exposure:
impaired vision.
explanation of carcinogenicity: this product is not listed by iarc, ntp
or osha as a carcinogen, mutagen, teratogen or neurotoxin.
effects of overexposure: toxic effects are exerted upon the nervous
system, expecially the optic nerve. Ingestion can produce
blindness. Symptoms include dizziness, blurring of vision, nausea,
cardiac depression, muscular inc oordination and narcosis. Solvent
actioncan dry the skin and cause dermatitis.
medical cond aggravated by exposure: may aggravate existing skin
disorders.
First aid: inhalation: remove to fresh air. Treat symptomatically. If
symptoms persist, get medical attention. Eyes: immediately flush
with running water for 15 minutes. Get medical attention. Skin:
immediately flush with water while removing contaminated clothing.
if irritation develops, get medical attention. Ingestion: if
conscious, give glass of water to drink & induce vomiting. Get
medical attention.
Hcc: f2
boiling pt: b.P. Text: 148f,64c
melt/freeze pt: m.P/f.P text: -144f,-98c
vapor pres: 100 @ 21c
vapor density: 1.11
spec gravity: 0.7928
evaporation rate & reference: 1 (ccl2=1)
solubility in water: complete
appearance and odor: clear, colorless liquid - characteristic alcohol
odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
alkali metals, strong bases, strong oxidizers
stability condition to avoid: high heat, sparks, open flames and other
sources of ignition
hazardous decomposition products: carbon monoxide and carbon dioxide
Waste disposal methods: dispose of large quantities of waste via a
licensed waste solvent disposal company, or reclaim via filtration
and distillation procedures. It can be incinerated in accordance
with local, state and fed eral regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara iii)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: 100.00%
other rec limits: none recommended
osha pel: s,200ppm/250stel
acgih tlv: s,200ppm/250stel; 93
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: ld50 (oral rat) is 5.6 g/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: may cause blindness.Harmful if
swallowed or inhaled. It is a defatting agent, can cause dermatitis
and liver damage. May cause blurred vision and blindness if
swallowed. Also reported to cause shootin g pains in the lower
extremities and multiple neuritis,characterized by numbness of the
skin and pain in hands,forearms.
explanation of carcinogenicity: none
effects of
overexposure: headaches,weakness,drowsiness,lightheadedness,nausea,v
omiting,drunkenness,eye irritation,blurred vision.Liver
toxicity,skin defatting,dermatitis,vertigo,chills,unsteady
gait,edema of arms,gastric pain ,insomnia,changes in color
perception,double vision,blindness,pain in lower
extremities,multiple neuritis,sleep problems
medical cond aggravated by exposure: persons with existing skin, kidney,
liver, or eye disorders may be at increased risk when exposed to
methanol. Methanol may enhance the toxicity of carbon monoxide.
First aid: eyes: flush with large amounts of water. Get medical
attention. Skin: remove contaminated clothing. Wash skin with soap
and water. If irritation persists, get medical attention.
inhalation: move to fr esh air. Give cpr if not breathing. Give
oxygen if breathing difficult. Get medical attention. Ingestion:
induce vomiting,then give 2 teaspoons of baking soda in glass of
water. Get medical attention.
Hcc: f5
boiling pt: b.P. Text: 147f,64c
melt/freeze pt: m.P/f.P text: -143f,-97c
decomp temp: decomp text: not known
vapor pres: 96mm/20c
vapor density: 1.1
spec gravity: 0.792
solubility in water: 100%
appearance and odor: clear, colorless liquid, faint alcoholic odor.
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
oxidizers, aluminum, zinc, hydrogen replacement metals, rubber, chromic
anhydride, lead perchlorate, perchloric acids.
stability condition to avoid: stable under normal conditions.
hazardous decomposition products: excessive heating and/or incomplete
combustion will produce carbon monoxide and toxic vapors such as
formaldehyde.
conditions to avoid polymerization: will not occur.
Waste disposal methods: report methanol spills over rq (5000 lbs) to the
national response center (800-424-8802). Dispose of all spill
material in accordance with local, state, and federal regulations.
disclaimer (provided with this information by the compiling agencies):
this information is formulated for use by elements of the department
of defense. the united states of america in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.
Ingred name: methyl alcohol (methanol) (sara 313) (cercla)
cas: 67-56-1
rtecs #: pc1400000
fraction by wt: >99.85%
other rec limits: s,200ppm,8/12 hr twa
osha pel: s, 200 ppm
acgih tlv: s,200ppm/250stel; 95
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: not provided.
health hazards acute and chronic: eye: may cause irritation. Direct
contact may cause pain, corneal inflammation and possible corneal
damage. Skin: absorption from prolonged or massive skin contact may
cause poisoning. Repeated or pro longed contact may result in
defatting, redness, itching, inflammation, cracking. Inhilation:
may irritate the respiratory tract and mucous membranes. May cause
central nervous system symptoms. Ingest ion: primary toxic effects
are metabolic acidonis and visual damage (blindness). Severe
intoxication may cause hypoglycemia. Chronic: may cause changes in
liver, kidneys, brain, gi tract and heart mus cle. Symptoms may be
delayed.
explanation of carcinogenicity: not provided.
effects of overexposure: eye: may cause irritation. Direct contact may
cause pain, corneal inflammation and possible corneal damage. Skin:
absorption from prolonged or massive skin contact may cause
poisoning. Repeated or pro longed contact may result in defatting,
redness, itching, inflammation, cracking. Inhilation: may irritate
the respiratory tract and mucous membranes. May cause central
nervous system symptoms. Ingest ion: primary toxic effects are
metabolic acidonis and visual damage (blindness). Severe
intoxication may cause hypoglycemia.
medical cond aggravated by exposure: persons with pre-existing liver
impairment, skin and respiratory disorders may be at increase risk
from exposure.
First aid: eyes: flush with large amount of water for at least 15
minutes. Eyelids should be held away from the eyeball to ensure
thorough rinsing. Get medical attention. Skin: remove contaminated
clothing. Was h area of contact thoroughly with soap and water.
launder clothing before reuse. Get medical attention. Inhilation:
remove affected person from source of exposure. If not breathing,
ensure clear airwa y and institute cpr. If breathing is difficult,
administer oxygen and keep person warm and at rest. Get medical
attention. Ingestion: if conscious, give 1-3 glasses of water and
induce vomiting. Get m edical attention immediately.
Hcc: f5
nrc/state lic num: not relevant.
boiling pt: =65.C, 149.F
melt/freeze pt: m.P/f.P text: not applicable.
decomp temp: decomp text: not provided.
vapor pres: 100mmhg@212c
vapor density: 1.59
spec gravity: 0.7893
ph: not applicable.
viscosity: 1.22cps @ 20c/68f
evaporation rate & reference: >1(water=1)
solubility in water: complete
appearance and odor: clear, colorless volatile liquid with an ethereal
odor.
percent volatiles by volume: 100%
corrosion rate: not provided.
Stability indicator/materials to avoid: yes
acetyl bromide, calcium carbide, chlorine, chromic anhydride, cyanuric
chloride, dichloromethane, diethyl zinc, lead perchlorate,
magnesium, metals, strong oxidizers, perchloric acid, phosphorous
trioxide, potassium, sodiu
stability condition to avoid: not provided.
hazardous decomposition products: combustion may produce co and co2.
Waste disposal methods: this substance, when discarded or disposed of,
is a hazardous wate according to federal regulations (40 cfr 261).
disposal can occur only in properly permitted facilities.Check
state and local regulat ions for any additional requirements as
these may be more restrictive than federal law and regulatio ns.
Ingred name: methyl alcohol
cas: 67-56-1
rtecs #: pc1400000
= wt: 99.8
other rec limits: none
osha pel: 260 mg/m3;200 ppm
acgih tlv: 262 mg/m3;200 ppm
acgih stel: 328 mg/m3;250 ppm
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
ingred name: water
cas: 7732-18-5
rtecs #: zc0110000
fraction by wt: trace
other rec limits: none
osha pel: none
acgih tlv: none
Ld50 lc50 mixture: no data provided by responsible party
routes of entry: inhalation: yes skin: yes ingestion: no
health hazards acute and chronic: eye: may cause mild eye irritation.
symptoms include stinging, tearing & redness. Skin: may cause mild
skin irritation. Prolonged or repeated contact may dry the skin.
symptoms may include redness, bu rning, drying & cracking of skin,
skin burns. Passage of this material into the body through the skin
is possible & may add to toxic effects from breathing or
swallowing. Swallowing: swallowing this m aterial may be harmful.
inhalation: breathing of vapor or mist is possible. Breathing small
amounts of this material during normal handling is not likely to
cause harmful effects. Breathing large amou nts may be harmful.
explanation of carcinogenicity: no data.
effects of overexposure: stomach upset (nausea, vomiting, diarrhea),
irritation (nose, throat, airways), central nervous system
depression (dizziness, drowsiness, weakness, fatigue, nausea,
headache, unconsciousness), leg cr amps, pain in back and lower
abdomen, blurred vision, shortness of breath, cyanosis (bluish
skin), visual impairment (including blindness), coma, death.
medical cond aggravated by exposure: exposure to this material may
aggravate any preexisting condition sensitive to a decrease in
available oxygen, such as chronic lung disease, coronary artery
disease or anemias.
First aid: eyes: if symptoms develop, move individual away from exposure
and into fresh air. Flush eyes gently with water while holding
eyelids apart. If symptoms persist or there is any visual
difficulty, seek medical attention. Skin: remove contaminated
clothing. Wash exposed area with soap and water. If symptoms
persist, seek medical attention. Launder clothing before reuse.
swallowing: seek medical atten tion: if individual is drowsy or
unconscious, do not give anything by mough; place individual on the
left side with the head down. Contact a physician, medical
facility, or poison control center.
Hcc: f2
boiling pt: =-97.6c, -144.F
vapor pres: 97.680 mmhg @ 68f
vapor density: 1.11
spec gravity: 0.795 @ 68f
voc pounds/gallon: 795
ph: no data
viscosity: 0.6 cps
evaporation rate & reference: 2.10 (n-butyl acetate)
solubility in water: complete
appearance and odor: clear, mobile liquidneat, colorless, mild alcohol
odor
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
avoid contact with: reactive metals such as aluminum and magnesium,
strong acids, strong oxidizing agents.
stability condition to avoid: no data provided by responsible party
hazardous decomposition products: may form: carbon dioxide and carbon
monoxide.
conditions to avoid polymerization: will not occur.
Waste disposal methods: dispose of in accordance with all applicable
local, state and federal regulations. For assistance with yolur
waste management needs - including disposal, recycling and waste
stream reduction, contact ashland distribution company, ic&s
environmental services group at 800-637-7922.
Ingred name: methyl alcohol
cas: 67-56-1
rtecs #: pc1400000
= wt: 100.
osha pel: 260 mg/m3;200 ppm
acgih tlv: 262 mg/m3;200 ppm
acgih stel: 328 mg/m3;250 ppm
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: oral ld50: 9100 mg/kg in rats
routes of entry: inhalation: yes skin: yes ingestion: yes
health hazards acute and chronic: inhalation: inhalation of high
concentrations for prolonged periods has resulted in death. Liver
damage has resulted from prolonged or repeated inhalation of
vapors. Skin: essentially non-irritating. eyes: may cause eye
injury which may persist for several days. Ingestion: poisonous if
swallowed.
explanation of carcinogenicity: no data provided by manufacturer
effects of overexposure: iinhalation: dizziness, nausea, visual
impairment, respiratory failure, muscular incoordination &
narcosis. Skin: drying, brittleness, cracking, irritation. Eyes:
irritation, tearing, burning sensatio n. Ingestion: blindness,
mental sluggishness, nausea, vomiting, severe illness, possible
death.
medical cond aggravated by exposure: methanol exposure may aggravate
existing eye, skin, kidney and liver disorders. Prelacemen and
annual medical examinations are recommended for workers who
normally handale methanol .
First aid: inhalation: remove to fresh air. If not breathing, administer
cpr. If breathing is difficult, give oxygen. Call a physician.
skin: remove contaminated clothing. Wash contaminated skin with
large amoun ts of water. If irritation persists, contact a
physician. Eyes: flush eyes with water for at least 15 minutes.
contact a physician immediately. Ingestion: induce vomiting of
conscious patient immediate ly by giving two glasses of water and
pressing finger down throat. Drink a large amount of water, milk or
sodium bicarbonate to dilute material in stomach. Contact a
physician immediately.
Hcc: f5
boiling pt: =64.7c, 148.4f
vapor pres: 138@25c
vapor density: 1.1
spec gravity: 0.791
evaporation rate & reference: >1
solubility in water: 100%
percent volatiles by volume: 100
Stability indicator/materials to avoid: yes
reacts vigorously with strong oxidizers, chromix anhydride, lead
perchlorate, perchloric acids.
stability condition to avoid: avoid strong oxidizing agents, excessive
heat and ignition sources.
hazardous decomposition products: occures from heat and reaction with
above stated materials.
conditions to avoid polymerization: will not occur.
Waste disposal methods: this product when spilled or disposed is a
hazardous solid waste. Preferred method is incineration or
biological treatment in federal/state approved facility.
Ingred name: methanol or methyl alcohol
cas: 67-56-1
rtecs #: pc1400000
= wt: 99.9
osha pel: 260 mg/m3;200 ppm
acgih tlv: 262 mg/m3;200 ppm
acgih stel: 328 mg/m3;250 ppm
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: rat ld50: 5628 mg/kg
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: target organs: kidneys, central
nervous system, liver, cardiovascular system, eyes. eyes-causes
moderate eye irritation. skin-may cause irritation. May be
absorbed through the skin in harmful amount s. Ingestion-may cause
irritation of the digestive tract. May cause kidney failure.
inhalation-may cause respiratory tract irritation, liver and kidney
damage, adverse central nervous system effects. chronic: prolonged
or repeated skin contact may cause dermatitis. Chronic inhalation &
ingestion may cause effects similar to those of acute inhalation &
ingestion.
explanation of carcinogenicity: carcinogenicity: methyl alcohol, 99%.
not listed by acgih, iarc, niosh, ntp, or osha.
effects of overexposure: eyes: may cause painful sensitization to light.
ingestion: may cause respiratory failure, vascular collapse and
respiratory failure. Inhalation: may cause headache, convulsions,
possible death. may c ause visual impairment and possible
permanent blindness.
First aid: eye-flush with plenty of water for 15 mins, lifting upper &
lower lids. Get medical aid immediately. Do not rub or keep eyes
closed. Skin-flush with plenty of soap & water for 15 mins while
removing s oiled clothes & shoes. Get medical aid if irritation
develops or persists. Ingestion-if victim is conscious & alert,
give 2-4 cupfuls of milk or water. Get medical aid immediately.
induce vomiting by giving one teaspoon of syrup of ipecac.
inhalation-get medical aid immediately. Remove from exposure. If
not breathing, give artificial respiration. If breathing is
difficult, give oxygen. "see supple mental"
Hcc: f5
boiling pt: =64.8c, 148.6f
melt/freeze pt: =-98.C, -144.4f
vapor pres: 29mmhg
vapor density: 1.1
spec gravity: 0.7910g/cm3
ph: neutral
viscosity: 0.006p@68f
evaporation rate & reference: 5.2 ether=1
solubility in water: miscible
appearance and odor: clear colorless liquid; slight alcohol like odor
Stability indicator/materials to avoid: yes
oxidants, active metals, acetyl bromide, alkyl aluminum salts,
beryllium dihydride, carbon tetrachloride+metals, chloroform+heat,
chloroform+sodium hydroxide, cyanuric chloride, diethyl zinc,
nitric acid & potassium tertbut
stability condition to avoid: high temperatures, incompatible materials,
ignition sources.
hazardous decomposition products: carbon monoxide, carbon dioxide,
formaldehyde.
Waste disposal methods: disose of in a manner consistent with federal,
state & local regs. rcra d-series maximum concentration of
contaminant: not listed. Rcra d-series chronic toxicity reference
level: not listed. Rcra f-s eries: not listed. Rcra p-series: not
listed. rcra u-series: waste # u154 (ignitable). This materia l is
banned from land disposal according to rcra.
Ingred name: methyl alcohol; einecs#: 200-659-6.
cas: 67-56-1
rtecs #: pc1400000
minumum % wt: 99.
maxumum % wt: 100.
other rec limits: 200 ppm-niosh
osha pel: 200 ppm
acgih tlv: 262 mg/m3;200 ppm
acgih stel: 328 mg/m3
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs
Ld50 lc50 mixture: not provided
routes of entry: inhalation: yes skin: yes ingestion: yes
reports of carcinogenicity: ntp: no iarc: no osha: no
health hazards acute and chronic: immediate effects (acute). Eyes:
exposure to liquid or vapor may cause mild eye irritation. Symptoms
may include stinging, tearing and redness. Skin: exposure may cause
mild irritation. Prolonged skin contact may cause defatting and
dermatitus. Breathing: exposure to vapor or mist is possible.
vapors may cause irritation of the eyes, nose and throat and at
high concentrations can cause headache, d rowsiness, central
nervous system effect, narcosis and possibly death. Intentional
misuse by deliberately concentrating and inhaling vapors may be
harmful or fatal.
explanation of carcinogenicity: iarc, ntp, or osha does not list this
material or its components as a carcinogen.
effects of overexposure: irritation of eyes, nose and throat from
contact with vapor or liquid. Mild skin irritant. Excessive
exposure to vapors may cause respiratory tract irritation,
dizziness, central nervous system effect s, unconscious, narcosis,
respiratory failure and possibly death.
medical cond aggravated by exposure: not provided
First aid: if swallowed: do not induce vomiting, call a physician
immediately. Inhalation: remove person from exposure area, if
breathing has stopped, use mouth-to-mouth resuscitation and get
medical attention. Eye contact: flush with water until irritation
stops. If persists, get medical attention. Skin contact: wash with
soap and water. Clothing: immediately wash contaminated clothes
before reuse.
Hcc: f5
nrc/state lic num: not relevant
boiling pt: =64.7c, 148.4f
melt/freeze pt: m.P/f.P text: not provided
decomp temp: decomp text: not provided
vapor pres: 138@25c
vapor density: (air=1)1.1
spec gravity: 0.791
viscosity: not provided
evaporation rate & reference: >1
solubility in water: 100%
appearance and odor: not provided
percent volatiles by volume: 100.0
corrosion rate: not provided
Stability indicator/materials to avoid: yes
isolate from strong oxidizers such as permanganates, chromates &
peroxides.
stability condition to avoid: isolate from oxidizers, heat, sparks,
electric equipment & open flame.
hazardous decomposition products: co and co2 and smoke from combustion.
Waste disposal methods: dispose in chemical disposal area or in a manner
that complies with local, state, and federal regulation. Do not
incinerate closed containers.
Ingred name: methanol
cas: 67-56-1
rtecs #: pc1400000
= wt: 99.9
other rec limits: not provided
osha pel: 260 mg/m3;200 ppm
acgih tlv: 262 mg/m3;200 ppm
acgih stel: 328 mg/m3;250 ppm
epa rpt qty: 5000 lbs
dot rpt qty: 5000 lbs